CN1878671A - 具有乙烯－乙烯醇共聚物层和保护层的多层复合材料 - Google Patents
具有乙烯－乙烯醇共聚物层和保护层的多层复合材料 Download PDFInfo
- Publication number
- CN1878671A CN1878671A CNA2005800012099A CN200580001209A CN1878671A CN 1878671 A CN1878671 A CN 1878671A CN A2005800012099 A CNA2005800012099 A CN A2005800012099A CN 200580001209 A CN200580001209 A CN 200580001209A CN 1878671 A CN1878671 A CN 1878671A
- Authority
- CN
- China
- Prior art keywords
- layer
- acid
- multilayer materials
- described multilayer
- hexamethylene diamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 8
- 239000010410 layer Substances 0.000 title claims description 58
- 239000011241 protective layer Substances 0.000 title description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000000463 material Substances 0.000 claims abstract description 35
- 229920002313 fluoropolymer Polymers 0.000 claims abstract description 34
- 239000004811 fluoropolymer Substances 0.000 claims abstract description 34
- 229920000642 polymer Polymers 0.000 claims abstract description 34
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229920000098 polyolefin Polymers 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 229920002647 polyamide Polymers 0.000 claims abstract description 17
- 239000004952 Polyamide Substances 0.000 claims abstract description 16
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims abstract description 15
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims abstract description 14
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 14
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims abstract description 12
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000178 monomer Substances 0.000 claims abstract description 9
- 229920000305 Nylon 6,10 Polymers 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 8
- 235000011037 adipic acid Nutrition 0.000 claims abstract description 8
- 239000000206 moulding compound Substances 0.000 claims abstract description 8
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims abstract description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000768 polyamine Polymers 0.000 claims abstract description 7
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920001971 elastomer Polymers 0.000 claims abstract description 5
- 239000005060 rubber Substances 0.000 claims abstract description 5
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 claims abstract 2
- -1 polyethylene Polymers 0.000 claims description 20
- 238000012986 modification Methods 0.000 claims description 12
- 239000011230 binding agent Substances 0.000 claims description 11
- 238000000465 moulding Methods 0.000 claims description 11
- 150000003951 lactams Chemical class 0.000 claims description 10
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 7
- 239000001361 adipic acid Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000004743 Polypropylene Substances 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 239000002033 PVDF binder Substances 0.000 claims description 5
- 150000004985 diamines Chemical class 0.000 claims description 5
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000012790 adhesive layer Substances 0.000 claims description 2
- 239000002826 coolant Substances 0.000 claims description 2
- 238000001746 injection moulding Methods 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 claims description 2
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims 2
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 239000002318 adhesion promoter Substances 0.000 abstract 1
- 229960000250 adipic acid Drugs 0.000 abstract 1
- 239000002671 adjuvant Substances 0.000 abstract 1
- 239000000446 fuel Substances 0.000 description 12
- 229920001577 copolymer Polymers 0.000 description 9
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 8
- RTWNYYOXLSILQN-UHFFFAOYSA-N methanediamine Chemical compound NCN RTWNYYOXLSILQN-UHFFFAOYSA-N 0.000 description 7
- 230000009471 action Effects 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 4
- 238000007664 blowing Methods 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229920006097 Ultramide® Polymers 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 150000002148 esters Chemical group 0.000 description 3
- 229920006129 ethylene fluorinated ethylene propylene Polymers 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 150000003628 tricarboxylic acids Chemical class 0.000 description 3
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 229920000914 Metallic fiber Polymers 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- 229920006367 Neoflon Polymers 0.000 description 2
- 229920002873 Polyethylenimine Polymers 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 229920006099 Vestamid® Polymers 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 150000003851 azoles Chemical class 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- KNCYXPMJDCCGSJ-UHFFFAOYSA-N piperidine-2,6-dione Chemical compound O=C1CCCC(=O)N1 KNCYXPMJDCCGSJ-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 230000003442 weekly effect Effects 0.000 description 2
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical class OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- VUYOLIKWIVQHBC-UHFFFAOYSA-N 1-methylpiperidine-2,6-dione Chemical class CN1C(=O)CCCC1=O VUYOLIKWIVQHBC-UHFFFAOYSA-N 0.000 description 1
- GVJRTUUUJYMTNQ-UHFFFAOYSA-N 2-(2,5-dioxofuran-3-yl)acetic acid Chemical compound OC(=O)CC1=CC(=O)OC1=O GVJRTUUUJYMTNQ-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical group 0.000 description 1
- 239000012296 anti-solvent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 description 1
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 239000002482 conductive additive Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000000412 dendrimer Substances 0.000 description 1
- 229920000736 dendritic polymer Polymers 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- GLUUGHFHXGJENI-UHFFFAOYSA-N diethylenediamine Natural products C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical class O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- CHSILQAFIZTLJN-UHFFFAOYSA-N heptadecane-1,17-diamine Chemical class NCCCCCCCCCCCCCCCCCN CHSILQAFIZTLJN-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000003949 imides Chemical group 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 125000004193 piperazinyl group Chemical group 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/16—Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/28—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J177/00—Adhesives based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Adhesives based on derivatives of such polymers
- C09J177/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J177/00—Adhesives based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Adhesives based on derivatives of such polymers
- C09J177/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J177/00—Adhesives based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Adhesives based on derivatives of such polymers
- C09J177/06—Polyamides derived from polyamines and polycarboxylic acids
- C09J177/08—Polyamides derived from polyamines and polycarboxylic acids from polyamines and polymerised unsaturated fatty acids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/12—Rigid pipes of plastics with or without reinforcement
- F16L9/133—Rigid pipes of plastics with or without reinforcement the walls consisting of two layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/02—Synthetic macromolecular particles
- B32B2264/0207—Particles made of materials belonging to B32B25/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/202—Conductive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/40—Closed containers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2597/00—Tubular articles, e.g. hoses, pipes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/08—Cars
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S138/00—Pipes and tubular conduits
- Y10S138/01—Adhesive
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S138/00—Pipes and tubular conduits
- Y10S138/07—Resins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
- Y10T428/1393—Multilayer [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/31728—Next to second layer of polyamide
- Y10T428/31732—At least one layer is nylon type
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Laminated Bodies (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
包括以下各层的多层复合材料具有改进的各层粘合性：I.选自氟聚合物模塑组合物和聚烯烃模塑组合物的内部层I；II.具有以下组成的粘结剂层II：a)0到80重量份多元胺－聚酰胺接枝共聚物，b)0到100重量份聚酰胺，c)0到85重量份选自氟聚合物和聚烯烃的聚合物，其中a)，b)和c)的重量份的总和为100，和，另外－组分a)和b)的总和包括至少20重量份衍生自以下的单体单元：己内酰胺和/或以下组合：六亚甲基二胺/己二酸、六亚甲基二胺/辛二酸、六亚甲基二胺/癸二酸、六亚甲基二胺/十二烷二酸、六亚甲基二胺/间苯二甲酸或六亚甲基二胺/对苯二甲酸和d)至多50重量份选自冲击改性橡胶和常规辅助剂和添加剂的添加剂；III.包括EVOH模塑组合物的层III。
Description
本发明涉及具有阻隔层和保护层的多层复合材料，该阻隔层包括乙烯-乙烯醇共聚物(EVOH)，而该保护层包括形成防醇阻隔层并选自氟聚合物和聚烯烃的材料。
在例如作为管子在机动车辆中用于输送液体或气态介质的多层复合材料的发展中，所使用的模塑组合物必须对将要输送的介质具有足够的耐化学品性且该管子即使在长期暴露于燃料、油或热下之后必须能满足所有的对它们提出的力学要求。除了要求足够的耐油性之外，汽车工业还要求燃料管线具有改进的阻隔作用以降低烃类排放到环境中的量。多层管路体系的开发也就应运而生，其中例如EVOH用作阻隔层材料。此类体系例如描述在US 5 038 883、US 5 076 329和EP-A-1 216826中。然而，这些已知管子的缺点在于防醇阻隔作用不是令人满意的且内部层的防水阻隔作用也不令人满意，水随着时间会进入该EVOH层并导致防醇阻隔作用的进一步恶化。
为了解决该问题，EP-A-0 559 445建议施用氟聚合物层作为最内层。氟聚合物层和EVOH层通过粘结剂彼此连接。所公开的粘结剂是乙烯-丙烯酸酯共聚物、乙烯-醋酸乙烯酯共聚物、带有环氧基的聚烯烃和偏二氟乙烯和甲基丙烯酸甲酯的接枝共聚物。然而，证实这几乎没有实现任何粘合，持久粘合就更少了。由于所公开的成分中其中有一些是可溶于燃料的，这些偶联剂不具有令人满意的耐油性和耐热变形性。另外，本领域技术人员在EP-A-0 559 445的一般教导下不能容易地在这一方面重复该工作。
作为改进，聚烯烃系内部层还能提高防醇阻隔作用并，具体来说，阻挡水来保护EVOH。然而，也存在这样的问题，就是必须达到令人满意的粘合性。
因此，本发明的目的是开发使EVOH和氟聚合物或聚烯烃间的良好的粘合性成为可能的粘结剂。另一个目的是使粘结免受接触燃料的不利影响成为可能。另外，该粘结在该复合材料的使用期间应该维持在令人满意的程度。总的说来，非常简单的技术解决方案是所需的。
这些目的通过包括以下各层的多层复合材料来实现：
I：选自粘合-改性或未改性的氟聚合物模塑组合物和粘合-改性或未改性的聚烯烃模塑组合物的内部层I；
II：具有以下组成的粘结剂层II：
a)0到80重量份，优选1到60重量份，特别优选3到40重量份使
用以下单体制备的接枝共聚物：
-基于该接枝共聚物计0.5到25wt％的具有至少4个、优选至少8个、特别优选至少11个氮原子和数均分子量Mn优选至少146g/mol、特别地优选至少500g/mol、非常特别优选至少800g/mol的多元胺，和
-选自内酰胺、ω-氨基羧酸和二胺和二元羧酸等摩尔组合(combinations)的形成聚酰胺的单体；
b)0到100重量份，优选10到75重量份，特别优选25到65重量份聚酰胺；
c)0到85重量份，优选5到75重量份，特别地优选10到65重量份，非常特别优选25到55重量份选自氟聚合物和聚烯烃的聚合物；
其中a)，b)和c)的重量份的总和为100，和，另外
-组分a)和b)的总和包括至少20重量份，优选至少40重量份，特别优选至少60重量份衍生自以下的单体单元：己内酰胺和/或以下组合：六亚甲基二胺/己二酸、六亚甲基二胺/辛二酸、六亚甲基二胺/癸二酸、六亚甲基二胺/十二烷二酸、六亚甲基二胺/间苯二甲酸或六亚甲基二胺/对苯二甲酸和
d)至多50重量份，优选至多30重量份，特别优选至多20重量份选自冲击-改性橡胶和常规辅助剂和添加剂的添加剂；
III.包括EVOH模塑组合物的层III。
该多层复合材料通常是管子或中空体。
用于层I的氟聚合物例如是聚偏二氟乙烯(PVDF)，乙烯-四氟乙烯共聚物(ETFE)，用第三组分如丙烯、六氟丙烯、乙烯基氟或偏二氟乙烯改性的ETFE(例如EFEP)，乙烯-三氟氯乙烯共聚物(E-CTFE)，聚三氟氯乙烯(PCTFE)，四氟乙烯-六氟丙烯-偏二氟乙烯共聚物(THV)，四氟乙烯-六氟丙烯共聚物(FEP)或四氟乙烯-全氟烷基乙烯基醚共聚物(PFA)。
如果层II的粘结剂本身不含足够量的氟聚合物，则层I的氟聚合物优选是粘合改性的，即存在这样的官能团，它们能与粘结剂的氨基反应并因此使相的粘结成为可能。此类粘合改进通常以两种方法实现：
-或者该氟聚合物包含内部(built-in)官能团，例如酸酐基团或碳酸根(酯)基团，如US5 576 106、US-A-2003148125、US-A-2003035914、US-A-2002104575、JP-A-10311461、EP-A-0 726 293、EP-A 0 992 518或者WO 9728394中所述。
-或者该氟聚合物模塑组合物包括这样的聚合物，其含有可与该氟聚合物混溶或者至少能与该氟聚合物相容的官能团。此类体系例如公开在EP-A-0 637 511或者美国相应专利US 5 510 160中和在EP-A-0 673 762或者美国相应专利US 5 554 426中，它们特意在此引入供参考。EP-A-0 673 762的改性氟聚合物包括：
-97.5到50wt％，优选97.5到80wt％，特别优选96到90wt％PVDF和-2.5到50wt％，优选2.5到20wt％，特别优选4到10wt％包括至少以下基本结构单元的丙烯酸酯共聚物：
i)14到85wt％酯结构单元，
ii)0到75wt％酰亚胺结构单元，
iii)0到15wt％羧酸结构单元和
iiii)7到20重量份羧酸酐结构单元。
有关详细情形，读者可参考有关内容特意在此引入本专利申请公开内容中供参考的文件。
做为候选用于层I的聚烯烃可以首先是聚乙烯，尤其是高密度聚乙烯(HDPE)，或者是等规聚丙烯。该聚丙烯可以是均聚物或共聚物，例如能够使用乙烯或1-丁烯作为共聚单体，也能使用无规和嵌段共聚物。另外，该聚丙烯也可以是冲击-改性的，例如，如现有技术中公开的，用乙丙橡胶(EPM)或EPDM改性。
当层II的粘结剂本身不包含足够量的聚烯烃时，则层I的聚烯烃优选通过存在能与粘结剂的氨基反应的官能团来粘合改性。适合的官能团首先是羧基、羧酸酐基团、碳酸根(酯)基团、酰基内酰胺基团、唑啉基团、嗪基团、嗪酮基团、碳二亚胺基团或环氧基团。
如现有技术中所公开的，该官能团通常借助自由基和/或热通过与诸如丙烯酸、马来酸、富马酸、马来酸单丁基酯、马来酸酐、乌头酸酐、衣康酸酐或乙烯基唑啉的烯属不饱和官能团化合物反应而接枝于聚烯烃链上，或它们通过烯属不饱和官能团化合物与烯烃的自由基共聚而引入该主链中。
在组分II.a)的接枝共聚物的情况下，氨基浓度优选为100到2500mmol/kg。
作为多元胺，有可能使用例如以下类别的物质：
-多乙烯胺(Rmpp Chemie Lexikon，第9版，第6卷，4921页，GeorgThieme Verlag Stuttgart 1992)；
-由交替聚酮制备的多元胺(DE-A 196 54 058)；
树型化合物(枝状体)，例如(H2N-(CH2)3)2N-(CH2)3)2-N(CH2)2-N((CH2)2-N((CH2)3-NH2)2)2(DE-A-196 54 179)或三(2-氨乙基)胺、N，N-双(2-氨乙基)-N’，N’-双[2-[双(2-氨乙基)氨基]乙基]-1，2-乙烷二胺、3，15-双(2-氨乙基)-6，12-双[2-[双(2-氨乙基)氨基]乙基]-9-[2-[双[2-双(2-氨乙基)-氨基)乙基]氨基]乙基]-3，6，9，12，15-五氮杂十七烷-1，17-二胺(J.M.Warakomski，Chem.Mat.1992，4，1000-1004)；
-通过聚合4，5-二氢-1，3-唑并随后水解制备的线性聚乙烯亚胺(Houben-Weyl，Methoden der Organischen Chemie，第E20卷，1482-1487页，Georg Thieme Verlag Stuttgart，1987)；
-通过聚合氮丙啶制备的支化聚乙烯亚胺(Houben-Weyl，Methodender Organischen Chemie，第E20卷，1482-1487页，Georg ThiemeVerlag Stuttgart，1987)且该聚合物通常具有以下氨基分布：
25到46％伯氨基，
30到45％仲氨基和
16到40％叔氨基。
在优选的情况中，多元胺具有至多20000g/mol，特别优选至多10000g/mol，非常特别优选至多5000g/mol的数均分子量Mn。
用作形成聚酰胺的单体的内酰胺或ω-氨基羧酸含有4到19，尤其是6到12个碳原子。特别优选使用ε-己内酰胺、ε-氨基己酸、辛内酰胺、ω-氨基辛酸、月桂内酰胺、ω-氨基十二烷酸和/或ω-氨基十一烷酸。
二胺和二元羧酸的组合例如是六亚甲基二胺/己二酸、六亚甲基二胺/十二烷二酸、辛亚甲基二胺/癸二酸、癸亚甲基二胺/癸二酸、癸亚甲基二胺/十二烷二酸、十二亚甲基二胺/十二烷二酸和十二亚甲基二胺/2，6-萘二甲酸。另外，还有可能使用所有其它组合，例如癸亚甲基二胺/十二烷二酸/对苯二甲酸、六亚甲基二胺/己二酸/对苯二甲酸、六亚甲基二胺/己二酸/己内酰胺、癸亚甲基二胺/十二烷二酸/ω-氨基十一烷酸、癸亚甲基二胺/十二烷二酸/月桂内酰胺、癸亚甲基二胺/对苯二甲酸/月桂内酰胺或十二亚甲基二胺/2，6-萘二甲酸/月桂内酰胺。
在优选实施方案中，该接枝共聚物是追加使用低元羧酸来制备的，在每种情况下，基于其它形成聚酰胺的单体的总和计，低元羧酸选自0.015到大约3mol％二元羧酸和0.01到大约1.2mol％三元羧酸。在这些百分率中，单独地考虑在二胺和二元羧酸的当量组合中的各种单体二胺和二元羧酸。这样，该形成聚酰胺的单体总体上羧基稍微过量。如果使用二元羧酸，优选添加0.03到2.2mol％，特别优选0.05到1.5mol％，非常特别优选0.1到1mol％，尤其是0.15到0.65mol％；如果使用三元羧酸，优选使用0.02到0.9mol％，特别优选0.025到0.6mol％，非常特别优选0.03到0.4mol％，尤其是0.4到0.25mol％。同时使用低元羧酸不但显著地提高了耐溶剂和油性，尤其是耐水解和醇解性和耐环境应力开裂性，而且提高了溶胀行为和与此相关的尺寸稳定性以及防漫射阻隔作用。
作为低元羧酸酸，有可能使用具有6到24个碳原子的任何二元羧酸或三元羧酸，例如己二酸、辛二酸、壬二酸、癸二酸、十二烷二酸、间苯二甲酸、2，6-萘二甲酸、环己烷-1，4-二羧酸、均苯三酸和/或偏苯三酸。
另外，如果需要的话有可能使用具有3到50个碳原子的脂族，脂环族，芳族芳烷基和/或烷芳基取代的单羧酸，例如十二烷酸、不饱和脂肪酸、丙烯酸或苯甲酸作为调节剂。这些调节剂使得有可能降低氨基的浓度而不会改变分子的结构。另外，用这种方法能引入诸如双或三键等的官能团。然而，希望该接枝共聚物具有相当大比例的氨基。该接枝共聚物的氨基浓度特别优选为150到1500mmol/kg，尤其是250到1300mmol/kg，非常特别优选300到1100mmol/kg。这里以及在下文中的术语“氨基”不但指端氨基而且指存在于多元胺中的任何仲或叔胺官能团。
这些接枝共聚物的制备更详细地描述在EP-A-1 065 048中。
组分II.b)的聚酰胺优选包括PA6、PA66、PA6/66、PA68、PA610、PA612、衍生自六亚甲基二胺以及间苯二甲酸和/或对苯二甲酸的聚酰胺、基于这些类型的共聚酰胺或它们的混合物。
PA6/66是由单体己内酰胺、六亚甲基二胺以及己二酸制备的共缩聚物。
作为能任选地作为组分II.c)的构分存在的氟聚合物和聚烯烃，有可能使用与层I相同的配混料。在这种情况下，当层I包括氟聚合物模塑组合物时，组分II.c)可同样包括氟聚合物(优选相同类型)，然而在这种情况下在组分II.c)中使用聚烯烃不会提高层的粘合性。
类似地，当层I包括聚烯烃模塑组合物时，组分II.c)同样可包括聚烯烃(优选相同类型)，然而在这种情况下在组分II.c)中使用氟聚合物不会提高层的粘合性。
任选存在于组分II.c)中的氟聚合物或聚烯烃优选如上所述是粘合-改性的。在这种情况下，层I的模塑组合物的粘合改性可省去。
作为组分II.d)中的辅助剂和/或添加剂，有可能使用例如增塑剂、阻燃剂、稳定剂、加工助剂、层状硅酸盐、颜料、成核剂等。
EVOH早就是已知的。它是乙烯和乙烯醇的共聚物且有时还称为EVAL。该共聚物的乙烯含量通常为25到60mol％，尤其是28到45mol％。许多类型是市场上可买到的。例如，可参考公司手册“Introduction to Kuraray EVALTM Resins”，版本1.2/9810，来自Kuraray EVAL Europe。
除了层I～III之外，本发明复合材料中还可以存在另外的层，例如层V，其包括聚酰胺模塑组合物或聚烯烃模塑组合物并通过适合的粘结剂(层IV)连接到层III。适于这一目的的粘结剂是现有的。该聚酰胺或聚烯烃层还能通过包括橡胶或热塑性弹性体的壳层(sheathing)连接。另外的，最内部的氟聚合物或聚烯烃层可同样连接该内部层I。
在一个实施例中，该多层复合材料还包括回用料层。在根据本发明的复合材料的生产中，例如在挤塑装置的启动期间或在挤坯吹塑中以溢料形式、或在管子精加工(finishing)中时常会产生碎片。将由该碎片制成的回用料层嵌入两个其它层之间，这样能很好补偿该回用料共混物的脆性。
本发明多层复合材料例如是管子、充填口或容器，尤其是用于输送或储存液体或气体。这样的管子可以是平滑的或波纹形的或者仅在小段成为波纹形。波纹形管是现有技术(例如US 5 460 771)，因此在这个问题上不需要另外详述。此类多层复合材料的重要用途是用作燃料管线、槽充填口、蒸汽管线(即燃料蒸汽在其中输送的管线，例如排气管线)、灌装工位管线、冷却剂管线、空调器管线或者燃料容器(例如罐或槽)。
当本发明多层复合材料用于输送或储存易燃液体，气体或尘埃，例如燃料或燃料蒸汽时，最好使组成复合材料的层或附加的内部层导电。这可以通过使用所有现有技术中的方法混合导电添加剂来实现。作为导电性添加剂，有可能使用例如导电性炭黑、金属薄片、金属粉末、金属化玻璃球、金属化玻璃纤维、金属纤维(例如不锈钢的金属纤维)、金属化晶须、碳纤维(包括金属化碳纤维)、本身导电性聚合物或石墨纤丝。也可以使用各种导电性添加剂的混合物。
在优选情况下，该导电层直接接触输送或储存的介质且具有至多109Ω/平方(Ω/square)，优选至多106Ω/平方的表面电阻。测定多层管电阻的测量方法描述在SAE J 2260(1996年11月，7.9节)中。
该多层复合材料可以以一个或多个步骤制造，例如通过单步骤工艺使用多组分注塑法、共挤塑法、共挤吹塑法(例如还有3D吹塑、将型坯挤压进入敞模瓣中、3D型坯操作、抽吸吹塑(suction blowmolding)、3D抽吸吹塑、连续吹塑)或通过多步骤工艺，例如涂覆。
以下将通过实施例来说明本发明。在实施例中，使用以下模塑组合物：
内部层(层I)：
氟聚合物1：如EP-A 0 673 762中所述的混合物，由95wt％市售PVDF和5wt％聚戊二酰亚胺组成，该聚戊二酰亚胺由以下基本结构单元构成：
57wt％衍生自甲基丙烯酸甲酯，
30wt％N-甲基-戊二酰亚胺类，
3wt％衍生自甲基丙烯酸和
10wt％戊二酸酐类(通过使甲基丙烯酸甲酯与在熔体状态下的甲胺的水溶液反应来制备)
氟聚合物2：NEOFLONRP 5000，来自Daikin Industries Ltd.，Japan，改性EFEP
氟聚合物3：NEOFLONRP 5000 AS，来自Daikin Industries Ltd.，Japan，已成为导电的改性EFEP
聚烯烃1：STAMYLANP 83MF 10，来自DSM Deutschland GmbH的PP共聚物
聚烯烃2：VESTOLENA 6013，来自DSM Deutschland GmbH的HDPE
粘结剂(层II和IV)：
接枝共聚物的制备：
将9.5kg月桂内酰胺于升温容器中在180℃-210℃下熔融并转入压力-分级的缩聚容器中；随后添加475g水和0.54g次磷酸。在自生压力下，内酰胺在280℃离解；然后在3小时的期间内将混合物减压到残留水蒸气压为5巴，并添加500g聚乙烯亚胺(来自BASF AG，Ludwigshafen的LUPASOL G 100)和15g十二烷二酸。在自生压力下同时混合两个成分；随后将混合物减压到大气压，然后在280℃于该熔体上方通过氮气2小时。借助熔体泵以线料形式排出透明熔体，在水浴中冷却并随后造粒。
HV 1：在双螺杆混配机(来自Berstorff均ZE 25 33D，270℃，150rpm，通过量为10kg/h)上熔融混合12.6kg PA6(来自BASF AG的ULTRAMIDB4)、22.82kg氟聚合物2和5.0kg接枝共聚物，挤出并造粒。
HV 2：PA6(来自BASF AG的ULTRAMIDB4)
HV 3：类似HV 1，除了氟聚合物2用接枝有马来酸酐的聚丙烯(来自Mitsui Chemicals Inc.，Japan的ADMERQB 520E)代替
HV 4：类似HV 1，除了氟聚合物2用接枝有马来酸酐的聚乙烯(来自Mitsui Chemicals Inc.，Japan的ADMERNF 408E)代替
HV 5：用双螺杆挤压机Berstorff ZE 25在280℃制备自35.3wt％VESTAMIDD22(来自Degussa AG的PA612)、48.1wt％ULTRAMIDB5W(来自BASF AG的PA6)、10.7wt％接枝共聚物和5.4wt％EXXELORVA1803(来自EXXON的用马来酸酐官能化的乙丙橡胶)的均质混合物，以线料形式挤出，造粒并干燥。
EVOH层(层III)：EVALF101，来自KURARAY的EVOH，含有32mol％乙烯
外层(层V)：
PA12：来自Degussa AG的冲击-改性，增塑聚酰胺(VESTAMIDX 7293)
聚烯烃2：如上
实施例1到5：
在装备有两个45型挤塑机和三个30型挤塑机的5-层装置上以大约12m/min的挤出速度生产尺寸为8×1mm的管子。
| 实施例 | 内部层＝层I | 层II | 层III | 层IV | 层v |
| 1 | 0.1mm氟聚合物1 | 0.2mmHV 2 | 0.1mmEVOH | 0.2mmHV 5 | 0.4mmPA 12 |
| 2 | 0.1mm氟聚合物2 | 0.2mmHV 1 | 0.1mmEVOH | 0.2mmHV 5 | 0.4mmPA 12 |
| 3 | 0.1mm氟聚合物3 | 0.2mmHV 1 | 0.1mmEVOH | 0.2mmHV 5 | 0.4mmPA 12 |
| 4 | 0.1mm聚烯烃1 | 0.2mmHV 3 | 0.1mmEVOH | 0.2mmHV 5 | 0.4mmPA 12 |
| 5 | 0.1mm聚烯烃2 | 0.2mmHV 4 | 0.1mmEVOH | 0.2mmHV 4 | 0.4mm聚烯烃2 |
管子的特征：
在实施例1～5的管子的情况下，内部氟聚合物或聚烯烃层与EVOH层间的粘合性高到当刚挤出时和在燃料中储存(使用CM 15的内部接触储存，即，测试燃料由42.5体积％异辛烷、42.5体积％甲苯和15体积％甲醇组成，在80℃，每周更换一次燃料，1000h)之后复合材料都不会分离。
根据SAE J 2260，在-40℃下的低温冲击韧性测试中，所有管子当刚挤出时和在燃料中储存(使用CM 15在80℃的内部接触储存，每周更换一次燃料，1000h)之后的破裂率都是0/10。
Claims (16)
1.包括以下各层的多层复合材料，
I：选自氟聚合物模塑组合物和聚烯烃模塑组合物的内部层I；
II：具有以下组成的粘结剂层II：
a)0到80重量份使用以下单体制备的接枝共聚物
-基于该接枝共聚物计0.5到25wt％具有至少4个氮原子的多元胺和
-形成聚酰胺的单体，其选自内酰胺、ω-氨基羧酸以及二胺和二元羧酸的等摩尔混合物；
b)0到100重量份聚酰胺；
c)0到85重量份选自氟聚合物和聚烯烃的聚合物；
其中a)，b)和c)的重量份的总和为100，和，另外
-组分a)和b)的总和包括至少20重量份衍生自以下的单体单元：己内酰胺和/或以下组合：六亚甲基二胺/己二酸、六亚甲基二胺/辛二酸、六亚甲基二胺/癸二酸、六亚甲基二胺/十二烷二酸、六亚甲基二胺/间苯二甲酸或六亚甲基二胺/对苯二甲酸和
d)至多50重量份选自冲击改性橡胶和常规辅助剂和添加剂的添加剂；
III：包括EVOH模塑组合物的层III。
2.权利要求1所述的多层复合材料，其中
-该组分IIa)的存在量为1到60重量份和/或
-该组分IIb)的存在量为10到75重量份。
3.权利要求1所述的多层复合材料，其中
-该组分IIa)的存在量为3到40重量份和/或
-该组分IIb)的存在量为25到65重量份。
4.上述权利要求中任一项所述的多层复合材料，其中存在5到75重量份组分IIc)。
5.权利要求4所述的多层复合材料，其中存在10到65重量份组分IIc)。
6.权利要求4所述的多层复合材料，其中存在20到55重量份组分IIc)。
7.上述权利要求中任一项所述的多层复合材料，其中该氟聚合物选自PVDF，ETFE、用第三组分改性的ETFE、E-CTFE、PCTFE、THV、FEP和PFA。
8.权利要求1到6中任一项所述的多层复合材料，其中聚乙烯或等规聚丙烯用作聚烯烃。
9.上述权利要求中任一项所述的多层复合材料，其中该氟聚合物或聚烯烃是粘合-改性的。
10.上述权利要求中任一项所述的多层复合材料，其中组分IIb的聚酰胺包括PA6、PA66、PA6/66、PA68、PA610、PA612、衍生自六亚甲基二胺和间苯二甲酸和/或对苯二甲酸的聚酰胺或它们的混合物。
11.上述权利要求中任一项所述的多层复合材料，它还具有这样的层，该层包括聚酰胺模塑组合物或聚烯烃模塑组合物并通过适合的粘结剂连接到层III。
12.上述权利要求中任一项所述的多层复合材料，它是管子或中空体。
13.上述权利要求中任一项所述的多层复合材料，它是整体成波纹形的或子区成波纹形的管子。
14.上述权利要求中任一项所述的多层复合材料，它是燃料管线、制动液管线、冷却剂管线、液压液管线、灌装工位管线、空调器管线、蒸汽管线、容器或充填口。
15.上述权利要求中任一项所述的多层复合材料，其中组成该复合材料的各层之一或附加的内部层已制成导电的。
16.上述权利要求中任一项所述的多层复合材料，它通过共挤塑、涂覆、多组分注塑或共挤吹塑来制备。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE200410048776 DE102004048776A1 (de) | 2004-10-07 | 2004-10-07 | Mehrschichtverbund mit EVOH-Schicht und Schutzschicht |
| DE102004048776.6 | 2004-10-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1878671A true CN1878671A (zh) | 2006-12-13 |
| CN100450772C CN100450772C (zh) | 2009-01-14 |
Family
ID=35385426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005800012099A Active CN100450772C (zh) | 2004-10-07 | 2005-08-10 | 具有乙烯-乙烯醇共聚物层和保护层的多层复合材料 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8133561B2 (zh) |
| EP (1) | EP1799452B1 (zh) |
| JP (1) | JP4938671B2 (zh) |
| KR (1) | KR100879698B1 (zh) |
| CN (1) | CN100450772C (zh) |
| AR (1) | AR051134A1 (zh) |
| BR (1) | BRPI0517546B1 (zh) |
| DE (1) | DE102004048776A1 (zh) |
| RU (1) | RU2387545C2 (zh) |
| WO (1) | WO2006040206A1 (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101966772A (zh) * | 2010-09-01 | 2011-02-09 | 丹东鑫马高科技塑料包装有限公司 | 高阻隔性塑料软包装膜 |
| CN107428139A (zh) * | 2016-01-15 | 2017-12-01 | 阿科玛法国公司 | 对于生物汽油中的提取具有改善的抗性的多层管状结构体和其用途 |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5352238B2 (ja) * | 2005-12-29 | 2013-11-27 | アーケマ・インコーポレイテッド | 多層フルオロポリマーフィルム |
| US20100183881A1 (en) * | 2006-01-26 | 2010-07-22 | Shigeyuki Yasui | Laminate |
| DE102006040112A1 (de) * | 2006-08-26 | 2008-03-06 | Evonik Degussa Gmbh | Verbundteil aus einer Mehrschichtfolie und einem Substrat auf Basis eines Polycarbonats |
| DE102006041138A1 (de) * | 2006-09-01 | 2008-03-06 | Evonik Degussa Gmbh | Verbund aus einer Folie und einem Substrat auf Basis eines amorphen Polyamids |
| FR2908075B1 (fr) * | 2006-11-07 | 2012-03-16 | Arkema France | Structure multicouche a base d'un polymere barriere eventuellement renforce a l'impact |
| DE102006054268A1 (de) * | 2006-11-17 | 2008-05-21 | Veritas Ag | Rohrförmiges Formteil |
| DE102006058681A1 (de) * | 2006-12-13 | 2008-06-19 | Evonik Degussa Gmbh | Transparentes Bauteil |
| DE102007003327A1 (de) * | 2007-01-17 | 2008-07-24 | Evonik Degussa Gmbh | Mehrschichtfolie und daraus hergestelltes Verbundteil |
| US9662869B2 (en) | 2007-02-08 | 2017-05-30 | Meissner Filtration Products, Inc. | Multilayer film, method of making the same and containers formed from the same |
| DE102007038578A1 (de) * | 2007-08-16 | 2009-02-19 | Evonik Degussa Gmbh | Verfahren zur Dekorierung von Oberflächen |
| US9682526B2 (en) | 2007-10-02 | 2017-06-20 | Meissner Filtration Products, Inc. | Radio frequency weldable multilayer tubing and method of making the same |
| US20140069546A1 (en) | 2011-05-05 | 2014-03-13 | Pipelion Pty Ltd | Fire retardant and anti static pipe |
| DE102011084518A1 (de) | 2011-10-14 | 2013-04-18 | Evonik Industries Ag | Verwendung einer Mehrschichtfolie mit Polyamid- und Polyesterschichten fürdie Herstellung photovoltaischer Module |
| DE102011084521A1 (de) | 2011-10-14 | 2013-04-18 | Evonik Industries Ag | Verwendung einer Mehrschichtfolie mit Polyamid- und Polypropylenschichten für die Herstellung photovoltaischer Module |
| DE102011084520A1 (de) | 2011-10-14 | 2013-04-18 | Evonik Industries Ag | Rückfolie für Photovoltaikmodule mit verbesserter Pigmentdispergierung |
| DE102012007031A1 (de) * | 2012-04-05 | 2013-10-10 | A. Schulman Gmbh | Rohrsystem zum Leiten von leicht entzündlichen Flüssigkeiten |
| EP2998339B1 (de) * | 2014-08-26 | 2019-01-30 | Evonik Degussa GmbH | Metallisches rohr mit einer hydrolysestabilisierten schicht aus einer polyamidformmasse |
| JP6575524B2 (ja) * | 2014-09-12 | 2019-09-18 | 宇部興産株式会社 | 積層チューブ |
| CZ27700U1 (cs) * | 2014-10-15 | 2015-01-12 | Pipelife Czech S.R.O. | Termoplastický kompozit a trubka z něho vyrobená |
| FR3044585B1 (fr) * | 2015-12-08 | 2020-01-31 | Arkema France | Structure multicouche comprenant une couche contenant un polymere fluore et copolymere acrylique - procede de fabrication et tube associes |
| FR3046827B1 (fr) | 2016-01-15 | 2018-05-25 | Arkema France | Structure tubulaire multicouche possedant une meilleure resistance a l'extraction dans la bio-essence et son utilisation |
| DE102016216446A1 (de) | 2016-08-31 | 2018-03-01 | Kautex Textron Gmbh & Co. Kg | Kunststoffformteil aus einem extrudierten Mehrschichtverbund sowie Kraftstoffbehälter aus einem extrudierten Mehrschichtverbund |
| DE102017221467A1 (de) | 2017-11-29 | 2019-05-29 | Aft Automotive Gmbh | Mehrschichtverbund sowie Fluidleitung |
| US11772369B2 (en) * | 2017-12-22 | 2023-10-03 | Ems-Patent Ag | Fuel line, method for producing same, and uses thereof |
| DE102018213140A1 (de) * | 2018-08-06 | 2020-02-06 | Aft Automotive Gmbh | Mehrschichtverbund sowie Fluidleitung |
| DE102018251759B4 (de) | 2018-12-28 | 2022-06-09 | Aft Automotive Gmbh | Mehrschichtverbund sowie Fluidleitung |
| WO2020223508A1 (en) * | 2019-04-30 | 2020-11-05 | Saint-Gobain Performance Plastics Corporation | Dissipative peristaltic pump tubing |
| WO2021079244A1 (en) | 2019-10-24 | 2021-04-29 | Invista North America S.A.R.L. | Polyamide compositions and articles made therefrom |
| US20220379578A1 (en) | 2021-05-28 | 2022-12-01 | AGC Inc. | Fuel filler pipe |
Family Cites Families (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4137431A1 (de) | 1991-11-14 | 1993-05-19 | Huels Chemische Werke Ag | Mehrschichtiges kunststoffrohr |
| DE69311403T2 (de) * | 1992-03-05 | 1997-12-04 | Nitta Moore Co Ltd | Brennstoffübertragendes Rohr |
| US5865218A (en) | 1992-04-14 | 1999-02-02 | Itt Corporation | Multi-layer fuel and vapor tube |
| DE4215608A1 (de) | 1992-05-12 | 1993-11-18 | Huels Chemische Werke Ag | Mehrschichtiges Kunststoffrohr |
| DE4310884A1 (de) | 1993-04-02 | 1994-10-06 | Huels Chemische Werke Ag | Mehrschichtiges Kunststoffrohr |
| DE4336290A1 (de) | 1993-10-25 | 1995-04-27 | Huels Chemische Werke Ag | Mehrschichtiges Kunststoffrohr |
| DE4410148A1 (de) | 1994-03-24 | 1995-09-28 | Huels Chemische Werke Ag | Mehrschichtiges Kunststoffrohr |
| DE19507026A1 (de) | 1995-03-01 | 1996-09-05 | Huels Chemische Werke Ag | Thermoplastische Mehrschichtverbunde |
| DE19507025A1 (de) * | 1995-03-01 | 1996-09-05 | Huels Chemische Werke Ag | Mehrschichtrohr mit elektrisch leitfähiger Innenschicht |
| DE19519481A1 (de) | 1995-05-27 | 1996-11-28 | Huels Chemische Werke Ag | Mehrschichtiger Kunststoff-Kraftstoffilter mit antistatischen Eigenschaften |
| CN1077029C (zh) | 1995-10-06 | 2002-01-02 | 克里奥瓦克公司 | 后封缝的筒状包装膜及其包装的制品 |
| JPH1024505A (ja) * | 1996-07-09 | 1998-01-27 | Kuraray Co Ltd | 燃料容器および燃料パイプ |
| DE19641751B4 (de) | 1996-10-10 | 2009-07-09 | Evonik Degussa Gmbh | Zweikomponenten-Anbindungselement |
| DE19641946A1 (de) | 1996-10-11 | 1998-04-16 | Huels Chemische Werke Ag | Mehrschichtiges Kunststoffrohr mit segmentierter Sperrschicht |
| FR2757444B1 (fr) * | 1996-12-20 | 1999-02-05 | Nyltech Italia | Structure multicouche a base de plastique et tube a structure multicouche |
| DE19720317A1 (de) | 1997-05-15 | 1998-11-19 | Huels Chemische Werke Ag | Haftvermittler für einen Mehrschichtverbund |
| DE19838709A1 (de) | 1998-08-26 | 2000-03-02 | Degussa | Mehrschichtverbund mit Barrierewirkung |
| DE19908640A1 (de) | 1999-02-27 | 2000-08-31 | Degussa | Mehrschichtverbund |
| ATE272497T1 (de) | 1999-06-29 | 2004-08-15 | Degussa | Mehrschichtverbund |
| ES2204396T3 (es) | 1999-06-29 | 2004-05-01 | Degussa Ag | Copolimeros de injerto de poliamida altamente ramificados. |
| ATE250640T1 (de) | 1999-06-29 | 2003-10-15 | Degussa | Polyamid-pfropfcopolymere |
| DE10002461A1 (de) | 2000-01-21 | 2001-07-26 | Degussa | Mehrschichtiges Kunststoffrohr mit guter Schichtenhaftung |
| DE10002948A1 (de) | 2000-01-25 | 2001-07-26 | Degussa | Leichtfließende transparente Polyamid-Formmasse |
| DE10025707A1 (de) | 2000-05-26 | 2001-11-29 | Degussa | Mehrschichtiges, verstärktes Kunststoffanbindungselement mit antistatischen Eigenschaften |
| DE10030716A1 (de) | 2000-06-23 | 2002-01-03 | Degussa | Tieftemperaturschlagzähe Polymerlegierung |
| DE10064333A1 (de) * | 2000-12-21 | 2002-06-27 | Degussa | Mehrschichtverbund mit einer EVOH-Schicht |
| DE10064338A1 (de) | 2000-12-21 | 2002-06-27 | Degussa | Formmasse mit guter Blasformbarkeit |
| DE10064335A1 (de) | 2000-12-21 | 2002-07-04 | Degussa | Leichtfließende Polyester-Formmasse |
| DE10064334A1 (de) | 2000-12-21 | 2002-06-27 | Degussa | Polyamid-Mehrschichtverbund |
| DE10064336A1 (de) | 2000-12-21 | 2002-06-27 | Degussa | Polyesterformmasse |
| DE10065177A1 (de) * | 2000-12-23 | 2002-06-27 | Degussa | Mehrschichtverbund auf Polyamid/Polyolefin-Basis |
| DE10150258A1 (de) | 2001-10-11 | 2003-04-17 | Degussa | Leitungssystem für Fluide und Gase in einer Brennstoffzelle |
| DE10164408A1 (de) | 2001-12-28 | 2003-07-17 | Degussa | Flüssigkeits- oder dampfführendes System mit einer Fügezone aus einem coextrudierten Mehrschichtverbund |
| DE10200804A1 (de) | 2002-01-11 | 2003-07-24 | Degussa | Leichtfliessende Polyester-Formmasse |
| DE10228439A1 (de) | 2002-06-26 | 2004-01-22 | Degussa Ag | Kunststoff-Lichtwellenleiter |
| CN1681878A (zh) | 2002-07-05 | 2005-10-12 | 德古萨公司 | 由聚合物和离子性液体形成的聚合物组合物 |
| DE10245355A1 (de) | 2002-09-27 | 2004-04-08 | Degussa Ag | Rohrverbindung |
| FR2845453B1 (fr) * | 2002-10-07 | 2004-11-26 | Nobel Plastiques | Conduite pour le transport de fluides contenant de l'hydrogene |
| DE10316996A1 (de) | 2003-04-11 | 2004-10-28 | Degussa Ag | Leitungssystem für Fluide und Gase in einer Brennstoffzelle |
| DE10318321A1 (de) | 2003-04-19 | 2004-10-28 | Degussa Ag | Verfahren zum Ultraschallschweißen von Kunstoffkomponenten |
| DE102004048777A1 (de) | 2004-10-07 | 2006-04-13 | Degussa Ag | Mehrschichtverbund mit Polyesterschicht und Schutzschicht |
| DE102004049652A1 (de) | 2004-10-11 | 2006-04-20 | Degussa Ag | Leitungssystem für Fluide und Gase in einer Brennstoffzelle |
| DE102004049653A1 (de) | 2004-10-11 | 2006-04-20 | Degussa Ag | Leitungssystem für Fluide und Gase in einer Brennstoffzelle |
| DE102005026264A1 (de) | 2005-06-08 | 2006-12-14 | Degussa Ag | Transparente Formmasse |
| DE102007038578A1 (de) | 2007-08-16 | 2009-02-19 | Evonik Degussa Gmbh | Verfahren zur Dekorierung von Oberflächen |
-
2004
- 2004-10-07 DE DE200410048776 patent/DE102004048776A1/de not_active Withdrawn
-
2005
- 2005-08-10 WO PCT/EP2005/053946 patent/WO2006040206A1/de active Application Filing
- 2005-08-10 KR KR1020077007938A patent/KR100879698B1/ko active IP Right Grant
- 2005-08-10 BR BRPI0517546A patent/BRPI0517546B1/pt not_active IP Right Cessation
- 2005-08-10 US US10/588,487 patent/US8133561B2/en active Active
- 2005-08-10 EP EP20050776170 patent/EP1799452B1/de active Active
- 2005-08-10 CN CNB2005800012099A patent/CN100450772C/zh active Active
- 2005-08-10 RU RU2007116698A patent/RU2387545C2/ru active
- 2005-08-10 JP JP2007535125A patent/JP4938671B2/ja active Active
- 2005-10-07 AR ARP050104227 patent/AR051134A1/es unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101966772A (zh) * | 2010-09-01 | 2011-02-09 | 丹东鑫马高科技塑料包装有限公司 | 高阻隔性塑料软包装膜 |
| CN101966772B (zh) * | 2010-09-01 | 2013-05-22 | 丹东鑫马高科技塑料包装有限公司 | 高阻隔性塑料软包装膜 |
| CN107428139A (zh) * | 2016-01-15 | 2017-12-01 | 阿科玛法国公司 | 对于生物汽油中的提取具有改善的抗性的多层管状结构体和其用途 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102004048776A1 (de) | 2006-04-13 |
| EP1799452A1 (de) | 2007-06-27 |
| JP4938671B2 (ja) | 2012-05-23 |
| RU2387545C2 (ru) | 2010-04-27 |
| EP1799452B1 (de) | 2013-10-02 |
| KR100879698B1 (ko) | 2009-01-21 |
| US8133561B2 (en) | 2012-03-13 |
| AR051134A1 (es) | 2006-12-20 |
| BRPI0517546A (pt) | 2008-10-14 |
| BRPI0517546B1 (pt) | 2015-11-17 |
| RU2007116698A (ru) | 2008-11-20 |
| JP2008515658A (ja) | 2008-05-15 |
| WO2006040206A1 (de) | 2006-04-20 |
| CN100450772C (zh) | 2009-01-14 |
| US20080317986A1 (en) | 2008-12-25 |
| KR20070094724A (ko) | 2007-09-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100450772C (zh) | 具有乙烯-乙烯醇共聚物层和保护层的多层复合材料 | |
| US8221890B2 (en) | Multilayer composite having a polyester layer and a protective layer | |
| CN1187185C (zh) | 具有两层或更多层的聚酰胺复合材料 | |
| CN1149146C (zh) | 多层复合材料 | |
| US8048504B2 (en) | Composite having two or more layers, including an EVOH layer | |
| US6794048B2 (en) | Multilayer composite based on polyamide/polyolefin | |
| CN1200974C (zh) | 低温冲击强度优良的聚合物共混物 | |
| JP2004143467A (ja) | 成形材料、多層複合材料およびその使用 | |
| CN1277336A (zh) | 用于输送汽油的以聚酰胺为基础的多层管道 | |
| CN105985635B (zh) | 包含部分芳族聚酰胺层的多层复合件 | |
| CN1255275C (zh) | 基于聚酰胺和共聚酰胺混合粘合剂的多层结构 | |
| CN1845821A (zh) | 包含改性冲击evoh层的多层结构 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: EVONIK DEGUSSA CO., LTD. Free format text: FORMER NAME: DEGUSSA CO., LTD. |
|
| CP01 | Change in the name or title of a patent holder |
Address after: Dusseldorf Patentee after: Degussa GmbH Address before: Dusseldorf Patentee before: Degussa AG |
|
| CP03 | Change of name, title or address |
Address after: essen Patentee after: Evonik Degussa GmbH Address before: Dusseldorf Patentee before: Degussa GmbH |
|
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Essen, Germany Patentee after: Evonik Operations Ltd. Address before: Essen, Germany Patentee before: EVONIK DEGUSSA GmbH |