CN1994935B - Odor-free energy-saving micro aerobiont combined processing system for cabaret sewage processing and reusing - Google Patents
Odor-free energy-saving micro aerobiont combined processing system for cabaret sewage processing and reusing Download PDFInfo
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Abstract
Description
所属技术领域Technical field
本发明涉及一种酒店污水处理与回用的无臭节能微氧生物处理组合工艺系统,属于污水处理工艺。The invention relates to an odorless and energy-saving micro-aerobic biological treatment combined process system for hotel sewage treatment and reuse, which belongs to the sewage treatment process.
背景技术Background technique
宾馆污水根据其来源主要有以下几种:According to the sources of hotel sewage, there are mainly the following types:
(1)厨房污水:含有机物,固体杂质,油脂含量高。(1) Kitchen sewage: contains organic matter, solid impurities, and high oil content.
(2)客房卫生间污水:冲洗便器污水和盥洗废水,主要含有有机物、固体杂质、细菌、洗涤剂和皂液。(2) Sewage from toilets in guest rooms: sewage from toilet flushing and washing, mainly containing organic matter, solid impurities, bacteria, detergent and soap.
(3)冲洗汽车废水:主要是固体杂质、石油类油垢。(3) Washing car waste water: mainly solid impurities and petroleum grease.
(4)锅炉房排放的废水:锅炉排出污水及软化再生废液,水中主要含盐类。(4) Wastewater discharged from the boiler room: sewage discharged from the boiler and softened regeneration waste liquid, the water mainly contains salt.
(5)空调冷却废水:主要为热污染。(5) Air-conditioning cooling wastewater: mainly thermal pollution.
(6)室内游泳馆或洗浴中心循环水的滤池冲洗废水及泳池排污废水。(6) The filter tank flushing wastewater and swimming pool sewage wastewater of circulating water in indoor swimming pools or bathing centers.
(7)洗衣房排水:主要含表面活性物质、磷。(7) Laundry drainage: mainly contains surface active substances and phosphorus.
(8)对于含有水景、观赏鱼塘等的园林式度假宾馆,还会有水景循环水。(8) For garden-style resort hotels with water features, ornamental fish ponds, etc., there will also be water features circulating water.
目前,酒店污水普遍采用生化法。生物转盘作为生物处理的主要设施,运行稳定,管理方便,噪音小,运行费用低,抗冲击负荷,污泥产量少,适合中小水量的宾馆使用。生物转盘系统BOD5面积负荷为16.7gBOD5/(m2·d),HRT为1h,且随着水力负荷的变化相应调整转盘转速,转盘出口处投加混凝剂PAC5~10mg/L,加氯消毒接触时间45min。采用四级生物转盘后再以砂滤过滤可以完全保证最终出水水质,但应注意对除油池的及时清淘At present, biochemical methods are widely used in hotel sewage. As the main facility of biological treatment, the biological turntable has stable operation, convenient management, low noise, low operating cost, impact load resistance, and low sludge output, suitable for hotels with small and medium water volumes. The BOD 5 area load of the biological turntable system is 16.7gBOD 5 /(m 2 ·d), the HRT is 1h, and the rotation speed of the turntable is adjusted accordingly with the change of the hydraulic load. Chlorine disinfection contact time 45min. The use of four-stage biological turntable followed by sand filtration can fully guarantee the final water quality, but attention should be paid to the timely cleaning of the degreasing tank
SBR工艺单池间歇运行,底物浓度高,伴随好氧、缺氧、厌氧的生化反应过程,可有效的去处厨房和洗衣房污水中的氮磷,抗冲击负荷强。作为一种技术探讨,将两个SBR池串联,处理哈尔滨香格里拉大酒店废水,对于污水中污染物的去除率基本相当,但两段式SBR出水水质波动更小,水质也稍好一些。两段SBR法处理宾馆污水,大部分(60%左右)有机物在第一段已去除掉,这部分有机物并没有经历长时间的充分氧化分解,节省了生物氧化所需的曝气量能耗和反应时间,去除率主要通过生物絮凝、高效吸附、沉淀网捕和吸附降解作用实现的,被吸附的有机物可通过污泥排放被去除,使得一些难降解物质也可通过污泥去除掉。The SBR process operates intermittently in a single pool, with high substrate concentration, accompanied by aerobic, anoxic, and anaerobic biochemical reaction processes, which can effectively remove nitrogen and phosphorus in kitchen and laundry sewage, and has strong impact load resistance. As a technical discussion, two SBR tanks are connected in series to treat the wastewater from the Shangri-La Hotel in Harbin. The removal rate of pollutants in the sewage is basically the same, but the fluctuation of the water quality of the two-stage SBR effluent is smaller and the water quality is slightly better. The two-stage SBR method treats hotel sewage. Most of the organic matter (about 60%) has been removed in the first stage. This part of the organic matter has not undergone sufficient oxidation and decomposition for a long time, which saves the amount of aeration and energy consumption required for biological oxidation. The reaction time and removal rate are mainly achieved through biological flocculation, high-efficiency adsorption, sedimentation net capture and adsorption degradation. The adsorbed organic matter can be removed through sludge discharge, so that some refractory substances can also be removed through sludge.
DAT-IAT工艺是SBR工艺的改进工艺,也是两个反应池串联运行,DAT持连续进水曝气,IAT间歇运行,这样的双系统可避免水力短路,且占地小,并能进行脱氮除磷。污水首先经DAT段的初步生化后再进入IAT段,由于连续曝气起到了水力均衡作用,提高了整个工艺的稳定性,然后在IAT段通过微生物的降解作用进一步去除污水中的有机污染物.反应池平均流量的水力停留时间为16.5h,泥龄44.3d,可去除难降解有机物。The DAT-IAT process is an improved process of the SBR process. It also operates in series with two reaction tanks. DAT maintains continuous water inflow and aeration, and IAT operates intermittently. Such a dual system can avoid hydraulic short circuit, and occupies a small area, and can perform nitrogen removal. Phosphorus removal. The sewage first passes through the preliminary biochemical treatment in the DAT section and then enters the IAT section. The continuous aeration plays a role in hydraulic balance and improves the stability of the entire process. Then, the organic pollutants in the sewage are further removed in the IAT section through microbial degradation. The hydraulic retention time of the average flow rate of the reaction tank is 16.5h, and the sludge age is 44.3d, which can remove refractory organic matter.
曝气生物滤池往往和水解酸化工艺组合应用,其中水解池多为上流式厌氧污泥床(UASB)的改进型,在池中存有一定高度的污泥层,集生物降解、物理沉降和生物吸附为一体,污水中的颗粒和胶体污染物被截留和吸附,并在产酸细菌等微生物的作用下得到降解。水解池对大肠杆菌和蛔虫卵等有显著去除,并且可以改善和提高原水的可生化性,有利于后续的好氧处理,同时也减少了污泥产量。且该污泥经浓缩、脱水一体化设备处理后含水率为75%~80%,可作为肥料使用。上向流曝气生物滤池(UBAF),滤层高为3m,在滤层的1m高度处设置曝气管系统,使滤层形成缺氧区和好氧区,并将部分出水回流到进水区进行内循环,在缺氧区实现反硝化的目的。采用铝盐作为除磷剂,反应形成的磷酸盐沉淀物通过纤维过滤器去除。The biological aerated filter is often used in combination with the hydrolysis and acidification process. The hydrolysis tank is mostly an improved version of the upflow anaerobic sludge bed (UASB). There is a certain height of sludge layer in the tank, which integrates biological degradation and physical settlement. Integrated with biosorption, the particulate and colloidal pollutants in sewage are trapped and adsorbed, and degraded under the action of microorganisms such as acid-producing bacteria. The hydrolysis tank can significantly remove Escherichia coli and roundworm eggs, etc., and can improve and enhance the biodegradability of raw water, which is conducive to subsequent aerobic treatment, and also reduces sludge production. And the moisture content of the sludge is 75%-80% after being treated by the integrated equipment of concentration and dehydration, and can be used as fertilizer. Upflow Biological Aerated Filter (UBAF), with a filter layer height of 3m, an aeration pipe system is set at a height of 1m in the filter layer, so that the filter layer forms an anoxic zone and an aerobic zone, and part of the effluent is returned to the inlet The water area is internally circulated to achieve the purpose of denitrification in the anoxic area. Aluminum salt is used as phosphorus removal agent, and the phosphate precipitate formed by the reaction is removed through fiber filter.
发明内容Contents of the invention
本发明的目的在于提供一种节能无臭的酒店污水处理与回用新技术,它是采用缺氧生物处理—二级微氧生物处理—二级好氧生物处理—气浮—过滤—UV杀菌消毒组合工艺处理酒店污水,使其达到生活杂用水质标准。The purpose of the present invention is to provide an energy-saving and odorless new technology for hotel sewage treatment and reuse, which uses anoxic biological treatment-secondary micro-aerobic biological treatment-secondary aerobic biological treatment-air flotation-filtration-UV sterilization Disinfection combination process treats hotel sewage to make it meet the domestic miscellaneous water quality standard.
本发明的技术解决方案是酒店污水进入调节池进行水质、水量的均衡调节后,通过提升泵进入缺氧生物处理池进行短暂的兼氧生物水解、酸化,废水溢流进入二级微氧生化池进行生化处理,出水自流进入二级好氧生化池进行好氧生化处理,然后通过投加混凝剂进行混凝气浮处理,最后通过石英砂过滤和颗粒活性炭二级过滤及UV杀毒后进行回用,回用水可达到生活杂用水标准。The technical solution of the present invention is that after the hotel sewage enters the adjustment pool for balanced adjustment of water quality and water volume, it enters the anoxic biological treatment pool through the lifting pump for short-term facultative biological hydrolysis and acidification, and the waste water overflows into the secondary micro-aerobic biochemical pool For biochemical treatment, the effluent flows into the secondary aerobic biochemical tank for aerobic biochemical treatment, and then coagulation and air flotation treatment is carried out by adding coagulant, and finally, it is returned through quartz sand filtration, granular activated carbon secondary filtration and UV disinfection. The reused water can meet the domestic miscellaneous water standard.
本发明的方法及其特征是它由生化处理工艺和物化处理工艺优化组合而成,所述的生化处理工艺是由节能、无臭的缺氧生物处理、二级微氧生物处理和二级好氧生物处理工艺依次优化组合集成的一体化设备;所述的物化处理是由作为后续处理工艺的混凝气浮和石英砂过滤、颗粒活性炭过滤及UV杀菌工艺的依次组合。The method of the present invention and its characteristics are that it is formed by the optimized combination of biochemical treatment process and physicochemical treatment process. Oxygen biological treatment process is sequentially optimized and combined with integrated integrated equipment; the physical and chemical treatment is a sequential combination of coagulation air flotation and quartz sand filtration, granular activated carbon filtration and UV sterilization processes as subsequent treatment processes.
所述的生物处理池均为生物接触氧化池,池内均安装有生物填料,如组合填料、弹性立体填料,微氧生物池和好氧生物池内底部均安装有微孔曝气系统,二级微氧池的DO分别控制在0.3~0.5mg/L,0.5~1.0mg/L,二级好氧生化池内的DO分别控制在1.5~2.0mg/L,2~4mg/L。The biological treatment tanks are all biological contact oxidation tanks, and biological fillers are installed in the tanks, such as combined fillers, elastic three-dimensional fillers, and microporous aeration systems are installed at the bottom of the microaerobic biological tank and the aerobic biological tank. The DO in the oxygen pool is controlled at 0.3-0.5 mg/L and 0.5-1.0 mg/L respectively, and the DO in the secondary aerobic biochemical tank is controlled at 1.5-2.0 mg/L and 2-4 mg/L respectively.
所述的后续物化处理工艺中,混凝剂选用铝盐,如PAC、Al2(SO4)3;气浮采用部分回流加压溶气气浮;过滤采用石英砂过滤,或者石英砂过滤加后续颗粒活性炭过滤;杀菌消毒采用UV254。In the subsequent physical and chemical treatment process, the coagulant is aluminum salt, such as PAC, Al 2 (SO 4 ) 3 ; the air flotation adopts partial reflux pressurized dissolved air flotation; the filter adopts quartz sand filtration, or quartz sand filtration plus Subsequent granular activated carbon filtration; sterilization and disinfection using UV254.
本发明的有益效果是:(1)缺氧生物处理停留时间短,不会产生恶臭,消除了常规厌氧生物处理出现的H2S臭气污染;(2)微氧生物处理工艺不会产生臭气污染,消除了厌氧处理的臭味,与好氧处理相比,减小了曝气量,降低了能耗;(3)缺氧、微氧和好氧生物处理过程依次优化组合而成,处理效果好,有机物去除效率高,出水可达国家综合污水一级排放标准。经后续气浮、过滤及UV消毒处理,出水满足回用水水质标准和要求,可作为生活杂用水。The beneficial effects of the present invention are: (1) the residence time of anoxic biological treatment is short, no stench will be produced, and the H2S odor pollution that occurs in conventional anaerobic biological treatment is eliminated; (2) the microaerobic biological treatment process will not produce Odor pollution eliminates the odor of anaerobic treatment. Compared with aerobic treatment, it reduces the amount of aeration and energy consumption; (3) Anoxic, microaerobic and aerobic biological treatment processes are optimized in sequence The treatment effect is good, the organic matter removal efficiency is high, and the effluent can reach the national comprehensive sewage first-level discharge standard. After subsequent air flotation, filtration and UV disinfection treatment, the effluent meets the water quality standards and requirements for reused water and can be used as miscellaneous domestic water.
附图说明Description of drawings
图1为本发明的工艺流程示意图。Fig. 1 is a schematic diagram of the process flow of the present invention.
具体实施方式Detailed ways
实施例1Example 1
某酒店污水,起水质特征如表1所示,采用本发明的图1工艺流程进行处理。在调节池HRT为8h;缺氧池2h;一级微氧池HRT为3h,DO为0.5~0.8mg/L;二级微氧池HRT为2h,DO为1.0~1.5mg/L;一级好氧池HRT为3h,DO为1.5~2.0mg/L;二级好氧池HRT为2h,DO为2~4mg/L;混凝剂为PAC,在5~10mg/L的条件下正常运行处理,最后出水依次经过石英砂、活性炭过滤和UV杀菌消毒后优于生活杂用水质标准和要求。处理结果见表1所示。另外,处理过程中无H2S等异味出现,处理系统与常规工艺相比节约能耗20%以上。Certain hotel sewage, water quality characteristic as shown in table 1, adopts Fig. 1 process flow of the present invention to process. In the adjustment pool, the HRT is 8 hours; the anoxic pool is 2 hours; the HRT of the first-level micro-oxygen pool is 3 hours, and the DO is 0.5-0.8 mg/L; the HRT of the second-level micro-oxygen pool is 2 hours, and the DO is 1.0-1.5 mg/L; The HRT of the aerobic pool is 3 hours, and the DO is 1.5-2.0 mg/L; the HRT of the secondary aerobic pool is 2 hours, and the DO is 2-4 mg/L; the coagulant is PAC, and it operates normally under the condition of 5-10 mg/L After treatment, the final effluent is better than domestic miscellaneous water quality standards and requirements after being filtered by quartz sand, activated carbon and UV sterilization. The processing results are shown in Table 1. In addition, no peculiar smell such as H 2 S occurs during the treatment process, and the treatment system saves energy consumption by more than 20% compared with conventional processes.
表1水质特征及处理结果(mg/L)Table 1 Water quality characteristics and treatment results (mg/L)
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| CN101172744B (en) * | 2007-11-20 | 2011-06-15 | 中国科学院南京地理与湖泊研究所 | A treatment method and device for recycling dimethyl ether production wastewater to industrial circulating cooling water |
| CN102101747A (en) * | 2011-03-21 | 2011-06-22 | 刘情生 | Three-stage anaerobic two-stage aerobic inner circulation reclaimed water treater |
| CN102351369A (en) * | 2011-07-04 | 2012-02-15 | 北京中科百旺环保科技有限公司 | Technology for processing refractory organic wastewater by using hybrid facultative biomembrane reactor |
| CN102976548A (en) * | 2011-09-06 | 2013-03-20 | 中国科学院城市环境研究所 | Zero emission district sewage resource treatment apparatus |
| CN102951773A (en) * | 2012-11-29 | 2013-03-06 | 贵州长绿科技有限公司 | Technique for treating beer waste water |
| CN103482815A (en) * | 2013-03-26 | 2014-01-01 | 新能(张家港)能源有限公司 | Wastewater processing apparatus and wastewater processing method |
| CN111170558A (en) * | 2020-01-06 | 2020-05-19 | 昆山水清华环保科技有限公司 | Pig farm sewage treatment process |
| CN111925076B (en) * | 2020-09-08 | 2022-09-02 | 福州大学 | Ship reclaimed water treatment and reuse integrated equipment and working method thereof |
| CN112125452A (en) * | 2020-09-24 | 2020-12-25 | 上海城市水资源开发利用国家工程中心有限公司 | System and method for removing medicine difficult to remove in water plant process |
| CN113233720A (en) * | 2021-06-24 | 2021-08-10 | 浙江工业大学 | Integrated treatment method for upgrading domestic sewage from first-level A to surface III-class water standard |
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| CN2410293Y (en) * | 2000-03-12 | 2000-12-13 | 陈漫漫 | Integral synchronous denitrification biological treatment reactor |
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|---|---|---|---|---|
| CN2410293Y (en) * | 2000-03-12 | 2000-12-13 | 陈漫漫 | Integral synchronous denitrification biological treatment reactor |
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| 肖羽堂等.酒店污水处理及回用技术的研究与工程应用.给水排水31 6.2005,31(6),第79页左栏第2-16行,右栏第3-26行. |
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