CN202651171U - Flexible-solar-cell high-reflection combination structure - Google Patents

Flexible-solar-cell high-reflection combination structure Download PDF

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Publication number
CN202651171U
CN202651171U CN 201220148120 CN201220148120U CN202651171U CN 202651171 U CN202651171 U CN 202651171U CN 201220148120 CN201220148120 CN 201220148120 CN 201220148120 U CN201220148120 U CN 201220148120U CN 202651171 U CN202651171 U CN 202651171U
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China
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layer
solar battery
composite construction
reflector
flexible solar
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CN 201220148120
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董清世
辛崇飞
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Xinyi Glass Engineering (Dongguan) Co Ltd
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Xinyi Glass Engineering (Dongguan) Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/52PV systems with concentrators

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Abstract

The utility model relates to a flexible-solar-cell high-reflection combination structure, comprising a base layer and a reflection layer. An ion implantation layer is arranged between the base layer and the reflection layer. The surface of the reflection layer is equipped with a protection layer. Through the formation of the ion implantation layer between the base layer and the reflection layer, the binding force of the reflection layer and base layer is increased. The protection layer isolates the reflection layer from peripheral atmosphere, guaranteeing the reflection performance and enhancing the stability and the durability of the high-reflection combination structure, which can be widely applied to flexible solar cells.

Description

The high reflection of a kind of flexible solar battery composite construction
Technical field
The utility model is specifically related to the high reflection of a kind of flexible solar battery composite construction about technical field of solar batteries.
Background technology
21 century is forming comprehensively more and more serious energy crisis, and traditional fossil fuel energy is developed by transition, is faced with exhaustion, and its use has serious and ever-increasing negative effect, such as CO 2Discharging, global warming, air pollution etc.For this reason, countries in the world have all been put into effect some relevant policy and rules and have been dealt with, and propose " U.S.'s clean energy resource and safe bill " in 2009 such as the U.S., and China has proposed the model of social economy of " sustainable development " and " low-carbon economy ".Under such background, research, the development and utilization of the regenerative resource of taking as the leading factor with solar energy obtains paying attention to day by day.Solar energy is compared other energy many advantages: energy is huge, and sunlight is the energy (4.3 * 10 of the directive earth per hour 20J) whole energy (4.1 * 10 of just consuming in 1 year greater than the earth 20J); Inexhaustible; Do not discharge any greenhouse gas, do not have noise, minimum on the impact of environment, be a kind of green energy resource; The distribution extend over the entire globe, regional limits is little; Can distributed energy supply, reliability is high.The development and use of solar energy have become the important component part of society energy strategy, to the abundant development and utilization of solar energy, be unable to do without the development of solar energy materials and technology.
Solar energy is a kind of low-density energy, and the solar energy reflection material can will reach the sunlight enrichment, and changed course in order to utilize to greatest extent solar energy, is the important material of a class in the solar thermal utilization of solar energy.At present, the solar energy reflection material is at solar power system (heat or photovoltaic generation), be widely used in the high temperature application system in the solar energy such as solar water heater, solar cooker, particularly for solar heat power generation system, the optically focused subsystem comprises that heliostat group and tracking means bringing into play vital effect, its cost accounts for the over half of total input, and the quality of reflecting material has directly determined the cost of hot generating.For a good solar energy reflection material, it should satisfy following requirement: 1. high solar reflectance (photo-thermal: 300 ~ 2500 nm, photovoltaic: the silion cell visible light); 2. the support low price of reflecting material and it; 3. quality is light, easily install, and long service life, concerning photo-thermal power generation and photovoltaic generation, useful life is at least more than 20 years.4. wind resistance, anti-crushing by snow, the anti-vibration ability is strong and should have good anti-mechanical stress characteristic, to adapt to the periodic cleaning to mirror surface; 5. be designed beautifully, environmentally friendly, do not contain poisonous harmful substance.
The utility model content
In view of this, provide the adhesion of a kind of reflector and basic unit strong, stablize the high reflection of lasting flexible solar battery composite construction.
The high reflection of a kind of flexible solar battery composite construction, it comprises basic unit and reflector, has one deck ion implanted layer between basic unit and reflector, surface, described reflector has layer protective layer.
Further, described basic unit is the PET film.
Further, described ion implanted layer is Al ion implantation layer or silver ion implanted layer.
Further, described reflector is aluminium film or silverskin.
Further, described reflector is the aluminium film, and described ion implanted layer is the Al ion implantation layer.
Further, the thickness of described aluminium film is 80~150nm.
Further, described reflector is silverskin, and described ion implanted layer is the silver ion implanted layer.
Further, the thickness of described silverskin is 20~60nm.
Further, described protective layer is silicon nitride film, oxygen silicon nitride membrane or silica membrane.
Further, the thickness of described ion implanted layer is 1~20nm.
In the high reflection of the above-mentioned flexible solar battery composite construction, by between basic unit and reflector, being formed with one deck ion implanted layer, improve the adhesion of reflector and basic unit with this; And have protective layer, and with reflector and peripheral gas isolating, guarantee reflecting properties, improve stability and the persistence of high reflection composite construction.Further, PET basic unit is strong to ultraviolet light stabilized, ageing resistance, and easily machine-shaping, quality are light, anti-aging, have good anti-mechanical stress characteristic, and is environmentally friendly.And aluminium or argentum reflecting layer a kind of reflectivity is high especially, low price, the flexible catoptric arrangement of long service life.High reflection composite construction of the present utility model can be widely used in the flexible solar battery.
Description of drawings
The utility model is described in further detail below in conjunction with drawings and Examples, in the accompanying drawing:
Fig. 1 is the schematic diagram of the high reflection of the flexible solar battery composite construction of the utility model embodiment.
Embodiment
In order to make the purpose of this utility model, technical scheme and advantage clearer, below in conjunction with drawings and Examples, the utility model is further elaborated.Should be appreciated that specific embodiment described herein only in order to explaining the utility model, and be not used in restriction the utility model.
See also Fig. 1, the high reflection of the flexible solar battery composite construction 10 of the utility model embodiment is shown, it comprises basic unit 11 and reflector 13, has one deck ion implanted layer 12 between basic unit 11 and reflector 13, and 13 surfaces, reflector have layer protective layer 14.
Particularly, basic unit 11 is the abbreviation of ethylene glycol terephthalate for PET() film.The PET film is strong to ultraviolet light stabilized, ageing resistance, and easily machine-shaping, quality are light, anti-aging, have good anti-mechanical stress characteristic, and is environmentally friendly.
Ion implanted layer 12 is Al ion implantation layer or silver ion implanted layer.Present embodiment utilizes the mode of the high energy beam Implantation in the ion technology to realize the surface modification of PET basic unit, makes to form a cambic implanted layer between the film base of two groups of samples, improves the adhesion of reflector and basic unit with this.Reflector 13 is aluminium film or silverskin.Preferably, when reflector 13 was the aluminium film, ion implanted layer 12 corresponded to the Al ion implantation layer; When reflector 13 was silverskin, ion implanted layer 12 corresponded to the silver ion implanted layer.By the homogeneity Implantation, more be conducive to improve the adhesion of reflector and basic unit.Preferably, the thickness of described ion implanted layer is 1~20nm.The thickness of aluminium film is preferably 80~150nm.The thickness of silverskin is preferably 20~60nm.
Further, protective layer 14 is silicon nitride film, oxygen silicon nitride membrane or silica membrane, and protective layer 14 is covered on the reflector 13, for the protection of reflector 13.Protective layer 14 is guaranteed reflecting properties with reflector 13 and peripheral gas isolating, has improved stability and the persistence of high reflection composite construction, increases useful life.
In the high reflection of the above-mentioned flexible solar battery composite construction 10, by between basic unit 11 and reflector 13, being formed with one deck ion implanted layer 12, improve the adhesion of reflector 13 and basic unit 11 with this; And have protective layer 14, and with reflector 13 and peripheral gas isolating, guarantee reflecting properties, improve stability and the persistence of high reflection composite construction.Further, PET basic unit is strong to ultraviolet light stabilized, ageing resistance, and easily machine-shaping, quality are light, anti-aging, have good anti-mechanical stress characteristic, and is environmentally friendly.And aluminium or argentum reflecting layer a kind of reflectivity is high especially, low price, the flexible catoptric arrangement of long service life can be widely used in the flexible solar battery.
Below by instantiation the aspects such as the concrete composition of heat insulating coat glass 10 of the present utility model and structure thereof are described.
Example 1
It is basic unit that the high catoptric arrangement of the flexible solar battery of this example adopts PET, and injects the Al sheath in basic unit, depositing Al reflector then, and silicon nitride film is as protective layer.The high catoptric arrangement preparation process of the flexible solar battery of this example is as follows.
1) cleaning of PET basic unit: adopt the smooth PET film of surfacing, with acetone or alcohol ultrasonic cleaning 5~15 minutes, use again the redistilled water ultrasonic cleaning after 5~15 minutes, for subsequent use after the vacuumize.
2) metal ion injects: with working media Al as negative electrode, carry out the Vacuum Arc discharge, produce highdensity plasma, under the effect of vacuum static electricity field, draw through three-electrode system, and acceleration forms as quickly as possible ion beam of high energy high current, carry energy Ions Bombardment processed workpiece (PET) surface, thereby the surface ion of finishing PET injects.
3) adopt advanced metal vapor vacuum arc (MEVVA) ion source to inject; the standby reflectance coating of Vacuum Magnetic filtering cathode arc plasma deposition plating multiple mechanism and diaphragm; the deposition plating of this instrument partly is equipped with magnetic filter; utilize the bent magnetic field that magnetic filter sets up (deflection angle is 90 degree usually) the given warp rail of plasma guiding that is produced by cathode arc; the uncharged bulky grain of following is not play the guiding role and is filtered; the ionization level 100% of deposited particles is so fine and close, smooth smooth, the surface uniform of the film of preparation, quality are high.
The final Al reflector thickness that obtains is 120nm, the anti-She of the high reflecting material that test obtains Shuais>=and 92%.
Example 2
The high catoptric arrangement of the flexible solar battery of this example and example 1 are basic identical, and difference is implanted layer and reflector, and this example adopts Ag ion layer, then deposits the Ag reflector, and silicon nitride film is as protective layer.The high catoptric arrangement preparation process of the flexible solar battery of this example is as follows.
1) cleaning of PET basic unit: adopt the smooth PET film of surfacing, with acetone or alcohol ultrasonic cleaning 5~15 minutes, use again the redistilled water ultrasonic cleaning after 5~15 minutes, for subsequent use after the vacuumize.
2) metal ion injects: with working media Ag as negative electrode, carry out the Vacuum Arc discharge, produce highdensity plasma, under the effect of vacuum static electricity field, draw through three-electrode system, and acceleration forms as quickly as possible ion beam of high energy high current, carry energy Ions Bombardment processed workpiece (PET) surface, thereby the surface ion of finishing PET injects.
3) adopt advanced metal vapor vacuum arc (MEVVA) ion source to inject; the standby reflectance coating of Vacuum Magnetic filtering cathode arc plasma deposition plating multiple mechanism and diaphragm; the deposition plating of this instrument partly is equipped with magnetic filter; utilize the bent magnetic field that magnetic filter sets up (deflection angle is 90 degree usually) the given warp rail of plasma guiding that is produced by cathode arc; the uncharged bulky grain of following is not play the guiding role and is filtered; the ionization level 100% of deposited particles is so fine and close, smooth smooth, the surface uniform of the film of preparation, quality are high.
The final Ag reflector thickness that obtains is 60nm, the anti-She of the high reflecting material that test obtains Shuais>=and 98%.
The above only is preferred embodiment of the present utility model; not in order to limit the utility model; all any modifications of within spirit of the present utility model and principle, doing, be equal to and replace and improvement etc., all should be included within the protection range of the present utility model.

Claims (10)

1. a flexible solar battery height reflects composite construction, and it comprises basic unit and reflector, it is characterized in that, has one deck ion implanted layer between basic unit and reflector, and surface, described reflector has layer protective layer.
2. the high reflection of flexible solar battery as claimed in claim 1 composite construction is characterized in that described basic unit is the PET film.
3. the high reflection of flexible solar battery as claimed in claim 1 composite construction is characterized in that described ion implanted layer is Al ion implantation layer or silver ion implanted layer.
4. the high reflection of flexible solar battery as claimed in claim 1 composite construction is characterized in that described reflector is aluminium film or silverskin.
5. the high reflection of flexible solar battery as claimed in claim 1 composite construction is characterized in that described reflector is the aluminium film, and described ion implanted layer is the Al ion implantation layer.
6. flexible solar battery height as claimed in claim 5 reflects composite construction, and the thickness of described aluminium film is 80~150nm.
7. the high reflection of flexible solar battery as claimed in claim 1 composite construction is characterized in that described reflector is silverskin, and described ion implanted layer is the silver ion implanted layer.
8. the high reflection of flexible solar battery as claimed in claim 7 composite construction is characterized in that the thickness of described silverskin is 20~60nm.
9. the high reflection of flexible solar battery as claimed in claim 1 composite construction is characterized in that described protective layer is silicon nitride film, oxygen silicon nitride membrane or silica membrane.
10. the high reflection of flexible solar battery as claimed in claim 1 composite construction is characterized in that the thickness of described ion implanted layer is 1~20nm.
CN 201220148120 2012-04-10 2012-04-10 Flexible-solar-cell high-reflection combination structure Expired - Lifetime CN202651171U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104576834A (en) * 2015-01-04 2015-04-29 浙江晶科能源有限公司 Method for manufacturing solar cell
CN104805402A (en) * 2015-05-20 2015-07-29 东莞理工学院 Manufacturing method of solar front surface reflector

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104576834A (en) * 2015-01-04 2015-04-29 浙江晶科能源有限公司 Method for manufacturing solar cell
CN104805402A (en) * 2015-05-20 2015-07-29 东莞理工学院 Manufacturing method of solar front surface reflector

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