CN1802919A - Repellant and method for making same, and uses of repellant - Google Patents
Repellant and method for making same, and uses of repellant Download PDFInfo
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- CN1802919A CN1802919A CN 200510128056 CN200510128056A CN1802919A CN 1802919 A CN1802919 A CN 1802919A CN 200510128056 CN200510128056 CN 200510128056 CN 200510128056 A CN200510128056 A CN 200510128056A CN 1802919 A CN1802919 A CN 1802919A
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Abstract
The invention provides an insect repellant for seed pellet inoculation, the preparing process and use, wherein the repellant comprises the following compositions: organophosphorus pesticide, organic stannum, cyclohexanone, toluene, dehydrogenized abietic acid, isocyanide and beta cyclodextrin.
Description
Technical field:
The present invention relates to the purposes of repellant and preparation method thereof and repellant, in particular for the purposes of the repellant of repellent bird, mouse harm and preparation method thereof and repellant.
Background technology:
China is that world population is maximum, is subjected to one of the most serious country of desertification harm.The sand ground scattered seeds by airplane for afforestation is a modernized sand control technology.At present, China's scattered seeds by airplane for afforestation sand control has had very big development, and blocks of plant seeds by airplane woods grass has appeared at the innerland, desert, forms the protection forest system that the woods grass mixes mutually, is controlling the harm of dust storm, is guaranteeing the high and stable yields of farming and animal husbandry.
The sand ground plant seeds by airplane irritate careless plant from plant seeds by airplane on-test so far, relatively successful plant species mostly is a leguminous plant, as poplar bavin, caragana microphylla etc.But, after these plant plant seeds by airplanes, land to becoming seedling from seed, be subjected to bird, mouse harm seriously, greatly influenced plant seeds by airplane sand control afforestation effect.Showing in Erdos Mu Us Shadi plant seeds by airplane sand control for many years afforestation experimental studies results according to the inventor, is example with the poplar bavin, and its mouse hazard ratio reaches as high as more than 90%.
Therefore, pressing for exploitation can solve the scattered seeds by airplane for afforestation seed and land the new technology of back opposing bird, mouse harm.
Summary of the invention:
The purpose of this invention is to provide a kind of repellant that can resist bird, mouse harm after the seed plant seeds by airplane is landed.
Another object of the present invention provides the preparation method of described repellant.
A further object of the present invention provides the purposes of described repellant.
First purpose of the present invention is implemented by following technical scheme:
Repellant of the present invention comprises the following composition in parts by weight:
Organophosphorous pesticide 20-70 part
Organotin 1-6 part
Cyclohexanone 5-30 part
Toluene 5-30 part
Dehydrogenation abietic acid 10-30 part.
Wherein said organophosphorous pesticide is selected from one or more in Isofenphos methyl, malathion, parathion-methyl, phoxim and the demeton-methyl;
Described organotin is selected from one or both in tributyltin oxide and the tributyltin chloride;
Described repellant also comprises in isobutyl cyanogen 20-60 part of parts by weight and beta-schardinger dextrin-1-6 part.
Another object of the present invention is implemented by following technical scheme:
The preparation method of repellant of the present invention is as follows:
(1) in proportion with organophosphorous pesticide and organotin mixed stability, check;
(2) in proportion with cyclohexanone, toluene and dehydrogenation abietic acid mixed stability, check;
(3) in the mixture that step (2) obtains, add root-growing agent, mix, check;
(4) mixture that step (1) and step (3) are obtained mixes, and is stable, and check obtains finished product.
Wherein the mixing in step (1) is that the pH value of check mixed liquor was 6.8-7.2 after mixing was stirred more than 60 minutes in reactor;
Mixing in the step (4) was carried out more than 60 minutes, finally stablized more than 24 hours, and the pH value of check mixed liquor is 6.8-7.2.
Wherein operating temperature is a normal temperature;
Wherein further adding isobutyl cyanogen in step (1) mixes;
Wherein in the mixture that step (1) obtains, add beta-schardinger dextrin-and carry out the inclusion reaction.
The 3rd purpose of the present invention implemented by following technical scheme:
The obducensization that above-mentioned repellant is used for seed.
Advantage of the present invention is: this repellant has high anti-repelling properties, and bird mouse diet rate can reach more than 75%, and aerial seeding seed germination and vegetation are not had injury, vegetative growth there is facilitation, free from environmental pollution, do not kill and wound bird, mouse and forest beneficial organism, to the person poultry safety.
Description of drawings:
Accompanying drawing 1 is a repellant preparation technology flow process.
Embodiment:
The present invention is further illustrated below in conjunction with embodiment.
Embodiment 1 repellant includes Isofenphos methyl 500 grams, isobutyl cyanogen 400 grams, tributyltin oxide 40 grams, cyclohexanone 150 grams, toluene 150 grams and dehydrogenation abietic acid 200 grams.
Prepare above-mentioned repellant, operating temperature is a normal temperature.
(1) get Isofenphos methyl 500 grams, tributyltin oxide 40 grams and isobutyl cyanogen 400 gram mixed stabilities, check, mixing are that the pH value of check mixed liquor was 6.8-7.2 after mixing was stirred more than 60 minutes in reactor;
(2) get cyclohexanone 150 gram, toluene 150 grams and dehydrogenation abietic acid 200 gram mixed stabilities, check, promptly mix be in reactor, mix stir more than 60 minutes after, the pH value of check mixed liquor is 6.8-7.2;
(3) add root-growing agent and little fertilizer in the mixture that step (2) obtains, wherein root-growing agent (as indolebutyric acid and salicylic acid) and little fertilizer (as humic acid complex fertilizer, boron fertilizer, phosphorus, magnesium, potassium etc.) mix, check;
(4) mixture that step (2) and step (3) are obtained mixes, and is stable, and check wherein mixes and carries out more than 60 minutes, finally stablizes more than 24 hours; The pH value of check mixed liquor is 6.8-7.2.Obtain finished product at last.
More than Zhi Bei repellant is used for the obducensization of seed.
Embodiment 2: repellant includes malathion 200 grams, tributyltin chloride 10 grams, cyclohexanone 50 grams, toluene 50 grams and dehydrogenation abietic acid 100 grams.
Prepare above-mentioned repellant, operating temperature is a normal temperature.
(1) get malathion 200 grams, tributyltin chloride 10 gram mixed stabilities, check, mixing are that the pH value of check mixed liquor was 6.8-7.2 after mixing was stirred more than 60 minutes in reactor;
(2) get cyclohexanone 50 gram, toluene 50 grams and dehydrogenation abietic acid 100 gram mixed stabilities, check, promptly mix be in reactor, mix stir more than 60 minutes after, the pH value of check mixed liquor is 6.8-7.2;
(3) add root-growing agent and little fertilizer in the mixture that step (3) obtains, wherein root-growing agent (as indolebutyric acid and salicylic acid) and little fertilizer (as humic acid complex fertilizer, boron fertilizer, phosphorus, magnesium, potassium etc.) mix, check;
(4) mixture that step (1) and step (3) are obtained mixes, and is stable, and check wherein mixes and carries out more than 60 minutes, finally stablizes more than 24 hours; The pH value of check mixed liquor is 6.8-7.2.Obtain finished product at last.
More than Zhi Bei repellant is used for the obducensization of seed.
Embodiment 3: repellant includes methyl to willow phosphorus 700 grams, isobutyl cyanogen 600 grams, tributyltin oxide 60 grams, beta-schardinger dextrin-60 grams, cyclohexanone 300 grams, toluene 300 grams and dehydrogenation abietic acid 300 grams.
Prepare above-mentioned repellant, operating temperature is a normal temperature.
(1) get Isofenphos methyl 700 grams, tributyltin oxide 60 grams and isobutyl cyanogen 600 gram mixed stabilities, check, mixing are that the pH value of check mixed liquor was 6.8-7.2 after mixing was stirred more than 60 minutes in reactor;
(2) in the mixture that step (1) obtains, add 60 gram beta-schardinger dextrin-s and carry out the inclusion reaction;
(3) get cyclohexanone 300 gram, toluene 300 grams and dehydrogenation abietic acid 300 gram mixed stabilities, check, promptly mix be in reactor, mix stir more than 60 minutes after, the pH value of check mixed liquor is 6.8-7.2;
(4) add root-growing agent and little fertilizer in the mixture that step (3) obtains, wherein root-growing agent (as indolebutyric acid and salicylic acid) and little fertilizer (as humic acid complex fertilizer, boron fertilizer, phosphorus, magnesium, potassium etc.) mix, check;
(5) mixture that step (2) and step (4) are obtained mixes, and is stable, and check wherein mixes and carries out more than 60 minutes, finally stablizes more than 24 hours; The pH value of check mixed liquor is 6.8-7.2.Obtain finished product at last.
More than Zhi Bei repellant is used for the obducensization of seed.
Embodiment 4: repellant includes hot willow phosphorus 600 grams, isobutyl cyanogen 500 grams, tributyltin chloride 60 grams, beta-schardinger dextrin-60 grams, cyclohexanone 300 grams, toluene 300 grams and dehydrogenation abietic acid 300 grams.
Prepare above-mentioned repellant, operating temperature is a normal temperature.
(1) get hot willow phosphorus 600 grams, tributyltin chloride 60 grams and isobutyl cyanogen 500 gram mixed stabilities, check, mixing are that the pH value of check mixed liquor was 6.8-7.2 after mixing was stirred more than 60 minutes in reactor;
(2) in the mixture that step (1) obtains, add 60 gram beta-schardinger dextrin-s and carry out the inclusion reaction;
(3) get cyclohexanone 300 gram, toluene 300 grams and dehydrogenation abietic acid 300 gram mixed stabilities, check, promptly mix be in reactor, mix stir more than 60 minutes after, the pH value of check mixed liquor is 6.8-7.2;
(4) add root-growing agent and little fertilizer in the mixture that step (3) obtains, wherein root-growing agent (as indolebutyric acid and salicylic acid) and little fertilizer (as humic acid complex fertilizer, boron fertilizer, phosphorus, magnesium, potassium etc.) mix, check;
(5) mixture that step (2) and step (4) are obtained mixes, and is stable, and check wherein mixes and carries out more than 60 minutes, finally stablizes more than 24 hours; The pH value of check mixed liquor is 6.8-7.2.Obtain finished product at last.Above-mentioned used hot willow phosphorus also can be used demeton-methyl.
More than Zhi Bei repellant is used for the obducensization of seed.
Embodiment 5 plague of rats kinds and hazard conditions research
In the plant seeds by airplane district, arrange 4 sample prescriptions.Wherein the plant seeds by airplane district arranges 1 in sample prescription, 3 in artificial after-culture district.Every sample prescription is arranged 473 of rattraps, catches 49 of samples, 7 kinds, and total capture rate 2.95%.Concrete situation is as shown in table 1.
Table 1 plant seeds by airplane district plague of rats application form
| Plant name | Quantity (only) | Capture rate %) | The people work area | The plant seeds by airplane district |
| The sufficient mouse Cricetulus barabensis Microtus fortis Shrew Murinus Myospalax aspalax (Pallas) of the little Mao of Dipus sagitta Meriones meridianus | 17 13 12 4 2 1 | 34.7 26.5 24.5 8.16 4.08 2.04 do not catch | + + + + + + + | + + + |
| Add up to | 49 | 7 kinds | 3 kinds |
Annotate: "+" has the kind of distribution for this district
As shown in Table 1, the project district is main bandicoot with three-toed jerboa, Meriones meridianus, the sufficient mouse of little Mao, and all to reach density of infection, special robber eaten grass seed to population density, gnaws the underground young root of plant seedlings.Field investigation dissect to find, more than the stomach of three kinds of mouse all contain the foods of white, brown, green, yellow 4 kinds of colors, but in the majority with white, brown two kinds of looks.White is seed, and brown is the young root of plant, and finds that at the scene the root soil of all individual plant seedling is mostly opened by plane, and the hair root of young root is eaten up, and main root is exposed outside, and plant will be withered soon, at concentrated hazard area 1196m
2In have 45 strains killed.
The anxious toxicity research of embodiment 6 different repellants
The principle and the target of repellant screening are exactly that selected repellant should have high anti-repelling properties, and bird mouse diet rate will reach more than 75%, and aerial seeding seed germination and vegetation are not had injury, vegetative growth there is facilitation, free from environmental pollution, do not kill and wound bird, mouse and forest beneficial organism, to the person poultry safety.
Adopt hypodermic injection, oral and external infiltration, manually carry out a large amount of repellant acute toxicity tests.Claim the small white mouse body weight before each test, the hypodermic injection amount is 0.1ml, oral dose 0.1ml, and external infiltration 0.2ml, every group of test repeats 2 times, observes the death time.Repellant of the present invention is as shown in table 2 to the acute toxicity test result of small white mouse.
2, the death time is until time of death after the administration.</entry></row></tbody></tgroup></table></tables>
Can find out significantly from table 2, be oral result from the test method of getting food near muroid, and after this use invention repellent agent, the death time of small white mouse is 27 hours.Therefore can reach and promptly not kill muroid, can also at utmost improve the effect of repellent effect.
The embodiment 7 mouse repellent effect of feeding
Experimental subjects is three-toed jerboa and small white mouse.Experimental technique be with the experimental rat circle in cage, the cage volume of feeding (length * wide * height) is 40 * 40 * 30cm, mouse of every cage.The repellant of feeding repeats twice.Repellant is rendered in the mouse cage according to 20g in the processing of dressing seed of 1: 50 ratio, regularly throws in the food-intake of time sight muroid and health reflection.
The feed intake and the lethality of muroid are as shown in table 3 under the repellant different disposal condition of the present invention:
Table 3 repellant feeding experiment result
| Feed intake (g) | Lethality (%) | |
| Handle one | 2.5 | 0.0 |
| Handle two | 0.0 | 0.0 |
| Handle three | 0.5 | 0.0 |
| On average | 0.75 | 0.0 |
| Remarks | Handling a seed is the poplar bavin, throws in the object small white mouse, and the seed dressing ratio is 1: 30, injected volume 10g; Handling two seeds is caragana microphylla, throws in the object small white mouse, seed dressing ratio 1: 60, injected volume 10g; Handling three seeds is the poplar bavin, throws in the object jerboa, and the seed dressing ratio is 1: 30, injected volume 10g. | |
From table 3 average feed intake and lethality, the average feed intake of handling with repellent agent of the present invention only is 0.75 gram, and lethality is zero.
Embodiment 8 plant seeds by airplane operation area repellent effect observations
Be arranged on plant seeds by airplane operation area in 2004, Tao Li township, Wushen Banner, Ordos City the observation sample.July 1 2004 plant seeds by airplane time, 5100 mu of plant seeds by airplane areas.Adopt the line surveying method, a both selected diagonal broadcasting the district with the method for mechanical sampling, is established 1m every 5m for the investigation line-transect
2The investigation sample prescription, seed grain number in the investigation sample prescription is encroached on the grain number, and then is counted the total defriment rate, and its value is more little, and repellent efficient is good more.
According to the indoor repellency test result that feeds, carry out large tracts of land plant seeds by airplane experiment in the actual plant seeds by airplane of Erdos hair crow sand ground Wushen Banner Tao Li bush district respectively, to verify between the dark green serial different model and and to contrast the difference of the repellent effect between the naked kind.Broadcast back 6 days the preservation and the hazard conditions of plant seeds by airplane district seed are investigated, the result is as shown in table 4:
2, broadcast investigation in back 6 days.</entry></row></tbody></tgroup></table></tables>
As can be seen from Table 4, repellant is handled the seed plague of rats rate of Pelleting well below the naked kind (contrast) that is left intact, and contrast is on average reached 39.2% by hazard ratio, and uses repellent agent of the present invention not take place by infestation.
From table 4, can also observe out simultaneously, because Pelleting is handled the weight of back seed and is strengthened, drift and offset phenomena reduce, therefore in the onesize sample prescription, the quantity of naked kind is minimum, on average only be 8.1, and kind of the amount that on average falls of repellant of the present invention is 14.0, after this has reflected that from another side the dressing Pelleting is handled, to reducing the action effect of seed drift displacement.
Claims (11)
1, a kind of repellant is characterized in that comprising the following composition in parts by weight:
Organophosphorous pesticide 20-70 part
Organotin 1-6 part
Cyclohexanone 5-30 part
Toluene 5-30 part
Dehydrogenation abietic acid 10-30 part.
2, repellant as claimed in claim 1 is characterized in that described organophosphorous pesticide is selected from one or more in Isofenphos methyl, malathion, parathion-methyl, phoxim and the demeton-methyl.
3, repellant as claimed in claim 1 is characterized in that described organotin is selected from one or both in tributyltin oxide and the tributyltin chloride.
4, as any described repellant among the claim 1-3, it is characterized in that also comprising in isobutyl cyanogen 20-60 parts of parts by weight and beta-schardinger dextrin-1-6 part one or both.
5, a kind of method for preparing the described repellant of claim 1 is characterized in that may further comprise the steps:
(1) in proportion with organophosphorous pesticide and organotin mixed stability, check;
(2) in proportion with cyclohexanone, toluene and dehydrogenation abietic acid mixed stability, check;
(3) in the mixture that step (2) obtains, add root-growing agent and little fertilizer, mix check;
(4) mixture that step (1) and step (3) are obtained mixes, and is stable, and check obtains finished product.
6, the described method for preparing repellant of claim 5 is characterized in that the mixing in the step (1) is that the pH value of check mixed liquor was 6.8-7.2 after mixing was stirred more than 60 minutes in reactor.
7, the described method for preparing repellant of claim 5 is characterized in that the mixing in the step (4) was carried out more than 60 minutes, finally stablizes more than 24 hours, and the pH value of check mixed liquor is 6.8-7.2.
8, the described method for preparing repellant of claim 5 is characterized in that operating temperature is a normal temperature.
9, any described method for preparing repellant among the claim 5-8 is characterized in that further adding in the step (1) isobutyl cyanogen and mixes.
10, any described method for preparing repellant among the claim 5-9 is characterized in that adding beta-schardinger dextrin-and carries out the inclusion reaction in the mixture that step (1) obtains.
11, the purposes of the described repellant of claim 1 is characterized in that the described repellant of claim 1 is used for the obducensization of seed.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101280566A CN100355343C (en) | 2005-11-24 | 2005-11-24 | Repellant and method for making same, and uses of repellant |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101280566A CN100355343C (en) | 2005-11-24 | 2005-11-24 | Repellant and method for making same, and uses of repellant |
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| Publication Number | Publication Date |
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| CN1802919A true CN1802919A (en) | 2006-07-19 |
| CN100355343C CN100355343C (en) | 2007-12-19 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106035415A (en) * | 2016-06-15 | 2016-10-26 | 安徽菲扬农业科技有限公司 | Pest repellent and preparation method thereof |
| CN106135317A (en) * | 2016-06-30 | 2016-11-23 | 安徽金培因科技有限公司 | A kind of insects repellant and preparation method thereof |
| CN111108848A (en) * | 2019-12-10 | 2020-05-08 | 亿利资源集团有限公司 | Pelleted seed and seed pelleting method |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1098634C (en) * | 1999-06-07 | 2003-01-15 | 广东省林业科学研究院 | Dieting agent for mouse and bird |
| CN1365611A (en) * | 2001-12-11 | 2002-08-28 | 陈铣 | Wettable 10% Shufuqubi powder |
-
2005
- 2005-11-24 CN CNB2005101280566A patent/CN100355343C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106035415A (en) * | 2016-06-15 | 2016-10-26 | 安徽菲扬农业科技有限公司 | Pest repellent and preparation method thereof |
| CN106135317A (en) * | 2016-06-30 | 2016-11-23 | 安徽金培因科技有限公司 | A kind of insects repellant and preparation method thereof |
| CN111108848A (en) * | 2019-12-10 | 2020-05-08 | 亿利资源集团有限公司 | Pelleted seed and seed pelleting method |
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| Publication number | Publication date |
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| CN100355343C (en) | 2007-12-19 |
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Granted publication date: 20071219 Termination date: 20121124 |