CN1986446A - Nitrobacteria growth promoter - Google Patents
Nitrobacteria growth promoter Download PDFInfo
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- CN1986446A CN1986446A CNA2005101118779A CN200510111877A CN1986446A CN 1986446 A CN1986446 A CN 1986446A CN A2005101118779 A CNA2005101118779 A CN A2005101118779A CN 200510111877 A CN200510111877 A CN 200510111877A CN 1986446 A CN1986446 A CN 1986446A
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- China
- Prior art keywords
- growth promoter
- nitrobacteria
- ammonia nitrogen
- sewage
- nitrobacteria growth
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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- Water Treatment By Sorption (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
The nitrobacteria growth promoter consists of molasses 100 weight portions, metal salt 0.2-2.5 weight portions and adsorbent 1-8 weight portions. The metal salt includes component A of MnSO4 or MnCl2, and component B of MgSO4 and/or CaCl2, in the molar ratio of 10 to (0.5-5). The adsorbent is zeolite powder, diatomite, powdered active carbon, fly ash or their mixture. The nitrobacteria growth promoter is used in biological nitrification process of eliminating ammonia nitrogen and thrown into sewage directly to promote the propagation and growth of nitrobacteria in sewage. It has raised ammonia nitrogen eliminating rate and low cost.
Description
Technical field
The present invention relates to a kind of nitrobacteria growth promoter that biological process is removed the sewage ammonia nitrogen that is used for.
Background technology
Ammonia nitrogen is the bigger pollution factor of harm in the water body, and it can cause the eutrophication in river, lake, and water body self-purification ability is weakened.The ammonia nitrogen of polluted-water is often referred to the nitrogen that exists with the ammonia form, and the difficulty of ammonia nitrogen removal is much bigger in the contaminated water body of other organic pollutant relatively.In the prior art, the removal method of ammonia nitrogen mainly contains physics, chemistry and biological method in the contaminated water body.Physics or chemical method comprise air stripping method, break point chlorination, ion exchange adsorption, flocculent precipitation, electroosmose process, catalytic wet air oxidation, liquid-film method etc.These methods generally are used for the pre-treatment of high-concentration ammonia nitrogenous wastewater, and processing cost is very high.Biological process removal ammonia nitrogen is the effect by certain micro-organisms, thereby makes the ammonia nitrogen in the contaminated water body finally form the purpose that nitrogen effusion water body reaches purifying treatment.The biological process cost is much lower, and its applicable surface is also wider, as the removal of ammonia nitrogen in ammonia nitrogen purifying treatment, sanitary wastewater or the trade effluent of fishery cultivating water body etc.
Biological process is removed ammonia nitrogen and is mainly comprised nitrification process and denitrification process.In the nitrification process, in being oxidized to nitrate or nitrite nitrogen under the effect of ammonia nitrogen nitrifier under the aerobic condition; Denitrification is meant that nitrate and nitrite are reduced to the process of gaseous nitrogen.Under anoxia condition, utilize organism as electron donor, denitrifying bacterium is reduced to nitrogen with nitrate and nitrite.In these two processes, it is generally acknowledged that the nitrification process is even more important, it is the key that biological process is removed ammonia nitrogen, its difficulty of finishing is also higher relatively.Because most of nitrifiers are chemosynthetic autotroph microorganisms, and compare with the heterotroph microorganism, the autotrophic microorganism proliferative speed is slow, growing environment is harsh, can't get the mastery in the growth competition with the heterotroph microorganism under a lot of conditions.Therefore, when nitrifier content in the water body is low, only regulate environment such as the oxygen supply of sewage and pH value and still can't make the breeding of nitrifier self-sow in the short period of time, in industrial common way is directly to throw in the nitrated bacterial classification of cultured high density in sewage, contains the active sludge of high density nitrifier as input.The nitrated bacterial classification of these high densitys is to cultivate by special operation to obtain, and has all introduced the cultural method of the nitrated bacterial classification of high density that is used for removing the sewage ammonia nitrogen as Chinese patent ZL02156977.0 and Chinese patent application 00808700.8.Introduce nitrated bacterial classification by the external world and can guarantee that really the nitrification process successfully carries out in the short period of time, but operational management is very inconvenient, cost is also higher relatively, and the suitability of this method is not wide in range, just as handling very not suitable for the bigger industrial sewage of quantity discharged.
Summary of the invention
The invention provides a kind of nitrobacteria growth promoter, it can directly drop in the sewage, means such as the oxygen supply of fit adjustment sewage and pH value can be built in water body and are fit to nitrobacteria growth breeding environment, nitrifier is growth and breeding at short notice, removes in the ammonia nitrogen nitrification process need and introduces this technical problem of nitrated bacterial classification by the external world thereby can solve biological process.
Below be the technical scheme that the present invention solves the problems of the technologies described above:
A kind of nitrobacteria growth promoter, this promotor is composition, it is characterized in that the component of said composition comprises molasses, metal-salt and sorbent material, its proportioning is:
Molasses: 100 weight parts;
Metal-salt: 0.2～2.5 weight part;
Sorbent material: 1～8 weight part.
Above-mentioned metal-salt comprises A and B, and wherein A is MnSO
4Or MnCl
2, B is MgSO
4Or CaCl
2Or both mixtures, the mol ratio of A and B is 10: (0.5～5);
Sorbent material is one or more the mixture in zeolite powder, diatomite, Powdered Activated Carbon or the flyash.
Metal-salt is preferably 0.5～1.5 weight part in the said ratio; The mol ratio of A and B is preferably 10: (1.5～3); Sorbent material is preferably 2～5 weight parts.
As everyone knows, nitrifier is relatively responsive to outside atmosphere, and growth and breeding is very high to environment requirement, also needs suitable growth helping matter existence except that aerobic and suitable potential of hydrogen of needs and temperature.Existing result of study shows that dissolved organic carbon (DOC), molecular state organism (POM), this three classes material growth to nitrifier under low consistency conditions of each biostearin have obvious facilitation.Nitrobacteria growth promoter provided by the invention mainly contains three kinds of components, and molasses wherein are main component, and it is rich in dissolved organic matter (DOC), macromolecular substance (POM), VITAMIN.It two is a metal-salt, and its effect is the necessary mineral substance of additional nitration bacteria growing, and participates in nitration reaction as the component of enzyme.The third composition is a sorbent material, and it plays absorption, precipitates ammonia nitrogen, the nitrobacteria growing carrier is provided in the nitration reaction system.
Compared with prior art, advantage of the present invention mainly comprises two aspects.The one, this promotor is adapted at biological process and removes directly to drop in the sewage in the nitrification process of ammonia nitrogen technology and use, make sewage itself produce the environment that is fit to the nitrobacteria growth breeding, nitrifier can breed growth at short notice fast, needn't introduce nitrated bacterial classification by the external world again.Environment such as the temperature of fit adjustment sewage, dissolved oxygen and pH value, the nitrification process can be carried out at short notice smoothly, under the identical situation of other condition, ammonia-N removal rate can improve more than 20% after having used this promotor, has satisfied the processing requirement of industrial biological method removal ammonia nitrogen well; The 2nd, owing to the main composition molasses as promotor are waste materials that sugar industry produces, price is very cheap, so the whole cost of this promotor is very low.From another angle, the comprehensive utilization of the refuse that the present invention also produces for sugar industry provides a new approach.
Below will the invention will be further described by specific embodiment.
Embodiment
[embodiment 1～10]
Each embodiment promotor is prepared in required ratio, and wherein molasses are 100 weight parts, and the proportioning of other component sees Table 1.
Table 1. unit: weight part
| Metal-salt | Sorbent material | |||||
| A | B | A: B (mol ratio) | Content | Title | Content | |
| Embodiment 1 | MnSO 4 | CaCl 2 | 10∶0.5 | 0.2 | Powdered Activated Carbon | 2 |
| Embodiment 2 | MnSO 4 | MgSO 4 | 10∶3 | 2.0 | Diatomite | 1 |
| Embodiment 3 | MnSO 4 | MgSO 4 | 10∶2 | 1.0 | Diatomite | 6 |
| Embodiment 4 | MnSO 4 | MgSO 4/CaCl 2 | 10∶1.5 | 1.5 | Zeolite powder | 4 |
| Embodiment 5 | MnSO 4 | CaCl 2 | 10∶4 | 0.5 | Zeolite powder/diatomite | 3 |
| Embodiment 6 | MnSO 4 | MgSO 4/CaCl 2 | 10∶5 | 2.5 | Zeolite powder/diatomite/Powdered Activated Carbon | 8 |
| Embodiment 7 | MnSO 4 | CaCl 2 | 10∶1.5 | 1.5 | Flyash | 2 |
| Embodiment 8 | MnCl 2 | MgSO 4 | 10∶0.5 | 0.5 | Flyash/zeolite powder | 1 |
| Embodiment 9 | MnCl 2 | MgSO 4/CaCl 2 | 10∶3 | 0.2 | Powdered Activated Carbon/diatomite | 8 |
| Embodiment 10 | MnCl 2 | MgSO 4/CaCl 2 | 10∶5 | 2.5 | Zeolite powder | 4 |
The promotor of the various embodiments described above preparation adopts following method to carry out experimental test:
The sewage of test is the petrochemical complex composite wastewater, and through first precipitation process, the water quality of water inlet is:
COD 357mg/l
NH
3-N 30mg/l
PH value 7.5
Sewage adopts batch activated sludge process (SBR technology) to handle, and reactor volume is 50m
3, the processing condition of operation are:
Flooding quantity 20m
3/ hr
Flooding time 1.5hr
Aeration time 3hr
Sedimentation time 1hr
Water outlet time 0.5hr
Complete cycle required time 6hr
Mud 20d in age
The about 0.3kgBOD of sludge loading
5/ kgSSd
35 ℃ of temperature of reaction
Promoter concentration 20mg/l in the sewage
With the dissolving extremely fully of service water heated and stirred, compound concentration is 0.5～1g/l to above-mentioned promotor, adds with water inlet then earlier.
Experimental test the results are shown in Table 2, adds the water quality of test back water outlet in the table for each embodiment promotor, and wherein comparative example is not for adding promotor, the same embodiment of all the other test conditionss.
Table 2.
| Water outlet COD (mg/l) | COD clearance (%) | Water outlet NH 3-N (mg/l) | NH 3-N clearance (%) | |
| Embodiment 1 | 65.3 | 81.7 | 3.1 | 89.7 |
| Embodiment 2 | 54.6 | 84.7 | 3.0 | 90.0 |
| Embodiment 3 | 53.9 | 84.9 | 3.2 | 89.3 |
| Embodiment 4 | 51 | 85.7 | 2.2 | 92.7 |
| Embodiment 5 | 63.9 | 82.1 | 2.7 | 91.0 |
| Embodiment 6 | 61.4 | 82.8 | 1.8 | 94.0 |
| Embodiment 7 | 69.6 | 80.5 | 2.1 | 93.0 |
| Embodiment 8 | 54.6 | 84.7 | 3.2 | 92.3 |
| Embodiment 9 | 51.8 | 85.5 | 2.3 | 91.0 |
| Embodiment 10 | 62.8 | 82.4 | 2.9 | 90.3 |
| Comparative example | 79.2 | 77.8 | 10.0 | 67.7 |
Claims (4)
1, a kind of nitrobacteria growth promoter, this promotor is composition, it is characterized in that the component of said composition comprises molasses, metal-salt and sorbent material, its proportioning is:
Molasses: 100 weight parts;
Metal-salt: 0.2～2.5 weight part;
Sorbent material: 1～8 weight part,
Above-mentioned metal-salt comprises A and B, and wherein A is MnSO
4Or MnCl
2, B is MgSO
4Or CaCl
2Or both mixtures, the mol ratio of A and B is 10: (0.5～5);
Sorbent material is one or more the mixture in zeolite powder, diatomite, Powdered Activated Carbon or the flyash.
2, nitrobacteria growth promoter according to claim 1 is characterized in that metal-salt is 0.5～1.5 weight part in the described proportioning.
3, nitrobacteria growth promoter according to claim 1 is characterized in that the mol ratio of A and B is 10 in the described proportioning: (1.5～3).
4, nitrobacteria growth promoter according to claim 1 is characterized in that sorbent material is 2～5 weight parts in the described proportioning.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101118779A CN100445367C (en) | 2005-12-22 | 2005-12-22 | Nitrobacteria growth promoter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101118779A CN100445367C (en) | 2005-12-22 | 2005-12-22 | Nitrobacteria growth promoter |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1986446A true CN1986446A (en) | 2007-06-27 |
| CN100445367C CN100445367C (en) | 2008-12-24 |
Family
ID=38183407
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|---|---|---|---|
| CNB2005101118779A Active CN100445367C (en) | 2005-12-22 | 2005-12-22 | Nitrobacteria growth promoter |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352318A (en) * | 2011-10-24 | 2012-02-15 | 沈阳建筑大学 | Fluid nutrient medium for promoting growth of halophilic nitrite oxidizing bacteria |
| CN105624087A (en) * | 2014-10-28 | 2016-06-01 | 中国石油化工股份有限公司 | Promoter for culturing nitrifying bacteria and preparation method of promoter |
| CN105621625A (en) * | 2014-10-28 | 2016-06-01 | 中国石油化工股份有限公司 | Nitrite bacteria growth promoter and preparation method thereof |
| CN109943516A (en) * | 2017-12-21 | 2019-06-28 | 中国石油化工股份有限公司 | Complete microorganism growth composition and its application of nitrifying process |
| CN114807001A (en) * | 2021-06-08 | 2022-07-29 | 上海未来企业股份有限公司 | Promoter beneficial to rapid propagation of nitrobacteria and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5239961A (en) * | 1975-09-24 | 1977-03-28 | Shinko Fuaudoraa Kk | Nitrating method using absorbent |
| US4790940A (en) * | 1986-11-26 | 1988-12-13 | Radian Corporation | Process for wastewater treatment |
| KR20020012210A (en) * | 1999-06-10 | 2002-02-15 | 가부시키가이샤 바이코무 | Method of high-concentration culture of nitrifying bacteria or denitrifying bactetia contained in activated sludge, culture promoter to be used in high-concentration culture method of nitrifying bacteria, and method of weight loss treatment of activated sludge |
| JP2002176972A (en) * | 2000-12-13 | 2002-06-25 | Bicom:Kk | High-concentration nitrite-oxidizing bacterium, and method for high-concentration culture of nitrite- oxidizing bacterium |
| CN1210395C (en) * | 2003-02-14 | 2005-07-13 | 中国科学院南京土壤研究所 | Heterotrophic nitrobacteri, culturing method and application thereof |
-
2005
- 2005-12-22 CN CNB2005101118779A patent/CN100445367C/en active Active
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352318A (en) * | 2011-10-24 | 2012-02-15 | 沈阳建筑大学 | Fluid nutrient medium for promoting growth of halophilic nitrite oxidizing bacteria |
| CN105624087A (en) * | 2014-10-28 | 2016-06-01 | 中国石油化工股份有限公司 | Promoter for culturing nitrifying bacteria and preparation method of promoter |
| CN105621625A (en) * | 2014-10-28 | 2016-06-01 | 中国石油化工股份有限公司 | Nitrite bacteria growth promoter and preparation method thereof |
| CN105621625B (en) * | 2014-10-28 | 2018-03-16 | 中国石油化工股份有限公司 | A kind of nitrite bacteria growth promoter and preparation method thereof |
| CN105624087B (en) * | 2014-10-28 | 2019-12-10 | 中国石油化工股份有限公司 | Promoter for culturing nitrifying bacteria and preparation method thereof |
| CN109943516A (en) * | 2017-12-21 | 2019-06-28 | 中国石油化工股份有限公司 | Complete microorganism growth composition and its application of nitrifying process |
| CN109943516B (en) * | 2017-12-21 | 2021-08-31 | 中国石油化工股份有限公司 | Microbial growth composition for completing nitration process and application thereof |
| CN114807001A (en) * | 2021-06-08 | 2022-07-29 | 上海未来企业股份有限公司 | Promoter beneficial to rapid propagation of nitrobacteria and preparation method thereof |
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| CN100445367C (en) | 2008-12-24 |
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