CN1896345A - Production of moisture-absorbing and sweat-exhausting fibre - Google Patents

Production of moisture-absorbing and sweat-exhausting fibre Download PDF

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Publication number
CN1896345A
CN1896345A CN 200510040966 CN200510040966A CN1896345A CN 1896345 A CN1896345 A CN 1896345A CN 200510040966 CN200510040966 CN 200510040966 CN 200510040966 A CN200510040966 A CN 200510040966A CN 1896345 A CN1896345 A CN 1896345A
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China
Prior art keywords
hygroscopic fibre
production method
cross
section
fibre
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CN 200510040966
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Chinese (zh)
Inventor
严建华
李刚
史利梅
马建平
陈翠红
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Sinopec Yizheng Chemical Fibre Co Ltd
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Sinopec Yizheng Chemical Fibre Co Ltd
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Priority to CN 200510040966 priority Critical patent/CN1896345A/en
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Abstract

The present invention provides a production process of moisture-absorbing and sweat-releasing fibre. This invention utilizes conventional PET slice or fusant, spinneret with special section and present high-speed spinning equipments, adopts super high-speed spinning technology to produce moisture-absorption and sweat-releasing HOY fibre without tension. This process has simple arts, high efficiency and reliable performance, the produced fibre is much softer and the fabric made of this fibre is more comfortable.

Description

The production method of hygroscopic fibre
Technical field
The present invention relates to a kind of production method of polyester filament, relate in particular to the production method of polyester filament, belong to the synthetic fiber technical field with moisture absorption sweat discharging functions.
Background technology
Along with growth in the living standard, people more and more pay attention to the comfort property of clothes, and the various high-tech contents of garment material are also more and more higher.The moisture absorbing and sweat releasing performance of clothes is important indicators of comfortableness.Hygroscopic fibre is meant that the capillarity of utilizing the fiber surface minute groove to produce makes sweat just through effects such as wicking, diffusion, transmission, move to the surface of fabric rapidly and disperse the purpose that reaches wet-guide quick-drying, people also are called respirable fiber with this fiber.In recent years, several hygroscopic fibres are studied and released to the U.S., Korea S, Japan, TaiWan, China etc. in succession, they all are to increase capillarity by fibre section heteromorphosis, make fabric owing on the fiber or interfibrous capillary channel produce core sucting action and have dry and comfortable perspiration functions.
It is reported to have the profiled filament of moisture absorption sweat discharging functions, the cross section of fiber is all fluted.As " Coolmax " polyester fiber that du pont company is produced, its cross section becomes unique flat cross, and fiber surface is vertically forming four grooves, has to have more 20% surface area than general fiber, and its moisture absorption sweat discharging functions is better than other allied fiber.The emerging limited company that weaves produces in the Taiwan " Coolplus " is by Y shape and star section equally, utilizes the fiber surface minute groove to produce capillarity, makes sweat wicking, diffusion, volatilization.The H type end side PET hygroscopic fibre (commodity are called EASTLENE) of Far East textiles company and " Topcool " hygroscopic fibre of the said firm have good wicking, can breathe, do soon, sticking characteristic such as take.
Odd-shaped cross section hygroscopic fibre in the market all is staple fibre yarn, low-stretch yarn and the full-drawn yarn (FDY, DT) of all size.The characteristics that the rigidity of polyster fibre is big, fabric is very scraped have been well known fact, when the odd-shaped cross section of many grooves is given the dry and comfortable characteristic of fabric moisture, have also given prominence to the inherent defect of polyster fibre, make the feel of fabric more coarse, stiffening.Because hygroscopic fibre must be made underwear or be used for its good moisture absorption function of a fabric competence exertion next to the shin, the soft feel of fabric next to the shin is undoubtedly another important indicator of comfort property, and the flexibility that existing hygroscopic fibre production technology does not all have how to improve fabric is included in the research.
Summary of the invention
The objective of the invention is to improve the existing coarse stiffening feel of moisture absorbing and sweat releasing fabric, a kind of production method with hygroscopic fibre of improved flexibility energy is provided, the fabric that utilizes this fiber to make, its comfort property improves a lot.
Purpose of the present invention is achieved through the following technical solutions:
The production method of hygroscopic fibre, it is characterized in that: polyester fondant is through being installed on the profiled-cross-section spinnerets spray silk in the spinning manifold, carry out slow cooling heating, lateral blowing then, oil, reel through 4800~10000m/min ultrahigh speed again, make hygroscopic fibre.
Further, in the production method of above-mentioned hygroscopic fibre, the temperature of described spinning manifold is that 280~300 ℃, the temperature of slow cooling heating are 270~290 ℃, and the temperature of lateral blowing is 20~26 ℃, and the wind speed of lateral blowing is 0.30~0.85m/s.
Further, in the production method of above-mentioned hygroscopic fibre, described profiled-cross-section spinnerets be have that wicking, quick-drying function, vertical table mask fluted spinnerets, especially cross section are Y-shaped, 3T shape, cross, H shape, five leaf or ninth of the ten Heavenly Stems word shape spinnerets.
Again further, in the production method of above-mentioned hygroscopic fibre, described polyester fondant directly comes the final polycondensation reactor of autopolyester synthesis phase; Also can be by polyester slice through after pre-crystallization and the dried, extrude and the melt that forms through screw extruder, the operating temperature of described screw extruder is 260~300 ℃.
The present invention is extruded into melt with the normal polyester section through screw extruder, perhaps directly uses the polyester fondant that forms after the polymerisation, by the profiled-cross-section spinnerets, utilizes the super high-speed spinning technology to produce different section type hygroscopic fibre (HOY).This HOY silk has odd-shaped cross section and the groove identical with hygroscopic fibre of the same type, thereby has kept the dry and comfortable characteristic of good moisture absorption that similar hygroscopic fibre had; Simultaneously, owing to adopt the super high-speed spinning winding process, the supramolecular structure of the HOY silk that forms obviously is different from fibers such as traditional polyester DTY, FDY, DT, the fabrics feel soft that adopts the HOY silk to make, significantly better than the fabric of producing with hygroscopic fibres such as similar polyester DTY, FDY, DT, improve the coarse stiffening feel of existing moisture absorbing and sweat releasing fabric, improved the soft comfort property that promotes this kind fabric.The present invention can utilize existing high-speed spinning equipment to produce, and technical process is simple, production efficiency height, stable.
The specific embodiment
Be that example is described further technical solution of the present invention to adopt the normal polyester section to be extruded into melt below through screw extruder.
Adopt normal polyester (PET) section, utilize the profiled-cross-section spinnerets, adopt the super high-speed spinning processing technology routine, drawn is not produced hygroscopic fibre HOY silk.Technological process is: PET section → drying → screw extruder → spinning → slow cooling heat block → lateral blowing cools off → oils → ultrahigh speed coiling → profiled-cross-section moisture absorbing and sweat releasing HOY silk.
The spinnerets cross section can be " Y " shape, " 3T " shape, " ninth of the ten Heavenly Stems " font, " ten " font, " H " shape, " five leaves " shape etc. among the present invention, also can be other shape with wicking, quick-drying function, the fluted profiled fibre of vertical table mask.
Enter screw extruder, 260~300 ℃ of extruder temperature, 280~300 ℃ of spinning manifold melt temperatures through pre-crystallization, dried section, 270~290 ℃ of slow cooling heat block temperature, 20~23 ℃ of lateral blowing temperature, side-blown wind speed 0.45~0.65m/s, spinning speed 4800~10000m/min.Spinning technology parameter can be adjusted according to different size, the different cross section shape of distinct device, fiber, general dried section is moisture can satisfy spinning requirement about 20ppm, low more good more, the cross section special-shaped degree of fiber is between 20~60%, degree of profile is lower than 20%, is difficult to guarantee the moisture absorbing and sweat releasing performance of fabric, is higher than 60%, easily broken end is difficult to normal winding.
Because it is high that HOY spins speed, oriented crystallineization takes place in the spinning process, the unformed shape of local orientation is very fast crystallization in the melt-spun process, so crystal degree of perfection height that forms, crystalline region degree of orientation height, crystallite dimension is big, correspondingly in the crystalline region between crystalline particle the slit bigger, promptly the amorphous region size increases greatly.Existing research data shows, the degree of orientation of ultra-high-speed spinning fiber amorphous region is low more than other, the composite bending modulus of fiber is lower, the feel that shows as fiber on the macroscopic view improves greatly than the pliability that low speed of the same type spins (FDY, DT, staple fibre yarn, DTY) fiber, thereby improve the soft degree that promotes fabric, improved the soft comfort property of moisture absorbing and sweat releasing fabric.
The wicking that the moisture absorbing and sweat releasing HOY fiber that the present invention produces is had, do pleasant performance and soft hand feeling soon and illustrate with the following example:
The DTY of same specification (83dt/36f), same cross section (" ninth of the ten Heavenly Stems " font) and the fabric that two kinds of hygroscopic fibres of HOY are made into same institutional framework are carried out testing its moisture absorbing and sweat releasing performance and softness after same dyeing and finishing technology is handled, concrete data such as following table 1 and table 2.The cross section degree of profile of two kinds of fibers is approaching, and its capillary height and moisture content are more or less the same, and illustrate that its moisture absorbing and sweat releasing performance is similar, and suspended coefficient differs greatly, and illustrates that the fabric sofetening degree that the HOY fiber is made into really is greatly improved.
Table 1: the contrast of two kinds of moisture absorbing and sweat releasing fabric capillary height and suspended coefficient
Project Degree of profile (%) Capillary height (cm) Suspended coefficient (%)
10min 20min 30min
DTY 28.1 8.7 10.7 11.9 29.9
HOY 27.8 8.8 11.1 12.7 22.4
Table 2: the contrast of two kinds of remaining moisture content of moisture absorbing and sweat releasing fabric
Time (min) 0 5 10 15 20 25 30 35
DTY 100 73.5 50.0 27.0 8.7 0.5 0.2 0.0
HOY 100 72.5 46.3 21.7 3.0 0.5 0.3 0.0
Wherein:
The degree of profile of fiber cross section is represented with the specific area increment rate, fiber cross section degree of profile height, its moisture absorbing and sweat releasing better performances.Specifically can calculate like this: the cross section of fiber is amplified 1000 times, calculate cross-sectional area S, the perimeter L of fiber, the specific area R=L/S of fiber cross section; According to S=π r 2, calculate r, thereby calculate the perimeter L of same specification circle ', further calculate specific area R '=L '/S of same specification circle, (R-R ') so/R ' is the specific area increment rate.
Capillary water absorption height (capillary height) characterizes the hygroscopicity of fabric energy, and the capillary height is big, and hygroscopicity of fabric can be good.With fabric be cut into specification for long * it is wide that (20cm's * 3cm) is rectangular, and an end clamps, and the other end does not have in the entry, carries out the test of capillary height in certain constant-temperature constant-humidity environment.
The present invention specifically tests (FZ/T01045-1996 method A) with the fabric fall analyzer with the softness of suspended coefficient sign fabric, and suspended coefficient is more little within test specification, and the pliability of fabric is good more so.
Remaining moisture content characterizes the perspiration discharging performance of fabric, requires after fabric is dripped as requested, and the remaining moisture content of home condition fabric after following 40 minutes is less than 20%.Remaining moisture content with fabric under the time is little, and the perspiration discharging performance of fabric is good.
Technical solution of the present invention will be further explained by the following example, and the following example only is representative of the present invention and the protection domain that do not limit the present invention in any way.The fabric of mentioning among the embodiment all adopt in this example hygroscopic fibre with identical institutional framework weave, identical dyeing and finishing technology handles, and tests its moisture absorbing and sweat releasing performance and pliability then.
" embodiment 1 ":
On the KF-POY of Ka Erfeixiu company Spinning Machine for Long Filament, adopt 3T type profile spinneret, spinning speed 4800m/min, the HOY specification is 110dt/36f, carries out spinning with technology in the table 31, and production run is stable, the package moulding is good, and the physical index of gained HOY silk sees Table 4.Adopt the woven fabric of this HOY silk, its moisture absorbing and sweat releasing performance be equal to same cross section, same specification the production of common process route hygroscopic fibre and the soft comfort property of fabric greatly improves.
" embodiment 2 ":
On the KF-POY of Ka Erfeixiu company Spinning Machine for Long Filament, adopt 3T type profile spinneret, spinning speed 5000m/min, the HOY specification is 83dt/36f, carries out spinning with technology in the table 32, and production run is stable, the package moulding is good, and the physical index of gained HOY silk sees Table 4.Adopt the woven fabric of this HOY silk, its moisture absorbing and sweat releasing performance be equal to same cross section, same specification the production of common process route hygroscopic fibre and the soft comfort property of fabric greatly improves.
" embodiment 3 ":
On the KF-POY of Ka Erfeixiu company Spinning Machine for Long Filament, adopt " ninth of the ten Heavenly Stems " font profile spinneret, spinning speed 5000m/min, the HOY specification is 110dt/36f, carries out spinning with technology in the table 33, and production run is stable, the package moulding is good, and the physical index of gained HOY silk sees Table 4.Adopt the woven fabric of this HOY silk, its moisture absorbing and sweat releasing performance be equal to same cross section, same specification the production of common process route hygroscopic fibre and the soft comfort property of fabric greatly improves.
" embodiment 4 ":
On the KF-POY of Ka Erfeixiu company Spinning Machine for Long Filament, adopt " ninth of the ten Heavenly Stems " font profile spinneret, spinning speed 5000m/min, the HOY specification is 83dt/36f, carries out spinning with technology in the table 34, and production run is stable, the package moulding is good, and the physical index of gained HOY silk sees Table 4.Adopt the woven fabric of this HOY silk, its moisture absorbing and sweat releasing performance is equal to the hygroscopic fibre of the common process route production of same cross section, same specification, and the soft comfort property of fabric greatly improves.
The spinning technique of table 3: embodiment 1~4
Project Unit Technology 1 Technology 2 Technology 3 Technology 4
Extruder temperature I 270 270 270 270
II 290 290 290 290
III 290 290 290 290
IV 290 290 290 290
V 290 290 290 290
Spin manifold temperature 292 292 292 292
Controlled pressure mpa 8.0 8.0 8.0 8.0
The side-blown wind speed m/s 0.50 0.45 0.50 0.45
The side-blown wind-warm syndrome 23±1 23±1 23±1 23±1
Side-blown rheumatism RH% 65±5 65±5 65±5 65±5
Winding speed m/min 4800 5000 5000 5000
The coiling overfeeding 18.0 19.0 19.0 19.0
The physical index of table 4: embodiment 1~4 gained HOY silk
Project Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Fiber number (dt) 111 82 110 83
Fracture strength (cN/dt) 2.67 2.75 2.83 2.92
Extension at break (%) 59.6 52.3 53.4 51.6
Boiling water shrinkage (%) 4.8 4.1 4.5 3.9
Remaining moisture content (%) 0min 100 100 100 100
10min 45.1 46.9 44.9 45.7
20min 2.8 3.1 2.5 3.0
30min 0.1 0.2 0.1 0.2
35min 0.0 0.0 0.0 0.0
Capillary height (cm) 10min 8.6 9.1 8.2 8.4
20min 10.9 11.7 11.0 11.9
30min 12.3 13.4 12.8 13.8
Suspended coefficient (%) 22.6 20.8 21.2 20.4

Claims (7)

1. the production method of hygroscopic fibre, it is characterized in that: polyester fondant is through being installed on the profiled-cross-section spinnerets spray silk in the spinning manifold, carry out slow cooling heating, lateral blowing then, oil, reel through 4800~10000m/min ultrahigh speed again, make hygroscopic fibre.
2. the production method of hygroscopic fibre according to claim 1, it is characterized in that: the temperature of described spinning manifold is that 280~300 ℃, the temperature of slow cooling heating are 270~290 ℃, the temperature of lateral blowing is 20~26 ℃, and the wind speed of lateral blowing is 0.30~0.85m/s.
3. the production method of hygroscopic fibre according to claim 1 and 2, it is characterized in that: described profiled-cross-section spinnerets is to have wicking, quick-drying function, the fluted spinnerets of vertical table mask.
4. the production method of hygroscopic fibre according to claim 3 is characterized in that: the cross section of described profiled-cross-section spinnerets is Y-shaped, 3T shape, cross, H shape, five leaf or ninth of the ten Heavenly Stems word shape.
5. the production method of hygroscopic fibre according to claim 1, it is characterized in that: described polyester fondant directly comes the final polycondensation reactor of autopolyester synthesis phase.
6. the production method of hygroscopic fibre according to claim 1 is characterized in that: described polyester fondant be by polyester slice through pre-crystallization and dried after, extrude and the melt that forms through screw extruder.
7. the production method of hygroscopic fibre according to claim 6, it is characterized in that: the operating temperature of described screw extruder is 260~300 ℃.
CN 200510040966 2005-07-11 2005-07-11 Production of moisture-absorbing and sweat-exhausting fibre Pending CN1896345A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102433611A (en) * 2011-10-31 2012-05-02 福建百宏聚纤科技实业有限公司 Technology for processing layered false twist high-elasticity moisture absorption and sweat releasing fibers
CN105155016A (en) * 2015-07-31 2015-12-16 江苏恒科新材料有限公司 Ultra-soft densely stained type polyester HOY fiber and preparation method thereof
CN105648552A (en) * 2016-02-25 2016-06-08 苏州龙杰特种纤维股份有限公司 Preparation method of HOY spring wire
CN108035006A (en) * 2017-12-14 2018-05-15 江苏恒力化纤股份有限公司 A kind of hygroscopic fibre and preparation method thereof
CN110219085A (en) * 2019-06-24 2019-09-10 吴江京奕特种纤维有限公司 For improving the Yarn spinning method and fabric of fabric moisture water vapour permeability
CN110923835A (en) * 2019-12-23 2020-03-27 苏州萧然新材料有限公司 Preparation process of moisture-absorbing and sweat-releasing terylene low-elasticity composite yarn

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102433611A (en) * 2011-10-31 2012-05-02 福建百宏聚纤科技实业有限公司 Technology for processing layered false twist high-elasticity moisture absorption and sweat releasing fibers
CN105155016A (en) * 2015-07-31 2015-12-16 江苏恒科新材料有限公司 Ultra-soft densely stained type polyester HOY fiber and preparation method thereof
CN105155016B (en) * 2015-07-31 2018-01-05 江苏恒科新材料有限公司 A kind of super soft dense dye type polyester HOY fibers and preparation method thereof
CN105648552A (en) * 2016-02-25 2016-06-08 苏州龙杰特种纤维股份有限公司 Preparation method of HOY spring wire
CN108035006A (en) * 2017-12-14 2018-05-15 江苏恒力化纤股份有限公司 A kind of hygroscopic fibre and preparation method thereof
CN108035006B (en) * 2017-12-14 2021-03-19 江苏恒力化纤股份有限公司 Moisture-absorbing and sweat-releasing fiber and preparation method thereof
CN110219085A (en) * 2019-06-24 2019-09-10 吴江京奕特种纤维有限公司 For improving the Yarn spinning method and fabric of fabric moisture water vapour permeability
CN110923835A (en) * 2019-12-23 2020-03-27 苏州萧然新材料有限公司 Preparation process of moisture-absorbing and sweat-releasing terylene low-elasticity composite yarn

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