CN1916077A - 高cti值高阻燃性增强聚酰胺 - Google Patents
高cti值高阻燃性增强聚酰胺 Download PDFInfo
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- CN1916077A CN1916077A CN 200610053337 CN200610053337A CN1916077A CN 1916077 A CN1916077 A CN 1916077A CN 200610053337 CN200610053337 CN 200610053337 CN 200610053337 A CN200610053337 A CN 200610053337A CN 1916077 A CN1916077 A CN 1916077A
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- value
- resistance property
- fire resistance
- polyamide
- property enhanced
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004952 Polyamide Substances 0.000 title claims abstract description 18
- 229920002647 polyamide Polymers 0.000 title claims abstract description 18
- 239000003063 flame retardant Substances 0.000 claims abstract description 16
- 239000000314 lubricant Substances 0.000 claims abstract description 9
- 239000003365 glass fiber Substances 0.000 claims description 8
- 150000001408 amides Chemical class 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 230000000979 retarding effect Effects 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 5
- 239000004793 Polystyrene Substances 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 8
- 230000003014 reinforcing effect Effects 0.000 abstract 2
- 239000003607 modifier Substances 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 description 26
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 9
- 239000004677 Nylon Substances 0.000 description 7
- 229920001778 nylon Polymers 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 229920002292 Nylon 6 Polymers 0.000 description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000005684 electric field Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 3
- 241001354529 Lasthenia Species 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 241000555268 Dendroides Species 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000006367 bivalent amino carbonyl group Chemical group [H]N([*:1])C([*:2])=O 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920006038 crystalline resin Polymers 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical group 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
材料 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 |
PA6 | 51.0 | 51.0 | 51.0 | 49.0 | 40.0 | 55.0 |
聚溴化苯乙烯 | 11.5 | 11.5 | 11.5 | 11.5 | 20.5 | 5.5 |
三氧化二锑 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 |
硼酸锌 | 12.0 | 12.0 | 12.0 | |||
氢氧化镁 | 14.0 | 14.0 | ||||
硼酸镁 | 14.0 | |||||
硬脂酸钙 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
抗氧剂1098 | 0.15 | 0.15 | 0.15 | 0.15 | 0.15 | 0.15 |
抗氧剂168 | 0.15 | 0.15 | 0.15 | 0.15 | 0.15 | 0.15 |
硅酮粉 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
滑石粉400目 | 23.5 | 23.5 | 23.5 | |||
滑石粉1250目 | 23.5 | |||||
玻璃纤维 | 23.5 | 23.5 |
材料名称 | 厂家及牌号 |
PA6 | 广州新会美达12400 |
聚溴化苯乙烯 | 大湖阻燃剂PBS-64HW |
三氧化二锑 | 湖南益阳锑品厂(0级) |
硼酸锌 | 济南泰星化工 |
氢氧化镁 | 山东海化股份有限公司 |
硼酸镁 | 邹城市中远化工有限公司 |
硬脂酸钙 | 杭州油脂化工 |
抗氧剂1098 | 天津利安隆 |
抗氧剂168 | 南京中庆化工 |
硅酮粉 | 中蓝晨光化工研究院 |
滑石粉400目 | 辽宁海城金田滑石粉厂 |
滑石粉1250目 | 辽宁海城金田滑石粉厂 |
玻璃纤维 | 重庆国际复合材料 |
检测项目 | 检测标准 | 通用材料1 | 通用材料2 |
拉伸强度(MPa) | GB/1040 | 65 | 135 |
弯曲强度(MPa) | GB/9304 | 100 | 165 |
缺口冲击强度(kJ/m2) | ISO179-1∶2000 | 6.0 | 14.5 |
非缺口冲击强度(kJ/m2) | ISO179 | 21.0 | 45.0 |
热变形(℃) | GB/1634 | 145 | 200 |
MI(g/10min) | GB/3682 | 8.0 | 6.5 |
CTI(V) | GB/4207 | 350 | 350 |
检测项目 | 检测标准 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 |
拉伸强度(MPa) | GB/1040 | 63.0 | 75.0 | 120.0 | 60.0 | 103.0 | 80.0 |
弯曲强度(MPa) | GB/9304 | 98.0 | 105.0 | 155.0 | 94.5 | 145.0 | 110.0 |
缺口冲击强度(kJ/m2) | ISO179-1∶2000 | 5.0 | 5.5 | 14.0 | 4.8 | 11.0 | 6.5 |
非缺口冲击强度(kJ/m2) | ISO179 | 21.0 | 22.0 | 40.0 | 20.0 | 29.0 | 25.0 |
热变形(℃) | GB/1634 | 160 | 160 | 200 | 160 | 195 | 170 |
MI(g/10min) | GB/3682 | 14.3 | 7.3 | 7.0 | 8.3 | 6.3 | 12.3 |
CTI(V) | GB/4207 | 550 | 550 | 525 | 550 | 525 | 550 |
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006100533374A CN100425654C (zh) | 2006-09-07 | 2006-09-07 | 高cti值高阻燃性增强聚酰胺 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006100533374A CN100425654C (zh) | 2006-09-07 | 2006-09-07 | 高cti值高阻燃性增强聚酰胺 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1916077A true CN1916077A (zh) | 2007-02-21 |
CN100425654C CN100425654C (zh) | 2008-10-15 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2006100533374A Expired - Fee Related CN100425654C (zh) | 2006-09-07 | 2006-09-07 | 高cti值高阻燃性增强聚酰胺 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN100425654C (zh) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102120879A (zh) * | 2011-02-19 | 2011-07-13 | 本松工程塑料(杭州)有限公司 | 一种耐高温、高cti阻燃聚酰胺复合材料及制备方法 |
CN102604377A (zh) * | 2012-02-17 | 2012-07-25 | 金发科技股份有限公司 | 一种阻燃热塑性聚酰胺组合物 |
CN103602061A (zh) * | 2013-11-01 | 2014-02-26 | 广东聚石化学股份有限公司 | 一种高灼热丝起燃温度无卤阻燃增强尼龙复合材料及其制备方法 |
CN104017355A (zh) * | 2014-01-15 | 2014-09-03 | 温州聚兴塑化有限公司 | 高cti值高阻燃增强尼龙及其制备方法 |
CN104403310A (zh) * | 2014-10-31 | 2015-03-11 | 浙江俊尔新材料股份有限公司 | 一种高cti阻燃聚酰胺染色材料及其制备方法 |
CN104403309A (zh) * | 2014-10-31 | 2015-03-11 | 浙江俊尔新材料股份有限公司 | 一种高cti阻燃聚酰胺材料及其制备方法 |
CN105566900A (zh) * | 2014-11-05 | 2016-05-11 | 上海耐特复合材料制品有限公司 | 一种具优异电气性能的玻纤增强阻燃尼龙材料及其制备方法 |
CN105623252A (zh) * | 2014-11-05 | 2016-06-01 | 上海耐特复合材料制品有限公司 | 一种高强度外观件聚酰胺复合材料及其制备方法 |
CN106349688A (zh) * | 2016-08-31 | 2017-01-25 | 浙江新力新材料股份有限公司 | 一种高cti阻燃尼龙6埃洛石填充复合材料及其制备方法 |
CN106380835A (zh) * | 2016-08-31 | 2017-02-08 | 浙江新力新材料股份有限公司 | 一种高cti阻燃尼龙6矿物填充复合材料及其制备方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE1010047A3 (nl) * | 1996-02-26 | 1997-12-02 | Dsm Nv | Vlamdovende polyamidesamenstelling. |
SG87882A1 (en) * | 1999-01-29 | 2002-04-16 | Kuraray Co | Polyamide composition |
CN1200044C (zh) * | 2000-08-09 | 2005-05-04 | 三井化学株式会社 | 阻燃性聚酰胺组合物、颗粒和成形体及其用途 |
KR20030040480A (ko) * | 2000-09-22 | 2003-05-22 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 개선된 난연성 폴리아미드 조성물 |
JP2005200636A (ja) * | 2003-12-18 | 2005-07-28 | Mitsubishi Engineering Plastics Corp | 難燃性ポリアミド樹脂組成物 |
US20050250885A1 (en) * | 2004-05-04 | 2005-11-10 | General Electric Company | Halogen-free flame retardant polyamide composition with improved electrical properties |
JP4703254B2 (ja) * | 2004-05-11 | 2011-06-15 | 三菱エンジニアリングプラスチックス株式会社 | ブレーカー用ポリアミド樹脂組成物 |
-
2006
- 2006-09-07 CN CNB2006100533374A patent/CN100425654C/zh not_active Expired - Fee Related
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102120879A (zh) * | 2011-02-19 | 2011-07-13 | 本松工程塑料(杭州)有限公司 | 一种耐高温、高cti阻燃聚酰胺复合材料及制备方法 |
CN102604377A (zh) * | 2012-02-17 | 2012-07-25 | 金发科技股份有限公司 | 一种阻燃热塑性聚酰胺组合物 |
CN102604377B (zh) * | 2012-02-17 | 2015-09-09 | 金发科技股份有限公司 | 一种阻燃热塑性聚酰胺组合物 |
CN103602061A (zh) * | 2013-11-01 | 2014-02-26 | 广东聚石化学股份有限公司 | 一种高灼热丝起燃温度无卤阻燃增强尼龙复合材料及其制备方法 |
CN103602061B (zh) * | 2013-11-01 | 2016-04-06 | 广东聚石化学股份有限公司 | 一种高灼热丝起燃温度无卤阻燃增强尼龙复合材料及其制备方法 |
CN104017355A (zh) * | 2014-01-15 | 2014-09-03 | 温州聚兴塑化有限公司 | 高cti值高阻燃增强尼龙及其制备方法 |
CN104403310A (zh) * | 2014-10-31 | 2015-03-11 | 浙江俊尔新材料股份有限公司 | 一种高cti阻燃聚酰胺染色材料及其制备方法 |
CN104403309A (zh) * | 2014-10-31 | 2015-03-11 | 浙江俊尔新材料股份有限公司 | 一种高cti阻燃聚酰胺材料及其制备方法 |
CN105566900A (zh) * | 2014-11-05 | 2016-05-11 | 上海耐特复合材料制品有限公司 | 一种具优异电气性能的玻纤增强阻燃尼龙材料及其制备方法 |
CN105623252A (zh) * | 2014-11-05 | 2016-06-01 | 上海耐特复合材料制品有限公司 | 一种高强度外观件聚酰胺复合材料及其制备方法 |
CN106349688A (zh) * | 2016-08-31 | 2017-01-25 | 浙江新力新材料股份有限公司 | 一种高cti阻燃尼龙6埃洛石填充复合材料及其制备方法 |
CN106380835A (zh) * | 2016-08-31 | 2017-02-08 | 浙江新力新材料股份有限公司 | 一种高cti阻燃尼龙6矿物填充复合材料及其制备方法 |
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Address after: Shanghai City Xinsheng road 201712 Qingpu Industrial Park No. 379, 3, 4, 5 Patentee after: SHANGHAI JUNER NEW MATERIALS Co.,Ltd. Patentee after: CGN JUNER NEW MATERIALS Co.,Ltd. Address before: Shanghai City Xinsheng road 201712 Qingpu Industrial Park No. 379, 3, 4, 5 Patentee before: SHANGHAI JUNER NEW MATERIALS Co.,Ltd. Patentee before: Zhejiang Juner New Materials Co.,Ltd. Address after: Shanghai City Xinsheng road 201712 Qingpu Industrial Park No. 379, 3, 4, 5 Patentee after: SHANGHAI JUNER NEW MATERIALS Co.,Ltd. Patentee after: Zhejiang Juner New Materials Co.,Ltd. Address before: Shanghai City Xinsheng road 201712 Qingpu Industrial Park No. 379, 3, 4, 5 Patentee before: SHANGHAI JUNER NEW MATERIALS Co.,Ltd. Patentee before: Zhejiang Juner New Material Co.,Ltd. |
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Address after: Qingpu Songze Avenue Industrial Park of Qingpu District 201700 Shanghai 6638 Lane 5, No. 7 Patentee after: CGN JUNER (SHANGHAI) NEW MATERIALS Co.,Ltd. Patentee after: CGN JUNER NEW MATERIALS Co.,Ltd. Address before: Shanghai City Xinsheng road 201712 Qingpu Industrial Park No. 379, 3, 4, 5 Patentee before: SHANGHAI JUNER NEW MATERIALS Co.,Ltd. Patentee before: CGN JUNER NEW MATERIALS Co.,Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20081015 Termination date: 20210907 |
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CF01 | Termination of patent right due to non-payment of annual fee |