CN1857882A - Anticorrosion mildew inhibitor for bamboo and timber material - Google Patents
Anticorrosion mildew inhibitor for bamboo and timber material Download PDFInfo
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- CN1857882A CN1857882A CN 200610051884 CN200610051884A CN1857882A CN 1857882 A CN1857882 A CN 1857882A CN 200610051884 CN200610051884 CN 200610051884 CN 200610051884 A CN200610051884 A CN 200610051884A CN 1857882 A CN1857882 A CN 1857882A
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- Prior art keywords
- antisepticize
- bamboo
- matrix
- mildew preventive
- bamboo wood
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Links
- 235000017166 Bambusa arundinacea Nutrition 0.000 title claims abstract description 113
- 235000017491 Bambusa tulda Nutrition 0.000 title claims abstract description 113
- 241001330002 Bambuseae Species 0.000 title claims abstract description 113
- 235000015334 Phyllostachys viridis Nutrition 0.000 title claims abstract description 113
- 239000011425 bamboo Substances 0.000 title claims abstract description 113
- 239000000463 material Substances 0.000 title claims abstract description 51
- 239000003112 inhibitor Substances 0.000 title abstract description 5
- 235000021419 vinegar Nutrition 0.000 claims abstract description 53
- 239000000052 vinegar Substances 0.000 claims abstract description 53
- 239000007788 liquid Substances 0.000 claims abstract description 51
- 239000011159 matrix material Substances 0.000 claims abstract description 48
- 229910021538 borax Inorganic materials 0.000 claims abstract description 23
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004327 boric acid Substances 0.000 claims abstract description 23
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 23
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 23
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 22
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims abstract description 16
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 claims abstract description 15
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 235000013024 sodium fluoride Nutrition 0.000 claims abstract description 8
- 239000011775 sodium fluoride Substances 0.000 claims abstract description 8
- 230000003449 preventive effect Effects 0.000 claims description 74
- 239000002023 wood Substances 0.000 claims description 53
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 4
- 239000003610 charcoal Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 abstract description 5
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 abstract 1
- 229910000365 copper sulfate Inorganic materials 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 229910000563 Arsenical copper Inorganic materials 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 150000001879 copper Chemical class 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 231100000572 poisoning Toxicity 0.000 description 3
- 230000000607 poisoning effect Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 244000045947 parasite Species 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 235000014347 soups Nutrition 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- OUFJROAVKKYZEN-UHFFFAOYSA-N [Cr].[Cu].[As] Chemical compound [Cr].[Cu].[As] OUFJROAVKKYZEN-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- PWGQHOJABIQOOS-UHFFFAOYSA-N copper;dioxido(dioxo)chromium Chemical compound [Cu+2].[O-][Cr]([O-])(=O)=O PWGQHOJABIQOOS-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- BPQWCZKMOKHAJF-UHFFFAOYSA-N scheele's green Chemical compound [Cu+2].O[As]([O-])[O-] BPQWCZKMOKHAJF-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The present invention discloses a kind of anticorrosion mildew inhibitor for bamboo and timber material. The anticorrosion mildew inhibitor for bamboo and timber material has bamboo vinegar liquid as matrix and contains chlorthalonil, triazolone, boric acid, borax, copper sulfate, santobrite, sodium dichromate, sodium fluoride or their mixture. The anticorrosion mildew inhibitor has bamboo vinegar liquid, rather than water, as matrix, and possesses high anticorrosion and mildew inhibiting effect and less environmental pollution.
Description
(1) technical field
The present invention relates to a kind of antisepticize and mildew preventive of bamboo wood material, especially a kind of is the antisepticize and mildew preventive of bamboo wood material of synergist with bamboo vinegar liquid.
(2) background technology
Bamboo and timber material contains the needed nutrient of microorganism, and under suitable environment, microorganism is ruined the degraded bamboo and timber material easily, light downgrades, serious meeting loses use value, causes the wasting of resources, handles so general bamboo and timber material need carry out anticorrosion mildew-resistant between using.
The anticorrosion mildew-resistant of traditional bamboo and timber material is handled, and mainly is to handle with poisonous chemical agent, thus the mushroom and the insects of poisoning harm timber.Present domestic use is more, effect preferably Antisepticize and mildew preventive mainly be copper chromate (ACC), ammonical copper arsenite (ACA) and copper chromium arsenic (CCA) and penta sodium pentachlorophenate and pentachlorophenol.Chromium arsenical copper series is owing to use back heavy metal pollution and arsenic to ambient influnence; produce bioxin pollution etc. in pentachlorophenol or the penta sodium pentachlorophenate manufacture process; environment is had negative interaction, to the attention of environmental protection, more and more cause researcher's attention along with in the world.The Japan and the U.S. have forbidden the use of chromium arsenical copper series, and relevant policies are also prepared to put into effect by European countries.At present, also do not have relevant policies in China, the Antisepticize and mildew preventive of use is still based on this series, and large usage quantity, and it is imperative with the consumption that reduces chromium arsenical copper series to seek a kind of new environmental friendly, anti-corrosive mould inhibitor.
(3) summary of the invention
The present invention is for the antisepticize and mildew preventive of bamboo wood material that a kind of antiseptic property is good, toxicity is little, environmental pollution is few is provided.
For reaching goal of the invention the technical solution used in the present invention be:
A kind of antisepticize and mildew preventive of bamboo wood material, described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, contains one of following in every 1L matrix or two or more mixture wherein: 1. Bravo, 2. triazolone, 3. boric acid, 4. borax, 5. copper sulphate, 6. penta sodium pentachlorophenate, 7. sodium dichromate, 8. sodium fluoride.Described is matrix with bamboo vinegar liquid, be meant with bamboo vinegar liquid as solvent, the material that Bravo, triazolone, boric acid, borax etc. are had a bactericidal action dissolves in wherein makes Antisepticize and mildew preventive, and above-mentioned substance is material commonly used in the anticorrisive agent, and its content can be determined according to actual needs with combination.
Preferably, described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, adds 5～100g Bravo in every 1L matrix.Perhaps, described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, adds 5～100g triazolone in every 1L matrix.
Common, described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, contains in every 1L matrix: copper sulphate 5～100g, borax 30～100g, boric acid 10～100g.
Preferably, described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, only contains in every 1L matrix: copper sulphate 5～100g, borax 30～100g, boric acid 10～100g, penta sodium pentachlorophenate 20～200g.
Perhaps, described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, only contains in every 1L matrix: copper sulphate 5～100g, borax 30～100g, boric acid 10～100g, 5～100g Bravo.
Described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, only contains in every 1L matrix: copper sulphate 5～100g, borax 30～100g, boric acid 10～100g, 5～100g triazolone.
Described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, only contains in every 1L matrix: copper sulphate 5～100g, borax 30～100g, boric acid 10～100g, penta sodium pentachlorophenate 20～200g, sodium dichromate 50～200g, sodium fluoride 50～200g.
Described bamboo vinegar liquid is in the bamboo wood process of making charcoal, and collects the gas that bamboo wood produces in pyrolytic, and this gas is cooled off the liquid substance that obtains at normal temperatures.Bamboo vinegar liquid plays the effect of synergy as matrix in the anticorrisive agent of the present invention, because bamboo vinegar liquid composition dewaters exceptionally, mainly is more than 200 kind of materials such as organic acid, ketone, aldehydes, phenols.These materials itself just have expelling parasite sterilization antibacterial action, add the compound action of each complicated component, so expelling parasite of bamboo vinegar liquid and sterilization antibacterial action are obvious.In addition, bamboo vinegar liquid itself also is the good solvent of a kind ofization, and the solubilizer that letones that the inside comprises and being of alcohols material are good is again good bleeding agent.Active component can well be dissolved in the bamboo vinegar liquid and also effectively permeate, is diffused in the bamboo and timber material and goes in the Antisepticize and mildew preventive, thereby better brings into play drug effect, reduces dosing, has played the effect of good raising drug effect.This province of bamboo vinegar liquid is nontoxic, derives from bamboo wood, belongs to the recyclability resource.So with bamboo vinegar liquid as synergist, both can improve the drug effect of various Antisepticize and mildew preventives, can reduce its murder by poisoning again to environment, it is the synergist of a kind of environmental protection and effective Antisepticize and mildew preventive, with bamboo vinegar liquid is the Antisepticize and mildew preventive of matrix preparation, under the effect same effect, can reduce drug dose 15～45%.Bamboo vinegar liquid can use in the process that bamboo wood makes charcoal among the present invention, collect the gas that bamboo wood produces in pyrolytic, and this gas cooled off at normal temperatures the bamboo vinegar stoste that obtains, also can use bamboo vinegar stoste is concentrated the bamboo vinegar concentrate that obtains through the refining bamboo vinegar refined liquid that obtains or with bamboo vinegar liquid, with anticorrosion anti-mold effect is that refined liquid or concentrate are more effective, but taking cost into account, generally adopt bamboo vinegar stoste to get final product.
Preferably, described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, only contains in every 1L matrix: copper sulphate 10g, borax 70g, boric acid 30g, penta sodium pentachlorophenate 25g.
Antisepticize and mildew preventive of bamboo wood material of the present invention is mainly used in the anticorrosion mildew-resistant of wood materials, can be applicable to the anticorrosion mildew-resistant of bamboo material equally.
The beneficial effect of anticorrisive agent of the present invention is mainly reflected in: gained Antisepticize and mildew preventive good drug efficacy, little to the environment murder by poisoning is a kind of effective Antisepticize and mildew preventive of environmental protection.
(4) specific embodiment
The present invention is described further below in conjunction with specific embodiment, but protection scope of the present invention is not limited in this:
Used bamboo vinegar liquid is bamboo vinegar stoste in the embodiment of the invention, bamboo charcoal Co., Ltd in building from Zhejiang.
Embodiment 1:
Get 200mL bamboo vinegar liquid, add the 14g borax, 6g boric acid, 2g copper sulphate, the 5g penta sodium pentachlorophenate mixes, and gets Antisepticize and mildew preventive.
Embodiment 2:
Get 200mL bamboo vinegar liquid, add the 14g borax, 6g boric acid, 2g copper sulphate, the 5g penta sodium pentachlorophenate, the 10g sodium dichromate, the 10g sodium fluoride mixes, and gets Antisepticize and mildew preventive.
Embodiment 3:
Get 200mL bamboo vinegar liquid, add the 14g borax, 6g boric acid, 2g copper sulphate, the 5g penta sodium pentachlorophenate, the 10g sodium dichromate, the 10g sodium fluoride mixes, and gets Antisepticize and mildew preventive.
Embodiment 4:
Get 200mL bamboo vinegar liquid, add 20g copper sulphate, the 20g borax, 20g boric acid, the 10g penta sodium pentachlorophenate, the 40g sodium dichromate, the 40g sodium fluoride mixes, and gets Antisepticize and mildew preventive.
Embodiment 6 (Comparative Examples):
Get 200mL water, add the 14g borax, 6g boric acid, 2g copper sulphate, the 5g penta sodium pentachlorophenate mixes, and gets Antisepticize and mildew preventive.
Embodiment 7:
Get 200mL bamboo vinegar liquid, add the 15g Bravo, mix, get Antisepticize and mildew preventive.
Embodiment 8:
Get 200mL bamboo vinegar liquid, add the 15g triazolone, mix, get Antisepticize and mildew preventive.
Embodiment 9:
Get 200mL bamboo vinegar liquid, add 15g copper sulphate, the 10g borax, 10g boric acid, the 2g Bravo mixes, and gets Antisepticize and mildew preventive.
Embodiment 10:
Get 200mL bamboo vinegar liquid, add 15g copper sulphate, the 10g borax, 10g boric acid, the 2g triazolone mixes, and gets Antisepticize and mildew preventive.
Embodiment 11 (Comparative Examples):
Get the 200mL clear water, add the 15g Bravo, mix, get Antisepticize and mildew preventive.
Embodiment 12 (Comparative Examples):
Get the 200mL clear water, add the 15g triazolone, mix, get Antisepticize and mildew preventive.
Embodiment 13: the experiment of wood preservation anti-mold effect
Get medium density fibre board (MDF), evenly be coated with embodiment 1～6 gained Antisepticize and mildew preventive (be not coated with Antisepticize and mildew preventive and be coated with bamboo vinegar liquid in contrast), place under the open-air natural conditions, observe the time that fiberboard begins to go mouldy, result such as table 1 with blank:
Table 1: wood preservation mildew-resistant experimental data
| Group | Soup applied amount (g/cm 2) | The beginning mouldy time |
| Untreatment fiber plate (blank) | 0 | 4 days |
| Bamboo vinegar liquid is handled | 0.6 | 10 days |
| Embodiment 1 Antisepticize and mildew preventive is handled | 0.6 | 12 days |
| Embodiment 2 Antisepticize and mildew preventives are handled | 0.6 | 14 days |
| Embodiment 3 Antisepticize and mildew preventives are handled | 0.6 | 14 days |
| Embodiment 4 Antisepticize and mildew preventives are handled | 0.6 | 18 days |
| Embodiment 5 Antisepticize and mildew preventives are handled | 0.6 | 15 days |
| Embodiment 6 Antisepticize and mildew preventives are handled (Comparative Examples) | 0.6 | 7 days |
Use Antisepticize and mildew preventive of the present invention as can be seen by data in the table, sheet material mouldy time and bamboo vinegar liquid processing and be that mouldy time that matrix makes the sheet material of Antisepticize and mildew preventive processing all has postponement in various degree with water.
Embodiment 14: the anticorrosion anti-mold effect experiment of bamboo wood
Get fresh bamboo wood, soak embodiment 7～12 gained Antisepticize and mildew preventives (being untreated with blank is contrast), under 25 ℃ of indoor temperatures, humidity 95% condition, around the observation, write down the time that bamboo wood begins to go mouldy, the results are shown in Table 2:
Table 2: the anticorrosion mildew-resistant experimental data of bamboo wood
| Group | The soup soak time (hour) | The beginning mouldy time (my god) |
| Fresh bamboo wood (blank) is untreated | 0 | 4 |
| Embodiment 7 Antisepticize and mildew preventives are handled | 2 | Do not go mouldy all around |
| Embodiment 8 Antisepticize and mildew preventives are handled | 2 | 22 |
| Embodiment 9 Antisepticize and mildew preventives are handled | 2 | 12 |
| Embodiment 10 Antisepticize and mildew preventives are handled | 2 | 14 |
| Embodiment 11 Antisepticize and mildew preventives are handled (Comparative Examples) | 2 | 20 |
| Embodiment 12 Antisepticize and mildew preventives are handled (Comparative Examples) | 2 | 15 |
By data in the table as can be seen, use Antisepticize and mildew preventive of the present invention, be under the situation of 7.5g/100mL matrix at Bravo or triazolone content, the bamboo wood mouldy time is that matrix, Bravo or triazolone content are the bamboo wood mouldy time that the Antisepticize and mildew preventive of 7.5g/100mL matrix handles and have postponed more than the week than with water; At Bravo or triazolone content only is under the situation of 1g/100mL matrix, and the bamboo wood mouldy time is with water to be that matrix, Bravo or triazolone content are the bamboo wood mouldy time difference that the Antisepticize and mildew preventive of 7.5g/100mL matrix handles little.
Claims (10)
1. antisepticize and mildew preventive of bamboo wood material, it is characterized in that described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, contain one of following in every 1L matrix or two or more mixture wherein: 1. Bravo, 2. triazolone, 3. boric acid, 4. borax, 5. copper sulphate, 6. penta sodium pentachlorophenate, 7. sodium dichromate, 8. sodium fluoride.
2. antisepticize and mildew preventive of bamboo wood material as claimed in claim 1 is characterized in that described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, adds 5～100g Bravo in every 1L matrix.
3. antisepticize and mildew preventive of bamboo wood material as claimed in claim 1 is characterized in that described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, adds 5～100g triazolone in every 1L matrix.
4. antisepticize and mildew preventive of bamboo wood material as claimed in claim 1 is characterized in that described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, contains in every 1L matrix: copper sulphate 5～100g, borax 30～100g, boric acid 10～100g.
5. antisepticize and mildew preventive of bamboo wood material as claimed in claim 4, it is characterized in that described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, only contains in every 1L matrix: copper sulphate 5～100g, borax 30～100g, boric acid 10～100g, penta sodium pentachlorophenate 20～200g.
6. antisepticize and mildew preventive of bamboo wood material as claimed in claim 4, it is characterized in that described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, only contains in every 1L matrix: copper sulphate 5～100g, borax 30～100g, boric acid 10～100g, 5～100g Bravo.
7. antisepticize and mildew preventive of bamboo wood material as claimed in claim 4, it is characterized in that described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, only contains in every 1L matrix: copper sulphate 5～100g, borax 30～100g, boric acid 10～100g, 5～100g triazolone.
8. antisepticize and mildew preventive of bamboo wood material as claimed in claim 4, it is characterized in that described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, only contain in every 1L matrix: copper sulphate 5～100g, borax 30～100g, boric acid 10～100g, penta sodium pentachlorophenate 20～200g, sodium dichromate 50～200g, sodium fluoride 50～200g.
9. as the described antisepticize and mildew preventive of bamboo wood material of one of claim 1～8, it is characterized in that described bamboo vinegar liquid is in the bamboo wood process of making charcoal, and collects the gas that bamboo wood produces, and this gas is cooled off the liquid substance that obtains at normal temperatures in pyrolytic.
10. antisepticize and mildew preventive of bamboo wood material as claimed in claim 1 is characterized in that described antisepticize and mildew preventive of bamboo wood material is a matrix with bamboo vinegar liquid, only contains in every 1L matrix: copper sulphate 10g, borax 70g, boric acid 30g, penta sodium pentachlorophenate 25g.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100518849A CN100439057C (en) | 2006-06-09 | 2006-06-09 | Anticorrosion mildew inhibitor for bamboo and timber material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100518849A CN100439057C (en) | 2006-06-09 | 2006-06-09 | Anticorrosion mildew inhibitor for bamboo and timber material |
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| Publication Number | Publication Date |
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| CN1857882A true CN1857882A (en) | 2006-11-08 |
| CN100439057C CN100439057C (en) | 2008-12-03 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2006100518849A Expired - Fee Related CN100439057C (en) | 2006-06-09 | 2006-06-09 | Anticorrosion mildew inhibitor for bamboo and timber material |
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| WO2011060652A1 (en) * | 2009-11-23 | 2011-05-26 | 福建省世竹环保科技有限公司 | Bamboo fiber material |
| CN104015238A (en) * | 2014-06-23 | 2014-09-03 | 福建农林大学 | Mildew-proof retreatment method of mildewed bamboo chips |
| CN104802275A (en) * | 2015-03-30 | 2015-07-29 | 广西宾阳县荣良新材料科技有限公司 | Anti-corrosion particle board and producing method thereof |
| CN104824027A (en) * | 2015-05-12 | 2015-08-12 | 柳州市耕青科技有限公司 | Special rot-resistant medicament for succulent plants, namely century plants |
| CN104999537A (en) * | 2015-07-15 | 2015-10-28 | 中南林业科技大学 | Manufacturing method of advanced wooden biological compound material |
| CN105360163A (en) * | 2015-11-18 | 2016-03-02 | 广德县常丰竹木业制品有限公司 | Bamboo wood mould inhibitor and preparation method thereof |
| CN106113192A (en) * | 2016-07-13 | 2016-11-16 | 阜南县猛发工艺品有限公司 | Back-shaped dose of a kind of softening for wicker products and using method thereof |
| CN107081827A (en) * | 2017-04-27 | 2017-08-22 | 广西钦州胜腾商务有限公司 | A kind of the preservation of timber against decay processing method |
| CN109049220A (en) * | 2018-09-26 | 2018-12-21 | 湖州欧宝木业有限公司 | The insect prevention soak of stair plank |
| CN109291185A (en) * | 2018-09-26 | 2019-02-01 | 湖州欧宝木业有限公司 | A kind of preparation method of stair plank insect prevention working solution |
| CN109650735A (en) * | 2018-12-06 | 2019-04-19 | 信义超薄玻璃(东莞)有限公司 | A kind of glass post-treatment agent and preparation method thereof |
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| CN100421562C (en) * | 2004-10-08 | 2008-10-01 | 浙江林学院 | Method for preparing plant nutrient preservative agent of bamboo vinegar liquid |
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- 2006-06-09 CN CNB2006100518849A patent/CN100439057C/en not_active Expired - Fee Related
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|---|---|---|---|---|
| EP2505324A4 (en) * | 2009-11-23 | 2014-12-03 | Fujian Simzu Environment Science And Technology Co Ltd | Bamboo fiber material |
| EP2505324A1 (en) * | 2009-11-23 | 2012-10-03 | Fujian Simzu Environment Science And Technology Co., Ltd. | Bamboo fiber material |
| US8480851B2 (en) | 2009-11-23 | 2013-07-09 | Fujian Simzu Environment Science And Technology Co., Ltd. | Bamboo fiber material |
| WO2011060652A1 (en) * | 2009-11-23 | 2011-05-26 | 福建省世竹环保科技有限公司 | Bamboo fiber material |
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