A kind of copper pipe that is used for square billet, circle base and rectangular billet caster
Technical field
The utility model belongs to the continuous casting installation for casting field of metallurgy industry, particularly a kind of copper pipe that is used for square billet, circle base and rectangular billet caster.
Background technology
Defectives such as the segregation of continuous casting billet and crackle are the inhomogeneity key factors of intensity, toughness, service life and structure property that influences steel, and the gross segregation problem of high-carbon, high-alloy steel continuous casting billet is a puzzlement continuous casting circle key technical problem for many years.The equiaxial crystal ratio, the thinning solidification structure that improve strand are the important means that alleviates the continuous casting billet center segregation.At present the technical measures that adopt mainly comprise and reduce superheat of liquid steel, gently depress with electromagnetic agitation etc., and in addition, the control that crystallizer conducts heat also has facilitation to the raising of strand equiaxial crystal ratio.
Solidifying of molten steel originates in crystallizer, and crystallizer is as the core component of conticaster, and its effect is the band liquid core strand that obtains to have Reasonable Shape and certain intensity.The heat transfer that slows down crystallizer top has the following advantages: (1) improves the uniformity of initial solidification thickness of the shell growth, suppresses the generation of slab surface crack; (2) thermograde of reduction solidification front suppresses the growth of column crystal, realizes the transformation of column crystal to equiax crystal in advance, thereby increases substantially the equiaxial crystal ratio of strand, reduces center segregation and loose degree.
With the heat transfer that slows down crystallizer top is target, patent 98119193.2 has proposed the crystallizer made by high conductivity material, its target is to improve the surface quality of continuous casting billet, principal character be provided with at outer surface a kind of than the crystallizer body coating material of low heat conductivity more, coating is single nickel and nickel alloy, at the coating of crystallizer upper semisection outer surface, this patent does not quantize explanation to the particular location of its thickness of coating and setting.Patent 02131319.9 has proposed a kind of mould product with heat insulation and wear-resistant coating, its target is to improve the internal soundness of strand, principal character be coated with on inner surface top a kind of than the crystallizer body heat insulation and wear resistance material of low heat conductivity more, thickness of coating is 0.2~5.0mm, the coating material is cermet material and metal material, but because the difference of the thermal coefficient of expansion of this heat-barrier material and crystallizer bulk material is bigger, therefore very high to adhesive force, the requirement of coating surface smoothness of coating and crystallizer body, be difficult to form industrial scale.
Summary of the invention
The purpose of this utility model is to provide a kind of copper pipe that is used for square billet, circle base and rectangular billet caster, and it is simple in structure, easy to make, the improved effect of strand internal soundness obvious, satisfy production requirement service life.
The utility model comprises copper pipe body, outer wall thermal barrier coating, inwall scuff-resistant coating, and zone, this external surface of copper pipe top has thermal barrier coating, and inner surface has scuff-resistant coating.The height of copper pipe is 700~1000mm, and the strand cross section of being cast is square, circle or rectangle, and the length of side of square billet or rectangular bloom is 120~380mm, and the diameter of circle base is 150~300mm, and it is constant that the wall thickness of copper pipe keeps, and is 14~30mm.
The top of the thermal barrier coating of outer surface of tube wall is 40~60mm apart from the minimum range s of copper pipe upper limb, and the bottom of the thermal barrier coating 3 of outer surface of tube wall is 1/2 of a copper pipe total height apart from the distance H of copper pipe upper limb, and the total inner surface of copper pipe body has all plated scuff-resistant coating 4.
Copper pipe can reduce the molten steel face and under the heat flow density 30%~50% in 300~400mm zone, reduce the thermograde of molten steel initial stage solidification front, improve the strand equiaxial crystal ratio, improve the internal soundness of strand.
Description of drawings
Fig. 1 is a structure chart of the present utility model.Wherein, molten steel face 5 in the thermal barrier coating 3 of Crystallizer tube 1, silver-bearing copper pipe 2, outer surface of tube wall, the scuff-resistant coating 4 of inner surface of tube wall, the Crystallizer tube, the top of the thermal barrier coating of s vial wall outer surface is apart from the minimum range of Crystallizer tube upper limb, H be the bottom of thermal barrier coating of outer surface of tube wall apart from the distance of Crystallizer tube upper limb, D2 and D3 represent the wall thickness of the first half copper pipe body and outer wall thermal barrier coating respectively.
The specific embodiment
The utility model comprises copper pipe body, outer wall thermal barrier coating, inwall scuff-resistant coating, and zone, this external surface of copper pipe top has thermal barrier coating, and inner surface has scuff-resistant coating.The height of copper pipe is 700~1000mm, and the strand cross section of being cast is square, circle or rectangle, and the length of side of square billet or rectangular bloom is 120~380mm, and the diameter of circle base is 150~300mm, and it is constant that the wall thickness of copper pipe keeps, and is 14~30mm.
The material that constitutes the copper pipe body 2 of copper pipe is the chromium zirconium copper that the silver-bearing copper of silver content 0.08wt.%~0.09wt.% or the beryllium-bronze that contains beryllium amount 0.2wt.%~0.5wt.% or chromium and zirconium content are respectively 0.60wt.%~0.70wt.% and 0.08wt.%~0.12wt.%, the thermal barrier coating 3 of copper pipe outer surface is composited by nickel and nickel-chromium alloy, chromium content is 20wt.%~30wt.% in the nickel-chromium alloy, the scuff-resistant coating 4 of copper pipe plating inner surface is a nickel cobalt (alloy), and wherein cobalt content is 10wt.%~20wt.%.
Thermal barrier coating 3 and scuff-resistant coating 4 keep homogeneous at the thickness of casting direction g, near silver-bearing copper pipe 2 outer surfaces is that thickness is the nickel of 0.1~0.5mm, having electroplated thickness on the nickel coating surface once more is the nichrome of 0.8~2.0mm, the design principle of nichrome coating thickness is the phase transition temperature that the temperature in the copper pipe is lower than copper pipe body 2 when guaranteeing continuous casting production, and the thickness D2 and the thermal conductivity factor λ 2 of the thickness D3 of thermal barrier coating 3 and thermal conductivity factor λ 3 and copper pipe body 2 satisfy following relational expression: D3/ λ 3+D2/ λ 2=(1.2~1.4) * 10
-4m
2℃/W, the thickness of close copper pipe body 2 inner surface scuff-resistant coatings 4 is 0.06~0.15mm.
The Application of Copper target be reduce molten steel face 5 in the copper pipe and under the heat flow density 30%~50% in 300~400mm zone, reduce the thermograde of molten steel initial stage solidification front, improve the strand equiaxial crystal ratio, improve the internal soundness of strand.