CN201538685U - Nozzle with swirlers used for preparing synthesis gas with gaseous materials containing carbon - Google Patents

Nozzle with swirlers used for preparing synthesis gas with gaseous materials containing carbon Download PDF

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Publication number
CN201538685U
CN201538685U CN2009200782785U CN200920078278U CN201538685U CN 201538685 U CN201538685 U CN 201538685U CN 2009200782785 U CN2009200782785 U CN 2009200782785U CN 200920078278 U CN200920078278 U CN 200920078278U CN 201538685 U CN201538685 U CN 201538685U
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China
Prior art keywords
nozzle
shower nozzle
gas
channel
spray head
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Expired - Lifetime
Application number
CN2009200782785U
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Chinese (zh)
Inventor
王辅臣
代正华
龚欣
于广锁
刘海峰
王亦飞
周志杰
陈雪莉
王兴军
李伟锋
郭晓镭
梁钦锋
郭庆华
许建良
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East China University of Science and Technology
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East China University of Science and Technology
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Priority to CN2009200782785U priority Critical patent/CN201538685U/en
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Publication of CN201538685U publication Critical patent/CN201538685U/en
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Abstract

The utility model provides a nozzle with swirlers used for preparing synthesis gas with gaseous materials containing carbon, which is mainly formed by a central nozzle, an inner circular nozzle, an outer circular nozzle, a central passage swirler, an outer circular passage swirler and a cooling system. The nozzle can be used for preparing synthesis gas by partially oxidizing gaseous materials containing carbon such as natural gas, coke-oven gas, coal bed gas, refinery gas, oil-field gas and the like. The swirlers arranged in a central passage and an outer circular passage of the nozzle promote mixture of materials, facilitate stabilizing length and state of flame, have fine technical performance, and are capable of achieving function of protecting the nozzle, refractory bricks and catalysts and prolonging service life of the nozzle.

Description

A kind of nozzle that the gaseous state carbonaceous material prepares synthetic gas that is used for swirler
Technical field
The present invention relates to a kind of burner, relate in particular to and be used for gaseous state carbonaceous material partial oxidation and prepare synthetic gas (CO+H with swirler 2) nozzle.
Background technology
The gaseous state carbonaceous material is meant that Sweet natural gas, coke(oven)gas, coal-seam gas, refinery gas, associated gas etc. are rich in CH 4, C 2H 6Gas Deng hydro carbons.Along with the enhancing of people's energy and Environmental awareness, the gaseous state carbonaceous material (as coke(oven)gas, coal-seam gas) of some direct emptyings in the past and directly burning emptying has changed the industrial raw material with high added value into.With the coke(oven)gas is example, China is the world main coke production state, the coke(oven)gas of about 900 billion cubic meters of annual by-product, personal and be used for town gas, produce synthetic ammonia and the methyl alcohol except that melting down heating, the annual coke(oven)gas that directly enters atmosphere or burn in vain is equivalent to the West-East National Gas Transmission Project amount of natural gas in every year, and causes serious environmental to pollute.
The gaseous state carbonaceous material is converted into synthetic gas (CO+H 2) be an important step in the gaseous state carbonaceous material whole industry chain, the synthetic gas of production can be used for preparing fields such as chemical, liquid fuel, direct reduction iron making, hydrogen manufacturing.The main technique that the gaseous state carbonaceous material prepares synthetic gas has catalyzing part oxidation and non-catalytic partial oxidation, and common ground is that the nozzle that is installed on the converter is all played the part of very important role in whole conversion process.Nozzle should promote mixing of gaseous state carbonaceous material and vaporized chemical (air, oxygen-rich air, empty oxygen, water vapor, carbonic acid gas or its mixture of dividing); form suitable flow field with the body of heater coupling again; and then form suitable temperature distribution, reach the multipurpose of protection nozzle, refractory brick and catalyzer.
Coke(oven)gas catalyzing part oxidation device with certain factory's actual motion is an example, has the following problem that makes catalyzer scaling loss and inefficacy in the operational process:
(1) jet combustion flame is long, and the upper strata catalyzer of converter beds directly contacts with flame;
(2) the nozzle mixed effect is poor, and oxygen totally promptly enters the beds of converter at converter combustion zone unreacted.
The objective of the invention is to overcome the deficiency of above-mentioned technology, propose a kind of nozzle that the gaseous state carbonaceous material prepares synthetic gas that is used for swirler.By in the passage of vaporized chemical, swirler being set,, promoted oxygen to react completely as far as possible in the converter combustion zone to optimize the mixed effect of nozzle; But the swirler stable burning length of flame and state are set simultaneously,, realize that whole device is stable to cover with excellent operation to reach the effect of protection nozzle, refractory brick and catalyzer.
The utility model content
The utility model proposes a kind of nozzle that the gaseous state carbonaceous material prepares synthetic gas that is used for swirler, it is characterized in that, described nozzle is by center shower nozzle (1), interior ring spray head (2), the outer shroud shower nozzle (3) of coaxial setting successively, and swirler (4,5) and cooling system (6) combine.
Form centre channel (7) between the described center shower nozzle (1) of coaxial setting successively, form outer ring channel (9) between described interior ring spray head (2) and the described outer shroud shower nozzle (3); Annular space passage (8) in forming between described center shower nozzle (1) and the described interior ring spray head (2).
Described swirler (4,5) is installed on respectively in described centre channel (7) and the described outer ring channel (9).
Described swirler (4,5) adopts axial screw slot type or axial rotary vane type, and swirling number is 0.1~0.9.
The flow velocity of the outlet vaporized chemical of described centre channel (7) is 10~200m/s, and the flow velocity of the outlet gaseous state carbonaceous material of described interior annular space passage (8) is 20~300m/s, and the flow velocity of the outlet vaporized chemical of described outer ring channel (9) is 20~300m/s.
The interior straight section length of center shower nozzle (1) H is 1~4 times of nozzle center's passage (7) end diameter; The interior angle of throat α of center shower nozzle (1) is 45~80 degree; The outer angle of throat of center shower nozzle (1), the interior angle of throat β of interior ring spray head (2) equate, are 30~80 degree; The outer angle of throat of interior ring spray head (2), the interior angle of throat γ of outer shroud shower nozzle (3) equate, are 30~80 degree; Center shower nozzle (1) is 1~5mm with interior ring spray head (2) tip spacing t1; Interior ring spray head (2) is 1~5mm with outer shroud shower nozzle (3) tip spacing t2.
Vaporized chemical in the allocation proportion of described centre channel (7) and described outer ring channel (9) is: centre channel 20~80%; Outer ring channel 20~80%.
Described gaseous state carbonaceous material is Sweet natural gas, coke(oven)gas, coal-seam gas, refinery gas, associated gas or their mixture.
The suitable pressure of the utility model nozzle is normal pressure~10.0MPa.
Because nozzle of the present utility model adopts the multi-channel structure that has swirler, promoted mixing and being convenient to the stabilized nozzle length of flame and state of vaporized chemical and gaseous state carbonaceous material, improved the gasification performance of nozzle.Nozzle of the present invention, have simple in structure, make easy to maintenance, nozzle, refractory brick, the long characteristics of catalyst life, of many uses.
Description of drawings
Fig. 1 is the structure of nozzle synoptic diagram of embodiment.
Nomenclature:
1-center shower nozzle
Ring spray head in the 2-
3-outer shroud shower nozzle
4-centre channel swirler
5-outer ring channel swirler
The 6-cooling system
The 7-centre channel
Annular space passage in the 8-
The 9-outer ring channel
Straight section length in the shower nozzle of H-center
Angle of throat in α-center shower nozzle
Angle of throat in the outer angle of throat of β-center shower nozzle, the interior ring spray head
Angle of throat in the outer angle of throat of γ-Nei ring spray head, the outer shroud shower nozzle
T1-center shower nozzle and interior ring spray cephalic par spacing
Ring spray head and outer shroud shower nozzle tip spacing in the t2-
Embodiment
Help to understand the utility model by the following description of the embodiments, but do not limit content of the present utility model.
Embodiment 1
Referring to Fig. 1, a kind of nozzle that the gaseous state carbonaceous material prepares synthetic gas that is used for that the utility model proposes with swirler, from thermal transition preparation with become gas, self-heating converter upper space is the combustion zone to this nozzle application in coke(oven)gas, the bottom is a beds.
The classical group of coke(oven)gas becomes (v%): H 258, CO 6, CO 22.7, CH 426, N 24, C 2 +2.5, S 0.02.Vaporized chemical is made up of pure oxygen and water vapor.The ratio of pure oxygen and coke(oven)gas is 0.26Nm 3O 2/ Nm 3Coke(oven)gas, the ratio of steam and coke(oven)gas are 0.3kg steam/Nm 3Coke(oven)gas.
The vaporized chemical flow velocity of the centre channel 7 of nozzle is 100m/s, and the coke(oven)gas flow velocity of annular space passage 8 is 120m/s in the nozzle, and the vaporized chemical flow velocity of nozzle outer ring channel 9 is 100m/s.
Vaporized chemical in the allocation proportion of centre channel 7 and outer ring channel 9 is: centre channel 40% (can change between 20~80%), outer ring channel 60%.
The swirling number of centre channel swirler 4, outer ring channel swirler 5 can be 0.1~0.9, is 0.5 herein.
Shower nozzle interior straight section length H in center is 2 times of nozzle center's passage 7 end diameter.
The interior angle of throat α of center shower nozzle 1 is 60 degree herein, can change between 45~80 degree.
The outer angle of throat of center shower nozzle 1, interior ring spray 2 an interior angle of throat β are 70 degree herein, can change between 30~80 degree.
The outer angle of throat of interior ring spray 2, the interior angle of throat γ of outer shroud shower nozzle 3 are 70 degree herein, can change between 30~80 degree.
Center shower nozzle 1 can value be 1~5mm with interior ring spray 2 a tip spacing t1, is 2mm herein.
Interior ring spray 2 can value be 1~5mm with outer shroud shower nozzle 3 tip spacing t2, is 2mm herein.

Claims (5)

1. nozzle that the gaseous state carbonaceous material prepares synthetic gas that is used for swirler, it is characterized in that, described nozzle is by center shower nozzle (1), interior ring spray head (2), the outer shroud shower nozzle (3) of coaxial setting successively, and swirler (4,5) and cooling system (6) combine;
Form centre channel (7) between the described center shower nozzle (1) of coaxial setting successively, form outer ring channel (9) between described interior ring spray head (2) and the described outer shroud shower nozzle (3); Annular space passage (8) in forming between described center shower nozzle (1) and the described interior ring spray head (2);
Described swirler (4,5) is installed on respectively in described centre channel (7) and the described outer ring channel (9).
2. nozzle according to claim 1 is characterized in that, described swirler (4,5) adopts axial screw slot type or axial rotary vane type, and swirling number is 0.1~0.9.
3. nozzle according to claim 1, it is characterized in that, the flow velocity of the outlet vaporized chemical of described centre channel (7) is 10~200m/s, the flow velocity of the outlet gaseous state carbonaceous material of annular space passage (8) is 20~300m/s in described, and the flow velocity of the outlet vaporized chemical of described outer ring channel (9) is 20~300m/s.
4. nozzle according to claim 1 is characterized in that, the interior straight section length of described center shower nozzle (1) is 1~4 times of described centre channel (7) end diameter; The interior angle of throat α of described center shower nozzle (1) is 45~80 degree; The interior angle of throat β of the outer angle of throat of described center shower nozzle (1) and described interior ring spray head (2) equates, is 30~80 degree; The interior angle of throat γ of outer angle of throat of ring spray head (2) and described outer shroud shower nozzle (3) equates in described, is 30~80 degree; Described center shower nozzle (1) is 1~5mm with the spacing t1 of described interior ring spray head (2) end; Ring spray head (2) is 1~5mm with the spacing t2 of described outer shroud shower nozzle (3) end in described.
5. according to the arbitrary described nozzle of claim 1~4, it is characterized in that vaporized chemical in the allocation proportion of described centre channel (7) and described outer ring channel (9) is: centre channel 20~80%; Outer ring channel 20~80%.
CN2009200782785U 2009-07-15 2009-07-15 Nozzle with swirlers used for preparing synthesis gas with gaseous materials containing carbon Expired - Lifetime CN201538685U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105178935A (en) * 2015-10-09 2015-12-23 中国石油集团钻井工程技术研究院江汉机械研究所 Central water tube gasifying and coal mining device
CN105271115A (en) * 2015-11-25 2016-01-27 华东理工大学 Gaseous hydrocarbon reformer nozzle
CN106010651A (en) * 2016-05-24 2016-10-12 华东理工大学 Tanning waste treatment device and treatment technique using device
WO2017121248A1 (en) * 2016-01-12 2017-07-20 华东理工大学 Partial oxidation process burner and use thereof
CN109422231A (en) * 2017-08-29 2019-03-05 中国石化工程建设有限公司 A kind of hydrogenation plant water filling device

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105178935A (en) * 2015-10-09 2015-12-23 中国石油集团钻井工程技术研究院江汉机械研究所 Central water tube gasifying and coal mining device
CN105271115A (en) * 2015-11-25 2016-01-27 华东理工大学 Gaseous hydrocarbon reformer nozzle
WO2017121248A1 (en) * 2016-01-12 2017-07-20 华东理工大学 Partial oxidation process burner and use thereof
CN106010651A (en) * 2016-05-24 2016-10-12 华东理工大学 Tanning waste treatment device and treatment technique using device
CN106010651B (en) * 2016-05-24 2019-06-04 华东理工大学 A kind of processing unit of tanning waste and treatment process containing it
CN109422231A (en) * 2017-08-29 2019-03-05 中国石化工程建设有限公司 A kind of hydrogenation plant water filling device

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Granted publication date: 20100804

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