CN203876331U - Hard coating film with double functions of fog resistance and glare resistance - Google Patents

Hard coating film with double functions of fog resistance and glare resistance Download PDF

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Publication number
CN203876331U
CN203876331U CN201420149576.XU CN201420149576U CN203876331U CN 203876331 U CN203876331 U CN 203876331U CN 201420149576 U CN201420149576 U CN 201420149576U CN 203876331 U CN203876331 U CN 203876331U
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China
Prior art keywords
cured film
dazzle
base material
layer
coating film
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Expired - Lifetime
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CN201420149576.XU
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Chinese (zh)
Inventor
陈凯
张美超
董红星
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Ningbo Huizhixing New Material Technology Co ltd
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Ningbo Hughstar Advanced Material Technology Co Ltd
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Abstract

The utility model belongs to the technical field of optical films, in particular relates to a hard coating film, and provides a hard coating film with double functions of fog resistance and glare resistance to overcome the defect that a conventional hard coating film is single in function. The hard coating film comprises a substrate, wherein an anti-fogging hardening layer is arranged on one side of the substrate; an anti-glare hardening layer is arranged on the other side of the substrate. Due to adoption of the hardening layer, moisture is effectively prevented from being fogged on the surface of the hard coating film, and the influence of moisture on the vision is eliminated; in addition, due to adoption of the anti-glare layer on the other side of the hard coating film, reflection of light can be effectively reduced, and the influence of glare on the vision is eliminated. Because of the two functions of fog resistance and glare resistance, the defect of the single function is made up, and thus the hard coating film can be widely applied to protecting films, cover plates and the like on liquid crystal display devices.

Description

A kind of have antifog and cured film anti-dazzle dual-use function
Technical field
The utility model belongs to cured film (Hard Coating Film) technical field, particularly relates to a kind of antifog and cured film anti-dazzle dual-use function that has.
Background technology
In modern industry is produced, the known method of preparing cured film is to apply hardening bath and through solidifying to form hardened layer, make it possess certain hardness and wearability on the film substrates such as PET, PC, PMMA.Aforementioned cured film has been widely used in the function protecting on the surfaces such as Mobile phone screen, touch display screen, LCDs, electrical equipment inscription plate, IMD in-mold decoration, instrument face plate, LGP, flat-panel monitor.At present, cured film kind is a lot, is divided into antistatic cured film, anti-scratch cured film, high rigidity cured film, antireflection cured film, anti-dazzle cured film, antifog cured film etc. by function, but the cured film of simple function can not meet market demand.
Summary of the invention
In order to overcome the defect of existing cured film function singleness, the utility model provides a kind of antifog and cured film anti-dazzle dual-use function that has.This cured film has antifog and dual-use function anti-dazzle.
In order to achieve the above object, the utility model adopts following technical proposals:
Have antifog and cured film anti-dazzle function, described cured film comprises base material, and a side of base material is provided with anti-fog layer, and the opposite side of base material is provided with anti-dazzle photosphere.The anti-fog layer of described cured film and anti-dazzle photosphere have higher hardness simultaneously, so anti-fog layer also can be described as antifog hardened layer.Anti-dazzle photosphere also can be described as anti-dazzle hardened layer.Described cured film is three-decker.
Further, described cured film is made up of base material, anti-fog layer and anti-dazzle photosphere, and described base material is arranged between described anti-fog layer and anti-dazzle photosphere.
Further, in above-mentioned cured film, described anti-fog layer is antifogging coating, and described anti-dazzle photosphere is Anti Glare Coatings.
Above-mentioned anti-fog layer coheres the side surface at base material by being coated with curing mode.Above-mentioned anti-dazzle photosphere coheres the opposite side surface at base material by being coated with curing mode.
Further, in above-mentioned cured film, the material of described base material is the one in PET, TAC, PC or PMMA, and the thickness of base material is 25-250 μ m.Further, the thickness of described base material is 100-150 μ m.
Further, in above-mentioned cured film, the material of described anti-fog layer is waterborne polyurethane resin, and thickness is 1-20 μ m.Described anti-fog layer adopts heat cure, UV to solidify or heat and the mixing cured mode solidified forming of UV.Further, the thickness of described anti-fog layer is 5-10 μ m.
Further, in above-mentioned cured film, the material of described anti-dazzle photosphere is polyurethane acrylic resin, and thickness is 1-20 μ m.Described anti-dazzle photosphere adopts heat cure, UV to solidify or heat and the mixing cured mode solidified forming of UV.Further, the thickness of described anti-dazzle photosphere is 10-15 μ m.
Further, in above-mentioned cured film, described anti-fog layer is formed by hydrophilic antifogging material.
Further, in above-mentioned cured film, described anti-dazzle photosphere comprises gluing layer, on gluing layer, coheres and has silica dioxide granule, and the material of described gluing layer is polyurethane acrylic resin, and the particle diameter of silica dioxide granule is 1-15 μ m.Further, the material footpath of described silica dioxide granule is 10-15 μ m.
Further, in above-mentioned cured film, described anti-fog layer is antifog film, and described anti-dazzle photosphere is antiglare film.
Further, in above-mentioned cured film, the material of described anti-fog layer is waterborne polyurethane resin, and the material of described anti-dazzle photosphere is polyurethane acrylic resin.
The preparation method of above-mentioned cured film is: first on the base material of 25-250 μ m, utilize the anti-dazzle photosphere that nick roller coat cloth a layer thickness is 1-20 μ m, solidify or heat and the mixing cured shaping of UV by heat cure, UV, utilize in the other one side of base material the anti-fog layer that nick roller coat cloth a layer thickness is 1-20 μ m again, solidify or heat and the mixing cured shaping of UV by heat cure, UV.
Compared with existing cured film, the cured film that the utility model provides is realized respectively anti-dazzle and antifog dual-use function on the two sides of same base material, has solved the deficiency of existing cured film function singleness.This cured film, owing to there being anti-fog layer, can effectively prevent that steam is at cured film surface knot mist, the impact of elimination steam on vision; In addition, the other one side of this cured film has anti-dazzle photosphere, can effectively reduce reflection of light, eliminates the impact of dazzle on vision.This cured film, owing to having antifog and two kinds of functions of anti-dazzle, has made up the deficiency of existing cured film function singleness, thereby can be applied even more extensively protector and the cover plate etc. in liquid crystal display device
Brief description of the drawings
Fig. 1 is for having of providing of the utility model is antifog and the structural representation of the cured film of anti-dazzle dual-use function.
Wherein, 1 is base material, and 2 is anti-fog layer, and 3 is anti-dazzle photosphere.
Detailed description of the invention
Below in conjunction with Figure of description, the application's technical scheme is described further.
As shown in Figure 1, what the utility model provided have, and antifog and cured film anti-dazzle dual-use function is made up of base material 1, anti-fog layer 2 and anti-dazzle photosphere 3, and described base material 1 is arranged between described anti-fog layer 2 and anti-dazzle photosphere 3.
Embodiment 1
Have antifog and cured film anti-dazzle dual-use function, as shown in Figure 1, be made up of base material 1, anti-fog layer 2 and anti-dazzle photosphere 3, described base material 1 is arranged between described anti-fog layer 2 and anti-dazzle photosphere 3.
Wherein, the material of described base material is PET film, and thickness is 100 μ m;
The material of described anti-fog layer is waterborne polyurethane resin (DSM R-960), and thickness is 3 μ m;
The material of described anti-dazzle photosphere is polyurethane acrylic resin (Sartomer CN968), and thickness is 5 μ m.Embodiment 2
Have antifog and cured film anti-dazzle dual-use function, as shown in Figure 1, be made up of base material 1, anti-fog layer 2 and anti-dazzle photosphere 3, described base material 1 is arranged between described anti-fog layer 2 and anti-dazzle photosphere 3.
Wherein, the material of described base material is TAC film, and thickness is 80 μ m;
The material of described anti-fog layer is waterborne polyurethane resin (DSM R-9649), and thickness is 10 μ m;
The material of described anti-dazzle photosphere is polyurethane acrylic resin (Sartomer CN9006), and thickness is 15 μ m.
Embodiment 3
Have antifog and cured film anti-dazzle dual-use function, as shown in Figure 1, be made up of base material 1, anti-fog layer 2 and anti-dazzle photosphere 3, described base material 1 is arranged between described anti-fog layer 2 and anti-dazzle photosphere 3.
Wherein, the material of described base material is PC film, and thickness is 248 μ m;
The material of described anti-fog layer is waterborne polyurethane resin (Bayer VPLS2150), and thickness is 17 μ m;
The material of described anti-dazzle photosphere is polyurethane acrylic resin (Changxing 6145-100), and thickness is 10 μ m.
Embodiment 4
What the application provided has antifog and cured film anti-dazzle dual-use function, and wherein, the material of described base material is PET, and thickness is 25 μ m.The material of described anti-fog layer is waterborne polyurethane resin (the special VTW1233 of cyanogen), and thickness is 1-2 μ m.The material of described anti-dazzle photosphere is polyurethane acrylic resin (Changxing 6145-100H), and thickness is 1-2 μ m.
Embodiment 5
What the application provided has antifog and cured film anti-dazzle dual-use function, and wherein, the material of described base material is PC, and thickness is 250 μ m.The material of described anti-fog layer is waterborne polyurethane resin (DSM R-9649), and thickness is 20 μ m.The material of described anti-dazzle photosphere is polyurethane acrylic resin (Sartomer CN968), and thickness is 20 μ m.
Embodiment 6
What the application provided has antifog and cured film anti-dazzle dual-use function, and wherein, the material of described base material is PC, and thickness is 150 μ m.The material of described anti-fog layer is waterborne polyurethane resin (Bayer VPLS2150), and thickness is 5 μ m.The material of described anti-dazzle photosphere is polyurethane acrylic resin (Changxing 6145-100H), and thickness is 8-10 μ m.
Embodiment 7
What the application provided has antifog and cured film anti-dazzle dual-use function, wherein, described anti-dazzle photosphere comprises gluing layer, on gluing layer, coheres and has silica dioxide granule, the material of described gluing layer is polyurethane acrylic resin (Changxing 6165), and the particle diameter of silica is 1-5 μ m.The material of described anti-fog layer is waterborne polyurethane resin (DSM R-960), and thickness is 12 μ m.The material of described base material is PC, and thickness is 150 μ m.
Embodiment 8
What the application provided has antifog and cured film anti-dazzle dual-use function, wherein, described anti-dazzle photosphere comprises gluing layer, on gluing layer, coheres and has silica dioxide granule, the material of described gluing layer is polyurethane acrylic resin (Sartomer CN9010), and the particle diameter of silica is 5-10 μ m.The material of described anti-fog layer is waterborne polyurethane resin (Bayer VPLS2150), and thickness is 10 μ m.The material of described base material is PET, and thickness is 188 μ m.
Embodiment 9
What the application provided has antifog and cured film anti-dazzle dual-use function, wherein, described anti-dazzle photosphere comprises gluing layer, on gluing layer, coheres and has silica dioxide granule, the material of described gluing layer is polyurethane acrylic resin (Changxing 6165), and the particle diameter of silica is 10-15 μ m.The material of described anti-fog layer is waterborne polyurethane resin (DSM R-9649), and thickness is 5 μ m.The material of described base material is PMMA, and thickness is 150 μ m.
Embodiment 10
What the application provided has antifog and cured film anti-dazzle dual-use function, and wherein, the material of described base material is PET, and thickness is 100 μ m.The material of described anti-fog layer is waterborne polyurethane resin (the special VTW1233 of cyanogen), and thickness is 5 μ m.The thickness of described anti-dazzle photosphere is 10 μ m.Described anti-dazzle photosphere comprises gluing layer, on gluing layer, coheres and has silica dioxide granule, and the material of described gluing layer is polyurethane acrylic resin (Changxing 6145-100H), and the particle diameter of silica is 10 μ m.
Existing of comparative example 1 has the antifog cured film of anti-fog function
Existing of comparative example 2 has the anti-dazzle cured film of anti-dazzle function
The test result of the main performance to the prepared cured film with antifog and anti-dazzle dual-use function of above-described embodiment and the single cured film of existing capability as shown in Table 1 and Table 2.
Performance test standard and the method for cured film are as follows,
1, anti-fog performance:
The 3cm place above that antifogging coating face is placed on to 60 DEG C of water of constant temperature, keeps 3 days, observes surface knot mist (condense and have tiny water droplet) situation, and not tying mist is qualified (O), and knot mist is defective (X);
2, anti-glare properties:
The WGT-S of Shanghai Shen Guang instrument and meter Co., Ltd light transmittance/mist degree analyzer;
3, pencil hardness:
GB GBT6739-2006 paint and varnish pencil method is measured hardness of paint film;
Table 1 the embodiment of the present application 1 to 4 is prepared has the test result of the main performance of the cured film of antifog and anti-dazzle dual-use function and the single cured film of existing capability
The test result of the main performance of the prepared cured film with antifog and anti-dazzle dual-use function of table 2 the embodiment of the present application 5-10
As table 1 and table 2 known, what the application provided have, and antifog and cured film anti-dazzle dual-use function has antifog property and anti-glare properties simultaneously, hardness is better simultaneously.
The above, be only preferred embodiment of the present invention, is not intended to limit protection scope of the present invention.Every equalization that content is done according to the present invention changes and modifies, and is all encompassed in the scope of the claims of the present invention.

Claims (10)

1. have antifog and cured film anti-dazzle function, it is characterized in that, described cured film comprises base material, and a side of base material is provided with anti-fog layer, and the opposite side of base material is provided with anti-dazzle photosphere.
2. cured film according to claim 1, is characterized in that, described cured film is made up of base material, anti-fog layer and anti-dazzle photosphere, and described base material is arranged between described anti-fog layer and anti-dazzle photosphere.
3. cured film according to claim 1 and 2, is characterized in that, described anti-fog layer is antifogging coating, and described anti-dazzle photosphere is Anti Glare Coatings.
4. cured film according to claim 1 and 2, is characterized in that, the material of described base material is the one in PET, TAC, PC or PMMA, and the thickness of base material is 25-250 μ m.
5. cured film according to claim 1 and 2, is characterized in that, the material of described anti-fog layer is waterborne polyurethane resin, and thickness is 1-20 μ m.
6. cured film according to claim 1 and 2, is characterized in that, the material of described anti-dazzle photosphere is polyurethane acrylic resin, and thickness is 1-20 μ m.
7. cured film according to claim 1 and 2, is characterized in that, described anti-fog layer is formed by hydrophilic antifogging material.
8. cured film according to claim 1 and 2, is characterized in that, described anti-dazzle photosphere comprises gluing layer, on gluing layer, coheres and has silica dioxide granule, and the material of described gluing layer is polyurethane acrylic resin, and the particle diameter of silica dioxide granule is 1-15 μ m.
9. cured film according to claim 1 and 2, is characterized in that, described anti-fog layer is antifog film, and described anti-dazzle photosphere is antiglare film.
10. cured film according to claim 1 and 2, is characterized in that, the material of described anti-fog layer is waterborne polyurethane resin, and the material of described anti-dazzle photosphere is polyurethane acrylic resin.
CN201420149576.XU 2014-03-28 2014-03-28 Hard coating film with double functions of fog resistance and glare resistance Expired - Lifetime CN203876331U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106405691A (en) * 2016-12-13 2017-02-15 江苏康耐特光学有限公司 Anti-fog optical resin lens and its preparation method
CN106739325A (en) * 2016-12-19 2017-05-31 登封市豫科玻璃技术有限公司 A kind of membrane screen with antifog anti-dazzle function
CN111100314A (en) * 2019-12-19 2020-05-05 合肥乐凯科技产业有限公司 Preparation method of anti-glare hardened film for polarizer

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106405691A (en) * 2016-12-13 2017-02-15 江苏康耐特光学有限公司 Anti-fog optical resin lens and its preparation method
CN106405691B (en) * 2016-12-13 2018-07-03 江苏康耐特光学有限公司 A kind of antifog optical resin lens and preparation method thereof
CN106739325A (en) * 2016-12-19 2017-05-31 登封市豫科玻璃技术有限公司 A kind of membrane screen with antifog anti-dazzle function
CN111100314A (en) * 2019-12-19 2020-05-05 合肥乐凯科技产业有限公司 Preparation method of anti-glare hardened film for polarizer
CN111100314B (en) * 2019-12-19 2022-05-03 合肥乐凯科技产业有限公司 Preparation method of anti-glare hardened film for polarizer

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Address after: 315000 building 4, 988 Qingfeng Road, Cicheng Town, Jiangbei District, Ningbo City, Zhejiang Province

Patentee after: Ningbo Huizhixing New Material Technology Co.,Ltd.

Address before: No. 1, Jingshi Road, High tech Industrial Park, Jiangbei District, Ningbo, Zhejiang 315031

Patentee before: NINGBO HUGHSTAR ADVANCED MATERIAL TECHNOLOGY Co.,Ltd.

CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20141015