CN1075114A - Production method of artificial inorganic marble and product - Google Patents
Production method of artificial inorganic marble and product Download PDFInfo
- Publication number
- CN1075114A CN1075114A CN 92109964 CN92109964A CN1075114A CN 1075114 A CN1075114 A CN 1075114A CN 92109964 CN92109964 CN 92109964 CN 92109964 A CN92109964 A CN 92109964A CN 1075114 A CN1075114 A CN 1075114A
- Authority
- CN
- China
- Prior art keywords
- lining
- product
- marble
- base
- production method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
- C04B2111/545—Artificial marble
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Finishing Walls (AREA)
Abstract
A kind of production method of artificial inorganic marble and product are made up of magnesium oxide, magnesium chloride, quartz sand, silica powder, stone, hydrochloric acid, Precondensed UreaFormaldehyde Resin, tertiary sodium phosphate, defoamer, Sodium hexametaphosphate 99, sodium silicate waterproofer etc.Making processes mainly was divided into for two steps, and the one, make lining, secondly be on lining, to drop into the base-material for preparing, then through processes such as vibrations, form the artificial marble finished product at last.Advantage such as the present invention has the intensity height, deliquescence, indeformable, acid and alkali-resistance, wear-resisting, anti-aging and surface luster be not good can be widely used in the surface decoration of various buildingss.
Description
The present invention relates to a kind of production method of artificial inorganic marble and product, this product can be widely used in the surface decoration of various buildingss.
At present, it is jointing compound that the making of artificial marble is adopted mostly with the cement of high index, is main auxiliary material with terrazzo, adds preparation by a certain percentage such as titanium dioxide, silicon carbide, glycerol, water, mineral dye, is cast in the mould to form through vibration, maintenance.Also have formulated in proportion with magnesium chloride, magnesium oxide, stone flour, colorant etc.Is that jointing compound, terrazzo are that the marble that main auxiliary material is made exists weight big with cement, cracky, mattness, shortcoming such as easily aging.The marble made from magnesium chloride, magnesium oxide, stone flour exist easy-weathering, deliquescence, immalleable, the surface is white because of the basicity height easily emits, aging decolouring, yielding, return shortcoming such as halogen.
Purpose of the present invention is exactly that a kind of production method of artificial inorganic marble and product are provided in order to overcome the deficiencies in the prior art.
Purpose of the present invention can realize by following measure:
The marmorean prescription of this artificial inorganic comprises magnesium oxide, magnesium chloride, quartz sand, silica powder, stone, hydrochloric acid, Precondensed UreaFormaldehyde Resin, tertiary sodium phosphate, defoamer, Sodium hexametaphosphate 99, sodium silicate waterproofer, whiteruss, natural inorganic mineral matter pigment.Its manufacture method was divided into for two steps, at first made the first layer (also claiming lining), secondly then made the second layer (also claiming base-material) on the first layer.
One. the making of lining
It is standby at first the magnesium chloride water to be reconciled into the liquid of Be24 °～28 ° of Baume concentration.Get 100 parts of magnesium oxide weight, getting magnesium chloride liquid, silica powder, hydrochloric acid, Precondensed UreaFormaldehyde Resin, tertiary sodium phosphate, Sodium hexametaphosphate 99 by proportioning stirred 15～20 minutes with magnesium oxide, add the tricresyl phosphate fourth then and decide fat stirring 5～10 minutes, make it evenly, this moment, the lining preparation was finished.It is standby to get an amount of natural inorganic mineral matter pigment preparation shades of colour (according to customer requirements) mill base.
Two. the making of base-material
Get 100 parts of magnesium oxide weight, getting magnesium chloride liquid, silica powder, hydrochloric acid, Precondensed UreaFormaldehyde Resin, tertiary sodium phosphate, Sodium hexametaphosphate 99 by proportioning stirred 15～20 minutes with magnesium oxide, adding tbp then stirred 5～10 minutes, make it even, and then add quartz sand, stone and stir standbyly, this moment, base-material was supporting finishes.
Getting shaper is put on the sheet glass, between mould and sheet glass, spread mylar, the lining for preparing is dropped in the mould, the mill base that input prepares on lining, then sheet glass is put on the shaking table together with mould, when spending 20～30 minutes lining solidifying slightly, add the base-material for preparing again, base-material drops into after vibration, lining produces natural marble figue, vibrates after 5～8 minutes, and die horizontal is placed 20～25 ℃ of room temperatures, place molding after 4～6 hours, promptly go out finished product, finished product is put into the storehouse of 20～25 ℃ of room temperatures, through typing maintenance naturally 20～25 days, with whiteruss lining is carried out surface finish again and handle, form the artificial marble finished product at last.
Purpose of the present invention can also realize by following measure:
Press the magnesium oxide weight ratio, get magnesium chloride liquid 75～90%, silica powder 5～15%, 450～550 milliliters of hydrochloric acid, Precondensed UreaFormaldehyde Resin 5～10%, tertiary sodium phosphate 2～4 ‰, Sodium hexametaphosphate 99 2～5 ‰, tbp 1.5～5 ‰, quartz sand 5～15%, stone 300～400%.
More than magnesium oxide 120 orders, content is more than 87%, and content of magnesium chloride is more than 45%, silica powder 240～270 orders, hydrochloric acid (industrial concentration 36～38%), quartz sand 40～80 orders, 4～6 millimeters of stone granularities.
1～1.5 millimeter of fabric thickness.
The finished product natural temperature is more than 0 ℃.
This product is three layers, and one deck is a lining, and another layer is a base-material, is color paste layer between lining and the base-material.
The present invention at first will solve oxygen and draw some subject matters that magnesium system tackiness agent exists, and as containing a large amount of sodium-chlor in the magnesium chloride, the sodium ion in the crystal space can be moved, make the product surface easy-weathering, deliquescence tarnishes, matrix generation efflorescence, physical strength significantly descends.In order to address this problem, the present invention adopts enriched bittern cake to extract pure magnesium chloride, has solved this problem.The present invention also utilizes technical hydrochloric acid with the magnesium chloride effect, makes goods not have sodium ion, and its quality and performance all are improved significantly.The major ingredient of tackiness agent is a basic magnesium chloride, also have unnecessary magnesium chloride to exist, under certain humidity, run into Atmospheric Carbon Dioxide gas, form the carbonic acid liquid film, this acid-base function causes the graphitic corrosion of product surface, make it to lose surface luster, and the tackiness agent skeleton is damaged, and reduced intensity, select several inorganic adhesives and additive for this reason, form the inorganic compounding tackiness agent, change crystal structural framework, strengthen the density and the hydrophobicity of material, corrode to resist sour gas such as carbonic acid gas.The present invention has intensity height, not deliquescence, indeformable, anti-aging, anticorrosive, acid and alkali-resistance, wear-resisting, advantage such as surface gloss is good.
Embodiment
Make lining
Magnesium chloride is transferred to Be24 °～30 ° with tap water, becomes liquid standby.Press the magnesium oxide weight ratio, get 50kg magnesium oxide, the 40kg magnesium chloride, 10% silica powder, 500 persons of outstanding talent rise hydrochloric acid, 5 ‰ Precondensed UreaFormaldehyde Resins, 2 ‰ tertiary sodium phosphates, 2 ‰ Sodium hexametaphosphate 99s stirred 15 minutes together, add 1.5 ‰ tbps then, stirred 5 minutes, reach evenly, lining completes.
Make base-material
Add 10% quartz sand on the basis of lining, 300% stone stirs, and base-material completes.
Make pigment
According to user's needs, with an amount of natural inorganic mineral matter pigment preparation.
Moulding
At sheet glass upper berth mylar, put mould then, the lining for preparing is dropped in the mould, on lining, drop into prepared dye, after about 20～30 minutes, treat to drop into again when lining solidifies slightly base-material, after vibrating 5 minutes on the shaking table, level is put into room temperature then.20 ℃～25 ℃ place reaches 4～6 hours, gets final product molding, goes out finished product, and then the storehouse that is put into 20 ℃～25 ℃ of the room temperatures maintenance 20～25 days of finalizing the design naturally, forms the artificial inorganic marble at last.
Claims (6)
1, a kind of production method of artificial inorganic marble and product is characterized in that; The prescription of this artificial marble comprises magnesium oxide, magnesium chloride, quartz sand, silica powder, stone, hydrochloric acid, Precondensed UreaFormaldehyde Resin, tertiary sodium phosphate, defoamer, Sodium hexametaphosphate 99, sodium silicate waterproofer, whiteruss, natural inorganic mineral matter pigment, its manufacture method was divided into for two steps, at first make the first layer (also claiming lining), secondly on the first layer, then make the second layer (also claiming base-material)
The making of lining
It is standby at first the magnesium chloride water to be reconciled into the liquid of Be24 °～30 ° of Baume concentration, get 100 parts of magnesium oxide weight, getting magnesium chloride liquid, silica powder, hydrochloric acid, Precondensed UreaFormaldehyde Resin, tertiary sodium phosphate, six meta-acid sodium by proportioning stirred 15～20 minutes with magnesium oxide, adding tbp then stirred 5～10 minutes, make it even, this moment, the lining preparation was finished, and it is standby to get an amount of natural inorganic mineral matter pigment preparation shades of colour (according to customer requirements) mill base
The making of base-material
Get 100 parts of magnesium oxide weight, getting magnesium chloride liquid, silica powder, hydrochloric acid, Precondensed UreaFormaldehyde Resin, tertiary sodium phosphate, Sodium hexametaphosphate 99 by proportioning stirred 15～20 minutes with magnesium oxide, adding tbp then stirred 5～10 minutes, make it even, and then add quartz sand, stone stirs standby, this moment, the base-material preparation was finished
Getting shaper is put on the sheet glass, between mould and sheet glass, spread mylar, the lining for preparing is dropped in the mould, the mill base that input prepares on lining, then sheet glass is put on the shaking table together with mould, when spending 20～30 minutes lining solidifying slightly, add the base-material for preparing again, base-material drops into after vibration, lining produces natural marble figue, vibrates after 5～8 minutes, and die horizontal is placed 20 ℃～25 ℃ of room temperatures, place molding after 4～6 hours, promptly go out finished product, finished product is put into the storehouse of 20 ℃～25 ℃ of room temperatures, through typing maintenance naturally 20～25 days, with whiteruss lining is carried out surface finish again and handle, form the artificial marble finished product at last.
2, according to said production method of artificial inorganic marble of claim 1 and product, it is characterized in that: press the magnesium oxide weight ratio, get magnesium chloride liquid 75～90%, silica powder 5～15%, 450～550 milliliters of hydrochloric acid, Precondensed UreaFormaldehyde Resin 5～10 ‰, tertiary sodium phosphate 2～4 ‰, Sodium hexametaphosphate 99 2～5 ‰, tbp 1.5～5 ‰, quartz sand 5～15%, stone 300～400%.
3, according to said production method of artificial inorganic marble of claim 1 and product, it is characterized in that: more than magnesium oxide 120 orders, content is more than 87%, content of magnesium chloride is more than 45%, silica powder 240～270 orders, hydrochloric acid (industrial concentration 36～38%), quartz sand 40～80 orders, 4～6 millimeters of stone granularities.
4, according to said production method of artificial inorganic marble of claim 1 and product, it is characterized in that: 1～1.5 millimeter of fabric thickness.
5, according to said production method of artificial inorganic marble of claim 1 and product, it is characterized in that: finished product nature setting temperature is more than 0 ℃.
6, according to said production method of artificial inorganic marble of claim 1 and product, it is characterized in that: this product is three layers, and one deck is a lining, and another layer is a base-material, is color paste layer between lining and the base-material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92109964 CN1075114A (en) | 1992-09-29 | 1992-09-29 | Production method of artificial inorganic marble and product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92109964 CN1075114A (en) | 1992-09-29 | 1992-09-29 | Production method of artificial inorganic marble and product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1075114A true CN1075114A (en) | 1993-08-11 |
Family
ID=4944514
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92109964 Pending CN1075114A (en) | 1992-09-29 | 1992-09-29 | Production method of artificial inorganic marble and product |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1075114A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331648C (en) * | 2003-11-18 | 2007-08-15 | 董少勇 | Preparation method of imitation sandstone product |
| CN1872766B (en) * | 2006-06-16 | 2010-07-28 | 张万勇 | Cement concrete of resin |
| EP2474373A1 (en) | 2008-08-29 | 2012-07-11 | Basf Se | Method for stabilising a subterranean formation using curable urea-formaldehyde resins |
| CN103482953A (en) * | 2013-09-27 | 2014-01-01 | 佛山市东鹏陶瓷有限公司 | Artificial synthetic stone and manufacturing method thereof |
| CN104802281A (en) * | 2014-01-23 | 2015-07-29 | 吴文鸿 | Preparation method of textured artificial stone |
| CN108033741A (en) * | 2017-11-30 | 2018-05-15 | 武威霖沐科技发展有限公司 | A kind of preparation method of Scagliola |
-
1992
- 1992-09-29 CN CN 92109964 patent/CN1075114A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331648C (en) * | 2003-11-18 | 2007-08-15 | 董少勇 | Preparation method of imitation sandstone product |
| CN1872766B (en) * | 2006-06-16 | 2010-07-28 | 张万勇 | Cement concrete of resin |
| EP2474373A1 (en) | 2008-08-29 | 2012-07-11 | Basf Se | Method for stabilising a subterranean formation using curable urea-formaldehyde resins |
| US8273691B2 (en) | 2008-08-29 | 2012-09-25 | Basf Se | Method for binding non-solid oxidic inorganic materials with etherified aminoplast resins and cured compositions of said materials and etherified aminoplast resins |
| CN103482953A (en) * | 2013-09-27 | 2014-01-01 | 佛山市东鹏陶瓷有限公司 | Artificial synthetic stone and manufacturing method thereof |
| CN104802281A (en) * | 2014-01-23 | 2015-07-29 | 吴文鸿 | Preparation method of textured artificial stone |
| CN108033741A (en) * | 2017-11-30 | 2018-05-15 | 武威霖沐科技发展有限公司 | A kind of preparation method of Scagliola |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |