CN1888317A - Illuminating light reflective concrete curb and producing method thereof - Google Patents
Illuminating light reflective concrete curb and producing method thereof Download PDFInfo
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- CN1888317A CN1888317A CNA200610200759XA CN200610200759A CN1888317A CN 1888317 A CN1888317 A CN 1888317A CN A200610200759X A CNA200610200759X A CN A200610200759XA CN 200610200759 A CN200610200759 A CN 200610200759A CN 1888317 A CN1888317 A CN 1888317A
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- concrete
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- illuminating light
- light reflective
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/807—Luminescent or fluorescent materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Road Paving Structures (AREA)
Abstract
The present invention relates to a luminous light-reflecting concrete curbstone and its production method. The included angle of top surface of concrete strip block and a vertical surface is formed into a smooth transition carved surface, on the above-mentioned top surface and curved surface a layer of luminous light-reflecting mortar surface layer containing glass microbeads is combined, the undersurface of said luminous light-reflecting mortar surface layer and laitance produced on the top surface of concrete strip block can be coagulated together. The composition of the above-mentioned luminous light-reflecting mortar surface layer material includes (by wt%) 5-30% of cement, 5-20% of fine said, 40-85% of glass microbeads, 1-10% of luminous powder, 0-5% of color powder and 0.1-6.0% of concrete additive.
Description
(1) technical field
The present invention relates to a kind of building unit and production method thereof of paving the way, particularly a kind of road kerb and production method thereof.
(2) background technology
At present, many roads also do not have the street lighting facility, and night, the pedestrian walked or driving, because dim light can not be differentiated road surface boundary and situation, traffic accident took place easily, and pedestrian, driving are caused hidden danger.If increase lighting installation, will significantly increase power consumption, huge municipal infrastructure investment and maintenance cost simultaneously.
Existing road kerb is that matrix material is made by concrete or stone material, and the no luminous reflective characteristic in surface is not having on the road of street lamp, can not clearly indicate the carriage way boundary line at night.Increasing luminous function if desired on road kerb, generally then is to be coated with last layer luminescent film, luminescent coating or to be stained with one deck light tiles on the road kerb matrix.Because luminescent layer is an organic material, its durability and lasting luminescent properties are not good enough, and be bonding not firm with matrix, and road kerb is using after a period of time, and luminescent layer just comes off easily and wears out.
(3) summary of the invention
The purpose of this invention is to provide a kind of illuminating light reflective concrete curb and production method thereof, solve existing road kerb and be subjected to the no luminous reflective problem in light irradiation back; And the luminescent layer that solves road kerb comes off easily and wears out and can not lastingly luminous technical barrier.
Technical scheme of the present invention: this illuminating light reflective concrete curb, be the Rectangular Concrete stick, it is characterized in that: the angle of the end face of concrete stick and a vertical plane is the cambered surface that seamlessly transits, compound one deck contains the luminous reflecting mortar surface layer of glass microballoon on above-mentioned end face and the cambered surface, and the bottom surface of luminous reflecting mortar surface layer is secreted the fresh laitance that and solidified above the concrete stick.
The weight proportion of above-mentioned luminous reflecting mortar surface material is as follows:
Cement 5-30%;
Fine sand 5-20%;
Bead 40%-85%;
Luminescent powder 1%-10%;
Toner 0-5%;
Concrete admixtures 0.1-6.0%;
Water/binder ratio: 0.25-0.33.
Above-mentioned bead is the bead of grating, and wherein directly selection scope of glass beads is: 20 orders, 30 orders, 40 orders, 60 orders, 80 orders, 100 orders, 200 orders and 325 orders, refractive index are 1.5-1.75.
The grating of above-mentioned bead can be:
20 order bead 10-20%, 40 order bead 15-25%, 60 order 15-25%, 120 order bead 35-45%, 200 order 1-5%;
Or: 20 order bead 5-15%, 30 order bead 10-20%, 40 order bead 10-20%, 60 order bead 15-20%, 80 order bead 20-30%, 120 order bead 15-25%, 200 order bead 1-5%, 325 order bead 1-3%;
Or: 20 order bead 10-20%, 60 order bead 30-40%, 120 order bead 45-55%;
Or: 40 order bead 15-25%, 60 order bead 25-35%, 80 order bead 25-35%, 100 order bead 15-25%.
Above-mentioned luminescent powder can be sulfide and rare earth aluminium borate luminescent powder or with the mixture of reflecting glass Bead.
Above-mentioned toner can be iron oxide red or iron oxide yellow.
The kind selected of above-mentioned Concrete admixtures comprises cement water reducing agent 0.1%-1.5%, concrete hardener 0-3%, redispersable latex powder 0-3%.
The production method of above-mentioned illuminating light reflective concrete curb is characterized in that following steps are arranged:
(1), earlier the proportioning of pressing ordinary concrete stirs cement, sandstone, Concrete admixtures, water, pours vibratory compaction in the mould into, is shaped to the concrete rectangular stick;
(2), on the concrete rectangular stick, make luminous reflecting mortar surface layer then, proportioning by above-mentioned luminous reflecting mortar surface material, stir and be poured over above the concrete rectangular stick, again through the vibratory compaction moulding, form luminous reflecting mortar surface layer, the bottom surface of luminous reflecting mortar surface layer is secreted above the concrete stick fresh laitance solidify;
(3) after the demoulding, carry out maintenance, make the illuminating light reflective concrete curb finished product.
9, the production method of illuminating light reflective concrete curb according to claim 8 is characterized in that: carry out step (4) after the described step (3): finished surface is washed, is polished, and obtains the concrete road kerb finished product of high luminous reflecting.
The production method of above-mentioned illuminating light reflective concrete curb is characterized in that following steps are arranged:
(1), earlier the proportioning of pressing ordinary concrete stirs cement, sandstone, Concrete admixtures, water, pours vibratory compaction in the mould into, is shaped to the concrete rectangular stick;
(2), then make luminous reflecting mortar surface layer on the concrete rectangular stick, the proportioning by above-mentioned luminous reflecting mortar surface material is stirred into the dryness powder, is sprinkling upon on the concrete stick end face of bleeding phase, and it is closely knit to carry out press polish;
(3), carry out surfacing after condensing, obtain illuminating light reflective concrete curb.
The present invention utilizes the light of bead reflected illumination on the concrete road kerb, utilizes luminescent powder to absorb the luminous road kerb surface light emitting that makes behind the light, utilizes reflecting glass Bead that the light reflection of luminescent powder is amplified again, strengthens luminescent properties; Utilize cement and Concrete admixtures as luminous and bonding agent reflectorized material, make it to be consolidated securely, composition has surface layer luminous, reflective function simultaneously.
The present invention has following beneficial effect:
1.) luminous reflecting mortar surface layer and matrix material are inorganic material---cement concrete material, the bottom surface of luminous reflecting mortar surface layer above the concrete stick, secrete fresh laitance solidify, form the long-acting luminous reflecting mortar surface layer of combining closely with base layer, surface layer and base layer condense firmly, can not come off, layering, the product strength height.
2.) anti-wear performance of the present invention and lasting good luminous performance, characteristics with high reflection external light, externally light irradiation even when not having the extraneous light irradiation of the surface layer that contains luminous and reflectorized material, road kerb all can send from yellow, green to versicolor light such as blueness, redness, whites, road is indicated boundary line and guide, remind driver and pedestrian, improve the safety of driving at night, walking along the street greatly.
3.) energy conservation of the present invention, good environmental protection is owing to adopt phosphor, make the present invention under shining without any light night, also can send light, radiationless, pollution-free, have also that storage light is fast, the high characteristics of storage light quantity, have luminous function of extinction on daytime, night.The present invention had both satisfied the requirement of strength of road kerb, had satisfied the reflective characteristics of luminescence again, did not need to waste energy simultaneously, did not need to exploit the mine, had avoided resource to consume in a large number.In the concrete fin formation of lots, also can add slag, flyash equal industrial residue, substitute the part cement consumption, help environmental protection more.
4.) production method of the present invention is simple, practical, has reduced product cost, and is can factory prefabricated in a large number.
5.) product strength height of the present invention, good frost resistance is widely used.The road stone that can be used for both sides, various highway section; Also can be used for various road tunnel engineerings; Can be used for town road, carriageway, square and landscape hardwork, also can be widely used in the place that residential quarter, expressway, road, playground, warehouse, building etc. need noctilucence or fluorescence to indicate, warn, and can realize not having power consumption beautifying city night scene.
(4) description of drawings
Fig. 1 is the structural representation of illuminating light reflective concrete curb of the present invention.
Fig. 2 is the structural representation in illuminating light reflective concrete curb vertical section.
(5) specific embodiment
Embodiment is referring to Fig. 1,2, and this illuminating light reflective concrete curb constitutes road kerb integral body jointly by concrete stick 1 and luminous reflecting mortar surface layer 2.The thickness of Rectangular Concrete stick is made 50-500mm by the difference requirement, the thickness 5-30mm of luminous reflecting mortar surface layer.The angle of the end face of concrete stick and a vertical plane is the cambered surface that seamlessly transits, compound one deck contains the luminous reflecting mortar surface layer of glass microballoon on above-mentioned end face and the cambered surface, and the bottom surface of luminous reflecting mortar surface layer is secreted the fresh laitance that and solidified above the concrete stick.
The mixing ratio by weight of concrete stick base layer calculates by general ordinary concrete.
Cement factor scope in the luminous reflecting mortar surface material is any number between the 5-30%, and part cement can substitute with flyash and slag.
The bead content range is any number between the 40%-85%, and it is 20 orders, 30 orders, 40 orders, 60 orders, 80 orders, 100 orders, 200 orders, 325 orders that the grating of bead can be selected particle diameter, and refractive index is the bead of 1.5-1.75.
The proportioning example of bead grating when higher-strength requires:
20 order beades 15%, 40 order beades 20%, 60 orders 20%, 120 order beades 40%, 200 orders 5%.
20 order beades 5%, 30 order beades 10%, 40 order beades 15%, 60 order beades 20%, 80 order beades 25%, 120 order beades 20%, 200 order beades 3%, 325 order beades 2%.
The proportioning example of bead grating during general requirements:
20 order beades 15%, 60 order beades 35%, 120 order beades 50%.
40 order beades 20%, 60 order beades 30%, 80 order beades 30%, 100 order beades 20%.
Luminescent powder content range: 1-10%, described luminescent powder be sulfide and rare earth aluminium borate luminescent powder or with the mixture of reflecting glass Bead.Can launch light such as white, yellowish green, blue, red.
Toner: make the luminous road kerb of color reflective, select colored beading or flint glass pearl color matching powder for use.Toner is to have
Good alkali-proof inorganic pigment can be selected different colours such as iron oxide red, iron oxide yellow look as a setting, and the light of emission different colours can have colors such as white, yellowish green, blue, red.Penetrate down the light of reflective light-emitting area reflection 40-85% in illumination.
Concrete admixtures content range: 0.1-6.0% comprises water reducing agent 0.1-3%, hardener 0-3%, re-dispersible glue powder 0-3%.
The mixing ratio by weight of luminous reflecting mortar surface material can be selected following embodiment:
| Cement (%) | Fine sand (%) | Bead (%) | Luminescent powder (%) | Toner (%) | Water reducing agent (%) | Concrete hardener (%) | Redispersable latex powder (%) |
| 5 | 5 | 85 | 1 | 1 | 0.1 | 0 | 2.9 |
| 10 | 5 | 75 | 5 | 2 | 1 | 0 | 2 |
| 15 | 10 | 60 | 10 | 0 | 1 | 1 | 3 |
| 20 | 10 | 60 | 5 | 2 | 1 | 0 | 2 |
| 25 | 15 | 50 | 3 | 3 | 1.5 | 0.5 | 2 |
| 30 | 20 | 40 | 8 | 0.5 | 1.5 | 0 | 0 |
Production method embodiment one of the present invention:
(1), the proportioning by the making ordinary concrete stirs cement, sandstone, Concrete admixtures, water earlier, pours in the mould preliminary vibration moulding into.
(2), then will be by cement 5-30%, fine sand 5-20%, luminescent powder 1-10%, bead 40-85%, Concrete admixtures 0.1-6%, toner 0-5%, water/binder ratio: 0.25-0.33 stirs, and be poured on the matrix of fresh moulding in the above-mentioned steps (1), again through vibration, pressure forming;
(3), after the demoulding, carry out maintenance, go out prefabricated illuminating light reflective concrete curb finished product in factory.
(4), finished surface carries out sandblast, polishing, obtains the high reflective luminous concrete road kerb in surface.
Production method embodiment two of the present invention:
(1) by the proportioning of making ordinary concrete cement, sandstone, Concrete admixtures, water are stirred earlier, pour in the mould, preliminary vibration moulding.
(2) will be stirred into the dryness powder by cement 5-30%, fine sand 5-20%, luminescent powder 1-10%, bead 40-85%, Concrete admixtures 0.1-6%, toner 0-5% then, and be sprinkling upon on the concrete stick laminar surface of bleeding phase, it is closely knit to carry out press polish.
(3) condensed seven days after, adopt the way of sandblast or polishing to obtain the illuminating light reflective concrete curb of field fabrication.
Above-mentioned cement, bead, toner, luminescent powder, cement water reducing agent, concrete hardener, redispersable latex powder, slag, flyash all have finished product to sell on market.
Claims (10)
1. illuminating light reflective concrete curb and production method thereof, be the Rectangular Concrete stick, it is characterized in that: the angle of the end face of concrete stick and a vertical plane is the cambered surface that seamlessly transits, compound one deck contains the luminous reflecting mortar surface layer of glass microballoon on above-mentioned end face and the cambered surface, and the bottom surface of luminous reflecting mortar surface layer is secreted the fresh laitance that and solidified above the concrete stick.
2. illuminating light reflective concrete curb according to claim 1 and production method thereof is characterized in that: the weight proportion of above-mentioned luminous reflecting mortar surface material is as follows:
Cement 5-30%;
Fine sand 5-20%;
Bead 40%-85%;
Luminescent powder 1%-10%;
Toner 0-5%;
Concrete admixtures 0.1-6.0%;
Water/binder ratio: 0.25-0.33.
3. illuminating light reflective concrete curb according to claim 2 and production method thereof, it is characterized in that: described bead is the bead of grating, wherein directly selection scope of glass beads is: 20 orders, 30 orders, 40 orders, 60 orders, 80 orders, 100 orders, 200 orders and 325 orders, refractive index are 1.5-1.75.
4. illuminating light reflective concrete curb according to claim 3 and production method thereof is characterized in that: the grating of described bead is:
20 order bead 10-20%, 40 order bead 15-25%, 60 order 15-25%, 120 order bead 35-45%, 200 order 1-5%;
Or: 20 order bead 5-15%, 30 order bead 10-20%, 40 order bead 10-20%, 60 order bead 15-20%, 80 order bead 20-30%, 120 order bead 15-25%, 200 order bead 1-5%, 325 order bead 1-3%;
Or: 20 order bead 10-20%, 60 order bead 30-40%, 120 order bead 45-55%;
Or: 40 order bead 15-25%, 60 order bead 25-35%, 80 order bead 25-35%, 100 order bead 15-25%.
5. according to claim 2 or 3 or 4 described illuminating light reflective concrete curb and production methods thereof, it is characterized in that: described luminescent powder be sulfide and rare earth aluminium borate luminescent powder or with the mixture of reflecting glass Bead.
6. according to claim 2 or 3 or 4 described illuminating light reflective concrete curb and production methods thereof, it is characterized in that: described toner is iron oxide red or iron oxide yellow.
7. according to claim 2 or 3 or 4 described illuminating light reflective concrete curb and production methods thereof, it is characterized in that: the kind selected of described Concrete admixtures comprises cement water reducing agent 0.1%-1.5%, concrete hardener 0-3%, redispersable latex powder 0-3%.
8. illuminating light reflective concrete curb according to claim 2 and production method thereof is characterized in that following steps are arranged:
(1), earlier the proportioning of pressing ordinary concrete stirs cement, sandstone, Concrete admixtures, water, pours vibratory compaction in the mould into, is shaped to the concrete rectangular stick;
(2), on the concrete rectangular stick, make luminous reflecting mortar surface layer then, proportioning by above-mentioned luminous reflecting mortar surface material, stir and be poured over above the concrete rectangular stick, again through the vibratory compaction moulding, form luminous reflecting mortar surface layer, the bottom surface of luminous reflecting mortar surface layer is secreted above the concrete stick fresh laitance solidify;
(3) after the demoulding, carry out maintenance, make the illuminating light reflective concrete curb finished product.
9. illuminating light reflective concrete curb according to claim 8 and production method thereof is characterized in that: carry out step (4) after the described step (3): finished surface is washed, is polished, and obtains the concrete road kerb finished product of high luminous reflecting.
10. according to claim 2 or 3 or 4 described illuminating light reflective concrete curb and production methods thereof, it is characterized in that following steps are arranged:
(1), earlier the proportioning of pressing ordinary concrete stirs cement, sandstone, Concrete admixtures, water, pours vibratory compaction in the mould into, is shaped to the concrete rectangular stick;
(2), then make luminous reflecting mortar surface layer on the concrete rectangular stick, the proportioning by above-mentioned luminous reflecting mortar surface material is stirred into the dryness powder, is sprinkling upon on the concrete stick end face of bleeding phase, and it is closely knit to carry out press polish;
(3), carry out surfacing after condensing, obtain illuminating light reflective concrete curb.
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| Application Number | Priority Date | Filing Date | Title |
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| CNA200610200759XA CN1888317A (en) | 2006-07-31 | 2006-07-31 | Illuminating light reflective concrete curb and producing method thereof |
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| CNA200610200759XA CN1888317A (en) | 2006-07-31 | 2006-07-31 | Illuminating light reflective concrete curb and producing method thereof |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102531495A (en) * | 2011-12-30 | 2012-07-04 | 重庆暄洁环保产业（集团）股份有限公司 | Concrete road edge stones capable of preventing moss from growing |
| CN103880354A (en) * | 2014-02-18 | 2014-06-25 | 安徽润杨电力器材有限公司 | Fluorescent concrete luminous pole and preparation method thereof |
| CN105269655A (en) * | 2015-09-11 | 2016-01-27 | 怀宁县鸿腾矿业开发有限责任公司 | Road edge stone processing technology |
| CN106531010A (en) * | 2016-12-27 | 2017-03-22 | 安徽星光标识系统有限公司 | Manufacturing process of signboard |
| CN106988181A (en) * | 2016-12-19 | 2017-07-28 | 梁洲辅 | A kind of luminous building block brick and preparation method thereof |
| CN107082606A (en) * | 2017-06-03 | 2017-08-22 | 合肥慧林建材有限公司 | One kind can light alkaline-resisting environmentally friendly kerbstone and preparation method thereof |
| CN107190663A (en) * | 2017-06-23 | 2017-09-22 | 长春建维市政工程有限公司 | A kind of reflective curb of Combined integrated |
| CN107555874A (en) * | 2017-09-12 | 2018-01-09 | 成都新柯力化工科技有限公司 | A kind of reflective light flexible decorating road curb and preparation method |
| CN108783769A (en) * | 2018-07-16 | 2018-11-13 | 福建夜光达科技股份有限公司 | A kind of reflective waterproof slide fastener of microprism monomer and preparation method thereof |
| CN110240439A (en) * | 2019-06-28 | 2019-09-17 | 湖北工业大学 | A kind of preparation method of the luminous ecological substrate of the cured high-strength light of microorganism |
| CN110272238A (en) * | 2019-05-08 | 2019-09-24 | 赖志标 | The cement mortar that shines and preparation method thereof, shine concrete and preparation method thereof |
| CN110344343A (en) * | 2019-07-15 | 2019-10-18 | 张永强 | A kind of road dental calculus fluorescer complex vibration coating technique |
| CN110386791A (en) * | 2019-08-23 | 2019-10-29 | 长安大学 | A kind of hydrophobic self-luminous fluorescent pavement material and preparation method thereof |
| CN111377678A (en) * | 2018-12-31 | 2020-07-07 | 江苏苏博特新材料股份有限公司 | Fiber-toughened regenerated high-performance self-luminous concrete roadblock and preparation method thereof |
| CN111763046A (en) * | 2020-05-25 | 2020-10-13 | 安徽汇辽新型装饰材料有限公司 | Self-luminous architectural decoration prefabricated part and production method thereof |
| CN112922005A (en) * | 2021-01-28 | 2021-06-08 | 延安大学 | Construction method of large-volume building foundation |
| CN115467212A (en) * | 2022-09-02 | 2022-12-13 | 山东鑫润透水环保建材有限公司 | Fluorescent road edge stone and manufacturing method thereof and fluorescent road |
| CN115572109A (en) * | 2022-09-16 | 2023-01-06 | 中国一冶集团有限公司 | Self-luminous terrazzo kerbstone and preparation method thereof |
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2006
- 2006-07-31 CN CNA200610200759XA patent/CN1888317A/en active Pending
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|---|---|---|---|---|
| CN102531495A (en) * | 2011-12-30 | 2012-07-04 | 重庆暄洁环保产业（集团）股份有限公司 | Concrete road edge stones capable of preventing moss from growing |
| CN103880354A (en) * | 2014-02-18 | 2014-06-25 | 安徽润杨电力器材有限公司 | Fluorescent concrete luminous pole and preparation method thereof |
| CN105269655A (en) * | 2015-09-11 | 2016-01-27 | 怀宁县鸿腾矿业开发有限责任公司 | Road edge stone processing technology |
| CN106988181A (en) * | 2016-12-19 | 2017-07-28 | 梁洲辅 | A kind of luminous building block brick and preparation method thereof |
| CN106531010A (en) * | 2016-12-27 | 2017-03-22 | 安徽星光标识系统有限公司 | Manufacturing process of signboard |
| CN107082606A (en) * | 2017-06-03 | 2017-08-22 | 合肥慧林建材有限公司 | One kind can light alkaline-resisting environmentally friendly kerbstone and preparation method thereof |
| CN107190663A (en) * | 2017-06-23 | 2017-09-22 | 长春建维市政工程有限公司 | A kind of reflective curb of Combined integrated |
| CN107555874A (en) * | 2017-09-12 | 2018-01-09 | 成都新柯力化工科技有限公司 | A kind of reflective light flexible decorating road curb and preparation method |
| CN108783769A (en) * | 2018-07-16 | 2018-11-13 | 福建夜光达科技股份有限公司 | A kind of reflective waterproof slide fastener of microprism monomer and preparation method thereof |
| CN111377678A (en) * | 2018-12-31 | 2020-07-07 | 江苏苏博特新材料股份有限公司 | Fiber-toughened regenerated high-performance self-luminous concrete roadblock and preparation method thereof |
| CN110272238A (en) * | 2019-05-08 | 2019-09-24 | 赖志标 | The cement mortar that shines and preparation method thereof, shine concrete and preparation method thereof |
| CN110240439A (en) * | 2019-06-28 | 2019-09-17 | 湖北工业大学 | A kind of preparation method of the luminous ecological substrate of the cured high-strength light of microorganism |
| CN110240439B (en) * | 2019-06-28 | 2021-06-04 | 湖北工业大学 | Preparation method of light high-strength luminous ecological base material solidified by microorganisms |
| CN110344343A (en) * | 2019-07-15 | 2019-10-18 | 张永强 | A kind of road dental calculus fluorescer complex vibration coating technique |
| CN110386791A (en) * | 2019-08-23 | 2019-10-29 | 长安大学 | A kind of hydrophobic self-luminous fluorescent pavement material and preparation method thereof |
| CN111763046A (en) * | 2020-05-25 | 2020-10-13 | 安徽汇辽新型装饰材料有限公司 | Self-luminous architectural decoration prefabricated part and production method thereof |
| CN112922005A (en) * | 2021-01-28 | 2021-06-08 | 延安大学 | Construction method of large-volume building foundation |
| CN115467212A (en) * | 2022-09-02 | 2022-12-13 | 山东鑫润透水环保建材有限公司 | Fluorescent road edge stone and manufacturing method thereof and fluorescent road |
| CN115572109A (en) * | 2022-09-16 | 2023-01-06 | 中国一冶集团有限公司 | Self-luminous terrazzo kerbstone and preparation method thereof |
| CN115572109B (en) * | 2022-09-16 | 2024-04-02 | 中国一冶集团有限公司 | Self-luminous terrazzo curb and preparation method thereof |
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