CN1817972A - Acid dye composition - Google Patents
Acid dye composition Download PDFInfo
- Publication number
- CN1817972A CN1817972A CN 200610200035 CN200610200035A CN1817972A CN 1817972 A CN1817972 A CN 1817972A CN 200610200035 CN200610200035 CN 200610200035 CN 200610200035 A CN200610200035 A CN 200610200035A CN 1817972 A CN1817972 A CN 1817972A
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- Prior art keywords
- acid
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000980 acid dye Substances 0.000 title claims abstract description 36
- 239000000203 mixture Substances 0.000 title claims description 34
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 claims description 53
- ZIUSSTSXXLLKKK-KOBPDPAPSA-N (1e,4z,6e)-5-hydroxy-1,7-bis(4-hydroxy-3-methoxyphenyl)hepta-1,4,6-trien-3-one Chemical compound C1=C(O)C(OC)=CC(\C=C\C(\O)=C\C(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 ZIUSSTSXXLLKKK-KOBPDPAPSA-N 0.000 claims description 44
- VFLDPWHFBUODDF-FCXRPNKRSA-N Curcumin Natural products C1=C(O)C(OC)=CC(\C=C\C(=O)CC(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-FCXRPNKRSA-N 0.000 claims description 44
- VFLDPWHFBUODDF-UHFFFAOYSA-N diferuloylmethane Natural products C1=C(O)C(OC)=CC(C=CC(=O)CC(=O)C=CC=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-UHFFFAOYSA-N 0.000 claims description 44
- 229920002472 Starch Polymers 0.000 claims description 31
- 239000008107 starch Substances 0.000 claims description 31
- 235000019698 starch Nutrition 0.000 claims description 31
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 29
- 239000002253 acid Substances 0.000 claims description 27
- AHKDJQYHVWSRLT-UHFFFAOYSA-N anthragallol Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=C(O)C(O)=C2O AHKDJQYHVWSRLT-UHFFFAOYSA-N 0.000 claims description 24
- JYJIGFIDKWBXDU-MNNPPOADSA-N inulin Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@]1(OC[C@]2(OC[C@]3(OC[C@]4(OC[C@]5(OC[C@]6(OC[C@]7(OC[C@]8(OC[C@]9(OC[C@]%10(OC[C@]%11(OC[C@]%12(OC[C@]%13(OC[C@]%14(OC[C@]%15(OC[C@]%16(OC[C@]%17(OC[C@]%18(OC[C@]%19(OC[C@]%20(OC[C@]%21(OC[C@]%22(OC[C@]%23(OC[C@]%24(OC[C@]%25(OC[C@]%26(OC[C@]%27(OC[C@]%28(OC[C@]%29(OC[C@]%30(OC[C@]%31(OC[C@]%32(OC[C@]%33(OC[C@]%34(OC[C@]%35(OC[C@]%36(O[C@@H]%37[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O%37)O)[C@H]([C@H](O)[C@@H](CO)O%36)O)[C@H]([C@H](O)[C@@H](CO)O%35)O)[C@H]([C@H](O)[C@@H](CO)O%34)O)[C@H]([C@H](O)[C@@H](CO)O%33)O)[C@H]([C@H](O)[C@@H](CO)O%32)O)[C@H]([C@H](O)[C@@H](CO)O%31)O)[C@H]([C@H](O)[C@@H](CO)O%30)O)[C@H]([C@H](O)[C@@H](CO)O%29)O)[C@H]([C@H](O)[C@@H](CO)O%28)O)[C@H]([C@H](O)[C@@H](CO)O%27)O)[C@H]([C@H](O)[C@@H](CO)O%26)O)[C@H]([C@H](O)[C@@H](CO)O%25)O)[C@H]([C@H](O)[C@@H](CO)O%24)O)[C@H]([C@H](O)[C@@H](CO)O%23)O)[C@H]([C@H](O)[C@@H](CO)O%22)O)[C@H]([C@H](O)[C@@H](CO)O%21)O)[C@H]([C@H](O)[C@@H](CO)O%20)O)[C@H]([C@H](O)[C@@H](CO)O%19)O)[C@H]([C@H](O)[C@@H](CO)O%18)O)[C@H]([C@H](O)[C@@H](CO)O%17)O)[C@H]([C@H](O)[C@@H](CO)O%16)O)[C@H]([C@H](O)[C@@H](CO)O%15)O)[C@H]([C@H](O)[C@@H](CO)O%14)O)[C@H]([C@H](O)[C@@H](CO)O%13)O)[C@H]([C@H](O)[C@@H](CO)O%12)O)[C@H]([C@H](O)[C@@H](CO)O%11)O)[C@H]([C@H](O)[C@@H](CO)O%10)O)[C@H]([C@H](O)[C@@H](CO)O9)O)[C@H]([C@H](O)[C@@H](CO)O8)O)[C@H]([C@H](O)[C@@H](CO)O7)O)[C@H]([C@H](O)[C@@H](CO)O6)O)[C@H]([C@H](O)[C@@H](CO)O5)O)[C@H]([C@H](O)[C@@H](CO)O4)O)[C@H]([C@H](O)[C@@H](CO)O3)O)[C@H]([C@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JYJIGFIDKWBXDU-MNNPPOADSA-N 0.000 claims description 21
- 239000012752 auxiliary agent Substances 0.000 claims description 20
- 229920001202 Inulin Polymers 0.000 claims description 18
- 229940029339 inulin Drugs 0.000 claims description 18
- 229930014626 natural product Natural products 0.000 claims description 16
- AOMZHDJXSYHPKS-DROYEMJCSA-L Amido Black 10B Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC=CC=3)C(O)=C2C(N)=C1\N=N\C1=CC=C(N(=O)=O)C=C1 AOMZHDJXSYHPKS-DROYEMJCSA-L 0.000 claims description 12
- IHZXTIBMKNSJCJ-UHFFFAOYSA-N 3-{[(4-{[4-(dimethylamino)phenyl](4-{ethyl[(3-sulfophenyl)methyl]amino}phenyl)methylidene}cyclohexa-2,5-dien-1-ylidene)(ethyl)azaniumyl]methyl}benzene-1-sulfonate Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 IHZXTIBMKNSJCJ-UHFFFAOYSA-N 0.000 claims description 11
- IURGIPVDZKDLIX-UHFFFAOYSA-M [7-(diethylamino)phenoxazin-3-ylidene]-diethylazanium;chloride Chemical compound [Cl-].C1=CC(=[N+](CC)CC)C=C2OC3=CC(N(CC)CC)=CC=C3N=C21 IURGIPVDZKDLIX-UHFFFAOYSA-M 0.000 claims description 11
- 230000007071 enzymatic hydrolysis Effects 0.000 claims description 10
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 claims description 10
- UDTJJVCMRRCRDB-UHFFFAOYSA-M sodium;4-(3-methyl-5-oxo-4-phenyldiazenyl-4h-pyrazol-1-yl)benzenesulfonate Chemical compound [Na+].CC1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=CC=C1 UDTJJVCMRRCRDB-UHFFFAOYSA-M 0.000 claims description 10
- DGOBMKYRQHEFGQ-UHFFFAOYSA-L acid green 5 Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 DGOBMKYRQHEFGQ-UHFFFAOYSA-L 0.000 claims description 8
- 229920001353 Dextrin Polymers 0.000 claims description 6
- 239000004375 Dextrin Substances 0.000 claims description 6
- LPQOADBMXVRBNX-UHFFFAOYSA-N ac1ldcw0 Chemical compound Cl.C1CN(C)CCN1C1=C(F)C=C2C(=O)C(C(O)=O)=CN3CCSC1=C32 LPQOADBMXVRBNX-UHFFFAOYSA-N 0.000 claims description 6
- 235000019425 dextrin Nutrition 0.000 claims description 6
- AOMZHDJXSYHPKS-UHFFFAOYSA-L disodium 4-amino-5-hydroxy-3-[(4-nitrophenyl)diazenyl]-6-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(N=NC=3C=CC=CC=3)C(O)=C2C(N)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 AOMZHDJXSYHPKS-UHFFFAOYSA-L 0.000 claims description 6
- 150000002016 disaccharides Chemical class 0.000 claims description 5
- 150000004676 glycans Chemical class 0.000 claims description 5
- 229920001282 polysaccharide Polymers 0.000 claims description 5
- 239000005017 polysaccharide Substances 0.000 claims description 5
- 150000003538 tetroses Chemical class 0.000 claims description 5
- 150000004043 trisaccharides Chemical class 0.000 claims description 5
- 229920001661 Chitosan Polymers 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 4
- LGWXIBBJZQOXSO-UHFFFAOYSA-L disodium 5-acetamido-4-hydroxy-3-[(2-methylphenyl)diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(NC(=O)C)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1C LGWXIBBJZQOXSO-UHFFFAOYSA-L 0.000 claims description 4
- 230000032050 esterification Effects 0.000 claims description 4
- 238000005886 esterification reaction Methods 0.000 claims description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- 235000012731 ponceau 4R Nutrition 0.000 claims description 4
- SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 claims description 4
- QUBWRMVVDDDDBG-UHFFFAOYSA-M sodium;1-amino-4-(4-butylanilino)-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=CC(CCCC)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O QUBWRMVVDDDDBG-UHFFFAOYSA-M 0.000 claims description 3
- MHHGZCMFNNAVCQ-UHFFFAOYSA-M sodium;1-amino-4-[3-(2-hydroxyethylsulfamoyl)-4,5-dimethylanilino]-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].OCCNS(=O)(=O)C1=C(C)C(C)=CC(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C(N)=C(C=2)S([O-])(=O)=O)=C1 MHHGZCMFNNAVCQ-UHFFFAOYSA-M 0.000 claims description 3
- PHBKXNWUWOCVEI-UHFFFAOYSA-M sodium;3-[[4-[(2-ethoxy-5-methylphenyl)diazenyl]naphthalen-1-yl]diazenyl]benzenesulfonate Chemical compound [Na+].CCOC1=CC=C(C)C=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC1=CC=CC(S([O-])(=O)=O)=C1 PHBKXNWUWOCVEI-UHFFFAOYSA-M 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 2
- QFVHZQCOUORWEI-UHFFFAOYSA-N 4-[(4-anilino-5-sulfonaphthalen-1-yl)diazenyl]-5-hydroxynaphthalene-2,7-disulfonic acid Chemical compound C=12C(O)=CC(S(O)(=O)=O)=CC2=CC(S(O)(=O)=O)=CC=1N=NC(C1=CC=CC(=C11)S(O)(=O)=O)=CC=C1NC1=CC=CC=C1 QFVHZQCOUORWEI-UHFFFAOYSA-N 0.000 claims description 2
- VVMPKPRQECVYDV-UHFFFAOYSA-N 5-butyl-2-[[4-(4-butyl-2-sulfoanilino)-5,8-dihydroxy-9,10-dioxoanthracen-1-yl]amino]benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC(CCCC)=CC=C1NC(C=1C(=O)C2=C(O)C=CC(O)=C2C(=O)C=11)=CC=C1NC1=CC=C(CCCC)C=C1S(O)(=O)=O VVMPKPRQECVYDV-UHFFFAOYSA-N 0.000 claims description 2
- DLFQBOOBABMDKU-UHFFFAOYSA-N 6637-87-2 Chemical compound OC1=C(N=NC=2C(=C(C=C(C=2)[N+]([O-])=O)[N+]([O-])=O)O)C=C(N=NC=2C3=C(O)C=C(C=C3C=C(C=2)S(O)(=O)=O)S(O)(=O)=O)C(O)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 DLFQBOOBABMDKU-UHFFFAOYSA-N 0.000 claims description 2
- 229920000858 Cyclodextrin Polymers 0.000 claims description 2
- HMEKVHWROSNWPD-UHFFFAOYSA-N Erioglaucine A Chemical compound [NH4+].[NH4+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 HMEKVHWROSNWPD-UHFFFAOYSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- XKTMIJODWOEBKO-UHFFFAOYSA-M Guinee green B Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC=CC=2)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 XKTMIJODWOEBKO-UHFFFAOYSA-M 0.000 claims description 2
- 229920002774 Maltodextrin Polymers 0.000 claims description 2
- 239000005913 Maltodextrin Substances 0.000 claims description 2
- 229920000881 Modified starch Polymers 0.000 claims description 2
- 108010090804 Streptavidin Proteins 0.000 claims description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- ANSOKCGDSQQISA-UHFFFAOYSA-N [1-(2-diphenylphosphanyl-5,6,7,8-tetrahydronaphthalen-1-yl)-5,6,7,8-tetrahydronaphthalen-2-yl]-diphenylphosphane Chemical compound C1CCCC(C=2C=3C(=CC=C4CCCCC4=3)P(C=3C=CC=CC=3)C=3C=CC=CC=3)=C1C=CC=2P(C=1C=CC=CC=1)C1=CC=CC=C1 ANSOKCGDSQQISA-UHFFFAOYSA-N 0.000 claims description 2
- LIKZXCROQGHXTI-UHFFFAOYSA-M acid blue 25 Chemical compound [Na+].C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S([O-])(=O)=O)C=C1NC1=CC=CC=C1 LIKZXCROQGHXTI-UHFFFAOYSA-M 0.000 claims description 2
- CQPFMGBJSMSXLP-UHFFFAOYSA-M acid orange 7 Chemical compound [Na+].OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 CQPFMGBJSMSXLP-UHFFFAOYSA-M 0.000 claims description 2
- 229920006320 anionic starch Polymers 0.000 claims description 2
- VUXVWHOCQSLYRN-UHFFFAOYSA-O benzyl-[4-[[4-[benzyl(ethyl)amino]phenyl]-(2,4-disulfophenyl)methylidene]cyclohexa-2,5-dien-1-ylidene]-ethylazanium Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=CC=CC=2)C=2C(=CC(=CC=2)S(O)(=O)=O)S(O)(=O)=O)C=CC=1N(CC)CC1=CC=CC=C1 VUXVWHOCQSLYRN-UHFFFAOYSA-O 0.000 claims description 2
- NKLPQNGYXWVELD-UHFFFAOYSA-M coomassie brilliant blue Chemical compound [Na+].C1=CC(OCC)=CC=C1NC1=CC=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=C1 NKLPQNGYXWVELD-UHFFFAOYSA-M 0.000 claims description 2
- ZEEMBOPWDPAXAI-UHFFFAOYSA-L dipotassium 5-amino-3-[[4-[[4-[(2,4-diaminophenyl)diazenyl]phenyl]sulfamoyl]phenyl]diazenyl]-4-hydroxy-6-[(4-nitrophenyl)diazenyl]naphthalene-2,7-disulfonate Chemical compound [K+].[K+].NC1=CC=C(N=NC2=CC=C(NS(=O)(=O)C3=CC=C(C=C3)N=NC3=C(O)C4=C(N)C(N=NC5=CC=C(C=C5)[N+]([O-])=O)=C(C=C4C=C3S([O-])(=O)=O)S([O-])(=O)=O)C=C2)C(N)=C1 ZEEMBOPWDPAXAI-UHFFFAOYSA-L 0.000 claims description 2
- GYVPMHHWPSYINH-UHFFFAOYSA-L disodium 2-[4-[[2,4-dihydroxy-3-[[4-(4-nitro-2-sulfonatoanilino)phenyl]diazenyl]phenyl]diazenyl]anilino]-5-nitrobenzenesulfonate Chemical compound [Na+].[Na+].OC1=CC=C(N=NC2=CC=C(NC3=CC=C(C=C3S([O-])(=O)=O)[N+]([O-])=O)C=C2)C(O)=C1N=NC1=CC=C(NC2=CC=C(C=C2S([O-])(=O)=O)[N+]([O-])=O)C=C1 GYVPMHHWPSYINH-UHFFFAOYSA-L 0.000 claims description 2
- XDBZPHDFHYZHNG-UHFFFAOYSA-L disodium 3-[(5-chloro-2-phenoxyphenyl)diazenyl]-4-hydroxy-5-[(4-methylphenyl)sulfonylamino]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].C1=CC(C)=CC=C1S(=O)(=O)NC(C1=C2O)=CC(S([O-])(=O)=O)=CC1=CC(S([O-])(=O)=O)=C2N=NC1=CC(Cl)=CC=C1OC1=CC=CC=C1 XDBZPHDFHYZHNG-UHFFFAOYSA-L 0.000 claims description 2
- VGCGYVHOTSGFBE-UHFFFAOYSA-L disodium 4-amino-3-[(4-aminophenyl)diazenyl]-5-oxido-6-phenyldiazenyl-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc(cc1)N=Nc1c(N)c2c(O)c(N=Nc3ccccc3)c(cc2cc1S([O-])(=O)=O)S([O-])(=O)=O VGCGYVHOTSGFBE-UHFFFAOYSA-L 0.000 claims description 2
- GLNHIAPTFHWQKY-UHFFFAOYSA-L disodium 4-amino-3-[[4-[[4-[(2,4-diaminophenyl)diazenyl]phenyl]sulfonylamino]phenyl]diazenyl]-5-oxido-6-phenyldiazenyl-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc(N=Nc2ccc(cc2)S(=O)(=O)Nc2ccc(cc2)N=Nc2c(N)c3c(O)c(N=Nc4ccccc4)c(cc3cc2S([O-])(=O)=O)S([O-])(=O)=O)c(N)c1 GLNHIAPTFHWQKY-UHFFFAOYSA-L 0.000 claims description 2
- OJFUEILETDLNQK-UHFFFAOYSA-L disodium 5-[[2,4-dihydroxy-3-[(2-hydroxy-5-nitrophenyl)diazenyl]phenyl]diazenyl]-4-hydroxy-3-[(4-nitrophenyl)diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=CC=C(C=C1N=NC1=C(O)C=CC(N=NC2=CC(=CC3=CC(=C(N=NC4=CC=C(C=C4)[N+]([O-])=O)C(O)=C23)S([O-])(=O)=O)S([O-])(=O)=O)=C1O)[N+]([O-])=O OJFUEILETDLNQK-UHFFFAOYSA-L 0.000 claims description 2
- WXUZMLVSQROLEX-UHFFFAOYSA-L disodium 5-[[4-[(4-anilino-3-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]-6-hydroxynaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Oc1ccc2cc(ccc2c1N=Nc1ccc(N=Nc2ccc(Nc3ccccc3)c(c2)S([O-])(=O)=O)c2ccccc12)S([O-])(=O)=O WXUZMLVSQROLEX-UHFFFAOYSA-L 0.000 claims description 2
- HRMOLDWRTCFZRP-UHFFFAOYSA-L disodium 5-acetamido-3-[(4-acetamidophenyl)diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].OC1=C(C(=CC2=CC(=CC(=C12)NC(C)=O)S(=O)(=O)[O-])S(=O)(=O)[O-])N=NC1=CC=C(C=C1)NC(C)=O.[Na+] HRMOLDWRTCFZRP-UHFFFAOYSA-L 0.000 claims description 2
- ARZVLGVDYAMAFX-UHFFFAOYSA-L disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulfonatophenyl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc2cc(cc(O)c2c1N=Nc1ccc(cc1S([O-])(=O)=O)[N+]([O-])=O)S([O-])(=O)=O ARZVLGVDYAMAFX-UHFFFAOYSA-L 0.000 claims description 2
- LERIXBKRKBHLHG-UHFFFAOYSA-L disodium;2-[[5,8-dihydroxy-4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]-5-methylbenzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=C(O)C=CC(O)=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O LERIXBKRKBHLHG-UHFFFAOYSA-L 0.000 claims description 2
- FPVGTPBMTFTMRT-UHFFFAOYSA-L disodium;2-amino-5-[(4-sulfonatophenyl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-UHFFFAOYSA-L 0.000 claims description 2
- VVIVVAIHOWVTHB-UHFFFAOYSA-L disodium;3-[[4-amino-9,10-dioxo-3-[2-sulfonato-4-(2,4,4-trimethylpentan-2-yl)phenoxy]anthracen-1-yl]amino]-2,4,6-trimethylbenzenesulfonate Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C(C)=C1NC1=CC(OC=2C(=CC(=CC=2)C(C)(C)CC(C)(C)C)S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O VVIVVAIHOWVTHB-UHFFFAOYSA-L 0.000 claims description 2
- UHXQPQCJDDSMCB-UHFFFAOYSA-L disodium;3-[[9,10-dioxo-4-(2,4,6-trimethyl-3-sulfonatoanilino)anthracen-1-yl]amino]-2,4,6-trimethylbenzenesulfonate Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C(C)=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=C(C)C=C(C)C(S([O-])(=O)=O)=C1C UHXQPQCJDDSMCB-UHFFFAOYSA-L 0.000 claims description 2
- UTIACSXEVKXHPT-YIDQSHOPSA-L disodium;4-[(2z)-2-[(5z)-4,6-dioxo-5-[(4-sulfonatonaphthalen-1-yl)hydrazinylidene]cyclohex-2-en-1-ylidene]hydrazinyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].C12=CC=CC=C2C(S(=O)(=O)[O-])=CC=C1N\N=C(\C=CC\1=O)C(=O)C/1=N\NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 UTIACSXEVKXHPT-YIDQSHOPSA-L 0.000 claims description 2
- BOXAUJCFZBSNKZ-UHFFFAOYSA-L disodium;5-butyl-2-[[4-(4-butyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(CCCC)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(CCCC)C=C1S([O-])(=O)=O BOXAUJCFZBSNKZ-UHFFFAOYSA-L 0.000 claims description 2
- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 claims description 2
- XPRMZBUQQMPKCR-UHFFFAOYSA-L disodium;8-anilino-5-[[4-[(3-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C3=CC=CC=C3C(N=NC=3C4=CC=CC(=C4C(NC=4C=CC=CC=4)=CC=3)S([O-])(=O)=O)=CC=2)=C1 XPRMZBUQQMPKCR-UHFFFAOYSA-L 0.000 claims description 2
- LCZPIYCNOWJWPQ-UHFFFAOYSA-I disodium;chromium(3+);1-[(2-oxidonaphthalen-1-yl)diazenyl]-4-sulfonaphthalen-2-olate;3-oxido-4-[(2-oxidonaphthalen-1-yl)diazenyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].[Cr+3].C12=CC=CC=C2C(S(=O)(=O)O)=CC([O-])=C1N=NC1=C([O-])C=CC2=CC=CC=C12.C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3[O-])=C([O-])C=C(S([O-])(=O)=O)C2=C1 LCZPIYCNOWJWPQ-UHFFFAOYSA-I 0.000 claims description 2
- 238000006266 etherification reaction Methods 0.000 claims description 2
- 235000019233 fast yellow AB Nutrition 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 229940014259 gelatin Drugs 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 239000008103 glucose Substances 0.000 claims description 2
- WDPIZEKLJKBSOZ-UHFFFAOYSA-M green s Chemical compound [Na+].C1=CC(N(C)C)=CC=C1C(C=1C2=CC=C(C=C2C=C(C=1O)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](C)C)C=C1 WDPIZEKLJKBSOZ-UHFFFAOYSA-M 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- 229940035034 maltodextrin Drugs 0.000 claims description 2
- MCPLVIGCWWTHFH-UHFFFAOYSA-L methyl blue Chemical compound [Na+].[Na+].C1=CC(S(=O)(=O)[O-])=CC=C1NC1=CC=C(C(=C2C=CC(C=C2)=[NH+]C=2C=CC(=CC=2)S([O-])(=O)=O)C=2C=CC(NC=3C=CC(=CC=3)S([O-])(=O)=O)=CC=2)C=C1 MCPLVIGCWWTHFH-UHFFFAOYSA-L 0.000 claims description 2
- JMXROTHPANUTOJ-UHFFFAOYSA-H naphthol green b Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000004302 potassium sorbate Substances 0.000 claims description 2
- 235000010241 potassium sorbate Nutrition 0.000 claims description 2
- 229940069338 potassium sorbate Drugs 0.000 claims description 2
- 235000012752 quinoline yellow Nutrition 0.000 claims description 2
- 239000004172 quinoline yellow Substances 0.000 claims description 2
- 229940051201 quinoline yellow Drugs 0.000 claims description 2
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 claims description 2
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 2
- QERXHBDEEFLTOL-UHFFFAOYSA-M sodium 1-[[4-[(4-sulfophenyl)diazenyl]phenyl]diazenyl]naphthalen-2-olate Chemical compound [Na+].Oc1ccc2ccccc2c1N=Nc1ccc(cc1)N=Nc1ccc(cc1)S([O-])(=O)=O QERXHBDEEFLTOL-UHFFFAOYSA-M 0.000 claims description 2
- VFYDFVDOOIPQHX-UHFFFAOYSA-M sodium 2-[(4-aminophenyl)diazenyl]-5-sulfonaphthalen-1-olate Chemical compound [Na+].C1=CC(N)=CC=C1N=NC1=CC=C(C(=CC=C2)S([O-])(=O)=O)C2=C1O VFYDFVDOOIPQHX-UHFFFAOYSA-M 0.000 claims description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
- 235000010234 sodium benzoate Nutrition 0.000 claims description 2
- 239000004299 sodium benzoate Substances 0.000 claims description 2
- DJDYMAHXZBQZKH-UHFFFAOYSA-M sodium;1-amino-4-(cyclohexylamino)-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S([O-])(=O)=O)C=C1NC1CCCCC1 DJDYMAHXZBQZKH-UHFFFAOYSA-M 0.000 claims description 2
- OFHDOLUPOLKDSG-UHFFFAOYSA-M sodium;1-amino-4-[3-(benzamidomethyl)-2,4,6-trimethylanilino]-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].CC1=CC(C)=C(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C(N)=C(C=2)S([O-])(=O)=O)C(C)=C1CNC(=O)C1=CC=CC=C1 OFHDOLUPOLKDSG-UHFFFAOYSA-M 0.000 claims description 2
- SVNACZCPWZXXSW-UHFFFAOYSA-M sodium;1-amino-9,10-dioxo-4-(2,4,6-trimethyl-3-sulfoanilino)anthracene-2-sulfonate Chemical compound [Na+].CC1=CC(C)=C(S(O)(=O)=O)C(C)=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O SVNACZCPWZXXSW-UHFFFAOYSA-M 0.000 claims description 2
- RRETZLLHOMHNNB-UHFFFAOYSA-M sodium;1-amino-9,10-dioxo-4-(2,4,6-trimethylanilino)anthracene-2-sulfonate Chemical compound [Na+].CC1=CC(C)=CC(C)=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O RRETZLLHOMHNNB-UHFFFAOYSA-M 0.000 claims description 2
- BADRBIXUSUCBEG-UHFFFAOYSA-M sodium;2-[(4-amino-3-methyl-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC(C)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O BADRBIXUSUCBEG-UHFFFAOYSA-M 0.000 claims description 2
- GTKIEPUIFBBXJQ-UHFFFAOYSA-M sodium;2-[(4-hydroxy-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O GTKIEPUIFBBXJQ-UHFFFAOYSA-M 0.000 claims description 2
- SHBDDIJUSNNBLQ-UHFFFAOYSA-M sodium;3-[[4-[(2-chlorophenyl)-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)Cl)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SHBDDIJUSNNBLQ-UHFFFAOYSA-M 0.000 claims description 2
- RWVGQQGBQSJDQV-UHFFFAOYSA-M sodium;3-[[4-[(e)-[4-(4-ethoxyanilino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]-2-methylcyclohexa-2,5-dien-1-ylidene]methyl]-n-ethyl-3-methylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(OCC)=CC=C1NC1=CC=C(C(=C2C(=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=2C(=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=C1 RWVGQQGBQSJDQV-UHFFFAOYSA-M 0.000 claims description 2
- FJBHGWADYLMEJG-UHFFFAOYSA-M sodium;3-[[4-[[4-(diethylamino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC=1C=C(C=CC=1)S([O-])(=O)=O)=C(C=C1)C=CC1=[N+](CC)CC1=CC=CC(S([O-])(=O)=O)=C1 FJBHGWADYLMEJG-UHFFFAOYSA-M 0.000 claims description 2
- NTOOJLUHUFUGQI-UHFFFAOYSA-M sodium;4-(4-acetamidoanilino)-1-amino-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=CC(NC(=O)C)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O NTOOJLUHUFUGQI-UHFFFAOYSA-M 0.000 claims description 2
- BUJNIHFICKTDHT-UHFFFAOYSA-M sodium;4-[4-[acetyl(methyl)amino]anilino]-1-amino-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=CC(N(C(C)=O)C)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O BUJNIHFICKTDHT-UHFFFAOYSA-M 0.000 claims description 2
- RIJLWEYDGZAVGC-UHFFFAOYSA-M sodium;5-methyl-2-[[4-(methylamino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(NC)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O RIJLWEYDGZAVGC-UHFFFAOYSA-M 0.000 claims description 2
- FHIODWDKXMVJGO-UHFFFAOYSA-N sodium;8-anilino-5-[[4-[(5-sulfonaphthalen-1-yl)diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1-sulfonic acid Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC(C1=CC=CC(=C11)S(O)(=O)=O)=CC=C1NC1=CC=CC=C1 FHIODWDKXMVJGO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 claims description 2
- 239000012467 final product Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 22
- 238000004043 dyeing Methods 0.000 description 18
- 239000002131 composite material Substances 0.000 description 11
- 239000000835 fiber Substances 0.000 description 9
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 7
- 238000005303 weighing Methods 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- WBHAUHHMPXBZCQ-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound COC1=CC=CC(C)=C1O WBHAUHHMPXBZCQ-UHFFFAOYSA-N 0.000 description 1
- 240000004859 Gamochaeta purpurea Species 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- -1 carboxymethyl inulin Chemical compound 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Coloring (AREA)
Abstract
An acid dye compound is prepared by taking weak acid dye, natural assistant and stabilizer as raw material and mixing to obtain final product. It has higher absorptive rate, better biological degradability and washing fastness.
Description
Technical field
The invention belongs to chemical technology field, particularly acid dye composition.
Background technology
Tynex selects for use weak acid dye to dye in slightly acidic bath usually, and weak acid dye dyes nylon fibre, because dye molecule is bigger to the avidity of fiber, therefore most dye uptakes are all 80 ~ 90%, and the dyeing back adds an amount of laking agent fixation.But colouring is fast during owing to weak acid dye dyeing, and migration property is poor, and the adding anion surfactant is as levelling agent in the dye bath of therefore being everlasting.Add different levelling agents, all can cause degree of exhaustion in various degree to descend.
For the high dye uptake of realizing weak acid dye when dyeing and the high fastness of product dyed thereby, can in dyestuff, add auxiliary agent from natural product, this auxiliary agent can increase dye solution stability, improves the dye uptake of dyestuff and the wet colour fastness performance of dyeing polyamide fibers, has good homogeneity.
Up to now, Shang Weijian is delivered by the dye composite patent of forming by matching stain, from the auxiliary agent and the stablizer of natural product.
Summary of the invention
The objective of the invention is the problem that when tynex is dyeed, exists at weak acid dye in the existing dyeing, a kind of dyeing auxiliary is provided, after using this auxiliary agent and dyestuff composite by a certain percentage, can make matching stain exhaustion rate after composite near 100%, improve the wet colour fastness of dyeing back fiber simultaneously.
Technical scheme of the present invention is:
High-performance acid dye composition of the present invention is made up of following component by weight percentage:
Weak acid dye 5% ~ 90%
Auxiliary agent 5% ~ 90% from natural product
Stablizer 0 ~ 1%
After adopting general method uniform mixing said components, just obtain this acid dye composition.
Each compositions in weight percentage content preferred range of this high-performance acid dye composition is:
Weak acid dye 5% ~ 90%
Auxiliary agent 5% ~ 90% from natural product
Stablizer 1 ‰ ~ 19%
Another content preferred range of each compositions in weight percentage of this high-performance acid dye composition is:
Weak acid dye 5% ~ 90%
Auxiliary agent 20% ~ 50% from natural product
Stablizer 1 ‰ ~ 19%
In above-mentioned high-performance acid dye composition, described matching stain comprises:
C.I. turmeric yellow 25, C.I. quinoline yellow 6, C.I. turmeric yellow 40, C.I. turmeric yellow 40:1, C.I. turmeric yellow 42, C.I. turmeric yellow 44, C.I. turmeric yellow 49, C.I. turmeric yellow 61, C.I. turmeric yellow 72, C.I. turmeric yellow 76, C.I. turmeric yellow 79, C.I. acid yellow 99, C.I. acid yellow 11 4, C.I. acid yellow 11 6, C.I. acid yellow 11 7, C.I. acid yellow 11 7:1, C.I. acid yellow 11 8, C.I. turmeric yellow 121, C.I. turmeric yellow 127, C.I. turmeric yellow 128, C.I. turmeric yellow 151, C.I. turmeric yellow 158, C.I. turmeric yellow 158:1, C.I. turmeric yellow 194, C.I. turmeric yellow 199, C.I. turmeric yellow 200, C.I. turmeric yellow 219, C.I. turmeric yellow 220, C.I. acid yellow 23 2, C.I. turmeric yellow 242; C.I. von Muller's indicator 3, C.I. von Muller's indicator 24, C.I. von Muller's indicator 33, C.I. von Muller's indicator 51, C.I. von Muller's indicator 56, C.I. von Muller's indicator 60, C.I. von Muller's indicator 67, C.I. acid orange 74, C.I. von Muller's indicator 87, C.I. von Muller's indicator 88, C.I. von Muller's indicator 89, C.I. von Muller's indicator 95, C.I. Acid Orange 116, C.I. von Muller's indicator 127, C.I. von Muller's indicator 154, C.I. von Muller's indicator 156, C.I. von Muller's indicator 171; C.I. Xylene Red 6, C.I. acid red 35, C.I. Xylene Red 37, C.I. Xylene Red 42, C.I. Xylene Red 57, C.I. Xylene Red 73, C.I. Xylene Red 85, C.I. Xylene Red 97, C.I. azogeramine 06, C.I. azogeramine 11, C.I. azogeramine 14, C.I. azogeramine 14:1, C.I. azogeramine 15, C.I. azogeramine 18, C.I. azogeramine 19, C.I. azogeramine 22, C.I. azogeramine 37, C.I. azogeramine 38, C.I. azogeramine 42, C.I. acid red 151, C.I. azogeramine 54, C.I. azogeramine 72, C.I. acid red 18 3, C.I. acid red 18 6, C.I. Xylene Red 211, C.I. Xylene Red 213, C.I. Xylene Red 215, C.I. Xylene Red 226, C.I. Acid Red 249, C.I. Xylene Red 251, C.I. Xylene Red 257, C.I. Xylene Red 260, C.I. Xylene Red 266, C.I. Xylene Red 299, C.I. Xylene Red 308, C.I. Xylene Red 315, C.I. Xylene Red 336, C.I. Xylene Red 337, C.I. acid red 35 9, C.I. Xylene Red 361, C.I. Xylene Red 362, C.I. Xylene Red 374, C.I. Xylene Red 405, C.I. Xylene Red 407, C.I. Xylene Red 410; C.I. acid violet 1, C.I. acid violet 7, C.I. acid violet 17, C.I. acid violet 43, C.I. acid violet 48, C.I. acid violet 49, C.I. acid violet 54, C.I. acid violet 56, C.I. acid violet 68, C.I. Acid Violet 90; C.I. Blue VRS, C.I. Acid Blue 7, C.I. acid blue 9, C.I. Blue VRS 5, C.I. acid blue 25, C.I. acid blue 27, C.I. Acid Blue 40, C.I. acid blue 41, C.I. acid blue 47, C.I. acid blue 62, C.I. acid blue 80, C.I. acid blue 82, C.I. acid blue 83, C.I. acid blue 90, C.I. acid blue 92, C.I. acid blue 93, C.I. Acid blue 113, C.I. Blue VRS 20, C.I. Blue VRS 27, C.I. Blue VRS 27:1, C.I. ACID BLUE 129, C.I. ACID BLUE 129: 1, C.I. Blue VRS 38, C.I. Blue VRS 40, C.I. Blue VRS 42, C.I. Blue VRS 45, C.I. Blue VRS 58, C.I. Blue VRS 68, C.I. Blue VRS 71, C.I. Blue VRS 82, C.I. Blue VRS 83, C.I. Blue VRS 85, C.I. acid blue 193, C.I. acid blue 209, C.I. acid blue 225, C.I. acid blue 230, C.I. acid blue 260, C.I. acid blue 264, C.I. acid blue 277, C.I. acid blue 284, C.I. Basic Blue 3 17, C.I. Basic Blue 3 24, C.I. Basic Blue 3 28, C.I. Basic Blue 3 50, C.I. Basic Blue 3 71; C.I. acid green 1, C.I. acid green 3, C.I. acid green 5, C.I. acid green 9, C.I. acid green 20, C.I. ACID GREEN 25, C.I. acid green 27, C.I. acid green 28, C.I. acid green 41, C.I. acid green 43, C.I. acid green 50, C.I. acid green 54, C.I. acid green 73; C.I. acid brown 2, C.I. ACID BROWN 4, C.I. ACID BROWN 14, C.I. acid brown 21, C.I. acid brown 28, C.I. ACID BROWN 50, C.I. ACID BROWN 58, C.I. ACID BROWN 75, C.I. ACID BROWN 98, C.I. ACID BROWN 119, C.I. ACID BROWN 121, C.I. ACID BROWN 161, C.I. ACID BROWN 165, C.I. ACID BROWN 191, C.I. ACID BROWN 214, C.I. acid brown 2 82, C.I. acid brown 2 83, C.I. acid brown 2 89, C.I. ACID BROWN 349, C.I. ACID BROWN 354, C.I. ACID BROWN 355, C.I. ACID BROWN 365, C.I. ACID BROWN 440; C.I. Acid Black 1, C.I. acid black 2, C.I. acid black 24, C.I. acid black 26, C.I. acid black 29, C.I. erie black 31, C.I. erie black 52, C.I. erie black 58, C.I. erie black 60, C.I. erie black 63, C.I. erie black 94, C.I. Acid Black 1 07, C.I. Acid Black 1 09, C.I. Acid Black 1 68, C.I. Acid Black 1 70, C.I. acid black 172, C.I. Acid Black 1 94, C.I. acid black 2 07, C.I. ACID BLACK 210, C.I. ACID BLACK 234, C.I. acid black 2 43.
In above-mentioned high-performance acid dye composition, described auxiliary agent from natural product comprises:
Chitosan, starch, treated starch, enzymatic hydrolysis starch, dextrin, inulin, modified inulin, gelatin, guar gum, polysaccharide mixture, glucose or sucrose.
Treated starch comprises anionic starch, cationic starch, amphoteric starch, denaturated starch by acid, Sumstar 190, pre-gelatinized starch, esterification starch, etherification starch, Dian Fentang or water soluble starch.Enzymatic hydrolysis starch is the polysaccharide mixture of the above ratio 85 ~ 100% of tetrose, trisaccharide 0 ~ 15%, disaccharide 0 ~ 10% or monose 0 ~ 5.0%.Dextrin comprises cyclodextrine, white dextrin, yellow starch gum or maltodextrin.Modified inulin comprises negatively charged ion inulin, cationic inulin, both sexes inulin, sour sex change inulin, oxidation inulin, esterification inulin, etherificate inulin.
In above-mentioned high-performance acid dye composition, described stablizer comprises:
Sterilizations such as Sodium Benzoate, potassium sorbate, lactic acid streptavidin, oligochitosan, press down mould or sanitas.
The present invention is a kind of uniform mixture based on the compound synergic principle, has a significant effect for colouring performance of promoting dyestuff and the fastness that improves coloured fibre from the auxiliary agent of natural product.After the dye well auxiliary agent mixes by a certain percentage, particularly when specific auxiliary agent with after specific matching stain mixes, can make dyestuff have good colouring performance and fastness ability.
Effect of the present invention and benefit be, can make matching stain exhaustion rate after composite near 100%, improves the wet colour fastness of dyeing back fiber simultaneously, can not change the fiber feel, residual additive discharging back fully biodegradable in the colorless clear liquid after the dyeing.It can be used for the dyeing of materials such as nylon, silk, wool, leather, synthetic resins, paper pulp, paper and recycled writing paper, is particularly suited for various novel polyamide fibers, and the dyeing as Ta Silong (Taslon) etc. obtains uniform Color.
Embodiment
Be described in detail the specific embodiment of the present invention and embodiment below in conjunction with technical scheme.
High-performance acid dye composition of the present invention is by matching stain, formed from auxiliary agent, the stablizer of natural product, and the three all can directly buy from the market.
Above-mentioned three components are mixed in proportion, just obtain high-performance acid dye composition of the present invention.
Embodiment 1
Take by weighing 200g C.I. Acid Orange 116 (200%), the 150g maltodextrin, the 1g phenylformic acid mixes, and just obtains 351g high-performance acid dye composition.This dye composite is used for the dyeing of tynex, can reaches 100% degree of exhaustion, good fastness ability.
Example 1 ~ 10.
In example 1 ~ 10, the weight percent of each component is as shown in the table:
| Example | Matching stain | Auxiliary agent from natural product | Stablizer |
| 1 | 90 | 9 | 1 |
| 2 | 85 | 15 | 0 |
| 3 | 80 | 19 | 1 |
| 4 | 85 | 14.7 | 0.3 |
| 5 | 70 | 29.7 | 0.3 |
| 6 | 50 | 49.7 | 0.3 |
| 7 | 90 | 10 | 0 |
| 8 | 90 | 9.7 | 0.3 |
| 9 | 50 | 50 | 0 |
| 10 | 60 | 40 | 0 |
Embodiment 2
Take by weighing 200g C.I. azogeramine 14 (300%), 200g enzymatic hydrolysis starch, the 1.2g phenylformic acid mixes, and just obtains 401.2g high-performance acid dye composition.This dye composite is used for the dyeing of Ta Silong (Taslon) fiber, can reaches 100% degree of exhaustion, good fastness ability.The above ratio 85-100% of tetrose in the enzymatic hydrolysis starch, trisaccharide 0-15%, disaccharide 0-10%, monose 0-5.0%.
Example 11 ~ 20.
In example 11 ~ 20, the weight percent of each component is as shown in the table:
| Example | Matching stain | Auxiliary agent from natural product | Stablizer |
| 11 | 60 | 39.7 | 0.3 |
| 12 | 80 | 20 | 0 |
| 13 | 80 | 19.7 | 0.3 |
| 14 | 50 | 49 | 1 |
| 15 | 75 | 24 | 1 |
| 16 | 75 | 24.7 | 0.3 |
| 17 | 70 | 30 | 0 |
| 18 | 75 | 25 | 0 |
| 19 | 65 | 35 | 0 |
| 20 | 65 | 34.7 | 0.3 |
Embodiment 3
Take by weighing 200g C.I. azogeramine 14 and 40g Xylene Red 361 former dyestuffs, 60g enzymatic hydrolysis starch, the 0.9g phenylformic acid mixes, and just obtains 300.9g high-performance acid dye composition.This dye composite is used for the dyeing of tynex, can reaches 100% degree of exhaustion, good fastness ability.The above ratio 80-100% of tetrose in the enzymatic hydrolysis starch, trisaccharide 0-20%, disaccharide 0-15%, monose 0-1.0%; Form polysaccharide example 21 ~ 30 with 1,4,1,6 glycosidic link between monose.
In example 21 ~ 30, the weight percent of each component is as shown in the table:
| Example | Matching stain | Auxiliary agent from natural product | Stablizer |
| 21 | 88 | 11 | 1 |
| 22 | 82 | 18 | 0 |
| 23 | 79 | 20 | 1 |
| 24 | 81 | 18.7 | 0.3 |
| 25 | 66 | 33.7 | 0.3 |
| 26 | 55 | 44.7 | 0.3 |
| 27 | 89 | 11 | 0 |
| 28 | 86 | 13.7 | 0.3 |
| 29 | 55 | 55 | 0 |
| 30 | 66 | 34 | 0 |
Embodiment 4
Take by weighing 200g C.I. acid blue 230 (200%), the 100g water soluble starch, the 1g phenylformic acid mixes, and just obtains 301g high-performance acid dye composition.This dye composite is used for the dyeing of tynex, can reaches 100% degree of exhaustion, good fastness ability.
Embodiment 5
Take by weighing 200g C.I. acid blue 225 (200%) and 20g C.I. acid violet 48,100g enzymatic hydrolysis starch, the 1g phenylformic acid mixes, and just obtains 321g high-performance acid dye composition.This dye composite is used for the dyeing of tynex, can reaches 100% degree of exhaustion, good fastness ability.The above ratio 75-100% of tetrose in the enzymatic hydrolysis starch, trisaccharide 0-20%, disaccharide 0-10%, monose 0-2.0%.
Embodiment 6
Take by weighing 200g C.I. acid blue 277 (200%), 50g carboxymethyl inulin, the 1g phenylformic acid mixes, and just obtains 251g high-performance acid dye composition.This dye composite is used for the dyeing of tynex, can reaches 100% degree of exhaustion, good fastness ability.
Embodiment 7
Take by weighing 200g C.I. Basic Blue 3 50 (200%), the 100g inulin, the 1g phenylformic acid mixes, and just obtains 301g high-performance acid dye composition.This dye composite is used for the dyeing of tynex, can reaches 100% degree of exhaustion, good fastness ability.
Example 31 ~ 40.
In example 31 ~ 40, the weight percent of each component is as shown in the table:
| Example | Matching stain | Auxiliary agent from natural product | Stablizer |
| 31 | 68 | 31.7 | 0.3 |
| 32 | 84 | 26 | 0 |
| 33 | 87 | 12.7 | 0.3 |
| 34 | 51 | 48 | 1 |
| 35 | 74 | 25 | 1 |
| 36 | 74 | 25.7 | 0.3 |
| 37 | 68 | 32 | 0 |
| 38 | 77 | 23 | 0 |
| 39 | 64 | 36 | 0 |
| 40 | 63 | 36.7 | 03. |
Claims (6)
1. acid dye composition is characterized in that, the acid dye composition of forming by matching stain, from the auxiliary agent and the stablizer of natural product; Wherein the weight ratio of matching stain is 5% to 90%, is 5% to 90% from the weight ratio of the auxiliary agent of natural product, and the weight ratio of stablizer is 0 to 1%; The chitosan, starch, treated starch, enzymatic hydrolysis starch, dextrin, inulin, modified inulin, gelatin, guar gum, polysaccharide mixture, sucrose or the glucose that wherein comprise different molecular weight from the auxiliary agent of natural product;
Matching stain wherein comprises: C.I. turmeric yellow 25, C.I. quinoline yellow 6, C.I. turmeric yellow 40, C.I. turmeric yellow 40:1, C.I. turmeric yellow 42, C.I. turmeric yellow 44, C.I. turmeric yellow 49, C.I. turmeric yellow 61, C.I. turmeric yellow 72, C.I. turmeric yellow 76, C.I. turmeric yellow 79, C.I. acid yellow 99, C.I. acid yellow 11 4, C.I. acid yellow 11 6, C.I. acid yellow 11 7, C.I. acid yellow 11 7:1, C.I. acid yellow 11 8, C.I. turmeric yellow 121, C.I. turmeric yellow 127, C.I. turmeric yellow 128, C.I. turmeric yellow 151, C.I. turmeric yellow 158, C.I. turmeric yellow 158:1, C.I. turmeric yellow 194, C.I. turmeric yellow 199, C.I. turmeric yellow 200, C.I. turmeric yellow 219, C.I. turmeric yellow 220, C.I. acid yellow 23 2, C.I. turmeric yellow 242; C.I. von Muller's indicator 3, C.I. von Muller's indicator 24, C.I. von Muller's indicator 33, C.I. von Muller's indicator 51, C.I. von Muller's indicator 56, C.I. von Muller's indicator 60, C.I. von Muller's indicator 67, C.I. acid orange 74, C.I. von Muller's indicator 87, C.I. von Muller's indicator 88, C.I. von Muller's indicator 89, C.I. von Muller's indicator 95, C.I. Acid Orange 116, C.I. von Muller's indicator 127, C.I. von Muller's indicator 154, C.I. von Muller's indicator 156, C.I. von Muller's indicator 171; C.I. Xylene Red 6, C.I. acid red 35, C.I. Xylene Red 37, C.I. Xylene Red 42, C.I. Xylene Red 57, C.I. Xylene Red 73, C.I. Xylene Red 85, C.I. Xylene Red 97, C.I. azogeramine 06, C.I. azogeramine 11, C.I. azogeramine 14, C.I. azogeramine 14:1, C.I. azogeramine 15, C.I. azogeramine 18, C.I. azogeramine 19, C.I. azogeramine 22, C.I. azogeramine 37, C.I. azogeramine 38, C.I. azogeramine 42, C.I. acid red 151, C.I. azogeramine 54, C.I. azogeramine 72, C.I. acid red 18 3, C.I. acid red 18 6, C.I. Xylene Red 211, C.I. Xylene Red 213, C.I. Xylene Red 215, C.I. Xylene Red 226, C.I. Acid Red 249, C.I. Xylene Red 251, C.I. Xylene Red 257, C.I. Xylene Red 260, C.I. Xylene Red 266, C.I. Xylene Red 299, C.I. Xylene Red 308, C.I. Xylene Red 315, C.I. Xylene Red 336, C.I. Xylene Red 337, C.I. acid red 35 9, C.I. Xylene Red 361, C.I. Xylene Red 362, C.I. Xylene Red 374, C.I. Xylene Red 405, C.I. Xylene Red 407, C.I. Xylene Red 410; C.I. acid violet 1, C.I. acid violet 7, C.I. acid violet 17, C.I. acid violet 43, C.I. acid violet 48, C.I. acid violet 49, C.I. acid violet 54, C.I. acid violet 56, C.I. acid violet 68, C.I. Acid Violet 90; C.I. Blue VRS, C.I. Acid Blue 7, C.I. acid blue 9, C.I. Blue VRS 5, C.I. acid blue 25, C.I. acid blue 27, C.I. Acid Blue 40, C.I. acid blue 41, C.I. acid blue 47, C.I. acid blue 62, C.I. acid blue 80, C.I. acid blue 82, C.I. acid blue 83, C.I. acid blue 90, C.I. acid blue 92, C.I. acid blue 93, C.I. Acid blue 113, C.I. Blue VRS 20, C.I. Blue VRS 27, C.I. Blue VRS 27:1, C.I. ACID BLUE 129, C.I. ACID BLUE 129: 1, C.I. Blue VRS 38, C.I. Blue VRS 40, C.I. Blue VRS 42, C.I. Blue VRS 45, C.I. Blue VRS 58, C.I. Blue VRS 68, C.I. Blue VRS 71, C.I. Blue VRS 82, C.I. Blue VRS 83, C.I. Blue VRS 85, C.I. acid blue 193, C.I. acid blue 209, C.I. acid blue 225, C.I. acid blue 230, C.I. acid blue 260, C.I. acid blue 264, C.I. acid blue 277, C.I. acid blue 284, C.I. Basic Blue 3 17, C.I. Basic Blue 3 24, C.I. Basic Blue 3 28, C.I. Basic Blue 3 50, C.I. Basic Blue 3 71; C.I. acid green 1, C.I. acid green 3, C.I. acid green 5, C.I. acid green 9, C.I. acid green 20, C.I. ACID GREEN 25, C.I. acid green 27, C.I. acid green 28, C.I. acid green 41, C.I. acid green 43, C.I. acid green 50, C.I. acid green 54, C.I. acid green 73; C.I. acid brown 2, C.I. ACID BROWN 4, C.I. ACID BROWN 14, C.I. acid brown 21, C.I. acid brown 28, C.I. ACID BROWN 50, C.I. ACID BROWN 58, C.I. ACID BROWN 75, C.I. ACID BROWN 98, C.I. ACID BROWN 119, C.I. ACID BROWN 121, C.I. ACID BROWN 161, C.I. ACID BROWN 165, C.I. ACID BROWN 191, C.I. ACID BROWN 214, C.I. acid brown 2 82, C.I. acid brown 2 83, C.I. acid brown 2 89, C.I. ACID BROWN 349, C.I. ACID BROWN 354, C.I. ACID BROWN 355, C.I. ACID BROWN 365, C.I. ACID BROWN 440; C.I. Acid Black 1, C.I. acid black 2, C.I. acid black 24, C.I. acid black 26, C.I. acid black 29, C.I. erie black 31, C.I. erie black 52, C.I. erie black 58, C.I. erie black 60, C.I. erie black 63, C.I. erie black 94, C.I. Acid Black 1 07, C.I. Acid Black 1 09, C.I. Acid Black 1 68, C.I. Acid Black 1 70, C.I. acid black 172, C.I. Acid Black 1 94, C.I. acid black 2 07, C.I. ACID BLACK 210, C.I. ACID BLACK 234, C.I. acid black 2 43;
Stablizer wherein comprises Sodium Benzoate, potassium sorbate, lactic acid streptavidin or oligochitosan.
2. acid dye composition according to claim 1, it is characterized in that treated starch comprises anionic starch, cationic starch, amphoteric starch, denaturated starch by acid, Sumstar 190, pre-gelatinized starch, esterification starch, etherification starch, Dian Fentang or water soluble starch.
3. acid dye composition according to claim 1 is characterized in that, enzymatic hydrolysis starch is the polysaccharide mixture of the above ratio 85 ~ 100% of tetrose, trisaccharide 0 ~ 15%, disaccharide 0 ~ 10% or monose 0 ~ 5.0%.
4. acid dye composition according to claim 1 is characterized in that dextrin comprises cyclodextrine, white dextrin, yellow starch gum or maltodextrin.
5. acid dye composition according to claim 1 is characterized in that, modified inulin comprises negatively charged ion inulin, cationic inulin, both sexes inulin, sour sex change inulin, oxidation inulin, esterification inulin or etherificate inulin.
6. acid dye composition according to claim 1 is characterized in that, the matching stain in the composition and be one-component or different ratios compound from the auxiliary agent of natural product.
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| CN1023811C (en) * | 1987-10-31 | 1994-02-16 | 新华皮革化工厂 | Resin type pigment paste for leather processing |
| JP3619988B2 (en) * | 2000-09-22 | 2005-02-16 | 株式会社加美乃素本舗 | Acid hair dye composition |
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