CN1769581A - Treating agent for synthetic fiber and method for treating synthetic fiber - Google Patents
Treating agent for synthetic fiber and method for treating synthetic fiber Download PDFInfo
- Publication number
- CN1769581A CN1769581A CN 200510120110 CN200510120110A CN1769581A CN 1769581 A CN1769581 A CN 1769581A CN 200510120110 CN200510120110 CN 200510120110 CN 200510120110 A CN200510120110 A CN 200510120110A CN 1769581 A CN1769581 A CN 1769581A
- Authority
- CN
- China
- Prior art keywords
- ingredient
- weight
- synthetic fibers
- carbon atom
- inorganic agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides a treating agent for synthetic fiber and a method for treating synthetic fiber, which can fully prevent fluffing, broken ends and stain from happening corresponding to the high speed of the spinning process and the processing process of the synthetic fiber in recent years. A synthetic fiber treating agent containing a specific base oil composition in an amount of 70 wt% or more is used. The base oil composition comprises: component A, which is one or more selected from specific alkylene oxide adducts; component B, which is one or more than one selected from other specific alkylene oxide addition compounds; c component, which is one or more selected from ionic surface active agents; and component D is one or more selected from specific nonionic surfactants. The base oil composition consists of: 50-90 wt% of component A; 3 to 30 wt% of component B; 0.1 to 10 wt% of component C; 0.1 to 20 wt% (total 100 wt%) of component D.
Description
Technical field
The present invention relates to the processing methods of a kind of synthetic fibers inorganic agent and synthetic fibers.In recent years, in the spinning process of synthetic fibers, manufacturing procedure, high speed further upgrades, and consequent is increasingly to be easy to happen the fluffing for producing silk and broken end and the specking on braided fabric.The generation of such fluffing and broken end, specking in order to prevent, following method can be used: the increased substance of content ratio for being used to prevent the functional improver of the above problem is used as to the synthetic fibers inorganic agent for being attached to synthetic fibers, or improve adhesion amount of the synthetic fibers with inorganic agent with respect to synthetic fibers, but it still cannot sufficiently cope with high speed in recent years.It is and corresponding in the high speed of the spinning process of synthetic fibers, manufacturing procedure in recent years the present invention relates to the processing method of a kind of synthetic fibers inorganic agent and synthetic fibers, the generation of fluffing, broken end and specking can be substantially prevented from.
Background technique
Currently, generally using the substance for containing lubricant and functional improver as synthetic fibers inorganic agent.It has been known that there is various such synthetic fibers inorganic agents, wherein containing for preventing the functional improver of fluffing, the generation of broken end (for example, referring to Patent Documents 1 to 8).But in high speed spinning process in recent years, manufacturing procedure, these existing synthetic fibers inorganic agents have that cannot be substantially prevented from fluffing, broken end and specking occurs.
[patent document 1] Japanese Unexamined Patent Application 60-9971 bulletin
[patent document 2] Japanese Unexamined Patent Publication 1-298281 bulletin
[patent document 3] Japanese Unexamined Patent Publication 2-47372 bulletin
[patent document 4] Japanese Unexamined Patent Application 60-181368 bulletin
[patent document 5] Japanese Unexamined Patent Publication 2000-136448 bulletin
[patent document 6] US6432144B1
[patent document 7] Japanese Laid-Open Patent Publication 3-97961 bulletin
[patent document 8] Japanese Laid-Open Patent Publication 6-207379 bulletin
Summary of the invention
The present invention want solve project be, provide it is a kind of with it is corresponding in the high speed of the spinning process of synthetic fibers, manufacturing procedure in recent years, can be substantially prevented from fluffing, broken end and specking generation synthetic fibers inorganic agent and synthetic fibers processing method.
Therefore the present inventor is studied to solve aforementioned problems, as a result, it has been found that: the synthetic fibers inorganic agent preferably to scale containing the base oil composition being grouped as by specific 4 one-tenth adheres to such synthetic fibers inorganic agent by specified amount with respect to synthetic fibers.
That is, the present invention relates to:
A kind of synthetic fibers inorganic agent, which is characterized in that its following base oil composition for containing 70 weight % or more.
Base oil composition has following composition: it at being grouped as, and contains 50~90 weight % of the A ingredient by following A ingredient, B component, C ingredient and D；3~30 weight % of the B component；0.1~10 weight % of the C ingredient；0.1~20 weight % of the D ingredient (total 100 weight %),
A ingredient: selected from one of the alkylene oxide adducts for meeting following conditions 1~3 simultaneously or more than one,
Condition 1: it is the alkylene oxide adducts that a kind of number-average molecular weight is 1000~12000, the epoxyalkane that addition carbon atom number is 2~4 in the aliphatic alcohol that 1~3 yuan of carbon atom number is 1~24,
Condition 2: it is the alkylene oxide adducts with polyoxyalkylenes, wherein 10~80 weight % for forming its total oxyalkylene units are ethylene oxide units,
Condition 3: being the alkylene oxide adducts containing the 35 weight % of alkylene oxide adducts or more of addition ethylene oxide and propylene oxide in the aliphatic alcohol that 1 yuan of carbon atom number is 6~10,
B component: it is the alkylene oxide adducts that the number-average molecular weight that addition ethylene oxide or ethylene oxide and propylene oxide are formed in the aliphatic alcohol that 1 yuan of carbon atom number is 6~10 is 140~800, and for selected from one of alkylene oxide adducts with polyoxyalkylenes or more than one, wherein, constituting 30 weight % of its total oxyalkylene units, the above are ethylene oxide units；
C ingredient: its be selected from one of ionic surface active agent or more than one；
D ingredient, be selected from one of following surfactant or more than one, it may be assumed that addition ethylene oxide and propylene oxide, ether type nonionic surfactant that the number-average molecular weight of formation is 210~950 in the aliphatic alcohol that 1 yuan of carbon atom number is 11~24；In 1 yuan of carbon atom number for addition in 6~10 aliphatic alcohol ethylene oxide or propylene oxide, the ether type nonionic surfactant that the number-average molecular weight of formation is 900~2000；In 1 yuan of carbon atom number for addition in 11~24 aliphatic alcohol ethylene oxide or propylene oxide, the ether type nonionic surfactant that the number-average molecular weight of formation is 150~2500；In 1 yuan of carbon atom number for addition in 8~24 fatty acid ethylene oxide and/or propylene oxide, the ester type nonionic surfactant that the number-average molecular weight of formation is 200~2000；Addition ethylene oxide and/or propylene oxide in animal and plant fat, the nonionic surfactant that the number-average molecular weight of formation is 700~10000；In carbon atom number for addition in 8~24 aliphatic amine ethylene oxide and/or propylene oxide, the amino ether type nonionic surfactant that the number-average molecular weight of formation is 200~2500；In carbon atom number for addition in 8~24 aliphatic amide ethylene oxide and/or propylene oxide, the amide ether type nonionic surfactant that the number-average molecular weight of formation is 250~2500；The fatty acid partial ester that the aliphatic alcohol that carbon atom number by 2~6 yuan is 2~6 is 8~24 with carbon atom number, the partial ester type nonionic surfactant of formation；The fatty acid partial ester that the aliphatic alcohol that carbon atom number by 3~6 yuan is 3~6 is 8~24 with carbon atom number, addition ethylene oxide and/or propylene oxide in the partial ester of formation, the Etheric ester type nonionic surfactant that the number-average molecular weight of formation is 400~6000.
Moreover, it relates to a kind of processing method of synthetic fibers, which is characterized in that relative to synthetic fibers, synthetic fibers of the invention is made to adhere to 0.1~3 weight % with inorganic agent.
Firstly, being illustrated to synthetic fibers of the invention with inorganic agent (inorganic agent hereinafter referred to as of the invention).Inorganic agent of the invention is containing the substance by A ingredient, B component, C ingredient and D at the base oil composition being grouped as.In the ingredient for forming such base oil composition, A ingredient be selected from and meanwhile one of alkylene oxide adducts for meeting condition 1~3 or more than one.
For the condition 1 of A ingredient, alkylene oxide adducts are the alkylene oxide adducts that the number-average molecular weight for the epoxyalkane that addition carbon atom number is 2~4 in the aliphatic alcohol that 1~3 yuan of carbon atom number is 1~24 is 1000~12000.In such condition 1, the aliphatic alcohol that 1~3 yuan of carbon atom number is 1~24 can be enumerated: 1) the unitary linear saturation aliphatic alcohol such as methanol, ethyl alcohol, propyl alcohol, butanol, amylalcohol, hexanol, enanthol, octanol, nonyl alcohol, decyl alcohol, undecyl alcohol, lauryl alcohol, tridecanol, tetradecyl alchohol, pentadecanol, hexadecanol, heptadecanol, octadecyl alcolol, nonadecanol, eicosanol, two undecyl alcohols, docosanol, tricosanol, tetracosanol；2) the unitary branch representative examples of saturated aliphatic alcohol such as isopropanol, isobutanol, isoamyl alcohol, 2- methyl-pentanol, 2- ethyl-hexanol, 2- propyl-heptanol, 2- butyl-octanol, 2- amyl-nonyl alcohol, 2- hexyl-decyl alcohol, 2- heptyl-undecyl alcohol, 2- octyl-dodecanol, 2- nonyl-tridecanol, 2- decyl-tetradecanol, 2- undecyl-pentadecanol, 2- dodecyl-hexadecanol；3) 10- undecylenic alcohol, cis- 9- tetradecene alcohol, cis- 9- hexadecenol, cis- 9- oleyl alcohol, trans- 9- oleyl alcohol, suitable, cis- 9, it is 18 carbon dienol of 12-, suitable, it is suitable, cis- 9,12,15- octadecatrienol, cis- 9- gadoleyl alcohol, 5, the unitary straight chain unsaturated aliphatic alcohol such as 8,11,14- catadonyl alcohols, bis- lanolin alcohol of cis- 13-, bis- lanolin alcohol of trans- 13-；4) the dibasic aliphatics alcohol such as ethylene glycol, 1,2-PD, 1,3-PD, 1,4-butanediol, 1,6- hexylene glycol, neopentyl glycol；5) ternary aliphatics such as glycerol, trimethylolpropane race alcohol etc..
In addition, in condition 1, the epoxyalkane for being 2~4 as carbon atom number is specific for instance that ethylene oxide, propylene oxide, 1,2- propylene oxide, Isosorbide-5-Nitrae-propylene oxide etc., wherein optimization ethylene oxide, propylene oxide.These epoxyalkane can be used alone or as a mixture.When being used in mixed way, as opposite 1~3 yuan of carbon atom number be 1~24 aliphatic alcohol epoxyalkane addition mode for instance that random addition, block addition, random block addition.
The alkylene oxide adducts number-average molecular weight for meeting condition 1 described above is 1000~12000, but preferably 1000~10000.
For the condition 2 of A ingredient, alkylene oxide adducts are the alkylene oxide adducts with polyoxyalkylenes, wherein 10~80 weight % for forming its total oxyalkylene units are ethylene oxide unit.
For the condition 3 of A ingredient, alkylene oxide adducts have been the addition alkylene oxide adducts of ethylene oxide and propylene oxide in the aliphatic alcohol that 1 yuan of carbon atom number is 6~10 containing 35 weight % or more.In such condition 3, the aliphatic alcohol for being 6~10 as 1 yuan of carbon atom number can be enumerated: 1) the linear saturationes aliphatic alcohol such as hexanol, enanthol, octanol, nonyl alcohol, decyl alcohol；2) branches representative examples of saturated aliphatic alcohol such as 2- methyl-pentanol, 2- ethyl-hexanol, 2- propyl-heptanol etc..
A ingredient be selected from and meanwhile one of alkylene oxide adducts for meeting condition 1~3 described above or more than one.Wherein, such A ingredient preferably comprises the following E ingredients and F ingredient of 50 weight % of total amount or more, and the content ratio of the E ingredient and the F ingredient are as follows: the E ingredient/ingredient=50/50~90/10 F (weight ratio).
E ingredient: be 1 yuan carbon atom number be 6~10 aliphatic alcohol in, by number-average molecular weight made of the ratio addition of ethylene oxide and propylene oxide in ethylene oxide/propylene oxide=35/65~80/20 (weight ratio) for 1000~12000 alkylene oxide adducts；
F ingredient: be 1 yuan carbon atom number be 11~16 aliphatic alcohol in, by number-average molecular weight made of the ratio addition of ethylene oxide and propylene oxide in ethylene oxide/propylene oxide=10/90~80/20 (weight ratio) for 1000~12000 alkylene oxide adducts.
In E ingredient above-mentioned, the aliphatic alcohol for being 6~10 as 1 yuan of carbon atom number can be enumerated: 1) the linear saturationes aliphatic alcohol such as hexanol, enanthol, octanol, nonyl alcohol, decyl alcohol；2) branches representative examples of saturated aliphatic alcohol such as 2- methyl-pentanol, 2- ethyl-hexanol, 2- propyl-heptanol etc..
In F ingredient above-mentioned, the aliphatic alcohol for being 11~16 as 1 yuan of carbon atom number, it can enumerate: undecyl alcohol, lauryl alcohol, tridecanol, tetradecyl alchohol, pentadecanol, hexadecanol, 2- propyl-heptanol, 2- butyl-octanol, 2- amyl-nonyl alcohol, 2- hexyl-decyl alcohol, cis- 9- tetradecene alcohol, cis- 9- hexadecenol etc., wherein, the straight-chain aliphatics alcohol such as 70 moles of % or more lauryl alcohols, tridecanol, tetradecyl alchohol, pentadecanol, hexadecanols is preferably comprised.
As the alkylene oxide adducts of A ingredient described above itself, can be synthesized with well known method.Wherein for example: in aliphatic alcohol, in the presence of base catalyst, the method that makes the epoxyalkane of carbon atom number 2~4 gradually carry out polyaddition reaction.
B component is the addition epoxyalkane compound of ethylene oxide or ethylene oxide and propylene oxide in the aliphatic alcohol that 1 yuan of carbon atom number is 6~10.The aliphatic alcohol for being 6~10 as 1 yuan of carbon atom number, can enumerate: 1) the linear saturationes aliphatic alcohol such as hexanol, enanthol, octanol, nonyl alcohol, decyl alcohol；2) isooctanol, 2- methyl-pentanol, 2- ethyl-hexanol, 3, branches representative examples of saturated aliphatic alcohol such as 3,5- trimethyls-hexanol, 2- methyl-octanol, 2- propyl-heptanol etc..The number-average molecular weight of alkylene oxide adducts as B component is 140~800, preferably 200~700.In addition, the ratio of the ethylene oxide unit in total oxyalkylene units of the polyoxyalkylenes as composition alkylene oxide adducts, is 30 weight % or more, preferably 50 weight % or more.To fatty alcohol addition of ethylene oxide and propylene oxide to the mode of aliphatic alcohol, it is not particularly limited.
C ingredient is ionic surface active agent.Conventionally known substance can be used in such ionic surface active agent.Wherein for instance that 1) the organo-sulfates salt such as the organic sulfonates such as neopelex, polyoxyethylene laural base sodium sulfovinate, the organophosphorus esters salt such as polyoxygenated 1-isobutyl-3,5-dimethylhexylphosphoric acid potassium, the anionic surfactants such as organic fatties hydrochlorates such as enuatrol, alkenyl succinic potassium；2) cationic surfactants such as the quaternary ammonium salts such as dodecyl trimethyl ammonium sulfovinate, 2- heptadecene base-hydroxyethyl imidazole quinoline；3) two surfactants such as octyldimethyl ammonium acetate-(mono- ト of オ Network チ Le ジ メ チ Le ア ソ モ ニ オ ア セ タ), dodecyl alanine salt, lauryl amine oxide, wherein preferred anionic surfactant.
D ingredient is specific nonionic surfactant.In such nonionic surfactant comprising: 1) ether type nonionic surfactant that in aliphatic alcohol that 1 yuan of carbon atom number be 11~24 number-average molecular weight of addition ethylene oxide and propylene oxide be 210~950；2) the ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide or propylene oxide is 900~2000 in the aliphatic alcohol that 1 yuan of carbon atom number is 6~10；3) the ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide or propylene oxide is 150~2500 in the aliphatic alcohol that 1 yuan of carbon atom number is 11~24；4) the ester type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 200~2000 in the fatty acid that 1 yuan of carbon atom number is 8~24；5) nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 700~10000 in animal and plant fat；6) the amino ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 200~2500 in the aliphatic amine that carbon atom number is 8~24；7) the amide ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 250~2500 in the aliphatic amide that carbon atom number is 8~24；8) the partial ester type nonionic surfactant for crossing the aliphatic alcohol that 2~6 yuan of carbon atom number is 2~6 with the fatty acid partial ester that carbon atom number is 8~24；9) the Etheric ester type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 400~6000 in the partial ester that the fatty acid partial ester that the aliphatic alcohol for being 3~6 by 3~6 yuan of carbon atom number is 8~24 with carbon atom number is crossed.
For D ingredient, the ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and propylene oxide is 210~950 in the aliphatic alcohol that 1 yuan of carbon atom number is 11~24, it can enumerate: α-undecyl-ω-hydroxyl-polyoxyethylene polyoxypropylene, α-dodecyl-ω-hydroxyl-polyoxyethylene polyoxypropylene, α-tridecyl-omega-hydroxy-polyoxyethylene polyoxypropylene, α-myristyl-ω-hydroxyl-polyoxyethylene polyoxypropylene, α-pentadecyl-ω-hydroxyl-polyoxyethylene polyoxypropylene, α-cetyl-ω-hydroxyl-polyoxyethylene polyoxypropylene, α-heptadecyl-ω-hydroxyl-polyoxyethylene polyoxypropylene, α-octadecyl-ω-hydroxyl-polyoxyethylene polyoxypropylene, α-octadecenyl-co-hydroxy-polyoxyethylene Polyoxypropylene, α-nonadecyl-ω-hydroxyl-polyoxyethylene polyoxypropylene, α-eicosyl-ω-hydroxyl-polyoxyethylene polyoxypropylene, α-eicosylene base-ω-hydroxyl-polyoxyethylene polyoxypropylene, α-docosyl-ω-hydroxyl-polyoxyethylene polyoxypropylene etc..
For D ingredient, as the ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide or propylene oxide is 900~2000 in the aliphatic alcohol that 1 yuan of carbon atom number is 6~10, can enumerate: α-hexyl-ω-hydroxyl-polyoxyethylene, α-octyl-ω-hydroxyl-polyoxyethylene, α-nonyl-ω-hydroxyl-polyoxyethylene, alpha-decyl-ω-hydroxyl-polyoxyethylene, α-hexyl-ω-hydroxyl-polyoxypropylene, α-octyl-ω-hydroxyl-polyoxypropylene, α-nonyl-ω-hydroxyl-polyoxypropylene, alpha-decyl-ω-hydroxyl-polyoxypropylene etc..
For D ingredient, as the ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide or propylene oxide is 150~2500 in the aliphatic alcohol that 1 yuan of carbon atom number is 11~24, it can enumerate: α-undecyl-ω-hydroxyl-polyoxyethylene, α-dodecyl-ω-hydroxyl-polyoxyethylene, α-tridecyl-omega-hydroxy-polyoxyethylene, α-myristyl-ω-hydroxyl-polyoxyethylene, α-pentadecyl-ω-hydroxyl-polyoxyethylene, α-cetyl-ω-hydroxyl-polyoxyethylene, α-heptadecyl-ω-hydroxyl-polyoxyethylene, α-octadecyl-ω-hydroxyl-polyoxyethylene, α-octadecenyl-co-hydroxy-polyoxyethylene, α-nonadecyl-ω-hydroxyl-polyoxyethylene, α-eicosyl-ω-hydroxyl Polyoxyethylene, α-eicosylene base-ω-hydroxyl-polyoxyethylene, α-docosyl-ω-hydroxyl-polyoxyethylene, α-undecyl-ω-hydroxyl-polyoxypropylene, α-dodecyl-ω-hydroxyl-polyoxypropylene, α-tridecyl-omega-hydroxy-polyoxypropylene, α-myristyl-ω-hydroxyl-polyoxypropylene, α-pentadecyl-ω-hydroxyl-polyoxypropylene, α-cetyl-ω-hydroxyl-polyoxypropylene, α-heptadecyl-ω-hydroxyl-polyoxypropylene, α-octadecyl-ω-hydroxyl-polyoxypropylene, α-octadecenyl-co-hydroxy-polyoxypropylene, α-nonadecyl-ω-hydroxyl-polyoxypropylene, α-eicosyl-ω-hydroxyl-polyoxypropylene, α-eicosylene base-ω-hydroxyl-polyoxypropylene, α-docosyl- ω-hydroxyl-polyoxypropylene etc..
For D ingredient, as the ester type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 200~2000 in the fatty acid that 1 yuan of carbon atom number is 8~24, it can enumerate: sad (polyoxyethylene) ester, lauric acid (polyoxyethylene) ester, myristic acid (polyoxyethylene) ester, palmitinic acid (polyoxyethylene) ester, stearic acid (polyoxyethylene) ester, oleic acid (polyoxyethylene) ester, linoleic acid (polyoxyethylene) ester, erucic acid (polyoxyethylene) ester, ricinoleic acid (polyoxyethylene) ester, lignoceric acid (polyoxyethylene) ester, sad (polyoxyethylene polyoxypropylene) ester, lauric acid (polyoxyethylene polyoxypropylene) ester, myristic acid (polyoxyethylene polyoxypropylene) ester, palmitinic acid (polyoxyethylene polyoxypropylene) ester, stearic acid (polyoxyethylene polyoxy third Alkene) ester, oleic acid (polyoxyethylene polyoxypropylene) ester, linoleic acid (polyoxyethylene polyoxypropylene) ester, erucic acid (polyoxyethylene polyoxypropylene) ester, ricinoleic acid (polyoxyethylene polyoxypropylene) ester, lignoceric acid (polyoxyethylene polyoxypropylene) ester, lauric acid (polyoxypropylene) ester, myristic acid (polyoxypropylene) ester, palmitinic acid (polyoxypropylene) ester, stearic acid (polyoxypropylene) ester, oleic acid (polyoxypropylene) ester etc..
For D ingredient, as the nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 700~10000 in animal and plant fat, can enumerate: 1) ethylene oxide and/or propylene oxide adduct of the vegetable fat such as soybean oil, sunflower oil, cottonseed oil, sesame oil, rapeseed oil, rice bran oil, castor oil, hardened castor oil, palm oil, palm-kernel oil, coconut oil；2) ethylene oxide and/or propylene oxide adduct of the animal fats such as butter, lard, sheep oil.
For D ingredient, as the amino ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 200~2500 in the aliphatic amine that carbon atom number is 8~24, it can enumerate: N, bis- (2- ethoxy) octylames of N-, N, bis- (2- ethoxy) nonyl amines of N-, N, bis- (2- ethoxy) lauryl amines of N-, N, bis- (2- ethoxy) the nutmeg amine of N-, N, bis- (2- ethoxy) cetylamines of N-, N, bis- (2- ethoxy) stearylamines of N-, N, N- bis- (2- ethoxys) 20 amine (ア ラ キ ニ Le ア ミ Application), N- (2- ethoxy) dioctylamine, N- (2- ethoxy) nonyl amine, N- (2- ethoxy) dilaurylamine (DLA), two nutmeg amine of N- (2- ethoxy), N- (2- hydroxyl Ethyl) two cetylamines, N- (2- ethoxy) distearyl amine, N, bis- (2- hydroxypropyl) octylames of N-, N, bis- (2- hydroxypropyl) nonyl amines of N-, N, bis- (2- hydroxypropyl) lauryl amines of N-, N, bis- (polyoxyethylene) octylames of N-, N, bis- (polyoxyethylene) nonyl amines of N-, N, bis- (polyoxyethylene) lauryl amines of N-, N, bis- (polyoxyethylene) the nutmeg amine of N-, N, bis- (polyoxyethylene) cetylamines of N-, N, bis- (polyoxyethylene) stearylamines of N-, N, bis- (polyoxyethylene) 20 amine of N-, N- (polyoxyethylene) dioctylamine, N- (polyoxyethylene) nonyl amine, N- (polyoxyethylene) dilaurylamine (DLA), two nutmeg amine of N- (polyoxyethylene), two cetylamine of N- (polyoxyethylene), N- (polyoxyethylene) distearyl amine, N, N- is bis- (poly- Ethylene oxide polypropylene) octylame, N, bis- (polyoxyethylene polypropylene) nonyl amines of N-, N, bis- (polyoxyethylene polypropylene) lauryl amines of N-, N, bis- (polyoxyethylene polypropylene) the nutmeg amine of N-, N, bis- (polyoxyethylene polypropylene) cetylamines of N-, N, bis- (polyoxyethylene polypropylene) stearylamines of N-, N, bis- (polypropylene) octylames of N-, N, bis- (polypropylene) nonyl amines of N-, N, bis- (polypropylene) lauryl amines of N-, N, bis- (polypropylene) the nutmeg amine of N-, N, bis- (polypropylene) cetylamines of N-, N, bis- (polypropylene) stearylamines of N- etc..
For D ingredient, as the amide ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 250~2500 in the aliphatic amide that carbon atom number is 8~24, it can enumerate: N, bis- (ethoxy) caprylamides of N-, N, bis- (ethoxy) lauramides of N-, N, bis- (ethoxy) kemanide Ss of N-, N, bis- (ethoxy) octadecenamides of N-, N, bis- (ethoxy) Erucamides of N-, N, bis- (polyoxyethylene) caprylamides of N-, N, bis- (polyoxyethylene) lauramides of N-, N, bis- (polyoxyethylene) kemanide Ss of N-, N, bis- (polyoxyethylene) octadecenamides of N-, N, bis- (polyoxyethylene) Erucamides of N-, N, bis- (polyoxyethylene polyoxypropylene) caprylamides of N- , N, bis- (polyoxyethylene polyoxypropylene) lauramides of N-, N, bis- (polyoxyethylene polyoxypropylene) kemanide Ss of N-, N, bis- (polyoxyethylene polyoxypropylene) octadecenamides of N-, N, bis- (polyoxyethylene polyoxypropylene) Erucamides of N-, N, bis- (polyoxypropylene) caprylamides of N-, N, bis- (polyoxypropylene) lauramides of N-, N, bis- (polyoxypropylene) kemanide Ss of N-, N, bis- (polyoxypropylene) octadecenamides of N-, N, bis- (polyoxypropylene) Erucamides of N- etc..
For D ingredient, it as the partial ester type nonionic surfactant that the aliphatic alcohol for being 2~6 by 2~6 yuan of carbon atom number is crossed with the fatty acid partial ester that carbon atom number is 8~24, can enumerate: 1) partial ester of the ethylene glycol such as ethylene glycol monolaurate, glycol monopalmitate, ethylene glycol monoleate, ethylene glycol docosane acid esters；2) partial ester of the propylene glycol such as propylene glycol list myristinate, propylene glycol monopalmitate, propylene glycol monostearate, propylene glycol mono-oleate；3) partial ester of the glycerol such as glyceryl monolaurate, glycerol monopalmitate, Monoolein, glyceryl monolinoleate, dilaurin, diolein, dilinolein, glycerol monolaurate myristinate, glycerol palm acid ester stearate；4) partial ester of the trimethylolpropanes such as trimethylolpropane monolaurate, trimethylolpropane monopalmitate, trimethylolpropane monoleate, trimethylolpropane list docosane acid esters；5) partial ester of the pentaerythrites such as pentaerythrite list myristinate, pentaerythrite list tetradecene ester ester, pentaerythritol monooleate, pentaerythrite dilaurate, pentaerythrite dilinoleic acid ester, pentaerythrite laurate myristinate, pentaerythrite trioleate, pentaerythrite dilaurate myristinate, two palm acid ester stearate of pentaerythrite, two palm acid ester oleate of pentaerythrite；6) partial ester of the diglycerols such as diglycerol monolaurate, diglyceryl monooleate, diglycerol dipalmitate, diglycerol trilaurin, diglycerol dilaurate myristinate, two palm acid ester of diglycerol stearate；7) sorbitan monolaurate, sorbitan monosterate, dehydrating sorbitol monooleate, anhydrosorbitol list linoleate, two myristinate of anhydrosorbitol, anhydrosorbitol dipalmitate, anhydrosorbitol dioleate, anhydrosorbitol palm acid ester, anhydrosorbitol tripalmitate, anhydrosorbitol trioleate, three linoleate of anhydrosorbitol, anhydrosorbitol dilaurate myristinate, the partial ester of the anhydrosorbitols such as two palm acid ester of anhydrosorbitol；8) partial ester of the triglycerins such as triglycerol monolaurate, Triglyceryl monooleate, triglycerin dioleate, triglycerin trilaurin, triglycerin trioleate, triglycerin palm acid ester dioleate；9) partial ester of four glycerol such as four glyceryl monolaurates, four Monooleins, four dioleins；10) partial ester of dipentaerythritols such as dipentaerythritol list myristinate, dipentaerythritol list linoleate, dipentaerythritol dioleate etc..
For D ingredient, as the Etheric ester type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 400~6000 in the partial ester that the fatty acid partial ester that the aliphatic alcohol for being 3~6 by 3~6 yuan of carbon atom number is 8~24 with carbon atom number is crossed, can enumerate: the ethylene oxide and/or propylene oxide adduct of the partial esters such as glycerol partial ester, trimethylolpropane partial ester, pentaerythrite partial ester, diglycerol partial ester, two glycerin ether partial ester of ethylene glycol, anhydrous sorbitol partial ester, triglycerin partial ester, four glycerol partial esters, dipentaerythritol partial ester.
Inorganic agent of the invention is by the material composition containing 70 weight % of base oil composition or more, the base oil composition contains 50~90 weight % of A ingredient as described above, 3~30 weight %, C ingredient of B component, 0.1~10 weight % and D ingredient, 0.1~20 weight % (total 100 weight %), it is preferred that the base oil composition contains by the material composition containing 80 weight % of base oil composition or more: 55~90 weight % of the A ingredient, 1~20 weight % of 5~20 weight % of the B component, 0.3~5 weight % of the C ingredient and the D ingredient (total 100 weight %).
Inorganic agent of the invention further preferably contains following G components.
G component: be selected from one of the aliphatic ester compound that is indicated with followingization 1 and the aliphatic ester compound indicated with following chemical formula 2 or more than one,
[changing 1]
R1-X-R2
[changing 2]
R3-R4
Changing 1 and changing in 2,
R1, R3: the residue after removing hydrogen atom in the aliphatic monobasic alcohol that carbon atom number is 8~18；
R2: the residue after removing hydrogen atom in the aliphatic monocarboxylic acid that carbon atom number is 8~18；
R4: the residue after removing hydroxyl in the aliphatic monocarboxylic acid that carbon atom number is 8~18；
X: the residue after removing whole hydroxyls in (poly-) the alkane glycol with (poly-) oxyalkylene group formed with total 1~10 ethylene oxide unit and/or propylene oxide unit.
R in the aliphatic ester compound indicated with chemical formula 1, in chemical formula 11Refer to and removes the residue after hydrogen atom in the aliphatic monobasic alcohol for being 8~18 from carbon atom numbers such as octanol, laruyl alcohol, tridecanol, tetradecyl alchohol, hexadecanol, octadecyl alcolol, oleyl alcohol.In addition, the R in chemical formula 12Refer to and removes the residue after hydrogen atom in the Aliphatic monoacid for being 8~18 from carbon atom numbers such as caproic acid, octanoic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitinic acid, stearic acid, palmitoleic acid, oleic acid, isooctyl acid, different hexadecylic acid, different stearic acids.Moreover, the X in chemical formula 1 refers to the residue after removing whole hydroxyls in (poly-) the alkane glycol with (poly-) oxyalkylene group formed with total 1~10 ethylene oxide unit and/or propylene oxide unit.It can be enumerated as such residue: 1) residue after removing whole hydroxyls in (poly-) ethylene glycol with (poly-) Oxyranyle formed with 1~10 ethylene oxide unit；2) residue after removing whole hydroxyls in (poly-) propylene glycol with (poly-) the propylene oxide base formed with 1~10 propylene oxide unit；3) residue after removing whole hydroxyls in (poly-) the alkane glycol having with (poly-) ethylene oxide (poly-) the propylene oxide base for amounting to 2~10 ethylene oxide units and/or propylene oxide unit composition.
R in the aliphatic ester compound indicated with change 2, in chemical formula 23With the R in chemical formula 1 above-mentioned1It is identical.In addition, the R in chemical formula 24Refer to and removes the residue after hydrogen atom in the Aliphatic monoacid for being 8~18 from carbon atom numbers such as caproic acid, octanoic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitinic acid, stearic acid, palmitoleic acid, oleic acid, isooctyl acid, different hexadecylic acid, different stearic acids.
When containing G component described above, with respect to 100 parts by weight of base oil composition, the contained ratio of the G component is 5~40 parts by weight in inorganic agent of the invention, but the contained ratio of the preferably G component is 5~30 parts by weight.
Inorganic agent of the invention further preferably contains following H ingredients and/or I ingredient.
H ingredient: polyoxyalkylene-modified organosilicon and/or dimethyl organosilicon；
I ingredient: selected from one of phenol antioxidant, phosphite antioxidant and thioether antioxidants or more than one.
H ingredient is for instance that 1) polyoxyalkylene-modified organosilicon；2) dimethyl organosilicon；1) and 2) 3) aforementioned mixture, preferably 1) polyoxyalkylene-modified organosilicon.Aforementioned polyoxyalkylene-modified organosilicon 1), it is the polyoxyalkylene-modified organosilicon with polyoxyalkylenes, wherein, the ethylene oxide unit for forming it is ethylene oxide unit and/or propylene oxide unit, also, it is preferred that content ratio is the polyoxyalkylene-modified organosilicon of polyoxyalkylenes/organosilicon chain=25/75~90/10 (weight ratio).Such polyoxyalkylene-modified organosilicon can be enumerated: 1) polyoxyethylene-modified organosilicon；2) polyoxypropylene modified organic silicon；3) polyoxyethylene polyoxypropylene modified organic silicon, wherein the 25 weight % or more more preferably with the total oxyalkylene units for forming it are the substances of the polyoxyalkylenes of ethylene oxide unit.In preferably polyoxyalkylene-modified organosilicon described above, it is preferred that its content ratio is polyoxyalkylenes/organosilicon chain=25/75~90/10 (weight ratio), its more preferable content ratio is polyoxyalkylenes/organosilicon chain=30/70~85/15 (weight ratio).In addition, its number-average molecular weight is preferably 2500~50000.
In addition, the dimethyl organosilicon of H ingredient is preferred are as follows: 30 DEG C of viscosity is 1 × 10-6~1 × 10-4m2The linear dimethyl organosilicon of/s.
I ingredient can be enumerated: 1) phenol antioxidant；2) phosphite antioxidant；3) thioether antioxidants；4) it is aforementioned 1)~3) more than one mixture, preferred 1) phenol antioxidant.
The phenol antioxidant of I ingredient is all well known, can enumerate: triethylene glycol-is bis- [3- (3- tert-butyl -5- methyl -4- hydroxy benzenes) base propionic ester], 1, 3, 5- trimethyl -2, 4, 6- tri- (3, 5- di-tert-butyl-4-hydroxyl benzyl) benzene, 1, 6- hexylene glycol-bis- [3- (3, 5- di-tert-butyl-hydroxy phenyl) propionic ester], [the 3- (3 of pentaerythrite-four, 5- di-tert-butyl-hydroxy phenyl) propionic ester], 2, 2 '-methylene-bis--(6- tert-butyl-4-methyl-Phenol), 2, 2 '-butylidenes-bis--(6- tert-butyl-4-methyl-Phenol), 1, 1, 3- tri- (2- methyl -4- hydroxyl -5- tert-butyl phenol) butane, 1, 3, 5- tri- (3 ', 5 '-di-t-butyl -4- Hydroxybenzyl) cyamelide, 1,3,5- tri- (4- butyl -3- hydroxyl -2,6- dimethyl benzyl) cyamelides etc..
The phosphite antioxidant of I ingredient is all well known, it can enumerate: octyl diphenyl phosphite ester, trisnonylphenyl phosphite, four-tridecyl -4,4 '-butanes-bis--(2- tert-butyl -5- cresols) diphosphites, (dinonylphenyl) phosphite ester, two (to nonyl phenyl) phosphite esters etc..
The thioether antioxidants of I ingredient be all it is well known, can enumerate: 4,4 '-thiobis-(6- tert-butyl -3- cresols), 3,3 '-thiodipropionate of dilauryl-etc..
When containing H ingredient described above and/or I ingredient, opposite 100 parts by weight of base oil composition, total ratio containing the H ingredient and/or the I ingredient in inorganic agent of the invention is 0.3~6 parts by weight, but it is 0.5~3 parts by weight that the content ratio of the preferably H ingredient, which is the content ratio of 0.5~3 parts by weight and the I ingredient,.
In the range of without detriment to effect of the invention, inorganic agent of the invention can contain other ingredients.Such ingredient can be enumerated: the various adjuvants such as lubricant, defoaming agent, preservative, antirust agent of emulsification regulator, mineral oil etc..
Then, the processing method of synthetic fibers of the invention (following to be only known as processing method of the invention) is illustrated.Processing method of the invention is to instigate inorganic agent of the invention as described above with respect to the method for 0.1~3 weight % of synthetic fibers, preferably 0.3~1.2 weight % attachment.Inorganic agent of the invention, which is attached to the process on synthetic fibers, to be enumerated: spinning process, spinning and stretching while the process carried out etc..In addition, inorganic agent of the invention, which is attached to the method on synthetic fibers, to be enumerated: roller to oil process, using the guiding device of metering pump to oil process, dipping to oil process, spraying to oil process etc..Moreover, mode when inorganic agent of the invention is attached on synthetic fibers can be enumerated: directly using inorganic agent (mono- ト of ニ), organic solvent solution, the aqueous solution etc., preferably aqueous solution, wherein the preferably aqueous solution of 5~30 weight %.When the aqueous solution of inorganic agent of the invention is adhered to, opposite synthetic fibers make 0.1~3 weight % of adhesion amount, preferably 0.3~1.2 weight % of inorganic agent of the invention.
The synthetic fibers of the applicable object of processing method of the present invention can be enumerated: 1) polyester fibers such as polyethylene terephthalate, polytrimethylene terephthalate, poly-lactic acid ester；2) polyamide fibers such as nylon 6, nylon66 fiber；3) polyacrylic fibers such as polyacrylic acid, modified acroleic acid；4) polyolefin fibrids such as polyethylene, polypropylene, polyurethane fiber etc., wherein when being applied to polyester fiber or polyamide fiber, effect of the invention is good.
As described above, carried out present invention mentioned above have the effect that can with it is corresponding in the high speed of the spinning process of synthetic fibers, manufacturing procedure in recent years, be substantially prevented from the generation of fluffing and broken end and specking.
In the following, enumerating embodiment etc., but the present invention is not limited to these embodiments to further illustrate composition and effect of the invention.It should be noted that part indicates that parts by weight, % indicate weight % in following Examples and Comparative Examples.
Embodiment
Test classification 1 (preparation of synthetic fibers inorganic agent)
Embodiment 1 { preparation of synthetic fibers inorganic agent (P-1) }
By the uniformly mixing of 10 parts of 75 parts following of A ingredients, 13 parts of B component, 2 parts of C ingredient and D ingredient, 100 parts of base oil composition are prepared, using it as synthetic fibers inorganic agent (P-1).
A ingredient: being a kind of mixture of polyether-type monohydric alcohol=40/20/15 (weight ratio) that polyether-type monohydric alcohol/number-average molecular weight that polyether-type monohydric alcohol/number-average molecular weight that number-average molecular weight is 1000 is 3000 is 3500, wherein, the polyether-type monohydric alcohol that number-average molecular weight is 1000 is in 2-Ethylhexyl Alcohol by ethylene oxide (hereinafter referred to as EO) and propylene oxide (hereinafter referred to as PO), it is formed in the random addition of the ratio of EO/PO=40/60 (weight ratio), the polyether-type monohydric alcohol that number-average molecular weight is 3000 is to form EO and PO in the random addition of ratio of EO/PO=50/50 (weight ratio) in butanol, the polyether-type monohydric alcohol that number-average molecular weight is 3500 is by EO and PO in laruyl alcohol by EO/PO= The random addition of ratio of 70/30 (weight ratio) and formed.
B component: being every 1 mole 3, the EO of 5,5- 5 moles of trimethyl hexanol additions and the alkylene oxide adducts that are formed.
C ingredient: phosphate potassium/cis-9-octadecenoic acid potassium=0.5/1/0.5 (weight ratio) mixture of decane sulfonic acid potassium/α-dodecyl-ω-hydroxyl poly- (ethylene oxide) (repeat number of ethylene oxide unit is 3, hereinafter referred to as n=3).
D ingredient: the mixture of nonionic surfactant=5/5 (weight ratio) made of nonionic surfactant made of every 7 moles of 1 mole of cis-9-octadecenoic acid addition of EO/every 20 moles of 1 mole of hardened castor oil addition of EO.
Embodiment 2~36 and comparative example 1~28 { preparation of synthetic fibers inorganic agent (P-2)~(P-36) and (R-1)~(R-28) }
It is equally operated with the synthetic fibers of embodiment 1 with inorganic agent (P-1), prepares synthetic fibers inorganic agent and (R-1)~(R-28) of synthetic fibers inorganic agent (P-2)~(P-36) and the comparative example 1~28 of embodiment 2~36.The content of the ingredient of the synthetic fibers inorganic agent of above each example is used to prepare as shown in 1~table of table 8, in addition, the content of the synthetic fibers inorganic agent prepared in above each example is as shown in 9~table of table 18.
[table 1]
| A ingredient type | Aliphatic alcohol for synthesis | Alkylene oxide adducts | ||||||
| Type | First number | Carbon atom number | Linear chain or branched chain | The type of AO | EO ratio (%) | Number-average molecular weight | E ingredient or F ingredient | |
| A-1 A-2 A-3 A-4 A-5 A-6 A-7 A-8 A-9 A-10 | The different hexadecanol propylene glycol of 2-Ethylhexyl Alcohol decyl alcohol 2-Ethylhexyl Alcohol hexanol butanol octadecyl alcolol trimethylolpropane lauryl alcohol | 1 1 1 1 1 1 3 1 1 2 | 8 10 8 6 4 18 6 12 16 3 | Branch straight chain branch straight chain straight chain straight chain branch straight chain branch straight chain | EO/PO EO/PO EO/PO/BO EO/PO EO/PO EO/PO EO/PO EO/PO EO/PO EO/PO | 40 60 20 75 50 40 40 70 30 25 | 1000 2500 3000 1000 3000 2000 6000 3500 2000 2000 | E ingredient E ingredient E ingredient F ingredient F ingredient |
| a-1 a-2 a-3 | Anhydrosorbitol glycerol butanol | 4 3 1 | 6 3 4 | Branch straight chain straight chain | EO/PO EO/PO EO/BO | 40 30 90 | 1500 20000 2000 | |
In table 1,
The type of AO: the type of the epoxyalkane of addition in aliphatic alcohol
EO ratio: the ratio (%) of the EO in AO
EO: ethylene oxide
PO: propylene oxide
BO: ring fourth propane
[table 2]
| B component type | Aliphatic alcohol for synthesis | Alkylene oxide adducts | ||||
| Type | First number | Carbon atom number | The type of AO | EO ratio (%) | Number-average molecular weight | |
| B-1 B-2 B-3 B-4 | 3,3,5- trimethyl hexanol 2- methyl-octanol 2-Ethylhexyl Alcohol hexanols | 1 1 1 1 | 9 9 8 6 | EO EO EO/PO EO | 100 100 50 100 | 350 660 400 530 |
[table 3]
| C ingredient type | Type | Chemical combination name |
| C-1 C-2 C-3 C-4 C-5 C-6 | Anionic anionic anion cationically ampholytic anion | The phosphate potassium of decane sulfonic acid potassium α-dodecyl-ω-hydroxyl (polyoxyethylene) (n=3) phosphate potassium cis-9-octadecenoic acid potassium tributyl-methyl phosphonium ammonium diethylphosphate Dimethyl Lauryl Amine oxide tetracosanol |
[table 4]
| D ingredient type | Chemical combination name | Number-average molecular weight | The carbon atom number of starting material for synthesis | Type |
| D-1 D-2 D-3 D-4 D-5 D-6 D-7 D-8 D-9 | ω-hydroxyl (polyoxyethylene) (n=7) octadecene acid esters ω-hydroxyl (polyoxyethylene) (n=20) hardened castor oil α-dodecyl-ω-hydroxyl (polyoxyethylene polyoxypropylene) (m=3, n=4) α -2- ethylhexyl-ω-hydroxyl (polyoxyethylene) (n=20) α-dodecyl-ω-hydroxyl (polyoxyethylene) (n=7) N, bis- (polyoxyethylene) lauryl amine (n=10) N of N-, the ethylene oxide adduct (n=10) of the diisopstearate of bis- (polyoxyethylene) lauramide (n=10) the dehydrating sorbitol monooleate trimethylolpropanes of N- | 590 1820 540 1010 480 620 640 430 1070 | 18 57 12 8 12 12 12 6 6 | Ester type comes from grease type ether type ether type ether type amino ether type amide ether type partial ester type Etheric ester type |
In table 4,
N: the repeat number of ethylene oxide unit
M: the repeat number of propylene oxide unit
Similarly hereinafter
[table 5]
| G component type | Change 1 or changes the 2 aliphatic ester compounds indicated | ||||
| R1 | R2 | R3 | R4 | X | |
| G-1 G-2 | Lauryl | Nonyl phosphinylidyne oxygroup | Lauryl | Caprylyl | Polyoxyethylene (6 moles) |
[table 6]
| H ingredient type | Content |
| H-1 H-2 H-3 | Polyoxyalkylenes/organosilicon chain=70/30 (weight ratio), ethylene oxide unit/propylene oxide unit=50/50 (molar ratio), polyoxyalkylenes modified organic silicon polyoxyalkylenes/organosilicon chain=35/65 (weight ratio) of number-average molecular weight 16000, ethylene oxide unit/propylene oxide unit=20/80 (molar ratio), number-average molecular weight 11000 30 DEG C of polyoxyalkylenes modified organic silicon of viscosity be 1 × 10-5m2The dimethyl organosilicon of/s |
[table 7]
| I ingredient type | Chemical combination name | Type |
| I-1 I-2 I-3 I-4 | 1,3,5- tri- (4- butyl -3- hydroxyl -2,6- dimethyl benzyl) cyamelide, 2,2 '-methylene-bis- (4- methyl-6-tert-butylphenol) octyl diphenyl phosphite esters dilauryl -3,3 '-thiodipropionates | Phenolic antioxidants phenolic antioxidants phosphite antioxidant thioether antioxidants |
[table 8]
| Other ingredients | Chemical combination name |
| J-1 J-2 J-3 | The viscosity that 30 DEG C of glycol adipic acid diisodecyl ester is 2.4 × 10-5m2The mineral oil of/s |
[table 9]
| Subregion | Type | A ingredient | B component | C ingredient | D ingredient | Other ingredients | *1 | |||||
| Type | Dosage | Type | Dosage | Type | Dosage | Type | Dosage | Type | Dosage | |||
| Embodiment 123456789 10 11 12 | P-1 P-2 P-3 P-4 P-5 P-6 P-7 P-8 P-9 P-10 P-11 P-12 | A-1 A-5 A-8 A-2 A-5 A-8 A-1 A-3 A-8 A-4 A-5 A-8 A-1 A-5 A-8 A-1 A-1 A-5 A-9 A-1 A-5 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-6 A-8 A-1 A-7 A-8 | 40 20 15 40 20 15 40 20 15 40 20 15 20 40 15 75 40 20 15 40 35 40 25 10 40 13 22 40 20 15 40 20 15 | B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 | 13 13 13 13 13 13 13 13 13 13 13 13 | C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 | 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 | D-1 D-2 D-1 D-2 D-2 D-5 D-1 D-8 D-9 D-1 D-2 D-1 D-2 D-1 D-7 D-2 D-6 D-1 D-2 D-1 D-2 D-1 D-2 D-1 D-2 | 5 5 5 5 5 5 5 3 2 5 5 5 5 8 2 7 3 5 5 5 5 5 5 5 5 | J-1 | 2 | 100 100 100 100 100 100 100 100 100 100 100 98.0 |
[table 10]
| Subregion | The composition (%) of base oil composition | The ratio (part) of opposite 100 parts of base oil composition | The detail of A ingredient | |||||||
| A ingredient | B ingredient | C ingredient | D ingredient | G ingredient | H ingredient | I ingredient | *2 | *3 | *4 | |
| Embodiment 123456789 10 11 12 | 75 75 75 75 75 75 75 75 75 75 75 75 | 13 13 13 13 13 13 13 13 13 13 13 13 | 2 2 2 2 2 2 2 2 2 2 2 2 | 10 10 10 10 10 10 10 10 10 10 10 10 | 0 0 0 0 0 0 0 0 0 0 0 0 | 0 0 0 0 0 0 0 0 0 0 0 0 | 0 0 0 0 0 0 0 0 0 0 0 0 | 53.3 53.3 80 53.3 26.7 100 53.3 53.3 53.3 53.3 53.3 53.3 | 73.3 73.3 73.3 73.3 46.6 100 73.3 53.3 50 82.7 73.3 73.3 | 2.7 2.7 2.7 2.7 1.3 100 2.7 100 4 1.8 2.7 2.7 |
[table 11]
| Subregion | Type | A ingredient | B component | C ingredient | D ingredient | Other ingredients | *1 | |||||
| Type | Dosage | Type | Dosage | Type | Dosage | Type | Dosage | Type | Dosage | |||
| Embodiment 13 14 15 16 17 18 19 20 21 22 23 24 | P-13 P-14 P-15 P-16 P-17 P-18 P-19 P-20 P-21 P-22 P-23 P-24 | A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 | 30 20 10 40 25 20 40 20 15 40 20 15 40 25 15 40 25 15 35 16 12 40 20 15 40 20 16.4 40 20 16.8 40 16 13 40 25 15 | B-1 B-1 B-2 B-3 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 | 20 10 13 13 8 4 25 13 13 13 13 16 | C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-4 C-5 C-1 C-2 C-1 C-1 C-2 C-3 C-1 C-2 C-3 | 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 1 1 0.3 0.3 0.2 3 3 2 0.5 1 0.5 | D-1 D-2 D-3 D-2 D-1 D-2 D-1 D-2 D-2 D-5 D-1 D-2 D-3 D-1 D-2 D-1 D-7 D-8 D-1 D-2 D-1 D-2 D-1 D-2 D-5 | 5 5 8 3 5 5 5 5 5 5 5 5 4 5 5 5 1 4 5 5 5 5 5 5 2 | 100 100 100 100 100 100 100 100 100 100 100 100 | ||
[table 12]
| Subregion | The composition (%) of base oil composition | The ratio (part) of opposite 100 parts of base oil composition | The detail of A ingredient | |||||||
| A ingredient | B ingredient | C ingredient | D ingredient | G ingredient | H ingredient | I ingredient | *2 | *3 | *4 | |
| Embodiment 13 14 15 16 17 18 19 20 21 22 23 24 | 60 85 75 75 80 80 63 75 76.4 76.8 69 80 | 20 10 13 13 8 4 25 13 13 13 13 16 | 2 2 2 2 2 2 2 2 0.6 0.2 8 2 | 18 3 10 10 10 14 10 10 10 10 10 2 | 0 0 0 0 0 0 0 0 0 0 0 0 | 0 0 0 0 0 0 0 0 0 0 0 0 | 0 0 0 0 0 0 0 0 0 0 0 0 | 50 47 53.3 53.3 50 50 55.6 53.3 52.4 52.1 58.0 50 | 66.7 70.6 73.3 73.3 68.8 68.8 74.6 73.3 73.4 74.0 76.8 68.8 | 3.0 2.0 2.7 2.7 2.7 2.7 2.9 2.7 2.4 2.4 3.1 2.7 |
[table 13]
| Subregion | Type | A ingredient | B component | C ingredient | D ingredient | Other ingredients | *1 | |||||
| Type | Dosage | Type | Dosage | Type | Dosage | Type | Dosage | Type | Dosage | |||
| Embodiment 25 26 27 28 29 30 31 32 33 34 35 36 | P-25 P-26 P-27 P-28 P-29 P-30 P-31 P-32 P-33 P-34 P-35 P-36 | A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-2 A-5 A-9 A-2 A-5 A-8 | 40 20 15 36 18 13 40 20 15 40 20 15 40 20 15 40 20 15 40 20 15 40 20 15 40 20 15 40 20 15 40 20 15 40 20 15 | B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 | 17.5 13 13 13 13 13 13 13 13 13 13 13 | C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 | 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 | D-3 D-1 D-2 D-3 D-2 D-5 D-1 D-2 D-1 D-2 D-1 D-2 D-1 D-2 D-1 D-2 D-1 D-2 D-1 D-2 D-3 D-5 D-3 | 0.5 6 6 6 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 10 | G-1 G-2 G-2 G-2 J-2 H-1 I-1 H-2 H-1 I-2 I-3 G-2 H-1 I-1 G-1 G-2 H-3 I-4 G-2 H-2 I-1 J-1 | 15 25 6 35 5 1 1 0.5 2 1.5 1.5 20 1 1 5 10 1 1 15 1 0.5 2 | 100 100 87.0 80.0 94.3 71.4 98.0 99.5 95.2 82.0 85.5 84.4 |
[table 14]
| Subregion | The composition (%) of base oil composition | The ratio (part) of opposite 100 parts of base oil composition | The detail of A ingredient | |||||||
| A ingredient | B ingredient | C ingredient | D ingredient | G ingredient | H ingredient | I ingredient | *2 | *3 | *4 | |
| Embodiment 25 26 27 28 29 30 31 32 33 34 35 36 | 78.9 67 75 75 75 75 75 75 75 75 75 75 | 18.4 13 13 13 13 13 13 13 13 13 13 13 | 2.1 2 2 2 2 2 2 2 2 2 2 2 | 0.5 18 10 10 10 10 10 10 10 10 10 10 | 0 0 15 25 6 35 0 0 0 20 15 15 | 0 0 0 0 0 0 1 0.5 2 1 1 1 | 0 0 0 0 0 0 1 0 3 1 1 0.5 | 53.3 53.7 53.3 53.3 53.3 53.3 53.3 53.3 53.3 53.3 53.3 53.3 | 68.8 73.1 73.3 73.3 73.3 73.3 73.3 73.3 73.3 73.3 73.3 73.3 | 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 |
[table 15]
| Subregion | Type | A ingredient | B component | C ingredient | D ingredient | Other ingredients | *1 | |||||
| Type | Dosage | Type | Dosage | Type | Dosage | Type | Dosage | Type | Dosage | |||
| Comparative example 123456789 10 11 12 13 14 | R-1 R-2 R-3 R-4 R-5 R-6 R-7 R-8 R-9 R-10 R-11 R-12 R-13 R-14 | A-1 A-5 A-8 A-5 A-6 A-8 A-1 A-5 A-1 A-5 A-8 a-1 a-2 a-3 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 | 10 45 20 20 40 15 20 20 40 30 25 75 75 75 40 26 20 40 20 15 40 25 20 40 25 20 30 15 5 40 20 17 30 20 12 | B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 B-1 | 13 13 18 4 13 13 13 2 40 13 13 | C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 | 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 5 5 5 | D-1 D-2 D-1 D-2 D-1 D-2 D-3 D-2 D-1 D-2 D-1 D-2 D-1 D-2 D-1 D-2 D-1 D-2 D-3 D-3 D-4 D-1 D-1 D-2 D-1 D-2 | 5 5 5 5 15 15 10 0.5 5 5 5 5 5 5 5 5 5 5 13 13 13 5 5 5 5 5 | J-1 | 3 | 100 100 100 100 25 25 25 100 100 100 100 97 100 100 |
[table 16]
| Subregion | The composition (%) of base oil composition | The ratio (part) of opposite 100 parts of base oil composition | The detail of A ingredient | |||||||
| A ingredient | B ingredient | C ingredient | D ingredient | G ingredient | H ingredient | I ingredient | *2 | *3 | *4 | |
| Comparative example 123456789 10 11 12 13 14 | 75 75 40 95 0 0 0 86 75 85 85 51.5 77 62 | 13 13 18 4 52 52 52 2 0 0 0 41.2 13 13 | 2 2 2 0.5 8 8 8 2 2 2 2 2.1 0 15 | 10 10 40 0.5 40 40 40 10 23 13 13 5.2 10 10 | 0 0 0 0 0 0 0 0 0 0 0 0 0 0 | 0 0 0 0 0 0 0 0 0 0 0 0 0 0 | 0 0 0 0 0 0 0 0 0 0 0 0 0 0 | 13.3 0 50 42.1 0 0 0 46.5 53.3 47.1 47.1 60 51.9 48.4 | 40 20 50 68.4 0 0 0 69.8 73.3 70.6 70.6 70.0 74.0 67.8 | 0.5 0 100 1.6 0 0 0 2.0 2.7 2.0 2.0 6.0 2.4 2.5 |
[table 17]
| Subregion | Type | A ingredient | B component | C ingredient | D ingredient | Other ingredients | *1 | |||||
| Type | Dosage | Type | Dosage | Type | Dosage | Type | Dosage | Type | Dosage | |||
| Comparative example 15 16 17 18 19 20 21 22 23 24 25 26 27 28 | R-15 R-16 R-17 R-18 R-19 R-20 R-21 R-22 R-23 R-24 R-25 R-26 R-27 R-28 | A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-5 A-8 A-1 A-8 A-7 A-8 A-1 A-8 A-5 A-7 A-8 A-1 A-6 A-7 A-10 A-5 A-9 A-5 A-9 A-5 | 40 25 20 40 20 15 30 15 10 55 40 56 20 29 20 47 32 16 50 37 75 86.4 49.6 30.4 46.5 28.5 53.7 | B-1 B-1 B-1 B-3 B-4 B-1 B-1 B-2 | 13 13 13 8 10 8 7 12 | C-1 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-3 C-2 C-3 C-5 C-2 C-3 C-1 C-2 C-3 C-1 C-2 C-1 C-6 C-2 C-3 C-1 C-3 C-1 C-2 C-4 | 0.5 1 0.5 0.5 1 0.5 0.5 1 0.5 4 1 3 5 2 0.5 0.5 0.5 1 0.5 4 4 1.8 1.8 2 2 0.8 1.2 5 | D-4 D-1 D-2 D-3 D-3 D-3 D-1 D-3 D-2 D-3 D-4 D-2 D-3 D-3 D-3 | 10 10 10 10 5 10 2 10 6 2 12 6.4 1.6 10.1 9.5 | H-1 G-1 G-2 H-1 H-1 H-1 G-2 H-1 I-1 G-1 J-3 J-1 G-2 J-1 | 1 20 40 1 1 1.5 10 1 0.5 45 15 5.9 14.3 5.5 | 100 100 100 99 80 59 99.0 98.5 88.5 37.5 100 100 94.1 80.2 |
[table 18]
| Subregion | The composition (%) of base oil composition | The ratio (part) of opposite 100 parts of base oil composition | The detail of A ingredient | |||||||
| A ingredient | B ingredient | C ingredient | D ingredient | G ingredient | H ingredient | I ingredient | *2 | *3 | *4 | |
| Comparative example 15 16 17 18 19 20 21 22 23 24 25 26 27 28 | 85 75 55 96 95 83.1 97.9 88.3 84.7 0 86.4 80 79.7 67 | 13 13 13 0 0 0 0 0 0 22.2 10 8 7.4 15 | 2 2 2 4 5 8.5 2.1 1.5 1.7 22.2 3.6 4 2.1 6.2 | 0 10 30 0 0 8.5 0 10.2 13.6 55.6 0 8 10.7 11.8 | 0 0 0 0 25 67.8 0 0 11.3 125 0 0 0 17.8 | 0 0 0 1 0 1.7 1 1.5 1.7 0 0 0 0 0 | 0 0 0 0 0 0 0 0 0.6 0 0 0 0 0 | 47.1 53.3 54.5 57.9 0 59.2 0 57.5 0 0 0 0 0 0 | 70.6 73.3 72.7 100 26.3 100 16.8 57.5 0 0 0 38.0 38.0 0 | 2.0 2.7 3.0 1.4 0 1.5 0 100 0 0 0 0 0 0 |
In 9~table of table 18,
Dosage: part
* 1: the ratio (%) of the base oil composition in synthetic fibers inorganic agent
* the ratio (%) for the alkylene oxide adducts that the carbon atom number of the unitary in 2:A ingredient is formed for addition in 6~10 aliphatic alcohol ethylene oxide and propylene oxide
* the total ratio (%) of the E ingredient in 3:A ingredient and F ingredient
* 4:E ingredient/F ingredient ratio (weight ratio)
A-1~A-10, a-1~a-3: A ingredient recorded in table 1
B-1~B-4: the B component recorded in table 2
C-1~C-6: the C ingredient recorded in table 3
D-1~D-9: the D ingredient recorded in table 4
G-1~G-2: the G component recorded in table 5
H-1~H-3: the H ingredient recorded in table 6
I-1~I-4: the I ingredient recorded in table 7
J-1~J-3: the other ingredients recorded in table 8
Test classification 2 (to synthetic fibers attachment synthetic fibers inorganic agent, false twisting processing and evaluation)
Attachment of the synthetic fibers inorganic agent to synthetic fibers
Each example synthetic fibers inorganic agent and dilution water modulated in test classification 1 are uniformly mixed, 10% aqueous solution of synthetic fibers inorganic agent is made.It is 0.64 by intrinsic viscosity, after the polyethylene terephthalate piece that titanium oxide content is 0.2% is by well-established law drying, with extruder spinning at 295 DEG C, on the mobile strand after spraying cooling and solidifying from nozzle, by using the guiding of metering pump to oil process, it with the adhesive rate that inorganic agent relatively moves strand is that the adhesion amount that table 19 or table 20 are recorded adheres to aforementioned 10% aqueous solution of modulation according to synthetic fibers, then, boundling is allowed to traveller, it is batched in the case where no mechanicalness is stretched with 3000m/ minutes speed, obtain the 10kg winding cake of the partially drawn yarn of 128 dtex, 36 monofilament.
False twisting processing
Using spinning cake obtained above, in the case where carrying out false twisting processing conditions using following contact heater formula false twisting machines, false twisting processing is carried out.
The condition of false twisting processing is carried out using contact heater formula false twisting machine:
It uses contact heater formula false twisting machine (SDS1200 of Teijin machimery corporation), process velocity=700m/ minutes and two kinds of conditions of 1000m/ minute, under the following conditions: its stretching ratio=1.652, apply twirl mode=3 axis disk circumscribed friction modes (1, introduction side traveller disk, 1, export side traveller disk, 4, hard polyaminoester disk), twisting the long 2.5m surface temperature of side heater be 210 DEG C, without backtwisting side heater, target twisting count 3300T/m, it was continuously run by 25 days, carries out false twisting processing.
The evaluation of fluffing
In false twisting above-mentioned processing, before batching false twist yarn, every 1 hour approximate number is measured with fluffing counting device (DT-105 of eastern レ エ Application ジ ニ ア リ Application グ corporation), is evaluated with following standard.As a result summarize and be shown in table 19 and table 20.
AAA: the approximate number that rises of measurement is 0
AA: 0) approximate number of measurement (does not include wherein, less than 1
A: the approximate number that rises of measurement is 1~2
B: the approximate number that rises of measurement is 3~9
C: the approximate number that rises of measurement is 10 or more
The evaluation of broken end
In above-mentioned false twisting processing, daily number will be converted into continuously running the broken end number occurred in 25 days, evaluated with following standard.As a result summarize and be shown in table 19 and table 20.
AAA: the number to break end is 0 time
AA: 0) number to break end (does not include wherein, less than 0.5 time
A: the number to break end be 0.5~less than 1 time
B: the number to break end be 1~less than 5 times
C: the number to break end is 5 times or more
Chromatic evaluation
The false twist yarn to be fluffed with said determination, is made the fabric that diameter is 70mm, length is 1.2m using muslin tubing bad braider.The fabric being made is dyed with disperse dyes (one EBL-E of カ ヤ ロ Application Port リ エ ス テ Le Block Le of Japanese chemical drug corporation) by high-pressure dyeing.After dyed fabric is successively washed with well-established law, restores washing and drying, it is fitted into that diameter is 70mm, length is in the work durm of 1m, the points of the dense dye part of fabric surface will with the naked eye be counted, carry out 5 evaluations, it is converted into the points of every fabric by obtained evaluation result, is evaluated with following standard.As a result summarize and be shown in table 19 and table 20.
AAA: without dense dye part
AA: dense dye part has at 1 point
A: dense dye part has at 2 points
B: dense dye part has at 3~6 points
C: dense dye part has 7 points or more
[table 19]
| Subregion | Type | Adhesion amount (%) | False twisting process velocity | |||||
| 700m/ points | 1000m/ points | |||||||
| Fluffing | Broken end | Dyeability | Fluffing | Broken end | Dyeability | |||
| Embodiment 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 | P-1 P-2 P-3 P-4 P-5 P-6 P-7 P-8 P-9 P-10 P-11 P-12 P-13 P-14 P-15 P-16 P-17 P-18 P-19 P-20 P-21 P-22 P-23 P-24 P-25 P-26 P-27 P-29 P-29 P-30 P-31 P-32 P-33 P-34 P-35 P-36 | 0.4 0.5 0.4 0.3 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.5 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.6 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.3 0.4 0.4 0.5 0.4 0.4 0.4 | AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA | AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA | AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA | AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA A AA AA AA AAA AAA AA AA AAA AAA AA AAA AAA AAA | AAA AAA AAA AAA AA AAA AA AA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AA AAA AAA AA AA AAA AAA AA AAA AAA AAA AAA AAA AAA AA AAA AAA AAA | AAA AAA AAA AAA AAA AA AAA AA AAA AAA AAA AAA AAA AAA AAA AAA AAA AA AAA AAA AAA AA AA AAA AA AA AAA AAA AAA AA AAA AAA AAA AAA AAA AAA |
[table 20]
| Subregion | Type | Adhesion amount (%) | False twisting process velocity | |||||
| 700m/ points | 1000m/ points | |||||||
| Fluffing | Broken end | Dyeability | Fluffing | Broken end | Dyeability | |||
| Comparative example 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 | R-1 R-2 R-3 R-4 R-5 R-6 R-7 R-8 R-9 R-10 R-11 R-12 R-13 R-14 R-15 R-16 R-17 R-18 R-19 R-20 R-21 R-22 R-23 R-24 R-25 R-26 R-27 R-28 | 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.3 0.4 0.5 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.3 0.4 0.5 | B B C B C C B B B B C B B C B B C B B B B B B C B B B B | A A B A B B B A B B B B B C A A B A A A B A A C B A A A | B C B B B C B B B B B B C C A A B B C B B B B C C C C B | B B C B C C C C C C C C C C C B C C B C C B B C B B B B | B B C B C B B B B B B C C C B B C B B B B B B C B B B B | B C B B B C B C B B C B C C B B C C C C C B B C C C C B |
Claims (17)
1. a kind of synthetic fibers inorganic agent, which is characterized in that its following base oil composition for containing 70 weight % or more,
Base oil composition: by following A ingredient, B component, C ingredient and D at being grouped as, and it contains: 50~90 weight % of the A ingredient, 3~30 weight % of the B component, 0.1~10 weight % of the C ingredient, 0.1~20 weight % of the D ingredient, amounts to 100 weight %,
A ingredient: be selected from and meanwhile one of alkylene oxide adducts for meeting following conditions 1~3 or more than one,
Condition 1: being the alkylene oxide adducts that the number-average molecular weight for the epoxyalkane that addition carbon atom number is 2~4 in the aliphatic alcohol that 1~3 yuan of carbon atom number is 1~24 is 1000~12000,
Condition 2: being the alkylene oxide adducts with polyoxyalkylenes, wherein 10~80 weight % for forming its total oxyalkylene units are ethylene oxide units,
Condition 3: being the alkylene oxide adducts containing the 35 weight % of alkylene oxide adducts or more of addition ethylene oxide and propylene oxide in the aliphatic alcohol that 1 yuan of carbon atom number is 6~10,
B component: it is the alkylene oxide adducts that the number-average molecular weight that addition ethylene oxide or ethylene oxide and propylene oxide are formed in the aliphatic alcohol that 1 yuan of carbon atom number is 6~10 is 140~800, and for selected from one of alkylene oxide adducts with polyoxyalkylenes or more than one, wherein, constituting 30 weight % of its total oxyalkylene units, the above are ethylene oxide units
C ingredient: selected from one of ionic surface active agent or more than one,
D ingredient, in the following substance one of or more than one: the ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and propylene oxide is 210~950 in the aliphatic alcohol that 1 yuan of carbon atom number is 11~24, the ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide or propylene oxide is 900~2000 in the aliphatic alcohol that 1 yuan of carbon atom number is 6~10, the ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide or propylene oxide is 150~2500 in the aliphatic alcohol that 1 yuan of carbon atom number is 11~24, the ester type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 200~2000 in the fatty acid that 1 yuan of carbon atom number is 8~24, The nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 700~10000 in animal and plant fat, the amino ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 200~2500 in the aliphatic amine that carbon atom number is 8~24, the amide ether type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 250~2500 in the aliphatic amide that carbon atom number is 8~24, the partial ester type nonionic surfactant that the aliphatic alcohol that carbon atom number by 2~6 yuan is 2~6 is crossed with the fatty acid partial ester that carbon atom number is 8~24, it is crossed in the aliphatic alcohol for being 3~6 by 3~6 yuan of carbon atom number with the fatty acid partial ester that carbon atom number is 8~24 inclined The Etheric ester type nonionic surfactant that the number-average molecular weight of addition ethylene oxide and/or propylene oxide is 400~6000 in ester.
2. containing 80 weight % of base oil composition or more, and the base oil composition contains: 55~90 weight % of A ingredient such as the synthetic fibers inorganic agent that claim 1 is recorded；5~20 weight % of B component；0.3~5 weight % of C ingredient；1~20 weight % of D ingredient amounts to 100 weight %.
3. the synthetic fibers inorganic agent recorded such as claim 2, wherein, A ingredient contains the following E ingredients and F ingredient for amounting to 50 weight % or more, and the content ratio of the E ingredient and the F ingredient are as follows: with weight ratio meter, the E ingredient/ingredient=50/50~90/10 F
E ingredient: in the aliphatic alcohol that 1 yuan of carbon atom number is 6~10, by ethylene oxide and propylene oxide by weight the ratio addition of ethylene oxide/propylene oxide=35/65~80/20, the alkylene oxide adducts that the number-average molecular weight of formation is 1000~12000；
F ingredient: in the aliphatic alcohol that 1 yuan of carbon atom number is 11~16, by ethylene oxide and propylene oxide by weight the ratio addition of ethylene oxide/propylene oxide=10/90~80/20, the alkylene oxide adducts that the number-average molecular weight of formation is 1000~12000.
4. also containing following G components, and opposite 100 parts by weight of base oil composition such as the synthetic fibers inorganic agent that claim 3 is recorded, the content ratio of the G component is 5~40 parts by weight,
G component: be selected from one of the aliphatic ester compound that is indicated with followingization 1 and the aliphatic ester compound indicated with followingization 2 or more than one,
[changing 1]
R1-X-R2
[changing 2]
R3-R4
Changing 1 and changing in 2,
R1, R3: the residue after removing hydrogen atom in the aliphatic monobasic alcohol that carbon atom number is 8~18
R2: the residue after removing hydrogen atom in the aliphatic monocarboxylic acid that carbon atom number is 8~18
R4: the residue after removing hydroxyl in the aliphatic monocarboxylic acid that carbon atom number is 8~18
X: the residue after removing whole hydroxyls in (poly-) the alkane glycol with (poly-) oxyalkylene group being made of total 1~10 ethylene oxide unit and/or propylene oxide unit.
5. such as the synthetic fibers inorganic agent that claim 3 is recorded, also containing following H ingredients and/or I ingredient, and opposite 100 parts by weight of base oil composition, the content ratio of the H ingredient and/or I ingredient is total 0.3~6 parts by weight,
H ingredient: polyoxyalkylene-modified organosilicon and/or dimethyl organosilicon；
I ingredient: selected from one of phenol antioxidant, phosphite antioxidant and thioether antioxidants or more than one.
6. such as the synthetic fibers inorganic agent that claim 4 is recorded, also containing following H ingredients and/or I ingredient, and opposite 100 parts by weight of base oil composition, the content ratio of the H ingredient and/or I ingredient is total 0.3~6 parts by weight,
H ingredient: polyoxyalkylene-modified organosilicon and/or dimethyl organosilicon；
I ingredient: selected from one of phenol antioxidant, phosphite antioxidant and thioether antioxidants or more than one.
7. such as the synthetic fibers inorganic agent that claim 6 is recorded, opposite 100 parts by weight of base oil composition contain 0.5~3 parts by weight of 5~30 parts by weight of G component, 0.5~3 parts by weight of H ingredient and I ingredient.
8. wherein H ingredient is polyoxyalkylene-modified organosilicon such as the synthetic fibers inorganic agent that claim 5 is recorded.
9. wherein I ingredient is phenol antioxidant such as the synthetic fibers inorganic agent that claim 5 is recorded.
10. a kind of processing method of synthetic fibers, which is characterized in that opposite synthetic fibers, the synthetic fibers for recording claim 3 adhere to 0.1~3 weight % with inorganic agent.
11. a kind of processing method of synthetic fibers, which is characterized in that opposite synthetic fibers, the synthetic fibers for recording claim 4 adhere to 0.1~3 weight % with inorganic agent.
12. a kind of processing method of synthetic fibers, which is characterized in that opposite synthetic fibers, the synthetic fibers for recording claim 5 adhere to 0.1~3 weight % with inorganic agent.
13. a kind of processing method of synthetic fibers, which is characterized in that opposite synthetic fibers, the synthetic fibers for recording claim 7 adhere to 0.1~3 weight % with inorganic agent.
14. synthetic fibers to be made to the aqueous solution of 5~30 weight % with inorganic agent such as the processing method for the synthetic fibers that claim 10 is recorded, the aqueous solution is set to adhere to 0.1~3 weight % with respect to synthetic fibers as the synthetic fibers inorganic agent.
15. synthetic fibers to be made to the aqueous solution of 5~30 weight % with inorganic agent such as the processing method for the synthetic fibers that claim 11 is recorded, the aqueous solution is set to adhere to 0.1~3 weight % with respect to synthetic fibers as the synthetic fibers inorganic agent.
16. synthetic fibers to be made to the aqueous solution of 5~30 weight % with inorganic agent such as the processing method for the synthetic fibers that claim 12 is recorded, the aqueous solution is set to adhere to 0.1~3 weight % with respect to synthetic fibers as the synthetic fibers inorganic agent.
17. synthetic fibers to be made to the aqueous solution of 5~30 weight % with inorganic agent such as the processing method for the synthetic fibers that claim 13 is recorded, the aqueous solution is set to adhere to 0.1~3 weight % with respect to synthetic fibers as the synthetic fibers inorganic agent.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004319141 | 2004-11-02 | ||
| JP2004319141 | 2004-11-02 | ||
| JP2004-319141 | 2004-11-02 | ||
| JP2005239278 | 2005-08-22 | ||
| JP2005-239278 | 2005-08-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1769581A true CN1769581A (en) | 2006-05-10 |
| CN100422429C CN100422429C (en) | 2008-10-01 |
Family
ID=36751096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101201102A Active CN100422429C (en) | 2004-11-02 | 2005-11-02 | Treating agent for synthetic fiber and method for treating synthetic fiber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100422429C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101736577A (en) * | 2008-11-17 | 2010-06-16 | 竹本油脂株式会社 | Treating agent for synthetic fiber and method for treating synthetic fiber |
| CN101260613B (en) * | 2007-03-09 | 2012-12-19 | 竹本油脂株式会社 | Treating agent for polyolefin-based fiber, method for treating polyolefin-based fiber, and hydrophilic polyolefin-based fiber |
| CN106164040A (en) * | 2014-02-08 | 2016-11-23 | 埃瑟克斯化学有限责任公司 | The high-performance water dilution type oiliness additive applied for polymetallic intermetallic composite coating |
| CN107407044A (en) * | 2015-03-06 | 2017-11-28 | 松本油脂制药株式会社 | Elastomer inorganic agent and its utilization |
| CN108368671A (en) * | 2016-03-04 | 2018-08-03 | 松本油脂制药株式会社 | Synthetic fibers inorganic agent and application thereof |
| TWI689647B (en) * | 2018-04-27 | 2020-04-01 | 日商竹本油脂股份有限公司 | Polyolefin synthetic fiber treatment agent and polyolefin synthetic fiber |
| CN113785089A (en) * | 2019-06-13 | 2021-12-10 | 竹本油脂株式会社 | Treating agent for synthetic fiber and synthetic fiber |
| CN116324081A (en) * | 2020-09-28 | 2023-06-23 | 竹本油脂株式会社 | Treatment agent for nonwoven fabric made of polyolefin synthetic fibers, and spun-bonded nonwoven fabric made of polyolefin synthetic fibers |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2703620B2 (en) * | 1989-04-10 | 1998-01-26 | 日本エステル株式会社 | Manufacturing method of polyester false twisted yarn |
| ES2270576T3 (en) * | 1998-01-29 | 2007-04-01 | Asahi Kasei Kabushiki Kaisha | SMOOTH POLYESTER FIBER. |
-
2005
- 2005-11-02 CN CNB2005101201102A patent/CN100422429C/en active Active
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101260613B (en) * | 2007-03-09 | 2012-12-19 | 竹本油脂株式会社 | Treating agent for polyolefin-based fiber, method for treating polyolefin-based fiber, and hydrophilic polyolefin-based fiber |
| CN101736577A (en) * | 2008-11-17 | 2010-06-16 | 竹本油脂株式会社 | Treating agent for synthetic fiber and method for treating synthetic fiber |
| CN101736577B (en) * | 2008-11-17 | 2014-01-08 | 竹本油脂株式会社 | Treating agent for synthetic fiber and method for treating synthetic fiber |
| CN106164040B (en) * | 2014-02-08 | 2018-12-04 | 埃瑟克斯化学有限责任公司 | High-performance water dilution type oiliness additive for the application of polymetallic intermetallic composite coating |
| CN106164040A (en) * | 2014-02-08 | 2016-11-23 | 埃瑟克斯化学有限责任公司 | The high-performance water dilution type oiliness additive applied for polymetallic intermetallic composite coating |
| CN107407044A (en) * | 2015-03-06 | 2017-11-28 | 松本油脂制药株式会社 | Elastomer inorganic agent and its utilization |
| CN107407044B (en) * | 2015-03-06 | 2020-06-09 | 松本油脂制药株式会社 | Treating agent for elastic fiber and use thereof |
| CN108368671A (en) * | 2016-03-04 | 2018-08-03 | 松本油脂制药株式会社 | Synthetic fibers inorganic agent and application thereof |
| CN108368671B (en) * | 2016-03-04 | 2019-06-28 | 松本油脂制药株式会社 | Synthetic fibers inorganic agent and application thereof |
| TWI689647B (en) * | 2018-04-27 | 2020-04-01 | 日商竹本油脂股份有限公司 | Polyolefin synthetic fiber treatment agent and polyolefin synthetic fiber |
| CN113785089A (en) * | 2019-06-13 | 2021-12-10 | 竹本油脂株式会社 | Treating agent for synthetic fiber and synthetic fiber |
| CN113785089B (en) * | 2019-06-13 | 2022-08-09 | 竹本油脂株式会社 | Treating agent for synthetic fiber and synthetic fiber |
| CN116324081A (en) * | 2020-09-28 | 2023-06-23 | 竹本油脂株式会社 | Treatment agent for nonwoven fabric made of polyolefin synthetic fibers, and spun-bonded nonwoven fabric made of polyolefin synthetic fibers |
| CN116324081B (en) * | 2020-09-28 | 2024-04-30 | 竹本油脂株式会社 | Treatment agent for nonwoven fabric made of polyolefin synthetic fibers, and spun-bonded nonwoven fabric made of polyolefin synthetic fibers |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100422429C (en) | 2008-10-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1769581A (en) | Treating agent for synthetic fiber and method for treating synthetic fiber | |
| CN1948605A (en) | Treating agent and treating method for synthetic fiber for producing nonwoven fabric, and synthetic fiber for producing nonwoven fabric | |
| EP1652996B1 (en) | Processing agents and methods for treating synthetic fibres | |
| CN1704522A (en) | Treating agent for synthetic fiber and method for treating synthetic fiber | |
| JP2009155762A (en) | Treating agent for synthetic fiber, method for treating synthetic fiber, and synthetic fiber | |
| CN107208357B (en) | Treating agent for elastic fiber and use thereof | |
| TW202022191A (en) | Synthetic fiber treatment agent and method of producing synthetic fiber | |
| CN101033582A (en) | Agent for imparting water permeability and water permeable fiber attached by the same | |
| JP4471464B2 (en) | Oil for high-speed spinning of synthetic fiber and high-speed spinning method | |
| JP6321860B1 (en) | Synthetic fiber treatment agent, synthetic fiber, and synthetic fiber treatment method | |
| JPH11315480A (en) | Synthetic fiber treating agent and treating method therefor | |
| RU2202602C2 (en) | Usage of polydiorganosiloxane as admixture to fabric plasticizer composition and fabric plasticizer composition | |
| CN1648323A (en) | Fiber processing agent | |
| KR101052461B1 (en) | Method for preparing low concentration aqueous solution of synthetic fiber treatment agent, Method for treating low concentration aqueous solution of synthetic fiber treatment agent and synthetic fiber | |
| JP3904514B2 (en) | Synthetic fiber treatment agent and synthetic fiber treatment method | |
| CN1734011A (en) | Treating agent for synthetic fiber and method for treating synthetic fiber | |
| CN1143912C (en) | Spin finish for synthetic fibers, and synthetic fibers | |
| JP2023010233A (en) | Treatment agent for short fibers, aqueous solution for treatment agent for short fibers, treatment method for short fibers, production method for short fibers, and short fibers | |
| JP2002020971A (en) | Oil solution for high speed spinning of synthetic fiber and method for high speed spinning | |
| JP6434904B2 (en) | Treatment agent for synthetic fiber filament, synthetic fiber filament and base fabric | |
| WO2020250550A1 (en) | Synthetic fiber treatment agent and synthetic fiber | |
| JP2017066551A (en) | Polyamide fiber, and method of producing the same | |
| CN1727568A (en) | Directly oiling oil solution for fiber | |
| CN113785089B (en) | Treating agent for synthetic fiber and synthetic fiber | |
| US12123108B2 (en) | Treatment agent for short fibers, aqueous solution for treatment agent for short fibers, treatment method for short fibers, production method for short fibers, and short fibers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |