CN1969592B - Ceramic heater and production method therefor and hair iron - Google Patents
Ceramic heater and production method therefor and hair iron Download PDFInfo
- Publication number
- CN1969592B CN1969592B CN2005800203058A CN200580020305A CN1969592B CN 1969592 B CN1969592 B CN 1969592B CN 2005800203058 A CN2005800203058 A CN 2005800203058A CN 200580020305 A CN200580020305 A CN 200580020305A CN 1969592 B CN1969592 B CN 1969592B
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- ceramic
- conductor
- heater
- heating
- green sheet
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- 239000000919 ceramic Substances 0.000 title claims abstract description 194
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 48
- 229910052742 iron Inorganic materials 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000004020 conductor Substances 0.000 claims abstract description 79
- 230000015572 biosynthetic process Effects 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 22
- 238000007650 screen-printing Methods 0.000 claims description 11
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 238000011049 filling Methods 0.000 claims description 3
- 238000003475 lamination Methods 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 abstract description 11
- 239000011800 void material Substances 0.000 abstract description 5
- 238000010438 heat treatment Methods 0.000 description 202
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 53
- 238000005755 formation reaction Methods 0.000 description 18
- 239000000463 material Substances 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 239000000203 mixture Substances 0.000 description 11
- 230000014509 gene expression Effects 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 238000000576 coating method Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 230000006866 deterioration Effects 0.000 description 7
- 239000000523 sample Substances 0.000 description 7
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 7
- 238000005476 soldering Methods 0.000 description 7
- 229910052581 Si3N4 Inorganic materials 0.000 description 6
- 238000005452 bending Methods 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
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- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 238000005245 sintering Methods 0.000 description 5
- 230000003746 surface roughness Effects 0.000 description 5
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- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 4
- 239000000292 calcium oxide Substances 0.000 description 4
- 210000000078 claw Anatomy 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
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- 239000010931 gold Substances 0.000 description 3
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- 238000013508 migration Methods 0.000 description 3
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- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 229910001120 nichrome Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000003870 refractory metal Substances 0.000 description 3
- 229910052702 rhenium Inorganic materials 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 2
- 229910017944 Ag—Cu Inorganic materials 0.000 description 2
- 229910002708 Au–Cu Inorganic materials 0.000 description 2
- 229910017398 Au—Ni Inorganic materials 0.000 description 2
- 229920002160 Celluloid Polymers 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000003321 amplification Effects 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
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- 239000003085 diluting agent Substances 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
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- 238000010304 firing Methods 0.000 description 2
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- 239000002075 main ingredient Substances 0.000 description 2
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- 238000003199 nucleic acid amplification method Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- RBNWAMSGVWEHFP-UHFFFAOYSA-N trans-p-Menthane-1,8-diol Chemical compound CC(C)(O)C1CCC(C)(O)CC1 RBNWAMSGVWEHFP-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910017083 AlN Inorganic materials 0.000 description 1
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 206010020843 Hyperthermia Diseases 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910016006 MoSi Inorganic materials 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
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- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000009193 crawling Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
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- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036031 hyperthermia Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
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- 230000002093 peripheral effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 150000003657 tungsten Chemical class 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D1/00—Curling-tongs, i.e. tongs for use when hot; Curling-irons, i.e. irons for use when hot; Accessories therefor
- A45D1/02—Curling-tongs, i.e. tongs for use when hot; Curling-irons, i.e. irons for use when hot; Accessories therefor with means for internal heating, e.g. by liquid fuel
- A45D1/04—Curling-tongs, i.e. tongs for use when hot; Curling-irons, i.e. irons for use when hot; Accessories therefor with means for internal heating, e.g. by liquid fuel by electricity
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/18—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor the conductor being embedded in an insulating material
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/22—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible
- H05B3/28—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material
- H05B3/283—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material the insulating material being an inorganic material, e.g. ceramic
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/40—Heating elements having the shape of rods or tubes
- H05B3/42—Heating elements having the shape of rods or tubes non-flexible
- H05B3/48—Heating elements having the shape of rods or tubes non-flexible heating conductor embedded in insulating material
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D1/00—Curling-tongs, i.e. tongs for use when hot; Curling-irons, i.e. irons for use when hot; Accessories therefor
- A45D2001/004—Curling-tongs, i.e. tongs for use when hot; Curling-irons, i.e. irons for use when hot; Accessories therefor with a ceramic component, e.g. heater, styling surface
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/002—Heaters using a particular layout for the resistive material or resistive elements
- H05B2203/003—Heaters using a particular layout for the resistive material or resistive elements using serpentine layout
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Resistance Heating (AREA)
- Surface Heating Bodies (AREA)
Abstract
A ceramic heater which can prevent a reduction in insulation at high temperature and is excellent in durability, and which comprises a ceramic body having an outer surface and a buried conductor pattern, wherein the conductor pattern is formed as a conductor so provided as to form a turned-back portion working as a resistance heater, and the void share of a ceramic unit held between adjacent conductors ranges from 0.01 to 50% at the turned-back portion.
Description
Technical field
The present invention relates to the transducer heater, ceramic heater that the air-fuel ratio detecting sensor heating of particularly using at automobile is used with aspects such as heater, hair iron (hair iron), soldering irons with, vaporizer and heater and the hair iron that adopts its formation.
Background technology
All the time, be in the pottery of principal component with the aluminium oxide, bury the formed aluminium oxide ceramics heater of heating resistor that constitutes by refractory metals such as W, Re, Mo underground and be widely used.
For example, when making the cylindrical ceramic heater, as shown in figure 10, preparation ceramic formation body 12 and ceramic green sheet 13, on a face of ceramic green sheet, form the heating resistor 14 and the lead-in wire lead division 15 that constitute by refractory metals such as W, Re, Mo, after (another side) forms electrode pad overleaf, become inboard mode with heating resistor 14 and lead-in wire lead division 15 and ceramic formation body 12 is reeled and connected airtight burn till.The lead division 15 that wherein goes between is connected (for example, with reference to patent documentation 1) with electrode pad by formed perforation 16 on the ceramic green sheet.
So, ceramic heater in the past, be with paste (paste) shape heating resistor 14 and ceramic formation body 12 and ceramic green sheet 12 burn till simultaneously form.Then, the heating resistor of the ceramic heater of so making forms tortuous shape (Fig. 1 of patent documentation 2 etc.) through repeatedly turning back.
In addition, disclose following content in patent documentation 3～patent documentation 5: a pair of base portion of controlling parts connects by axle freely openable ground, tension force by the spring set in the bearing portion, two leading sections of controlling parts are opened up to each other at ordinary times, possess the hair iron of heating plate simultaneously in two inboards of controlling the peristome of parts leading section.
This hair iron has following structure: the nichrome wire of on the insulation board of ceramic, reeling, and the two sides is further surveyed on plate body by the heating plate that insulation board covered closed, perhaps to push by leaf spring, the heat that heating plate is sent is delivered on the plate body.
Patent documentation 1: the spy opens the 2001-126852 communique
Patent documentation 2: the spy opens the 2001-102156 communique
Patent documentation 3: the spy opens the 2000-232911 communique
Patent documentation 4: the spy opens the 2002-291517 communique
Patent documentation 5: the spy opens the 2000-14438 communique
But ceramic heater is used under the higher temperature environment gradually recently, so the durability reduction has just become problem.That is, when carrying out switching on continuously under the high temperature, the insulating properties deterioration between adjacent patterns, durability reduce, and final generation as initiation are for a moment cremated, for a moment Duan Xian problem.
In addition, on insulation board, the reel heater of the heater made that constitutes by nichrome wire, break because of heating energising repeatedly, heater and airborne reaction of moisture form conversion zone, it is big that the resistance value of heater just becomes, and has the problem that the danger that can not reach uniform temperature under the certain voltage and durability lower.
In addition, the heating plate that is made of nichrome wire is difficult in heater is set on the heating plate equably, has the problem that the heating surface of plate body can not evenly heat.
In addition, because do not contact with same temperature, the heat of heating plate is difficult on the plate body and propagates equally the heating surface of heating plate, has the uneven temperature problem of heating surface with tabular dignity.
Summary of the invention
The 1st purpose of the present invention used for reference the formed parts of above-mentioned thing, provides to prevent that insulating properties reduces under the high temperature, the ceramic heater that durability is good.
The 2nd purpose of the present invention provides the heater and the hair iron that can evenly heat the plate body heating surface in addition.
In order to reach above the 1st purpose, the feature of ceramic heater of the present invention is: comprise ceramic body, the conductive pattern that this ceramic body has outer surface and buried underground, described conductive pattern is made of conductor, described conductor is set up according to the mode that formation becomes the return portion of resistance heater, emptying aperture occupation rate by the folded ceramic part of the conductor of adjacency in described return portion is 0.01～50%, the length along described outer surface of the emptying aperture that exists between described contiguous conductor is, below 1/2 length of this conductor separation.
Here, folded ceramic part between so-called above-mentioned contiguous conductor, be defined as be with this conductor have in fact identical thickness and along above-mentioned outer surface as in the interior zone, be clipped in the ceramic segment between conductor.
In addition, the 1st manufacture method of ceramic heater of the present invention, its feature comprises:
Form the operation of conductor paste by the pattern of regulation on the first ceramic green sheet surface,
With on the face of the formation conductor paste of this first ceramic green sheet, lamination has and same thickness of this conductive pattern and second ceramic green sheet more soft than above-mentioned first ceramic green sheet at least, the operation of making the ceramic green sheet duplexer,
With the operation of this ceramic green sheet duplexer of bonding on ceramic formation body,
With the ceramic green sheet duplexer that burns till this bonding and the operation of ceramic formation body.
In addition, the 2nd manufacture method of ceramic heater of the present invention is characterized in that comprising:
Pattern in accordance with regulations forms the operation of conductor paste on the surface of ceramic green sheet,
And in the afore mentioned rules pattern, fill the operation of insulant between the conductor paste,
And will between this conductor paste, fill the ceramic green sheet of insulant, the face that forms above-mentioned conductor paste is bonded in operation on the ceramic formation body as adhesive surface,
With the operation of burning till this bonding ceramic green sheet and ceramic formation body.
In addition, in order to reach above-mentioned the 2nd purpose, heater of the present invention is characterized by, and possesses:
Heating plate, it is made of the tabular ceramic body of being buried underground resistance heater, has the thickness of 0.5～5.0mm scope; With
Plate body, it has the 1st and the 2nd, at described the 1st described heating plate is set, with described the 2nd as heating surface, this heating surface is made of planar portions and its peripheral chamfered section.
Described hair iron of the present invention is characterized by: adopt ceramic heater of the present invention or heater of the present invention and constitute.
More than the described ceramic heater of invention because the emptying aperture occupation rate of ceramic body is 0.01～50% between above-mentioned conductor, so can prevent that insulating properties reduces under the hot conditions, can provide durability high ceramic heater.
That is, the invention of ceramic heating body is if the emptying aperture occupation rate of finding the ceramic part between above-mentioned conductor within the specific limits the time, just can prevent insulating properties reduction under the hot conditions, and finish the present invention.
In addition, heater of the present invention, because of in tabular ceramic body, burying resistance heater underground, so situation of exposure resistance heater in steam etc. not, thereby durability brilliance, can heat rapidly repeatedly simultaneously, and the temperature difference in the heating surface can be very little, therefore heating heating object equably becomes possibility.
And then hair iron of the present invention by possessing ceramic heater of the present invention or heater of the present invention, can have high durability.
In addition, on hair iron of the present invention,,, for example can not occur hair is carried out heat partly and cause the hair iron of damage so can provide because can not produce portion of localized hyperthermia at heating surface by possessing heater of the present invention.
Description of drawings
Fig. 1 is partly cut-away's stereogram of structure of the ceramic heater of expression embodiments of the present invention 1.
Fig. 2 is the profile of X-X line of the ceramic heater of Fig. 1.
Fig. 3 is the amplification profile between the conductor of cylindrical ceramic heater of expression execution mode 1.
Fig. 4 is the amplification profile between the conductor of tabular ceramic heater of variation of expression execution mode 1.
Fig. 5 is the end view of the hair iron component part otch of expression embodiment of the present invention 2.
Fig. 6 is the heating plate of hair iron of expression application drawing 5 and the front view of plate body position relation.
Fig. 7 is the X-X profile of presentation graphs 6.
Fig. 8 is the profile of heater of the variation of expression embodiment of the present invention 2.
Fig. 9 is the vertical view that is illustrated in the heating plate of using in the heater of execution mode 2.
Figure 10 is the expanded view of ceramic heater in the past.
Among the figure: 1-ceramic heater, 2-pottery core, 3-potsherd, 4-heating resistor, the 5-lead division that goes between, 6-through hole, 7-electrode pad, 8-lead member, zone between A-cylindrical ceramic heater conductor, zone between B-tabular ceramic heater conductor, the 5-heater, 50-controls parts, the 52-axle, 53-helical spring, 54-bearing portion, the 55-plate body, 55a-heating surface, 57-heating plate, the 58-resistance heater, 59-spring, 61-lead-in wire.
Embodiment
Below, with reference to the description of drawings embodiments of the present invention.
Fig. 1 is the part cutaway drawing of the ceramic heater 1 of embodiment of the present invention 1.Fig. 2 is the X-X profile of Fig. 1.
The feature of the ceramic heater 1 of present embodiment 1 be in the ceramic body that constitutes by ceramic core 2 and potsherd 3 in the dress heating resistor 4.Here, heating resistor 4 is made of the return portion of conductive pattern, and in the part that forms this heating resistor 4, the emptying aperture of ceramic body (void) occupation rate is 0.01～50% between proximity conductor.
This ceramic heater 1 is to form heating resistor 4 and lead-in wire lead division 5 on the surface; Form the ceramic green sheet (burn till back for potsherd 3) of electrode pad 7 overleaf, make heating resistor 4 and lead-in wire lead division 5 become the inboard, be wound on the ceramic formation body (burn till the back and be ceramic core 2), obtain by connecting airtight to burn till.Wherein, lead-in wire lead division 5 is connected by formed through hole 6 on potsherd 3 with electrode pad 7.
Ceramic body is made of the ceramic core 2 of Low fire ceramic formed body and the potsherd 3 of Low fire ceramic raw cook.This ceramic body is made of various potteries such as aluminum oxide pottery, silicon nitride pottery, aluminium nitride matter pottery, the siliceous potteries of carbonization, special advantageous applications aluminium oxide or silicon nitride be as the parts of important composition, can obtain to heat up rapidly and the ceramic heater 1 of durability brilliance with this.For example, when adopting aluminium oxide (Alumina), preferably adopt by Al
2O
3: 88～95 weight %, SiO
2: 2～7 weight %, CaO:0.5～3 weight %, MgO:0.5～3 weight %, ZrO
2: the aluminium oxide that 1～3 weight % constitutes.If Al
2O
3When containing quantity not sufficient 88 weight %, then because the nature of glass increases the danger with migration (migration) increase during energising.On the other hand, if Al
2O
3When content surpasses 95 weight %, then because the amount of glass of the interior diffusion of the metal level of the heating resistor 4 of inside dress reduces the danger with durability deterioration of ceramic heater 1.In addition, when adopting the siliceous pottery of carbonization, with respect to the Main Ingredients and Appearance silicon nitride, as the rare earth oxide of preferred 3～12 weight % of sintering adjuvant and the Al of 0.5～3 weight
2O
3, and then as the SiO that contains in the sintered body
2Amount, SiO
2Be mixed into 1.5～5 weight % as far as possible.The SiO here
2The SiO that amount generates for the oxidation of impurities that contains in the silicon nitride raw material
2, the impurity that contains of other additives SiO
2SiO with the intention interpolation
2Summation.In addition, by making the MoSi in the mother metal silicon nitride
2Or WSi
2Disperse, the coefficient of thermal expansion of the coefficient of thermal expansion of mother metal and heating resistor 4 is approaching, thereby can improve the durability of heating resistor 4.
In addition, heating resistor 4 is made of the conductive pattern that crawls, and to connect resistance value with respect to this heating resistor 4 be about 1/10 lead-in wire lead division 5.Usually in order to simplify these operations, on ceramic green sheet, (burn till the back and form potsherd 3) that to print the situation that forms heating resistor 4 and lead-in wire lead division 5 simultaneously more.Wherein, return portion of the present invention is phase resistance value and contain the turn back parts of the shape or the shape of crawling of U word in order to reach.
Here, about the size of ceramic heater 1, for example not having external diameter can be wide 2～20mm, about long 40～200mm.As the ceramic heater 1 of Automotive Air Fuel Ratio transducer heating usefulness, preferred external diameter and wide be 2～4mm, length is 50～65mm.In addition, the heating length at automobile preferred heating resistor 4 aspect purposes is 3～15mm as far as possible.When heating was shorter in length than 3mm, the intensification during energising can be very fast, but the durability of ceramic heater 1 has been reduced.When heating length was longer than 15mm, programming rate was slack-off, wants to accelerate programming rate, and the electric power that ceramic heater 1 consumes must become greatly, does not therefore preferably adopt.Wherein, so-called heating length is the length of heating resistor 4 length directions that crawl shown in Figure 1, and this heating length is suitably selected according to this purpose purposes.
Wherein, although in Fig. 2, between ceramic core 2 and potsherd 3, drawn the boundary line, after ceramic formation body that does not in fact burn till and the ceramic green sheet bonding, through burning till the border that does not have under a lot of situations as this adhesive surface.
When present embodiment 1, preferably on the electrode pad 7 of ceramic heater 1, form and burn till back 1 electrodeposited coating.This 1 electrodeposited coating, when the surperficial soldering lead member 8 at electrode pattern 7, it is good that braze is flowed, and has the effect that increases soldering strength.1 time electrodeposited coating increases preferred because of connecting airtight power when thickness is 1～5 μ m.As the material of an electrodeposited coating, preferred Ni, Cr or be the composite material of Main Ingredients and Appearance with these compositions, and then be the plating of main composition with the Ni of durability brilliance preferably.
In addition, when in the atmosphere of high humility, using, adopt the braze of Au system, Cu system preferred because of being difficult for that migration takes place.As braze, the material of Au, the Cu that preferred thermal endurance is high, Au-Cu, Au-Ni, Ag, Ag-Cu system.In order to improve durability, especially further preferred Au-Cu soldering, Au-Ni soldering, Ag-Cu soldering.Surface in braze is preferably formed 2 electrodeposited coatings that are made of Ni usually in order to improve high temperature durability and to protect braze to be corroded.
In addition, as the material of lead member 8, because in use pass the heat that comes by heating resistor 4 temperature of lead member 8 is risen, preferably using thermal endurance good Ni system or Fe-Ni is alloy etc.
And, feature of the present invention have following some, in the ceramic heater 1 of interior dress conductive pattern, conductive pattern has the return portion that constitutes heating resistor 4, the emptying aperture occupation rate of the ceramic body in this return portion between adjacent any conductor is 0.01～50%.And the emptying aperture occupation rate of the ceramic body in this return portion between adjacent any conductor and then preferred 0.1～40% is more preferably 1～20%.During emptying aperture occupation rate less than 0.01%, if heat up rapidly repeatedly and rapid cooling, when the heating resistor 4 of heating part adds thermal expansion, because the loss of the heat of the pottery around the heating resistor 4 is insufficient, the thermal expansion of ceramic body can not be followed the thermal expansion of heating resistor 4, cause stress to focus on the edge portion 41 of heating resistor, have the danger that the fracture broken string takes place.On the other hand, when this emptying aperture occupation rate greater than 50% the time, when switching on continuously under hot conditions, the insulating properties deterioration of the ceramic body in the heating part around the heating resistor 4 has the tendency that durability reduces.Wherein, directly the bonding ceramic green sheet connects airtight when burning till it on ceramic formation body, just becomes than the bigger numerical value of above-mentioned scope emptying aperture occupation rate.Therefore, in order to reach the void content of above-mentioned scope, adopted following manufacture method.
Fig. 2 is the expression and the routine profile (X-X line profile shown in Figure 1) of length direction vertical cross section, and the conductor of return portion (heating resistor 4) that is illustrated in conductive pattern is at the configuration mode of the periphery circle of ceramic core 2.Here, the emptying aperture occupation rate of ceramic body is 0.01～50% between so-called conductor, and the meaning is that the emptying aperture occupation rate of ceramic body when between any proximity conductor pattern of mensuration (4a among Fig. 3 and 4b) is 0.01～50%.So ceramic body emptying aperture occupation rate is 0.01～50% part, can be any part of cutting off the section of heating resistor 4 in the direction vertical with length direction.Wherein, between so-called conductor be, when ceramic body when being cylindric, as shown in Figure 3, be (to change and put into words along ceramic core 2 peripheries circle, the outer surface of ceramic body) connects the line of proximity conductor 4a top and 4b top and the line of and 4b bottom following, the zone of the regional A that is coated on conductor 4a, 4b surface along the periphery circle bonding conductor 4a of ceramic core 2; In addition, when ceramic body is tabular, as shown in Figure 4, be to connect the line of proximity conductor 4c top and 4d top and the line of bonding conductor 4c bottom and 4d bottom, coat the zone of area B on the surface of conductor 4c, 4d.
In addition, in this manual, so-called conductor forms the zone, is meant when ceramic body when being cylindric the periphery of ceramic core 2 and the folded circle ring area between the periphery of conductor thickness outward along this periphery from this periphery; When ceramic body is tabular, as each conductor top connecting line of connection with as connecting folded interior zone between each conductor bottom connecting line.That is, between conductor, form position part between conductor adjacent in the zone at conductor as above-mentioned definition.
And then, in the ceramic heater of present embodiment 1, be preferably below 1/2 of conductor separation along the length of existing emptying aperture outer surface between contiguous conductor.That is,, on the free-throw line that connects between contiguous conductor, preferably do not exist length to surpass 1/2 the emptying aperture of this line length (distance between conductors) in the ceramic body between conductor along outer surface in the conductive pattern return portion.When the length of emptying aperture surpass distance between conductors 1/2 the time, when switching on continuously under the hot conditions, the insulating properties of ceramic body of heating resistor 4 that coats the heating part is with regard to deterioration, so durability is with regard to deterioration.Wherein, so-called free-throw line is as shown in Figure 3 when for columned ceramic heater, the line arbitrarily of adjacent conductor 4a and 4b in the outer surface join domain A.At this moment free-throw line serve as reasons round center that the profile (outer surface of ceramic body) of profile of cylindrical ceramic heater as shown in Figure 3 constitutes with have roughly concentric circular-arc curve; In addition, when tabular ceramic heater as shown in Figure 4, the arbitrary line of adjacent conductor 4c and 4d is called free-throw line among the join domain B.
And then conductive pattern among the present invention particularly constitutes preferred 5～100 μ m of conductor thickness of heating resistor.When conductive pattern thickness less than 5 μ m,, when durable continuously, the high thermoperiod long duration test of high temperature, cause the resistance variations and the broken string of the heating resistor 4 of heating part, the durability deterioration although can prevent emptying aperture between contiguous above-mentioned arbitrarily conductor.On the other hand, when conductive pattern thickness surpasses 100 μ m, has void content between any conductor that is difficult to suppress adjacent and is the tendency below 50%.
Next the ceramic body emptying aperture occupation rate between the contiguous any conductor of explanation reaches 0.01～50% method.
As an example, can adopt following method: form conductive pattern on first ceramic green sheet surface, form the side lamination at the conductive pattern of first ceramic green sheet and have at least and the roughly the same second more soft ceramic green sheet of ratio first ceramic green sheet that preferably has the same thickness of the thickness of conductive pattern.According to this method, bury the second soft ceramic green sheet underground by thickness space partly at conductive pattern, can get rid of the emptying aperture between pattern.Here, second ceramic green sheet need be than the first ceramic green sheet softness, because when second ceramic green sheet is soft, when boning second ceramic green sheet on first ceramic green sheet of implementing conductive pattern, at least the central part between conductor can connect airtight between two ceramic green sheets.Here, the hardness of this ceramic green sheet is measured by digital indicator (ミ Star ト ヨ system), the pin of preferred φ 1mm 30 seconds depths of invasion more than 200 μ m.The hardness of ceramic green sheet during promptly above-mentioned depth of invasion less than 200 μ m, forms emptying aperture because can not closely contact between conductor.Wherein in order to reduce the space between pattern, can the working pressure machine etc. exert pressure.
In addition, as other method, the method that can adopt screen printing to stick with paste.This method is as described below to be finished.At first, on ceramic green sheet, carry out screen printing heating resistor 4 and lead-in wire lead division 5.At this moment, at the paste of screen printing coating for mixing the adhesive of the organic resin system that constitutes as the powder and the bonding composition of principal component by refractory metal (W, Mo, Re etc.), be mainly ethyl cellulose, celluloid and, be mainly the material that T.P.O (terpinol), D.B.P (dibutyl phthalate), D.O.P (dioctyl phthalate), B.C.A (diethylene glycol monobutyl ether acetate) etc. form as the organic solvent that diluent adopted.These pastes of printing in original thickness is 5～150 mu m ranges.In addition, reach about 10 times mode of the resistance value that is approximately lead-in wire lead division 5, adjust the ratio resistance etc. of live width, print thickness or paste and form conductive pattern with the resistance value of heating resistor 4.Then, in order to fill the space of thickness portion between proximity conductor, the paste that contains insulant is implemented screen printing.At this moment the paste of the Cai Yonging high melting point insulant of serving as reasons, the main and same composition of ceramic green sheet is promptly by Al
2O
3: 88～95 weight %, SiO
2: 2～7 weight %, CaO:0.5～3 weight %, MgO:0.5～3 weight %, ZrO
2: being mixed with the organic resin that is made of bonding composition in the aluminium oxide ceramics that 1～3 weight % constitutes is adhesive, be mainly ethyl cellulose, celluloid and, be mainly the material that T.P.O (terpinol), D.B.P (dibutyl phthalate), D.O.P (dioctyl phthalate), B.C.A (diethylene glycol monobutyl ether acetate) etc. form as the organic solvent that diluent adopted.And then, also can use single alumina composition or specific volume resistance 10 as sticking with paste except ceramic green sheet is formed
8The material that Ω is above with insulating properties.Here, the viscosity of paste is preferably adjusted in 50dPa.s～1000dPa.s scope, prints.Although when stick with paste viscosity be 50dPa.s when following printing performance good, because of raw material density is low, dry to shrink quantitative change big, produces difference of height in conductive pattern top portion, is easy to generate emptying aperture after burning till.In addition, viscosity is 1000dPa.s when above, because of the reduction of leveling (leveling) property, is easy to generate emptying aperture in the tunicle, thereby not preferred.Wherein, screen printing is to carry out on the web plate with heating resistor and the counter-rotating of lead-in wire lead division.
And then, can adopt the fill method of using distributor (dispenser) as additive method.As mentioned above, sticking with paste viscosity is the above material of 1000dPa.s, and setting high raw material density becomes possibility, in order to produce the dry amount of contraction that causes of shrinking in Min. ground, although the space between conductor is reliably filled, not preferred during the method for usefulness screen printing, and can not adopt.Therefore, when using full-bodied pastes like this, can preferably adopt the fill method of application distributor.
So, using screen printing or using the method for distributor, is not on the conductive pattern but can fill on this aspect of insulant to say it is effective method between conductor.
Wherein, in the embodiment of the invention, the ceramic body that burns till about coiling ceramic green sheet in the cylindrical ceramic formed body has been done clearly indication, but the present invention also comprises: the tabular ceramic formation body or in ceramic green sheet bonding burn till the ceramic body that the ceramic green sheet of the printing of implementing conductor etc. forms.
Execution mode 2
Next the heater 51 of execution mode 2 of the present invention is described.
Fig. 5 is the end view of the part shortcoming of a configuration example of the hair iron 100 of expression use present embodiment 2 heaters 51.In this Fig. 5,50 for controlling parts, and 52 for connecting a pair of axles of controlling parts of freely openable, and 53 keep two helical springs of power of open direction of controlling the leading section of parts at ordinary times for installation in bearing portion 54.55 embed opposed facing plate body 55 respectively for controlling two in the set peristome 56 of the leading section of parts 50.The heating plate at plate body 55 back sides is connected airtight in 57 expressions.
Fig. 6 represents from Fig. 5 heater 51 front view of the position relation of the heating plate 57 that takes out and plate body 55, and Fig. 7 is this X-X line profile.The heat of heating plate 57 can evenly heat the opposing party's of plate body 55 the heating surface 55a that interarea had like this by the interarea 55b that a side's of heating plate 57 interarea 57a passes to plate body one side.
Because of formation like this is arranged, use the heating plate 57 of small-sized ceramic efficient evenly to heat plate body 55 well with big heating surface 55a.
Promptly, the heater 51 of present embodiment 2 is made of the plate body 55 of the heating plate 57 of burying resistance heater 58 in tabular ceramic body underground with the heating surface 55a that possesses the heating heating object, and side's interarea 55b of plate body 55 and side's interarea 57a of above-mentioned heating plate 57 contact.So feature of the present invention is: the C face that above-mentioned heating surface 55a is possessed by planar portions and its periphery or the chamfered section of curved surface constitute, and the thickness H of heating plate 57 is 0.5～5mm.Heating plate 57 has been buried resistance heater 58 underground in tabular ceramic body inside, and resistance heater 58 has been blocked air, and resistance heater 58 can prevent to contain in the air corrosion of moisture etc.In addition, the resistance heater of burying underground in tabular ceramic body inside 58 is because itself have resistance, and joule generates heat to set point of temperature when certain electric power prints down, and heating plate 57 can be warming up to desired set point of temperature as heater.
So,, also seldom have pair heating object to cause the danger of damage even heating object was inserted into when sliding on heating surface 55a because the C face that above-mentioned heating surface 55a is possessed by planar portions and its periphery or the chamfered section of curved surface constitute.So, during hair, in order hair not to be caused damage, the preferred Wc of its size was 0.1～5mm when above-mentioned chamfered section was the C face, and then preferred 0.3～4mm during heating object.More preferably 1～3mm.In addition, when above-mentioned chamfered section was curved surface, so-called curved surface was exactly by circular arc type or 2 formed zones of curve, so little preferred because of the damage that heating object is caused when its wide Wr is 0.2～5mm in the vertical section of end face.And then preferred 0.3～4mm, more preferably 1～3mm.
In addition, when the thickness H of heating plate 57 was 0.5～5.0mm, the heat of heating plate 57 can be passed to plate body 55 efficiently.During the thickness of heating plate 57 is not enough 0.5mm, the flatness of plate body 55 1 side's interareas will be greatly to 0.02～0.2mm, and therefore stress application when heating plate 57 is installed then has the danger of heating plate 57 breakages.
In addition, when the thickness of heating plate 57 surpasses 5mm, even heating plate 57 is installed in plate body 55, one side's interarea 57a of heating plate 57 is also indeformable, one side's of heating plate 57 an interarea 57a and a side's of plate body 55 interarea 55b just can not contact by wide area, therefore just can not evenly heat the heating surface 55a of plate body 55.
Therefore, when heating plate 55 thickness were 0.5～5mm, heating plate 57 1 sides' interarea 57a and plate body 55 1 side's interarea 55b can be out of shape identical respectively, so extensively heat heating surface 55a under the even temperature.More preferably heating plate 55 thickness are 1～3mm.
In addition, between plate body 55 1 sides' interarea 55b and heating plate 57 1 side's interarea 57a, preferably possesses conducting-heat elements 63.Above-mentioned surface roughness is that heating plate 57 heat conduction between square interarea 57a and plate body 55 1 side's interarea 55b of Ra becomes easier when having conducting-heat elements 63, and the heat of heating plate 57 can efficiently be passed to plate body 55 and preferred.
Conducting-heat elements 63 is preferably the resin that silicon is the big metal particle powder of resin or heat of mixing conductivity.As big gold, silver, copper, the nickel of the preferred hot transmission rate of above-mentioned metal particle powder, and then preferred silver.In addition, can adopt silicon as resin is resin or fluorine material resin.And then, when conducting-heat elements is can be between plate body 55 1 side's interarea 55a and heating plate 57 1 side's interarea 57a very close to each other, even because of the thermal expansion difference of 57 of above-mentioned plate body 55 and heating plates telescopic slide takes place, by conducting-heat elements 63 heat conduction between interarea 55a and the interarea 57a is not changed, can prevent that the temperature difference of heating surface 55a from becoming excessive and preferred.
In addition, the surface roughness Ra of heater 51 preferred heating plate 57 1 side's interarea 57a of the present invention is 1～30.When the roughness Ra of heating plate 57 1 side's interarea 57a is not enough 1.0 the time, be difficult to conduction heat as one man by contact-making surface with plate body 55, therefore just have and be heated that temperature difference becomes big danger in the face 55a face.The surface roughness Ra that is more preferably heating plate 57 1 side's interareas is 3～10.
Fig. 5,6 heater 51 push heating plate 57 by the claw 55c of plate body 55 makes plate body 55 contact (Fig. 7) with heating plate 57, replace and directly push heating plate 57 with claw 55c, push heating plate 57 with the spring of being fixed on the claw 59 as shown in Figure 8, can make plate body 55 1 sides' interarea 55b and heating plate 57 1 sides' interarea 57 pass through the elasticity face contact.By setting the press section of a plurality of springs 59, heating plate 57 is contacted in can broad range with plate body 55 thereby preferred.So, the parts that spring 59 preferably is made of the latch plate that possesses a plurality of fulcrums.
In addition, tabular ceramic body of the present invention is preferably with any pottery as principal component of aluminium oxide, mullite or silicon nitride.The preferred pyroconductivity of above-mentioned pottery is bigger, good corrosion resistance, the big pottery of insulation resistance under the hot conditions.
In addition, when tabular ceramic body is aluminium oxide, preferred 80～98 quality % of this aluminium oxide amount.Because such parts can reach above-mentioned tabular ceramic body pyroconductivity be under 16.7～25.21W/ (m.K), the 300 ℃ of hot conditionss insulation resistance 10
13Ω .cm is above, bending strength is more than 300MPa.When aluminium oxide amount during less than 90 quality %, increased sintering adjuvant or impurity such as Mn, Ca, Si, therefore just have the danger that insulation resistance reduces under the hot conditions.
In addition, when alumina content surpassed 99.5 quality %, sintering adjuvant was few, made its dense sintering just become difficult when the situation of the ratio lower temperature below 1700 ℃, so produced also just difficult at a low price in a large number.
In addition, plate body 5 of the present invention is preferably the metal of conductivity.The metal fever conductivity reaches more than the 200W/ (m.K), therefore can pass to heating surface 55a to the heat of heating plate 7 equably.As the preferred aluminium of above-mentioned metal, iron or these alloy.Preferably the coefficient of expansion that constitutes plate body 5 by metal is 8～25 * 10
-6/ ℃ below, the scope of the thermal coefficient of expansion of preferred especially tabular ceramic body 57 is near 8～17 * 10
-6/ ℃.Because of plate body 55 and heating plate 57 have thermal expansion difference, the interval of interarea 57a and interarea 55b just becomes inhomogeneous, and heat conduction just becomes and can not evenly carry out, therefore the danger that just has temperature distribution evenness to suffer damage.And then, although heating object contacts with heating surface 55a from heating surface 55a to heating object conduction heat, but at this moment because heating object contacts simultaneously with heating surface 55a and slides, the danger that static takes place is just arranged at heating surface 55a, when having conductivity on the heating surface 55a, make effect that these static discharge and preferred with regard to having.
In addition, the area of the contact-making surface that contacts with heating plate 57 of plate body 55 is 20～80% of a heating surface 55a area.The danger of the heating surface 55a that can not evenly heat plate body 55 is arranged when less than 20%.In addition, when the area of the contact-making surface that contacts with heating plate 57 when plate body 55 surpassed heating surface 55a area 80%, the price that heating plate 57 becomes big heater 51 uprised, and the danger in industrial very difficult utilization is just arranged.And then the area of preferred contact-making surface is 30～60% of a heating surface 55a area.
In addition, plate body 55 thickness B are preferably 0.2～10mm.This thickness is during less than 0.2mm, with latch plate fixedly during heating plate 57 intensity little, are produced from gaps in plate body 55 distortion, and defective situations such as only contact on one side take place, and therefore have the big danger of temperature difference change in the heating surface 55a face.In addition, even the danger that the big heating of thermal capacitance quantitative change heating plate 57 also has the temperature of the heating surface 55a of plate body 55 not to be rapidly heated when plate body 55 thickness surpass 10mm.Thickness B is 1～3mm more preferably.
In addition, the thickness of so-called heating plate 57 can be represented with 3 mean value in the distance between interarea 55b and the interarea 55a.
So plate body 55 preferably by the parts of the above metal formation of pyroconductivity 200W/ (m.K), possesses claw 55c in order to contact its periphery with 57 of heating plates, preferably increases the thickness of periphery, increases thermal capacity, reduces the parts of heating surface temperature difference.
Next manufacture method and other formations of heater 51 of the present invention are described.
In addition, the lead-in wire 61 of soldered joint is made of metals such as nickel on resistance heater 58 on the above-mentioned opening A, this lead-in wire 61 makes resistance heater 58 be connected with the external electric loop, also plays the effect that resistance heater 58 produces the necessary certain electric power of set point of temperature Joule heat of supplying with by the external electric loop simultaneously.
Lead-in wire 61 utilizes the recess 62 that is provided with at opening A sidewall in exposing the upper central portion of resistance heater 58, accurately weld, simultaneously the braze such as scolding tin 61 that dissolve by supply at this weld part securely soldering on resistance heater 58.
Therefore, heater 51 of the present invention utilizes lead-in wire 61 to supply with resistance heater 58 certain electric power, makes resistance heater 58 send the Joule heat that reaches uniform temperature, and performance is as the function of heater.
In addition, foregoing invention not only is defined in the foregoing description, in the scope that does not break away from main idea of the present invention, can carry out numerous variations, the resistance heater 58 that on above-mentioned execution mode 2, exposes for example, utilize braze bonding wires 61 such as scolding tin, in opening A, strengthen this and engage, also can strengthen joint by covering opening with insulation board in the filling thermal endurance material in opening A by potting resin or glass etc.At this moment, resistance heater 58 and the joint that goes between between 61 become more firm, can be preferred.In addition, although utilize braze bonding wire 61 on resistance heater 58 such as scolding tin in the foregoing description, lead-in wire 61 is welded on the resistance heater 58 also can engages this welding simultaneously for this reason by casting resin or glass etc. in opening A.
Above-mentioned heater 51 is contacted with metal plate body 55 via silicon grease, and this moment is at plate body 55 with also as preferred 5～100 μ m of thickness of the fender of the conducting-heat elements 63 of ceramic heat plate 57.In order to connect ceramic heat plate 57 and the plate body 57 that hair iron is used, when ceramic heat plate 57 is directly contacted with metal heater plate 57, warpage takes place between porcelain ceramic heat plate 57 and the metal plate-like body 55 or during because of heating thermal expansion cause distortion, can not contact the composition surface equably and form contact on one side, point type heat conduction takes place, and the temperature difference with heating surface 55a becomes big danger.Thickness with fender of conducting-heat elements 63 is preferably necessary Min., the opposite blocked up danger that ceramic heater and metallic plate heat conduction deterioration problem will take place, preferred 1～100 μ m of the thickness of conducting-heat elements 63.
In the hair iron of above execution mode 2, heating plate 57 possesses the conductive pattern that constitutes heating resistor 4 return portion of explanation in the execution mode 1, the emptying aperture occupation rate of the ceramic body in this return portion between any conductor of adjacency is preferably 0.01～50% (for example, adopting by the heating plate that constitutes as enforcement mode 1 tabular ceramic heater shown in Figure 4).Like this, because the durability of heating plate 57 can improve, can provide the more hair iron of high-durability.And the emptying aperture occupation rate of the ceramic body between any conductor of the adjacency of this return portion is further preferred 0.1～40%, more preferably 1～20%.
Preparation is with Al
2O
3For principal component is adjusted SiO as far as possible
2, CaO, MgO, ZrO
2Be aggregated in 10 weight % with interior ceramic green sheet, adopt the paste that constitutes by W (tungsten) powder adhesives and solvent, printing heating resistor 4 and lead-in wire lead division 5 on this surface.
In addition, the pole plate 7 that prints electrode overleaf.The shape of heating resistor 4 is to carry out reciprocal pattern 4 times with the heating length of 5mm.
Then, in order to fill insulant between conductor, the paste that will contain insulant carries out screen printing.At this moment, for the occupation rate that makes ceramic body emptying aperture between conductor changes, prepared the material of not implementing screen printing and to sticking with paste that viscosity changes and the material that carries out screen printing.
Then,, form through hole 6, and, make between electrode pad 7 and the lead-in wire lead division 5 and obtain conducting to sticking with paste by injecting here at the end of the lead-in wire lead division 5 that constitutes by W.The position of through hole 6 forms in the mode that enters the inboard of braze welding joint when implementing soldered joint.
Then, around ceramic formation body, connect airtight the ceramic green sheet of preparation, burn till by 1600 ℃ and form ceramic heater 1.
For the ceramic heater 1 that obtains like this, measure resistance variations 1200 ℃ of continuous down energisings after 100 hours, estimate durability.N=10 estimates with each group (lot).
In addition, about the sample of each group n=3, SEM observes the heating resistor 4 after burning till, and measures void content.This result is as shown in table 1.
(table 1)
Each sample material is aluminium oxide, and head-stamp has
*The sample of mark is the sample outside the scope of the invention.
Judge that according to table 1 ceramic body emptying aperture occupation rate surpasses among 50% the sample No9 and in the sample No1 of emptying aperture occupation rate 0.005% between conductor, resistance change breaks more than 15%.Corresponding with it, the emptying aperture occupation rate does not break at the sample below 50%, and expression has favorable durability.
In addition, as long as the emptying aperture occupation rate is in the scope of the invention, other key elements are such as emptying aperture length, black varied in thickness, and are nonsensical to endurance quality.
Embodiment 2
At first, in order to obtain ceramic heat plate as shown in Figure 9, with Al
2O
3For principal component is adjusted SiO as far as possible
2, CaO, MgO, ZrO
2Be aggregated in 10 weight % with on the interior ceramic green sheet, the resistance heater that printing is made of W.The opening A that the resistance heater two ends are exposed has the effect in the zone that forms soldered joint resistance heater and lead-in wire, and it punches by use the perforation processing method in advance on the ceramic green sheet that forms heating plate, and forms in the heating plate end.Above-mentioned opening A further forms recess at the pore size of the corresponding lead-in wire 61 of this sidewall, is used for carrying out at opening A the lead division and the lead-in wire of soldered joint resistance heater.Then, form the coating layer that is made of potsherd and roughly the same composition in the resistance heating surface, after the intensive drying and then the pottery of above-mentioned potsherd and roughly the same composition is disperseed, liquid is connected airtight in coating, the stacked like this potsherd that connects airtight preparation burns till under 1500～1600 ℃.
And then, after the lead division of above-mentioned resistance heater surface forms the thickness that is made of Ni and is the coating of 3 μ m, adopt the braze 62 that constitutes by Ag, in reducing atmosphere, 1030 ℃ engage with Ni down is that the lead-in wire 61 of principal component obtains heating plate.
Heating plate and plate body that combination utilizes said method to obtain, the hair iron that produce thickness to heating plate, surface roughness (Ra), has or not spring to push, have or not conducting-heat elements or material to change.
Then, the Temperature Distribution on the hair iron heating surface surface that makes is measured Temperature Distribution by NEC system (TG-6200) measuring temperature distribution device, calculate the maximum temperature and the minimum temperature on heating surface surface, the difference of maximum temperature and minimum temperature is measured as the temperature instability.
This result is as shown in table 2.
Table 2
Estimate with plate body thickness 1.5mm, plate body heating plate contact area and heating surface area ratio 70%.
In addition, be printed on
*Mark be test portion outside the scope of the invention.
Analyzing according to table 2, is that the test portion heating surface temperature instability of 0.5～5mm is below 19 ℃ as the thickness of test portion No.3～15 heating plates, shows excellent characteristic.
Relative therewith, when the thickness of test portion No.1,2 heating plates was thinned to 0.3mm, when installing heating plate on plate body, heating plate occurred damaged.In addition, be the test portion of 7mm as test portion No.16,17 heating plate thickness, heating surface temperature instability is greatly to more than 22 ℃, and not preferred.
In addition, possess test portion No.5～13 of conducting-heat elements between plate body and the heating plate, heating surface temperature instability is below 16 ℃, even the test portion of littler temperature instability and preferred.
In addition, the roughness on heating plate interarea surface is test portion No.6～11 of 1～30 μ m, heating surface temperature instability little to below 15 ℃, and further preferred.
In addition, with test portion No.7～9 that spring is pushed plate body one side's interarea and heating plate one side's interarea, heating surface temperature instability becomes below 13 ℃, distinguishes that the temperature instability is enhanced.
Then, will be as the principal component Al of heating plate
2O
3Amount be adjusted between 70%～99.8%, make potsherd, these potsherds are made heating plates according to the described methods of embodiment 2.For these Al
2O
3The material that the composition amount is different is measured 200 ℃ of following high-temperature insulation intensity and bending strength.Making 20 test films is the standard test bending strength with 4 bending strength tests of JIS specification, and this mean value is as follows.
(table 3)
Analyze according to table 3, the aluminium oxide amount is that test portion No.23～25 high-temperature insulation resistances of 80～99.5% reach 1 * 10
13More than the Ω .cm,, can not leak electricity from heater power source even use as hair iron yet, therefore preferred.In addition, bending strength is greatly to more than the 300MPa, even heating resistor heater rapidly repeatedly seldom has because of the damaged danger of thermal stress, thereby preferred.
But as test portion No.21,22, when the aluminium oxide amount is little during to 70,75 quality %, insulation resistance is little of 10 under the hot conditions
11Below the Ω .cm, utilize heating plate that the danger that electric leakage takes place is just arranged.In addition, test portion No.26 aluminium oxide amount is up to 99.8 quality %, need be under firing temperature more than 1700 ℃ sintering, a large amount of at a low price produce just very difficult.
Further preferred, be 90～99.5% o'clock as test portion No.24,25 aluminium oxide amounts, bending strength is big and preferred.
Wherein, the aluminium oxide amount is tried to achieve by the tabular ceramic body of ICO quantitative analysis making.
Then, the profile of plate body is fixing according to 4mm * 80mm * 20mm (thick * long * wide), changes the length and the embodiment 2 same hair irons of making change contact area and heating surface (area) (HS ratio of heating plate gradually.
Then, possessing silicon between heating plate and plate body is that resin is as conducting-heat elements, by depressing, resistance heater is applied rated voltage at spring, measuring from room temperature is that time till 200 ℃ the saturation temperature is as the heating surface saturation time to the heating surface maximum temperature.
Its result is as shown in table 4.
(table 4)
According to table 4 as can be known, area ratio is that test portion No.33～42 heating surface saturation times of 20～80% are little of below 60 seconds, demonstrates excellent characteristic.
In addition, area ratio is that test portion No.34～41 heating surface saturation times of 30～60% are little of below 57 seconds, shows excellent characteristic more.
On the other hand, the contact area of heating plate 7 and plate body 5 and heating surface contact area ratio less than 20% test portion No.31,32 saturation times greatly to more than 63 seconds, and not preferred.
In addition, surpass at 80% o'clock as test portion No.43 contact area, it is excessive that heating plate becomes, and the cost of heating plate just uprises, and industrial utilization just reduces.
Further preferred plate body thickness is test portion No.36～39 of 0.2～10mm, and this is because their heating saturation times are little of below 50 seconds.
Claims (8)
1. ceramic heater is characterized in that:
Comprise ceramic body, the conductive pattern that this ceramic body has outer surface and buried underground,
Described conductive pattern is made of conductor, and described conductor is set up according to the mode that formation becomes the return portion of resistance heater, and the emptying aperture occupation rate by the folded ceramic part of the conductor of adjacency in described return portion is 0.01～50%,
The length along described outer surface of the emptying aperture that exists between described contiguous conductor is, below 1/2 length of this conductor separation.
2. ceramic heater as claimed in claim 1, wherein:
The thickness setting of described conductor is at 5～100 mu m ranges.
3. manufacture method of making the described ceramic heater of claim 1, it comprises:
Form the operation of conductor paste by the pattern of regulation on the first ceramic green sheet surface;
With on the face of the formation conductor paste of this first ceramic green sheet, have at least and same thickness of this conductive pattern and second ceramic green sheet more soft, the operation of making the ceramic green sheet duplexer than described first ceramic green sheet by lamination;
Operation with this ceramic green sheet duplexer of bonding on ceramic formation body;
With the ceramic green sheet duplexer that burns till this bonding and the operation of ceramic formation body.
4. manufacture method of making the described ceramic heater of claim 1, it comprises:
Pattern in accordance with regulations forms the operation of conductor paste on the surface of ceramic green sheet;
And fill the operation of insulant between the conductor paste in described predetermined pattern;
And will between this conductor paste, fill the ceramic green sheet of insulant, the face that has formed described conductor paste is bonded in operation on the ceramic formation body as adhesive surface;
With the operation of burning till this bonding ceramic green sheet and ceramic formation body.
5. the manufacture method of ceramic heater as claimed in claim 4 is characterized in that:
The operation of filling described insulant is stuck with paste by screen printing and is carried out.
6. the manufacture method of ceramic heater as claimed in claim 4 is characterized in that:
Filling the operation of described insulant utilizes distributor to carry out.
7. hair iron, it possesses claim 1 or 2 described ceramic heaters.
8. hair iron, it possesses a pair of parts of controlling that switching freely links, and possesses claim 1 or 2 described ceramic heaters respectively at described front end of controlling parts.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004187479 | 2004-06-25 | ||
| JP187479/2004 | 2004-06-25 | ||
| JP2004220541 | 2004-07-28 | ||
| JP220541/2004 | 2004-07-28 | ||
| PCT/JP2005/011629 WO2006001373A1 (en) | 2004-06-25 | 2005-06-24 | Ceramic heater and production method therefor and heating device and hair iron |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1969592A CN1969592A (en) | 2007-05-23 |
| CN1969592B true CN1969592B (en) | 2010-12-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2005800203058A Active CN1969592B (en) | 2004-06-25 | 2005-06-24 | Ceramic heater and production method therefor and hair iron |
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| Country | Link |
|---|---|
| JP (1) | JP4818922B2 (en) |
| KR (1) | KR101127114B1 (en) |
| CN (1) | CN1969592B (en) |
| GB (1) | GB2431326B (en) |
| WO (1) | WO2006001373A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP4775186B2 (en) * | 2006-08-31 | 2011-09-21 | パナソニック電工株式会社 | Hair iron |
| GB2446440A (en) * | 2007-02-09 | 2008-08-13 | Duna Entpr Sa | Ceramic heating plate for hair straightener iron |
| GB2465865B (en) * | 2008-01-09 | 2013-01-02 | Ghd Korea Inc | Hair iron |
| DE602008001156D1 (en) * | 2008-03-28 | 2010-06-17 | Braun Gmbh | Heating element with temperature sensor |
| CN103546998B (en) * | 2013-10-24 | 2016-01-20 | 东莞市国研电热材料有限公司 | A kind of high-power ceramic heater |
| JP6298342B2 (en) * | 2014-03-31 | 2018-03-20 | イビデン株式会社 | Manufacturing method of ceramic heater |
| JP2016081608A (en) * | 2014-10-10 | 2016-05-16 | イビデン株式会社 | Method for manufacturing ceramic heater |
| FR3028391B1 (en) * | 2014-11-18 | 2017-01-06 | Seb Sa | STEAMING HAIRSTYLE APPARATUS WITH IMPROVED HOUSING |
| JP6661311B2 (en) | 2015-09-11 | 2020-03-11 | キヤノン株式会社 | Image heating device and heater used in image heating device |
| GB2545233B (en) | 2015-12-09 | 2018-06-27 | Dyson Technology Ltd | Flexible heating plate for hair |
| JP6604884B2 (en) * | 2016-03-30 | 2019-11-13 | 日本特殊陶業株式会社 | Ceramic heater |
| CN108263080B (en) * | 2016-12-30 | 2023-07-25 | 上海烟草集团有限责任公司 | Heating body machining device and machining method |
| KR101845428B1 (en) * | 2017-06-30 | 2018-04-04 | (주)알비에스 | Soft synthetic resins inserted heating plate for electric hair iron and the manufacturing method thereof |
| GB2567448A (en) * | 2017-10-11 | 2019-04-17 | Dyson Technology Ltd | A hair styling appliance |
| JP7025258B2 (en) * | 2018-03-20 | 2022-02-24 | 京セラ株式会社 | heater |
| JP6940443B2 (en) * | 2018-03-27 | 2021-09-29 | 京セラ株式会社 | heater |
| US11903472B2 (en) * | 2019-02-08 | 2024-02-20 | Lexmark International, Inc. | Hair iron having a ceramic heater |
| CN113248237A (en) * | 2021-06-15 | 2021-08-13 | 江苏天宝陶瓷股份有限公司 | Method for manufacturing far infrared ceramic heater |
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| JP2971167B2 (en) * | 1991-05-01 | 1999-11-02 | 日本特殊陶業株式会社 | Ceramic heater |
| JPH05343162A (en) * | 1992-06-09 | 1993-12-24 | Nippon Cement Co Ltd | Manufacture of ceramic heating element |
| JPH0679859U (en) * | 1993-04-19 | 1994-11-08 | 積水化成品工業株式会社 | Antifreeze device for water pipes |
| JPH08148260A (en) * | 1994-11-16 | 1996-06-07 | Nippondenso Co Ltd | Ceramic heater |
| JPH08153572A (en) * | 1994-11-29 | 1996-06-11 | Tokai Konetsu Kogyo Co Ltd | Far infrared radiation heater |
| JP3608185B2 (en) * | 1997-08-26 | 2005-01-05 | 東芝セラミックス株式会社 | Plate heater and manufacturing method thereof |
| JP3646914B2 (en) * | 1999-04-13 | 2005-05-11 | 東芝セラミックス株式会社 | Manufacturing method of ceramic heater |
| JP3618678B2 (en) * | 2001-03-30 | 2005-02-09 | 株式会社ティ．アイ．プロス | Hair iron |
| US20050016986A1 (en) | 2001-11-30 | 2005-01-27 | Yasutaka Ito | Ceramic heater |
| JP3898504B2 (en) * | 2001-12-20 | 2007-03-28 | 京セラ株式会社 | Heater for contact heating |
| JP3977663B2 (en) * | 2002-02-27 | 2007-09-19 | 孝 向井 | Hair iron |
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| JP2003243494A (en) * | 2002-10-28 | 2003-08-29 | Ibiden Co Ltd | Ceramic substrate |
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| JP4416427B2 (en) * | 2003-04-24 | 2010-02-17 | 京セラ株式会社 | Ceramic heater and manufacturing method thereof |
| KR100908429B1 (en) * | 2003-12-24 | 2009-07-21 | 쿄세라 코포레이션 | Ceramic heater and its manufacturing method |
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- 2005-06-24 CN CN2005800203058A patent/CN1969592B/en active Active
- 2005-06-24 JP JP2006528624A patent/JP4818922B2/en active Active
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| JP特开平8-148260A 1996.06.07 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB0701445D0 (en) | 2007-03-07 |
| CN1969592A (en) | 2007-05-23 |
| JP4818922B2 (en) | 2011-11-16 |
| JPWO2006001373A1 (en) | 2008-04-17 |
| KR101127114B1 (en) | 2012-03-23 |
| GB2431326B (en) | 2008-08-27 |
| WO2006001373A1 (en) | 2006-01-05 |
| KR20070034514A (en) | 2007-03-28 |
| GB2431326A (en) | 2007-04-18 |
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