CN106405691A - Anti-fog optical resin lens and its preparation method - Google Patents
Anti-fog optical resin lens and its preparation method Download PDFInfo
- Publication number
- CN106405691A CN106405691A CN201611142470.7A CN201611142470A CN106405691A CN 106405691 A CN106405691 A CN 106405691A CN 201611142470 A CN201611142470 A CN 201611142470A CN 106405691 A CN106405691 A CN 106405691A
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- film layer
- resin lens
- antifog
- stiffened
- fog
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- 239000011347 resin Substances 0.000 title claims abstract description 49
- 229920005989 resin Polymers 0.000 title claims abstract description 49
- 230000003287 optical effect Effects 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000011248 coating agent Substances 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims abstract description 6
- 239000010408 film Substances 0.000 claims description 81
- 239000010409 thin film Substances 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000003292 glue Substances 0.000 claims description 13
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 9
- 238000003618 dip coating Methods 0.000 claims description 8
- 238000002604 ultrasonography Methods 0.000 claims description 8
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 claims description 7
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 7
- 239000011159 matrix material Substances 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 239000002210 silicon-based material Substances 0.000 claims description 3
- 238000001771 vacuum deposition Methods 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 239000002086 nanomaterial Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 abstract description 79
- 238000000034 method Methods 0.000 abstract description 5
- 239000000758 substrate Substances 0.000 abstract description 4
- 230000035515 penetration Effects 0.000 abstract 5
- 239000012790 adhesive layer Substances 0.000 abstract 2
- 239000002390 adhesive tape Substances 0.000 abstract 1
- 238000007747 plating Methods 0.000 abstract 1
- 238000004506 ultrasonic cleaning Methods 0.000 abstract 1
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- 239000003595 mist Substances 0.000 description 4
- 229920002301 cellulose acetate Polymers 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 2
- 238000000016 photochemical curing Methods 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JHQVCQDWGSXTFE-UHFFFAOYSA-N 2-(2-prop-2-enoxycarbonyloxyethoxy)ethyl prop-2-enyl carbonate Chemical class C=CCOC(=O)OCCOCCOC(=O)OCC=C JHQVCQDWGSXTFE-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- 206010047513 Vision blurred Diseases 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 239000006117 anti-reflective coating Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- -1 polyethylene terephthalate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/113—Anti-reflection coatings using inorganic layer materials only
Abstract
The invention discloses an anti-fog optical resin lens and its preparation method. The lens comprises the following elements arranged in sequence: a resin lens substrate, a stiffened film layer, a penetration increasing and reflection reducing film layer, a connecting adhesive layer and an anti-fog film layer. The method further discloses a preparation method for the anti-fog optical resin lens, and the method comprises the following steps: conducting ultrasonic cleaning to the resin lens substrate; using an immersing and coating manner to plate for the stiffened film layer; under the vacuumed condition, plating on the stiffened layer the penetration increasing and reflection reducing film layer; and finally, coating the connecting adhesive layer onto the penetration increasing and reflection reducing film layer; and adhering the anti-fog film layer. The anti-fog film layer is prepared from a high-molecular hydrophilic film. According to the anti-fog optical resin lens of the invention, the optical transparent adhesive tape is used to have a penetration increasing and reflection reducing film layer and a high-molecular hydrophilic film adhered together, which means that without undermining the original functions of the resin lens, the penetration rate of the resin lens is increased while the reflection rate is reduced and that the lens has an anti-fog function.
Description
Technical field
The present invention relates to a kind of antifog optical resin lens.
The invention still further relates to a kind of preparation method of antifog optical resin lens.
Background technology
Compare with unorganic glass eyeglass, optical resin lens rely on the advantage of itself, such as lightweight, good toughness, price
Cheap etc., increasingly welcome by consumers in general.But the people of wearing spectacles is it can be seen that summer stops in air-conditioning
After staying a period of time, then one layer of fog is occurred on eyeglass when going out, lead to blurred vision, and wipe eyeglasses all do not see
Thing.Equally, to enter temperature higher within doors for winter colder from the outside environment, also droplet occurs, this just gives people on eyeglass
Life produce bring very big puzzlement.The principle forming droplet is that temperature reduction causes the water saturation of resin lens surface to steam
Air pressure is less than the steam partial pressure of in the air, makes steam coagulation become little water droplet.Therefore, between material surface and external environment
When there is the notable temperature difference, surface arises that water smoke even water droplet.
The main path that anti-fog effect will be reached at present has two aspects：
One is from thermodynamics, so that the little mist pearl that vapor is atomized generation is waved in the extremely short time and turns to vapor；Two
It is from material structure mechanism, study Small molecular surfactant antifoggant and long-acting macromolecule anti-fog coating, among this again
Have hydrophilic and hydrophobicity point.Hydrophilic, that is, reduce the water contact angle of resin lens skin covering of the surface, can be fast when there being water droplet to produce
Speed sprawls film forming, thus reaching anti-fog effect.Hydrophobicity, that is, increase the water contact angle on resin lens surface, produces when there being water droplet
When can drop down rapidly, little mist pearl will not be formed, thus reaching anti-fog effect.Both approaches have certain antifog effect
Really, but every kind of method all has respective pluses and minuses.Later approach makes substrate surface larger to the contact of water, makes water drops flows down
The thin film with anti-fog performance, the adhesive force with hydrophobic thin film and material main body passes through poor, substantially can not maintain
Anti- fog effect for a long time.Therefore, how a lot of researchs increases hydrophilic thus reaching anti-fog effect if all concentrating on.
Chinese patent 201410122579.9 provides a kind of preparation method of the antifog light-cured resin of long-acting hydrophilic, it
Prepare gained resin after netted double bond containing silicone oligomer and other acrylic monomerss copolymerization using sol-gal process, join
Make coating and can obtain larger polymeric coating layer, excellent water resistance after photocuring.Chinese patent 201310565802.2 is public
Open a kind of preparation method of high refractive power anti-fog thin film coating, be first prepared into for primary raw material with isophorone diisocyanate etc.
To high refractive power hydrophilic UV performed polymer, resynthesis prepare TiO2Colloidal sol, finally above two synthesis material in TMPTA, light
Initiator 819 and 1-Methyl-2-Pyrrolidone mixing and stirring, coat film forming, after solvent is evaporated completely, in UV illumination
Under can get high refractive power anti-fog thin film.Chinese patent 201510318690.X relate to a kind of superficial film and stores the hydrophilic factor
The manufacture method of antifog resin lens, is made up of resin substrate, stiffened save mesh film layer, hydrophilic factor slow release antifog film, tool
Body step includes：1) prepare silica surface hardening liquid, 2) prepare hydrophilic antifogging liquid, 3) print stiffened save mesh film layer figure
Case, 4) lens surface applies hydrophilic antifogging liquid and drying.
A lot of schemes are attained by certain anti-fog effect, but in actually used resin lens, resin lens due to
Hardness itself is inadequate, rub resistance is poor, can plate one layer of stiffened film layer first by the way of dip-coating；Then, in order to increase further
Plus the transmitance of light and the reflection reducing light and effect attractive in appearance, one layer of anti-reflection antireflective coating can be coated with stiffened film layer
Layer, main material is silicon oxide, zirconium oxide, tin indium oxide etc., and color is based on partial veil, blue film, yellowish green film.But, if
It may appear that problem if being coated with antifog film layer in these film layers.If adopting the antifog film layer of heat cure, when temperature is more than 50 DEG C
When, anti-reflection antireflection film layer is different due to the coefficient of thermal expansion of various materials, can produce film and split；If adopting photocuring antifog film
If layer, the antifog film adhesion that it produces is not so good, easy to fall off.
Accordingly, it is desirable to provide a kind of new technical scheme is solving the above problems.
Content of the invention
The technical problem to be solved in the present invention is to provide a kind of antifog optical resin lens.
Present invention technical problem also to be solved is to provide a kind of preparation method of antifog optical resin lens.
For solving above-mentioned technical problem, a kind of antifog optical resin lens of the present invention, it includes resin lens base successively
Body, stiffened film layer, anti-reflection antireflection film layer, connection glue-line and antifog film layer, described stiffened film layer adopts silicone-based materials to lead to
Cross the mode plated film of dip-coating；Described connection glue-line is optical clear glue；Described antifog film layer is high molecular weight hydrophilic thin film.
Described anti-reflection antireflection film layer adopts vacuum coating, and raw material is silicon oxide, zirconium oxide, tin indium oxide.
The thickness of described antifog film layer is in 10-50 micron.
Described stiffened film layer adopts organic-inorganic hybrid nano material, and main component is nano metal oxide silicon and organosilicon
Resin.
The preparation method of a kind of antifog optical resin lens of the present invention, its preparation method includes step in detail below：
The first step, after the cleaning of resin lens ultrasound wave, plates stiffened film layer by the way of dip-coating；
Second step, under vacuum, plates anti-reflection antireflection film layer in stiffened film layer, according to film layer need adjust silicon oxide,
Zirconium oxide and the thickness of tin indium oxide, conventional film layer mainly has partial veil, blue film and anti-blue light film.Taking partial veil as a example, every thickness degree
As follows：1st tunic silicon oxide layer thickness is 170 nanometers；2nd 40 nanometers of tunic zirconia layer；3rd tunic silicon oxide layer thickness is
8 nanometers；4th tunic zirconia layer thickness is 75 nanometers；5th tunic indium tin oxide layer thickness is 6.5 nanometers；6th tunic oxidation
Silicon layer thickness is 95 nanometers；
3rd step, after resin lens are cleaned by ultrasonic totally, on anti-reflection antireflection film layer, first coats connection glue-line, connects glue-line
Using optical clear glue, then it is stained with antifog film layer, antifog film layer adopts high molecular weight hydrophilic thin film.
Beneficial effects of the present invention：By optical clear glue, anti-reflection antireflection film layer and high molecular weight hydrophilic thin film are bondd
Together, on the basis of not affecting resin lens original function, that is, increase the transmitance of light and the reflectance reducing light, have again
For anti-fog performance newly, and the optical clear glue using and high molecular weight hydrophilic thin film do not interfere with resin lens refractive index.
Therefore, this resin lens feature is higher, and market prospect is more preferable.
Brief description
Fig. 1 is present configuration schematic diagram.
1st, resin lens matrix, 2, stiffened film layer, 3, anti-reflection antireflection film layer, 4, connect glue-line, 5, antifog film layer.
Specific embodiment
In order to deepen the understanding of the present invention, below the invention will be further described, this embodiment be only used for explain this
Invention, does not constitute the restriction to protection scope of the present invention.
A kind of antifog optical resin lens of the present invention, it includes resin lens matrix 1 successively, stiffened film layer 2, anti-reflection subtracts
Reflective coating 3, connection glue-line 4, antifog film layer 5.
Stiffened film layer 2 plated film by the way of silicone-based materials are by dip-coating, stiffening layer thickness is 2.0 ~ 3.5 microns.
Anti-reflection antireflection film layer 3 adopts vacuum coating, and raw material is silicon oxide, zirconium oxide, tin indium oxide, according to film layer need
The thickness of silicon oxide to be adjusted, zirconium oxide and tin indium oxide, conventional film layer mainly has partial veil, blue film and anti-blue light film.With partial veil
As a example, every thickness degree is as follows：1st tunic silicon oxide layer thickness is 170 nanometers；2nd 40 nanometers of tunic zirconia layer；3rd tunic
Silicon oxide layer thickness is 8 nanometers；4th tunic zirconia layer thickness is 75 nanometers；5th tunic indium tin oxide layer thickness is received for 6.5
Rice；6th tunic silicon oxide layer thickness is 95 nanometers.
Connecting glue-line 4 is optical clear glue；Antifog film layer 5 is high molecular weight hydrophilic thin film, and thickness is at 10 ~ 50 microns.
Embodiment 1
Selection resin lens matrix 1 is diallyl diglycol carbonate esters (CR39), first after ultrasound wave cleaning, using leaching
Painting mode plates stiffened film layer 2；Then, under vacuum, it is coated with anti-reflection antireflection film layer 3, the color choosing according to needed for film layer
Select order and the thickness of raw material；Again after ultrasound wave cleaning, Merlon (PC) is selected to be high molecular weight hydrophilic thin film as anti-
Mist film layer 5, thickness is 10 microns, is used optical clear glue OCA glue as connecting glue-line 4, PC thin film is sticked to anti-reflection
On antireflection film layer 3, cold curing.
Embodiment 2
Select resin lens matrix 1 to be unsaturated esters of acrylic acid, first after ultrasound wave cleaning, stiffened is plated using dip coating manner
Film layer 2；Then, under vacuum, be coated with anti-reflection antireflection film layer 3, the color selecting raw material according to needed for film layer suitable
Sequence and thickness；Again after ultrasound wave cleaning, polyethylene terephthalate (PET) is selected to be high molecular weight hydrophilic thin film as anti-
Mist film layer 5, thickness is 50 microns, is used optical clear glue OCA glue as connecting glue-line 4, PET film is sticked to anti-reflection
On antireflection film layer, cold curing.
Embodiment 3
Selection resin lens matrix 1 is polyurethaness, first after ultrasound wave cleaning, plates stiffened film layer 2 using dip coating manner；So
Afterwards, under vacuum, it is coated with anti-reflection antireflection film layer 3, the order of color selecting raw material according to needed for film layer and thickness；
Again after ultrasound wave cleaning, select cellulose acetate (CA) for high molecular weight hydrophilic thin film as antifog film layer 5, thickness is micro- for 30
Rice, is used optical clear glue OCA glue as connecting glue-line 4, CA thin film is sticked on anti-reflection antireflection film layer, room temperature is solid
Change.
Light transmittance detects：Detected using ultraviolet-uisible spectrophotometer；
Rub resistance is tested：Uniformly exerted oneself on the surface of eyeglass with cleaning cloth for glasses, wipe 500 times back and forth, resin lens film layer is not sent out
Hair is spent, substantially unchanged；
Anti-fog performance detects：Ocular estimate：Resin lens are put in and fill at about 10cm above 50 DEG C of thermostat water bath, 5 minutes
Whether interior viewing lens surface hazes；
Resin lens obtained by embodiment 1 to 3 are measured its light transmittance, wearability and anti-fog properties respectively.Embodiment 1
Transmitance 95.62%, wearability and anti-fog properties qualified, the transmitance 92.37% of embodiment 2, wearability and anti-fog properties qualified, enforcement
The transmitance 90.86% of example 3, wearability and anti-fog properties qualified.
Claims (5)
1. a kind of antifog optical resin lens are it is characterised in that it includes resin lens matrix successively, stiffened film layer, anti-reflection subtract
Reflective coating, connection glue-line and antifog film layer, described stiffened film layer plated film by the way of silicone-based materials are by dip-coating；Institute
Stating connection glue-line is optical clear glue；Described antifog film layer is high molecular weight hydrophilic thin film.
2. a kind of antifog optical resin lens according to claim 1 it is characterised in that：Described anti-reflection antireflection film layer is adopted
With vacuum coating, raw material is silicon oxide, zirconium oxide, tin indium oxide.
3. a kind of antifog optical resin lens according to claim 1 it is characterised in that：The thickness of described antifog film layer exists
10-50 micron.
4. a kind of antifog optical resin lens according to claim 1 it is characterised in that：Described stiffened film layer adopts organic
Inorganic hybrid nano-material, main component is nano metal oxide silicon and organic siliconresin.
5. a kind of preparation method of antifog optical resin lens according to claim 1 is it is characterised in that its preparation method
Including step in detail below：
The first step, after the cleaning of resin lens ultrasound wave, plates stiffened film layer by the way of dip-coating；
Second step, under vacuum, plates anti-reflection antireflection film layer in stiffened film layer, according to Film color adjust silicon oxide,
The thickness of zirconium oxide and tin indium oxide and order；
3rd step, after resin lens are cleaned by ultrasonic totally, on anti-reflection antireflection film layer, first coats connection glue-line, connects glue-line
Using optical clear glue, then it is stained with antifog film layer, antifog film layer adopts high molecular weight hydrophilic thin film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611142470.7A CN106405691B (en) | 2016-12-13 | 2016-12-13 | A kind of antifog optical resin lens and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611142470.7A CN106405691B (en) | 2016-12-13 | 2016-12-13 | A kind of antifog optical resin lens and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106405691A true CN106405691A (en) | 2017-02-15 |
| CN106405691B CN106405691B (en) | 2018-07-03 |
Family
ID=58084900
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108398734A (en) * | 2018-04-03 | 2018-08-14 | 江苏俊联光学眼镜科技有限公司 | A kind of coating Anti-fog glasses piece and preparation method |
| CN108490514A (en) * | 2018-07-03 | 2018-09-04 | 佛山王氏航空光学科技有限公司 | A kind of antifog transparent face mask of aspheric curve plastics heat conduction |
| CN108549120A (en) * | 2018-06-28 | 2018-09-18 | 江苏万新光学有限公司 | A kind of yellowish green film resin eyeglass of anti-reflection anti-reflection and its production technology |
| CN109143610A (en) * | 2018-09-28 | 2019-01-04 | 镇江奥视达光学有限公司 | A kind of fog-proof lens and preparation method thereof |
| CN109337321A (en) * | 2018-08-14 | 2019-02-15 | 江苏硕延光学眼镜有限公司 | A kind of antifog optical resin lens of high-performance and preparation method thereof |
| CN110187416A (en) * | 2019-07-06 | 2019-08-30 | 丹阳市宏鑫光学眼镜有限公司 | A kind of coating fog-proof lens |
| CN112285810A (en) * | 2020-11-20 | 2021-01-29 | 厦门谨德光电科技有限公司 | Antifogging and oil-stain-preventing lens with high light transmittance and preparation method thereof |
| CN112305780A (en) * | 2020-10-30 | 2021-02-02 | 江苏康耐特光学有限公司 | High anti-reflection coating film antifogging resin lens |
| CN112505804A (en) * | 2020-11-25 | 2021-03-16 | 湖北长旭光电科技有限公司 | Optical lens and manufacturing method thereof |
| CN112578482A (en) * | 2020-12-08 | 2021-03-30 | 江苏全真光学科技股份有限公司 | Color-changing lens and preparation method thereof |
| CN112630870A (en) * | 2020-12-04 | 2021-04-09 | 明月镜片股份有限公司 | Long-acting wear-resistant antifogging lens coating and preparation method thereof |
| WO2021113857A1 (en) * | 2019-12-02 | 2021-06-10 | Ripclear Llc | Anti-fog lens covering systems |
| CN112946920A (en) * | 2021-01-29 | 2021-06-11 | 深圳市宏海福新材料有限公司 | Wear-resistant anti-fog easy-to-clean resin spectacle lens and manufacturing method thereof |
| CN113835141A (en) * | 2021-11-08 | 2021-12-24 | 厦门谨德光电科技有限公司 | Fade-proof ultraviolet-resistant sunglasses lens |
| CN115505253A (en) * | 2022-10-18 | 2022-12-23 | 烟台佳隆纳米产业有限公司 | Heat absorption type antifogging lens and preparation process thereof |
| CN115975508A (en) * | 2022-12-22 | 2023-04-18 | 惠州市日大实业有限公司 | Photocuring antifogging wear-resistant layer material, photocuring antifogging antireflection coating and preparation method thereof |
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| CN202008536U (en) * | 2011-03-23 | 2011-10-12 | 云南汇恒光电技术有限公司 | Hydrophobic antifog lens |
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