CN1872766A - Cement concrete of resin - Google Patents

Cement concrete of resin Download PDF

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Publication number
CN1872766A
CN1872766A CNA2006100449054A CN200610044905A CN1872766A CN 1872766 A CN1872766 A CN 1872766A CN A2006100449054 A CNA2006100449054 A CN A2006100449054A CN 200610044905 A CN200610044905 A CN 200610044905A CN 1872766 A CN1872766 A CN 1872766A
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China
Prior art keywords
resin concrete
particle
granularity
accounts
resin
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CNA2006100449054A
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CN1872766B (en
Inventor
韩付勇
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New Mstar Technology Ltd, Jiangsu
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HAN KUYONG
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

This invention discloses a resin concrete, which is composed of: aggregate 71-86 wt.%, filler 3-12 wt.%, reinforcing material 3-8 wt.%, and binding material 7-11 wt.%. the resin concrete is manufactured by: (1) mixing epoxy resin, curing agent and fly ashes, and uniformly stirring; (2) adding stone and glass fiber, and stirring; (3) mounting the mold onto a vibration desk; (4) injecting the mixture into the mold with vibrating; (5) standing for 7 d, and demolding. The resin concrete has such advantages as high impact strength, high cracking resistance and reasonable aggregate particle sizes.

Description

Resin concrete
Technical field
The present invention relates to the new concrete technical field, specifically a kind of resin concrete that is used for the manufacturing machine plant bottom case.
Background technology
At present, at lathe, the equipment of industrial widespread use, its support is mostly made by cast iron, cast steel.There is following shortcoming in it: one, manufacturing process complexity, manufacturing cost are higher; Two, erosion resistance is relatively poor, especially for chemical industry equipment, then needs often it to be carried out rotproofing, and its maintenance cost is higher; Three, shock-absorbing wave energy power is relatively poor; Because of lathe, equipment produce certain vibrations in the running, this vibrations can't absorb for the support of cast iron, cast steel manufacturing, and it not only directly has influence on the working accuracy of lathe, but also can have influence on operation stability of equipment and working life.
For solving this type of problem, people manage to adopt non-metallic material to substitute cast iron, cast steel is made support.Chinese patent 200510043683.X discloses a kind of " granolith, marble mechanical fitting and preparation method thereof ", it adopts aggregate, sizing material and promotor mixing manufacture, the problem of its existence is: one, do not throw in this compound as the glass fibre or carbon fiber or steel fiber or the polymer fiber that strengthen material, make to can not get improving that it directly has influence on the comprehensive strength and the work-ing life of lathe, equipment support as its toughness behind the epoxy resin cure of sizing material and anti-fissibility.Two, in the research data of relevant special concrete, the adding packing material has all been mentioned in design about proportioning, the add-on of stopping composition is generally all about 10%, and in the grating smallest particles the stone flour add-on should near or greater than the add-on of intermediate particle, only in this way the space of macrobead stone could be tamped the concrete density height of promptly producing, comprehensive strength height.And the 200510043683.X patent application adopts the stone flour of 0.01-0.5mm as filler, and its add-on is less than the add-on of intermediate particle, and the proportioning concrete density of making is relatively poor thus, intensity is not high.Three, promotor be meant in the epoxy resin cure process, add improve the solidified chemical substance, it should not be talcum powder, natural marble powder, the natural granite powder that contains certain sizing material amount, simultaneously, it does not have the promotor effect yet.
Summary of the invention
The purpose of this invention is to provide a kind of resin concrete, what it can solve that prior art exists makes easily that because of not strengthening material its toughness and anti-fissibility can not get improving behind the epoxy resin cure, and the coarseness of grading of aggregate is unreasonable, and it can directly have influence on the problem of concrete comprehensive strength.
Purpose of the present invention is achieved through the following technical solutions: resin concrete, and it comprises following raw materials by weight percent:
71-86% stopping composition 3-12% gathers materials
Strengthen material 3-8% agglutinate 7-11%.
For further realizing purpose of the present invention, also can finish by the following technical programs:
Described resin concrete, it comprises following raw materials by weight percent:
78-82% stopping composition 5-8% gathers materials
Strengthen material 5-8% agglutinate 8-9.5%.
Described resin concrete, it comprises following raw materials by weight percent:
80-81.5% stopping composition 5-7% gathers materials
Strengthen material 5-6% agglutinate 8-9%.
Described resin concrete, it comprises following raw materials by weight percent:
81.5% stopping composition 5.5% gathers materials
Strengthen material 5% agglutinate 8%.
Described grating of gathering materials is different, and wherein: granularity is the 42-47% that the particle of 14-20mm accounts for the resin concrete sum; Granularity is the 14-19% that the particle of 3.5-5mm accounts for the resin concrete sum; Granularity accounts for the 15-20% of resin concrete sum for the<particle of 1mm.Described grating of gathering materials is different, wherein: granularity is the 44-48.5% that the particle of 7-10mm accounts for the resin concrete sum, granularity is the 14-19% that the particle of 1-2mm accounts for the resin concrete sum, and granularity accounts for the 13-18.5% of resin concrete sum for the<particle of 1mm.Described grating of gathering materials is different, wherein: granularity is the 42-47% that the particle of 10-14mm accounts for the resin concrete sum, granularity is the 14-19% that the particle of 2-3.5mm accounts for the resin concrete sum, and granularity accounts for the 15-20% of resin concrete sum for the<particle of 1mm.Described gathering materials is the crushed granite of ultimate compression strength>240Mpa.Described stopping composition be flyash, silica powder or pozzuolanic any.Described enhancing material is any of glass fibre, carbon fiber, steel fiber or polymer fiber.
The beneficial effect that the present invention can produce: because of respectively will be as the stone that gathers materials, flyash or silica powder or volcanic ash as stopping composition, as the glass fibre that strengthens material or carbon fiber or steel fiber or polymer fiber and as the Resins, epoxy and the solidifying agent of agglutinate, after stirring, form resin concrete by scientific matching, because as the stone that gathers materials is the grouan that adopts ultimate compression strength>240Mpa, the maximum particle diameter of stone is between 7-20mm, and by scientific and reasonable grating formation, it mixes through Resins, epoxy and solidifying agent with the stopping composition of 200 order left and right sides particle diameters and the enhancing material that is fibers form, it solidifies the formed lathe in back, in the plant bottom case, each stone that varies in size all becomes the unit combination that is cross-linked with each other one by one with epoxy resin cured product, when focus acts on the base, its each unit combination all can play buffering and absorb the effect of seismic wave, with this with lathe, the seismic wave rapid absorption that produces during equipment work is fallen, so guaranteed the working accuracy and the operation stability of equipment of lathe; Because stopping composition is about 200 orders, and the add-on of stopping composition is generally all about 10%, and in the grating the most fine grain add-on near or greater than the add-on of intermediate particle, therefore fine particle mixes and can tamp stone space each other in the stopping composition of capacity and the grating, makes lathe, plant bottom case firmer; Be fibers form owing to strengthen material, it can make toughness and anti-fissibility behind the epoxy resin cure improve, and the comprehensive strength of lathe, equipment support and work-ing life are improved greatly; Because the present invention is by lathe, the plant bottom case of the pourable one-tenth all size of different moulds model, it not only can save a large amount of iron and steel, aluminum metal, and makes manufacturing process quite simple, so greatly reduce manufacturing cost.The present invention is particularly suitable for making the base of high-accuracy lathe, equipment, instrument.Tangible society, economic benefit that widespread use of the present invention can produce.
The lathe, the plant bottom case that adopt the present invention to make, its various physical indexs are respectively after testing: ultimate compression strength 100-160Mpa, tensile strength 12-18Mpa, bending strength 19-35Mpa, Young's modulus 15-40 * 10 4Kg.cm -3, water-intake rate 0.1-1%, density 2.62 * 10 3Kg/m 3, thermal expansivity 13-126 * 10-6k -1, thermal conductivity 0.24wcm/1 ℃, Poisson's ratio 0.26, specific heat 0.26cal/g ℃.
Adopt lathe, the plant bottom case of manufacturing of the present invention to compare with traditional cast steel, cast iron base, institute has following remarkable advantage: one, erosion resistance is strong, special resistance to chemical attack; Two, there are internal stress in foundry goods or steel part, easily produce distortion, influence quality product, and then there are not the internal stress problem substantially in the lathe of manufacturing of the present invention, plant bottom case, so base is not yielding; Three, foundry goods or steel part are easy to generate resonance, thereby influence the processing quality of lathe, and the vibration resistance of subduing of the lathe of manufacturing of the present invention, plant bottom case is cast iron and cast steel 15 times, be 50 times of cast aluminium, its this performance is more suitable for being applied on high-accuracy lathe, high-accuracy mechanical component, opticinstrument, the precision measurement instrument; Four, the process-cycle of foundry goods or steel part long, and the lathe that the present invention makes, plant bottom case only need several days to tens days, it has shortened the process-cycle greatly; Five, foundry goods or the steel part shape of easy-formation complexity not, this is by its character decision, and the present invention then can process the shape of any complexity, is not subjected to any design limit; In case six, foundry goods or steel part produce waste product then can't repair, and the present invention has reparation, it can adopt repeatedly casting to repair, so the waste product situation generally can not occur; Seven, foundry goods or steel part smelt and casting process in, easily environment is polluted, and the present invention does not pollute the environment, but also barren rock of industrial generation, flyash etc. can be used, played the effect that waste material economizes on resources of reclaiming.Therefore, the present invention is a kind of novel environment-friendly materials.
Embodiment
Raw material of the present invention can have following multiple embodiments:
1, stone 71% flyash 10% glass fibre, 8% Resins, epoxy and solidifying agent 11%.
2, stone 86% silica powder 4% carbon fiber, 3% Resins, epoxy and solidifying agent 7%.
3, stone 78.5% volcanic ash 8.5% steel fiber, 4% Resins, epoxy and solidifying agent 9%.
4, stone 78% flyash 7% polymer fiber, 7% Resins, epoxy and solidifying agent 8%.
5, stone 82% volcanic ash 5% glass fibre, 5% Resins, epoxy and solidifying agent 8%.
6, stone 80% silica powder 6% glass fibre, 6% Resins, epoxy and solidifying agent 8%.
7, stone 80% volcanic ash 5% polymer fiber, 5% Resins, epoxy and solidifying agent 10%.
8, stone 81.5% flyash 5% steel fiber, 5.5% Resins, epoxy and solidifying agent 8%.
9, stone 80.75% silica powder 7.25% glass fibre, 5% Resins, epoxy and solidifying agent 7%.
10, stone 81.5% flyash 5.5% glass fibre, 5% Resins, epoxy and solidifying agent 8%.
Stone described in the raw material of the present invention also can be made of particles of different sizes, wherein:
11, granularity is that the particle of 14-20mm accounts for 42% of resin concrete sum, granularity be the particle of 3.5-5mm account for the resin concrete sum 14%, granularity accounts for 15% of resin concrete sum for the particle of<1mm; Add flyash 10% again, glass fibre 8%, Resins, epoxy and solidifying agent 11% gets final product.
12, granularity is that the particle of 14-20mm accounts for 47% of resin concrete sum, granularity be the particle of 3.5-5mm account for the resin concrete sum 19%, granularity accounts for 20% of resin concrete sum for the particle of<1mm; Add silica powder 4% again, carbon fiber 3%, Resins, epoxy and solidifying agent 7% gets final product.
13, granularity is that the particle of 14-20mm accounts for 44.5% of resin concrete sum, granularity be the particle of 3.5-5mm account for the resin concrete sum 16.5%, granularity accounts for 17.5% of resin concrete sum for the particle of<1mm; Add volcanic ash 8.5% again, steel fiber 4%, Resins, epoxy and solidifying agent 9% gets final product.
14, granularity is that the particle of 7-10mm accounts for 44% of resin concrete sum, granularity be the particle of 1-2mm account for the resin concrete sum 14%, granularity accounts for 13% of resin concrete sum for the particle of<1mm; Add flyash 10% again, glass fibre 8%, Resins, epoxy and solidifying agent 11% gets final product.
15, granularity is that the particle of 7-10mm accounts for 48.5% of resin concrete sum, granularity be the particle of 1-2mm account for the resin concrete sum 19%, granularity accounts for 18.5% of resin concrete sum for the particle of<1mm; Add silica powder 4% again, carbon fiber 3%, Resins, epoxy and solidifying agent 7% gets final product.
16, granularity is that the particle of 7-10mm accounts for 46% of resin concrete sum, granularity be the particle of 1-2mm account for the resin concrete sum 16.5%, granularity accounts for 16% of resin concrete sum for the particle of<1mm; Add volcanic ash 8.5% again, steel fiber 4%, Resins, epoxy and solidifying agent 9% gets final product.
17, granularity is that the particle of 10-14mm accounts for 42% of resin concrete sum, granularity be the particle of 2-3.5mm account for the resin concrete sum 14%, granularity accounts for 15% of resin concrete sum for the particle of<1mm; Add flyash 10% again, glass fibre 8%, Resins, epoxy and solidifying agent 11% gets final product.
18, granularity is that the particle of 10-14mm accounts for 47% of resin concrete sum, granularity be the particle of 2-3.5mm account for the resin concrete sum 19%, granularity accounts for 20% of resin concrete sum for the particle of<1mm; Add silica powder 4% again, carbon fiber 3%, Resins, epoxy and solidifying agent 7% gets final product.
19, granularity is that the particle of 10-14mm accounts for 44.5% of resin concrete sum, granularity be the particle of 2-3.5mm account for the resin concrete sum 16.5%, granularity accounts for 17.5% of resin concrete sum for the particle of<1mm; Add volcanic ash 8.5% again, steel fiber 4%, Resins, epoxy and solidifying agent 9% gets final product.
Raw material in the foregoing description is earlier stirred Resins, epoxy and solidifying agent and flyash, and then drop into the stone of above-mentioned grating and glass fibre according to the above ratio and continue to stir and be the present invention.At this moment, the lathe base mould is installed on the shaking table, opens the shaking table vibration when the present invention is poured into a mould in its mould, after the pourer finishes, treat that the demoulding gets final product after 7 days.
Raw material in the middle of above-mentioned all embodiment all is weight percentage.

Claims (10)

1, resin concrete is characterized in that it comprises following raw materials by weight percent:
71-86% stopping composition 3-12% gathers materials
Strengthen material 3-8% agglutinate 7-11%.
2, resin concrete according to claim 1 is characterized in that it comprises following raw materials by weight percent:
78-82% stopping composition 5-8% gathers materials
Strengthen material 5-8% agglutinate 8-9.5%.
3, resin concrete according to claim 1 is characterized in that it comprises following raw materials by weight percent:
80-81.5% stopping composition 5-7% gathers materials
Strengthen material 5-6% agglutinate 8-9%.
4, resin concrete according to claim 1 is characterized in that it comprises following raw materials by weight percent:
81.5% stopping composition 5.5% gathers materials
Strengthen material 5% agglutinate 8%.
5, according to claim 1,2,3 or 4 described resin concretes, it is characterized in that described grating of gathering materials is different, wherein: granularity is the 42-47% that the particle of 14-20mm accounts for the resin concrete sum; Granularity is the 14-19% that the particle of 3.5-5mm accounts for the resin concrete sum; Granularity accounts for the 15-20% of resin concrete sum for the<particle of 1mm.
6, according to claim 1,2,3 or 4 described resin concretes, it is characterized in that described grating of gathering materials is different, wherein: granularity is the 44-48.5% that the particle of 7-10mm accounts for the resin concrete sum, granularity is the 14-19% that the particle of 1-2mm accounts for the resin concrete sum, and granularity accounts for the 13-18.5% of resin concrete sum for the<particle of 1mm.
7, according to claim 1,2,3 or 4 described resin concretes, it is characterized in that described grating of gathering materials is different, wherein: granularity is the 42-47% that the particle of 10-14mm accounts for the resin concrete sum, granularity is the 14-19% that the particle of 2-3.5mm accounts for the resin concrete sum, and granularity accounts for the 15-20% of resin concrete sum for the<particle of 1mm.
8, resin concrete according to claim 5 is characterized in that described gathering materials is the crushed granite of ultimate compression strength>240Mpa.
9, resin concrete according to claim 6, it is characterized in that described stopping composition be flyash, silica powder or pozzuolanic any.
10, resin concrete according to claim 7, any that it is characterized in that described enhancing material is glass fibre, carbon fiber, steel fiber or polymer fiber.
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CN101531808B (en) * 2009-04-17 2011-05-04 山东大学 Glass fiber and carbon fiber mixed reinforced polyester mineral composite material and preparation method thereof
CN101381213B (en) * 2008-09-16 2011-06-29 张万勇 Resin concrete machine tool basic fittings and preparation method thereof
CN102192486A (en) * 2010-03-10 2011-09-21 曾建祥 Lamp post made of composite material
CN102357834A (en) * 2011-10-14 2012-02-22 周卫 Filling accessory for machine tool and manufacturing process thereof
CN102503254A (en) * 2011-10-14 2012-06-20 周卫 Accessory for concrete machine tool and preparation method thereof
CN102826791A (en) * 2012-09-12 2012-12-19 建研建材有限公司 Ultra-wearproof epoxy precast slab and installation method thereof
CN103145388A (en) * 2013-04-03 2013-06-12 潘锋 Iron tailing doped high-performance concrete and manufacturing method thereof
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CN105060782A (en) * 2015-07-29 2015-11-18 苏州科淼新材料有限公司 Enhanced polymer concrete and non-impregnation preparation method
CN105753367A (en) * 2016-01-25 2016-07-13 重庆鹏方路面工程技术研究院有限公司 Resin concrete for quick maintenance of bridge expansion joints
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CN101531808B (en) * 2009-04-17 2011-05-04 山东大学 Glass fiber and carbon fiber mixed reinforced polyester mineral composite material and preparation method thereof
CN102192486A (en) * 2010-03-10 2011-09-21 曾建祥 Lamp post made of composite material
CN102357834B (en) * 2011-10-14 2014-03-26 周卫 Filling accessory for machine tool and manufacturing process thereof
CN102357834A (en) * 2011-10-14 2012-02-22 周卫 Filling accessory for machine tool and manufacturing process thereof
CN102503254A (en) * 2011-10-14 2012-06-20 周卫 Accessory for concrete machine tool and preparation method thereof
CN102826791A (en) * 2012-09-12 2012-12-19 建研建材有限公司 Ultra-wearproof epoxy precast slab and installation method thereof
CN103145388A (en) * 2013-04-03 2013-06-12 潘锋 Iron tailing doped high-performance concrete and manufacturing method thereof
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CN105753367A (en) * 2016-01-25 2016-07-13 重庆鹏方路面工程技术研究院有限公司 Resin concrete for quick maintenance of bridge expansion joints
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