The specific embodiment
Embodiment 1
A kind of metal piercing formula used for solar batteries backboard, include successively insulating barrier, metal level, tack coat, substrate layer and weathering layer, described weathering layer is coated on substrate layer by coating apparatus, this weathering layer is fluororesin composition, and this fluororesin composition includes by quality 100%:
Modified fluorin resin 46%;
Aerosil 4%;
Titanium dioxide 15 %;
Curing agent 5%;
Butyl ester 30%.
Described modified fluorin resin is for carrying out the vinylidene fluoride copolymers of modification with carboxylic acid group and two groups of hydroxyl.
This curing agent is polyisocyanates.
This substrate layer is PETG.
This tack coat is epoxyn.
This metal level is Copper Foil.
This insulating barrier is that epoxy resin ink is coated on metal level by serigraphy, is then solidified into insulating barrier.
The thickness of this weathering layer is 20 μ m.
The preparation method of this metal piercing formula used for solar batteries backboard, includes following steps:
First prepare fluororesin composition, modified fluorin resin 46%, aerosil 4%, titanium dioxide 15 %, curing agent 5 % and solvent 30% are mixed;
Then by scraper for coating method, a surface of fluororesin composition being coated to substrate layer is upper, after baking oven baking-curing, forms weathering layer;
Then on another surface of substrate layer, be coated with tack coat, then hot pressing laminating metal level on tack coat;
Finally after metal level printed wiring, serigraphy insulating barrier in the above.
Embodiment 2
A kind of metal piercing formula used for solar batteries backboard, include successively insulating barrier, metal level, tack coat, substrate layer and weathering layer, described weathering layer is coated on substrate layer by coating apparatus, this weathering layer is fluororesin composition, and this fluororesin composition includes by quality 100%:
Modified fluorin resin 25%;
Aerosil 2%;
Titanium dioxide 20 %;
Curing agent 8 %;
Butyl ester 45%.
This modified fluorin resin is for carrying out the hexafluoropropene homopolymers of modification with carboxylic acid group.
This curing agent is hydrogenated diphenyl methane diisocyanate.
This substrate layer is polybutylene terephthalate (PBT).
This tack coat is saturated polyester adhesive.
This metal level is aluminium foil.
This insulating barrier is that mylar ink is coated on metal level by serigraphy, is then solidified into insulating barrier.
The thickness of this weathering layer is 25 μ m.
The preparation method of this metal piercing formula used for solar batteries backboard, comprises the steps:
First prepare fluororesin composition, modified fluorin resin 25%, aerosil 2%, titanium dioxide 20 %, curing agent 8 % and solvent 45 % are mixed;
Then by scraper for coating method, a surface of fluororesin composition being coated to substrate layer is upper, after baking oven baking-curing, forms weathering layer;
Then on another surface of substrate layer, be coated with tack coat, then hot pressing laminating metal level on tack coat;
Finally after metal level printed wiring, serigraphy insulating barrier in the above.
Embodiment 3
A kind of metal piercing formula used for solar batteries backboard, include successively insulating barrier, metal level, tack coat, substrate layer and weathering layer, described weathering layer is coated on substrate layer by coating apparatus, this weathering layer is fluororesin composition, and this fluororesin composition includes by quality 100%:
Modified fluorin resin 35%;
Aerosil 3%;
Titanium dioxide 25%;
Curing agent 5 %;
Butyl ester 32%.
This modified fluorin resin is for using aziridine base proplast.
This curing agent is hexamethylene diisocyanate.
This substrate layer is PEN.
This tack coat is polyurethane adhesive.
This metal level is Copper Foil.
This insulating barrier is that epoxy resin ink, mylar ink or acrylic resin ink are coated on metal level by serigraphy, is then solidified into insulating barrier.
The thickness of this weathering layer is 22 μ m.
The preparation method of this metal piercing formula used for solar batteries backboard, first prepares fluororesin composition, and modified fluorin resin 35%, aerosil 3%, titanium dioxide 25 %, curing agent 5 % and solvent 32 % are mixed;
Then by scraper for coating method, a surface of fluororesin composition being coated to substrate layer is upper, after baking oven baking-curing, forms weathering layer;
Then on another surface of substrate layer, be coated with tack coat, then hot pressing laminating metal level on tack coat;
Finally after metal level printed wiring, serigraphy insulating barrier in the above.
Embodiment 4
A kind of metal piercing formula used for solar batteries backboard, include successively insulating barrier, metal level, tack coat, substrate layer and weathering layer, described weathering layer is coated on substrate layer by coating apparatus, this weathering layer is fluororesin composition, and this fluororesin composition includes by quality 100%:
Modified fluorin resin 45%;
Aerosil 3%;
Titanium dioxide 10 %;
Curing agent 2%;
Butyl ester 30%.
This modified fluorin resin is for carrying out the copolymer of the tetrafluoroethene of modification with carboxylic acid group and sulfonic group two groups.
This curing agent is IPDI.
This substrate layer is PETG.
This tack coat is acrylic resin adhesive.
This metal level is Copper Foil.
This insulating barrier is that epoxy resin ink is coated on metal level by serigraphy, is then solidified into insulating barrier.
The thickness of this weathering layer is 25 μ m.
The preparation method of this metal piercing formula used for solar batteries backboard, includes following steps:
First prepare fluororesin composition, modified fluorin resin 45%, aerosil 3%, titanium dioxide 10 %, curing agent 2% and solvent 30 % are mixed;
Then by scraper for coating method, a surface of fluororesin composition being coated to substrate layer is upper, after baking oven baking-curing, forms weathering layer;
Then on another surface of substrate layer, be coated with tack coat, then hot pressing laminating metal level on tack coat;
Finally after metal level printed wiring, serigraphy insulating barrier in the above.
Embodiment 5
A kind of metal piercing formula used for solar batteries backboard, include successively insulating barrier, metal level, tack coat, substrate layer and weathering layer, described weathering layer is coated on substrate layer by coating apparatus, this weathering layer is fluororesin composition, and this fluororesin composition includes by quality 100%:
Modified fluorin resin 40%;
Aerosil 3%;
Titanium dioxide 15%;
Curing agent 10%;
Butyl ester 32 %.
This modified fluorin resin is the homopolymers with aziridine base vinylidene.
This curing agent is hydrogenated diphenyl methane diisocyanate.
This substrate layer is PETG.
This tack coat is polyurethane adhesive.
This metal level is Copper Foil.
This insulating barrier is that mylar ink is coated on metal level by serigraphy, is then solidified into insulating barrier.
The thickness of this weathering layer is 20 μ m.
The preparation method of this metal piercing formula used for solar batteries backboard, includes following steps:
First prepare fluororesin composition, modified fluorin resin 40%, aerosil 3%, titanium dioxide 15 %, curing agent 10 % and solvent 32 % are mixed;
Then by scraper for coating method, a surface of fluororesin composition being coated to substrate layer is upper, after baking oven baking-curing, forms weathering layer;
Then on another surface of substrate layer, be coated with tack coat, then hot pressing laminating metal level on tack coat;
Finally after metal level printed wiring, serigraphy insulating barrier in the above.
Embodiment 6
A kind of metal piercing formula used for solar batteries backboard, include successively insulating barrier, metal level, tack coat, substrate layer and weathering layer, described weathering layer is coated on substrate layer by coating apparatus, this weathering layer is fluororesin composition, and this fluororesin composition includes by quality 100%:
Modified fluorin resin 35%;
Aerosil 1%;
Titanium dioxide 10%;
Curing agent 4%;
Solvent 50 %.
This modified fluorin resin is isocyanate base hexafluoropropene homopolymers.
This curing agent is IPDI.
This substrate layer is PETG.
This tack coat is acrylic resin adhesive.
This metal level is nickel foil.
This insulating barrier is that epoxy resin ink is coated on metal level by serigraphy, is then solidified into insulating barrier.
The thickness of this weathering layer is 23 μ m.
The preparation method of this metal piercing formula used for solar batteries backboard, comprises the steps:
First prepare fluororesin composition, modified fluorin resin 35%, aerosil 1%, titanium dioxide 10 %, curing agent 4 % and solvent 50 % are mixed;
Then by scraper for coating method, a surface of fluororesin composition being coated to substrate layer is upper, after baking oven baking-curing, forms weathering layer;
Then on another surface of substrate layer, be coated with tack coat, then hot pressing laminating metal level on tack coat;
Finally after metal level printed wiring, serigraphy insulating barrier in the above.
Embodiment 7
A kind of metal piercing formula used for solar batteries backboard, include successively insulating barrier, metal level, tack coat, substrate layer and weathering layer, described weathering layer is coated on substrate layer by coating apparatus, this weathering layer is fluororesin composition, and this fluororesin composition includes by quality 100%:
Modified fluorin resin 50%;
Aerosil 2%;
Titanium dioxide 13 %;
Curing agent 5 %;
Solvent 30 %.
This modified fluorin resin is active methylene group vinylidene fluoride homopolymer.
This curing agent is polyisocyanates.
This substrate layer is polybutylene terephthalate (PBT).
This tack coat is epoxyn.
This metal level is aluminium foil.
This insulating barrier is that mylar ink is coated on metal level by serigraphy, is then solidified into insulating barrier.
The thickness of this weathering layer is 25 μ m.
A preparation method for metal piercing formula used for solar batteries backboard, first prepares fluororesin composition, and modified fluorin resin 50%, aerosil 2%, titanium dioxide 13 %, curing agent 5 % and solvent 30 % are mixed;
Then by scraper for coating method, a surface of fluororesin composition being coated to substrate layer is upper, after baking oven baking-curing, forms weathering layer;
Then on another surface of substrate layer, be coated with tack coat, then hot pressing laminating metal level on tack coat;
Finally after metal level printed wiring, serigraphy insulating barrier in the above.
Comparative example
A kind of metal piercing formula used for solar batteries backboard, include successively insulating barrier, metal level, tack coat, substrate layer and weathering layer, described weathering layer is coated on substrate layer by coating apparatus, this weathering layer is fluororesin composition, and this fluororesin composition includes by quality 100%:
Fluorine resin 35%;
Aerosil 1%;
Titanium dioxide 10%;
Curing agent 4%;
Solvent 50 %.
Fluorine resin is vinylidene (PVDF) and copolymer, tetrafluoroethene and the tetrafluoroethene of vinylidene and alkyl vinyl ether (ester) and the copolymer of alkyl vinyl ether (ester).
This curing agent is hexamethylene diisocyanate.
This substrate layer is PETG.
This tack coat is acrylic resin adhesive.
This metal level is nickel foil.
This insulating barrier is that epoxy resin ink is coated on metal level by serigraphy, is then solidified into insulating barrier.
The thickness of this weathering layer is 23 μ m.
The preparation method of this metal piercing formula used for solar batteries backboard, comprises the steps:
First prepare fluororesin composition, modified fluorin resin 35%, aerosil 1%, titanium dioxide 10 %, curing agent 4 % and solvent 50 % are mixed;
Then by scraper for coating method, a surface of fluororesin composition being coated to substrate layer is upper, after baking oven baking-curing, forms weathering layer;
Then on another surface of substrate layer, be coated with tack coat, then hot pressing laminating metal level on tack coat;
Finally after metal level printed wiring, serigraphy insulating barrier in the above.
The test result of above characteristic is as follows:
Above-mentioned performance test is adopted with the following method:
(1) adopt GB1037-1988 method to carry out moisture-vapor transmission test, be shown in Table 2;
(2) adopt the open method of solar cell authentication/solar photovoltaic cell panel IEC61215, embodiment and comparative example are tested, test condition is: 85 ℃ of temperature, and relative humidity 85%RH, more than time 1000hrs, glue face has delamination, foaming defective; Otherwise, qualified;
(3) adopt IEC61730-2/IEC60664-1 and ASTM D149-97a method to carry out respectively shelf depreciation and electrical breakdown test to embodiment and comparative example;
(4) according to IEC61215-2005, GB/T16422.3-1997, embodiment and comparative example are carried out to resistance to ultraviolet test, glue face has xanthochromia defective; Without xanthochromia, qualified;
(5) according to the cross cut test > > of standard GB/T/T 9286-1998 < < paint and varnish paint film, measure:
In sum, by apply one deck modified fluorin resin weathering layer on backboard, make the metal piercing formula used for solar batteries backboard making there is lower moisture-vapor transmission and higher anti-electrical breakdown performance; Simultaneously, this backboard has stronger weatherability, uvioresistant and heat resistance performance, wherein, by using modified fluorin resin weathering layer, resulting weathering layer has good tack to substrate layer, and this tack is used non-modified fluoride-containing resin weathering layer not compare.Owing to adopting modified fluorin resin weathering layer and substrate layer to there is stronger adhesive force; the middle adhesive that does not need to add other; make this weathering layer thinner identical protection effect that just can reach that becomes; thereby reduce associated materials and simplified production technology, having reduced product cost, improved the competitiveness of product in market.
The above, it is only preferred embodiment of the present utility model, not technical scope of the present utility model is imposed any restrictions, therefore every foundation technical spirit of the present utility model, to any trickle modification made for any of the above embodiments, equivalent variations and modification, all still belongs in the scope of technical solutions of the utility model.