CN1980628B

CN1980628B - Liquid ester composition and cosmetic preparation containing the same

Info

Publication number: CN1980628B
Application number: CN2005800223121A
Authority: CN
Inventors: 江原多朗
Original assignee: Nisshin Oillio Ltd
Current assignee: Nisshin Oillio Group Ltd
Priority date: 2004-06-30
Filing date: 2005-06-30
Publication date: 2010-05-05
Anticipated expiration: 2025-06-30
Also published as: US20070110702A1; EP1782789A4; KR101259529B1; WO2006003992A1; EP1782789A1; EP1782789B1; JP4834548B2; CN1980628A; US7550623B2; JPWO2006003992A1; KR20070029759A

Abstract

A liquid ester composition obtained by esterifying dipentaerythritol with a branched isostearic acid, e.g., 2-(1,3,3-trimethyl)butyl-5,7,7-trimethyloctoic acid, the composition having a viscosity at 25 DEG C of 100,000-2,000,000 mPas, a hydroxy value of 10-160, and a cloud point lower than 5 DEG C. Like the polybutene used as one of the oil materials for cosmetic preparations, this liquid ester composition enables a cosmetic film to give a lasting filmy feeling and improves the gloss and moist feeling of a cosmetic preparation, the shape retention of a lipstick, etc., and other properties. In addition, the composition has the ability to disperse pigments and the ability to contain water unlike the polybutene.

Description

Liquid ester composition and the cosmetic material that contains it

Technical field

The lasting agent of cosmetic overlay film that the present invention relates in cosmetics such as cosmetic, skin protection and hair products material, to can be used as the liquid ester composition of raw material use and contain the cosmetic material of this liquid ester composition and contain this liquid ester composition.

Background technology

At present,, particularly improve film sense, gloss, the moist feeling of cosmetic film, use the hydrocarbon liquids oil of high viscosities such as wax and polybutene all the time in order to improve the usability of make up material, skin composition etc.Because polybutene is being very excellent raw material aspect the film sense that improves the cosmetic film, the gloss, and film sense persistence is also high, so be widely used (patent documentation 1,2,3) in cosmetic is made up material.

But when increasing the combined amount of the polybutene in the material of making up for further improving film sense persistence, the sense of being clamminess smartens, can not be satisfactory.In addition, polybutene is nonpolar liquid oil, so the moisture hold facility is very low, and when being mixed in make up material or the skin composition, diaphoresis such as skin cause taking place to make up damaging, and cosmetic persistency aspect is unsatisfactory.

Reported as the cosmetic material raw material of usability excellences such as film sense, dense sense, developed use 2-(1,3, the 3-trimethyl) butyl-5,7, the sad isostearic acid polyglycerin ester of 7-trimethyl (patent documentation 4) as fatty acid.Yet the isostearic acid polyglycerin ester is because the peak of its viscosity is 35000mPas, so requiring for function such as the persistence that further improves pigment-dispersing and cosmetic film to use under the situation of the high-viscosity material more than 100,000 mPas and can't use.

In addition, developed the oil preparation (patent documentation 5) that contains the carboxylate that constitutes by highly branched chain type fatty acid and alcohol.Yet in the document, the peak of the viscosity of gained carboxylate is 30,000 mPas (30000mPas), and the manufacture method according to wherein putting down in writing can obtain the high product of cloud point, and the quality aspect can't be met.

And then in patent documentation 6,2-(1,3, the 3-trimethyl) butyl-5,7, the 7-trimethyl is sad as drug effect agent a kind of composition in the percutaneous external agent that absorbs or absorbed by horny layer and being used effectively, but the ester composition that obtains carrying out esterification with alcohol does not carry out any research as yet.

Patent documentation 1: Japanese kokai publication hei 9-151111 communique

Patent documentation 2: TOHKEMY 2002-3340 communique

Patent documentation 3: TOHKEMY 2002-316910 communique

Patent documentation 4: TOHKEMY 2003-113025 communique

Patent documentation 5:WO03/055451A1 communique

Patent documentation 6: Japanese communique spy opens flat 2-207018 communique

Summary of the invention

The object of the present invention is to provide a kind of liquid ester composition, it is as the polybutene of using one of oil preparation raw material as the material of making up, the film sense of cosmetic film is continued, improve the make up gloss of material and the shape retention of moist feeling, raising lipstick etc. etc., and have not available pigment-dispersing energy of polybutene and moisture performance.

Further aim of the present invention is to provide the cosmetic that contains the aforesaid liquid ester composition material, particularly cosmetic (make up) cosmetic material.

The further purpose of the present invention is to provide the cosmetic overlay film that contains the aforesaid liquid ester composition to continue agent.

The inventor etc. further further investigate discovery to the invention that patent documentation 5 is put down in writing, when specific branched chain type isostearic acid and the long-time reaction of dipentaerythritol are carried out esterification, when adding the operation of removing lower-molecular substance, can obtain the viscosity height, hydroxyl value is specific value, and the carboxylate that the cloud point less than is 5 ℃, this carboxylate, the persistence excellence of its cosmetic overlay film, have gloss and moist feeling with the cosmetic overlay film that normally used polybutene compared favourably in the material of making up in the past, and have the not available pigment-dispersing of polybutene can and moisture performance, based on such opinion, finished the present invention.

That is, the invention provides a kind of liquid ester composition, it is characterized in that, it carries out the liquid ester composition that esterification obtains for branched chain type isostearic acid and the dipentaerythritol shown in the following general formula (I), its viscosity under 25 ℃ is 100,000～2,000,000 mPas, and hydroxyl value is 10～160,5 ℃ of cloud point less thaies.

(in the formula, R represents that carbon number is 7 branched hydrocarbyl.)

Here, preferred acid number is below 10.

In addition, the branched chain type isostearic acid is preferably 2-(1,3, the 3-trimethyl) butyl-5,7, and the 7-trimethyl is sad.

The present invention also provides a kind of cosmetic material, it is characterized in that, contains the aforesaid liquid ester composition.

Here, described cosmetic material is preferably and is selected from make up a kind of in the material of cosmetic cosmetic material, emulsion, facial cream, sunscreen and Hair grooming.

The present invention also provides a kind of cosmetic cosmetic material, it is characterized in that, contains aforesaid liquid ester composition and oil-base gel agent.

The present invention also provides a kind of cosmetic overlay film to continue agent, it is characterized in that, contains the aforesaid liquid ester composition.

The specific embodiment

At first, describe at liquid ester composition of the present invention.

The branched chain type isostearic acid that uses among the present invention with above-mentioned general formula (I) expression, in the formula, is 7 branched hydrocarbyl as the represented carbon number of R, is preferably branched alkyl, and preferred end is a tertiary alkyl.Preferred especially end is the tert-butyl group.Particularly, preferred 4,4-dimethyl amyl group, 1,3,3-trimethyl butyl and 2,3,3-trimethyl butyl.Wherein, preferred especially 1,3,3-trimethyl butyl.Specifically can enumerate 2-(1,3, the 3-trimethyl) butyl-5,7, the 7-trimethyl is sad etc.As the branched chain type isostearic acid, can use commercially available product, for example can enumerate the commodity isostearic acid that daily output chemical industry (strain) is made.

The dipentaerythritol that uses among the present invention can use commercially available product, for example can enumerate the commodity dipentaerythritol of wide flourish chemical industry (strain) manufacturing, the commodity dipentaerythritol that Perstorp Co. makes etc.

Liquid ester composition of the present invention is the two or more mixture in monoesters, diester, three esters, four esters, five-ester and six esters that are selected from dipentaerythritol.

The viscosity of liquid ester composition of the present invention under 25 ℃ is 100,000～2,000,000 mPas, is preferably 110,000～1,000,000 mPas, most preferably is 150,000～600,000 mPas.This is because when viscosity during in this scope, form the cosmetic film high to the tack of skin when being used to make up material, makes the sense of cosmetic film lasting, can obtain gratifying cosmetic material aspect the cosmetic persistency.In addition, the lasting sense that can form coating excellence, the film of making up, and cosmetic overlay film uniformly is excellent, and is satisfactory aspect the cosmetic persistency, satisfactory aspect usability and gloss.

The viscosity of liquid ester composition of the present invention can be measured by material raw material benchmark ordinary test method viscosimetry the 2nd method (Brookfield viscometer (BH type)) of making up.

The hydroxyl value of liquid ester composition of the present invention is 10～160, is preferably 20～140, most preferably is 25～95.Hydroxyl value is when this scope, and the cosmetic film continues sense and moist feeling excellence, can not cause that the cosmetic floats, and can obtain gratifying cosmetic material aspect the cosmetic persistency.And then coating is also excellent, can not increase the sense of being clamminess during coating, also can not produce transparency reduction or solid constituent and separate out, and can be met the cosmetic material of ageing stability.

The mensuration of hydroxyl value can be undertaken by the material raw material benchmark ordinary test method hydroxy value measuring method of making up.

Liquid ester composition of the present invention, 5 ℃ of its cloud point less thaies are preferably below 0 ℃, more preferably-20 ℃ below.Cloud point can be kept the product appearance beauty under the low temperature aspect transparent when this scope, so preferred.

The mensuration of cloud point can be undertaken by the material raw material benchmark ordinary test method cloud point algoscopy of making up.

Liquid ester composition of the present invention, its acid number is preferably below 10, more preferably below 5, most preferably is 0～1.Acid number is when this scope, and little to the stimulation of skin, storage stability is good, and can suppress to be clamminess sense aspect sense of touch, so preferred.

The mensuration of acid number can be undertaken by the material raw material benchmark ordinary test method acid value measuring method of making up.

Below, the manufacture method of liquid ester composition of the present invention is described.

Liquid ester composition of the present invention can carry out esterification by branched chain type isostearic acid shown in the above-mentioned general formula (I) and dipentaerythritol and make.

The words that further describe, for example, with 10: 35～10: 90 mass ratio pack into dipentaerythritol and 2-(1,3, the 3-trimethyl) butyl-5,7, the 7-trimethyl is sad, (for example, 0.02～0.5% Dibutyltin oxide of total charge under) the existence, carry out 10～40 hours (being preferably 20～40 hours) esterifications in proper catalyst in 200～250 ℃.Preferably after reaction finishes, the gained reactant is carried out adsorption treatment etc. and carries out catalyst and remove processing, be cooled to below 70 ℃ after (for example 50～60 ℃), remove low molecular compositions such as unreacted raw material by filtration, distillation etc., make with this.

The raw material charging mass ratio (dipentaerythritol: the value of branched chain type isostearic acid) be preferably 10: 35～10: 90, more preferably 10: 39～10: 72, most preferably be 10: 48～10: 70 of dipentaerythritol and branched chain type isostearic acid.

Below, the cosmetic material that contains liquid ester composition of the present invention is described.

The content of liquid ester composition in the material of making up is preferably 0.1～90 quality %, and more preferably 0.5～80, most preferably be 10～80 quality %.

There is no particular limitation to contain the cosmetic material of liquid ester composition of the present invention, for example can enumerate cosmetic cosmetic material, emulsion, facial cream, sunscreen and the Hair grooming material etc. of making up.Owing to especially require functions such as the film sense of cosmetic overlay film continues, gloss, pigment-dispersing energy, moisture performance, heat-insulating property, be effective therefore to cosmetic cosmetic material, emulsion, facial cream, sunscreen and the suitable of Hair grooming cosmetic material.

Here, cosmetic is made up and is expected to be meant lipstick, lip gloss, lip gloss, foundation cream, rouge, eye coloured silk, eye shadow, informer, mascara, nial polish.In addition, Hair grooming makes up that material is meant suppurative mastitis, becomes visible, moulding mousse, hair styling gel having, moulding pomade.

The cosmetic material that contains liquid ester composition of the present invention in the scope of not damaging effect of the present invention, can mix usually the various compositions that use as required and pass through conventional method manufacturing objective product in the material of making up etc.

For example, can be as required suitable mixed anion surfactant, cationic surfactant, amphoteric surfactant, the lipophile non-ionic surface active agent, hydrophilic non-ionic surfactant, the natural series surfactant, liquid fat, solid grease, the wax class, hydrocarbon ils, higher fatty acids, higher alcohol, ester oil, silicone oil, powder, wetting agent, water-soluble macromolecule, semi-synthetic water soluble polymer, the synthesizing water-solubility macromolecule, inorganic water soluble polymer, thickening agent, UV absorbent, sequestering agent, lower alcohol, polyhydric alcohol, monosaccharide, oligosaccharide, polysaccharide, aminoacid, organic amine, synthetic resin emulsion, the pH regulator agent, vitamins, antioxidant, the antioxidation auxiliary agent, spice and water etc.

As anion surfactant; for example can enumerate the soap raw material; sodium laurate; fatty acid soaps such as sodium palmitate; sodium lauryl sulfate; senior alkyl sulfate salt such as lauryl potassium sulfate; the POE-triethanolamine lauryl sulfate; alkyl ether sulphate salts such as POE-sodium lauryl sulfate; N-acyl group sarcosine such as sodium lauroyl sarcosine; N-myristoyl-N methyl taurine sodium; coco-nut oil fatty acid N-methyltaurine sodium; senior fatty acid amide sulfonates such as lauryl methyl sodium taurocholate; POE-oleyl ether phosphoric acid sodium; phosphate ester salts such as POE-stearoyl ether phosphoric acid; two-2-ethylhexyl sodium sulfosuccinate; single lauroyl single ethanol amide polyoxyethylene sodium sulfosuccinate; sulfosuccinates such as lauryl polypropylene glycol sodium sulfosuccinate; linear alkyl benzene sulphonate; straight chain DBSA triethanolamine; alkylbenzenesulfonates such as straight chain DBSA; N-lauroyl glutamate list sodium; N-stearyl disodium glutamate; N-myristoyl-N-acyl glutamates such as L-monosodium glutamate; senior fatty acid ester sulfuric acids such as sclerosis coco-nut oil fatty acid glycerol sodium sulfate; Turkey red wet goods sulfated oil, the POE-alkyl ether carboxylic acid; POE-alkyl allyl ether carboxylate; alpha-alkene sulfonate; the higher fatty acids sulfonated ester; the secondary alcohol sulfuric acid; higher fatty acids alkylolamides sulfuric acid; lauroyl single ethanol amide sodium succinate; in N-palmityl aspartic acid two triethanolamine and the casein sidium etc. more than a kind or 2 kinds.

As cationic surfactant, for example can enumerate the stearyl trimethyl ammonium chloride, alkyl trimethyl ammonium salts such as lauryl trimethyl ammonium chloride, the VARISOFT TA100 dialkyl dimethyl ammonium salt, chlorination gathers (N, N '-dimethyl-3, the 5-methylenepiperidines), Fixanols such as cetylpyridinium chloride, alkyl quaternary ammonium salts, alkyl dimethyl benzyl ammonium salt, alkyl isoquinolinium salt, the dialkyl group alkylbenzyldimethylasaltsum saltsum, the POE-alkylamine, alkylamine salt, the polyamine derivative of fatty acid, the amylalcohol derivative of fatty acid, in benzalkonium chloride and the benzethonium chloride etc. more than a kind or 2 kinds.

As amphoteric surfactant, for example can enumerate 2-undecyl-N, N, N-(hydroxyethyl-carboxymethyl)-2-imidazoline sodium, 2-cocoyl-2-imidazoline hydroxide-imidazolines such as 1-carboxylic ethyoxyl disodium salt are amphoteric surfactant, betanins such as 2-heptadecyl-N-carboxymethyl-N-hydroxyethyl imidazole quinoline betanin, lauryl dimethyl glycine betanin, alkyl betaine, amido betaine and sulfobetaines be in amphoteric surfactant etc. more than a kind or 2 kinds.

As the lipophile non-ionic surface active agent, for example can enumerate dehydrated sorbitol mono-fatty acid ester, sorbitan list isostearate, sorbitan monolaurate, the sorbitan monopalmitate, sorbitan monostearate, NOFABLE SO-992 NOFABLE SO-902, sorbitan trioleate, five-2 ethyl hexanoic acid, two dehydrating glycerin sorbitol esters, sorbitan fatty acid esters classes such as four-2 ethyl hexanoic acid, two dehydrating glycerin sorbitol esters, single cottonseed oil fatty acid glyceride, single erucic acid glyceride, the sesquialter olein, glyceryl monostearate, α, α '-oleic acid pyroglutamic acid glyceride, fatty acid glycerine esters such as glyceryl monostearate, single isostearic acid two glyceride, polyglyceryl fatty acid esters such as two isostearic acids, two glyceride, methyl glycol fatty acid ester classes such as propylene glycolmonostearate, in hardened castor oil derivant and the glycerol alkyl ether etc. more than a kind or 2 kinds.

As hydrophilic non-ionic surfactant, for example can enumerate the POE-dehydrated sorbitol mono-fatty acid ester, the POE-sorbitan monostearate, the POE-dehydrated sorbitol mono-fatty acid ester, POE-sorbitan fatty acid esters classes such as POE-sorbitan four oleates, POE-is sorbityl monododecanoate, the POE-sorbitol monooleate, POE-Sorbitol five oleates, POE-Sorbitol fatty acid esters such as POE-Sorbitol monostearate, the POE-glyceryl monostearate, POE-glycerol list isostearate, POE-glycerine fatty acid esters such as POE-glycerol three isostearates, the POE-monoleate, the POE-distearate, the single dioleate of POE-, POE-fatty acid esters such as diglycol stearate, the POE-lauryl ether, POE-oleyl ether, POE-stearoyl ether, POE-Shan Yu acyl ether, POE-2-octyl group lauryl ether, POE-alkyl ethers such as POE-cholestane alcohol ether, Pluronic Pluronic type classes such as (addition polymers of polypropylene glycol and oxirane), the POEPOP-cetyl ether, POEPOP-2-decyl ether in four last of the ten Heavenly stems, the POEPOP-monobutyl ether, the POEPOP-hydrogenated lanolin, POEPOP-alkyl ethers such as POEPOP-glycerin ether, テトロニッ Network four POE, four POP-ethylenediamine condensation substance classes such as (Tetronic), the POE-Oleum Ricini, the POE-hardened castor oil, POE-hardened castor oil list isostearate, POE-hardened castor oil three isostearates, POE-hardened castor oil list pyroglutamic acid list isostearic acid diester, POE-Oleum Ricini hardened castor oil derivants such as POE-hardened castor oil maleic acid, POE-Cera Flava lanolin derivatives such as POE-Sorbitol Cera Flava, cocoanut fatty acid diethanolamide, lauric monoethanolamide, alkanolamides such as fatty acid isopropanol amide, the POE-methyl glycol fatty acid ester, the POE-alkylamine, the POE-fatty acid amide, sucrose fatty acid ester, POE-nonyl phenyl formaldehyde condensation products, in alkyl ethoxy dimethyl oxidation amine and the three oleyl phosphoric acid etc. more than a kind or 2 kinds.

As the natural series surfactant, for example can enumerate in lecithin classes such as soybean phospholipid, hydrogenated soya phosphatide, lecithin, hydrogenation lecithin or soybean soapstock chitin etc. more than a kind or 2 kinds.

As liquid fat, for example can enumerate in American Avocado Tree oil, Camellia oil, Oleum Trionyx sinensis Wiegmann, macadimia nut oil, Semen Maydis oil, Oleum helianthi, ermine oil, olive oil, Oleum Brassicae campestris, egg oil, Oleum sesami, almond oil, Semen Tritici aestivi germ oil, Flos Camelliae Japonicae caul-fat, Oleum Ricini, Semen Lini oil, safflower oil, Oleum Vitis viniferae, Oleum Gossypii semen, perilla oil, soybean oil, Oleum Arachidis hypogaeae semen, Oleum Camelliae, Oleum Cocois, Testa oryzae oil, Paulownia oil, Japanese tung oil, Jojoba oil, germ oil, Radix Oenotherae erythrosepalae oil, tricaprylin and the three different tripalmitins etc. more than a kind or 2 kinds.In addition, the liquid fat here refers to be under the room temperature oils and fats of liquid.

As solid grease, for example can enumerate in cocoa butter, Oleum Cocois, Adeps Bovis seu Bubali, Adeps caprae seu ovis, horse fat, palm-kernel oil, leaf fat, Os Bovis seu Bubali fat, vegetable wax oil, cattle foot fat, vegetable wax, sclerosis Oleum Cocois, hardened palm oil, sclerosis Adeps Bovis seu Bubali, fixed oil and the hardened castor oil etc. more than a kind or 2 kinds.

As the wax class, for example can enumerate in Cera Flava, candelilla wax, cotton wax, palm wax, bayberry wax, insect wax, spermaceti, montan wax, rice bran wax, kapok wax, sugarcane wax, lanoline, acetic acid lanoline, liquid lanolin, lanolin fatty acid isopropyl ester, reduction lanoline, hard lanoline, lauric acid hexyl ester, Simmondsia chinensis wax, shellac wax, POE lanoline alcohol ether, POE lanolin alcohol acetas, POE cholesterol ethers, lanolin fatty acid Polyethylene Glycol and the POE hydrogenated lanolin alcohol ether etc. more than a kind or 2 kinds.

As hydrocarbon ils, for example can enumerate in liquid paraffin, isoparaffin, heavy liquid isoparaffin, paraffin hydrocarbon, ceresine, squalane, vegetalitas squalane, pristane, ceresin, Squalene, vaseline, microwax, paraffin, montan wax, olefin oligomer, polyisobutylene, polybutene and the hydrogenated polybutene etc. more than a kind or 2 kinds.

As higher fatty acids, for example can enumerate in lauric acid, myristic acid, Palmic acid, stearic acid, behenic acid (Behenic acid), oleic acid, 9-undecylenic acid, talloleic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA) and the docosahexenoic acid (DHA) etc. more than a kind or 2 kinds.

As higher alcohol, for example can enumerate straight chain alcohols such as lauryl alcohol, spermol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, 16 stearyl alcohols, in the branched-chain alcohos such as single stearyl glycerin ether (batilol), 2-decyl tetradecanol, lanolin alcohol, cholesterol, plant sterol, hexyl dodecanol, isooctadecanol and octyldodecanol etc. more than a kind or 2 kinds.

As ester oil, for example can enumerate isopropyl myristate; the isooctyl acid cetyl; myristic acid octyl group dodecane ester; isopropyl palmitate; iso-octyl palmitate; butyl stearate; lauric acid hexyl ester; myristyl myristate; decyl oleate; the sad hexyl of dimethyl ester in the last of the ten Heavenly stems; the lactic acid cetyl; Tetradecyl lactate; lactic acid octyl group dodecane ester; the acetic acid lanoline; Standamul 7061; the different cetyl of isostearic acid; 12-hydroxy stearic acid cholesteryl ester; 12-hydroxy stearic acid plant sterol ester; the oleic acid plant sterol ester; two-2 ethyl hexanoic acid glycol ester; the didecyl acid propylene glycol ester; the dipentaerythritol fatty acid ester; single isostearic acid N-alkyl diol ester; two capric acid DOPCP; malic acid two different stearyl esters; two-2-heptyl hendecanoic acid glyceride; trimethylolpropane tris-2-ethylhexanoate; the trimethylolpropane tris isostearate; four-2 ethyl hexanoic acid pentaerythritol ester; three-2 ethyl hexanoic acid glyceride; three (capryl capric acid) glyceride; three (capryl decanoin myristin stearic acid) glyceride; the trimethylolpropane tris isostearate; the 2 ethyl hexanoic acid cetyl; Palmic acid 2-Octyl Nitrite; myristin; three-2-heptyl hendecanoic acid glyceride; two isostearic acid polyglycerin ester; three isostearic acid polyglycerin ester; four isostearic acid polyglycerin ester; three isostearic acids, two glyceride; four isostearic acids, two glyceride; three 2 ethyl hexanoic acid erithritol esters; two trimethylolpropane tris-2-ethylhexanoate; (isostearic acid/decanedioic acid) two trimethylolpropane oligoesters; the Castor Oil Fatty Acid methyl ester; oleic acid oleic alcohol ester; acetoglyceride; Palmic acid 2-heptyl hendecane ester; diisobutyl adipate; (adipic acid 2 ethyl hexanoic acid stearic acid) glycerol oligoester; (2-hexyldecanoic acid decanedioic acid) two glyceride oligoesters; N-lauroyl-L-glutamic acid-2-octyl group dodecane ester; adipic acid two-2-heptyl hendecane ester; ethyl laurate; Diisooctyl Sebacate; myristic acid 2-hexyl ester in the last of the ten Heavenly stems; Palmic acid 2-hexyl ester in the last of the ten Heavenly stems; adipic acid 2-hexyl ester in the last of the ten Heavenly stems; Dermol DIPS; succinic acid 2-Octyl Nitrite; ethyl acetate; in butyl acetate and the triethyl citrate etc. more than a kind or 2 kinds.

As silicone oil, for example can enumerate in the poly-alkylsiloxane of cyclic polysiloxanes such as chain polysiloxanes such as dimethyl polysiloxane, methyl phenyl silicone, methylhydrogenpolysi,oxane, octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes, tetrahydrochysene tetramethyl-ring tetrasiloxane and polyoxyethylene etc. more than a kind or 2 kinds.

By adding powder, can improve the material of making up usability, adjust color matching. in addition, spendable powder is not subjected to shapes such as spherical, lamellar and needle-like; Or particle diameters such as smoke-like, microgranule and pigment-level; The special qualification of grain structures such as porous matter and atresia matter etc., can use the inorganic powder class, the photism powdery type, the organic dust class, the pigment powdery type, metal dust class and composite powder class etc. as concrete powder, can use titanium oxide, zinc oxide, cerium oxide, white inorganic pigments such as barium sulfate, ferrum oxide, iron titanate, gamma-iron oxide, yellow ferric oxide, Black Rouge, white carbon black, titanium suboxide, chromium oxide, chromic oxide gel, dark purple, ultramarine, loess, the Fructus Mangifera Indicae purple, cobalt violet, coloured inorganic pigment such as cobalt titanate, Talcum, Muscovitum, white mica, phlogopite, rubellan, biotite, synthetic mica, sericite (sericite), lepidolite, Vermiculitum, synthetic sericite, Kaolin, carborundum, bentonite, Montmorillonitum, aluminium oxide, magnesium oxide, zirconium oxide, stibium oxide, kieselguhr, aluminium silicate, the metasilicic acid magnalium, calcium silicates, barium silicate, magnesium silicate, strontium silicate, the wolframic acid slaine, calcium phosphate, calcium carbonate, magnesium carbonate, sintering calcium sulfate, fluoridated apatite, hydroxyapatite, Silicon stone, zeolite, ceramics, white body constitution powder such as boron nitride, titanium dioxide lining Muscovitum, titanium dioxide lining Muscovitum, titanium dioxide lining Talcum, titanium dioxide lining bismuth oxychloride, painted titanium oxide lining Muscovitum, the ferrum oxide mica titanium, dark purple processing mica titanium, carmine is handled mica titanium, bismuth oxychloride, guanin, polyethylene terephthalate aluminum epoxy laminate powder, photism powder such as polyethylene terephthalate laminated polyolefin powder, polyamide-based resin, polyethylene-based resin, the polyacrylic resin, polyester based resin, fluorine resin, cellulose-based resin, polystyrene resin, copolymer resins such as cinnamic acrylic ester class copolymer resins, polypropylene-based resin, silicones, polyurethane resin, benzoguanamine resin, organic polymer resin powder such as polyflon, Grillocin P 176, zinc stearate, calcium palmitate, aluminium stearate, organic low molecular powder such as N-amyl group lysine, starch, the silk powder, natural organic dust such as cellulose powder, red No. 201, red No. 202, red No. 205, red No. 220, red No. 226, red No. 228, red No. 405, orange No. 203, orange No. 204, No. 404, cyan, yellow No. 205, wait the organic pigment powder yellow No. 401, red No. 3, red No. 104, red No. 106, red No. 227, red No. 230, red No. 401, red No. 505, orange No. 205, yellow No. 4, yellow No. 5, yellow No. 202, yellow No. 203, green No. 3, cyan waits zirconium No. 1, organic pigment powder such as barium or aluminum color lake, and aluminium powder, magnesium powder, copper powder, bronze, metal dusts such as argentum powder, the titanium coated mica titanium of particulate oxide, particulate oxide zinc lining mica titanium, barium sulfate lining mica titanium, the silicon dioxide that contains titanium oxide, the composite powders such as silicon dioxide that contain zinc oxide. can use more than a kind or 2 kinds of these powder, also can use the powder of further compoundization. in addition, these powder can use the powder that applies after the surface treatment, and the fluorine based compound is used in described surface treatment, the silicon based compound, metallic soap, lecithin, hydrolecithin, collagen protein, hydrocarbon, higher fatty acids, higher alcohol, ester, wax, in wax oil and the surfactant etc. more than a kind or 2 kinds.

As wetting agent, for example can enumerate in Polyethylene Glycol, propylene glycol, glycerol, 1,3 butylene glycol, xylitol, Sorbitol, maltose alcohol, chondroitin sulfate, hyaluronic acid, mucoitin sulfuric acid, glucosan acid, end collagen, cholesteryl-12-hydroxy stearic acid ester, sodium lactate, carbamide, bile salt, dl-pyrrolidone carboxylic acid salt, short chain soluble collagen albumen, two glycerol (EO) PO addition product, Fructus Rosae Normalis extract, Achillea millefolium L. extract, the Cladrastis kentukea Rudd rhinoceros extract etc. more than a kind or 2 kinds.

As water-soluble macromolecule, for example can enumerate animals such as department of microbiology macromolecule such as arabic gum, Tragacanth, galactan, guar gum, locust bean gum, POLY-karaya, carrageenin, pectin, agar, Semen Fructus Chaenomelis (Fructus Chaenomelis), Sargassum colloid (the yellow extract of rock algae), starch department of botany's macromolecules such as (rice, corn, Rhizoma Solani tuber osi, Semen Tritici aestivis), xanthan gum, dextran, succinic acid glucosan and collagen protein, casein, albumin, gelatin and be in the macromolecule more than a kind or 2 kinds.

As semi-synthetic water soluble polymer, for example can enumerate starch such as carboxymethyl starch, methyl hydroxypropyl starch and be alginic acid such as cellulose-based macromolecule such as macromolecule, methylcellulose, NC Nitroncellulose, methylhydroxypropylcellulose, cellulose sodium sulfate, hydroxypropyl cellulose, carboxymethyl cellulose, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder and sodium alginate, propylene glycol alginate and be in the macromolecule more than a kind or 2 kinds.

As the synthesizing water-solubility macromolecule, for example can enumerate polyvinyl alcohol, polyvinyl methyl ether, polyvinylpyrrolidone, CVP Carbopol ETD2050 (carbopol, Ka Baibo) wait polyoxyethylene such as ethylene base system macromolecule, Macrogol 2000 0,40000,60000 be in acrylic acid series macromolecule, polymine and the cationic polymers etc. such as macromolecule, poloxalkol copolymerization family macromolecule, sodium polyacrylate, polyethyl acrylate, polyacrylamide more than a kind or 2 kinds.

As inorganic water soluble polymer, for example can enumerate in bentonite, silicic acid AlMg (bee gum, propolis), LAPONITE, Strese Hofmann's hectorite. and the silicic acid anhydride etc. more than a kind or 2 kinds.

As thickening agent, for example can enumerate in arabic gum, carrageenin, POLY-karaya, Tragacanth, locust bean gum, Semen Fructus Chaenomelis (Fructus Chaenomelis), casein, dextrin, gelatin, pectic acid sodium, arachidic acid sodium, methylcellulose, ethyl cellulose, CMC, hydroxyethyl-cellulose, hydroxypropyl cellulose, PVA, PVM, PVP, sodium polyacrylate, CVP Carbopol ETD2050, Semen Nelumbinis glue, guar gum, tamarind gum, dialkyl dimethyl ammonium sulfate cellulose, xanthan gum, Magnesiumaluminumsilicate, bentonite and the Strese Hofmann's hectorite. etc. more than a kind or 2 kinds.

As UV absorbent; for example can enumerate para-aminobenzoic acid (being designated hereinafter simply as PABA); the PABA monoglyceride; N; N-dipropoxy PABA ethyl ester; N; N-diethoxy PABA ethyl ester; N; N-dimethyl PABA ethyl ester; N; N-dimethyl PABA butyl ester; N; benzoic acids such as N-dimethyl PABA ethyl ester are UV absorbent; all menthyl-ortho-aminobenzoic acids such as N-acetyl group o-aminobenzoa are UV absorbent; salicylic acid amyl group ester; the menthyl salicylate; equal menthyl salicylate; the octyl group salicylate; phenyl salicylic acid esters; the benzyl salicylate; right-salicylic acid such as isopropyl alcohol phenyl salicylic acid esters are UV absorbent; the cinnamic acid monooctyl ester; Ethyl 4-isopropylcinnamate.; methyl-2; 5-diisopropyl cinnamate; ethyl-2; 4-diisopropyl cinnamate; methyl-2; 4-diisopropyl cinnamate; propyl group-p-methoxycinnamic acid ester; isopropyl-p-methoxycinnamic acid ester; isopentyl-p-methoxycinnamic acid ester; octyl group-p-methoxycinnamic acid ester (2-ethylhexyl-p-methoxycinnamic acid ester); 2-ethoxyethyl group-p-methoxycinnamic acid ester; cyclohexyl-p-methoxycinnamic acid ester; ethyl-alpha-cyano-beta-phenyl cinnamate; 2-ethylhexyl-alpha-cyano-beta-phenyl cinnamate; list-2-ethyl hexanoyl-cinnamic acid such as di-p-methoxy cinnamic acid glyceride are UV absorbent; 2; the 4-dihydroxy benaophenonel; 2; 2 '-dihydroxy-4-methoxy benzophenone; 2; 2 '-dihydroxy-4; 4 '-dimethoxy-benzophenone; 2; 2 '; 4; 4 '-tetrahydroxybenzophenone; 2-hydroxyl-4-methoxy benzophenone; 2-hydroxyl-4-methoxyl group-4 '-methyldiphenyl ketone; 2-hydroxyl-4-methoxy benzophenone-5-sulfonate; the 4-phenyl benzophenone; 2-ethylhexyl-4 '-phenyl benzophenone-2-carboxylate; Octabenzone; 4-hydroxyl-benzophenone series UV absorbent such as 3-carboxyl benzophenone; 3-(4 '-methyl benzal)-d; l-Camphora; 3-benzal-d; l-Camphora; urocanic acid; the urocanic acid ethyl ester; 2-phenyl-5-Jia base benzoxazole; 2; 2 '-hydroxy-5-methyl base phenyl benzotriazole; 2-(2 '-hydroxyl-5 '-uncle's octyl phenyl) benzotriazole; 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) benzotriazole; the dibenzylidene azine; two anisoyl methane; 4-methoxyl group-4 '-tert-butyl group dibenzoyl methane; 5-(3; the inferior norbornene of 3-dimethyl-2-)-3-penta-2-ketone and 2; 4; 6-triphen amido-right-(carbonyl-2 '-ethylhexyl-1 '-oxygen base) 1; 3, in the 5-triazine etc. more than a kind or 2 kinds.

As sequestering agent, for example can enumerate 1-hydroxyl ethane-1,1-di 2 ethylhexyl phosphonic acid, 1-hydroxyl ethane-1, in 1-di 2 ethylhexyl phosphonic acid tetrasodium salt, disodiumedetate, sodium versenate, tetrasodium ethylenediamine tetraacetate, sodium citrate, polyphosphate sodium, Polymeric sodium metaphosphate., gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, ethylenediaminetetraacetic acid and the ethylenediamine ethoxy three acetic acid trisodiums etc. more than a kind or 2 kinds.

As lower alcohol, for example can enumerate in methanol, ethanol, propanol, isopropyl alcohol, isobutanol and the tert-butyl alcohol etc. more than a kind or 2 kinds.

As polyhydric alcohol, for example can enumerate ethylene glycol, propylene glycol, triethylene glycol, 1,2-butanediol, 1,3 butylene glycol, tetramethylene glycol, 2,3-butanediol, penta-methylene glycol, 2-butylene-1, dihydroxylic alcohols such as 4-glycol, hexanediol, ethohexadiol; Glycerol, trimethylolpropane, 1,2, trihydroxylic alcohols such as 6-hexanetriol; Hexahydroxylic alcohols such as pentabasis alcohols such as tetrahydroxylic alcohols such as tetramethylolmethane, xylitol, Sorbitol, mannitol; Polyhydric alcohol polymers such as diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene glycol, TEG, diglycerol, Polyethylene Glycol, triglycerin, four glycerol, polyglycereol; Dihydroxylic alcohols alkyl ethers such as glycol monomethyl methyl ether, ethylene glycol monomethyl ether, ethylene glycol monobutyl ether, glycol monomethyl phenyl ether, ethylene glycol mono hexyl ether, glycol monomethyl 2-methyl hexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol bisthioglycolate ethylether, ethylene glycol bisthioglycolate butyl ether; Dihydroxylic alcohols alkyl ethers such as diethylene glycol monomethyl ether, TC, diethylene glycol single-butyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol ethylmethyl ether, triethylene glycol monomethyl ether, triethylene glycol list ethylether, propylene glycol monomethyl ether, propylene glycol list ethylether, propylene glycol single-butyl ether, propylene glycol isopropyl ether, dipropylene glycol methyl ether, dipropylene glycol ethylether, dipropylene glycol butyl ether; Diatomic alcohol ether acid esters such as ethylene glycol monomethyl ether acetate, ethylene glycol monomethyl ether acetate, ethylene glycol monobutyl ether acetas, glycol monomethyl phenyl ether acetas, ethylene glycol bisthioglycolate ethanedioic acid ester, ethylene glycol bisthioglycolate succinate, ethylene glycol monomethyl ether acetate, diethylene glycol single-butyl ether acetas, propylene glycol monomethyl ether, propylene glycol list ethylether acetas, propylene glycol list propyl ether acetas, propylene glycol list phenyl ether acetas; Glycerol monoalkyl ethers such as .alpha.-hexadecylglyceryl ether, selachyl alcohol, batilol; Sorbitol, maltose alcohol, maltotriose alcohol, mannitol, lactose, sucrose, erythritol, glucose, fructose, amylolysis sugar, maltose, xylose, amylolysis sugar go back in sugar alcohol, solid glycine (glysolid), tetrahydroxy furfuryl alcohol, POE-tetrahydroxy furfuryl alcohol, POP-butyl ether, POPPOE-butyl ether, three polyoxypropylene glycerin ethers, POP-glycerin ether, POP-glycerin ether phosphoric acid and the POPPOE-tetramethylolmethane ethers etc. such as carbinol more than a kind or 2 kinds.

As monosaccharide, for example can enumerate trioses such as D-glyceraldehyde, dihydroxy acetone; Tetroses such as D-erythrose, D-Erythrulose, D-threose, erythritol; Pentoses such as L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose; Hexoses such as D-glucose, D-talose, D-psicose, D-galactose, D-fructose, L-galactose, L-mannose, D-Tagatose; Seven carbon sugar such as aldoheptose, ketoheptose; Eight carbon sugar such as octulose; Deoxysaccharides such as 2-deoxy-D-ribose, 6-deoxidation-L-galactose, 6-deoxy-L-mannose; In alduronic acid such as amino sugars such as D-glycosamine, D-galactosamine, sialic acid, amino sugar aldehydic acid, 3-O-.alpha.-carboxyethyl-D-glucosamine. and D-glucuronic acid, D-mannuronic acid, L-golonic acid, D-galacturonic acid, L-iduronic acid etc. more than a kind or 2 kinds.

As oligosaccharide, for example can enumerate sucrose, gentianose, umbelliferose, lactose, planteose, isolychnose class, α, in α-trehalose, cottonseed sugar, LychnisFlos-Cuculi saccharide, umbilicine and the stachyose Herba Verbasci Thapsi saccharide etc. more than a kind or 2 kinds.

As polysaccharide, for example can enumerate in cellulose, Semen Fructus Chaenomelis, chondroitin sulfate, starch, dextrin, glucomannoglycan, chitin, galactan, dermatan sulfate, glycogen, arabic gum, Heparan sulfate, hyaluronic acid, Tragacanth, keratan sulfate, chrondroitin, xanthan gum, mucoitin sulfuric acid, guar gum, glucosan, keratosulfate, Semen Nelumbinis glue, succinoglucan, the glucosan acid etc. more than a kind or 2 kinds.

As aminoacid, for example can enumerate neutral amino acids such as threonine, cysteine; Basic amino acids such as oxylysine.In addition, as amino acid derivativges, for example can enumerate among acyl group sodium sarcosinate (sodium lauroyl sarcosine), acyl glutamic acid sodium, acyl group Beta-alanine sodium, glutathion and the 2-pyrrolidone-5-carboxylic acid etc. more than a kind or 2 kinds.

As organic amine, for example can enumerate monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1, in ammediol and the 2-amino-2-methyl-1-propanol etc. more than a kind or 2 kinds.

As synthetic resin emulsion, for example can enumerate in acrylic resin emulsion, polyethyl acrylate emulsion, acrylic resin liquid, polyalkyl acrylate emulsion and the polyvinyl acetate resins emulsion etc. more than a kind or 2 kinds.

As the pH regulator agent, for example can enumerate in buffer agents such as lactic acid-sodium lactate and citric acid-sodium citrate etc. more than a kind or 2 kinds.

As vitamins, for example can enumerate in vitamin A, vitamin B1, vitamin B2, vitamin B6, vitamin E, vitamin K and their derivant, pantothenic acid and derivant, the biotin etc. more than a kind or 2 kinds.

As antioxidant, for example can enumerate in tocopherols, dibenzylatiooluene, butylhydroxy anisoyl-and the gallate ester etc. more than a kind or 2 kinds.

As the antioxidation auxiliary agent, for example can enumerate in phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, cephalin, hexametaphosphate, phytic acid and the ethylenediaminetetraacetic acid etc. more than a kind or 2 kinds.

Can blended composition as other, can enumerate antiseptic such as ethylparaben, butyl p-hydroxybenzoate; Benzophenone series derivant, PABA are that derivant, cinnamic acid are that derivant, salicylic acid are UV absorbent such as derivant, the 4-tert-butyl group-4 '-methoxybenzoyl methane, oxybenzone; Antiinflammatory such as glycyrrhizin derivative, Enoxolone derivative, salicyclic acid derivatives, hinokitiol, zinc oxide, allantoin; Whitening agent such as intacellin, Herba Saxifragae extract; The extract of Cortex Phellodendri, Rhizoma Coptidis, Rhizoma Seu Herba Bergeniae, Radix Paeoniae, mud sandfly, birch, Salvia japonica Thunb., Folium Eriobotryae, Radix Ginseng, Aloe, Radix Malvae sylvestris, flag flower, Fructus Vitis viniferae, Semen Coicis, Fructus Luffae, Bulbus Lilii, Stigma Croci, Rhizoma Chuanxiong, Rhizoma Zingiberis Recens, Herba Hyperici Erecti, spiny restharrow, Bulbus Allii, Fructus Capsici, Pericarpium Citri Reticulatae, Radix Angelicae Sinensis, Sargassum etc., Lac regis apis, sensitization element, cholesterol derivative, childhood activating agent such as blood extract; In lipotropism bleeding, tranexamic acid, thiolaurine and the hypotaurine etc. such as blood flow circulation promoter such as Vanillyl pelargonic amide, benzyl nicotinate, nicotinic acid β-Ding 2-ethoxyethyl acetate, capsaicin, (4-hydroxy-3-methoxyphenyl)ethyl methyl ketone, cantharis tincture, ichthyol, tannin, α-Borneolum Syntheticum, tocopheryl nicotinate, hexanicotinate, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, gamma oryzanol, sulfur, two first sulfur Onion more than a kind or 2 kinds.

In addition, in cosmetic material of the present invention, can contain the oil-base gel agent, especially contain the cosmetic cosmetic material of liquid ester composition and oil-base gel agent, its usability excellence, shape retention and storage stability height.

By making up liquid ester composition of the present invention and gelating agent, shape hold facility and gel formation ability double to improve, the film sense of the film that can obtain making up continues, the cosmetic of cosmetic excellent durability is made up material.

Here, the material that oil-base gel agent of the present invention refers to curing such as the oiliness composition that can make oils, wax class, hydrocarbon ils, higher fatty acids, higher alcohol, ester oil, silicone oil or gelation can use commercially available product.

As the oil-base gel agent, for example can enumerate wax, 12-hydroxy stearic acid, dextrin fatty acid ester, sucrose fatty acid ester, metallic soap, anhydrous silicic acid, (behenic acid/eicosane diacid) glyceride and organo-clay mineral etc., can use wherein more than a kind or 2 kinds.

As the wax of oil-base gel agent, for example can enumerate paraffin, ceresine, microwax, Fischer-Tropsch synthetic wax, Tissuemat E, palm wax and candelilla wax etc., can use wherein more than a kind or 2 kinds.

As these the example of commercially available product, can enumerate commodity: refining palm wax No.1 (wild field wax company make), trade name: OZOKERAITE WAX SP-273P (STRAHL; PITSH INC. makes), trade name: Microwax 190Y (Mobil Oil Co. manufacturing), trade name: Himic 1080/2095 (Japan system wax company makes), trade name: Sanwax E-200/E-300 (Sanyo changes into industrial group and makes), trade name: Mobil 180 (Mobil Oil Co. manufacturing), trade name: star wax 100 (Bareco Co. manufacturing), trade name: day stone microwax 180 (Japan National Oil Corp's manufacturings), trade name: Fischer-Tropsch synthetic wax FT-95/FT100H/FT-150/FT-200 (SasolCo. manufacturing), trade name: BeSquare 180/185/190/195 (Bareco Co. manufacturing), trade name: poly-wax 500/655 (Bareco Co. manufacturing) and trade name: Sasol wax H1/C1/C2 (Sasol Co. manufacturing) etc.

12-hydroxy stearic acid as the oil-base gel agent is hydroxyl fatty acid, for example, can carry out hydrogenation to the castor oil acid that obtains and obtain from Oleum Ricini.

As the dextrin fatty acid ester of oil-base gel agent the dextrin reaction of the saturated or unsaturated fatty acid of straight or branched of carbon number 8～24 (preferred 14～18) and average degree of polymerization 10～50 (preferred 20～30) and the oil-soluble ester compounds that obtains.

For example can enumerate Dextrin palmitate, Palmic acid/2 ethyl hexanoic acid dextrin, stearic acid dextrin, Palmic acid/stearic acid dextrin, oleic acid dextrin, different Dextrin palmitate and isostearic acid dextrin etc., can use wherein more than a kind or 2 kinds.

As the commercially available product of Dextrin palmitate, for example can enumerate trade name: Leopal KL (Chiba powder process (strain) manufacturing), Leopal TL (Chiba powder process (strain) manufacturing) etc.In addition, as the commercially available product of Palmic acid/2 ethyl hexanoic acid dextrin, for example can enumerate trade name: Leopal TT (Chiba powder process (strain) manufacturing) etc.

As the sucrose fatty acid ester of oil-base gel agent, so long as the sucrose fatty acid ester that is generally used for making up in expecting then can use any, especially preferred Palmic acid, stearic acid, behenic acid, oleic acid and lauric fatty acid ester.

As the metallic soap of oil-base gel agent, can enumerate isostearic acid aluminum, aluminium stearate and calcium stearate etc., can use wherein more than a kind or 2 kinds.

As the anhydrous silicic acid of oil-base gel agent, so long as the anhydrous silicic acid in the material that is generally used for making up, just can use smoke-like, porous matter, atresia matter, spherical etc. any, can use wherein more than a kind or 2 kinds.Wherein, especially preferably use smoke-like anhydrous silicic acid or the smoke-like anhydrous silicic acid carried out that hydrophobization is handled and the hydrophobization smoke-like anhydrous silicic acid that obtains.

In addition, the primary particle size of smoke-like anhydrous silicic acid or hydrophobization smoke-like anhydrous silicic acid is preferably below the 50nm, especially is preferably below the 20nm.The smoke-like anhydrous silicic acid can be hydrolyzed to Silicon chloride. in hydrogen and oxygen flame and obtain.

As the commercially available product of anhydrous silicic acid, for example can enumerate the trade name that Japanese Aerosil Co. makes: (Aerosil 50, Aerosil 130, Aerosil 200, Aerosil 200V, Aerosil 200CF, Aerosil 200FAD, Aerosil 300, Aerosil 300CF, Aerosil 380) etc.

As the method for the smoke-like anhydrous silicic acid being carried out the hydrophobization processing, can enumerate the trimethicone processing, the octyl group silanization that utilize trim,ethylchlorosilane or hexamethyldisiloxane and handle, use the coating calcination processing of hydrogenated methyl diene polysiloxanes, utilize the coating of metallic soap etc.

As the commercially available product of hydrophobization smoke-like anhydrous silicic acid, for example can enumerate the trade name that Japanese Aerosil Co. makes: the trade name that (Aerosil R-972, Aerosil R-972V, Aerosil R-972CF, Aerosil R-974, Aerosil R-976S, AerosilRX200, Aerosil RY200, Aerosil R-202, Aerosil R-805, AerosilR-812, Aerosil RA200H), Talco Co. make: the trade name that Taranox500, Cabot Co. make: CAB-O-SIL TS-530 etc.

(behenic acid/eicosane diacid as the oil-base gel agent) glyceride, the oligoester of Shi behenic acid and eicosane diacid and glycerol.As commercially available product, can enumerate for example trade name: Nomcort HK-G (a day clear sharp friend difficult to understand (strain) makes).

As the organo-clay mineral of oil-base gel agent, can enumerate organic modified bentonite, handle material that the water-swellable clay mineral obtains etc. with quaternary ammonium salt, can use these more than a kind or 2 kinds.As the organic modified bentonite commercially available product, can enumerate for example trade name: bentone 38 (NL Industries, Inc makes), trade name: bentone 27 (NL Industries, Inc makes) etc.

In the cosmetic of the such solid shape of lipstick, lip gloss and bar-shaped foundation cream was made up material, preferably using under the room temperature was solid oil-base gel agent, especially preferably uses wax.This is that a spot of addition just can obtain sufficient shape retention because wax can be given full play to the curing function as wax in product of the present invention.

The liquid ester composition content that the cosmetic of solid shape is made up in expecting is preferably 3～90 quality %, and more preferably 5～80 quality % most preferably are 10～50 quality %, are more preferably 20～30 quality %.In addition, the oil-base gel agent content that the cosmetic of solid shape is made up in expecting is preferably 2～30 quality %, and more preferably 5～25 quality % most preferably are 5～20 quality %.This is because in this scope the time, and shape retention and usability are excellent more, and the gloss of film and the product that the cosmetic persistency is further enhanced can obtain making up.

In addition, the cosmetic of the paste-like that liquid kermes and liquid eye shadow the are such material of making up preferably uses the oil-base gel agent more than a kind or 2 kinds that is selected from down in organizing: 12-hydroxy stearic acid, dextrin fatty acid ester, sucrose fatty acid ester, metallic soap, anhydrous silicic acid, (behenic acid/eicosane diacid) glyceride and organo-clay mineral etc.

The liquid ester composition content that the cosmetic of paste-like is made up in the material is preferably 3～90 quality %, 5～80 quality % more preferably, and 10～50 quality % more preferably add most and are preferably 10～30 quality %.In addition, the oil-base gel agent content that the cosmetic of paste-like is made up in expecting is preferably 0.001～10 quality %, and more preferably 0.1～5 quality % most preferably is 0.3～3 quality %.This is because in this scope the time, and shape retention and usability are excellent more, and the gloss of film and the material that the cosmetic persistency is further enhanced can obtain making up.

The cosmetic material that contains liquid ester composition of the present invention except using liquid ester composition as the raw material, can be made by the manufacture method of known cosmetic material.

In addition, the cosmetic that contains liquid ester composition and oil-base gel agent of the present invention is made up and is expected, except using liquid ester composition and oil-base gel agent as the raw material, can make by the manufacture method of known cosmetic cosmetic material.

Secondly, liquid ester composition of the present invention can be used as the lasting agent use of cosmetic overlay film.

This be because: the viscosity of liquid ester composition of the present invention is the above high viscositys of 100,000 mPas, the cosmetic overlay film is to the tack height of skin, therefore has the effect that the cosmetic overlay film is continued, can make the cosmetic persistency good. liquid ester composition of the present invention can continue agent as the cosmetic overlay film separately to be used, also can and use other composition, the oils of liquid for example, the wax class of liquid, the hydrocarbon ils of liquid, the higher fatty acids of liquid, the higher alcohol of liquid, isopropyl alcohol, the ester oil of liquid, silicone oil, antioxidant, in the UV absorbent more than a kind or 2 kinds. in addition, the liquid component here is meant and is the material of liquid under the room temperature. for the oils of liquid, isopropyl alcohol, silicone oil, antioxidant, UV absorbent, the identical material of material that can use and in containing the cosmetic material of liquid ester composition, illustrate. in addition, wax class for liquid, the hydrocarbon ils of liquid, the higher fatty acids of liquid, the higher alcohol of liquid, the ester oil of liquid can use in the material that illustrated under the room temperature composition as liquid in containing the cosmetic material of liquid ester composition.

The content that the cosmetic overlay film continues the liquid ester composition of the present invention in the agent is preferably 50～100 quality %, and more preferably 70～100 quality % most preferably are 80～100 quality %.

Cosmetic film of the present invention continues agent, can be used in the material of making up such as cosmetic cosmetic material, emulsion, facial cream, sunscreen and Hair grooming cosmetic material.Make up and expect for cosmetic cosmetic material, Hair grooming, identical with the material that in containing the cosmetic material of liquid ester composition, illustrates.

Liquid ester composition of the present invention can make the film sense of cosmetic film continue, and in addition, can improve the shape retention of lipstick etc.Therefore, the liquid ester composition of the application of the invention can provide the cosmetic cosmetic material, emulsion, facial cream, sunscreen of cosmetic excellent durability and the Hair grooming material etc. of making up.

In addition, therefore liquid ester composition of the present invention can make the pigment in the material of making up stably disperse owing to have the pigment-dispersing energy.And then therefore liquid ester composition of the present invention can give gloss and moist feeling to the oil-based cosmetic material owing to have moisture performance.

Embodiment

The present invention is described in more detail by the following examples, executes example but the present invention is not limited to these.

Make embodiment 1[dipentaerythritol and 2-(1,3, the 3-trimethyl) butyl-5,7,7-three Methyloctanoic acid carries out esterification and the manufacturing of the liquid ester composition 1 that obtains]

In the four-hole boiling flask of the 3L that possesses blender, thermometer, nitrogen air inlet pipe and separated form water pipe, 279g (1.1 moles) dipentaerythritol [trade name: dipentaerythritol of packing into, wide flourish chemical industry (strain) is made] and 1874g (6.6 moles) 2-(1,3, the 3-trimethyl) butyl-5,7,7-trimethyl sad [trade name: isostearic acid, daily output chemical industry (strain) manufacturing] (raw material charging mass ratio=10: 67.2).Then, be incorporated as the dimethylbenzene (reflux solvent) of 5 quality % of the Dibutyltin oxide (catalyst) of 0.1 quality % of total charge, total charge, under 200～250 ℃, reacted while stirring about 36 hours.After reaction finished, the dimethylbenzene as reflux solvent was removed in distilling under reduced pressure.To carrying out adsorption treatment, then, be cooled to 60 ℃ of left and right sides after-filtration with active hargil, carry out the deodorization distillation by conventional method and handle, obtain 1399g liquid ester composition 1 except that the reactant behind the removal xylene.

The acid number of liquid ester composition 1 is 0.3, and hydroxyl value is 32, and freezing point and cloud point be all below-30 ℃, and the viscosity under 25 ℃ is 180,000 mPas.Viscosity uses rotor No.6, revolution to be set at 4rpm and to measure by using Brookfield viscometer (BH type) down at 25 ℃.

Make embodiment 2[dipentaerythritol and 2-(1,3, the 3-trimethyl) butyl-5,7,7-three Methyloctanoic acid carries out esterification and the manufacturing of the liquid ester composition 2 that obtains]

Possessing blender, thermometer, in the four-hole boiling flask of the 3L of nitrogen air inlet pipe and separated form water pipe, 58.4g (0.23 mole) dipentaerythritol [trade name: dipentaerythritol of packing into, wide flourish chemical industry (strain) is made] and 293.9g (1.03 moles) 2-(1,3, the 3-trimethyl) butyl-5,7, sad [the trade name: isostearic acid acid of 7-trimethyl, daily output chemical industry (strain) is made] (raw material charging mass ratio=10: 50.3). then, the Dibutyltin oxide (catalyst) that adds 0.05 quality % of total charge, the dimethylbenzene (reflux solvent) of 5 quality % of total charge, the following reaction under 200～250 ℃ about 21 hours stirred on the limit. after reaction finishes, the dimethylbenzene as reflux solvent is removed in distilling under reduced pressure. with active hargil the reactant that removes behind the removal xylene is carried out adsorption treatment, then, be cooled to 60 ℃ of left and right sides after-filtration, carry out the deodorization distillation by conventional method and handle, obtain 245g liquid ester composition 2.

The acid number of liquid ester composition 2 is 0.2, and hydroxyl value is 81, and freezing point is-16 ℃, and muddiness does not take place under-30 ℃ yet.In addition, the viscosity under 25 ℃ is 350,000 mPas.Viscosity uses rotor No.6, revolution to be set at 2rpm and to measure by using Bu Shi type viscometer (BH type) down at 25 ℃.

Make embodiment 3[dipentaerythritol and 2-(1,3, the 3-trimethyl) butyl-5,7,7-three Methyloctanoic acid carries out esterification and the manufacturing of the liquid ester composition 3 that obtains]

In the four-hole boiling flask of the 3L that possesses blender, thermometer, nitrogen air inlet pipe and separated form water pipe, 63.5g (0.25 mole) dipentaerythritol [trade name: dipentaerythritol of packing into, wide flourish chemical industry (strain) is made] and 248.5g (0.88 mole) 2-(1,3, the 3-trimethyl) butyl-5,7,7-trimethyl sad [trade name: isostearic acid acid, daily output chemical industry (strain) manufacturing] (raw material charging mass ratio=10: 39.1).Then, add the dimethylbenzene (reflux solvent) of 5 quality % of the Dibutyltin oxide (catalyst) of 0.05 quality % of total charge, total charge, under 200～250 ℃, reacted while stirring about 14 hours.After reaction finished, the dimethylbenzene as reflux solvent was removed in distilling under reduced pressure.To carrying out adsorption treatment, then, be cooled to 60 ℃ of left and right sides after-filtration with active hargil, carry out the deodorization distillation by conventional method and handle, obtain 185g liquid ester composition 3 except that the reactant behind the removal xylene.

The acid number of liquid ester composition 3 is 0.2, and hydroxyl value is 140, and freezing point is-12 ℃, and muddiness does not take place under-30 ℃ yet.In addition, the viscosity under 25 ℃ is 1,580,000 mPas.Viscosity uses rotor No.7, revolution to be set at 2rpm and to measure by using Bu Shi type viscometer (B H type) down at 25 ℃.

Make comparative example 1[tetramethylolmethane and 2-(1,3, the 3-trimethyl) butyl-5,7, the 7-front three The manufacturing of the sad relatively product liquid ester composition 1 that carries out esterification and obtain of base]

In the four-hole boiling flask of the 3L that possesses blender, thermometer, nitrogen air inlet pipe and separated form water pipe, 32.6g (0.24 mole) tetramethylolmethane [trade name: tetramethylolmethane of packing into, Perstorp Group makes] and 286.3g (1.01 moles) 2-(1,3, the 3-trimethyl) butyl-5,7,7-trimethyl sad [trade name: isostearic acid acid, daily output chemical industry (strain) manufacturing].Then, add the dimethylbenzene (reflux solvent) of 5 quality % of the Dibutyltin oxide (catalyst) of 0.1 quality % of total charge, total charge, under 200～250 ℃, reacted while stirring about 28 hours.After reaction finished, the dimethylbenzene as reflux solvent was removed in distilling under reduced pressure.To carrying out adsorption treatment, be cooled to 60 ℃ of left and right sides after-filtration with active hargil, carry out the deodorization distillation by conventional method and handle, obtain relatively product liquid ester composition 1 of 251g except that the reactant behind the removal xylene.

Relatively the acid number of product liquid ester composition 1 is 0.3, and hydroxyl value is 10, and freezing point and cloud point are all below-30 ℃.In addition, the viscosity under 25 ℃ is 30,000 5000mPas.Viscosity uses rotor No.3, revolution to be set at 2rpm and to measure by using Bu Shi type viscometer (BH type) down at 25 ℃.

Make comparative example 2[dipentaerythritol and 2-(1,3, the 3-trimethyl) butyl-5,7,7-three Methyloctanoic acid carries out esterification and the manufacturing of the relatively product liquid ester composition 2 that obtains]

Possessing blender, thermometer, in the four-hole boiling flask of the 3L of nitrogen air inlet pipe and separated form water pipe, 63.5g (0.25 mole) dipentaerythritol [trade name: dipentaerythritol of packing into, wide flourish chemical industry (strain) is made] and 218.9g (0.75 mole) 2-(1,3, the 3-trimethyl) butyl-5,7, sad [the trade name: isostearic acid acid of 7-trimethyl, daily output chemical industry (strain) is made] (raw material charging mass ratio=10: 34.5). then, the Dibutyltin oxide (catalyst) that adds 0.03 quality % of total charge, the dimethylbenzene (reflux solvent) of 5 quality % of total charge, reacting under 200～250 ℃ about 12 hours while stirring. after reaction finishes, the dimethylbenzene as reflux solvent is removed in distilling under reduced pressure. and the dimethylbenzene of gained is removed thing, under 100 ℃, comprise a large amount of solid insolubles, and then under 50 ℃ milky paste-like semi-solid material, therefore can't carry out adsorption treatment and utilize deodorization distillation processing to carry out refinement treatment, relatively product liquid ester composition 2. in addition, the acid number of milky paste-like semi-solid material is 8, and hydroxyl value is 175.

To the liquid ester composition of making embodiment 1～3 and making gained in the comparative example 1, carry out that pigment-dispersing can be estimated, moisture performance evaluation and with the performance evaluation that mixes of various oil preparationes.Below evaluation methodology and evaluation result are described.

[sample and evaluation methodology that pigment-dispersing can be estimated]

1. assess sample

To liquid ester composition 1～3, relatively the product liquid ester composition 1, malic acid two different stearyl ester (trade name: Cosmole 222, clear sharp friend difficult to understand of day (strain) manufacturing), used three isostearic acids, the two glyceride (trade name: Cosmole 43N that has the isostearic acid of identical branched structure with aqueous ester composition 1～3, clear sharp friend difficult to understand of day (strain) manufacturing), hydrogenated polybutene (trade name: Parleam 24, Japan's oils and fats (strain) is made) and liquid paraffin (trade name: Silkool P-70, (strain) loose village oil is made) estimate.

2. evaluation methodology

In being with graduated test tube with ground stopper, add 4g assess sample and 16g liquid paraffin (trade name: Silkool P-70, (strain) pinaster oil are made) as the dilution oil preparation, be heated to 80 ℃ after mix homogeneously.Then, in the mixed liquor of gained, add the titanium oxide (trade name: TIPAQUE CR-50, stone former industry manufacturing) of 4g, at room temperature forcibly vibrate up and down and mixed about 5 minutes, make its dispersion with hands as pigment.Then, the temperature chamber of putting into 40 ℃ leaves standstill preservation, observes after 1 hour and estimates the pigment dispersity.

Pigment-dispersing can evaluation be by measuring because the length (mm) of the transparent separation phase of pigment sedimentation and the oil that produces on dispersible pigment dispersion top is carried out.In addition, liquid paraffin is used as assess sample, the temperature chamber of putting into 40 ℃ leaves standstill preservation 24 hours, be made as sedimentation rate 100% at the length 100mm of the transparent separation phase of the oil of dispersible pigment dispersion top generation this moment, calculate sedimentation rate after 1 hour by following mathematical expression, estimate with the determinating reference shown in the table 1.Here, A=after under 40 ℃ assess sample being left standstill 1 hour apart from the degree of depth (mm) of liquid level, B=will be only in 40 ℃ temperature chamber dispersive assess sample leaves standstill and preserves the degree of depth (100mm) that distance after 24 hours is separated into transparent liquid level with liquid paraffin.

Sedimentation rate (%)=A/B * 100

Table 1

[pigment-dispersing energy evaluation result]

Can evaluation result at pigment-dispersing shown in the table 2. from this result as can be known, the liquid ester composition 1～3rd that obtains among the present invention, the compositions of the dispersive property excellence of inorganic pigment titanium oxide, and titanium oxide is considered to be difficult to keep dispersity usually. by comparison, relatively the product liquid ester composition 1, three isostearic acids, two glyceride that have the isostearic acid of identical branched structure with liquid ester composition 1～3 have been used, material is used raw material and widely used malic acid two different stearyl esters as making up, can't satisfy aspect the dispersive property of titanium oxide. in addition, hydrogenated polybutene is not found dispersive property fully.

Table 2

[sample of moisture performance evaluation and evaluation methodology]

1. assess sample

To liquid ester composition 1～3, relatively the product liquid ester composition 1, malic acid two different stearyl ester (trade name: Cosmole 222, clear sharp friend difficult to understand of day (strain) manufacturing), used three isostearic acids, the two glyceride (trade name: Cosmole 43N that has the isostearic acid of identical branched structure with liquid ester composition 1～3, clear sharp friend difficult to understand of day (strain) manufacturing), hydrogenated polybutene (trade name: Parleam 24, Japan's oils and fats (strain) is made) and vaseline (trade name: Nomcort W, clear sharp friend difficult to understand of day (strain) manufacturing) estimates.

2. evaluation methodology

Moisture performance evaluation is following carries out: water-retention value (the Water absorption capacity) algoscopy of the lanoline by British Pharmacopoeia (BP) is measured water-retention value, carries out moisture performance evaluation based on resulting water-retention value.Concrete evaluation methodology is as follows.

In the 100mL of stainless steel beaker, add the vaseline (trade name: Nomcort W, a day clear sharp friend difficult to understand (strain) make) of 1g assess sample, 9g dilution oil preparation, be heated to 80 ℃ after, dissolving mixes equably, is modulated into uniform sample.Then, with the sample cool to room temperature of gained, confirm to be solidified into the vaseline shape.Then, in 40 ℃ temperature chamber, in every 10g sample, drip 0.1～0.5g Purified Water, the limit with stainless steel propeller stir, the limit refines into Purified Water, when no longer entering in the sample with water as terminal point.

Moisture performance evaluation is by following mathematical expression, tries to achieve the water-retention value (quality %) of assess sample, estimates with the metewand shown in the table 3.In addition, the judgement of water-retention value is the big more sample of numerical value (benchmark is more than 100%), and it is high more to estimate its moisture performance.

The total addition level (g) of water-retention value (%)=Purified Water/sample weight (10g) * 100

Table 3

[moisture performance evaluation result]

In moisture performance evaluation result shown in the table 4.From this result as can be known, the liquid ester composition 1～3 of gained among the present invention and has used that to have a water-retention value of three isostearic acids, two glyceride of isostearic acid of identical branched structure high equally with liquid ester composition 1～3, moisture excellent performance.The malic acid two different stearyl esters that use tetramethylolmethane to replace relatively product liquid ester composition 1, the conduct material of making up commonly used of dipentaerythritol to be widely used with raw material, water-retention value is low, can't satisfy at moisture aspect of performance.In addition, hydrogenated polybutene is not found moisture performance fully.

Table 4

[with the sample and the evaluation methodology of the performance evaluation that mixes of various oil preparationes]

1. assess sample

To liquid ester composition 1～3, relatively product liquid ester composition 1, malic acid two different stearyl esters (trade name: Cosmole 222, day clear sharp friend difficult to understand (strain) make), used with three isostearic acids, two glyceride (trade name: Cosmole 43N, a day clear sharp friend difficult to understand (strain) make), hydrogenated polybutene (trade name: Parleam 24, Japanese oils and fats (strain) are made) that liquid ester composition 1～3 has an isostearic acid of identical branched structure and estimated.

2. evaluation methodology

In sample bottle with cover, put into the various oil preparationes of 10g assess sample and 10g ((1) isopropyl alcohol, (2) Oleum Ricini, (3) three 2 ethyl hexanoic acid glyceride, (4) liquid paraffin, (5) 10cs dimethyl siloxane), after being heated to 70 ℃, with hands forcibly up and down vibration mixed about 5 minutes, with its mixing.After the mixing, in temperature chamber, leave standstill once more and preserve after 15 minutes, return to room temperature and left standstill 2 days, observe appearance, estimate by metewand shown in the table 5.

Table 5

[with the performance evaluation result that mixes of various oil preparationes]

Shown in the table 6 with the performance evaluation result that mixes of various oil preparationes.From this result as can be known, liquid ester composition 1～3 of the present invention is to any all mixes equably in oil preparation (1)～(4).Therefore as can be known, may be mixed in in the various cosmetic material.Particularly liquid ester composition 1, owing to also mix with the low viscous dimethyl siloxane of oil preparation (5), therefore can also be mixed in the skin care or foundation cream that contains low viscous dimethyl siloxane.

In addition, therefore liquid ester composition 1～3 can handle the raw material of usefulness as powder surface owing to also high to the intermiscibility of isopropyl alcohol, and the powder that the use liquid ester composition carries out after the surface treatment can be used for the cosmetic material.

On the other hand, relatively product liquid ester composition 1 and hydrogenated polybutene are mixed into them when making up material as can be known owing to do not have intermiscibility with Oleum Ricini, need manage with other material combination etc., and its use is restricted on the prescription.

In addition, the oil preparation in the table (1) is that isopropyl alcohol (making with the pure medicine of light (strain)), oil preparation (2) are that three 2 ethyl hexanoic acid glyceride (trade name: T.I.O, a day clear sharp friend difficult to understand (strain) make), oil preparation (4) are 10cs dimethyl siloxane (trade name: KF-9610CS, SHIN-ETSU HANTOTAI's chemistry (strain) are made) for liquid paraffin (trade name: Silkool P-70, (strain) loose village oil are made), oil preparation (5) for Oleum Ricini (trade name: refined caster oil, rich state's system oil (strain) are made), oil preparation (3).

Table 6

Embodiment 1～6 and comparative example 1～7

[modulation of liquid lip gloss]

Make formulations of liquid lip gloss shown in table 7～10.At first, at 90～105 ℃ of following uniform mixing compositions 1～8, modulate cosmetic film retention agent.In resulting cosmetic film retention agent, limit heating edge solvent components 9 adds composition 10, and uniform mixing obtains mixture.Then, resulting mixture is filled in the bottle container of lip ring brush, cooling obtains the liquid lip gloss then.

In addition, in table, composition 5 is hydrogenated polybutene (trade name: Parleam 24, Japan's oils and fats (strain) is made), composition 6 is three stearic acid, two glyceride (trade names: Cosmole 43N, clear sharp friend difficult to understand of day (strain) manufacturing), composition 7 is malic acid two different stearyl ester (trade name: Cosmole 222, clear sharp friend difficult to understand of day (strain) manufacturing), composition 8 is an olefin oligomer (trade name: Salacos HPD-C, clear sharp friend difficult to understand of day (strain) manufacturing), composition 9 is (behenic acid/eicosane diacid) glyceride (trade name: NomcortHK-G, clear sharp friend difficult to understand of day (strain) manufacturing).

Table 7

Table 8

Table 9

Table 10

[evaluation methodology of liquid lip gloss]

Liquid lip gloss to gained, sensory evaluation is carried out in usability (being clamminess property and ductility etc.) during at the film sense of cosmetic film, gloss, moist feeling, coating, the lasting sense of cosmetic film. in addition, to preserve the liquid lip gloss 30 days down at 50 ℃, estimate the storage stability under the high temperature. evaluation methodology is as follows.

1. the evaluation methodology of sensory evaluation

The discussion group that constitutes with 10 people is an object, to the film sense of cosmetic film, the gloss of cosmetic film, each assessment item of usability (being clamminess property, ductility), adds up the number that 10 philtrums are answered " excellence ", estimates with the metewand shown in the table 11.

Table 11

2. stable

In 50 ℃ temperature chamber, preserve the liquid lip gloss of gained, observe the state after 1 month, do not change be evaluated as zero, observe minor variations sign be evaluated as being evaluated as of △, affirmation significant change *.

[evaluation result of liquid lip gloss]

Evaluation result at liquid lip gloss shown in table 12～15.As can be known from these results, contain the liquid lip gloss of liquid ester composition 1～3 of the present invention, the usability when the film sense of its cosmetic film, gloss, moist feeling, coating, the lasting sense of cosmetic film and storage stability are also excellent.

Relative with it, used the comparative example 1,2 of low-viscosity (mobile) liquid ester composition and used with 5 and 6 the liquid lip gloss of branched chain type isostearic acid as the ester composition of raw material, can't be met aspect the lasting sense of the film sense of cosmetic film, gloss, cosmetic film and the storage stability, in addition, used the comparative example 3 of polybutene and 4 liquid lip gloss, aspect the usabilities such as being clamminess property in when coating, can't be met.

And then, to have used as the liquid lip gloss of cosmetic material commonly used with the comparative example 7 of the malic acid two different stearyl esters of raw material, all projects all do not satisfy.

Table 12

Table 13

Table 14

Table 15

Embodiment 7: lip stick

[modulation of lip stick and evaluation result]

Make the lip stick of prescription shown in the table 16 in the following order.

A. at 110～120 ℃ of following heating for dissolving compositions 1～11, add composition 12～15 then, uniform mixing.

B. add composition 16,17 in the mixture that obtains in the A operation, heating mixes equably, after the deaeration, pours into and is filled in the mould cooling forming.

C. will from mould, take out by the solidfied material of B operation molding, install to and obtain lip stick in the container.

Screw out the lip stick of gained from container, in 50 ℃ temperature chamber, traverse leaves standstill to be confirmed not change fully in 1 week, was the lipstick of shape retention excellence.In addition, the usability during coating is also good, and the film sense of cosmetic film, gloss, moist feeling are also excellent, and cosmetic persistency aspect is also satisfactory.

In addition, the composition 5 in the table 16 uses liquid ester composition 2 of the present invention, and other composition uses as making up expects with the commercially available product of raw material.

Table 16

Embodiment 8: the paste-like lipstick

[modulation of paste-like lipstick and evaluation result]

Make the paste-like lipstick of prescription shown in the table 17 in the following order.

A. after heating mixed dissolution composition 1～11 equably, add composition 12～17, uniform mixing.

B. fill the mixture that obtains in the A operation, obtain the paste-like lipstick.

The paste-like lipstick of gained, the usability in its when coating, the film sense of cosmetic film, gloss, moist feeling are all excellent, and cosmetic persistency aspect is also satisfactory. and in addition, not having the problem of waste liquid etc., is the good lipstick of shape retention.

In addition, the trade name that composition 2 in the table 17 uses Chiba powder process (strain) to make: Leopal TL, the trade name that composition 3 uses Japanese Aerosil Co. to make: AerosilR-976S, composition 5 uses liquid ester composition 1 of the present invention, composition 6 uses the trade name of clear sharp friend difficult to understand of day (strain) manufacturing: Salacos E-38, other composition use as the material commercially available product of raw material of making up.

Table 17

Embodiment 9: bar-shaped lip gloss

[modulation of bar-shaped lip gloss and evaluation result]

Make the bar-shaped lip gloss of prescription shown in the table 18 in the following order.

A. at 90 ℃ of following heating for dissolving compositions 1～4, add composition 5,6 then, uniform mixing.

B. add composition 7 in the mixture that obtains in the A operation, heating mixes equably, after the deaeration, pours into and is filled in the mould cooling forming.

C. from mould, take out solidfied material, install to and obtain bar-shaped lip gloss in the container by the molding of B operation.

The bar-shaped lip gloss of gained, usability, the film sense of cosmetic film, gloss, moist feeling, the persistent aspect of cosmetic during its coating are also satisfactory, and in addition, shape retention is also good.

In addition, the composition 1 in the table 18 uses liquid ester composition 3 of the present invention, and composition 2 uses the trade name of Chiba powder process (strain) manufacturing: Leopal KL, other composition use as the material commercially available product of raw material of making up.

Table 18

Embodiment 10: the solid powdery foundation cream

[modulation of solid powdery foundation cream and evaluation result]

Make the solid powdery foundation cream of prescription shown in the table 19 in the following order.

A. at 90 ℃ of following heating compositions 10～12, with its mixing.

B. composition 1～9 is mixed and disperse.

C. add the mixture that obtains in the A operation in the mixture that in the B operation, obtains, with its mixing.

D. pulverize the mixture that obtains in the C operation, compression forming obtains the solid powdery foundation cream in dish.

The solid powdery foundation cream of gained, the usability during its coating, the adhesiveness of cosmetic film, cosmetic persistency aspect be excellence all, and be satisfactory.In addition, the molding product are placed in the container, carry under the situation of moving for 1 week, also do not find crackle or peel off, shape retention is also good.

In addition, the trade name that the composition 9 in the table 19 uses Ganz Chemical Co.Ltd to make: Ganzpearl GS-0605, composition 12 uses liquid ester composition 1 of the present invention, other composition uses as the material commercially available product of raw material of making up.

Table 19

Embodiment 11: emulsion

[modulation of emulsion and evaluation result]

Make the emulsion of prescription shown in the table 20 in the following order.

A. 80 ℃ of following blending constituents 1～6.

B. composition 7～13 is heated to 80 ℃, adds in the mixture that in the A operation, obtains, carry out emulsifying.

C. cool off the emulsion that obtains in the B operation, obtain emulsion.

The emulsion of gained is also satisfactory aspect the persistence of film sense, moist feeling.

In addition, the composition 3 in the table 20 uses liquid ester composition 1 of the present invention, and other composition uses as making up expects with the commercially available product of raw material.

Table 20

Embodiment 12: foundation emulsion

[modulation of foundation emulsion and evaluation result]

Make the foundation emulsion of prescription shown in the table 21 in the following order.

A. heat blending constituent 10～17, be cooled to 40 ℃, add composition 1～9 then, disperse by the intimate mixing device.

B. mixed dissolution composition 18～23 equably.

C. add the mixture that obtains in the B operation in the dispersion thing that in the A operation, obtains, carry out emulsifying, obtain foundation emulsion.

The foundation emulsion of gained, the usability in its when coating is good, and the film sense of cosmetic film, moist feeling, cosmetic persistency aspect are also satisfactory.

In addition, the composition 10 in the table 21 uses liquid ester composition 1 of the present invention, and composition 16 uses the trade name of SHIN-ETSU HANTOTAI's chemical industry (strain) manufacturing: KF-6017, and other composition uses as the material commercially available product of raw material of making up.

Table 21

Embodiment 13: hand cream

[modulation of hand cream and evaluation result]

Make the hand cream of prescription shown in the table 22 in the following order.

A. blending constituent 1～7, therein by dispersing mixer dispersion component 8.

B. mixed dissolution composition 9～12 equably.

C. add the mixture that obtains in the B operation in the dispersion thing that in the A operation, obtains, carry out emulsifying, obtain the water-in-oil type hand cream.

The hand cream of gained, the usability during coating is good, overlay film sense, moist feeling excellence, the persistence aspect is also satisfactory.In addition, leave standstill in 40 ℃ temperature chamber and also found separation etc. in 1 month, stability is also good.

In addition, composition 4 in the table 22 uses liquid ester composition 2 of the present invention, composition 5 uses the trade name of clear sharp friend difficult to understand of day (strain) manufacturing: Salacos E-38, composition 7 uses the trade name of Goldschmidt AG company manufacturing: ABIL EM-90, other composition use as the material commercially available product of raw material of making up.

Table 22

Embodiment 14: sunscreen

[modulation of sunscreen and evaluation result]

Make the sunscreen of prescription shown in the table 23 in the following order.

A. the uniform mixing composition 1～12.

B. the uniform mixing composition 13～16.

C. add the mixture that obtains in the B operation in the dispersion thing that in the A operation, obtains, carry out emulsifying.

D. the emulsion that obtains in the C operation is filled in the resin bottle that stainless steel ball is housed, obtains sunscreen.

The sunscreen of gained, the usability during coating is good, overlay film sense, moist feeling excellence, cosmetic persistency aspect is also satisfactory.In addition, at room temperature leave standstill after 24 hours the coagulation of also not finding powder when observing, do not find apparent variation, have good stability by optical microscope (1000 times).

In addition, composition 1 in the table 23 uses liquid ester composition 1 of the present invention, composition 2 uses the trade name of clear sharp friend difficult to understand of day (strain) manufacturing: Salacos E-38, the trade name that composition 3 uses the former industry of stone (strain) to make: TIPAQUE TTO-S2, composition 8 uses the trade name of Goldschmidt AG company manufacturing: ABIL EM-90, other composition use as the material commercially available product of raw material of making up.

Table 23

Embodiment 15: eye is color

[modulation and evaluation result that eye is color]

The eye of making prescription shown in the table 24 in the following order is color.

A. heat mixed dissolution composition 1～11 equably.

B. fill the mixture that obtains in the A operation, the eye that obtains paste-like is color.

The eye of gained is color, and the usability during coating is good, and the film sense of cosmetic film, gloss, moist feeling are all excellent, and cosmetic persistency aspect is also satisfactory.In addition, also do not have character such as waste liquid or separation to change, shape retention is good.

In addition, the trade name that composition 2 in the table 24 uses the first industrial pharmacy (strain) to make: Sugar Wax S-10E, composition 3 uses NL Industries, Inc. the trade name made of company: bentone 27, composition 6 uses liquid ester composition 1 of the present invention, composition 7 uses the trade name of clear sharp friend difficult to understand of day (strain) manufacturing: Salacos E-38, other composition use as the material commercially available product of raw material of making up.

Table 24

Embodiment 16: eye shadow

[modulation of eye shadow and evaluation result]

Make the eye shadow of prescription shown in the table 25 in the following order.

A. at 90 ℃ of following heating for dissolving compositions 1～7, add composition 8～12, uniform mixing.

B. add composition 13,14 in the mixture that obtains in the A operation, heating mixes equably, after the deaeration, is filled in the container, is cooled to 5 ℃, obtains bar-shaped eye shadow.

The eye shadow of gained, the usability during coating is good, and the film sense of cosmetic film, gloss, moist feeling are all excellent, and cosmetic persistency aspect is also satisfactory.In addition, shape retention is also good.

In addition, the composition 1 in the table 25 uses liquid ester composition 1 of the present invention, and other composition uses as making up expects with the commercially available product of raw material.

Table 25

Embodiment 17: suppurative mastitis

[modulation of suppurative mastitis and evaluation result]

Make the suppurative mastitis of prescription shown in the table 26 in the following order.

A. mixed dissolution composition 1～4 equably.

B. mixed dissolution composition 5～9 and 11 equably.

C. under 80 ℃, the mixture that obtains in the B operation is added in the mixture that obtains in the A operation, carry out emulsifying.Behind the adding ingredient 10, cooling obtains suppurative mastitis.

The suppurative mastitis of gained, the usability during coating is good, the gloss of cosmetic film, moist feeling excellence, cosmetic persistency aspect is also satisfactory.In addition, leave standstill under the room temperature and also found separation etc. in 1 month, stability is also good.

In addition, the composition 4 in the table 24 uses liquid ester composition 1 of the present invention, and composition 6 uses the trade name of nihon emulsion (strain) manufacturing: EMALEX 503, and other composition uses as the material commercially available product of raw material of making up.

Table 26

Claims

1. a liquid ester composition is characterized in that, it carries out the liquid ester composition that esterification obtains for branched chain type isostearic acid and dipentaerythritol, the viscosity of this liquid ester composition under 25 ℃ is 100,000～2,000,000 mPas, hydroxyl value is 10～160,5 ℃ of cloud point less thaies

Described branched chain type isostearic acid is 2-(1,3, a 3-trimethyl) butyl-5,7, and the 7-trimethyl is sad,

This liquid ester composition is by in the presence of catalyst, in 200～250 ℃, makes dipentaerythritol and branched chain type isostearic acid carry out 10～40 hours esterifications with 10: 35～10: 90 mass ratio and obtains.

2. liquid ester composition according to claim 1 is characterized in that, uses dipentaerythritol and branched chain type isostearic acid with 10: 39～10: 72 mass ratioes.

3. liquid ester composition according to claim 1 is characterized in that, acid number is below 10.

4. liquid ester composition according to claim 1 is characterized in that, hydroxyl value is 20～140.

5. liquid ester composition according to claim 1 is characterized in that, cloud point is below 0 ℃.

6. the material of making up is characterized in that, contains each described liquid ester composition in the claim 1～5.

7. cosmetic material according to claim 6 is characterized in that, the material of making up is selected from make up in the group that material forms a kind of cosmetic cosmetic material, emulsion, facial cream, sunscreen and Hair grooming,

Cosmetic is made up and is expected to be meant lipstick, lip gloss, lip gloss, foundation cream, rouge, eye coloured silk, eye shadow, informer, mascara or nial polish,

Hair grooming makes up that material is meant suppurative mastitis, becomes visible, moulding mousse, hair styling gel having or moulding pomade.

8. a cosmetic is made up and is expected, it is characterized in that, contains each described liquid ester composition and oil-base gel agent in the claim 1～5.

9. cosmetic according to claim 8 is made up and is expected, it is characterized in that, cosmetic is made up and expected to be solid shape, contains 3～90 quality % liquid ester compositions, 2～30 quality % oil-base gel agent.

10. cosmetic according to claim 8 is made up and is expected, it is characterized in that, this cosmetic is made up and expected to be paste-like, contains 3～90 quality % liquid ester compositions, 0.001～10 quality % oil-base gel agent.

11. each described liquid ester composition continues the purposes of agent in the claim 1～5 as the cosmetic overlay film.

12. purposes according to claim 11 is characterized in that, described cosmetic overlay film continues to contain 50～100 quality % liquid ester compositions in the agent.