CN1861698A - Dispersion blue dye composition - Google Patents
Dispersion blue dye composition Download PDFInfo
- Publication number
- CN1861698A CN1861698A CN 200610051792 CN200610051792A CN1861698A CN 1861698 A CN1861698 A CN 1861698A CN 200610051792 CN200610051792 CN 200610051792 CN 200610051792 A CN200610051792 A CN 200610051792A CN 1861698 A CN1861698 A CN 1861698A
- Authority
- CN
- China
- Prior art keywords
- dyestuff
- grades
- dye composition
- formula
- disperse dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 26
- 239000001045 blue dye Substances 0.000 title description 4
- 239000006185 dispersion Substances 0.000 title description 2
- 239000000975 dye Substances 0.000 claims abstract description 107
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
- 239000000986 disperse dye Substances 0.000 claims description 21
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 18
- 239000012752 auxiliary agent Substances 0.000 claims description 17
- 239000002270 dispersing agent Substances 0.000 claims description 11
- 239000007859 condensation product Substances 0.000 claims description 7
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 claims description 4
- 229920001732 Lignosulfonate Polymers 0.000 claims description 4
- -1 alkyl naphthalene sulfonic acid formaldehyde Chemical compound 0.000 claims description 4
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 4
- 235000019357 lignosulphonate Nutrition 0.000 claims description 4
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 4
- 229920004934 Dacron® Polymers 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 239000005020 polyethylene terephthalate Substances 0.000 abstract 1
- 210000004243 sweat Anatomy 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- AIARLPIXVMHZLJ-UHFFFAOYSA-N 4,8-diamino-2-bromo-1,5-dihydroxyanthracene-9,10-dione Chemical compound O=C1C2=C(N)C=C(Br)C(O)=C2C(=O)C2=C1C(O)=CC=C2N AIARLPIXVMHZLJ-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920004935 Trevira® Polymers 0.000 description 2
- 239000001000 anthraquinone dye Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- DMLAVOWQYNRWNQ-UHFFFAOYSA-N azobenzene Chemical compound C1=CC=CC=C1N=NC1=CC=CC=C1 DMLAVOWQYNRWNQ-UHFFFAOYSA-N 0.000 description 1
- 150000004054 benzoquinones Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 102220187649 rs145044428 Human genes 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Abstract
A dispersed blue dyestuff compound is made up of the one or a few dyestuff A, one or few dyestuff B, one or a few dyestuff C and the assistant which the weight percent of the A is 30-90%, the B is 5-50%, the C is 1-40%. The Dacron fiber material dying by the dyestuff has the good pile-on properties, so the dying fabric has the good color, dispersibility and sun proof, wash resistance, sweat resistance.
Description
(1) technical field
The present invention relates to a kind of disperse dye composition, relate in particular to the disperse dye composition that a kind of dyeing polyester materials is used.
(2) background technology
C.I. Disperse Blue-56 is one of most important blue disperse dye admittedly in the world wide, and it can offer polyester and the extremely bright ruddiness blueness of polyester BLENDED FABRIC, and the sun-proof excellent property.But the anthraquinone dyes as representative is undesirable because of its tinctorial strength, and the dyeing cost improves when dying dark color thereby make, and polluting increases.In addition, aspect level-dyeing property, also be weak.Along with the fast development of the new fiber of polyester in recent years, the dyeing behavior that dispersed dye had is had higher requirement.Thereby people are in order to overcome the deficiency of C.I. Disperse Blue-56, attempt adding other class dispersed blue dye and piece together mixedly, improving dyeing behavioies such as lifting force, level-dyeing property, and reduce the dyeing cost.In Japanese Patent JP10-077425, JP11-158402, JP11-158403, disclose in succession and utilized azobenzene dyestuff and benzoquinones/anthraquinone dye compound, the composite dye that obtains all has raising in various degree at aspects such as lifting force, circulation ratio, level-dyeing properties, patent JP10-88049 also discloses the blue compound of multiple azoic dyestuff, but when above-mentioned composite dyestuff is applied to trevira dyeing, still can't satisfy the demands fully.
(3) summary of the invention
Problems such as the lifting force of existence, level-dyeing property deficiency when using for solving C.I. Disperse Blue-56 monochrome, the invention provides a kind of disperse dye composition, when dying Polyester Fibers, depth is good, and can obtain to have that coloured light is gorgeous, the dyeing and weaving thing of premium properties such as good dispersity, sun-proof, washable, perspiration resistance.
The technical solution adopted for the present invention to solve the technical problems is: a kind of disperse dye composition, basically by one or more suc as formula the dyestuff A shown in (I), one or more suc as formula the dyestuff B shown in (II), one or more form suc as formula dyestuff C and auxiliary agent shown in (III):
Wherein, R
1For-OH, R
2, R
3Independently separately be-OH or-NH
2, R wherein
2Be preferably-NH
2, R
3Be preferably-OH;
R
4For-H, halogen, replaced or unsubstituted phenyl by hydroxyl, be preferably Br or
R
5Be C
1~C
4Alkyl, be preferably-CH
3Or-C
2H
5
R
6, R
7Independent separately is H or C
1~C
4Alkyl, R
6, R
7Preferably be-C
2H
5
R
8, R
9Independent separately is C
1~C
4Alkyl, preferred, R
8, R
9Independently be-CH separately
3Or-C
2H
5
R
10, R
11Independent separately is C
1~C
4Alkyl, C
1~C
4Alkoxyalkyl, preferred R
10, R
11Independently be-C separately
2H
4OCH
3Or-C
2H
4OC
2H
5
X
1For halogen or-CN, be preferably Cl or Br or-CN;
X
2Be halogen, be preferably Cl or Br.
Disperse dye composition of the present invention, based on dyestuff A, dyestuff B and dyestuff C, the weight percentage of dyestuff A is 30~90%, is preferably 40~85%; The weight percentage of dyestuff B is 5~50%, is preferably 5~45%; The weight percentage of dyestuff C is 1~40%, is preferably 5~35%.
When preparing disperse dye composition of the present invention, employed dyestuff A, dyestuff B and dyestuff C can make easily by industry technique known such as patent JP32-9089B/JP60-8245A/EP324404.With dyestuff A, dyestuff B, when dyestuff C mixes assembly, generally need to add auxiliary agent and disperse.For example that structural formula (I), (II) and structural formula (III) is represented former dyestuff carries out corpusculed with pulverizers such as sand mill or shredders after mixing by above-mentioned proportioning in the presence of auxiliary agent, water or other wetting agent; Former dyestuff that also can structural formula (I), (II) and structural formula (III) is represented carries out mixing with above-mentioned ratio after corpusculed is handled with pulverizers such as sand mill or shredders respectively in the presence of auxiliary agent, water or other wetting agent in addition.Usually, auxiliary agent is 0.8~5: 1 with the ratio of former dyestuff weight.
Described disperse dye composition, form by dyestuff A, dyestuff B, dyestuff C and auxiliary agent, based on dyestuff A, dyestuff B and dyestuff C, the weight percentage of described dyestuff A is 40~85%, the weight percentage of described dyestuff B is 5~45%, the weight percentage of described dyestuff C is 5~35%, and described auxiliary agent is 0.8~5: 1 with the ratio of dyestuff A, dyestuff B, dyestuff C weight sum.Here reach foregoing based on dyestuff A, dyestuff B and dyestuff C, the implication of the weight percentage of described dyestuff A, B, C is meant: the weight percentage of dyestuff A or B or C is that total amount with respect to dyestuff A and dyestuff B and dyestuff C is 100%, and the amount of auxiliary agent is disregarded interior.
Described auxiliary agent is dispersed dye dispersion agent, diffusants commonly used when composite, as anionic dispersing agents such as naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic formaldehyde condensation compound, sulfonated lignin.Particularly, naphthalene sulfonic acidformaldehyde condensation product such as dispersing agent NNO, alkyl naphthalene sulfonic acid formaldehyde condensation products such as Dispersant MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde), benzyl naphthalene sulfonic formaldehyde condensation compound such as dispersing agent CNF, sulfonated lignin such as sodium lignosulfonate (as commercial dispersants Reax 83A, Reax 85A) etc.
Further, described dyestuff A is preferably from suc as formula in the compound shown in (Ia), (Ib) one or both:
Described dyestuff B is preferably from suc as formula in the compound shown in (IIa), (IIb), (IIc) one or more:
Described dyestuff C is preferably from suc as formula in the compound shown in (IIIa), (IIIb), (IIIc) one or more:
Disperse dye composition of the present invention particularly preferably is the combination of formula (Ia), formula (IIb), formula (IIIa).
Disperse dye composition of the present invention, the liquid state after can corpusculed, emulsifiable paste attitude or with spray-drying process etc. carry out dried powdery, graininess is supplied with dyeing.When dying Polyester Fibers with compound dispersed blue dye of the present invention, depth is good, and can obtain to have that coloured light is gorgeous, the dyeing and weaving thing of premium properties such as good dispersity, sun-proof, washable, perspiration resistance.
(4) embodiment
The invention will be further described below in conjunction with embodiment, but protection scope of the present invention is not limited to this.
Embodiment 1
Dyestuff A, dyestuff B, the dyestuff C of 24 gram formulas (IIIa) of 16 gram formulas (IIb), 195 sodium lignosulfonates that restrain with 60 gram formulas (Ia), after adding water and piece together mixing, grind with shredder and to disperse spraying drying, get product, this dyestuff can offer the bright-coloured blueness of fabric.
Embodiment 2~14
According to the preparation method of embodiment 1, the structure of the defined dyestuff A of each substituting group, dyestuff B, dyestuff C is as shown in table 1, and described composite dye is pieced together dyestuff A, dyestuff B, dyestuff C mixed by the continuous data shown in the table 2.
Table 1
C2 | Br | CH 3 | CH 3 | C 2H 4OC 2H 5 | C 2H 4OC 2H 5 |
C3 | Br | C 2H 5 | C 2H 5 | C 2H 4OCH 3 | C 2H 4OCH 3 |
C4 | Cl | CH 3 | C 3H 7 | C 2H 4OC 2H 5 | C 2H 4OC 2H 5 |
C5 | Cl | CH 3 | CH 3 | C 2H 4OCH 3 | C 2H 4OCH 3 |
C6 | Cl | C 2H 5 | CH 3 | C 2H 4OC 3H 7 | C 2H 4OC 3H 7 |
C7 | Br | C 3H 7 | CH 3 | C 2H 5 | C 2H 5 |
C8 | Cl | C 4H 9 | C 2H 5 | CH 3 | C 3H 7 |
C9 | Cl | C 3H 7 | C 3H 7 | C 2H 5 | C 3H 6OC 2H 5 |
C10 | Br | CH 3 | CH 3 | C 3H 7 | CH 2OC 3H 7 |
Table 2
The embodiment title | Each composition weight of dyestuff (gram) | Auxiliary agent (gram) | Pure water (gram) | |
Embodiment 2 | A1∶B1∶C1=26∶17∶7 | NNO | 120 | 220 |
Embodiment 3 | A2∶B2∶C3=40∶5∶5 | 120 | 220 | |
Embodiment 4 | A2∶B3∶C4=35∶10∶5 | 120 | 220 | |
Embodiment 5 | A3∶B1∶C2=30∶10∶10 | MF | 120 | 220 |
Embodiment 6 | A3∶B3∶C5=25∶10∶15 | 120 | 220 | |
Embodiment 7 | A4∶B4∶C5=20∶15∶15 | CNF | 120 | 220 |
Embodiment 8 | A5∶B1∶C6=28∶20∶2 | 120 | 220 | |
Embodiment 9 | A5∶B7∶C7=28∶18∶4 | Reax 85A | 120 | 220 |
Embodiment 10 | A5∶B5∶C8=15∶25∶10 | NNO | 40 | 200 |
Embodiment 11 | A4∶B6∶C9=40∶2.5∶7.5 | MF | 250 | 250 |
Embodiment 12 | A3∶B8∶C10=20∶10∶20 | CNF | 200 | 280 |
Embodiment 13 | A1∶A3∶B5∶C6=15∶15∶15∶5 | Reax 83A | 120 | 220 |
Embodiment 14 | A4∶B1∶B3∶C5=25∶6∶18∶1 | MF | 160 | 250 |
Embodiment 15
Respectively getting 0.5 dispersed dye that make of gram embodiment 1~14 is dispersed in 500 ml waters, mix with 60 milliliters water after drawing 20 milliliters, transferring dye bath PH with acetic acid is 5, be warming up to 70 ℃ put into simultaneously 2 the gram trevira dye, in 30 minutes, be warmed up to 130 ℃ by 70 ℃, be incubated 30 minutes, begin sampling when being cooled to 90 ℃.Observe sample cloth coloured light, adopt that GB GB/T3921-1997, GB/T3920-1997, GB/T3922-1997, GB/T8427-1998 test respectively that it is washable, rub resistance, perspiration resistance, sun-resistant fastness, the results are shown in Table 3.
Comparative Examples 1
Get 0.5 gram C.I. Disperse Blue-56 dyestuff and repeat embodiment 11.Test result sees Table 3.
Comparative Examples 2
Get 0.5 gram C.I. Red-1 200,83 dyestuffs and repeat embodiment 11.Test result sees Table 3.
Comparative Examples 3
Get 0.5 gram C.I. Disperse Red, 301 dyestuffs and repeat embodiment 11.Test result sees Table 3.
Table 3
The embodiment title | Fastness to washing (60 ℃) | Fastness to rubbing | Fastness to perspiration | Sun-resistant fastness | |||
Variable color | Nylon staining | Do | Wet | Acid | Alkali | ||
Embodiment 1 | 5 grades | 5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 7 grades |
Embodiment 2 | 5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 3 | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 4 | 5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 5 | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 6 | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 7 | 5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 8 | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 9 | 5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 10 | 5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 11 | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 12 | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 13 | 5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Embodiment 14 | 5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 4~5 grades | 6~7 grades |
Comparative Examples 1 | 4~5 grades | 3~4 grades | 4~5 grades | 4~5 grades | 4 grades | 4 grades | 6~7 grades |
Comparative Examples 2 | 4 grades | 3~4 grades | 4~5 grades | 3~4 grades | 4 grades | 4 grades | 5~6 grades |
Comparative Examples 3 | 4~5 grades | 4 grades | 4~5 grades | 4 grades | 4 grades | 4 grades | 5~6 grades |
Test result shows: the every fastness excellent property of dispersed blue dye mixture provided by the invention, composite effect is remarkable.
Claims (10)
1. disperse dye composition, basically by one or more suc as formula the dyestuff A shown in (I), one or more suc as formula the dyestuff B shown in (II), one or more form suc as formula dyestuff C and auxiliary agent shown in (III), based on dyestuff A, dyestuff B and dyestuff C, the weight percentage of described dyestuff A is 30~90%, the weight percentage of dyestuff B is 5~50%, and the weight percentage of dyestuff C is 1~40%:
Wherein, R
1For-OH, R
2, R
3Independently separately be-OH or-NH
2
R
4For-H, halogen, replaced or unsubstituted phenyl by hydroxyl;
R
5Be C
1~C
4Alkyl;
R
6, R
7Independent separately is H or C
1~C
4Alkyl;
R
8, R
9Independent separately is C
1~C
4Alkyl;
R
10, R
11Independent separately is C
1~C
4Alkyl or C
1~C
4Alkoxyalkyl;
X
1For halogen or-CN;
X
2Be halogen.
2. disperse dye composition as claimed in claim 1, it is characterized in that described composition is made up of dyestuff A, dyestuff B, dyestuff C and auxiliary agent, based on dyestuff A, dyestuff B and dyestuff C, the weight percentage of described dyestuff A is 40~85%, the weight percentage of described dyestuff B is 5~45%, the weight percentage of described dyestuff C is 5~35%, and described auxiliary agent is 0.8~5: 1 with the ratio of dyestuff A, dyestuff B, dyestuff C weight sum.
3. disperse dye composition as claimed in claim 2 is characterized in that described auxiliary agent is one of following: naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic formaldehyde condensation compound, sulfonated lignin.
4. disperse dye composition as claimed in claim 3 is characterized in that: described naphthalenesulfonateformaldehyde formaldehyde condensation is a dispersing agent NNO; Described alkyl naphthalene sulfonic acid formaldehyde condensation products is a Dispersant MF; Described benzyl naphthalene sulfonic formaldehyde condensation compound is a dispersing agent CNF; Described sulfonated lignin are sodium lignosulfonate.
6. as the described disperse dye composition of one of claim 1~4, it is characterized in that: described X
1For Cl or Br or-CN, R
5For-CH
3Or-C
2H
5, R
6, R
7Be-C
2H
5
7. as the described disperse dye composition of one of claim 1~4, it is characterized in that: described X
2Be Cl or Br, R
8, R
9Independently be-CH separately
3Or-C
2H
5, R
10, R
11Independently be-C separately
2H
4OCH
3Or-C
2H
4OC
2H
5
8. disperse dye composition as claimed in claim 7 is characterized in that: described dyestuff A is selected from suc as formula in the compound shown in (Ia), (Ib) one or both:
Described dyestuff B is selected from suc as formula in the compound shown in (IIa), (IIb), (IIc) one or more:
Described dyestuff C is selected from suc as formula in the compound shown in (IIIa), (IIIb), (IIIc) one or more:
9. the disperse dye composition shown in claim 8, it is characterized in that: described dyestuff A is that the compound shown in the formula (Ia), described dyestuff B are that the compound shown in the formula (IIb), described dyestuff C are the compound shown in the formula (IIIa).
10. the disperse dye composition shown in claim 8, it is characterized in that: described composition is by dyestuff A, dyestuff B, dyestuff C and auxiliary agent are formed, based on dyestuff A, dyestuff B and dyestuff C, the weight percentage of dyestuff A is 40~85%, the weight percentage of dyestuff B is 5~45%, the weight percentage of dyestuff C is 5~35%, described auxiliary agent and dyestuff A, dyestuff B, the ratio of the weight sum of dyestuff C is 0.8~5: 1, and described auxiliary agent is one of following or their arbitrary combination: dispersing agent NNO, Dispersant MF, dispersing agent CNF, sodium lignosulfonate.
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CNB2006100517920A CN100415835C (en) | 2006-06-02 | 2006-06-02 | Dispersion blue dye composition |
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---|---|---|---|
CNB2006100517920A CN100415835C (en) | 2006-06-02 | 2006-06-02 | Dispersion blue dye composition |
Publications (2)
Publication Number | Publication Date |
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CN1861698A true CN1861698A (en) | 2006-11-15 |
CN100415835C CN100415835C (en) | 2008-09-03 |
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CNB2006100517920A Expired - Fee Related CN100415835C (en) | 2006-06-02 | 2006-06-02 | Dispersion blue dye composition |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102127315A (en) * | 2010-12-24 | 2011-07-20 | 上海宜连化工科技有限公司 | Blue disperse dye composition with high light fastness and application thereof |
CN104804471A (en) * | 2015-03-19 | 2015-07-29 | 江苏亚邦染料股份有限公司 | Black disperse dye composition, black disperse dye and application of black disperse dye |
CN106046855A (en) * | 2016-06-16 | 2016-10-26 | 浙江山峪染料化工有限公司 | Disperse blue dye composition |
CN106084890A (en) * | 2016-06-20 | 2016-11-09 | 浙江工业大学上虞研究院有限公司 | A kind of azo dye composition and application thereof |
CN108264780A (en) * | 2017-12-31 | 2018-07-10 | 浙江龙盛化工研究有限公司 | A kind of disperse dye composition and dye preparations |
CN108264778A (en) * | 2017-12-31 | 2018-07-10 | 浙江龙盛化工研究有限公司 | A kind of disperse dye composition and dye preparations |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2901666A1 (en) * | 1979-01-17 | 1980-07-24 | Bayer Ag | COLORING PROCEDURE |
CN1312227C (en) * | 2004-12-16 | 2007-04-25 | 浙江龙盛集团股份有限公司 | Dispersed blue dye composition |
-
2006
- 2006-06-02 CN CNB2006100517920A patent/CN100415835C/en not_active Expired - Fee Related
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102127315A (en) * | 2010-12-24 | 2011-07-20 | 上海宜连化工科技有限公司 | Blue disperse dye composition with high light fastness and application thereof |
CN104804471A (en) * | 2015-03-19 | 2015-07-29 | 江苏亚邦染料股份有限公司 | Black disperse dye composition, black disperse dye and application of black disperse dye |
CN106046855A (en) * | 2016-06-16 | 2016-10-26 | 浙江山峪染料化工有限公司 | Disperse blue dye composition |
CN106084890A (en) * | 2016-06-20 | 2016-11-09 | 浙江工业大学上虞研究院有限公司 | A kind of azo dye composition and application thereof |
CN108264780A (en) * | 2017-12-31 | 2018-07-10 | 浙江龙盛化工研究有限公司 | A kind of disperse dye composition and dye preparations |
CN108264778A (en) * | 2017-12-31 | 2018-07-10 | 浙江龙盛化工研究有限公司 | A kind of disperse dye composition and dye preparations |
CN108264778B (en) * | 2017-12-31 | 2019-11-05 | 浙江龙盛化工研究有限公司 | A kind of disperse dye composition and dye preparations |
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