CN100445366C

CN100445366C - Nitrobacteria culture promoter

Info

Publication number: CN100445366C
Application number: CNB2005101118764A
Authority: CN
Inventors: 吴敏; 仓一华; 祝娟芝; 杨玉梅
Original assignee: Sinopec Shanghai Petrochemical Co Ltd
Current assignee: Sinopec Shanghai Petrochemical Co Ltd
Priority date: 2005-12-22
Filing date: 2005-12-22
Publication date: 2008-12-24
Anticipated expiration: 2025-12-22
Also published as: CN1986445A

Abstract

The nitrobacteria culture promoter consists of molasses 100 weight portions, manganese salt 0.2-3.0 weight portions and adsorbent 1-8 weight portions. The manganese salt includes is sulfate or hydrochloride. The adsorbent is zeolite powder, diatomite, powdered active carbon, fly ash or their mixture. The nitrobacteria culture promoter is used in biological nitrification process of eliminating ammonia nitrogen and thrown into sewage directly to promote the propagation and growth of nitrobacteria in sewage. Through combination with sewage temperature regulation, dissolving oxygen, regulating pH, etc, the nitrification may be completed in short period. It has raised ammonia nitrogen eliminating rate and low cost.

Description

Nitrobacteria culture promoter

Technical field

The present invention relates to a kind of nitrobacteria culture promoter that biological process is removed the sewage ammonia nitrogen that is used for.

Background technology

Ammonia nitrogen is the bigger pollution factor of harm in the water body, and it can cause the eutrophication in river, lake, and water body self-purification ability is weakened.The ammonia nitrogen of polluted-water is often referred to the nitrogen that exists with the ammonia form, and the difficulty of ammonia nitrogen removal is much bigger in the contaminated water body of other organic pollutant relatively.In the prior art, the removal method of ammonia nitrogen mainly contains physics, chemistry and biological method in the contaminated water body.Physics or chemical method comprise air stripping method, break point chlorination, ion exchange adsorption, flocculent precipitation, electroosmose process, catalytic wet air oxidation, liquid-film method etc.These methods generally are used for the pre-treatment of high-concentration ammonia nitrogenous wastewater, and processing cost is very high.Biological process removal ammonia nitrogen is the effect by certain micro-organisms, thereby makes the ammonia nitrogen in the contaminated water body finally form the purpose that nitrogen effusion water body reaches purifying treatment.The biological process cost is much lower, and its applicable surface is also wider, as the removal of ammonia nitrogen in ammonia nitrogen purifying treatment, sanitary wastewater or the trade effluent of fishery cultivating water body etc.

Biological process is removed ammonia nitrogen and is mainly comprised nitrification process and denitrification process.In the nitrification process, in being oxidized to nitrate or nitrite nitrogen under the effect of ammonia nitrogen nitrifier under the aerobic condition; Denitrification is meant that nitrate and nitrite are reduced to the process of gaseous nitrogen.Under anoxia condition, utilize organism as electron donor, denitrifying bacterium is reduced to nitrogen with nitrate and nitrite.In these two processes, it is generally acknowledged that the nitrification process is even more important, it is the key that biological process is removed ammonia nitrogen, its difficulty of finishing is also higher relatively.Because most of nitrifiers are chemosynthetic autotroph microorganisms, and compare with the heterotroph microorganism, the autotrophic microorganism proliferative speed is slow, growing environment is harsh, can't get the mastery in the growth competition with the heterotroph microorganism under a lot of conditions.Therefore, when nitrifier content in the water body is low, only regulate environment such as the oxygen supply of sewage and pH value and still can't make the breeding of nitrifier self-sow in the short period of time, in industrial common way is directly to throw in the nitrated bacterial classification of cultured high density in sewage, contains the active sludge of high density nitrifier as input.The nitrated bacterial classification of these high densitys is to cultivate by special operation to obtain, and has all introduced the cultural method of the nitrated bacterial classification of high density that is used for removing the sewage ammonia nitrogen as Chinese patent ZL02156977.0 and Chinese patent application 00808700.8.Introduce nitrated bacterial classification by the external world and can guarantee that really the nitrification process successfully carries out in the short period of time, but operational management is very inconvenient, cost is also higher relatively, and the suitability of this method is not wide in range, just as handling very not suitable for the bigger industrial sewage of quantity discharged.

Summary of the invention

The invention provides a kind of nitrobacteria culture promoter, it can directly drop in the sewage, means such as the oxygen supply of fit adjustment sewage and pH value can be built in water body and are fit to nitrobacteria growth breeding environment, nitrifier is growth and breeding at short notice, removes in the ammonia nitrogen nitrification process need and introduces this technical problem of nitrated bacterial classification by the external world thereby can solve biological process.

Below be the technical scheme that the present invention solves the problems of the technologies described above:

A kind of nitrobacteria culture promoter, this promotor are composition.Component comprises molasses, manganese salt and sorbent material, and its proportioning is:

Molasses: 100 weight parts;

Manganese salt: 0.2～3.0 weight part;

Sorbent material: 1～8 weight part.

Above-mentioned manganese salt is vitriol or hydrochloride, and sorbent material is one or more the mixture in zeolite powder, diatomite, Powdered Activated Carbon or the flyash.

Manganese salt is preferably 0.8～2.5 weight part in the said ratio; Sorbent material is preferably 2～6 weight parts.

As everyone knows, nitrifier is relatively responsive to outside atmosphere, and growth and breeding is very high to environment requirement, also needs suitable cultivation and promote the material existence except that aerobic and suitable potential of hydrogen of needs and temperature.Existing result of study shows that dissolved organic carbon (DOC), molecular state organism (POM), this three classes material cultivation to nitrifier under low consistency conditions of each biostearin have obvious facilitation.Nitrobacteria culture promoter provided by the invention mainly contains three kinds of components, and molasses wherein are main component, and it is rich in dissolved organic matter (DOC), macromolecular substance (POM), VITAMIN.It two is a manganese salt, and its effect is the necessary mineral substance of additional nitration bacteria growing, and participates in nitration reaction as the component of enzyme.The third composition is a sorbent material, and it plays absorption, precipitates ammonia nitrogen, the nitrobacteria growing carrier is provided in the nitration reaction system.

Compared with prior art, advantage of the present invention mainly comprises two aspects.The one, this promotor is adapted at biological process and removes directly to drop in the sewage in the nitrification process of ammonia nitrogen technology and use, make sewage itself produce the environment that is fit to the nitrobacteria growth breeding, nitrifier can breed growth at short notice fast, needn't introduce nitrated bacterial classification by the external world again.Environment such as the temperature of fit adjustment sewage, dissolved oxygen and pH value, the nitrification process can be carried out at short notice smoothly, under the identical situation of other condition, ammonia-N removal rate can improve more than 20% after having used this promotor, has satisfied the processing requirement of industrial biological method removal ammonia nitrogen well; The 2nd, owing to the main composition molasses as promotor are waste materials that sugar industry produces, price is very cheap, so the whole cost of this promotor is very low.From another angle, the comprehensive utilization of the refuse that the present invention also produces for sugar industry provides a new approach.

Below will the invention will be further described by specific embodiment.

Embodiment

[embodiment 1～10]

Each embodiment promotor is prepared in required ratio, and wherein molasses are 100 weight parts, and the proportioning of other component sees Table 1.

Table 1. unit: weight part

The promotor of the various embodiments described above preparation adopts following method to carry out experimental test:

The sewage of test is the petrochemical complex composite wastewater, and through first precipitation process, the water quality of water inlet is:

COD 326mg/l

NH ₃-N 28mg/l

PH value 7.5

Sewage adopts batch activated sludge process (SBR technology) to handle, and reactor volume is 50m ³, the processing condition of operation are:

Flooding quantity 20m ³/ hr

Flooding time 1.5hr

Aeration time 3hr

Sedimentation time 1hr

Water outlet time 0.5hr

Complete cycle required time 6hr

Mud 20d in age

The about 0.3kgBOD of sludge loading ₅/ kgSSd

35 ℃ of temperature of reaction

Promoter concentration 20mg/l in the sewage

With the dissolving extremely fully of service water heated and stirred, compound concentration is 0.5～1g/l to above-mentioned promotor, adds with water inlet then earlier.

Experimental test the results are shown in Table 2, adds the water quality of test back water outlet in the table for each embodiment promotor, and wherein comparative example is not for adding promotor, the same embodiment of all the other test conditionss.

Table 2.

	Water outlet COD (mg/l)	COD clearance (%)	Water outlet NH ₃-N (mg/l)	NH ₃-N clearance (%)
	Water outlet COD (mg/l)	COD clearance (%)	Water outlet NH ₃-N (mg/l)	NH ₃-N clearance (%)	Embodiment 1	65.5	79.9	4.3	84.6
Embodiment 2	56.7	82.6	3.7	86.7	Embodiment 1	65.5	79.9	4.3	84.6
Embodiment 2	56.7	82.6	3.7	86.7	Embodiment 3	52.8	83.8	2.6	90.7
Embodiment 4	55.7	82.9	2.9	89.6	Embodiment 3	52.8	83.8	2.6	90.7
Embodiment 4	55.7	82.9	2.9	89.6	Embodiment 5	70.7	78.3	2.8	90.0
Embodiment 6	71.4	78.1	3.8	86.4	Embodiment 5	70.7	78.3	2.8	90.0
Embodiment 6	71.4	78.1	3.8	86.4	Embodiment 7	70.3	78.4	2.7	90.1
Embodiment 8	68.4	79.0	3.1	88.7	Embodiment 7	70.3	78.4	2.7	90.1
Embodiment 8	68.4	79.0	3.1	88.7	Embodiment 9	54.8	83.2	2.7	90.4
Embodiment 10	69.5	78.7	3.5	87.4	Embodiment 9	54.8	83.2	2.7	90.4
Embodiment 10	69.5	78.7	3.5	87.4	Comparative example	74.1	77.3	9.5	66.2

Claims

1, a kind of nitrobacteria culture promoter, this promotor is composition, it is characterized in that the component of said composition comprises molasses, manganese salt and sorbent material, its proportioning is:

Molasses: 100 weight parts;

Manganese salt: 0.2～3.0 weight part;

Sorbent material: 1～8 weight part,

2, nitrobacteria culture promoter according to claim 1 is characterized in that manganese salt is 0.8～2.5 weight part in the described proportioning.

3, nitrobacteria culture promoter according to claim 1 is characterized in that sorbent material is 2～6 weight parts in the described proportioning.