CN1833495A - Insect killing line fragrnant - Google Patents
Insect killing line fragrnant Download PDFInfo
- Publication number
- CN1833495A CN1833495A CN 200610067904 CN200610067904A CN1833495A CN 1833495 A CN1833495 A CN 1833495A CN 200610067904 CN200610067904 CN 200610067904 CN 200610067904 A CN200610067904 A CN 200610067904A CN 1833495 A CN1833495 A CN 1833495A
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- China
- Prior art keywords
- incense stick
- insect disinfestation
- mixture
- hydrocarbon solvent
- base material
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Abstract
The invention relates to a method for producing disinsection coils, which comprises: coating the mixture of 2, 2, 3, 3 - tetramethyl cyclopropane carboxyl acid, 2, 3, 5, 6 - tetrafluoride - 4 - methoxy methyl benzyloxycarbonyl and the hydrocarbon solvent on the coil basic material.
Description
The present invention relates to a kind of method of incense stick for insect disinfestation (insecticidal coil) and incense stick for insect disinfestation that obtains by this method of preparing.
JP2001-302591A and EP60617A disclose the Pesticidal compound 2,2,3 shown in a kind of formula (I), 3-Tetramethylcycloprop-ne-ne carboxylic acid (2,3,5,6-tetrafluoro-4-methoxy benzyl) ester:
JP2001-302591A discloses a kind of incense stick for insect disinfestation that obtains by compound shown in hybrid (I) and line spices base material.
Yet the insecticidal effect of this incense stick for insect disinfestation is usually not enough, therefore needs the more effective incense stick for insect disinfestation of exploitation.
The invention solves the problems referred to above, and the present invention's method of preparing incense stick for insect disinfestation is included in the step of the mixture of coating formula (I) compound and hydrocarbon solvent on the line spices base material.
The incense stick for insect disinfestation of the inventive method preparation has excellent effectiveness, so the present invention can reduce the dosage of formula (I) compound to save cost.
The line spices base material mainly is made up of one or more combustion adjuvants and one or more adhesives usually.The example of combustion adjuvant comprises dried plant powder such as wood powder, Dalmatian chrysanthemum slag, citrus peel meal, palm oil-bound distemper, coconut shell powder and walnut parting; Carbon dust such as charcoal powder, activated carbon powder and coal dust; And their mixture.The example of adhesive comprises polymer such as Tabu powder (dry powder of Matilus sp.), starch (for example tapioca, corn starch, wheaten starch), and casein, Siam sticks with paste, methylcellulose, carboxymethyl cellulose and polyvinyl alcohol, and composition thereof.The weight ratio of combustion adjuvant and adhesive is generally 8: 2 to 6: 4 scope.
The line spices base material normally is prepared as follows: combustion adjuvant is mixed with adhesive, and optional and water is mediated, and moulding is also dry.
The shape of line spices base material can be plate-like or strip without limits.The present invention is generally used for the conventional line spices base material of about 12cm of diameter and the about 3-5mm of thickness, in this routine line spices base material one cover two line spices is arranged.
Formula (I) compound is open in JP2001-302591A and EP60617A, and they can prepare by the method described in the above-mentioned document.
Be used for the hydrocarbon solvent that hydrocarbon solvent of the present invention normally has 150-350 ℃ of boiling point.The preferred saturated hydrocarbon of hydrocarbon solvent of the present invention.The example of saturated hydrocarbon comprises straight chain and branched-chain hydrocarbons, alicyclic and composition thereof.Representative instance is that Norpar 13 is (by the straight chain saturation alkane of Exxon Mobil production, boiling point 222-243 ℃), Norpar 15 is (by the straight chain saturation alkane of Exxon Mobil production, boiling point 255-279 ℃), Isopar G is (by the saturated C9-12 hydrocarbon of side chain of Exxon Mobil production, boiling point 160-176 ℃), Isopar H is (by the saturated C10-13 hydrocarbon of side chain of Exxon Mobil production, boiling point 178-188 ℃), Isopar M is (by the saturated C11-16 hydrocarbon of side chain of Exxon Mobil production, boiling point 223-254 ℃), Isopar V (by the saturated C13-20 hydrocarbon of side chain of Exxon Mobil production, boiling point 273-312 ℃), Exxsol D40 is (by the saturated alicyclic hydrocarbon of Exxon Mobil production, boiling point 159-204 ℃), Exxsol D80 (by the saturated alicyclic hydrocarbon of Exxon Mobil production, boiling point 207-234 ℃), Exxsol D110 is (by the saturated alicyclic hydrocarbon of Exxon Mobil production, boiling point 251-269 ℃) and Exxsol D130 (by the saturated alicyclic hydrocarbon of Exxon Mobil production, boiling point 281-315 ℃).Kerosene also can be used as hydrocarbon solvent.
Mixture Chinese style (I) compound concentrations at formula (I) compound and hydrocarbon solvent is generally 0.01-10.0w/v%, is preferably 0.1-5.0w/v%, more preferably 0.5-5.0w/v%.
The mixture of formula (I) compound and hydrocarbon solvent also can contain surfactant or other auxiliary agent such as aromatic, colouring agent and microbicide.The example of surfactant comprises alkyl sulfate, alkylsulfonate, alkylaryl sulfonates, polyoxyalkylene alkyl, polyoxyalkylene alkyl aryl ether, polyoxyalkylene styryl phenyl ether, polyol ester and sugar alcohol derivant.
The method of the mixture of coating type (I) compound and hydrocarbon solvent can followingly be carried out: with brush mixture evenly is coated on the line spices base material, evenly be added drop-wise to mixture on the line spices base material or with the mixture even spraying to the line spices base material.After mixture being coated on the line spices base material, make the incense stick for insect disinfestation drying.This dry run can for example be carried out by incense stick for insect disinfestation is placed at 5-35 ℃ in 0.1-10 hour.
Incense stick for insect disinfestation can in statu quo be packaged in the box.But each incense stick for insect disinfestation can be independent or a plurality of packing together, is loaded on then that box is medium-term and long-term to be preserved.Packaging material can be paper, glassine paper, cloth, aluminium film or resin molding.The example of resin molding comprises polyethylene (for example low density polyethylene (LDPE), high density polyethylene (HDPE)), polypropylene (for example non-oriented polypropylene, oriented polypropylene), polyvinyl chloride, polyvinylidene chloride, polyamide and PETG.
The incense stick for insect disinfestation that obtains above can use according to a conventional method.That is to say, incense stick for insect disinfestation of the present invention is lighted in the habitat of insect (for example, family, office, stock barn) or its adjacent domain.The burning of incense stick for insect disinfestation makes the ester compounds of formula (I) evaporate, thus the insect of control such as mosquito, fly and cockroach.
This incense stick for insect disinfestation can effectively be prevented and treated dipteral insect such as Culex (Culex spp.) (Culex pipiens pallens (Culex pipiens pallens) for example, Culex tritaeniorhynchus (Culex tritaeniorhynchus)), Aedes (Aedes spp.) (Aedes aegypti (Aedes aegypti) for example, aedes albopictus (Aedesalbopictus)), Anopheles (Anopheles spp.) (for example Anopheles sinensis (Anophelessinensis)), Nuscidae (Muscidae) (housefly (Musca domestica) for example, false stable fly (Muscina stabulans), Fannia canicularis (Fannia canicularis)), Calliphoridae (Calliphoridae), Flesh flies (Sarcophagidae), Moth files (Psychodidae) and Phoridae (Phorodae); And Dictyoptera (Dictyoptera) insect such as Groton bug (Blattellagermanica), Peroplaneta fluligginosa (Periplaneta fuliginosa), American cockroach (PeriplanetaAmericana), big Lian of foxiness (Periplaneta brunnea) and oriental cockroach (Blattaorientalis).
Embodiment
Below the present invention is described in detail; But the present invention is not limited to following examples.
Preparation embodiment 1
In the mixture of the Tabu of 99.99 weight portions powder, Dalmatian chrysanthemum slag and wood powder (4: 3: 3), add the water of 120 weight portions and mediate evenly dry then the line spices base material (diameter 11.8cm, thick 4mm become counterweight 25g) that forms with coil shape.
On the other hand, preparation concentration is 2,2 of 1.25w/v%, 3,3-Tetramethylcycloprop-ne-ne carboxylic acid (2,3,5,6-tetrafluoro-4-methoxy benzyl) solution of ester (compound (1) hereinafter referred to as) in ExxsolD80 (saturated alicyclic hydrocarbon of producing by Exxon Mobil).
Evenly drip 1ml above-mentioned solution at this on to the line spices base material with micro syringe, room temperature is placed 3 hours incense stick for insect disinfestation with the compound (1) that contained 0.05w/w% in pairs then.
Preparation embodiment 2
In the mixture of the Tabu of 99.97 weight portions powder, Dalmatian chrysanthemum slag and wood powder (4: 3: 3), add the water of 120 weight portions and mediate evenly dry then the line spices base material (diameter 11.8cm, thick 4mm become counterweight 25g) that forms with coil shape.
On the other hand, preparation compound (1) concentration in Exxsol D80 (saturated alicyclic hydrocarbon of being produced by Exxon Mobil) is the solution of 2.5w/v%.
Evenly drip 1ml above-mentioned solution at this on to the line spices base material with micro syringe, room temperature is placed 3 hours to be contained the incense stick for insect disinfestation of 0.10w/w% compound (1) in pairs then.
Preparation embodiment 3
In the mixture of the Tabu of 99.97 weight portions powder, Dalmatian chrysanthemum slag and wood powder (4: 3: 3), add the water of 120 weight portions and mediate evenly dry then the line spices base material (diameter 11.8cm, thick 4mm become counterweight 25g) that forms with coil shape.
On the other hand, preparation compound (1) concentration in Exxsol D80 (saturated alicyclic hydrocarbon of being produced by Exxon Mobil) is the solution of 5.0w/v%.
Evenly drip 0.5ml above-mentioned solution at this on to the line spices base material with micro syringe, room temperature is placed 3 hours incense stick for insect disinfestation with the compound (1) that contained 0.10w/w% in pairs then.
Reference example 1
The compound (1) of 0.05 weight portion is dissolved in the acetone of 15.8 weight portions, and the mixture with 99.95 weight portion Tabu powder, Dalmatian chrysanthemum slag and wood powder (4: 3: 3) mixes then.Add 120 weight parts waters, mediate evenly, be shaped then and dry reference incense stick for insect disinfestation (diameter 11.8cm, thick 4mm become counterweight 25g) to obtain containing 0.05w/w% compound (1).
The test implementation example
10 female adult mosquitos (Culex quinquefaciatus) are released to glass tube (internal diameter: 4cm, length: seal with 16 order nylon wires 12cm) and with its two ends.
On the other hand, with plastic cylinder (internal diameter: 20cm, height: 30cm) be put in stainless steel cylinder (internal diameter: 20cm, height: 80cm).The glass tube that mosquito is housed is put into plastic cylinder, make the bottom of glass tube consistent with the height of plastic cylinder bottom.Then, will test to light to make to test with incense stick for insect disinfestation after its smooth combustion a little while and be put in stainless steel cylinder bottom center with incense stick for insect disinfestation.
In setting-up time, count the quantity of mosquito that to go down.Calculate respectively and knock down the required time (KT of 50% or 90% test mosquito
50, KT
90).Each incense stick for insect disinfestation retest 3 times is also averaged.The result is as follows.
| The concentration (w/w%) of compound (1) | KD 50(min) | KD 90(min) | |
| Preparation embodiment 1 | 0.05 | 6.9 | 11.6 |
| Preparation embodiment 2 | 0.10 | 4.2 | 6.4 |
| Preparation embodiment 3 | 0.10 | 4.6 | 7.1 |
| Reference example 1 | 0.05 | 8.5 | 16.3 |
As implied above, incense stick for insect disinfestation of the present invention has higher desinsection than the incense stick for insect disinfestation by method preparation known in the state of the art and renders a service.For example, in reference example 1,0.05w/w% compound (1) obtained 90% rate of knockdown after 16.3 minutes; And 0.05w/w% compound (1) just obtained 90% rate of knockdown after 11.6 minutes in preparation embodiment 1.This has shown superiority of the present invention.
Claims (6)
1. produce the method for incense stick for insect disinfestation, comprise that with 2,2,3 the mixture of 3-Tetramethylcycloprop-ne-ne carboxylic acid (2,3,5,6-tetrafluoro-4-methoxy benzyl) ester and hydrocarbon solvent is coated on the line spices base material.
2. according to the process of claim 1 wherein that the content of ester compounds is 0.01-10.0w/v% in the mixture.
3. according to the method for claim 1 or 2, wherein hydrocarbon solvent is the saturated hydrocarbon solvent with 150-350 ℃ of boiling point.
4. incense stick for insect disinfestation, wherein this incense stick for insect disinfestation is by with 2,2,3, the mixture of 3-Tetramethylcycloprop-ne-ne carboxylic acid (2,3,5,6-tetrafluoro-4-methoxy benzyl) ester and hydrocarbon solvent is coated on the line spices base material available.
5. according to the incense stick for insect disinfestation of claim 4, wherein the content of ester compounds is 0.01-10.0w/v% in the mixture.
6. according to the incense stick for insect disinfestation of claim 4 or 5, wherein hydrocarbon solvent is the saturated hydrocarbon solvent with 150-350 ℃ of boiling point.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005074723A JP2006256991A (en) | 2005-03-16 | 2005-03-16 | Method for producing insecticidal incense stick and insecticidal incense stick |
| JP2005074723 | 2005-03-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1833495A true CN1833495A (en) | 2006-09-20 |
Family
ID=37001515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200610067904 Pending CN1833495A (en) | 2005-03-16 | 2006-03-14 | Insect killing line fragrnant |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP2006256991A (en) |
| CN (1) | CN1833495A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101180966B (en) * | 2006-11-15 | 2013-03-06 | 大日本除虫菊株式会社 | Shoofly joss stick |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5884590B2 (en) * | 2012-03-23 | 2016-03-15 | 富士ゼロックス株式会社 | Electrostatic image developing toner, electrostatic image developer, toner cartridge, developer cartridge, process cartridge, image forming apparatus, and image forming method |
| JP7058855B2 (en) * | 2017-08-10 | 2022-04-25 | フマキラー株式会社 | How to make incense sticks |
| JP6626912B2 (en) * | 2018-02-26 | 2019-12-25 | フマキラー株式会社 | Incense stick and method for producing the same |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4628119B1 (en) * | 1968-12-27 | 1971-08-14 | ||
| GB2097384A (en) * | 1981-03-18 | 1982-11-03 | Ici Plc | Fluorinated benzyl esters of tetramethylcyclopropane carboxylic acid |
| JP4183790B2 (en) * | 1998-03-24 | 2008-11-19 | アース製薬株式会社 | Insecticide incense and method of migration and dissipation of insecticidal components |
| JP3690215B2 (en) * | 1998-11-20 | 2005-08-31 | 住友化学株式会社 | Pyrethroid compound and pest control agent containing it as an active ingredient |
| JP2004143151A (en) * | 2002-10-02 | 2004-05-20 | Dainippon Jochugiku Co Ltd | Fly repellant incense |
-
2005
- 2005-03-16 JP JP2005074723A patent/JP2006256991A/en active Pending
-
2006
- 2006-03-14 CN CN 200610067904 patent/CN1833495A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101180966B (en) * | 2006-11-15 | 2013-03-06 | 大日本除虫菊株式会社 | Shoofly joss stick |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006256991A (en) | 2006-09-28 |
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Application publication date: 20060920 |