CN1870309A - Reflection white-light LED excited by fluorescent powder - Google Patents
Reflection white-light LED excited by fluorescent powder Download PDFInfo
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- CN1870309A CN1870309A CNA2005100720291A CN200510072029A CN1870309A CN 1870309 A CN1870309 A CN 1870309A CN A2005100720291 A CNA2005100720291 A CN A2005100720291A CN 200510072029 A CN200510072029 A CN 200510072029A CN 1870309 A CN1870309 A CN 1870309A
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Abstract
A white light LED of reflection type by applying fluorescent powder excitation is prepared as arranging reflector on outgoing light path of blue light or ultraviolet ray diode in proper angle, shooting out said outgoing light by light outgoing surface of LED after it is reflected by reflector, coating fluorescent powder on reflector or on light outgoing surface of diode to let fluorescent powder generate white light by exciting blue light or ultraviolet ray form diode on fluorescent powder.
Description
Technical field
The present invention relates to is about white light emitting diode, especially relates to a kind ofly separating phosphor powder and diode chip for backlight unit and carrying out the white light emitting diode that phosphor powder excites in the reflection mode.
Background technology
Common at present and ripe white light emitting diode technology, be that light-emitting diode chip for backlight unit by blue light excites coating above it or be filled in its peripheral gold-tinted phosphor powder, be excited back gold-tinted that produces and the blue light that is used to excite of phosphor powder is complementary and produce the white light of two wavelength.Utilize white light that this mode produces wayward because participate in the ratio of the blue light of color matching and gold-tinted usually, photochromic inhomogeneous, problem such as colour temperature is higher, color rendering is on the low side is arranged.
Other has a kind of similar techniques, be to adopt ultraviolet light-emitting diode chip for backlight unit, the ultraviolet ray excited coating that makes its generation above it or be filled in the phosphor powder of its peripheral red, green, blue three looks and is made into the white light of three-wavelength by three coloured light that phosphor powder excites the back to produce.Though ultraviolet ray itself does not participate in color matching, still have suitable difficulty owing to the ratio of phosphor powder of all kinds and with ultraviolet cooperation, so the white light that this mode produces still has problems such as the photochromic uniformity.
Except the problem of the uniformity, the heat that the technology of above-mentioned white light-emitting diodes also can be produced because of light-emitting diode chip for backlight unit itself, feasible coating above it or be filled in its peripheral phosphor powder deterioration, and then cause the performance of whole light-emitting diode, comprise colourity and brightness, and all can and then reduce the life-span of light-emitting diode.
In order to solve the problem of the white light uniformity, industry has had the scheme that proposes several solutions.For example, United States Patent (USP) the 5th, 962, No. 971 and 5,813, No. 753 all is the uniformity of improving the white light mixed light that is provided with that increases filter (filter) in the encapsulation of light-emitting diode.The TaiWan, China patent the 569th in addition, No. 479 is that blue light or ultraviolet light-emitting diodes chip are arranged in the fluorescent glue, be folded in again in the comprehensive reflector plate of mediumization (dielectric omni-directional reflector), make blue light or ultraviolet light through repeatedly and multidirectional reflection and excite phosphor powder as far as possible, and therefore make blue light or ultraviolet light depleted of energy to improve the conversion usefulness of white light.But the heat that all also unresolved because light-emitting diode of above-mentioned these technology itself is produced, and cause the problem of the phosphor powder deterioration of direct contact.The setting of this outer filter or reflecting piece also can increase the complexity of processing procedure and cause cost to improve and yield decline.
At the problem of phosphor powder deterioration, the novel patent of TaiWan, China proposes a kind of light fixture of white light emitting diode for M246528 number, by phosphor powder is separated the thermal degradation when that is subjected to of avoiding phosphor powder with light-emitting diode chip for backlight unit.But this technology is design gives the light fixture that contains a plurality of blue light-emitting diodes, rather than at individual other light-emitting diode.
Summary of the invention
Therefore, one of main purpose of the present invention, provide a kind of white light emitting diode, utilize the way of separating be excited thing (being phosphor powder) and light source (being blue light or ultraviolet light-emitting diodes chip), make the two not directly contact, avoid being subjected to thermal degradation when and the life-span of improving white light emitting diode of the present invention of phosphor powder.
Another main purpose of the present invention, provide a kind of white light emitting diode, utilize the simple reflection framework of a kind of processing procedure, utilize reflection way, make the blue light that light-emitting diode chip for backlight unit sent or the ultraviolet light of blue light or ultraviolet light can carry out exciting of once above phosphor powder, therefore improve the effect of blue light or ultraviolet light and phosphor powder, thereby effectively improve the problem of the white light uniformity, colour temperature and color rendering.
To achieve the above object, the present invention is on the path of the emergent light of blue light or ultraviolet-ray diode chip, the speculum at one suitable angle of inclination is set, and blue light that chip is penetrated or ultraviolet light reflection are penetrated from the light outgoing plane of light-emitting diode of the present invention.Speculum, the outgoing plane of light-emitting diode, or all be coated with the phosphor powder that mates with blue light or ultraviolet-ray diode chip on the two, so at first reached the requirement that separates phosphor powder and diode chip for backlight unit, if reflecting surface and outgoing plane all are coated with the words of phosphor powder in addition, can make blue light or ultraviolet light that chip sends at first excite the phosphor powder that is coated with on the speculum and produce white light, still unspent blue light of these white lights and energy or ultraviolet light pass through the reflection of speculum again, again with outgoing plane on the phosphor powder effect that is coated with, and reach photochromic evenly, unlikely higher and the effect that color rendering is good of colour temperature.
Description of drawings
Fig. 1 a, Fig. 1 b figure is respectively side-looking and the front elevational schematic that shows according to the white light emitting diode of the first embodiment of the present invention.
Fig. 1 c is the schematic side view that shows according to the white light emitting diode of the second embodiment of the present invention.
Fig. 1 d is the schematic side view that shows according to the white light emitting diode of the third embodiment of the present invention.
Fig. 2 is the schematic side view that shows according to the white light emitting diode of the fourth embodiment of the present invention.
Among the figure
0 diode chip for backlight unit, 20 circuit boards
21,22 negative electrodes, 30 epoxy resin outer covers
31 sloped top face, 32 outgoing planes
40 speculums, 50,55 phosphor powders
60 spectroscopes, 70 epoxy resin outer covers
71 end faces, 72 sides
73 outgoing planes, 81 speculums
82 speculums, 91 phosphor powders
92 phosphor powders
The φ angle of inclination
Embodiment
Below with reference to detailed description and claim scope, address other purpose of the present invention and advantage on the detailed description to accompanying drawing, embodiment.Need to prove that each accompanying drawing is to establish in order to explain orally essence of the present invention, should not be regarded as the definition of the scope of the invention.The definition of the relevant scope of the invention please refer to claim.
Fig. 1 a, Fig. 1 b are side-looking and the front elevational schematic that shows respectively according to the white light emitting diode of the first embodiment of the present invention.As shown in the figure, white light emitting diode proposed by the invention is blue light or the ultraviolet light-emitting diodes chip 10 with in the past, is arranged on the circuit board 20 with positive and negative electrode 21 and 22.When applying external voltage on positive and negative electrode 21 and 22 time, diode chip for backlight unit 10 can be driven and send blue light or ultraviolet light.
In transparent, the columniform bell cover that light-emitting diode in the past normally is coated on epoxy resin and is constituted, comprise chip 10 and circuit board 20 in it with protection.This bell cover also has the effect of convex lens optically focused simultaneously.Present embodiment is not the epoxy resin outer cover that adopts bell, but the similar column type outer cover 30 that obtains having a sloped top face 31 with an angle cutting circle cylinder that tilts.The included angle of one angle between 15 °~75 ° arranged between sloped top face 31 and the circuit board 20.According to test, the desirable angle of this included angle generally should be between 30 °~60 °.Please note that in Fig. 1 a the upper surface of the lower edge of sloped top face 31 and circuit board 20 is to be positioned at same position, but, a suitable distance can be arranged also between the upper surface of the lower edge of sloped top face 31 and circuit board 20 at other embodiment.
On the inner surface of sloped top face 31, the film forming method that the present embodiment utilization is electroplated or other is commonly used, for example sputter, chemical vapour deposition (CVD) etc., form the metallic film that one deck is constituted with one of gold (Au), aluminium (Al), nickel (Ni), titanium (Ti) and chromium materials such as (Cr), with as a speculum 40.In other embodiments, speculum 40 also can be to adopt the Bragg reflector (Braggreflector) that dielectric material constituted.Metallic film speculum or Bragg mirror all are technology that the general technology personage is understood in the technology of the present invention field.
It needs to be noted that here present embodiment is to utilize the sloped top face 31 of epoxy resin outer cover 30 that the position of implementing speculum 40 is provided.The benefit of doing like this is simple in structure.Therefore but in other embodiments, speculum 40 also can be to be arranged in addition in the epoxy resin outer cover 30, and it is cylindrical that the shape of epoxy resin outer cover 30 is not limited to also that end face splays.
Being coated with the light that is sent with chip 10 on the speculum 40 is complementary to produce the phosphor powder 50 of white light.Such as what adopt as fruit chip 10 is the light-emitting diode of blue light-emitting, and phosphor powder 50 can be the yellow phosphor powder of yttrium-aluminium-garnet; What adopt as fruit chip 10 is the light-emitting diode of sending out ultraviolet light, and phosphor powder 50 can be the red bluish-green three look phosphor powders that the barium aluminum oxide adds europium ion.Mode as for coating can adopt any suitable method of knowing, for example spin coating, sputter, printing etc.
After electrode 21 and 22 applied appropriate voltage, diode chip for backlight unit 10 can send blue light or ultraviolet light orientating reflex mirror 40 advances.The incident angle and the angle φ sum that note that blue light or ultraviolet light orientating reflex mirror 40 are 90 °.In other words, the setting of speculum 40 makes the incident angle of blue light or ultraviolet light between 15 °~75 °, and desirable angle generally should be between 30 °~60 °.These blue lights or ultraviolet light at first can excite speculum 40 lip-deep phosphor powders 50, and via producing white light behind the mixed light.Mirror 40 reflection that then can be reflected together of these white lights that generate is advanced towards outgoing plane 32.
In the present embodiment, cylindrical because epoxy resin outer cover 30 has, so outgoing plane 32 is a protruding face, have the spotlight effect of convex lens.In other embodiments, epoxy resin outer cover 30 tools have plenty of the cylindricality that cross section is a semicircle, and its outgoing plane 32 is a plane.Being the present invention does not have specific requirement to the geometry of outgoing plane 32.
Present embodiment adopts a kind of simple reflection framework that phosphor powder is separated setting with diode chip for backlight unit, has therefore avoided phosphor powder to be subjected to thermal degradation when and to reduce the problem in the life-span of diode.Based on same notion, another embodiment of the present invention is shown in Fig. 1 c.The framework of present embodiment and working method and aforementioned first embodiment are identical, and unique difference is that phosphor powder system coats within the outgoing plane 32 on the surface, and on the non-reflective mirror 40.The same with speculum 40 with first embodiment is coated with the light that is sent with chip 10 and is complementary to produce the phosphor powder 55 of white light on the surface within the outgoing plane 32.In the present embodiment, the blue light that sends of diode chip for backlight unit 10 or ultraviolet light advance towards outgoing plane 32 after speculum 40 reflections.These blue lights or ultraviolet light can excite the phosphor powder 55 on outgoing plane 32 inner surfaces, and are penetrated by outgoing plane 32 via producing white light behind the mixed light.
Though aforementioned first and second embodiment effectively realizes the setting that separates of phosphor powder and diode chip for backlight unit, the white light that is generated may also comprise blue light or the ultraviolet light that energy does not exhaust fully.Therefore, in order further to improve the photochromic uniformity, first and second embodiment can be in conjunction with the 3rd embodiment that is embodied as shown in Fig. 1 d, and promptly speculum 40 is coated with phosphor powder 50 and 55 respectively with the inner surface of outgoing plane 32.The phosphor powder 55 of outgoing plane 32 can be the same with the phosphor powder 50 of speculum 40, also can be different materials.Its emphasis makes unspent blue light of energy or ultraviolet light after acting on phosphor powder 50, is able to act on phosphor powder 55 again, improves the uniformity and the higher problem of solution colour temperature of white light.In addition, no matter the shape of outgoing plane 32 why, importantly it is the configuration of vertical (or very near vertical) with light (white light and blue light, ultraviolet light) that speculum 40 is reflected, makes unspent blue light of energy or ultraviolet light be able to fully and phosphor powder 55 acts on.
In sum, present embodiment adopts a kind of simple reflection framework, makes blue light that diode chip for backlight unit sends or ultraviolet light that the chance with the phosphor powder effect be arranged twice, makes that the white light that produces is more even, and does not have the problem of colour temperature and color rendering.Can also draw the way that other adopts two or more speculum from the present embodiment extension, these speculums can be all or partly are coated with phosphor powder, and the phosphor powder that obtains more than the secondary by the repeatedly reflection that these speculums provide excites.
From the essence of previous embodiment, can obtain the fourth embodiment of the present invention as shown in Figure 2.In this embodiment, spectroscope 60 is that angle of inclination with the speculum 40 of similar last embodiment is arranged on the emergent light path of diode chip for backlight unit 10.Act on the blue light or the ultraviolet light that diode chip for backlight unit 10 is sent of spectroscope 60 partly penetrate, partly reflect.
In the present embodiment, epoxy resin outer cover 70 can be cylindrical or cube.Its end face 71 is provided with speculum 81 and 82 respectively with side 72.The execution mode of speculum 81,82 is the same with aforesaid speculum 40.In addition, speculum 81,82 also is coated with the coloured light that is sent with chip 10 and is complementary to produce the phosphor powder 91,92 of white light.The material of phosphor powder 91,92 can be identical with coating method, also can be different.
Partly penetrate the blue light of spectroscope 60 or the speculum 81 lip-deep phosphor powders 91 that ultraviolet light at first can excite end face 71, and via producing white light behind the mixed light.Then be reflected again mirror 81 of these white lights that generate advances towards outgoing plane 73 with spectroscope 60 reflections.Similarly, blue light that is reflected by spectroscope 60 or ultraviolet light speculum 82 lip-deep phosphor powders 92 that at first can excite side 72 partly, and via producing white light behind the mixed light.These white lights that generate then be reflected again mirror 82 reflection, penetrate spectroscope 60 backs and advance towards outgoing plane 73.
With aforementioned the 3rd embodiment relatively, the blue light of the 3rd embodiment or ultraviolet light are through the exciting of twice phosphor powder, and present embodiment be with blue light or ultraviolet light be divided into two partly make its each through once with the effect of phosphor powder.The both is with the lifting white light uniformity at the scope that increases blue light or ultraviolet light and phosphor powder effect and number of times.Present embodiment even also can also be coated with phosphor powder at outgoing plane 73 in conjunction with the method for last embodiment secondary excitation is so when producing better white light.
By the detailed description of above specific embodiment, more clearly described feature of the present invention and essence, but above-mentioned concrete form of implementation is not construed as limiting to scope of the present invention.And the scope of protection of present invention also is included in the interior various changes of claim scope and the replacement of equivalent feature.
Claims (18)
1. reflection white-light LED that adopts phosphor powder to excite, it comprises at least:
Circuit board, described circuit board has positive electrode, negative electrode and light-emitting diode chip for backlight unit, and when applying appropriate voltage between described positive and negative electrode, described light-emitting diode chip for backlight unit can be driven and send specific coloured light;
Speculum, described speculum is arranged on the outgoing path of the described specific coloured light that described light-emitting diode chip for backlight unit sends with suitable angle tilt, the light incidence surface of described speculum is coated with first phosphor powder with described specific coloured light coupling, described first phosphor powder through described special color optical excitation meeting with it mixed light produce white light; And
Outer cover, this outer cover is sealed in its inside with described circuit board and described speculum, penetrates to described white light emitting diode outside through the light of the described mirror reflects outgoing plane via described outer cover;
It is characterized in that: the described specific coloured light that described light-emitting diode chip for backlight unit sends, after described outgoing path arrives described speculum, described first phosphor powder of described light incidence surface that excites described speculum is to produce white light, and described white light penetrates through the described outgoing plane of described mirror reflects by described outer cover.
2. the reflection white-light LED that employing phosphor powder according to claim 1 excites is characterized in that: described light-emitting diode chip for backlight unit is blue LED chip or ultraviolet light-emitting diodes chip.
3. the reflection white-light LED that employing phosphor powder according to claim 1 excites is characterized in that: described suitable angle of inclination is to make the incident angle of described specific coloured light between 15 °~75 °.
4. the reflection white-light LED that employing phosphor powder according to claim 1 excites is characterized in that: described speculum is the Bragg reflector that is coated with the metallic mirror of suitable metal material or adopts suitable dielectric material.
5. the reflection white-light LED that employing phosphor powder according to claim 4 excites is characterized in that: described metal material is one of following material: gold (Au), aluminium (Al), nickel (Ni), titanium (Ti) and chromium (Cr).
6. the reflection white-light LED that employing phosphor powder according to claim 1 excites, it is characterized in that: the inner surface of described outgoing plane is coated with second phosphor powder with described specific coloured light coupling, described second phosphor powder through described special color optical excitation meeting with it mixed light produce white light.
7. reflection white-light LED that adopts phosphor powder to excite, it comprises at least:
Circuit board, described circuit board has positive electrode, negative electrode and light-emitting diode chip for backlight unit, and when applying appropriate voltage between described positive and negative electrode, described light-emitting diode chip for backlight unit can be driven and send specific coloured light;
Speculum, described reflective mirror are arranged on the outgoing path of the described specific coloured light that described light-emitting diode chip for backlight unit sends with suitable angle tilt; And
Outer cover, described outer cover is sealed in its inside with described circuit board and described speculum, penetrate to described white light emitting diode outside through the light of described mirror reflects outgoing plane via described outer cover, the inner surface of described outgoing plane is coated with first phosphor powder with described specific coloured light coupling, described first phosphor powder through described special color optical excitation meeting with it mixed light produce white light;
It is characterized in that: the described specific coloured light that described light-emitting diode chip for backlight unit sends, after described outgoing path arrives described speculum, by described mirror reflects to described outgoing plane, described first phosphor powder of described inner surface that excites described outgoing plane is to produce white light, and described white light is penetrated by the described outgoing plane of described outer cover.
8. the reflection white-light LED that employing phosphor powder according to claim 7 excites is characterized in that: described light-emitting diode chip for backlight unit is blue LED chip or ultraviolet light-emitting diodes chip.
9. the reflection white-light LED that employing phosphor powder according to claim 7 excites is characterized in that: described suitable angle of inclination is to make the incident angle of described specific coloured light between 15 °~75 °.
10. the reflection white-light LED that employing phosphor powder according to claim 7 excites is characterized in that: described speculum is the Bragg reflector that is coated with the metallic mirror of suitable metal material or adopts suitable dielectric material.
11. the reflection white-light LED that employing phosphor powder according to claim 10 excites is characterized in that: described metal material is one of following material: gold (Au), aluminium (Al), nickel (Ni), titanium (Ti) and chromium (Cr).
12. the reflection white-light LED that employing phosphor powder according to claim 7 excites, it is characterized in that: the light incidence surface of described speculum is coated with second phosphor powder with described specific coloured light coupling, described second phosphor powder through described special color optical excitation meeting with it mixed light produce white light.
13. a reflection white-light LED that adopts phosphor powder to excite, it comprises at least:
Circuit board, described circuit board has positive electrode, negative electrode and light-emitting diode chip for backlight unit, and when applying appropriate voltage between described positive and negative electrode, described light-emitting diode chip for backlight unit can be driven and send specific coloured light;
First speculum, the light incidence surface of described first speculum are coated with first phosphor powder with described specific coloured light coupling, described first phosphor powder through described special color optical excitation meeting with it mixed light produce white light;
Second speculum, the light incidence surface of described second speculum are coated with second phosphor powder with described specific coloured light coupling, described second phosphor powder through described special color optical excitation meeting with it mixed light produce white light;
Spectroscope, described reflective mirror is arranged at suitable angle tilt on the outgoing path of the described specific coloured light that described light-emitting diode chip for backlight unit sends, and described spectroscope causes that the described specific coloured light of injecting via described outgoing path partly penetrates described first speculum of directive, partly reflection is towards described second speculum; And
Outer cover, described outer cover is sealed in its inside with described circuit board and described speculum, penetrates to described white light emitting diode outside through the light of the described mirror reflects outgoing plane via described outer cover;
It is characterized in that: the described specific coloured light that arrives described first speculum, described first phosphor powder of described light incidence surface that excites described first speculum to be producing white light, and described white light is penetrated by described first speculum and the described spectroscope reflection back described outgoing plane by described outer cover; Arrive the described specific coloured light of described second speculum, described second phosphor powder of reflective surface of described light that excites described second speculum is to produce white light, and described white light is penetrated by the described outgoing plane of described outer cover by described second mirror reflects and after penetrating described spectroscope.
14. the reflection white-light LED that employing phosphor powder according to claim 13 excites is characterized in that: described light-emitting diode chip for backlight unit is blue LED chip or ultraviolet light-emitting diodes chip.
15. the reflection white-light LED that employing phosphor powder according to claim 13 excites is characterized in that: described first speculum is the Bragg reflector that is coated with the metallic mirror of suitable metal material or adopts suitable dielectric material.
16. the reflection white-light LED that employing phosphor powder according to claim 13 excites is characterized in that: described second speculum is the Bragg reflector that is coated with the metallic mirror of suitable metal material or adopts suitable dielectric material.
17. the reflection white-light LED that employing phosphor powder according to claim 16 excites is characterized in that: described metal material is one of following material: gold (Au), aluminium (Al), nickel (Ni), titanium (Ti) and chromium (Cr).
18. the reflection white-light LED that employing phosphor powder according to claim 13 excites, it is characterized in that: described outgoing plane is coated with the 3rd phosphor powder with described specific coloured light coupling, described the 3rd phosphor powder through described special color optical excitation meeting with it mixed light produce white light.
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