CN201425893Y - Ceramic capacitor - Google Patents
Ceramic capacitor Download PDFInfo
- Publication number
- CN201425893Y CN201425893Y CN2009200571799U CN200920057179U CN201425893Y CN 201425893 Y CN201425893 Y CN 201425893Y CN 2009200571799 U CN2009200571799 U CN 2009200571799U CN 200920057179 U CN200920057179 U CN 200920057179U CN 201425893 Y CN201425893 Y CN 201425893Y
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- Prior art keywords
- capacitor
- silver
- ceramic capacitor
- copper
- ceramic
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- 239000003985 ceramic capacitor Substances 0.000 title claims abstract description 31
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052802 copper Inorganic materials 0.000 claims abstract description 32
- 239000010949 copper Substances 0.000 claims abstract description 32
- 239000003990 capacitor Substances 0.000 claims abstract description 31
- 229910052709 silver Inorganic materials 0.000 claims abstract description 25
- 239000004332 silver Substances 0.000 claims abstract description 25
- 229910000679 solder Inorganic materials 0.000 claims abstract description 22
- 239000000919 ceramic Substances 0.000 claims abstract description 10
- 238000005538 encapsulation Methods 0.000 claims description 5
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims description 5
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 229920001568 phenolic resin Polymers 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 239000005011 phenolic resin Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract 1
- 229910001431 copper ion Inorganic materials 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 13
- -1 silver ions Chemical class 0.000 description 6
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- UKHWJBVVWVYFEY-UHFFFAOYSA-M silver;hydroxide Chemical compound [OH-].[Ag+] UKHWJBVVWVYFEY-UHFFFAOYSA-M 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000005476 soldering Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000002003 electrode paste Substances 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000005007 epoxy-phenolic resin Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
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- Ceramic Capacitors (AREA)
Abstract
本实用新型公开了一种陶瓷电容器,包括陶瓷电容的本体和电容量的引出端子。所述的电容器本体是在薄片状的陶瓷介质芯片正反两面印刷有铜内电极层。与现有技术相比,陶瓷电容器的内电极是铜电极,铜的成本比银的成本低的多,相应的焊膏也可以是少含银或不含银的无铅焊膏。另外,该电容器在生产和使用的过程中,惰性的铜离子也不会发生迁移。所以具有陶瓷电容器可靠性和稳定性高、产品的生产成本低、且符合环保要求。
The utility model discloses a ceramic capacitor, which comprises a body of the ceramic capacitor and a lead-out terminal of the capacitor. In the capacitor body, copper internal electrode layers are printed on the front and back sides of a sheet-shaped ceramic dielectric chip. Compared with the prior art, the inner electrode of the ceramic capacitor is a copper electrode, the cost of copper is much lower than that of silver, and the corresponding solder paste can also be a lead-free solder paste containing less silver or no silver. In addition, the inert copper ions will not migrate during the production and use of the capacitor. Therefore, the ceramic capacitor has high reliability and stability, low production cost of the product, and meets environmental protection requirements.
Description
技术领域 technical field
本实用新型涉及一种陶瓷电容器,尤其涉及一种内电极结构改变的陶瓷电容器。The utility model relates to a ceramic capacitor, in particular to a ceramic capacitor with a changed inner electrode structure.
背景技术 Background technique
目前传统的交流电容器内电极材料使用价格高昂的银浆。在圆片陶瓷电容器成品生产焊接时需使用价格昂贵的含银焊锡才可能获得良好的焊接效果。但是银离子比较活跃,很容易产生迁移。传统银电极电容器在高温或高电压条件下工作时,渗入电容器内部的水分子产生电解,在阳极产生氧化反应,银离子与氢氧根离子结合生成氢氧化银。在阴极产生还原反应,氢氧化银与氢离子反应生成银和水。由于电极反应,阳极的银离子不断向阴极还原成不连续金属银粒,靠水膜连接成树状向阳极延伸。银离子迁移不仅发生在无机介质表面,银离子还能扩散到无机介质内部,引起漏电流增大,严重时可使两个银电极之间完全短路,导致电容器击穿。另外,银浆的价格很贵。同时,银作为电容的内电极层就需要用银焊锡膏焊接引线,由引线来引出电容器的容量。所以银内电极的圆片陶瓷电容器生产成本很高。At present, the traditional AC capacitor inner electrode material uses expensive silver paste. In the production and welding of finished disc ceramic capacitors, it is necessary to use expensive silver-containing solder to obtain a good welding effect. However, silver ions are relatively active and easily migrate. When traditional silver electrode capacitors work under high temperature or high voltage conditions, the water molecules infiltrated into the capacitor will undergo electrolysis, and an oxidation reaction will occur at the anode, and silver ions will combine with hydroxide ions to form silver hydroxide. A reduction reaction occurs at the cathode, and silver hydroxide reacts with hydrogen ions to form silver and water. Due to the electrode reaction, the silver ions in the anode are continuously reduced to the cathode to form discontinuous metal silver particles, which are connected by the water film to form a tree and extend to the anode. The migration of silver ions not only occurs on the surface of the inorganic medium, but also diffuses into the interior of the inorganic medium, causing an increase in leakage current. In severe cases, it can completely short-circuit the two silver electrodes, resulting in breakdown of the capacitor. In addition, the price of silver paste is very expensive. At the same time, silver as the internal electrode layer of the capacitor needs to be welded with silver solder paste to lead wires, and the capacity of the capacitor is drawn out from the lead wires. Therefore, the production cost of disc ceramic capacitors with silver inner electrodes is very high.
实用新型内容 Utility model content
本实用新型需解决的技术问题是提供一种产品可靠性和稳定性好、生产成本低的陶瓷电容器。The technical problem to be solved by the utility model is to provide a ceramic capacitor with good product reliability and stability and low production cost.
本实用新型需解决的技术问题是通过以下技术方案实现的:一种陶瓷电容器,包括陶瓷电容的本体和电容量的引出端子,所述的电容器本体是在薄片状的陶瓷介质芯片正反两面印刷有铜内电极层。The technical problem to be solved by the utility model is achieved through the following technical solutions: a ceramic capacitor, including a ceramic capacitor body and a lead-out terminal of the capacitor, and the capacitor body is printed on both sides of a sheet-shaped ceramic dielectric chip There is a copper inner electrode layer.
进一步:在上述铜内电极陶瓷电容器中,所述的陶瓷介质芯片是圆片、方片、椭圆片中的一种。Further: in the copper inner electrode ceramic capacitor, the ceramic dielectric chip is one of a circular chip, a square chip, and an elliptical chip.
所述的容量引出端子是用焊锡层焊接在铜电极层外侧的引线。为进一步降低生产成本,所述的焊锡层是低银或无银的无铅焊锡层。电容器本体外表还设有保护本体的环氧树脂或酚醛树脂包封层。陶瓷电容器的整体是圆片状。The capacity lead-out terminal is a lead wire welded on the outer side of the copper electrode layer with a solder layer. In order to further reduce the production cost, the solder layer is a low-silver or silver-free lead-free solder layer. The outer surface of the capacitor body is also provided with an epoxy resin or phenolic resin encapsulation layer to protect the body. The whole ceramic capacitor is in the shape of a disc.
与现有技术相比,陶瓷电容器的内电极是铜内电极层,在铜内电极的电容器芯片与外接电极引线焊接时,内电极金属铜不会溶解于焊料(焊锡)中,即不会发生飞铜(铜蚀)现象,因此电容器内部焊点更可靠。在生产和使用这种电容器时,惰性的铜不会产生迁移,所以产品的可靠性和稳定性都比银内电极的电容器好。另外,银的价格很高,焊引线时,需要价格高的银焊锡膏层。所以铜电极陶瓷电容器生产成本低。Compared with the prior art, the internal electrode of the ceramic capacitor is a copper internal electrode layer. When the capacitor chip of the copper internal electrode is welded with the external electrode lead, the internal electrode metal copper will not dissolve in the solder (solder), that is, it will not occur. Flying copper (copper corrosion) phenomenon, so the solder joints inside the capacitor are more reliable. When producing and using this kind of capacitor, the inert copper will not migrate, so the reliability and stability of the product are better than that of the capacitor with silver internal electrodes. In addition, the price of silver is high, and an expensive silver solder paste layer is required when soldering lead wires. Therefore, the production cost of the copper electrode ceramic capacitor is low.
上述陶瓷电容器是通过铜电极浆料的开发选用,配合气氛烧成工艺,以金属铜作为圆片陶瓷电容器的内电极。它经过生坯成型、陶瓷基片烧结、印刷铜浆、铜电极烧结(需要用合适的气氛)、焊接外接引线、绝缘包封和测试,生产出铜电极圆片陶瓷电容器。它应用现有的氧化气氛对陶瓷基片进行烧结,然后使用适当的还原气氛烧结铜电极,制成铜电极电容器芯片,然后采用廉价的低含银量焊料对电容器进行焊接,从而节约了电容器生产成本,又提高了电容器的稳定性和可靠性。The above-mentioned ceramic capacitors are developed and selected through the development and selection of copper electrode paste, combined with the atmosphere firing process, and metal copper is used as the internal electrode of the disc ceramic capacitor. It goes through green molding, ceramic substrate sintering, copper paste printing, copper electrode sintering (need to use a suitable atmosphere), welding external leads, insulation encapsulation and testing to produce copper electrode disc ceramic capacitors. It uses the existing oxidizing atmosphere to sinter the ceramic substrate, and then uses an appropriate reducing atmosphere to sinter the copper electrode to make a copper electrode capacitor chip, and then uses cheap low-silver content solder to weld the capacitor, thus saving capacitor production Cost, but also improve the stability and reliability of the capacitor.
附图说明 Description of drawings
图1是本实用新型实施方式的正面半部示意图;Fig. 1 is a schematic diagram of the front half of the utility model embodiment;
图2是本实用新型实施方式的纵截面示意图。Fig. 2 is a schematic longitudinal section of an embodiment of the utility model.
其中:1陶瓷介质芯片、2铜内电极层、3引线、4无铅焊锡层、5环氧或酚醛树脂包封层。Among them: 1 ceramic dielectric chip, 2 copper inner electrode layer, 3 lead wire, 4 lead-free solder layer, 5 epoxy or phenolic resin encapsulation layer.
具体实施方案 specific implementation plan
参照附图1~2及具体实施方式来说明本实用新型。The utility model is described with reference to accompanying
一种陶瓷电容器,包括陶瓷电容的本体和电容量的引出端子,所述的电容器本体是在薄片状的陶瓷介质芯片1正反两面印刷有铜内电极层2。在图1中,所述的陶瓷介质芯片1是圆片状,它也可以是方片、椭圆片中的一种。在铜内电极层外侧用低银或无银的无铅焊锡层焊接有作为容量引出端子的引线3。该电容器本体外表还设有保护本体的环氧或酚醛树脂包封层5。该电容器整体形状是圆片状。A ceramic capacitor includes a body of the ceramic capacitor and lead-out terminals of the capacitor. The body of the capacitor is printed with copper
与现有技术相比,陶瓷电容器的内电极是铜内电极层2,在铜内电极层的电容器芯片1与外接电极引线3焊接时,内电极金属铜不会溶解于焊料(焊锡)中,即不会发生飞铜(铜蚀)现象,因此电容器内部焊点更可靠。在生产和使用这种电容器时,惰性的铜不会产生迁移,所以产品的可靠性和稳定性都比银内电极的电容器好。另外,银的价格很高,焊引线时,需要价格高的银焊锡膏层。而铜内电极在焊接引线时,是用低银或无银的焊锡层。所以陶瓷电容器生产成体低。Compared with the prior art, the inner electrode of the ceramic capacitor is a copper
以上所述为本实用新型的一个较佳实施例,在不脱离本实用新型构思情况下,进行任何显而易见的变形和替换,均属本实用新型保护范围。The above is a preferred embodiment of the utility model, and any obvious deformation and replacement without departing from the concept of the utility model shall fall within the protection scope of the utility model.
Claims (6)
Priority Applications (1)
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CN2009200571799U CN201425893Y (en) | 2009-05-22 | 2009-05-22 | Ceramic capacitor |
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CN2009200571799U CN201425893Y (en) | 2009-05-22 | 2009-05-22 | Ceramic capacitor |
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CN2009200571799U Expired - Lifetime CN201425893Y (en) | 2009-05-22 | 2009-05-22 | Ceramic capacitor |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104701009A (en) * | 2015-02-10 | 2015-06-10 | 鞍山奇发电子陶瓷科技有限公司 | Small-sized chip type surface mounting (SMD) high-voltage and safety standard recognized ceramic capacitor |
CN113161092A (en) * | 2021-04-01 | 2021-07-23 | 肇庆市鼎湖正科集志电子有限公司 | Method for manufacturing strontium titanate annular piezoresistor copper-tin electrode |
-
2009
- 2009-05-22 CN CN2009200571799U patent/CN201425893Y/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104701009A (en) * | 2015-02-10 | 2015-06-10 | 鞍山奇发电子陶瓷科技有限公司 | Small-sized chip type surface mounting (SMD) high-voltage and safety standard recognized ceramic capacitor |
CN113161092A (en) * | 2021-04-01 | 2021-07-23 | 肇庆市鼎湖正科集志电子有限公司 | Method for manufacturing strontium titanate annular piezoresistor copper-tin electrode |
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Granted publication date: 20100317 |