CN1988055A - Extra-fine copper alloy wire, extra-fine copper alloy twisted wire, coaxial cable, multi-core cable and manufacturing method thereof - Google Patents
Extra-fine copper alloy wire, extra-fine copper alloy twisted wire, coaxial cable, multi-core cable and manufacturing method thereof Download PDFInfo
- Publication number
- CN1988055A CN1988055A CNA2006101687702A CN200610168770A CN1988055A CN 1988055 A CN1988055 A CN 1988055A CN A2006101687702 A CNA2006101687702 A CN A2006101687702A CN 200610168770 A CN200610168770 A CN 200610168770A CN 1988055 A CN1988055 A CN 1988055A
- Authority
- CN
- China
- Prior art keywords
- copper alloy
- wire
- superfine
- mentioned
- coaxial cable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
Landscapes
- Conductive Materials (AREA)
- Non-Insulated Conductors (AREA)
- Communication Cables (AREA)
- Processes Specially Adapted For Manufacturing Cables (AREA)
Abstract
The object of the invention is to provide an extra-fine copper alloy wire, an extra-fine copper alloy twisted wire, an extra-fine insulated wire, a coaxial cable having high intensity, low resistance and high heat tolerance, their manufacturing method and a multicore cable thereof. The extra-fine copper alloy wire has 1 to 3 weight % of silver in the copper, a wire diameter less than 0.025 mm, and a tensile strength of more than 850 MPa, an electrical conductivity of more than 85% IACS after heat treatment; the coaxial cable (20A) is configured that, an inner conductor is formed by an extra-fine copper alloy twisted wire (3) twisted from seven extra-fine copper alloy wires (1), the inner conductor is then peripherally envelopped with a solid insulator (5a) to form an extra-fine insulated wire (10), a plurality of conductor wires (13) are winding in a screw shape on the periphery of the extra-fine insulated wire along a length direction of the extra-fine insulated wire to form an outer conductor (15), thereafter, the outer conductor is envenlopped with a protection layer (17).
Description
Technical field
The present invention relates to have high strength, high conduction performance, and its intensity also is difficult to reduce in the operation that applies heat load of squeeze job, solder operation and so on, heat resistance is also very excellent superfine copper alloy wire, its twisted wire, insulated wire, coaxial cable and their manufacture method and use the multicore cable that their make.
Background technology
The anti-bending cable employed conductor materials such as (for example, probe cable) that anti-bending cable of using as electronic equipment (for example, the automatics cable) or Medical Devices are used uses the alloy with high-strength and high-conductivity usually.
Now, as the copper alloy wire made from a large amount of levels of production, can enumerate the Cu-Sn alloy wire and the Cu-Sn-In alloy wire of the economical that can produce with continuous casting and milling method, and be widely used as electronic equipment with and the conductor material of the anti-bending cable used of Medical Devices.In addition, other copper alloy wire also is applicable to various fields according to the various characteristics of product cost and copper alloy wire.
In recent years, along with the miniaturization of miniaturization, lightweight or the Medical Devices of electronic equipment, the conductor diameter of their employed electric wires also requires superfine, reaches the following degree of conductor diameter requirement Φ 0.03mm.Complicated along with the ultrasonic endoscope head can be found the tendency that ultrasonic endoscope has further the direction to multiple-core (200-260 core) develop with cable.On the other hand, in order to reduce patient's misery, the diameter that reduces endoscope head has also been improved requirement.Also be significant the employed curling cable etc. when the requirement of thin footpathization is performed the operation in implementing in blood vessel near the blood vessel of the affected part of being scheduled to.
In addition, not only require thin footpathization recently, and in order to improve resistance to bend(ing) and to increase transmission capacity, also the strong request exploitation has the conductor material of high-strength characteristic and high conductive characteristic simultaneously.
The copper alloy that above-mentioned Cu-Sn alloy wire and Cu-Sn-In alloy wire have generated by added Sn in the reverberatory refining copper as parent metal constitutes.Yet the Cu-Sn alloy wire must increase the addition of Sn in order to gain in strength, its result, and its conductance reduction will take into account intensity and conductance two aspects are difficult.
On the other hand, as the copper alloy that has high intensity and high conductance simultaneously, the Cu-Ag alloy comes into one's own.The Cu-Ag alloy that tensile strength and conductance are good for example passes through, the Cu-Ag alloy that will contain 1.0-15 weight % in copper carries out following processing and makes: 1. the bar that casting is obtained carries out cold working and makes after its reduction of area reaches more than 70%, 2. under 400-500 ℃ temperature, carry out 1-30 hour heat treatment, subsequently, 3. carry out reduction of area and reach cold working (with reference to patent documentation 1-TOHKEMY 2001-40439 communique) more than 95.
In addition, also can manufacture superfine copper alloy twisted wire as follows: the silver that adds 0.1-1.0 weight % in fine copper forms the Cu-Ag alloy, making diameter again is that 0.01-0.8mm, tensile strength are the above single line of 600MPa, with this single line with predetermined bar number stranded after, make (with reference to patent documentation 1-TOHKEMY 2001-234309 communique) by this twisted wire being heat-treated with the stress of eliminating when stranded.
When this superfine copper alloy wire that is made of the Cu-Ag alloy is used as anti-bending cable, generally be to coat in skin extruding to use after fusing point is a insulator about 300 ℃, but in this squeeze job, because the heat of the insulator when coating and the heat load of extruder head reduce mechanical property, the especially tensile strength of superfine copper alloy wire.And then, endways in the processing, owing to the heat of about 300-350 ℃ flatiron of solder operation significantly reduces the tensile strength of the superfine copper alloy wire of terminal part.Therefore, after squeeze job and solder operation, then be difficult to sometimes guarantee electrical characteristic and mechanical property both, especially because the reduction of tensile strength, the Mechanical Reliability to cable and cable end piece processing part produces infringement greatly sometimes.Thereby, as to the desired characteristic of superfine copper alloy wire, not only to have high intensity and high conductance simultaneously, but also require its intensity not because of standing the thermal stability that thermal processs such as squeeze job reduce.
In addition, for example, in the cable that probe cable that diagnostic ultrasound equipment is used or ultrasonic endoscope are used, owing to use diameter to be the superfine wire below the 0.025mm, thereby, then become problem with the corresponding resistance of such conductor size.Concrete is according to American wire gage (AWG-America Wire Gauge) standard, to require really to reach the superfine copper alloy twisted wire of thin footpathization and good this two aspect of electrical characteristic.The pass of AWG standard and twisted wire structure (twisted wire radical/line footpath) is 42AWG (7/0.025), 43AWG (7/0.023), 44AWG (7/0.020), 45AWG (7/0.018), 46AWG (7/0.016), 48AWG (7/0.013), 50A
Yet, for the Cu-Ag alloy of patent documentation 1 record, as the method that it is reached have simultaneously high tensile strength and high conductance to be taken into account, owing to be under specific temperature, it to be carried out the heat treatment of (1-30 hour) for a long time, thereby, not only reduced production efficiency but also improved cost.In addition, the thermal process during for the heat load that applied by squeeze job etc. and intensity is reduced had not both had any relating to, and did not take some countermeasures yet.Have again, for also not having any relating to the corresponding resistance of the conductor size of superfine diameter.
On the other hand, in the superfine copper alloy twisted wire of patent documentation 2, though record silver as the interpolation element of copper alloy, addition arrives 0.1-1.0 weight % less, does not look to improving intensity with it.In addition, in this superfine copper alloy twisted wire, though with the flexural property that improves the plastic deformation field be purpose mainly guaranteed the elongation characteristic more than 5%, for having paid attention to the elongation characteristic, its tensile strength must reduce.Therefore, especially for use line through as the electronic equipment of the superfine wire below the 0.025mm with cable or cable for medical apparatus, for example there is its undercapacity in the cable applications used of the probe cable used of diagnostic ultrasound equipment or ultrasonic endoscope, the inadequate problem of bendability.
Summary of the invention
Therefore, purpose of the present invention just is to solve aforesaid problem, the superfine wire of a kind of finish line footpath below 0.025mm is provided, have simultaneously high-strength characteristic and low resistance characteristic (high conductivity) both, and, its intensity also is difficult to reduce in the heat load of the extruding manufacturing operation of the coaxial cable that has used superfine wire and the solder operation of end portion etc., also has the superfine copper alloy wire of high-fire resistance, superfine copper alloy twisted wire, superfine insulating properties and coaxial cable and their manufacture method simultaneously and has used their multicore cable.
In order to realize the foregoing invention purpose, superfine copper alloy wire of the present invention is that line directly is 0.010-0.025mm, by the silver that contains 1-3 weight % (Ag), all the other superfine copper alloy wires for copper (Cu) and unavoidable impurities formation, its tensile strength is more than the 850MPa, conductance is more than 85%IACS, and elongation is 0.5-3.0%; And, through the heat treated of temperature below 350 ℃, below 5 seconds of time, the tensile strength (σ after the heat treated
H1) with respect to the tensile strength (σ before the heat treated
H0) reduced rate [(1-σ
H1/ σ
H0) * 100%] below 2%.，
Can be at the coating that forms tin (Sn), silver (Ag) or nickel (Ni) on the surface of above-mentioned alloy wire.
Can form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded.Above-mentioned superfine copper alloy twisted wire is being 6000 Ω/below the km for the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.025mm at 20 ℃ resistance directly with 7 lines; Be 7000 Ω/below the km at 20 ℃ resistance directly with 7 lines for the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.023mm; Be 9500 Ω/below the km at 20 ℃ resistance directly with 7 lines for the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.020mm; Be 11500 Ω/below the km at 20 ℃ resistance directly with 7 lines for the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.018mm; Be 15000 Ω/below the km at 20 ℃ resistance directly with 7 lines for the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.016mm; Be 22000 Ω/below the km at 20 ℃ resistance directly with 7 lines for the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.013mm; Be 38000 Ω/below the km at 20 ℃ resistance directly with 7 lines for the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.010mm.
In order to realize the foregoing invention purpose, superfine copper alloy wire of the present invention manufacture method, it is characterized in that, the silver that adds 1-3 weight % in fine copper generates copper alloy, carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm, by carry out the 0.2-5 heat treatment of second under 300-500 ℃ temperature, making it become tensile strength is more than the 850MPa, conductance is more than 85%IACS, and elongation is 0.5-3.0%; And, through the heat treated of temperature below 350 ℃, below 5 seconds of time, the tensile strength (σ after the heat treated
H1) with respect to the tensile strength (σ before the heat treated
H0) reduced rate [(1-σ
H1/ σ
H0) * 100%] at the superfine copper alloy wire below 2%.
(, can also have the operation that forms the coating of tin (Sn), silver (Ag), nickel (Ni) on the surface of this superfine copper alloy wire making above-mentioned line directly for behind the superfine copper alloy wire of 0.010-0.025mm.
In addition, the feature of the manufacture method of superfine copper alloy twisted wire of the present invention is, the silver that adds 1-3 weight % in fine copper generates copper alloy, carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm, form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded, by under 300-500 ℃ temperature, carrying out the 0.2-5 heat treatment of second, thereby make above-mentioned superfine copper alloy twisted wire.
In order to realize the foregoing invention purpose, the feature of superfine insulated wire of the present invention is, form the superfine copper alloy wire twisted wire with many for the 0.010-0.025mm superfine copper alloy wire is stranded by the silver that contains 1-3 weight % (Ag), all the other line footpaths for copper (Cu) and unavoidable impurities formation, the tensile strength of above-mentioned superfine copper alloy wire twisted wire is that conductance is more than 85%IACS more than the 850MPa; And,, coated the following solid insulator of thickness 0.07mm and formed in the periphery of above-mentioned superfine copper alloy twisted wire.
Above-mentioned superfine copper alloy twisted wire is after heat treatment twisted wire preferably, and the resistance reduced rate after the above-mentioned heat treatment is more than 6%, and the tensile strength reduced rate after the above-mentioned heat treatment is below 20%.
Can be at the coating that forms tin (Sn), silver (Ag) or nickel (Ni) on the surface of above-mentioned copper alloy wire.
In order to realize the foregoing invention purpose, the feature of the manufacture method of superfine insulated wire of the present invention is, the silver that adds 1-3 weight % in fine copper generates copper alloy, carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm, form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded, by after carrying out the 0.2-5 heat treatment of second under 300-500 ℃ the temperature, coating thickness in the periphery of above-mentioned copper alloy twisted wire again is that solid insulator below the 0.07mm forms.
In order to realize the foregoing invention purpose; coaxial cable of the present invention is to form length direction along above-mentioned superfine insulated wire with the helically wound external conductor of many strip conductors coil of wire in the periphery of above-mentioned superfine insulated wire, has coated protective layer in the said external surface of conductors again.
Can make following coaxial cable: the line footpath of copper alloy wire that constitutes above-mentioned superfine insulated wire is for greater than the coaxial cable of 0.021mm below 0.025mm, its resistance is 7200 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 0.6-1.0db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 20000 times under the condition of radius of curvature R=2mm, load=50g; The line footpath of copper alloy wire that constitutes above-mentioned superfine insulated wire is for greater than the coaxial cable of 0.018mm below 0.022mm, its resistance is 9500 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 0.8-1.2db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 20000 times under the condition of radius of curvature R=2mm, load=50g; The line footpath of copper alloy wire that constitutes above-mentioned superfine insulated wire is for greater than the coaxial cable of 0.016mm below 0.020mm, its resistance is 12200 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 1.0-1.5db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 20000 times under the condition of radius of curvature R=2mm, load=50g; The line footpath of copper alloy wire that constitutes above-mentioned superfine insulated wire is for greater than the coaxial cable of 0.014mm below 0.018mm, its resistance is 14700 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 1.1-1.6db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 30000 times under the condition of radius of curvature R=2mm, load=50g; The line footpath of copper alloy wire that constitutes above-mentioned superfine insulated wire is for greater than the coaxial cable of 0.013mm below 0.017mm, its resistance is 16500 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 1.3-1.8db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 30000 times under the condition of radius of curvature R=2mm, load=20g; The line footpath of copper alloy wire that constitutes above-mentioned superfine insulated wire is for greater than the coaxial cable of 0.011mm below 0.015mm, its resistance is 22500 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 1.7-2.4db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 30000 times under the condition of radius of curvature R=2mm, load=20g; The line footpath of copper alloy wire that constitutes above-mentioned superfine insulated wire is for greater than the coaxial cable of 0.010mm below 0.012mm, its resistance is 38000 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 2.5-3.8db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 10000 times under the condition of radius of curvature R=2mm, load=20g.
In order to realize the foregoing invention purpose; the feature of the manufacture method of coaxial cable of the present invention is: the silver that adds 1-3 weight % in fine copper generates copper alloy; carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm; form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded; by after carrying out the 0.2-5 heat treatment of second under 300-500 ℃ the temperature; coating thickness in the periphery of above-mentioned copper alloy twisted wire again is that solid insulator below the 0.07mm becomes superfine insulated wire; again in the periphery of above-mentioned superfine insulated wire; length direction along above-mentioned superfine insulated wire after having formed external conductor, coats many strip conductors coil of wire coiled protective layer in the said external surface of conductors again and forms.
In order to realize the foregoing invention purpose, the feature of coaxial cable of the present invention is, form the superfine copper alloy wire twisted wire with many for the 0.010-0.025mm superfine copper alloy wire is stranded by the silver that contains 1-3 weight % (Ag), all the other line footpaths for copper (Cu) and unavoidable impurities formation, the tensile strength of above-mentioned superfine copper alloy wire twisted wire is that conductance is more than 85%IACS more than the 850MPa; And; periphery at above-mentioned superfine copper alloy twisted wire; coat the cellular insulation body; form along the length direction of above-mentioned superfine copper alloy twisted wire in the periphery of above-mentioned cellular insulation body more strip conductors coil of wire coiled is formed external conductor, coated protective layer in the said external surface of conductors again.
Above-mentioned superfine copper alloy twisted wire is after heat treatment twisted wire preferably, and the resistance reduced rate after the above-mentioned heat treatment is more than 6%, and the tensile strength reduced rate after the above-mentioned heat treatment is below 20%.
Can form the coating of tin (Sn), silver (Ag) or nickel (Ni) on the surface of above-mentioned copper alloy wire.
Can make following coaxial cable: the line of above-mentioned superfine copper alloy wire footpath is for greater than the coaxial cable of 0.021mm below 0.025mm, and its resistance is that 7500 Ω/below the km, electrostatic capacitance is 30-80pF/m; The line of above-mentioned superfine copper alloy wire footpath is for greater than the coaxial cable of 0.018mm below 0.022mm, and its resistance is that 10000 Ω/below the km, electrostatic capacitance is 30-80pF/m; The line of above-mentioned superfine copper alloy wire footpath is for greater than the coaxial cable of 0.016mm below 0.020mm, and its resistance is that 13000 Ω/below the km, electrostatic capacitance is 30-80pF/m; The line of above-mentioned superfine copper alloy wire footpath is for greater than the coaxial cable of 0.014mm below 0.018mm, and its resistance is that 15500 Ω/below the km, electrostatic capacitance is 30-80pF/m; The line of above-mentioned superfine copper alloy wire footpath is for greater than the coaxial cable of 0.013mm below 0.017mm, and its resistance is that 17000 Ω/below the km, electrostatic capacitance is 30-80pF/m; The line of above-mentioned superfine copper alloy wire footpath is for greater than the coaxial cable of 0.011mm below 0.015mm, and its resistance is that 23500 Ω/below the km, electrostatic capacitance is 30-80pF/m; The line of above-mentioned superfine copper alloy wire footpath is for greater than the coaxial cable of 0.010mm below 0.012mm, and its resistance is that 40000 Ω/below the km, electrostatic capacitance is 30-80pF/m.
In order to realize the foregoing invention purpose; the feature of the manufacture method of coaxial cable of the present invention is; the silver that adds 1-3 weight % in fine copper generates copper alloy; carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm; form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded; by after carrying out the 0.2-5 heat treatment of second under 300-500 ℃ the temperature; again in the periphery of above-mentioned copper alloy twisted wire after to coat thickness be cellular insulation body below the 0.28mm; form epidermal area; again in the periphery of this epidermal area; length direction along above-mentioned copper alloy twisted wire after forming external conductor, coats many strip conductors coil of wire coiled protective layer in the said external surface of conductors again and forms.
And then, can or be situated between stranded many above-mentioned coaxial cables and constitute multicore cable at tension member in the periphery of heart yearn.
Can also or be situated between at tension member in the periphery of heart yearn, many above-mentioned coaxial cables and above-mentioned superfine insulated wire is stranded and constitute multicore cable.
Can also or be situated between at tension member in the periphery of heart yearn, many above-mentioned superfine insulated wires is stranded and constitute multicore cable.
Can also or be situated between in the periphery of heart yearn at tension member, the coaxial cable unit that many above-mentioned coaxial cable harnesses are formed is a plurality of stranded and constitute multicore cable.
Many above-mentioned superfine insulated wire spacings at certain intervals can also be wound on the center conductor line and constitute multicore cable.
Many above-mentioned coaxial cables can also be disposed and the formation multicore cable side by side with a determining deviation.
According to the present invention, can provide finish line directly to be the following superfine wire of 0.025mm, have simultaneously high-strength characteristic and low resistance characteristic (high conductivity) both, even also be difficult to reduce through its intensity of affected by hot loading, and have the superfine copper alloy wire of high-fire resistance, superfine copper alloy twisted wire, superfine insulated wire, coaxial cable and a multicore cable.
Description of drawings
Fig. 1 is the cross-sectional view of the superfine copper alloy wire of an embodiment of the invention.
Fig. 2 is the cross-sectional view of the superfine copper alloy twisted wire of an embodiment of the invention.
Fig. 3 is the cross-sectional view of the plating superfine copper alloy wire of an embodiment of the invention.
Fig. 4 is the cross-sectional view of the superfine copper alloy twisted wire of the plating of an embodiment of the invention.
Fig. 5 is the cross-sectional view of the superfine insulated wire of an embodiment of the invention.
Fig. 6 is the cross-sectional view of the coaxial cable of an embodiment of the invention.
Fig. 7 is the cross-sectional view of the coaxial cable of another execution mode of the present invention.
Fig. 8 is the cross-sectional view of the multicore cable of an embodiment of the invention.
Fig. 9 is the cross-sectional view of the multicore cable of another embodiment of the invention.
Figure 10 is the cross-sectional view of the multicore cable of another execution mode of the present invention.
Figure 11 is the cross-sectional view of the multicore cable of another execution mode of the present invention.
Figure 12 is the end view of the multicore cable of other execution mode of the present invention.
Figure 13 is the sectional drawing of the multicore cable of other execution mode of the present invention.
Embodiment
The first, superfine copper alloy wire of the present invention is described.
Fig. 1 represents the superfine copper alloy wire of present embodiment.
This superfine copper alloy wire 1 is the Cu-Ag alloy wire, and its line directly is 0.025-0.010mm, the heavy % of argentiferous 1-3, and preferred argentiferous 1.5-2.5 weight %, its tensile strength is more than the 850MPa, and conductance is more than the 85%IACS, and elongation is 0.5-3.0%.
The reason that argentiferous is measured 1-3 weight % is because if less than 1 weight %, the raising of intensity does not reach requirement, if surpass 3 weight %, reduces though intensity improves conductance.Have again, by with silver content preferably in the scope of 1.5-2.5 weight %, then can obtain strength characteristics and the good performance of conductivity characteristics both.In addition, when tensile strength is got more than the 850MPa, conductance is more than the 85%IACS, when elongation is 0.5-3.0%, consider the situation that is used for cable for medical apparatus, above-mentioned scope can satisfy the requirement of various characteristicses such as bendability, resistance, pliability, and outside above-mentioned scope, then can not satisfy these characteristics.
Have, superfine copper alloy wire 1 is through temperature below 350 ℃ again, the heat treated of time below 5 seconds, the tensile strength (σ after the heat treated
H1) with respect to the tensile strength (σ before the heat treated
H0) reduced rate [(1-σ
H1/ σ
H0) * 100%] be decided to be below 2%.
Why the heat treated condition is decided to be temperature below 350 ℃, the time is because in the cables manufacturing process of superfine copper alloy wire and twisted wire, for example the heat load condition of insulator extrusion process is in this scope below 5 seconds.In addition, why with the tensile strength (σ after the heat treated
H1) with respect to the tensile strength (σ before the heat treated
H0) reduced rate [(1-σ
H1/ σ
H0) * 100%] be decided to be below 2%, be because if reduced rate surpasses 2%, in extrusion process, can produce broken string, cause cable properties significantly to reduce.Therefore, fix in the above-mentioned scope, then can make and can not break and the performance cable that can not change by reduction with intensity.
The second, superfine copper alloy twisted wire is described.
Fig. 2 represents the superfine copper alloy twisted wire of present embodiment.
This superfine porgy alloy twisted wire 3 has set relation with 7 superfine copper alloy wires shown in Figure 1,1 stranded forming between its line footpath and the resistance.
Promptly, this superfine copper alloy twisted wire 3 is with 7 Cu-Ag alloy wires, be that line directly is 0.025-0.010mm, silver content is 1-3 weight %, preferred silver content is 1.5-2.5 weight %, and tensile strength is more than the 850MPa, and conductance is more than the 85%IACS, elongation is superfine copper alloy wire 1 stranded the forming of 0.5-3.0%, and its line footpath and resistance have following relation.
Article 7, line is directly for 20 ℃ resistance of the twisted wire of 0.025mm is 6000 Ω/below the km,
Article 7, line is directly for 20 ℃ resistance of the twisted wire of 0.023mm is 7000 Ω/below the km,
Article 7, line is directly for 20 ℃ resistance of the twisted wire of 0.020mm is 9500 Ω/below the km,
Article 7, line is directly for 20 ℃ resistance of the twisted wire of 0.018mm is 11500 Ω/below the km,
Article 7, line is directly for 20 ℃ resistance of the twisted wire of 0.016mm is 15000 Ω/below the km,
Article 7, line is directly for 20 ℃ resistance of the twisted wire of 0.013mm is 22000 Ω/below the km,
Article 7, line is directly for 20 ℃ resistance of the twisted wire of 0.010mm is 38000 Ω/below the km,
It is the superfine copper alloy twisted wire 3 of really having taken into account thin footpathization and electrical characteristic in order to make by the AWG standard that each size is all defined resistance.
Below, the superfine copper alloy wire that has formed coating, superfine copper alloy twisted wire are described.
Fig. 3 represents the example of plating superfine copper alloy wire.
Plating superfine copper alloy wire 2 is the periphery formation coating 6 at superfine copper alloy wire shown in Figure 11.Coating 6 is mainly considered from the corrosion resistance and the solder connectivity aspect that improve superfine copper alloy wire 1, is formed the coating that is made of tin (Sn), silver (Ag) or nickel (Ni) usually.
In addition, as shown in Figure 4, with 7 plating superfine copper alloy wires, the 2 stranded superfine copper alloy twisted wires 4 of plating of also can making.
Below, the manufacture method of the superfine copper alloy wire 1 and the superfine copper alloy twisted wire 3 of present embodiment is described.
At first, in fine copper, add the silver of 1-3 weight %, preferably add the silver of 1.5-2.5 weight %, generate copper alloy, then, through wire drawing processing or carry out intermediate heat-treatment and make line and directly be the superfine wire of 0.025-0.010mm.At this moment, also can in the course of processing, carry out zinc-plated (Sn), silver (Ag) or nickel (Ni) and handle, finally make line and directly be the superfine wire of 0.025-0.010mm the line surface.
Secondly, resulting superfine copper alloy wire single line or for example 7 stranded superfine copper alloy twisted wires that form that will be scheduled to the bar number are heat-treated under given conditions.Heat treatment is handled 0.2-5 and is carried out second by moving in being heated to 300-500 ℃ heating furnace.
Why being decided to be as heat-treat condition and carrying out under 300-500 ℃ 0.2-5 second, is because if heat treatment temperature is lower than 300 ℃, heat treatment time less than 0.2 second, though then the reduction of tensile strength is little, the increase of conductance is also less and the characteristic that can not obtain requiring.In addition, if heat treatment temperature surpasses 500 ℃, heat treatment time surpasses 5 seconds, though conductance increases, tensile strength significantly reduces, and can not obtain desired characteristic.
Concrete is, by heat-treating under the condition of 300-500 ℃ and 0.2-5 second, can accomplish to make the tensile strength (σ after the heat treatment
A1) with respect to the tensile strength (σ before the heat treatment
A0) reduced rate [(1-σ
A1/ σ
A0) * 100%] be below 30%, and, make the conductance (ρ after the heat treatment
A1) with respect to the conductance (ρ before the heat treatment
A0) increment rate [((ρ
A1)/(ρ
A0)-1) * 100% be more than 60%].
Carry out the superfine copper alloy wire or the superfine copper alloy twisted wire that obtain after the above processing, its line is 0.025-0.010mm directly, contains the silver of 1-3 weight %, the silver of preferred 1.5-2.5 weight %, its tensile strength is more than the 850MPa, and conductance is more than the 85%IACS, and elongation is 0.5-3.0%; And, through temperature below 350 °, the heat treated of time below 5 seconds, the tensile strength (σ after its heat treated
H1) with respect to the tensile strength (σ before the heat treated
H0) reduced rate [(1-σ
H1/ σ
H0) * 100%] below 2%.
If adopt present embodiment, can obtain finish line and directly be the following superfine wire of 0.025mm, can be had simultaneously high-strength characteristic and low resistance characteristic (high conductivity) both, and, even its intensity also is difficult to reduce in the heat loads such as extruding manufacturing process of the coaxial cable that has used superfine wire, also with the superfine copper alloy wire and the superfine copper alloy twisted wire of high-fire resistance.
Therefore, make coaxial cable etc. if use these superfine copper alloy wires, superfine copper alloy twisted wire, just can be applicable to require miniaturization, thin footpathization, in light weight, high resistance to bend(ing) the electronic equipment usefulness and the cable for medical apparatus of performance such as transmission performance is good well.
Embodiment 1
Make the Cu-Ag alloy wire.
The silver that in oxygen-free copper, adds 2.0 weight %, elongation (%).And then, as stable on heating evaluation,, compared the Strength Changes of tensile strength thereafter 350 ℃ of heat treated of having carried out 5 seconds.Carry out respectively more directly processing, just obtained superfine copper alloy wire for the wire drawing of 0.025-0.010mm up to line.Then, under the heat-treat condition in prescribed limit resulting superfine copper alloy wire is heat-treated, just made superfine copper alloy wire.
For the superfine copper alloy wire of each size that makes, measured its tensile strength (MPa), conductance (%IACS), elongation (%).And then, as stable on heating evaluation,, compared the Strength Changes of tensile strength thereafter 350 ℃ of heat treated of having carried out 5 seconds.At this, the intensity decrease rate of thermal endurance after with heat treated estimated, and intensity decrease rate is the tensile strength (σ after the heat treated
H1) with respect to the tensile strength (σ before the heat treated
H0) reduced rate [(1-σ
H1/ σ
H0) * 100%].The results are shown in table 1.
Table 1
| NO. | Line footpath (mm) | Ag concentration (weight %) | Tensile strength (MPa) | Conductance (%IACS) | Elongation (%) | Thermal endurance (%) | Heat treatment (℃ * second) |
| 1 | 0.025 | 2.0 | 952 | 86.2 | 1.3 | 1.3 | 350×5.0 |
| 2 | 0.025 | 2.0 | 915 | 88.3 | 1.5 | 1.2 | 450×1.5 |
| 3 | 0.025 | 2.0 | 910 | 87.2 | 1.4 | 1.1 | 500×0.4 |
| 4 | 0.023 | 2.0 | 960 | 86.4 | 1.2 | 1.2 | 350×5.0 |
| 5 | 0.023 | 2.0 | 920 | 88.1 | 1.0 | 1.1 | 450×1.5 |
| 6 | 0.023 | 2.0 | 915 | 87.6 | 1.5 | 1.2 | 500×0.4 |
| 7 | 0.020 | 2.0 | 954 | 86.0 | 1.2 | 1.0 | 350×5.0 |
| 8 | 0.020 | 2.0 | 930 | 87.2 | 1.4 | 0.5 | 450×1.5 |
| 9 | 0.020 | 2.0 | 925 | 86.5 | 1.3 | 0.6 | 500×0.4 |
| 10 | 0.018 | 2.0 | 965 | 87.8 | 1.4 | 1.2 | 350×5.0 |
| 11 | 0.018 | 2.0 | 925 | 88.1 | 1.5 | 1.0 | 450×1.5 |
| 12 | 0.018 | 2.0 | 920 | 87.1 | 1.4 | 1.0 | 500×0.4 |
| 13 | 0.016 | 2.0 | 962 | 86.8 | 1.3 | 1.2 | 350×5.0 |
| 14 | 0.016 | 2.0 | 935 | 87.4 | 1.2 | 1.3 | 450×1.5 |
| 15 | 0.016 | 2.0 | 923 | 87.2 | 1.4 | 1.3 | 500×0.4 |
| 16 | 0.013 | 2.0 | 975 | 86.0 | 1.2 | 1.1 | 350×5.0 |
| 17 | 0.013 | 2.0 | 950 | 86.3 | 1.0 | 1.2 | 450×1.5 |
| 18 | 0.013 | 2.0 | 940 | 86.2 | 1.3 | 1.0 | 500×0.4 |
| 19 | 0.010 | 2.0 | 985 | 87.5 | 1.2 | 1.2 | 350× 5.0 |
| 20 | 0.010 | 2.0 | 950 | 86.5 | 1.0 | 1.4 | 450×1.5 |
| 21 | 0.010 | 2.0 | 935 | 87.1 | 1.3 | 1.2 | 500×0.4 |
Embodiment 2
Below, illustrate and make Cu-Ag alloy twisted wire.
The silver that adds 2.0 weight % in oxygen-free copper after the heat fused, uses the graphite casting die continuous casting to make the line base of Φ 8.0mm in the black-fead crucible in being fixed in vacuum tank., through wire drawing processing, intermediate annealing, hot candied processing, silver-plated operation, subsequently, more respectively carry out up to line directly for the wire drawing of 0.025-0.010mm process, just obtained superfine copper alloy wire thereafter.And then, carry out the superfine copper alloy wire of 7 resulting every kind of sizes stranded again and obtained superfine copper alloy twisted wire.
For the superfine copper alloy wire of each size that makes, measured its tensile strength (MPa), resistance (Ω/km), elongation (%).And then, as stable on heating evaluation,, compared the Strength Changes of tensile strength thereafter 350 ℃ of heat treated of having carried out 5 seconds.At this, thermal endurance is estimated with the intensity decrease rate after the heat treated similarly to Example 1, and intensity decrease rate is the tensile strength (σ after the heat treated
H1) with respect to the tensile strength (σ before the heat treated
H0) reduced rate [(1-σ
H1/ σ
H0) * 100%].The results are shown in table 2.
Table 2
| NO. | Bar number/line footpath (bar/mm) | Ag concentration (weight %) | Tensile strength (MPa) | Resistance (Ω/km) | Elongation (%) | Thermal endurance (%) | Heat treatment (℃ * second) |
| 1 | 7/0.025 | 2.0 | 932 | 5,630 | 2.0 | 1.0 | 350×5.0 |
| 2 | 7/0.025 | 2.0 | 905 | 5,500 | 2.4 | 1.2 | 450×1.5 |
| 3 | 7/0.025 | 2.0 | 910 | 5,600 | 2.2 | 1.3 | 500×0.4 |
| 4 | 7/0.023 | 2.0 | 942 | 6,680 | 2.4 | 1.2 | 350×5.0 |
| 5 | 7/0.023 | 2.0 | 910 | 6,500 | 2.5 | 1.1 | 450×1.5 |
| 6 | 7/0.023 | 2.0 | 910 | 6,620 | 2.3 | 1.3 | 500×0.4 |
| 7 | 7/0.020 | 2.0 | 955 | 8,850 | 2.2 | 1.0 | 350×5.0 |
| 8 | 7/0.020 | 2.0 | 920 | 8,700 | 2.4 | 0.5 | 450×1.5 |
| 9 | 7/0.020 | 2.0 | 915 | 8,800 | 2.3 | 0.8 | 500×0.4 |
| 10 | 7/0.018 | 2.0 | 943 | 11,000 | 2.3 | 1.2 | 350×5.0 |
| 11 | 7/0.018 | 2.0 | 915 | 10,900 | 2.5 | 1.0 | 450×1.5 |
| 12 | 7/0.018 | 2.0 | 920 | 10,950 | 2.4 | 1.0 | 500×0.4 |
| 13 | 7/0.016 | 2.0 | 945 | 14,080 | 2.3 | 1.2 | 350×5.0 |
| 14 | 7/0.016 | 2.0 | 925 | 14,000 | 2.2 | 1.3 | 450×1.5 |
| 15 | 7/0.016 | 2.0 | 930 | 14,000 | 2.3 | 1.2 | 500×0.4 |
| 16 | 7/0.013 | 2.0 | 954 | 20,550 | 2.2 | 1.3 | 350×5.0 |
| 17 | 7/0.013 | 2.0 | 940 | 20,500 | 2.0 | 1.2 | 450×1.5 |
| 18 | 7/0.013 | 2.0 | 945 | 20,500 | 2.4 | 1.0 | 500×0.4 |
| 19 | 7/0.010 | 2.0 | 955 | 37,100 | 2.2 | 1.3 | 350×5.0 |
| 20 | 7/0.010 | 2.0 | 950 | 37,000 | 2.0 | 1.4 | 450×1.5 |
| 21 | 7/0.010 | 2.0 | 945 | 37,080 | 2.3 | 1.2 | 500×0.4 |
Comparative example 1
The making of Cu-Ag alloy wire.
Made superfine copper alloy wire according to silver concentration or heat-treat condition that prescribed limit of the present invention is outer.Other condition is identical with embodiment 1.The results are shown in table 3.
(052) table 3
| NO. | Line footpath (mm) | Ag concentration (weight %) | Tensile strength (MPa) | Conductance (%IACS) | Elongation (%) | Thermal endurance (%) | Heat treatment (℃ * second) |
| 1 | 0.023 | 2.0 | 1025 | 83.5 | 1.0 | 5.0 | Do not have |
| 2 | 0.023 | 0.5 | 750 | 90.5 | 1.5 | 3.5 | 450×1.5 |
| 3 | 0.023 | 3.5 | 1100 | 82.0 | 1.5 | 1.5 | 450×1.5 |
| 4 | 0.023 | 2.0 | 1090 | 82.4 | 1.5 | 3.0 | 250×5.0 |
| 5 | 0.023 | 2.0 | 700 | 88.4 | 4.0 | 1.5 | 600×0.2 |
| 6 | 0.023 | 2.0 | 980 | 84.0 | 1.0 | 4.5 | 450×0.1 |
| 7 | 0.023 | 2.0 | 800 | 88.8 | 3.5 | 1.2 | 450×6.0 |
(054) table 4
| NO. | Bar number/line footpath (bar/mm) | Ag concentration (weight %) | Tensile strength (MPa) | Resistance (Ω/km) | Elongation (%) | Thermal endurance (%) | Heat treatment (℃ * second) |
| 1 | 7/0.023 | 2.0 | 1020 | 6,800 | 1.1 | 5.5 | Do not have |
| 2 | 7/0.023 | 0.5 | 760 | 6,300 | 2.5 | 4.5 | 450×1.5 |
| 3 | 7/0.023 | 3.5 | 1150 | 7,100 | 1.7 | 2.5 | 450×1.5 |
| 4 | 7/0.023 | 2.0 | 1050 | 7,050 | 1.6 | 3.5 | 250×5.0 |
| 5 | 7/0.023 | 2.0 | 720 | 6,400 | 4.5 | 2.5 | 600×0.2 |
| 6 | 7/0.023 | 2.0 | 985 | 6,800 | 1.5 | 4.8 | 450×0.1 |
| 7 | 7/0.023 | 2.0 | 810 | 6,400 | 4.0 | 1.5 | 450×6.0 |
Comparative example 2
The making of Cu-Ag alloy twisted wire.
Made superfine copper alloy twisted wire according to silver concentration or heat-treat condition that prescribed limit of the present invention is outer.Other condition is identical with embodiment 2.The results are shown in table 4.
Original example 1
Made the Cu-Sn alloy wire.
The tin that has added 0.3 weight % in oxygen-free copper after the heat fused, uses the graphite casting die continuous casting to make the line base of Φ 8.0mm in the black-fead crucible in being fixed in vacuum tank., through wire drawing processing, intermediate annealing, hot candied processing, silver-plated operation, subsequently carry out Wire Drawing up to line footpath 0.023mm, made superfine copper alloy wire and carried out evaluation similarly to Example 1 thereafter.And then re-using this material is that heat-treat condition is made superfine copper alloy wire according to of the present invention creating conditions, and has carried out same evaluation.The results are shown in table 5.
Table 5
| NO | Line footpath mm | Sn concentration (weight %) | Tensile strength (MPa) | Conductance (%IACS) | Elongation (%) | Thermal endurance (%) | Heat treatment (℃ * second) |
| 1 | 0.023 | 0.3 | 800 | 78.0 | 1.0 | 18.0 | Do not have |
| 2 | 0.023 | 0.3 | 700 | 82.0 | 1.0 | 4.0 | 450×1.5 |
Original example 2
The making of Cu-Sn alloy twisted wire.
The tin that has added 0.3 weight % in oxygen-free copper after the heat fused, uses the graphite casting die continuous casting to make the line base of Φ 8.0mm in the black-fead crucible in being fixed in vacuum tank., through wire drawing processing, intermediate annealing, hot candied processing, silver-plated operation, subsequently carry out backguy processing up to line footpath 0.023mm, made superfine copper alloy wire thereafter.With 7 polar curve copper alloy wire stranded make superfine copper alloy twisted wire, and carried out similarly to Example 2 evaluation thereafter.And then re-using this material is that heat-treat condition is made superfine copper alloy twisted wire according to of the present invention creating conditions, and has carried out same evaluation.The results are shown in table 6.
Table 6
| NO | Bar number/line footpath (bar/mm) | Sn concentration (weight %) | Tensile strength (MPa) | Resistance (Ω/km) | Elongation (%) | Thermal endurance (%) | Heat treatment (℃ * second) |
| 1 | 7/0.023 | 0.3 | 780 | 7500 | 1.1 | 17.5 | Do not have |
| 2 | 7/0.023 | 0.3 | 710 | 7100 | 2.5 | 4.5 | 450×1.5 |
Evaluation to above result is as follows:
As shown in table 1, the superfine copper alloy wire of embodiment 1 has all in various sizes that tensile strength is more than the 850MPa, conductance is the high strength of 85%IACS, high conductive characteristic, relatively has obvious superiority with the characteristic of the original example 1 shown in the table 5.Show in addition,, reduce greatly, be difficult to reach the characteristic of taking into account this two aspect simultaneously though its conductance improves its tensile strength even original Cu-Sn alloy wire has been carried out heat treatment similarly to Example 1 (NO.2 of table 5).
As shown in table 2, the superfine copper alloy twisted wire of embodiment 2, with the characteristic of the original example 2 shown in the table 6 relatively because its tensile strength height and resistance is low, thereby be most appropriate to as the coaxial cable that turns to purpose with thin footpath.In addition, can know that even existing C u-Sn alloy twisted wire is carried out similarly to Example 2 processing (NO.2 of table 6), tensile strength reduces significantly though its resistance diminishes, and is difficult to reach the characteristic of taking into account two aspects.
In addition, the thermal endurance of the twisted wire of embodiment 2, its intensity decrease rate is about 1.0%, and is highly stable to heat; By comparison, the thermal endurance of the twisted wire of original example 2 (NO.1 of table 6) is 17.5%, and its intensity significantly reduces.Have, even carried out heat treatment similarly to Example 2 (NO.2 of table 6), intensity decrease rate is also greatly to 4.5% again.In order to estimate these stable on heating difference, the superfine copper alloy twisted wire of use embodiment 2 (NO.5 of table 2) and original example 2 (NO.1 of table 6,2) has carried out the squeeze test of insulator.Its result, the superfine copper alloy twisted wire of embodiment 2 (NO.5 of table 2) can successfully push, and broken string appears in the superfine copper alloy twisted wire of original example 2 (NO.1 of table 6,2) in extrusion process.Therefore, the superfine copper alloy twisted wire of embodiment 2 is with respect to the superfine copper alloy twisted wire of original example 2, and the superiority aspect thermal endurance is obvious.
Table 3 is evaluation results of the superfine copper alloy wire made according to the extraneous condition of the present invention regulation.NO.1 though its tensile strength high conductance is low, and represents that stable on heating intensity decrease rate is also greatly to 5% owing to do not heat-treat.The interpolation concentration of NO.2 and 3 silver is outside scope, and intensity is low if silver concentration is crossed low then conductance height, if silver concentration too high then intensity height and conductance is low.Though the heat treatment time of NO.4 and 5 is within scope, because heat treatment temperature is outside scope, thereby, be difficult to take into account intensity and conductance.Though the heat treatment temperature of NO.6 and 7 within condition and range, because of heat treatment time outside scope, thereby, be difficult to take into account the performance of intensity and conductance two aspects equally.
Table 4 is evaluation results of the superfine copper alloy twisted wire made according to the extraneous condition of the present invention regulation.NO.1 though its tensile strength height resistance is also high, and represents that stable on heating intensity decrease rate is also greatly to 5.5% owing to do not heat-treat.The interpolation concentration of NO.2 and 3 silver is outside scope, and is low and intensity is also low if silver concentration is crossed low then resistance, if silver concentration too high then intensity height and resistance is also high.Though the heat treatment time of NO.4 and 5 is within scope, because heat treatment temperature is outside scope, thereby, be difficult to take into account intensity and conductance.Though the heat treatment temperature of NO.6 and 7 within condition and range, because of heat treatment time outside scope, thereby, be difficult to take into account the performance of intensity and conductance two aspects equally.
Below, other execution mode is described.As the interpolation element of copper alloy of the present invention, can also add total metering beyond the desilver is one or both metals of selecting from magnesium (Mg), indium (In) of 0.02-0.10 weight %.Increase and add element,, can expect further to improve intensity though want corresponding increase cost.
The 3rd, superfine insulated wire is described.
Fig. 5 represents the sectional drawing of the superfine insulated wire of present embodiment.
This superfine insulated wire 10 is by the stranded copper alloy twisted wire that forms 3 of 7 superfine copper alloy wires 1 is formed inner conductors, coats solid insulator 5a in the periphery of this inner conductor again and forms.
The manufacture method of superfine insulated wire of the present invention is, the silver that adds 1-3 weight % in fine copper generates copper alloy, carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm, form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded, by after carrying out the 0.2-5 heat treatment of second under 300-500 ℃ the temperature, coating thickness in the periphery of above-mentioned copper alloy twisted wire again is that solid insulator below the 0.07mm forms.
Superfine copper alloy wire uses the superfine copper alloy wire of described superfine copper alloy wire of this embodiment first or band coating.Superfine copper alloy twisted wire 3 uses the described superfine copper alloy twisted wire of this embodiment second portion.
In addition, this superfine copper alloy twisted wire 3 has carried out heat treatment, and the resistance reduced rate after the heat treatment is more than 6%, and the tensile strength reduced rate after the above-mentioned heat treatment is in 20%.If the resistance reduced rate after the heat treatment is less than 6%, and the tensile strength reduced rate after the above-mentioned heat treatment surpasses 20%, then in the solder operation of extruding manufacturing operation or end portion, be easy to generate broken string, be difficult to realize having simultaneously high-strength characteristic and low resistance characteristic (high conductivity) both.
Have, the line of the resistance of this Albatra metal-twisted wire 3 and superfine copper alloy wire 1 directly has following relation again.
(1) when 0.025mm was following, resistance was 7200 Ω/below the km greater than 0.021mm the line of superfine copper alloy wire 1 footpath.
(2) when 0.022mm was following, resistance was 9500 Ω/below the km greater than 0.018mm the line of superfine copper alloy wire 1 footpath.
(3) when 0.020mm was following, resistance was 12200 Ω/below the km greater than 0.016mm the line of superfine copper alloy wire 1 footpath.
(4) when 0.018mm was following, resistance was 14700 Ω/below the km greater than 0.014mm the line of superfine copper alloy wire 1 footpath.
(5) when 0.017mm was following, resistance was 16500 Ω/below the km greater than 0.013mm the line of superfine copper alloy wire 1 footpath.
(6) when 0.015mm was following, resistance was 22500 Ω/below the km greater than 0.011mm the line of superfine copper alloy wire 1 footpath.
(7) when 0.012mm was following, resistance was 38000 Ω/below the km greater than 0.010mm the line of superfine copper alloy wire 1 footpath.
It is in order really to accomplish to guarantee simultaneously thin footpathization and electrical characteristic by the AWG standard that the resistance of the superfine copper alloy wire of every kind of size has been carried out limiting.
Being formed with thickness in the periphery of superfine copper alloy twisted wire 3 is solid insulator 5a below the 0.07mm.It is because by the standard of 43AWG-50AWG coaxial cable, make electrostatic capacitance more than 100pF/m that thickness is decided to be below the 0.07mm.
As solid insulator 5a, for example can use the resin that is 2.1, selects the material of fusing point about 300 ℃ from the full root skin of tetrafluoroethene propyl vinyl ether (パ-Off ロ ロ プ ロ PVC Le PVC ニ Le エ-テ Le) copolymer (PFA), tetrafluoroethene hexafluoropropylene copolymer dielectric constants such as (FEP).
The 4th, coaxial cable is described.
Fig. 6 is the sectional drawing of the coaxial cable 20A of expression present embodiment.
This coaxial cable 20A is wound into the length direction of many strip conductors line 13 along superfine insulated wire 10 helical form and forms external conductor 15 in the periphery of superfine insulated wire 10 shown in Figure 5, and externally the surface of conductor 15 coats protective layer 17 and forms again.
The manufacture method of coaxial cable 20A is; the silver that adds 1-3 weight % in fine copper generates copper alloy; carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm; form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded; by after carrying out the 0.2-5 heat treatment of second under 300-500 ℃ the temperature; coating thickness in the periphery of above-mentioned copper alloy twisted wire again is that solid insulator below the 0.07mm becomes superfine insulated wire; again in the periphery of above-mentioned superfine insulated wire; length direction along above-mentioned superfine insulated wire after having formed external conductor, coats many strip conductors coil of wire coiled protective layer in the said external surface of conductors again and forms.
Conductor lines 13 such as many (for example 30-60) plating Sn copper cash, Sn-plated copper alloy line, silver-coated copper wire, silver-plated copper alloy wire are formed external conductor 15 (helical shield) by both determining deviation horizontal wraparound curls.
Protective layer 17 can coat tetrafluoroethene full root skin propyl ethylene ether copolymer (PFA), tetrafluoroethene hexafluoropropylene copolymer (FEP), ethylene tetrafluoroethylene copolymer (ETFE) etc. by extruding and be provided with.
The electrostatic capacitance of above-mentioned coaxial cable 20A, attenuation, bend right and left 90 the degree life-spans and the line of superfine copper alloy wire 1 directly have following relation.
1. in the line of superfine copper alloy wire 1 footpath greater than 0.021mm when 0.025mm is following, its electrostatic capacitance is 100-130pF/m, attenuation is 0.6-1.0dB/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 20000 times under the condition of radius of curvature R=2mm, load=50g.
2. in the line of superfine copper alloy wire 1 footpath greater than 0.018mm when 0.022mm is following, its electrostatic capacitance is 100-130pF/m, attenuation is 0.8-1.2dB/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 20000 times under the condition of radius of curvature R=2mm, load=50g.
3. in the line of superfine copper alloy wire 1 footpath greater than 0.016mm when 0.020mm is following, its electrostatic capacitance is 100-130pF/m, attenuation is 1.0-1.5dB/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 20000 times under the condition of radius of curvature R=2mm, load=50g.
4. in the line of superfine copper alloy wire 1 footpath greater than 0.014mm when 0.018mm is following, its electrostatic capacitance is 100-130pF/m, attenuation is 1.1-1.6dB/m (frequency is 1 0MHz), and the life-span of 90 degree that bend right and left is being more than 30000 times under the condition of radius of curvature R=2mm, load=50g.
5. in the line of superfine copper alloy wire 1 footpath greater than 0.013mm when 0.017mm is following, its electrostatic capacitance is 100-130pF/m, attenuation is 1.3-1.8dB/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 30000 times under the condition of radius of curvature R=2mm, load=20g.
6. in the line of superfine copper alloy wire 1 footpath greater than 0.011mm when 0.015mm is following, its electrostatic capacitance is 100-130pF/m, attenuation is 1.7-2.4dB/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 30000 times under the condition of radius of curvature R=2mm, load=20g.
7. in the line of superfine copper alloy wire 1 footpath greater than 0.010mm when 0.012mm is following, its electrostatic capacitance is 100-130pF/m, attenuation is 2.5-3.8dB/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 10000 times under the condition of radius of curvature R=2mm, load=20g.
Having carried out limiting for the life-spans of electrostatic capacitance, the attenuation of the superfine copper alloy wire of every kind of size, 90 degree that bend right and left is in order really to accomplish to guarantee simultaneously thin footpathization and electrical characteristic and mechanical property by the AWG standard.
Fig. 7 is the sectional drawing of the another kind of coaxial cable 20B of expression present embodiment.
This coaxial cable 20B is the periphery coating cellular insulation body 5b at the copper alloy twisted wire (inner conductor) 3 that 7 superfine copper alloys 1 are twisted into; the periphery of the epidermal area 11 that forms in its outside again; the length direction of many strip conductors line 13 along copper alloy twisted wire (inner conductor) 3 is wound into helical form and becomes external conductor 15, coat protective layer 17 on the surface of this external conductor 15 again and form.
The manufacture method of coaxial cable 20B is; the silver that adds 1-3 weight % in fine copper generates copper alloy; carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm; form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded; by after carrying out the 0.2-5 heat treatment of second under 300-500 ℃ the temperature; again in the periphery of above-mentioned copper alloy twisted wire after to coat thickness be cellular insulation body below the 0.28mm; form epidermal area; again in the periphery of this epidermal area; length direction along above-mentioned copper alloy twisted wire after forming external conductor, coats many strip conductors coil of wire coiled protective layer in the said external surface of conductors again and forms.
Employed superfine copper alloy wire 1 of the coaxial cable 20B of present embodiment or plating superfine copper alloy wire 2 be because of identical with above-mentioned coaxial cable 20A, thereby omit its detailed description.
The inner conductor of the employed inner conductor of coaxial cable 20B of present embodiment and the employed superfine insulated wire of above-mentioned coaxial cable 20A is superfine copper alloy twisted wire 3, and except that its resistance and superfine copper alloy wire 1 have the following relation, all the other are also identical.
1. when 0.025mm was following, resistance was below the 7500/km greater than 0.021mm the line of superfine copper alloy wire 1 footpath.
2. when 0.022mm was following, resistance was 10000 Ω/below the km greater than 0.018mm the line of superfine copper alloy wire 1 footpath.
3. when 0.020mm was following, resistance was 13000 Ω/below the km greater than 0.016mm the line of superfine copper alloy wire 1 footpath.
4. when 0.018mm was following, resistance was 15500 Ω/below the km greater than 0.014mm the line of superfine copper alloy wire 1 footpath.
5. when 0.017mm was following, resistance was 17000 Ω/below the km greater than 0.013mm the line of superfine copper alloy wire 1 footpath.
6. when 0.015mm was following, resistance was 23500 Ω/below the km greater than 0.011mm the line of superfine copper alloy wire 1 footpath.
7. when 0.012mm was following, resistance was 40000 Ω/below the km greater than 0.010mm the line of superfine copper alloy wire 1 footpath.
As cellular insulation body 5b, for example can use extruding foam tetrafluoroethene full root skin propyl ethylene ether copolymer (PFA).Form the cellular insulation body 5b of the following thickness of 0.28mm in the periphery of superfine copper alloy twisted wire 3.Why being decided to be the following thickness of 0.28mm, is for the coaxial cable standard according to 43AWG-50AWG, and electrostatic capacitance is reached more than the 30pF/m.
As epidermal area 11, can coat tetrafluoroethene full root skin propyl ethylene ether copolymer (PFA), tetrafluoroethene hexafluoropropylene copolymer (FEP), ethylene tetrafluoroethylene copolymer (ETFE) by coiling PET band or extruding and be provided with.
Conductor lines 13 such as many (for example 30-60) plating Sn copper cash, Sn-plated copper alloy line, silver-coated copper wire, silver-plated copper alloy wire are formed external conductor 15 (helical shield) by both determining deviation horizontal wraparound curls.
Protective layer 17 can coat tetrafluoroethene full root skin propyl ethylene ether copolymer (PFA), tetrafluoroethene hexafluoropropylene copolymer (FEP), ethylene tetrafluoroethylene copolymer (ETFE) by coiling PET band or extruding and be provided with.
The electrostatic capacitance of coaxial cable 20B in the line of superfine copper alloy wire 1 footpath for greater than 0.021mm when 0.025mm is following, greater than 0.018mm when 0.022mm is following, greater than 0.016mm when 0.020mm is following, greater than 0.014mm when 0.018mm is following, greater than 0.013mm when 0.017mm is following, greater than 0.011mm when 0.015mm is following, greater than 0.010mm when 0.012mm is following all at 30-80pF/m, its capacitance is very low.
Below, enumerate the specific embodiment of making coaxial cable 20A and 20B.
Embodiment 3
The manufacturing of the coaxial cable of 43AWG.
The silver that adds 2.0 weight % in oxygen-free copper after the heat fused, uses the graphite casting die continuous casting to make the line base of Φ 8mm in the graphite crucible in being fixed in vacuum tank., through wire drawing processing, intermediate annealing, hot candied processing, and final wire rod plated Ag make its thickness of coating reach 1 μ m, carry out wire drawing processing again and reach line and directly obtain superfine copper alloy wire for 0.023mm thereafter.Prepare the copper alloy wire (Cu-2%Ag) of the plating Ag of 7 this 0023mm, with the spacing of 1.1mm it is carried out strandedly, be made into the twisted wire that its external diameter is 0.069mm.Then, resulting twisted wire is carried out 5 kinds mobile heat treatment in being heated to 350 ℃ heat-treatment furnace, obtain superfine copper alloy twisted wire.
This superfine copper alloy twisted wire is measured conductance after tensile strength before and after the heat treatment and resistance, the heat treatment, calculated tensile strength and changes in resistance rate.And rate of change calculates with the formula of [heat before (value after the value-heat treatment before the heat treatment)/heat treatment] * 100%.It the results are shown in table 7.
And then pushing the PFA resin that coats 0.053mm thickness and formed external diameter in the periphery of this twisted wire is the solid interior insulator of 0.175mm.Be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.025mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this internal insulator again; coat the protective layer that constitutes by the PFA resin that thickness is 0.03mm in the periphery of this external conductor again, thereby obtain the coaxial cable 20A that external diameter is 0.285mm.
Perhaps, coating thickness in the extruding of the periphery of this twisted wire is that to have formed external diameter be the internal insulator with bubble of 0.210mm for the foam PFA resin of 0.07mm.Form the thick epidermal area that constitutes by the PET band of 0.01mm in the periphery of this internal insulator again; be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.025mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this epidermal area again; forming by thickness in the periphery of this external conductor again is the protective layer that the PET band of 0.015mm constitutes, thereby obtains the coaxial cable 20B that external diameter is 0.310mm.
Embodiment 4
The making of the coaxial cable of 43AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of embodiment 1.
Embodiment 5
The making of the coaxial cable of 43AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of embodiment 1.
Embodiment 6
The making of the coaxial cable of 44AWG.
The silver that adds 2.0 weight % in oxygen-free copper after the heat fused, uses the graphite casting die continuous casting to make the line base of Φ 8mm in the graphite crucible in being fixed in vacuum tank., through wire drawing processing, intermediate annealing, hot candied processing, and final wire rod plated Ag make its thickness of coating reach 0.9 μ m, carry out wire drawing processing again and reach line and directly obtain superfine copper alloy wire for 0.020mm thereafter.Prepare the copper alloy wire (Cu-2%Ag) of the plating Ag of 7 this 0020mm, with the spacing of 1.0mm it is carried out strandedly, be made into the twisted wire that its external diameter is 0.06mm.Then, resulting twisted wire is carried out 5 kinds mobile heat treatment in being heated to 350 ℃ heat-treatment furnace, obtain superfine copper alloy twisted wire.
To this superfine copper alloy twisted wire, similarly to Example 3, measured the conductance after tensile strength before and after the heat treatment and resistance, the heat treatment, calculated tensile strength and changes in resistance rate.And rate of change calculates with the formula of [heat before (value after the value-heat treatment before the heat treatment)/heat treatment] * 100%.It the results are shown in table 7.
And then pushing the PFA resin that coats 0.048mm thickness and formed external diameter in the periphery of this twisted wire is the solid interior insulator of 0.156mm.Be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.020mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this internal insulator again; coat the protective layer that constitutes by the PFA resin that thickness is 0.03mm in the periphery of this external conductor again, thereby obtain the coaxial cable 20A that external diameter is 0.256mm.
Perhaps, pushing the foam PFA village's fat that coats 0.06mm thickness and formed external diameter in the periphery of this twisted wire is the internal insulator with bubble of 0.180mm.Form the thick epidermal area that constitutes by the PET band of 0.01mm in the periphery of this internal insulator again; be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.025mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this epidermal area again; forming by thickness in the periphery of this external conductor again is the protective layer that the PET band of 0.015mm constitutes, thereby obtains the coaxial cable 20B that external diameter is 0.280mm.
Embodiment 7
The making of the coaxial cable of 44AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of embodiment 6.
Embodiment 8
The making of the coaxial cable of 44AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of embodiment 6.
Embodiment 9
The making of the coaxial cable of 45AWG.
The silver that adds 2.0 weight % in oxygen-free copper after the heat fused, uses the graphite casting die continuous casting to make the line base of Φ 8mm in the graphite crucible in being fixed in vacuum tank., through wire drawing processing, intermediate annealing, hot candied processing, and final wire rod plated Ag make its thickness of coating reach 0.8 μ m, carry out wire drawing processing again and reach line and directly obtain superfine copper alloy wire for 0.018mm thereafter.Prepare the copper alloy wire (Cu-2%Ag) of the plating Ag of 7 this 0018mm, with the spacing of 0.8mm it is carried out strandedly, be made into the twisted wire that its external diameter is 0.054mm.Then, resulting twisted wire is carried out 5 kinds mobile heat treatment in being heated to 350 ℃ heat-treatment furnace, obtain superfine copper alloy twisted wire.
To this superfine copper alloy twisted wire, similarly to Example 3, measured the conductance after tensile strength before and after the heat treatment and resistance, the heat treatment, calculated tensile strength and changes in resistance rate.And rate of change calculates with the formula of [heat before (value after the value-heat treatment before the heat treatment)/heat treatment] * 100%.It the results are shown in table 7.
And then pushing the PFA resin that coats 0.038mm thickness and formed external diameter in the periphery of this twisted wire is the solid interior insulator of 0.130mm.Be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.020mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this internal insulator again; coat the protective layer that constitutes by the PFA resin that thickness is 0.025mm in the periphery of this external conductor again, thereby obtain the coaxial cable 20A that external diameter is 0.22mm.
Perhaps, pushing the foam PFA village's fat that coats 0.05mm thickness and formed external diameter in the periphery of this twisted wire is the internal insulator with bubble of 0.154mm.Form the thick epidermal area that constitutes by the PET band of 0.01mm in the periphery of this internal insulator again; be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.020mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this epidermal area again; forming by thickness in the periphery of this external conductor again is the protective layer that the PET band of 0.015mm constitutes, thereby obtains the coaxial cable 20B that external diameter is 0.244mm.
The making of the coaxial cable of 45AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of embodiment 9.
Embodiment 11
The making of the coaxial cable of 45AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of embodiment 9.
Embodiment 12
The making of the coaxial cable of 46AWG.
The silver that adds 2.0 weight % in oxygen-free copper after the heat fused, uses the graphite casting die continuous casting to make the line base of Φ 8mm in the graphite crucible in being fixed in vacuum tank., through wire drawing processing, intermediate annealing, hot candied processing, and final wire rod plated Ag make its thickness of coating reach 0.7 μ m, carry out wire drawing processing again and reach line and directly obtain superfine copper alloy wire for 0.016mm thereafter.Prepare the copper alloy wire (Cu-2%Ag) of the plating Ag of 7 this 0016mm, with the spacing of 0.8mm it is carried out strandedly, be made into the twisted wire that its external diameter is 0.048mm.Then, resulting twisted wire is carried out 5 kinds mobile heat treatment in being heated to 350 ℃ heat-treatment furnace, obtain superfine copper alloy twisted wire.
To this superfine copper alloy twisted wire, similarly to Example 3, measured the conductance after tensile strength before and after the heat treatment and resistance, the heat treatment, calculated tensile strength and changes in resistance rate.And rate of change calculates with the formula of [heat before (value after the value-heat treatment before the heat treatment)/heat treatment] * 100%.It the results are shown in table 7.
And then pushing the PFA resin that coats 0.033mm thickness and formed external diameter in the periphery of this twisted wire is the solid interior insulator of 0.114mm.Be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.020mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this internal insulator again; coat the protective layer that constitutes by the PFA resin that thickness is 0.025mm in the periphery of this external conductor again, thereby obtain the coaxial cable 20A that external diameter is 0.204mm.
Perhaps, pushing the foam PFA village's fat that coats 0.04mm thickness and formed external diameter in the periphery of this twisted wire is the internal insulator with bubble of 0.128mm.Form the thick epidermal area that constitutes by the PET band of 0.01mm in the periphery of this internal insulator again; be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.020mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this epidermal area again; forming by thickness in the periphery of this external conductor again is the protective layer that the PET band of 0.015mm constitutes, thereby obtains the coaxial cable 20B that external diameter is 0.218mm.
Embodiment 13
The making of the coaxial cable of 46AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of embodiment 12.
Embodiment 14
The making of the coaxial cable of 46AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of embodiment 12.
Embodiment 15
The making of the coaxial cable of 47AWG.
The silver that adds 2.0 weight % in oxygen-free copper after the heat fused, uses the graphite casting die continuous casting to make the line base of Φ 8mm in the graphite crucible in being fixed in vacuum tank., through wire drawing processing, intermediate annealing, hot candied processing, and final wire rod plated Ag make its thickness of coating reach 0.6 μ m, carry out wire drawing processing again and reach line and directly obtain superfine copper alloy wire for 0.015mm thereafter.Prepare the copper alloy wire (Cu-2%Ag) of the plating Ag of 7 this 0015mm, with the spacing of 0.8mm it is carried out strandedly, be made into the twisted wire that its external diameter is 0.045mm.Then, resulting twisted wire is carried out 5 kinds mobile heat treatment in being heated to 350 ℃ heat-treatment furnace, obtain superfine copper alloy twisted wire.
To this superfine copper alloy twisted wire, similarly to Example 3, measured the conductance after tensile strength before and after the heat treatment and resistance, the heat treatment, calculated tensile strength and changes in resistance rate.And rate of change calculates with the formula of [heat before (value after the value-heat treatment before the heat treatment)/heat treatment] * 100%.It the results are shown in table 7.
And then pushing the PFA resin that coats 0.030mm thickness and formed external diameter in the periphery of this twisted wire is the solid interior insulator of 0.105mm.Be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.020mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this internal insulator again; coat the protective layer that constitutes by the PFA resin that thickness is 0.020mm in the periphery of this external conductor again, thereby obtain the coaxial cable 20A that external diameter is 0.185mm.
Perhaps, pushing the foam PFA village's fat that coats 0.035mm thickness and formed external diameter in the periphery of this twisted wire is the internal insulator with bubble of 0.115mm.Form the thick epidermal area that constitutes by the PET band of 0.01mm in the periphery of this internal insulator again; be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.020mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this epidermal area again; forming by thickness in the periphery of this external conductor again is the protective layer that the PET band of 0.015mm constitutes, thereby obtains the coaxial cable 20B that external diameter is 0.205mm.
Embodiment 16
The making of the coaxial cable of 47AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of embodiment 15.
Embodiment 17
The making of the coaxial cable of 47AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of embodiment 15.
Embodiment 18
The making of the coaxial cable of 48AWG.
The silver that adds 2.0 weight % in oxygen-free copper after the heat fused, uses the graphite casting die continuous casting to make the line base of Φ 8mm in the graphite crucible in being fixed in vacuum tank., through wire drawing processing, intermediate annealing, hot candied processing, and final wire rod plated Ag make its thickness of coating reach 0.5 μ m, carry out wire drawing processing again and reach line and directly obtain superfine copper alloy wire for 0.013mm thereafter.Prepare the copper alloy wire (Cu-2%Ag) of the plating Ag of 7 this 0013mm, with the spacing of 0.7mm it is carried out strandedly, be made into the twisted wire that its external diameter is 0.039mm.Then, resulting twisted wire is carried out 5 kinds mobile heat treatment in being heated to 350 ℃ heat-treatment furnace, obtain superfine copper alloy twisted wire.
To this superfine copper alloy twisted wire, similarly to Example 3, measured the conductance after tensile strength before and after the heat treatment and resistance, the heat treatment, calculated tensile strength and changes in resistance rate.And rate of change calculates with the formula of [heat before (value after the value-heat treatment before the heat treatment)/heat treatment] * 100%.It the results are shown in table 7.
And then pushing the PFA resin that coats 0.030mm thickness and formed external diameter in the periphery of this twisted wire is the solid interior insulator of 0.105mm.Be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.020mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this internal insulator again; coat the protective layer that constitutes by the PFA resin that thickness is 0.020mm in the periphery of this external conductor again, thereby obtain the coaxial cable 20A that external diameter is 0.185mm.
Perhaps, pushing the foam PFA village's fat that coats 0.03mm thickness and formed external diameter in the periphery of this twisted wire is the internal insulator with bubble of 0.099mm.Form the thick epidermal area that constitutes by the PET band of 0.01mm in the periphery of this internal insulator again; be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.016mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this epidermal area again; forming by thickness in the periphery of this external conductor again is the protective layer that the PET band of 0.015mm constitutes, thereby obtains the coaxial cable 20B that external diameter is 0.181mm.
Embodiment 19
The making of the coaxial cable of 48AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of embodiment 18.
The making of the coaxial cable of 48AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of embodiment 18.
Embodiment 21
The making of the coaxial cable of 50AWG.
The silver that adds 2.0 weight % in oxygen-free copper after the heat fused, uses the graphite casting die continuous casting to make the line base of Φ 8mm in the graphite crucible in being fixed in vacuum tank., through wire drawing processing, intermediate annealing, hot candied processing, and final wire rod plated Ag make its thickness of coating reach 0.4 μ m, carry out wire drawing processing again and reach line and directly obtain superfine copper alloy wire for 0.010mm thereafter.Prepare the copper alloy wire (Cu-2%Ag) of the plating Ag of 7 this 0010mm, with the spacing of 0.5mm it is carried out strandedly, be made into the twisted wire that its external diameter is 0.030mm.Then, resulting twisted wire is carried out 5 kinds mobile heat treatment in being heated to 350 ℃ heat-treatment furnace, obtain superfine copper alloy twisted wire.
To this superfine copper alloy twisted wire, similarly to Example 3, measured the conductance after tensile strength before and after the heat treatment and resistance, the heat treatment, calculated tensile strength and changes in resistance rate.And rate of change calculates with the formula of [heat before (value after the value-heat treatment before the heat treatment)/heat treatment] * 100%.It the results are shown in table 7.
And then pushing the PFA resin that coats 0.020mm thickness and formed external diameter in the periphery of this twisted wire is the solid interior insulator of 0.07mm.Be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.013mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this internal insulator again; coat the protective layer that constitutes by the PFA resin that thickness is 0.015mm in the periphery of this external conductor again, thereby obtain the coaxial cable 20A that external diameter is 0.126mm.
Perhaps, pushing the foam PFA village's fat that coats 0.025mm thickness and formed external diameter in the periphery of this twisted wire is the internal insulator with bubble of 0.08mm.Form the thick epidermal area that constitutes by the PET band of 0.01mm in the periphery of this internal insulator again; be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.016mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this epidermal area again; forming by thickness in the periphery of this external conductor again is the protective layer that the PET band of 0.015mm constitutes, thereby obtains the coaxial cable 20B that external diameter is 0.162mm.
Embodiment 22
The making of the coaxial cable of 50AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of embodiment 21.
Embodiment 23
The making of the coaxial cable of 50AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of embodiment 21.
Comparative example 3
The making of the coaxial cable of 43AWG.
Except not heat-treating this point, carry out the processing identical with the manufacture method of embodiment 3.
Comparative example 4
The making of the coaxial cable of 43AWG.
Except the interpolation concentration of silver is this point of 0.5 weight %, carry out the processing identical with the manufacture method of embodiment 4.
Comparative example 5
The making of the coaxial cable of 43AWG.
Except the interpolation concentration of silver is this point of 3.5 weight %, carry out the processing identical with the manufacture method of embodiment 4.
Comparative example 6
The making of the coaxial cable of 43AWG.
Except 250 ℃ carry out 5.0 seconds heat treatment this point, carry out the processing identical with the manufacture method of embodiment 3.
Comparative example 7
The making of the coaxial cable of 43AWG.
Except 600 ℃ carry out 0.2 second heat treatment this point, carry out the processing identical with the manufacture method of embodiment 3.
Comparative example 8
The making of the coaxial cable of 43AWG.
Except 450 ℃ carry out 0.1 second heat treatment this point, carry out the processing identical with the manufacture method of embodiment 3.
Comparative example 9
The making of the coaxial cable of 43AWG.
Except 450 ℃ carry out 6.0 seconds heat treatment this point, carry out the processing identical with the manufacture method of embodiment 3.
Original example 3
The making of the coaxial cable of 43AWG.
Except replacing with the Sn of 0.3 weight % and do not heat-treat this point from Ag, carry out the processing identical with the manufacture method of embodiment 3 with adding metal.
Original example 4
The making of the coaxial cable of 43AWG.
Except with adding metal from Ag replaces with this point of Sn of 0.3 weight %, carry out the processing identical with the manufacture method of embodiment 3.
Original example 5
The making of the coaxial cable of 43AWG.
Except with adding metal from Ag replaces with this point of Sn of 0.3 weight %, carry out the processing identical with the manufacture method of embodiment 4.
Original example 6
The making of the coaxial cable of 43AWG.
Except with adding metal from Ag replaces with this point of Sn of 0.3 weight %, carry out the processing identical with the manufacture method of embodiment 5.
Comparative example 10
The making of the coaxial cable of 42AWG.
In oxygen-free copper, add the Sn of 0.19 weight % and the In of 0.20 weight %, after the heat fused, use the graphite casting die continuous casting to make the line base of Φ 8mm in the graphite crucible in being fixed in vacuum tank., through wire drawing processing, intermediate annealing, hot candied processing, and final wire rod plated Ag make its thickness of coating reach 1.1 μ ms, carry out wire drawing processing again and reach line and directly obtain superfine copper alloy wire for 0.025mm thereafter.Prepare the Cu-In-Sn copper alloy wire (In of the Sn of 0.19 weight %, 0.20 weight %) of the plating Ag of 7 this 0025mm, with the spacing of 1.3mm it is carried out strandedly, be made into the twisted wire that its external diameter is 0.075mm.Then, resulting twisted wire is carried out 5 kinds mobile heat treatment in being heated to 350 ℃ heat-treatment furnace, obtain superfine copper alloy twisted wire.
To this superfine copper alloy twisted wire, similarly to Example 3, measured the conductance after tensile strength before and after the heat treatment and resistance, the heat treatment, calculated tensile strength and changes in resistance rate.It the results are shown in table 7.
And then pushing the PFA resin that coats 0.006mm thickness and formed external diameter in the periphery of this twisted wire is the solid interior insulator of 0.195mm.Be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.19 weight %) of 0.025mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this internal insulator again; coat the protective layer that constitutes by the PFA resin that thickness is 0.003mm in the periphery of this external conductor again, thereby obtain the coaxial cable 20A that external diameter is 0.305mm.
Perhaps, pushing the foam PFA village's fat that coats 0.08mm thickness and formed external diameter in the periphery of this twisted wire is the internal insulator with bubble of 0.235mm.Form the thick epidermal area that constitutes by the PET band of 0.01mm in the periphery of this internal insulator again; be that the Cu-In-Sn alloy wire (containing the Sn of 0.19 weight % and the In of 0.20 weight %) of 0.025mm forms external conductor at the periphery horizontal wraparound gauge or diameter of wire of this epidermal area again; forming by thickness in the periphery of this external conductor again is the protective layer that the PET band of 0.015mm constitutes, thereby obtains the coaxial cable 20B that external diameter is 0.335mm.
Comparative example 11
The making of the coaxial cable of 42AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of comparative example 10.
Comparative example 12
The making of the coaxial cable of 42AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of comparative example 10.
Comparative example 13
The making of the coaxial cable of 44AWG.
Except the In of the Sn that adds 0.19 weight % and 0.19 weight % replaces carrying out the processing identical with the manufacture method of embodiment 6 this point of silver.
Comparative example 14
The making of the coaxial cable of 44AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of comparative example 13.
Comparative example 15
The making of the coaxial cable of 44AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of comparative example 13.
Comparative example 16
The making of the coaxial cable of 46AWG.
Except the In of the Sn that adds 0.19 weight % and 0.19 weight % replaces carrying out the processing identical with the manufacture method of embodiment 12 this point of silver.
Comparative example 17
The making of the coaxial cable of 46AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of comparative example 16.
Comparative example 18
The making of the coaxial cable of 46AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of comparative example 16.
Comparative example 19
The making of the coaxial cable of 48AWG.
Except the In of the Sn that adds 0.19 weight % and 0.19 weight % replaces carrying out the processing identical with the manufacture method of embodiment 18 this point of silver.
Comparative example 20
The making of the coaxial cable of 48AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of comparative example 19.
Comparative example 21
The making of the coaxial cable of 48AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of comparative example 19.
Comparative example 22
The making of the coaxial cable of 50AWG.
Except the In of the Sn that adds 0.19 weight % and 0.19 weight % replaces carrying out the processing identical with the manufacture method of embodiment 21 this point of silver.
Comparative example 23
The making of the coaxial cable of 50AWG.
Except 450 ℃ carry out 1.5 seconds heat treatment this point, carry out the processing identical with the manufacture method of comparative example 22.
Comparative example 24
The making of the coaxial cable of 50AWG.
Except 500 ℃ carry out 0.4 second heat treatment this point, carry out the processing identical with the manufacture method of comparative example 22.
Below, the 3-23 to embodiment is described, comparative example 3-24, the evaluation result of the superfine copper alloy twisted wire of original routine 3-6.
Table 7 expression be conductance, tensile strength and tensile strength and changes in resistance rate after tensile strength before and after the superfine copper alloy twisted wire of embodiment 3-23, comparative example 3-24, original routine 3-6 is heat-treated and resistance, the heat treatment.
Table 7
[the 7th table] (based on the data of 7 cabling lines)
* rate of change=[value before (value after the value-heat treatment before the heat treatment)/heat treatment] * 100%
As shown in table 1, for 7 cabling lines of embodiment 3-5 (43AWG), because interpolation metal concentration and heat-treat condition are suitable, thereby, the reduced rate of tensile strength arrives 6.9-10.8% at most, and the tensile strength after the heating is 910MPa, surpasses the tensile strength 850MPa as desired value.In addition, the reduced rate of resistance also arrives 6.1-7.3% (resistance change rate is more than 6%) significantly greatly, and the resistance after the heating is 6450 Ω/km, can obtain the wire rod of the high conductivity of conductance more than 85%.
Corresponding therewith, 7 cabling lines of the original routine 3-6 (43AWG) of signal bronze, its tensile strength is lower than 850MPa, and then, even original signal bronze line is carried out heat treatment of the present invention (original routine 3-6) equally, its tensile strength also is reduced to 710-730MPa significantly, and the reduced rate of resistance at most only 0.9% is difficult to reach the characteristic that has high tensile strength and high conductivity two aspects simultaneously.
7 cabling lines of original Cu-Sn-In alloy wire (with reference to comparative example 10-24), its tensile strength is lower than 850MPa after heating, can not obtain high-intensity material.
In addition, comparative example 3 is not owing to heat-treat, though its tensile strength height, its resistance still can not obtain the material of the high conductivity of conductance more than 85% up to 6870 Ω/km.
Comparative example 4 is because the interpolation concentration of silver is 0.5 weight % and low excessively, thereby its tensile strength is lower than the 850MPa of desired value, and the reduced rate of resistance is up to 2%, and hence one can see that, and it is difficult to reach the characteristic that has high tensile strength and low resistance two aspects simultaneously.
Comparative example 5 is because the interpolation concentration of silver is 3.5 weight % and too high, thereby, the highest ability 1% of its resistance reduced rate, hence one can see that, and it is difficult to reach the characteristic that has high tensile strength and low resistance two aspects simultaneously.
Comparative example 6 is because heat treatment temperature is low to 250 ℃, thereby its resistance reduced rate is up to 0.5%, and hence one can see that, and it is difficult to reach the characteristic that has high tensile strength and low resistance two aspects simultaneously.
Comparative example 7 since heat treatment temperature up to 600 ℃, thereby the reduced rate of its tensile strength is significantly up to 27.3%, hence one can see that, it is difficult to reach the characteristic that has high tensile strength and low resistance two aspects simultaneously.
Comparative example 8 is because heat treatment time is short to 0.1 second, thereby its resistance reduced rate is up to 1%, and hence one can see that, and it is difficult to reach the characteristic that has high tensile strength and low resistance two aspects simultaneously.
Comparative example 9 is because heat treatment time reaches 6 seconds, thereby its tensile strength reduced rate is 22.1%, and tensile strength is low, and hence one can see that to 810MPa, and it is difficult to reach the characteristic that has high tensile strength and low resistance two aspects simultaneously.
If embodiment 3-23 and comparative example 10-24 are compared, the twisted wire of comparative example 10-24, its resistance reduced rate is up to about 0.8-3.2%, all is the higher wire rod of resistance value.As for comparative example 10-comparative example 24, its tensile strength also is lower than desired value 850MPa.
That is to say, as known from Table 7, as comparative example 10-24, using under the situation of Cu-0.19%Sn-0.19%In alloy that no matter whether heat-treat, its tensile strength all is lower than embodiment 3-23, and its resistance also all is higher than embodiment 3-23.
In addition, as illustrated in the prior art, existing product uses the Cu-0.19%Sn-0.19%In alloy twisted wire without special heat treated, does not carry out other heat treatment.Therefore, even have high conductivity and high-intensity characteristic 7 bursts of twisted wire bare wire stages, but the heating that produces during because of squeeze job (for example 400-300 ℃ 1 second-5 seconds), shown in the alloy twisted wire of comparative example 10-24, its resistance reduced rate is also little, but its tensile strength reduces than heating is preceding.
In contrast, the twisted wire of embodiment, owing to after twisted wire processing, carried out heat treatment in advance, thereby, can provide is not squeezed adds the influence of the thermal process that the heating that produces man-hour causes, at the coaxial cable that can not change aspect its tensile strength of the front and back of extrusion process and the resistance two.
Result according to table 7, the electrical characteristic of the coaxial cable of embodiment and the thicker original coaxial electric axis identical (for example, the electrical characteristic of the coaxial cable of the 43AWG of embodiment, 45AWG, 47AWG is identical with the electrical characteristic and the mechanical property of the coaxial cable of original 42 AWG, 44 AWG, 46 AWG with mechanical property) of wire size.Therefore, as 43 AWG, 45 AWG, 47 AWG,, when just can make coaxial cable realize carefully the footpathization, can also prevent the rapid deterioration of coaxial wire rod electrical characteristic by using the coaxial wire rod of odd number size.
Below, the evaluation result to the coaxial cable of embodiment 3-23, original routine 3-6 is described.
At first, the various coaxial cables of embodiment 3-23, comparative example 3-24, original routine 3-6 are carried out bend test, estimated flex life.Bend test is to be fixed on the anchor clamps that bending radius is 2mm in the end with sample cable (coaxial cable), according to the size of sample cable the weight of 50gf or 20gf is suspended under the state on the other end of sample cable, be to make sample 90 ° of alternating bendings about on the length direction of coaxial cable under 30 times/minute the condition in test speed, measure test up to the number of times (life-span) of the inner conductor fracture of sample cable; Always sample is applied the voltage of several V at the trial, relatively reduced by moment of 20% during with current value and on-test as the life-span.Numeric representation in table 8, the table 9 be number of bends up to the life-span.
In addition, the various coaxial cables of embodiment 3-23, comparative example 3-24, original routine 3-6 electrostatic capacitance, attenuation and characteristic impedance have also been estimated.
The mensuration of electrostatic capacitance is to be connected with the LCR table between the inner conductor of the sample cable (coaxial cable) of 1m and the external conductor, to measure the electrostatic capacitance of 1KHz.In addition, with measuring with coaxial cable (lead-in wire), measured the attenuation of 10MHz with being connected with receiving terminal with the transmitting terminal of network analyzer between the inner conductor at the sample cable two ends of 1m and the external conductor.And, before the attenuation of measuring sample, proofread and correct the influence of measuring with coaxial cable (lead-in wire) to get rid of.In addition, characteristic impedance is to use network analyzer to measure numerical value at 10MHz.
Table 8, table 9 have been represented the evaluation result of these electrical characteristics and mechanical property.
Table 8 and table 9 are as follows:
*Flex life in the bracket before the expression heating
*Flex life in the bracket before the expression heating
As shown in table 8, flex life with respect to the coaxial cable 20A of embodiment 3-5 (43 AWG) is more than 40900 times, the flex life of comparative example 3-9 (43 AWG) and original routine 3-6 (43 AWG) is respectively 37600 times, 22300 times, 38200 times, 36600 times, 31400 times, 36800 times, 35300 times, 26500 times, 19400 times, 21800 times, 20400 times, hence one can see that, the flex life of the coaxial cable of embodiment 3-5 is long, shows good flexural property.In addition, the embodiment 6-23 of identical wire size and comparative example 13-24 compared also know that the coaxial cable of embodiment is longer with respect to its flex life of coaxial cable of comparative example, flexural property is better.
As shown in table 9, flex life with respect to the coaxial cable 20B of embodiment 3-5 (43 AWG) is more than 20900 times, the flex life of comparative example 3-9 (43 AWG) and original routine 3-6 (43 AWG) is respectively 19600 times, 12300 times, 18200 times, 20600 times, 12400 times, 18800 times, 9300 times, 16500 times, 12400 times, 11900 times, 12300 times, hence one can see that, the flex life of the coaxial cable of embodiment 3-5 is long, shows good flexural property.
In addition, the embodiment 6-23 of identical wire size and comparative example 13-24 compared also know that the coaxial cable of embodiment is longer with respect to its flex life of coaxial cable of comparative example, flexural property is better.
In addition, the result according to table 8, table 9 can confirm that the coaxial cable of the coaxial cable of embodiment 3-23 and comparative example and original example has relatively been kept identical electrostatic capacitance and characteristic impedance.Attenuation when being 10MHz about frequency can confirm that also the coaxial cable of embodiment compares with the original example of identical wire size and the coaxial cable of comparative example, has kept equal above attenuation characteristic.
Especially, though comparative example 8 is coaxial cables of 42 AWG, when comparing with regard to the coaxial cable of flex life and attenuation and embodiment 3-5, then can be evaluated as, embodiment 3-5 is longer aspect flex life, and equates substantially aspect attenuation.
In addition, with reference to table 7, when the tensile strength of twisted wire state and resistance are compared, then can be evaluated as, embodiment 3-5 is better aspect tensile strength, and about the same aspect resistance.
That is to say, according to present embodiment, according to requirement of client etc., even it is thinner that coaxial cable is made wire size, its electrical characteristic (center conductor resistance, attenuation) is also identical with the thicker comparative example of wire size, and flexural property (tensile strength) the comparative example higher coaxial cable thicker than wire size of coaxial wire rod can be provided.Therefore, when reducing the size of coaxial cable, can suppress the deterioration of electrical characteristic (resistance, attenuation) and mechanical property (flex life) as much as possible.
Other embodiment
As the interpolation element of copper alloy of the present invention, beyond the desilver, can also add one or both metals of from magnesium (Mg) indium (In), selecting in total amount 0.02-0.10 weight %.Though can increase cost along with increasing the interpolation element, can expect and further to improve intensity.
The 5th, multicore cable is described.
At first, the multicore cable that uses four coaxial cables is described.
What Fig. 8 represented is the sectional drawing of the multicore cable of an embodiment of the invention.
This multicore cable 30 is configured in coaxial cable 20A shown in Figure 6 or four of coaxial cable 20B shown in Figure 7 on the concentric circles and carries out stranded in the periphery of tension member 31 (or be situated between at heart yearn), the strapping 33 of reeling then is provided with screen 35 and outer shell 37 in its periphery again.
The volume of strapping 33 is thick to be for example 0.05mm.In addition, use thickness for example will plate the litzendraht wire that the Sn annealed copper wire has carried out braiding as screen 35 as 0.05mm.Screen 35 also can use the screen of other cross winding.Outer shell 37 can be by coiling PET band, and perhaps extruding coating tetrafluoroethene full root skin propyl ethylene ether copolymer (PFA), tetrafluoroethene hexafluoropropylene copolymer (FEP), ethylene tetrafluoroethylene copolymer (ETFE), polyvinyl chloride (PVC) wait and be provided with.
In addition, though what represent among Fig. 8 is that coaxial cable 20A or 20B are disposed one deck and carry out stranded structure on concentric circles, also can use more coaxial cable 20A or 20B to be configured to carry out more than two-layer stranded.
Secondly, the multicore cable that has used three coaxial cables and a superfine insulated wire is described.
What Fig. 9 represented is the sectional drawing of the multicore cable of another embodiment of the present invention.
This multicore cable 40 be the periphery of tension element 31 (or be situated between at heart yearn) will coaxial cable 20A shown in Figure 6 or three of coaxial cable 20B shown in Figure 7 be configured on the concentric circles with 10 1 of superfine insulated wires shown in Figure 5 and carry out stranded, the strapping 33 of reeling again, and then, screen 35 and outer shell 37 are set and the composite cable made in its periphery again.
And though Fig. 9 uses 3 coaxial cable 20A or 20B and 1 superfine insulated wire 10, the ratio of coaxial electrical 20A or 20B and superfine insulated wire 10 can change arbitrarily as required.In addition, though Fig. 9 expression is that coaxial cable 20A or 20B and superfine insulated wire 10 disposes the also stranded structure that forms of one deck on concentric circles, also can use more coaxial cable 20A or 20B and superfine insulated wire 10 to be configured to the stranded structure that forms more than two layers.
Then, the multicore cable that has used four superfine insulated wires is described.
What Figure 10 represented is the sectional drawing of the multicore cable of another execution mode.
This multicore cable 50 is that the periphery at tension member 31 (or be situated between at heart yearn) is configured in 10 4 of superfine insulated wires shown in Figure 5 on the concentric circles and carries out stranded, the strapping 33 of reeling again, and then, the differential transmission cable of making at its arranged outside screen 35 and outer shell 37 again.
And,, also can use more superfine insulated wire 10 to be configured to the stranded structure that forms more than two layers though Figure 10 expression is the superfine insulated wire 10 stranded structures that form of configuration one deck on concentric circles.
Below, the multicore cable that has used four groups of coaxial cable unit is described.
What Figure 11 represented is the sectional drawing of the multicore cable of another execution mode.
This multicore cable 60 is that coaxial cable 20A shown in the multiple bar chart 6 or coaxial cable 20B harness shown in Figure 7 are formed coaxial cable unit 61, assemble this coaxial cable of many groups unit 61 and carry out stranded in the periphery of tension member 31 (or Jie) again at heart yearn, the strapping 33 of reeling again, and then, again at its arranged outside screen 35 and outer shell 37 and make.
Below, the multicore cable of spiral form is described.
What Figure 12 represented is the end view of the multicore cable of other execution mode.
This multicore cable 70 is to prepare to have certain intervals between 10, two lines of two superfine insulated wires shown in Figure 5, and is wound on the center conductor line 71 with a determining deviation and makes helix.As center conductor 71, for example can using, the line footpath is the silver-coated copper wire of 0.16mm.In addition, also two superfine insulated wires 10 can be twisted together earlier, again with certain spacing 1 or 2 such twisted wires 2 superfine insulated wires 10 that replace reeling of reeling.
Below, ribbon cable formula multicore cable is described.
What Figure 13 represented is the sectional drawing of the multicore cable of other execution mode.
This multicore cable 80 is that coaxial cable 20A shown in the multiple bar chart 6 or coaxial cable 20B shown in Figure 7 are disposed side by side with certain spacing, again the multicore ribbon cable of making in the two sides of its body arranged side by side stickup adhesive tape 81.
Claims (43)
1. superfine copper alloy wire, its characteristic is:
It is that line directly is 0.010-0.025mm, by the silver that contains 1-3 weight % (Ag), all the other superfine copper alloy wires for copper (Cu) and unavoidable impurities formation, its tensile strength is more than the 850MPa, and conductance is more than 85%IACS, and elongation is 0.5-3.0%; And, through the heat treated of temperature below 350 ℃, below 5 seconds of time, the tensile strength (σ after the heat treated
H1) with respect to the tensile strength (σ before the heat treated
H0) reduced rate [(1-σ
H1/ σ
H0) * 100%] below 2%.
2. superfine copper alloy wire according to claim 1, its characteristic is:
Form the coating of tin (Sn), silver (Ag) or nickel (Ni) on the surface of above-mentioned alloy wire.
3. superfine copper alloy twisted wire is characterized in that:
With many claims 1 or 2 described superfine copper alloy wire is stranded forms.
4. superfine copper alloy twisted wire according to claim 3 is characterized in that:
Being that 7 lines directly are the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.025mm, is 6000 Ω/below the km at 20 ℃ resistance.
5. superfine copper alloy twisted wire according to claim 3 is characterized in that:
Being that 7 lines directly are the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.023mm, is 7000 Ω/below the km at 20 ℃ resistance.
6. superfine copper alloy twisted wire according to claim 3 is characterized in that:
Being that 7 lines directly are the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.020mm, is 9500 Ω/below the km at 20 ℃ resistance.
7. superfine copper alloy twisted wire according to claim 3 is characterized in that:
Being that 7 lines directly are the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.018mm, is 11500 Ω/below the km at 20 ℃ resistance.
8. superfine copper alloy twisted wire according to claim 3 is characterized in that:
Being that 7 lines directly are the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.016mm, is 15000 Ω/below the km at 20 ℃ resistance.
9. superfine copper alloy twisted wire according to claim 3 is characterized in that:
Being that 7 lines directly are the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.013mm, is 22000 Ω/below the km at 20 ℃ resistance.
10. superfine copper alloy twisted wire according to claim 3 is characterized in that:
Being that 7 lines directly are the stranded twisted wire that forms of above-mentioned superfine copper alloy wire of 0.010mm, is 38000 Ω/below the km at 20 ℃ resistance.
11. a superfine insulated wire is characterized in that:
It is directly to carry out the stranded superfine copper alloy twisted wire that forms for many superfine copper alloy wires of 0.010-0.025mm by the silver that contains 1-3 weight % (Ag), all the other lines for copper (Cu) and unavoidable impurities formation, the tensile strength of above-mentioned superfine copper alloy twisted wire is more than the 850MPa, conductance is more than 85%IACS, and to have coated thickness in the periphery of above-mentioned copper alloy twisted wire be solid insulator below the 0.07mm.
12. superfine insulated wire according to claim 11 is characterized in that:
Above-mentioned superfine copper alloy twisted wire is a twisted wire after heat treatment, and the resistance reduced rate after the above-mentioned heat treatment is more than 6%, and the tensile strength reduced rate after the above-mentioned heat treatment is below 20%.
13. superfine insulated wire according to claim 11 is characterized in that:
Formed the coating of tin (Sn), silver (Ag) or nickel (Ni) on the surface of above-mentioned copper alloy wire.
14. a coaxial cable is characterized in that:
The formation of the periphery of any one described superfine insulated wire with the helically wound external conductor of many strip conductors coil of wire, has coated protective layer in the said external surface of conductors along the length direction of above-mentioned superfine insulated wire again in claim 11-13.
15. coaxial cable according to claim 14 is characterized in that:
Constitute above-mentioned superfine insulated wire copper alloy wire line footpath for greater than 0.021mm below 0.025mm, its resistance is 7200 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 0.6-1.0db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 20000 times under the condition of radius of curvature R=2mm, load=50g.
16. coaxial cable according to claim 14 is characterized in that:
Constitute above-mentioned superfine insulated wire copper alloy wire line footpath for greater than 0.018mm below 0.022mm, its resistance is 9500 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 0.8-1.2db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 20000 times under the condition of radius of curvature R=2mm, load=50g.
17. coaxial cable according to claim 14 is characterized in that:
Constitute above-mentioned superfine insulated wire copper alloy wire line footpath for greater than 0.016mm below 0.020mm, its resistance is 12200 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 1.0-1.5db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 20000 times under the condition of radius of curvature R=2mm, load=50g.
18. coaxial cable according to claim 14 is characterized in that:
Constitute above-mentioned superfine insulated wire copper alloy wire line footpath for greater than 0.014mm below 0.018mm, its resistance is 14700 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 1.1-1.6db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 30000 times under the condition of radius of curvature R=2mm, load=50g.
19. coaxial cable according to claim 14 is characterized in that:
Constitute above-mentioned superfine insulated wire copper alloy wire line footpath for greater than 0.013mm below 0.017mm, its resistance is 16500 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 1.3-1.8db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 30000 times under the condition of radius of curvature R=2mm, load=20g.
20. coaxial cable according to claim 14 is characterized in that:
Constitute above-mentioned superfine insulated wire copper alloy wire line footpath for greater than 0.011mm below 0.015mm, its resistance is 22500 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 1.7-2.4db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 30000 times under the condition of radius of curvature R=2mm, load=20g.
21. coaxial cable according to claim 14 is characterized in that:
Constitute above-mentioned superfine insulated wire copper alloy wire line footpath for greater than 0.010mm below 0.012mm, its resistance is 38000 Ω/below the km, electrostatic capacitance is 100-130pF/m, attenuation is 2.5-3.8db/m (frequency is 10MHz), and the life-span of 90 degree that bend right and left is being more than 10000 times under the condition of radius of curvature R=2mm, load=20g.
22. a coaxial cable is characterized in that:
The periphery of any one described superfine copper alloy twisted wire in aforesaid right requirement 3-10; coat the cellular insulation body; form length direction along above-mentioned superfine copper alloy twisted wire with the helically wound external conductor of many strip conductors coil of wire in the periphery of above-mentioned cellular insulation body again, coated protective layer in the said external surface of conductors again.
23. coaxial cable according to claim 22 is characterized in that:
Above-mentioned superfine copper alloy twisted wire is a twisted wire after heat treatment, and the resistance reduced rate after the above-mentioned heat treatment is more than 6%, and the tensile strength reduced rate after the above-mentioned heat treatment is below 20%.
24. coaxial cable according to claim 22 is characterized in that:
Formed the coating of tin (Sn), silver (Ag) or nickel (Ni) on the surface of above-mentioned copper alloy wire.
25. coaxial cable according to claim 22 is characterized in that:
The line of above-mentioned superfine copper alloy wire footpath for greater than 0.021mm below 0.025mm, its resistance is that 7500 Ω/below the km, electrostatic capacitance is 30-80pF/m.
26. coaxial cable according to claim 22 is characterized in that:
The line of above-mentioned superfine copper alloy wire footpath for greater than 0.018mm below 0.022mm, its resistance is that 10000 Ω/below the km, electrostatic capacitance is 30-80pF/m.
27. coaxial cable according to claim 22 is characterized in that:
The line of above-mentioned superfine copper alloy wire footpath for greater than 0.016mm below 0.020mm, its resistance is that 13000 Ω/below the km, electrostatic capacitance is 30-80pF/m.
28. coaxial cable according to claim 22 is characterized in that:
The line of above-mentioned superfine copper alloy wire footpath for greater than 0.014mm below 0.018mm, its resistance is that 15500 Ω/below the km, electrostatic capacitance is 30-80pF/m.
29. coaxial cable according to claim 22 is characterized in that:
The line of above-mentioned superfine copper alloy wire footpath for greater than 0.013mm below 0.017mm, its resistance is that 17000 Ω/below the km, electrostatic capacitance is 30-80pF/m.
30. coaxial cable according to claim 22 is characterized in that:
The line of above-mentioned superfine copper alloy wire footpath for greater than 0.011mm below 0.015mm, its resistance is that 23500 Ω/below the km, electrostatic capacitance is 30-80pF/m.
31. coaxial cable according to claim 22 is characterized in that:
The line of above-mentioned superfine copper alloy wire footpath for greater than 0.010mm below 0.012mm, its resistance is that 40000 Ω/below the km, electrostatic capacitance is 30-80pF/m.
32. a multicore cable is characterized in that:
At tension member or be situated between in the periphery of heart yearn, stranded many claims 14 or 22 described coaxial cables form.
33. a multicore cable is characterized in that:
At tension member or be situated between, many aforesaid rights are required stranded the forming of any one described superfine insulated wire among 14 coaxial cable and the claim 11-13 in the periphery of heart yearn.
34. a multicore cable is characterized in that:
At tension member or be situated between in the periphery of heart yearn, will many stranded the forming of any one described superfine insulated wire among the aforesaid rights requirement 11-13.
35. a multicore cable is characterized in that:
At tension member or be situated between in the periphery of heart yearn, a plurality of stranded the forming in coaxial cable unit that require 14 or 22 described coaxial cable harnesses to form many aforesaid rights.
36. a multicore cable is characterized in that:
Requiring among the 11-13 any one described superfine insulated wire spacing at certain intervals to be wound on the center conductor many aforesaid rights forms.
37. a multicore cable is characterized in that:
Requiring 14 or 22 described coaxial cables to dispose side by side with a determining deviation many aforesaid rights forms.
38. the manufacture method of a superfine copper alloy wire is characterized in that:
The silver that adds 1-3 weight % in fine copper generates copper alloy, carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm, by under 300-500 ℃ temperature, carrying out the 0.2-5 heat treatment of second, making it become tensile strength is more than the 850MPa, conductance is more than 85%IACS, and elongation is 0.5-3.0%; And, through the heat treated of temperature below 350 ℃, below 5 seconds of time, the tensile strength (σ after the heat treated
H1) with respect to the tensile strength (σ before the heat treated
H0) reduced rate [(1-σ
H1/ σ
H0) * 100%] at the superfine copper alloy wire below 2%.
39. the manufacture method according to the described superfine copper alloy wire of claim 38 is characterized in that:
Also have making above-mentioned line, form the operation of the coating of tin (Sn), silver (Ag), nickel (Ni) again on the surface of this superfine copper alloy wire directly for behind the superfine copper alloy wire of 0.010-0.025mm.
40. the manufacture method of a superfine copper alloy twisted wire is characterized in that:
The silver that adds 1-3 weight % in fine copper generates copper alloy, carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm, form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded, by under 300-500 ℃ temperature, carrying out the 0.2-5 heat treatment of second, thereby make any one described superfine copper alloy twisted wire among the aforesaid right requirement 4-10.
41. the manufacture method of a superfine insulated wire is characterized in that:
The silver that adds 1-3 weight % in fine copper generates copper alloy, carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm, form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded, by after carrying out the 0.2-5 heat treatment of second under 300-500 ℃ the temperature, coating thickness in the periphery of above-mentioned copper alloy twisted wire again is that solid insulator below the 0.07mm forms.
42. the manufacture method of a coaxial cable is characterized in that:
The silver that adds 1-3 weight % in fine copper generates copper alloy; carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm; form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded; by after carrying out the 0.2-5 heat treatment of second under 300-500 ℃ the temperature; coating thickness in the periphery of above-mentioned copper alloy twisted wire again is that solid insulator below the 0.07mm becomes superfine insulated wire; again in the periphery of above-mentioned superfine insulated wire; length direction along above-mentioned superfine insulated wire after having formed external conductor, coats many strip conductors coil of wire coiled protective layer in the said external surface of conductors again and forms.
43. the manufacture method of a coaxial cable is characterized in that:
The silver that adds 1-3 weight % in fine copper generates copper alloy; carry out wire drawing and be processed into line directly for behind the superfine copper alloy wire of 0.010-0.025mm; form superfine copper alloy twisted wire with many above-mentioned superfine copper alloy wires are stranded; by after carrying out the 0.2-5 heat treatment of second under 300-500 ℃ the temperature; again in the periphery of above-mentioned copper alloy twisted wire after to coat thickness be cellular insulation body below the 0.28mm; form epidermal area; again in the periphery of this epidermal area; length direction along above-mentioned copper alloy twisted wire after forming external conductor, coats many strip conductors coil of wire coiled protective layer in the said external surface of conductors again and forms.
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005366568 | 2005-12-20 | ||
| JP2005366566 | 2005-12-20 | ||
| JP2005366566A JP4143086B2 (en) | 2005-12-20 | 2005-12-20 | Extra-fine copper alloy wire, extra-fine copper alloy twisted wire, and manufacturing method thereof |
| JP2005-366566 | 2005-12-20 | ||
| JP2005366567A JP4143087B2 (en) | 2005-12-20 | 2005-12-20 | Ultra-fine insulated wire and coaxial cable, manufacturing method thereof, and multi-core cable using the same |
| JP2005366568A JP4143088B2 (en) | 2005-12-20 | 2005-12-20 | Coaxial cable, manufacturing method thereof, and multicore cable using the same |
| JP2005-366567 | 2005-12-20 | ||
| JP2005-366568 | 2005-12-20 | ||
| JP2005366567 | 2005-12-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1988055A true CN1988055A (en) | 2007-06-27 |
| CN1988055B CN1988055B (en) | 2010-05-19 |
Family
ID=38184805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006101687702A Active CN1988055B (en) | 2005-12-20 | 2006-12-18 | Copper alloy wire, copper alloy twisted wire, coaxial cable, its manufacturing method and multi-core cable |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP4143086B2 (en) |
| CN (1) | CN1988055B (en) |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101791638A (en) * | 2009-01-29 | 2010-08-04 | 住友电气工业株式会社 | The manufacture method of Cu-Ag alloy wire and Cu-Ag alloy wire |
| CN101819832A (en) * | 2009-02-26 | 2010-09-01 | 住友电气工业株式会社 | Coaxial cable and manufacture method thereof |
| CN102017018A (en) * | 2009-04-24 | 2011-04-13 | 住友电气工业株式会社 | Electrical wire and method for producing same |
| CN102623106A (en) * | 2012-04-19 | 2012-08-01 | 成都普天电缆股份有限公司 | Technology for processing ultrathin electronic wire |
| CN102057444B (en) * | 2008-06-06 | 2013-05-01 | Dlb德拉特和利曾有限责任公司 | Method for producing a braid, and also a braid comprising a plurality of wires |
| CN103151115A (en) * | 2013-02-28 | 2013-06-12 | 天恒达电工科技股份有限公司 | Method for producing high-tension copper alloy enameled wire |
| CN103238189A (en) * | 2010-11-22 | 2013-08-07 | 美国北卡罗来纳康普公司 | Twisted pair communications cable with selective separation of pairs |
| CN103650271A (en) * | 2011-04-19 | 2014-03-19 | Est日本株式会社 | Transmission medium, transmission device, and transmission method |
| CN104364852A (en) * | 2012-06-01 | 2015-02-18 | 矢崎总业株式会社 | Insulated electric wire |
| CN103035338B (en) * | 2011-08-17 | 2016-08-24 | 日立金属株式会社 | The manufacture method that fusion welding plating is twisted thread |
| CN105981112A (en) * | 2014-02-26 | 2016-09-28 | 株式会社自动网络技术研究所 | Stranded conductor and insulated wire |
| CN106029930A (en) * | 2014-02-28 | 2016-10-12 | 株式会社自动网络技术研究所 | Copper alloy twisted wire, manufacturing method therefor, and electrical wire for automobile |
| CN106067343A (en) * | 2015-04-07 | 2016-11-02 | 龚永祥 | A kind of remote radio head photoelectric mixed cable |
| CN106414215A (en) * | 2014-05-22 | 2017-02-15 | Tk控股公司 | Systems and methods for shielding a hand sensor system in a steering wheel |
| CN106504832A (en) * | 2016-12-15 | 2017-03-15 | 苏州陈恒织造有限公司 | A kind of preparation method of the cable of working stability |
| CN107103946A (en) * | 2016-02-23 | 2017-08-29 | 莱尼电缆有限公司 | Data cable and stranded conductor |
| CN107210096A (en) * | 2015-01-27 | 2017-09-26 | 日立金属株式会社 | Coaxial cable and medical cable |
| US10114513B2 (en) | 2014-06-02 | 2018-10-30 | Joyson Safety Systems Acquisition Llc | Systems and methods for printing sensor circuits on a sensor mat for a steering wheel |
| CN111398056A (en) * | 2020-03-09 | 2020-07-10 | 神宇通信科技股份公司 | Superfine coaxial cable |
| CN112201405A (en) * | 2020-09-27 | 2021-01-08 | 朱克凤 | Flat flexible cable with good conductivity |
| CN112447325A (en) * | 2019-08-27 | 2021-03-05 | 日立金属株式会社 | Coaxial cable |
| CN113299421A (en) * | 2020-02-06 | 2021-08-24 | 日立金属株式会社 | Copper alloy wire, plated wire, electric wire and cable |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4973437B2 (en) * | 2007-10-16 | 2012-07-11 | 日立電線株式会社 | Copper alloy wire, copper alloy twisted wire, coaxial cable, multi-core cable, and copper alloy wire manufacturing method |
| JP5442294B2 (en) * | 2009-03-31 | 2014-03-12 | 三菱電線工業株式会社 | Wire conductor manufacturing method, and wire conductor and insulated wire |
| CN102751050A (en) * | 2012-07-26 | 2012-10-24 | 衡阳三三融信电工有限公司 | Production method of superfine copper clad aluminum magnet wire with high dielectric strength |
| CN102800918B (en) * | 2012-08-06 | 2014-12-10 | 汕头市金桥电缆有限公司 | Manufacturing method of wireless communication antenna feeder |
| JP6155923B2 (en) * | 2013-07-16 | 2017-07-05 | 住友電気工業株式会社 | Method for producing copper-silver alloy wire |
| CN107068300A (en) * | 2017-03-28 | 2017-08-18 | 江苏藤仓亨通光电有限公司 | A kind of manufacturing process of high-strength high-conductivity copper-magnesium alloy strand |
| CN116633059B (en) * | 2023-05-15 | 2024-05-14 | 浙江大学 | Motor forming winding structure and processing method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4311277B2 (en) * | 2004-05-24 | 2009-08-12 | 日立電線株式会社 | Manufacturing method of extra fine copper alloy wire |
-
2005
- 2005-12-20 JP JP2005366566A patent/JP4143086B2/en active Active
-
2006
- 2006-12-18 CN CN2006101687702A patent/CN1988055B/en active Active
Cited By (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102057444B (en) * | 2008-06-06 | 2013-05-01 | Dlb德拉特和利曾有限责任公司 | Method for producing a braid, and also a braid comprising a plurality of wires |
| CN101791638A (en) * | 2009-01-29 | 2010-08-04 | 住友电气工业株式会社 | The manufacture method of Cu-Ag alloy wire and Cu-Ag alloy wire |
| CN101819832A (en) * | 2009-02-26 | 2010-09-01 | 住友电气工业株式会社 | Coaxial cable and manufacture method thereof |
| CN102017018A (en) * | 2009-04-24 | 2011-04-13 | 住友电气工业株式会社 | Electrical wire and method for producing same |
| CN103238189A (en) * | 2010-11-22 | 2013-08-07 | 美国北卡罗来纳康普公司 | Twisted pair communications cable with selective separation of pairs |
| CN103238189B (en) * | 2010-11-22 | 2016-04-27 | 美国北卡罗来纳康普公司 | Selectivity separates right twisted pair telecommunication cable |
| CN103650271A (en) * | 2011-04-19 | 2014-03-19 | Est日本株式会社 | Transmission medium, transmission device, and transmission method |
| CN103035338B (en) * | 2011-08-17 | 2016-08-24 | 日立金属株式会社 | The manufacture method that fusion welding plating is twisted thread |
| CN102623106A (en) * | 2012-04-19 | 2012-08-01 | 成都普天电缆股份有限公司 | Technology for processing ultrathin electronic wire |
| US9875827B2 (en) | 2012-06-01 | 2018-01-23 | Yazaki Corporation | Method for producing insulated electric wire |
| CN104364852A (en) * | 2012-06-01 | 2015-02-18 | 矢崎总业株式会社 | Insulated electric wire |
| CN104364852B (en) * | 2012-06-01 | 2016-08-31 | 矢崎总业株式会社 | For the method producing insulated electric conductor |
| CN103151115A (en) * | 2013-02-28 | 2013-06-12 | 天恒达电工科技股份有限公司 | Method for producing high-tension copper alloy enameled wire |
| CN105981112A (en) * | 2014-02-26 | 2016-09-28 | 株式会社自动网络技术研究所 | Stranded conductor and insulated wire |
| US10147518B2 (en) | 2014-02-26 | 2018-12-04 | Autonetworks Technologies, Ltd. | Stranded wire conductor and insulated wire |
| CN106029930A (en) * | 2014-02-28 | 2016-10-12 | 株式会社自动网络技术研究所 | Copper alloy twisted wire, manufacturing method therefor, and electrical wire for automobile |
| CN106029930B (en) * | 2014-02-28 | 2018-01-09 | 株式会社自动网络技术研究所 | Copper-alloy stranded conductor and its manufacture method, electric wire for automobiles |
| US11299191B2 (en) | 2014-05-22 | 2022-04-12 | Joyson Safety Systems Acquisition Llc | Systems and methods for shielding a hand sensor system in a steering wheel |
| CN106414215A (en) * | 2014-05-22 | 2017-02-15 | Tk控股公司 | Systems and methods for shielding a hand sensor system in a steering wheel |
| CN106414215B (en) * | 2014-05-22 | 2020-03-17 | Tk控股公司 | System and method for shielding hand sensor system in steering wheel |
| US10124823B2 (en) | 2014-05-22 | 2018-11-13 | Joyson Safety Systems Acquisition Llc | Systems and methods for shielding a hand sensor system in a steering wheel |
| US10698544B2 (en) | 2014-06-02 | 2020-06-30 | Joyson Safety Systems Acquisitions LLC | Systems and methods for printing sensor circuits on a sensor mat for a steering wheel |
| US11599226B2 (en) | 2014-06-02 | 2023-03-07 | Joyson Safety Systems Acquisition Llc | Systems and methods for printing sensor circuits on a sensor mat for a steering wheel |
| US10114513B2 (en) | 2014-06-02 | 2018-10-30 | Joyson Safety Systems Acquisition Llc | Systems and methods for printing sensor circuits on a sensor mat for a steering wheel |
| CN107210096A (en) * | 2015-01-27 | 2017-09-26 | 日立金属株式会社 | Coaxial cable and medical cable |
| CN107210096B (en) * | 2015-01-27 | 2019-11-05 | 日立金属株式会社 | Coaxial cable and medical cable |
| CN106067343A (en) * | 2015-04-07 | 2016-11-02 | 龚永祥 | A kind of remote radio head photoelectric mixed cable |
| CN106067343B (en) * | 2015-04-07 | 2018-01-23 | 江苏帝诚线缆有限公司 | A kind of remote radio head photoelectric mixed cable |
| CN107103946A (en) * | 2016-02-23 | 2017-08-29 | 莱尼电缆有限公司 | Data cable and stranded conductor |
| CN106504832A (en) * | 2016-12-15 | 2017-03-15 | 苏州陈恒织造有限公司 | A kind of preparation method of the cable of working stability |
| CN112447325B (en) * | 2019-08-27 | 2024-02-09 | 株式会社博迈立铖 | Coaxial cable |
| CN112447325A (en) * | 2019-08-27 | 2021-03-05 | 日立金属株式会社 | Coaxial cable |
| CN113299421A (en) * | 2020-02-06 | 2021-08-24 | 日立金属株式会社 | Copper alloy wire, plated wire, electric wire and cable |
| CN113299421B (en) * | 2020-02-06 | 2023-10-31 | 株式会社博迈立铖 | Copper alloy wire, plated wire, wire and cable |
| CN111398056B (en) * | 2020-03-09 | 2023-10-20 | 神宇通信科技股份公司 | Testing method for superfine coaxial cable |
| CN111398056A (en) * | 2020-03-09 | 2020-07-10 | 神宇通信科技股份公司 | Superfine coaxial cable |
| CN112201405A (en) * | 2020-09-27 | 2021-01-08 | 朱克凤 | Flat flexible cable with good conductivity |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007169686A (en) | 2007-07-05 |
| CN1988055B (en) | 2010-05-19 |
| JP4143086B2 (en) | 2008-09-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1988055B (en) | Copper alloy wire, copper alloy twisted wire, coaxial cable, its manufacturing method and multi-core cable | |
| JP4143087B2 (en) | Ultra-fine insulated wire and coaxial cable, manufacturing method thereof, and multi-core cable using the same | |
| US7544886B2 (en) | Extra-fine copper alloy wire, extra-fine copper alloy twisted wire, extra-fine insulated wire, coaxial cable, multicore cable and manufacturing method thereof | |
| JP5062200B2 (en) | Coaxial cable manufacturing method | |
| JP4456696B2 (en) | Coaxial cable strands, coaxial cables, and coaxial cable bundles | |
| JP2002352630A (en) | Strand conductor for movable part wiring material and cable using it | |
| CN102017018A (en) | Electrical wire and method for producing same | |
| US4810593A (en) | High-strength conductors and process for manufacturing same | |
| US20140236125A1 (en) | Catheter wire | |
| JP4143088B2 (en) | Coaxial cable, manufacturing method thereof, and multicore cable using the same | |
| WO2006022117A1 (en) | Coaxial cable | |
| JP2002129262A (en) | Extra-fine copper alloy wire and its production method | |
| JP2929161B2 (en) | Semi-rigid coaxial cable with easy termination and method of manufacturing the same | |
| JP7265324B2 (en) | insulated wire, cable | |
| EP2843670B1 (en) | Coiled cable | |
| CN107887053B (en) | Plated copper wire, plated stranded wire, insulated wire, and method for producing plated copper wire | |
| CN113838612A (en) | Coaxial cable, method for manufacturing coaxial cable, and cable assembly | |
| JP2010257776A (en) | Coaxial electric wire and method for manufacturing same | |
| JP2020013658A (en) | cable | |
| JP2002358842A (en) | External conductor layer structure of very fine coaxial cable, and very fine coaxial cable | |
| CN210535378U (en) | Superfine bending-resistant Ethernet data line | |
| JP2020191248A (en) | Electric wire with terminal, conductive element wire, electric wire, communication cable with terminal and wire harness | |
| JP2020191249A (en) | Conductive element wire, electric wire with conductive element wire, electric wire with terminal connected to conductor of electric wire, and wire harness with electric wire with terminal | |
| JP2022109209A (en) | Copper alloy wire, plated wire, electric wire, and cable | |
| CN115547570A (en) | Cable for signal transmission and cable assembly |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |