CN201903504U - Fast detection kit for copper ions in food - Google Patents

Fast detection kit for copper ions in food Download PDF

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Publication number
CN201903504U
CN201903504U CN2010202885929U CN201020288592U CN201903504U CN 201903504 U CN201903504 U CN 201903504U CN 2010202885929 U CN2010202885929 U CN 2010202885929U CN 201020288592 U CN201020288592 U CN 201020288592U CN 201903504 U CN201903504 U CN 201903504U
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China
Prior art keywords
detection kit
food
copper ion
quick detection
standard
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Expired - Fee Related
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CN2010202885929U
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Chinese (zh)
Inventor
张遴
陈欣
蔡砚
王昌钊
乐爱山
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Inspection & Quarantine Technology Center Of Shannxi Entry-Exit Inspection And Quarantine Bureau
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Inspection & Quarantine Technology Center Of Shannxi Entry-Exit Inspection And Quarantine Bureau
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Priority to CN2010202885929U priority Critical patent/CN201903504U/en
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  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)

Abstract

The utility model provides a fast detection kit for copper ions in food, which mainly solves the problem that in the background art, no product is available for home use, is convenient to carry, and can detect copper content in food, such as fruits, vegetables and the like fast and conveniently at low cost. The fast detection kit comprises a suction tube, a colorimeter tube, a device containing a color-developing agent, a vessel and a standard color palette, wherein the vessel is provided with scales and can be sealed; the color-developing agent is a substance containing ferrocyanide ions; a standard colorimeter slot can be arranged on the standard color palette; and contrast color is coated in the standard colorimeter slot or different red brown ferrocyanide copper solutions are poured into the standard colorimeter slot.

Description

Copper ion quick detection kit in the food
Technical field
The utility model relates to a kind of quick detection kit, is specifically related to the quick detection kit of copper ion in a kind of food, is mainly used in the fast detecting to content of copper ion in the consumable products such as fruits and vegetables, beverage, water.
Background technology
Chlorophyll is a kind of natural colouring matter, and is relatively more responsive to light, heat, soda acid etc., normal fugitive color or variable color in the process of processing and storage.The coloring agent price that is used to bleaching and dyeing pollution-free food in the food additives is higher, and Color is not obvious, the price of every bottle 500 gram of common coloring agent about 50 yuan, quality high dyeing agent price even up to hundreds of unit.
Therefore, some illegal retailers strengthen sensory effects for the long-term green that keeps fruits and vegetables, cover low-quality goods, reduce cost, come the substitute food product adjuvant, as copper sulphate, stannous chloride, cupric chloride, cupric pyrophosphate, cuprous oxide, Schweinfurt green, copper carbonate etc. with mantoquita.
As everyone knows, copper sulphate is mainly used in fuel and pigment, pesticide, antiseptic, fabric mordant and beneficiation reagent etc. in inorganic industry, and the price of industrial sulphuric acid copper is 10 yuan/kilogram.The copper sulphate of excess intake can produce the look intense stimulus to human gastrointestinal tract, may cause nausea, vomit, mouthful in copper nature and flavor, heart-burn sense etc. are arranged; Severe patient may cause gastric colic, spitting blood, melena, hemoglobinuria, acute renal failure; Long-term contact can come in contact dermatitis and nose, eye stimulate, and gastrointestinal symptom occurs; Simultaneously,, cause the metabolic disturbance in the human body, symptoms such as cirrhosis and hepatic ascites occur when heavy metals such as the remaining a large amount of copper of human body very easily cause burden to internal organs.
The proposed standard of the World Health Organization (WHO) and grain farmer management committee is: man's average copper intake is no more than 12 milligrams/day, and woman's average copper intake is no more than 10 milligrams/day.And finding that in product investigation its copper content is up to 120 milligrams/kilogram-1200 milligrams/kilogram to illegal retailer, the consumer will produce huge threat to health when eating this series products.
At present, the method of measuring copper both at home and abroad in the food has atomic absorption method and extraction colorimetry, but above-mentioned two kinds of methods are to being applied to the laboratory or the professional detects, ordinary consumer is difficult to be suitable for, therefore, be badly in need of a kind of suitable family expenses, and be easy to carry, quick, easy, the cheap product that can detect copper content in the fruit-vegetable food.
Summary of the invention
The utility model to be to provide the quick detection kit of copper ion in a kind of food, and mainly having solved does not have the family expenses of being fit in the background technology, and be easy to carry, quick, easy, the cheap product that can detect copper content in the food such as fruits and vegetables.
Concrete technical solution of the present utility model is as follows:
The quick detection kit of copper ion in this food comprises suction pipe, color comparison tube, device, the Standard colour board of developer is housed; Developer is the material that contains ferrocyanide ion, is good with potassium ferrocyanide; When being used to detect copper ion concentration, need be diluted to the solution that concentration is 2%-15%.
In the charging apparatus, described device is Aluminium Foil Package pack, aluminium plastic packaging bag, plastic packaging bag, paper wrapping bag, composite packaging bag or graduated airtight container is set behind the above-mentioned developer quantitative weighing;
Above-mentioned Standard colour board is soft colourless transparent plastic plate, the colourless plastic plate of hard or cardboard, be provided with at least 6 reacted contrast colors of variable concentrations, individual with 6-10 is good, and the color of contrast colors is the different rufous materials of one group of depth according to identical ferrocyanide potassium concn and different Cu ion concentration reaction generation.
Can be provided with the standard cell on the above-mentioned Standard colour board, the one or both sides that this standard cell is arranged at Standard colour board are provided with simultaneously; The shape of standard cell can be circle, ellipse or polygon etc.; Contrast colors are to be coated in the standard cell or the different rufous ferrocyanide copper solution of injection in the standard cell.
Above-mentioned color comparison tube is that diameter is the column type transparent glass tube of 5-20mm, can be provided with scale mark.
Advantage of the present utility model is:
In this food the quick detection kit of copper ion be applicable to average family, need not any professional knowledge and skills training can detect whenever and wherever possible, simple in structure, easy to operate, result accurately, be suitable for the content of copper ion in the field quick detection determinand.
The detection limit of the quick detection kit of copper ion can reach 20ppm in this food, i.e. 0.0020% copper content.
Description of drawings
Fig. 1 does not have the Standard colour board structural representation of standard cell for quick detection kit;
Fig. 2 has the Standard colour board structural representation of standard cell for quick detection kit;
Fig. 3 has another Standard colour board structural representation of standard cell for quick detection kit;
Fig. 4 a is a quick detection kit color comparison tube structural representation;
Fig. 4 b is another structural representation of quick detection kit color comparison tube.
Embodiment
The utility model mainly is to contain the solution and the determinand reaction of ferrocyanide ion, and its principle is that ferrocyanide ion and copper ion reaction back generate the copper ferrocyanide red-brown precipitation, is example with the potassium ferrocyanide, and its chemical equation is:
K 4[Fe(CN) 6]+2CuSO 4=Cu 2[Fe(CN) 6]↓+2K 2SO 4
Utilize above-mentioned principle,, draw the reaction look of different colourities, according to making Standard colour board without the reaction look of colourity with the potassium ferrocyanide solution and the copper-bath reaction of normal concentration; The color and the Standard colour board that show with determinand compare, and determine content of copper ion.
Below in conjunction with accompanying drawing the utility model is described in detail.
The quick detection kit of copper ion in this food comprises suction pipe, color comparison tube, device, the Standard colour board of developer is housed;
Container is provided with scale and can be sealed; Developer is the material that contains ferrocyanide ion, is good with potassium ferrocyanide; When being used to detect copper ion concentration, need be diluted to the solution that concentration is 2%-15%;
In the charging apparatus, described device is Aluminium Foil Package pack, aluminium plastic packaging bag, plastic packaging bag, paper wrapping bag, composite packaging bag or graduated container that can be sealed is set behind the developer quantitative weighing.
Standard colour board is selected soft colourless transparent plastic plate or hard colourless transparent plastic plate for use, also can be cardboard.Be provided with at least 6 reacted contrast colors of variable concentrations, contrast colors are arranged in the standard cell, individual with 6-10 is good, and the color of contrast colors is the different rufous materials of one group of depth according to identical ferrocyanide potassium concn and different Cu ion concentration reaction gained.This colour table can be solution also can be the dehydration after the coating cardboard on solid matter.The one or both sides that above-mentioned standard cell is arranged at Standard colour board are provided with simultaneously; The shape of standard cell can be good with circle for circle, ellipse or polygon etc.
Contrast colors can directly prepare on Standard colour board, and the concentration of its potassium ferrocyanide just is fixed up.During so each detection, the potassium ferrocyanide solution of potassium ferrocyanide solution same concentrations when using with the preparation standard colour table as shown in Figure 1, comprises Standard colour board 1, contrast colors 2, concentration sign 3;
Or the cell 4 that on Standard colour board, sets up standard, as Fig. 2, shown in Figure 3, comprise Standard colour board 1, standard cell 4, during each the detection, can prepare potassium ferrocyanide solution as required, generate the rufous ferrocyanide copper material of different color ranges again with the solution reaction of the different content copper ion of concentration known, the contrast colors of the colour table that settles the standard.Color comparison tube is that diameter is the flat column type transparent glass tube of 5-20mm, shown in Fig. 4 a, 4b, can be provided with a plurality of scale marks such as 10ml, 11ml...20ml, also scale mark can be set.
During detection:
Get a pouch developer, directly pour in the color comparison tube, be diluted to scale with distilled water or pure water, shake up, this solution is chromogenic reagent solution; Also can pour in the container of developer device outfit, be diluted to scale with distilled water or pure water, shake up, this solution is chromogenic reagent solution, and the term of validity of chromogenic reagent solution is three months, can use in three months.
Pour chromogenic reagent solution into color comparison tube 10mL scale place, draw the scale place of solution to be measured with suction pipe then, shake up, observe its color at once, and compare, determine the content of copper ion in the solution according to immediate color range with Standard colour board in color comparison tube.The different dilution ratio of different scale representatives.

Claims (9)

1. copper ion quick detection kit in the food comprises suction pipe, color comparison tube, device, the Standard colour board of developer are housed, and it is characterized in that: described container is provided with scale and can be sealed.
2. according to copper ion quick detection kit in the food described in the claim 1, it is characterized in that: in the charging apparatus, described device is Aluminium Foil Package pack, aluminium plastic packaging bag, plastic packaging bag, paper wrapping bag, composite packaging bag or graduated airtight container is set behind the described developer quantitative weighing.
3. according to the quick detection kit of copper ion in the food described in claim 1 or 2, it is characterized in that: described developer is a potassium ferrocyanide.
4. according to the quick detection kit of copper ion in the food described in the claim 3, it is characterized in that: described Standard colour board is soft colourless transparent plastic plate, hard colourless transparent plastic plate or cardboard, is provided with at least 6 reacted contrast colors of variable concentrations.
5. according to copper ion quick detection kit in the food described in the claim 4, it is characterized in that: described Standard colour board is provided with the standard cell.
6. according to the quick detection kit of copper ion in the food described in the claim 5, it is characterized in that: described contrast colors are 6-10.
7. according to the quick detection kit of copper ion in the food described in the claim 6, it is characterized in that: described color comparison tube is that diameter is the column type transparent glass tube of 5-20mm.
8. according to the quick detection kit of copper ion in the food described in the claim 7, it is characterized in that: described color comparison tube is provided with scale mark.
9. the quick detection kit of copper ion in the food described in according to Claim 8, it is characterized in that: described standard cell is arranged at one or both sides; The standard cell is circle, ellipse or polygon.
CN2010202885929U 2010-08-11 2010-08-11 Fast detection kit for copper ions in food Expired - Fee Related CN201903504U (en)

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CN2010202885929U CN201903504U (en) 2010-08-11 2010-08-11 Fast detection kit for copper ions in food

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CN2010202885929U CN201903504U (en) 2010-08-11 2010-08-11 Fast detection kit for copper ions in food

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102818804A (en) * 2012-08-09 2012-12-12 中国科学院唐山高新技术研究与转化中心 Kit and detection method for determining copper ion concentration in water environment
CN103543147A (en) * 2013-10-12 2014-01-29 苏州金宏气体股份有限公司 Method for fast detecting acidic substance content of natural gas
CN107884405A (en) * 2017-12-13 2018-04-06 百奥森(江苏)食品安全科技有限公司 A kind of kit for copper ions in food quick detection
CN109520953A (en) * 2019-01-26 2019-03-26 陇东学院 Potassium ferrocyanide method in a kind of spectrophotometry measurement salt
CN111044512A (en) * 2019-12-17 2020-04-21 谱尼测试集团股份有限公司 Method for rapidly detecting potassium ferrocyanide in salt

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102818804A (en) * 2012-08-09 2012-12-12 中国科学院唐山高新技术研究与转化中心 Kit and detection method for determining copper ion concentration in water environment
CN103543147A (en) * 2013-10-12 2014-01-29 苏州金宏气体股份有限公司 Method for fast detecting acidic substance content of natural gas
CN103543147B (en) * 2013-10-12 2016-03-02 苏州金宏气体股份有限公司 A kind of method of quick detection rock gas acidic substance content
CN107884405A (en) * 2017-12-13 2018-04-06 百奥森(江苏)食品安全科技有限公司 A kind of kit for copper ions in food quick detection
CN109520953A (en) * 2019-01-26 2019-03-26 陇东学院 Potassium ferrocyanide method in a kind of spectrophotometry measurement salt
CN111044512A (en) * 2019-12-17 2020-04-21 谱尼测试集团股份有限公司 Method for rapidly detecting potassium ferrocyanide in salt

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C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20110720

Termination date: 20120811