CN1915518B - 一种催化裂化催化剂及其应用 - Google Patents
一种催化裂化催化剂及其应用 Download PDFInfo
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- CN1915518B CN1915518B CN200610107000A CN200610107000A CN1915518B CN 1915518 B CN1915518 B CN 1915518B CN 200610107000 A CN200610107000 A CN 200610107000A CN 200610107000 A CN200610107000 A CN 200610107000A CN 1915518 B CN1915518 B CN 1915518B
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- propylene
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- 239000003054 catalyst Substances 0.000 title claims abstract description 115
- 238000004523 catalytic cracking Methods 0.000 title claims abstract description 29
- 239000002808 molecular sieve Substances 0.000 claims abstract description 47
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 16
- 238000005342 ion exchange Methods 0.000 claims abstract description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 64
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 46
- 238000006243 chemical reaction Methods 0.000 claims description 32
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 25
- 229910021536 Zeolite Inorganic materials 0.000 claims description 22
- 239000010457 zeolite Substances 0.000 claims description 22
- 229910052782 aluminium Inorganic materials 0.000 claims description 19
- 239000004411 aluminium Substances 0.000 claims description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 19
- 238000012986 modification Methods 0.000 claims description 14
- 230000004048 modification Effects 0.000 claims description 14
- 229910052749 magnesium Inorganic materials 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 8
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 8
- 150000002910 rare earth metals Chemical class 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 239000000969 carrier Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 33
- 230000000694 effects Effects 0.000 abstract description 28
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 28
- 239000001257 hydrogen Substances 0.000 abstract description 28
- 238000012546 transfer Methods 0.000 abstract description 24
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 30
- 150000002431 hydrogen Chemical class 0.000 description 26
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 26
- 238000005336 cracking Methods 0.000 description 22
- 150000001336 alkenes Chemical class 0.000 description 18
- 239000003502 gasoline Substances 0.000 description 18
- 239000000047 product Substances 0.000 description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
- 239000003921 oil Substances 0.000 description 15
- 239000002872 contrast media Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 11
- 239000011777 magnesium Substances 0.000 description 11
- 238000011156 evaluation Methods 0.000 description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 4
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000010298 pulverizing process Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 238000004231 fluid catalytic cracking Methods 0.000 description 3
- 229910052733 gallium Inorganic materials 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000007670 refining Methods 0.000 description 3
- 229930195734 saturated hydrocarbon Natural products 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000006276 transfer reaction Methods 0.000 description 3
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000010009 beating Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- 238000011020 pilot scale process Methods 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- 239000010913 used oil Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- GJKFIJKSBFYMQK-UHFFFAOYSA-N lanthanum(3+);trinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GJKFIJKSBFYMQK-UHFFFAOYSA-N 0.000 description 1
- 239000003562 lightweight material Substances 0.000 description 1
- 229910001723 mesolite Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- -1 olefin hydrocarbon Chemical class 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- OIGNJSKKLXVSLS-VWUMJDOOSA-N prednisolone Chemical compound O=C1C=C[C@]2(C)[C@H]3[C@@H](O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 OIGNJSKKLXVSLS-VWUMJDOOSA-N 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
密度,g/ml | 0.9115 |
粘度,mm<sup>2</sup>/s80℃100℃ | 42.4923.46 |
残炭,% | 4.49 |
烃组成,w%饱和烃芳烃胶质+沥青质 | 59.229.111.7 |
元素组成,ppmSN | 13712830 |
馏程,℃ | |
IBP/5% | 265.4/350.9 |
10%/20% | 385.9/428.3 |
30%/40% | 462.3/501.4 |
50%/53.2% | 546.1/558.8 |
催化剂 | 对比剂 | A | B | C | D | E |
氢转移活性指数(HTC)<sup>*</sup> | 1.19 | 0.51 | 0.50 | 0.48 | 0.40 | 0.46 |
气体烯烃产率(占进料),w% | ||||||
其中,乙烯 | 1.75 | 3.66 | 3.45 | 3.41 | 3.38 | 3.50 |
丙烯C<sub>2</sub><sup>#</sup>~C<sub>1</sub><sup>#</sup>总烯烃 | 12.7123.68 | 14.3327.01 | 14.6826.89 | 14.7226.78 | 13.9526.50 | 14.0226.75 |
催化剂 | 对比剂 | A | B | C | D | E |
丙烯含量(占液化气),w% | 42.49 | 47.65 | 47.81 | 48.01 | 47.42 | 47.50 |
催化剂 | 对比剂 | F | G | H | I | J |
氢转移活性指数(HTC)<sup>*</sup> | 1.19 | 0.60 | 0.71 | 0.65 | 0.47 | 0.45 |
气体烯烃产率(占进料),w% | ||||||
其中,乙烯 | 1.75 | 3.60 | 3.80 | 3.71 | 3.41 | 3.84 |
丙烯C<sub>2</sub><sup>#</sup>~C<sub>1</sub><sup>#</sup>总烯烃 | 12.7123.68 | 14.0826.33 | 13.8626.55 | 14.0126.86 | 13.9726.88 | 15.0228.44 |
丙烯含量(占液化气),w% | 42.49 | 47.59 | 47.32 | 47.48 | 47.40 | 48.72 |
催化剂 | 对比剂 | K | L | M |
氢转移活性指数(HTC)<sup>*</sup> | 1.19 | 0.50 | 0.52 | 0.52 |
气体烯烃产率(占进料),w% | ||||
其中,乙烯 | 1.75 | 3.62 | 3.65 | 3.70 |
丙烯C<sub>2</sub><sup>#</sup>~C<sub>1</sub><sup>#</sup>总烯烃 | 12.7123.68 | 14.3826.98 | 14.2826.87 | 14.3526.86 |
丙烯含量(占液化气),w% | 42.49 | 47.55 | 47.24 | 47.18 |
催化剂 | 对比剂 | A | G | H | J |
氢转移活性指数(HTC) | 1.02 | 0.45 | 0.60 | 0.55 | 0.41 |
气体烯烃产率(占进料),w% | |||||
其中,乙烯 | 2.51 | 4.02 | 4.50 | 4.32 | 5.01 |
丙烯C<sub>2</sub><sup>#</sup>~C<sub>1</sub><sup>#</sup>总烯烃 | 15.3829.41 | 16.3431.12 | 16.0030.66 | 16.1130.98 | 17.2133.22 |
丙烯含量(占液化气),w% | 43.82 | 48.81 | 48.52 | 48.66 | 50.11 |
Claims (5)
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CN200610107000A CN1915518B (zh) | 2006-09-07 | 2006-09-07 | 一种催化裂化催化剂及其应用 |
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CN200610107000A CN1915518B (zh) | 2006-09-07 | 2006-09-07 | 一种催化裂化催化剂及其应用 |
Publications (2)
Publication Number | Publication Date |
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CN1915518A CN1915518A (zh) | 2007-02-21 |
CN1915518B true CN1915518B (zh) | 2010-05-12 |
Family
ID=37736668
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN200610107000A Expired - Fee Related CN1915518B (zh) | 2006-09-07 | 2006-09-07 | 一种催化裂化催化剂及其应用 |
Country Status (1)
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CN (1) | CN1915518B (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101870630B (zh) * | 2009-04-27 | 2014-02-05 | 中国石油化工股份有限公司 | 一种结合氢燃烧技术的烃类催化裂解制取低碳烯烃的方法 |
CN104096590B (zh) | 2013-04-10 | 2016-09-14 | 上海碧科清洁能源技术有限公司 | 混合分子筛催化剂及其制备方法和应用 |
CN109304205B (zh) * | 2017-07-28 | 2021-11-02 | 中国石油天然气股份有限公司 | 一种提高焦炭选择性的催化裂化催化剂及其制备方法 |
CN109304211B (zh) * | 2017-07-28 | 2021-07-02 | 中国石油天然气股份有限公司 | 一种提高y型分子筛催化活性的改性方法 |
CN112010323B (zh) * | 2019-05-31 | 2022-06-24 | 中国石油化工股份有限公司 | 一种含磷和金属的mfi结构分子筛及其制备方法 |
CN111482199B (zh) * | 2020-04-26 | 2023-12-15 | 中国石油大学(北京) | 烯烃裂解催化剂及其制备方法和烯烃裂解方法 |
CN111482198B (zh) * | 2020-04-26 | 2023-12-15 | 中国石油大学(北京) | 烯烃裂解催化剂及其制备方法和烯烃裂解方法 |
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Address after: 100029 Beijing City, Chaoyang District Hui Street No. 6 Co-patentee after: Luoyang Petrochemical Engineering Corporation /SINOPEC Patentee after: China Petrochemical Group Corp. Address before: 100029 Beijing City, Chaoyang District Hui Street No. 6 Co-patentee before: Luoyang Petrochemical Engineering Co., China Petrochemical Group Patentee before: China Petrochemical Group Corp. |
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