CN1871917A - Stability perchlorizing disinfection liquid, and preparation method - Google Patents
Stability perchlorizing disinfection liquid, and preparation method Download PDFInfo
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- CN1871917A CN1871917A CN 200510037372 CN200510037372A CN1871917A CN 1871917 A CN1871917 A CN 1871917A CN 200510037372 CN200510037372 CN 200510037372 CN 200510037372 A CN200510037372 A CN 200510037372A CN 1871917 A CN1871917 A CN 1871917A
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- acid
- perchlorizing
- disinfection liquid
- phosphoric acid
- diethylene triamine
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Abstract
A stable disinfecting peroxide solution for fast killing the bacteria, funguses, yeast and bacilli on the apparatus, tools, pipeline and package in food industry and decomposing their products into H2O and CO2 is prepared through mixing glacial acetic acid, propionic acid, salicylic acid, H2O2 and potassium hydrogen persulfate, catalytic reaction to generate the mixture of ethaneperoxoic acid, propaneperoxic acid and H2O2, adding stabilizer, and stirring.
Description
[affiliated technical field]
The present invention relates to a kind of food beverage industry equipment, instrument, pipeline, packing material thimerosal and preparation method thereof.
[background technology]
The bio-safety of food and drink is directly connected to people's life security, in the food and drink process of manufacture, all must carry out effectively disinfection of strictness to related equipment, instrument, pipeline, packing container etc.Food and drink production and processing field disinfectant commonly used has clorox, sodium dichloro cyanurate, chlorine dioxide, Peracetic acid, hydrogen peroxide etc., wherein clorox and sodium dichloro cyanurate are because cheap, be widely used in the past, but scientific research shows that chlorine-containing disinfectants such as clorox and sodium dichloro cyanurate can generate the halogenated hydrocarbons that carcinogenesis is arranged with the organic matter reaction in the water; Chlorine dioxide is the disinfectant of food processing industry high-efficiency broad spectrum commonly used, but owing to need activation when using, and have the smell of strong impulse chlorine to be subjected to certain restriction; As for independent hydrogen peroxide (hydrogen peroxide), its bactericidal effect is unsatisfactory.
The Peracetic acid of Xiao Shouing generally is a two-component packaging on the market, need shift to an earlier date mixing in 24 to 48 hours during use, and use is more serious to equipment corrosion; Also there is businessman that Peracetic acid is made the monobasic packing and sells, but the Peracetic acid instability of monobasic packing, the shelf-life is no more than one month.
[summary of the invention]
At the existing food and drink production and processing industry existing problem of thimerosal commonly used, the invention provides out a kind of efficient, wide spectrum, kill various microorganisms fast, and need not activate, can directly dilute use, shelf-life reached more than half a year, and catabolite is nontoxic, harmless, the stability perchlorizing disinfection liquid of noresidue and method for making.
The object of the present invention is achieved like this: glacial acetic acid, propionic acid, salicylic acid, hydrogen peroxide and potassium hydrogen peroxymonosulfate are mixed, in the presence of catalyst sulfuric acid and boric acid, it is the mixture that contains the peroxide of Peracetic acid, Perpropionic Acid, hydrogen peroxide that glacial acetic acid, propionic acid, salicylic acid and hydrogen peroxide, hydrogen peroxymonosulfate nak response generate finished product, the stabilizing agent that adds diethylene triamine pentamethylene phosphonic, ATMP or ethylenediamine tetramethylene phosphonic acid then mixes, and concrete preparation method is:
1, prepares raw material: 50kg～70kg glacial acetic acid, 30kg～50kg propionic acid, 50kg～70kg salicylic acid, 500kg～600kg hydrogen peroxide, 250kg～300kg potassium hydrogen peroxymonosulfate, 5kg～10kg sulfuric acid and 5kg～10kg boric acid in following ratio, above-mentioned material is joined in the enamel jacket reactor of band stirring, open and stir pump, stirred 30～60 minutes;
2, again with in 5kg～7kg diethylene triamine pentamethylene phosphonic or the amino trimethyl phosphoric acid of 3kg～5kg or the 3kg～5kg ethylenediamine tetramethylene phosphoric acid adding enamel jacket reactor, stirred 40～80 minutes, promptly make stability perchlorizing disinfection liquid;
3, open the PVC water-jet pump, the mixture pump in the enamel jacket reactor can be carried out can in the PVC storage tank;
When 4, using,, can be directly used in the quick sterilization of food beverage industry equipment, instrument, pipeline, packing material with 20～80 times of aforementioned stable perchlorizing disinfection liquid dilutions.
The invention provides a kind of novel, easy perchlorizing disinfection liquid and preparation method, the shelf-life of product was reached more than half a year, and need not activate before using, water directly dilutes the sterilization that can be used for food beverage industry equipment, instrument, pipeline, packing material more than 40 times, various microorganisms such as kill bacteria, mould, yeast, gemma fast, catabolite is water and carbonic acid gas, safe, nontoxic, noresidue.
[embodiment]
Embodiment 1:
(1) gets 60kg glacial acetic acid, 40kg propionic acid, 60kg salicylic acid, 550kg hydrogen peroxide, 280kg potassium hydrogen peroxymonosulfate, 60kg sulfuric acid and 60kg boric acid, above-mentioned material is joined in the enamel jacket reactor of band stirring, open and stir pump, stirred 40 minutes;
(2) again the 6kg diethylene triamine pentamethylene phosphonic is added in the enamel jacket reactor, stir and promptly make perchlorizing disinfection liquid after 60 minutes;
(3) open the PVC water-jet pump, the mixture pump in the enamel jacket reactor can be carried out can in the PVC storage tank;
When (4) using, the quick sterilization of food beverage industry equipment, instrument, pipeline, packing material will be can be used for promptly after 20 times of the perchlorizing disinfection liquid dilutions.
Embodiment 2:
(1) gets 50kg glacial acetic acid, 30kg propionic acid, 50kg salicylic acid, 500kg hydrogen peroxide, 250kg potassium hydrogen peroxymonosulfate, 5kg sulfuric acid and 5kg boric acid, join in the enamel jacket reactor of band stirring, open and stir pump, stirred 30 minutes;
(2) the more amino trimethyl phosphoric acid of 4kg is added in the enamel jacket reactor, stirred 40 minutes, promptly make perchlorizing disinfection liquid.
(3) open the PVC water-jet pump, the mixture pump in the enamel jacket reactor can be carried out can in the PVC storage tank.
When (4) using, the quick sterilization of food beverage industry equipment, instrument, pipeline, packing material will both have been can be used for after 40 times of the perchlorizing disinfection liquid dilutions.
Embodiment 3:
(1) 70kg glacial acetic acid, 50kg propionic acid, 70kg salicylic acid, 600kg hydrogen peroxide, 300kg potassium hydrogen peroxymonosulfate, 10kg sulfuric acid and 10kg boric acid are joined in the enamel jacket reactor of band stirring, open and stir pump, stirred 60 minutes.
(2) again 4kg ethylenediamine tetramethylene phosphoric acid is added in the enamel jacket reactor, stirred 80 minutes, promptly make perchlorizing disinfection liquid.
(3) open the PVC water-jet pump, the mixture pump in the enamel jacket reactor can be carried out can in the PVC storage tank.
When (4) using, the quick sterilization of food beverage industry equipment, instrument, pipeline, packing material will be can be used for promptly after 80 times of the perchlorizing disinfection liquid dilutions.
Claims (4)
1, a kind of stability perchlorizing disinfection liquid comprises peroxide that contains Peracetic acid, Perpropionic Acid, hydrogen peroxide and the stabilizing agent that contains diethylene triamine pentamethylene phosphonic, amino trimethyl phosphoric acid or ethylenediamine tetramethylene phosphoric acid.
2, the method for making of the described perchlorizing disinfection liquid of a kind of claim 1,50kg～70kg glacial acetic acid, 30kg～50kg propionic acid, 50kg～70kg salicylic acid, 500kg～600kg hydrogen peroxide, 250kg～300kg potassium hydrogen peroxymonosulfate, 5kg～10kg sulfuric acid and 5kg～10kg boric acid are joined in the enamel jacket reactor of band stirring, open and stir pump, stirred 30～60 minutes; And then add 5kg～7kg diethylene triamine pentamethylene phosphonic or the amino trimethyl phosphoric acid of 3kg～5kg or 3kg～stabilizing agents such as 5kg ethylenediamine tetramethylene phosphoric acid, stirred 40～80 minutes.
3, the method for making of the described perchlorizing disinfection liquid of claim 2, the stabilizing agent that uses is diethylene triamine pentamethylene phosphonic.
4, the described perchlorizing disinfection liquid of claim 1, dilute with water is 20～80 times before using, and can be used for the quick sterilization of food beverage industry equipment, instrument, pipeline, packing material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510037372 CN1871917A (en) | 2005-09-20 | 2005-09-20 | Stability perchlorizing disinfection liquid, and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510037372 CN1871917A (en) | 2005-09-20 | 2005-09-20 | Stability perchlorizing disinfection liquid, and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1871917A true CN1871917A (en) | 2006-12-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN 200510037372 Pending CN1871917A (en) | 2005-09-20 | 2005-09-20 | Stability perchlorizing disinfection liquid, and preparation method |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010184868A (en) * | 2009-02-10 | 2010-08-26 | Mitsubishi Gas Chemical Co Inc | Peracetic acid aqueous solution excellent in stability |
| CN101816310A (en) * | 2010-04-07 | 2010-09-01 | 刘思波 | Disinfectant for dialyser multiplexing machine |
| CN102037959A (en) * | 2010-12-29 | 2011-05-04 | 广东环凯微生物科技有限公司 | Method for preparing stable peracetic acid disinfectant |
| CN102090393A (en) * | 2010-12-29 | 2011-06-15 | 广东环凯微生物科技有限公司 | Stable peroxyacetic acid disinfectant |
| CN102511478A (en) * | 2011-11-01 | 2012-06-27 | 苏州晶瑞化学有限公司 | Stable peroxyacetic acid solution |
| CN102626104A (en) * | 2012-03-22 | 2012-08-08 | 广东环凯微生物科技有限公司 | Stabilized chlorine dioxide disinfection solution and its preparation method |
| CN103843817A (en) * | 2012-12-06 | 2014-06-11 | 夏美洲 | Hydrogen peroxide and peracetic acid mixed disinfectant and preparation method thereof |
| CN104996416A (en) * | 2015-07-31 | 2015-10-28 | 杭州精欣化工有限公司 | Stabilizer of hydrogen peroxide disinfectant in dairy beverage aseptic packaging device |
| CN107105641A (en) * | 2015-01-16 | 2017-08-29 | 三菱瓦斯化学株式会社 | Bactericide and use its method for disinfection |
| CN109805009A (en) * | 2019-01-24 | 2019-05-28 | 北京日光旭升精细化工技术研究所 | A kind of chlorine-containing disinfectant and preparation method thereof |
| CN114342929A (en) * | 2021-11-29 | 2022-04-15 | 鲍立锋 | Oxidant stabilizing solution and preparation method thereof |
-
2005
- 2005-09-20 CN CN 200510037372 patent/CN1871917A/en active Pending
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010184868A (en) * | 2009-02-10 | 2010-08-26 | Mitsubishi Gas Chemical Co Inc | Peracetic acid aqueous solution excellent in stability |
| CN101816310A (en) * | 2010-04-07 | 2010-09-01 | 刘思波 | Disinfectant for dialyser multiplexing machine |
| CN102037959A (en) * | 2010-12-29 | 2011-05-04 | 广东环凯微生物科技有限公司 | Method for preparing stable peracetic acid disinfectant |
| CN102090393A (en) * | 2010-12-29 | 2011-06-15 | 广东环凯微生物科技有限公司 | Stable peroxyacetic acid disinfectant |
| CN102090393B (en) * | 2010-12-29 | 2013-06-12 | 广东环凯微生物科技有限公司 | Stable peroxyacetic acid disinfectant |
| CN102037959B (en) * | 2010-12-29 | 2013-03-27 | 广东环凯微生物科技有限公司 | Method for preparing stable peracetic acid disinfectant |
| CN102511478B (en) * | 2011-11-01 | 2013-01-09 | 苏州晶瑞化学有限公司 | Stable peroxyacetic acid solution, preparation method thereof and stabilizer for preparation |
| CN102511478A (en) * | 2011-11-01 | 2012-06-27 | 苏州晶瑞化学有限公司 | Stable peroxyacetic acid solution |
| CN102626104A (en) * | 2012-03-22 | 2012-08-08 | 广东环凯微生物科技有限公司 | Stabilized chlorine dioxide disinfection solution and its preparation method |
| CN102626104B (en) * | 2012-03-22 | 2014-01-08 | 广东环凯微生物科技有限公司 | Stabilized chlorine dioxide disinfection solution and preparation method thereof |
| CN103843817A (en) * | 2012-12-06 | 2014-06-11 | 夏美洲 | Hydrogen peroxide and peracetic acid mixed disinfectant and preparation method thereof |
| CN107105641A (en) * | 2015-01-16 | 2017-08-29 | 三菱瓦斯化学株式会社 | Bactericide and use its method for disinfection |
| CN104996416A (en) * | 2015-07-31 | 2015-10-28 | 杭州精欣化工有限公司 | Stabilizer of hydrogen peroxide disinfectant in dairy beverage aseptic packaging device |
| CN109805009A (en) * | 2019-01-24 | 2019-05-28 | 北京日光旭升精细化工技术研究所 | A kind of chlorine-containing disinfectant and preparation method thereof |
| CN114342929A (en) * | 2021-11-29 | 2022-04-15 | 鲍立锋 | Oxidant stabilizing solution and preparation method thereof |
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