CN1752319A - Raising method for elastic non-woven base fabric - Google Patents
Raising method for elastic non-woven base fabric Download PDFInfo
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- CN1752319A CN1752319A CN200510030543.9A CN200510030543A CN1752319A CN 1752319 A CN1752319 A CN 1752319A CN 200510030543 A CN200510030543 A CN 200510030543A CN 1752319 A CN1752319 A CN 1752319A
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Abstract
The present invention adopts elastic sea-island fibre and inelastic sea-island fibre according to weight ratio of (20:80)-(80:20), and adopts the following steps: mixing, opening, carding, web-laying and needling to obtain elastic leather base fabric, then making shrinkage, applying water soluble slurry, sanding, applying adhesive, opening fibre, sanding, desizing, mellowing leather, sanding, dyeing and finishing so as to obtain the invented elastic non-woven base fabric.
Description
Technical field
The present invention relates to the raising method of a kind of elastic non-woven base fabric of non-woven field, is a kind of raising method of novel artificial sueded leather furtherly.
Background technology
The manufacturing of Qi Mao imitative chamois leather in the past all is to be base cloth with fabric, knitted fabric, non-weaving cloth, and after base cloth being given the resin of high molecular polymer, carries out the method that sanding produces a kind of imitative chamois leather process hides of filoplume on its surface.This fluffing is most important to the quality of final products artificial sueded leather, particularly feel and exterior quality and physical property such as brute force etc.Along with the development of superfine fibre, the application of superfine fibre in process hides constantly enlarges.Since the artificial leather that superfine fibre is made, the outward appearance grace, and inherent quality is good, is the high a kind of expensive goods of added value.Artificial leather with superfine fibre production mainly contains two big classes, and a class is an artificial sueded leather, and another kind of is silver-colored surface layer artificial leather.This two series products almost respectively accounts for half.The manufacturing of superfine fibre, what application was the most general at present has three kinds, all is the bi-component spinning, and a kind of is that the figured islands-in-sea fiber is produced in the figured islands-in-sea spinning, and promptly the cross section on island all is identical in two components of island, and the island axially is being continuous; A kind of is not figured type islands-in-sea type fibre spinning, and promptly in two components of island, the island is to be randomly dispersed in marinely, and the cross section on island is not wait, and the island axially is being discontinuous; The final component of these bicomponent fibers adopts the method for chemistry that its dissolving is removed, make superfine fibre (as deciding island or indefinite island fiber) or with the method for physics as friction, be heated etc. and make its separation, cut apart, peel off and make superfine fibre (as tangerine lobe type bicomponent fiber), this is that another kind is called divergence type or exfoliated, tangerine lobe fiber type.The figured islands-in-sea fiber is identical because of its cross section, so make the artificial leather base cloth, the surface is after sanding, and the diameter unanimity of filoplume is suitable for artificial sueded leather; And figured type islands-in-sea type fibre not is not of uniform size because of the quantity on island is many, and the island is suitable for silver-colored face type artificial leather axially interrupted.Artificial leather is different from synthetic leather, artificial leather, and it is specially to refer to the non-woven base cloth of making promptly by fiber opening, mixed, carding, lapping, with after acupuncture or water sting and make fibre web reinforce into non-woven base fabric to make.After deliberation, this method makes product, is similar to natural leather on its structure, and on the physical characteristic, on the taking, aspect such as clothes reduction, storage all is better than natural leather.These artificial leathers are mainly used in footwear, clothing, case and bag, gloves and aspects such as ball, bunting.
At home and abroad the polyurethane elastomeric fiber of being made by the polyurethane spinning can't be with the mode production application of short silk in weaving, can only with the mode of long filament weave, knitting or compound in use because the short silk of elastic polyurethane can't carry out carding on carding machine.
On the existing domestic and international artificial leather manufacturing technology, when adopting island fiber with figured sea-island to make artificial sueded leather, because the figured islands-in-sea fiber is after opening fibrillation, promptly sea dissolving is removed and forms superfine fibre, with respect to island fiber with figured sea-island not, because of the island axially continuously, base cloth intensity height, but the island number is few, and the feel of artificial leather poor (fiber number is thick) can influence the filoplume density after the fluffing; And adopt not figured type islands-in-sea type fibre with respect to the figured islands-in-sea fiber, and the island is axially discontinuous, and the length on island is shorter, the intensity difference of base cloth, the number of opening island, fine back is many, the good hand touch of artificial leather, but because of the weak effect of the chamois leather not of uniform size on island.Decide island and island fiber with figured sea-island not, after making non-woven base fabric, all adopt by the rubber-like solvent type polyurethane resin of Dupont in invention in 1963, this resin softness, film forming is flexible, but must dilute with DMF (dimethyl formamide) organic solvent viscosity reduction, DMF and water displacement when polyurethane resin solidifies simultaneously, epithelium produces micropore, makes artificial leather ventilative, saturating wet, have good taking, but DMF pollutes environment, diminish operator's health, so developed country, advanced technology country all manages seek to substitute, and studying more at present is with soluble polyurethane replace solvents type polyurethane.
Summary of the invention
The object of the invention provides a kind of raising method of elastic non-woven base fabric.Fibrous raw material and technology have been done meticulous research, reached the material choice science, Process configuration is reasonable, and has obtained good result.Use elastic superfine fiber, give the flexibility adhesive, the artificial sueded leather of making through rational raising method replaces the solvent borne polyurethane tradition leather-making technology to environment, human body harmful, is a kind of raising method of the manufacture of intraocular leather without solvent borne polyurethane.
It is ' ultra-fine denier polyurethane filament ' fabric of island-in-sea type bicomponent filament yarn by low density polyethylene (LDPE) parcel polyurethane (CN200510023909.X) that method of the present invention also is fit to denomination of invention, low density polyethylene (LDPE) and weight polyurethane ratio are 0.4～1.5: 1, its fine density is 150～200dtex, fibrous fracture intensity 1.9～2.1CN/dtex, extension at break 100～150%, sea component dissolving back filament number is the ultra-fine denier polyurethane bicomponent filament yarn of 0.08～0.3dtex.Elastic polyurethane fiber (number of patent application 200510023909X) is made elastomer woven fabric, knitted fabric or they and the non-woven base cloth that is combined into, and artificial sueded leather is made in arrangement after method sanding of the present invention etc.This is the method for the traditional manufacture of intraocular skin of a kind of solvent borne polyurethane that does not adopt contaminated environment to be harmful to human body.
Technology path of the present invention as shown in Figure 1.
Raw material adopts elasticity islands-in-sea type fibre and non-resilient islands-in-sea type fibre, is that island fiber with figured sea-island and non-island fiber with figured sea-island mix, and is the island of deciding the island by polyurethane promptly, is the two kinds of composite fibres mixing in island on indefinite island with polyamide also, and they all are that polyethylene is the component in sea.
Elasticity islands-in-sea type fibre and non-resilient islands-in-sea type fibre are that raw material carries out shredding, mixed, combing, lapping, acupuncture, obtain elasticity leather base cloth, and then shrink, go up water-soluble paste, sanding, go up adhesive, open fibre, sanding, destarch, rub leather, technology acquisition elastic non-wovens such as sanding, dyeing and whole hair are the artificial sueded leather of base cloth.Described shredding, mixed, combing, lapping, acupuncture, open fibre, rub leather, dyeing and whole hair technology etc. all are to adopt common technology and equipment to carry out.
Little close for the filoplume that makes product, sanding is respond well, the island number of deciding the island with the 16-37 island for well; The island numerical control on indefinite island is built in the 200-250 island, and thin island be distributed in fiber around, and thick island concentrates near the center of fiber, the thick island average fineness on indefinite island should be within limits with the fiber number of deciding the island, as to decide the thicker average fineness in the fiber number on island and indefinite island be 1: 1～10, the effect that this density to fluffing reaches imitative chamois leather is very important, and the filament number that also can take simultaneously to increase indefinite island makes itself and the method for deciding the fiber number convergence on island.The ratio of elastomer and non-elastic fiber is (20: 80)～(80: 20).
The shrinking process of taking in technology is that needle-punching substrate is placed hot water, vapours or hot blast, makes base cloth be subjected to thermal contraction, in general uses hot water to shrink better, shrinks evenly and with the hot water temperature to raise, and shrinkage factor constantly increases.Shrinkage factor can be calculated as follows:
The shrinkage factor of base cloth generally in 10%-30% for well.Because shrink the apparent density that has increased base cloth, the number of fiber of unit are increases, and is very important to a gross density and the uniformity of elastic base fabric like this.Suggestion elasticity needle-punching substrate shrinks through 90～98 ℃, 5～15 minutes hot water, and hot water was punctured into preferable in especially 95 ℃, 10 minutes.
Described in the method for the invention go up water-soluble paste be base cloth after shrinking, all contain and be dipped in the water-soluble paste by roll control starching amount, make surface of semi-finished smooth, be convenient to fluffing.The water-soluble paste amount can be regulated amount of binder, and adhesive is not directly combined with fiber, can make final products soft.Described water-soluble paste is polyvinyl alcohol (PVA) aqueous solution that contains 5～15% weight.
Behind starching, the drying, sanding first, because base cloth is smooth, fluffing is even, and the elasticity islands-in-sea type fibre is because the coating of slurry is fluffed easily, and the length of hair is even, and this is quite favourable to later fluffing.The suggestion of sanding first adopts 60～100
#Rubber paper carries out one side or two-sided sanding on roughing-up machine.
Soak soft adhesive then, surface hairiness is fitted again, adopts the aqueous solution impregnation that contains acrylate 15～35% weight usually; After the drying dissolving of the sea component in the fiber is removed, usually adopt organic solvent, extract to remove polyethylene in the fiber as organic solvents such as benzene, toluene, in containing the equipment of organic flux bath through more than 20 rolls repeatedly the padder of roll compacting-dipping remove polyethylene.Drying carries out sanding later on once more, and suggestion adopts 160
#～200
#The sanding of rubber paper, destarch 1～15 minute in 90～95 ℃ the aqueous solution is subsequently rubbed leather with rubbing the leather machine again, shrinks this moment approximately 2～5%, feel and the convenient silicone oil that sprays of fluffing in order to improve final products carry out the sanding suggestion once more and adopt 300～400
#The sanding of rubber paper, the whole hair in dyeing back.Silicone oil can make final products smooth, and sanding is easy.
The advantage of the inventive method
1, the present invention adopts the method for elasticity islands-in-sea type fibre and non-resilient islands-in-sea type fibre process hides, employing to decide the elastomer and the indefinite island non-elastic fiber method for leather-making on island, the rational technology of science has been taked in the fluffing of elastic non-woven base fabric, obtained that a gross density is big, the effect of fluffing good uniformity.Adopt the inventive method can on carding machine, carry out combing to the sea-island staple fiber of elastic polyurethane.
2, the product surface of the inventive method acquisition is level and smooth, outward appearance grace, softness, ABRASION RESISTANCE, the special good style of wrinkle resistance.
3, the inventive method makes product and is suitable for buntings such as producing high-grade clothes, footwear, case and bag, automobile.
The specific embodiment
The present invention has done further investigation in the fluffing of elastic non-woven base fabric, by selection and configuration to raw material, and detailed, the careful consideration in aspect such as processes, obtained the final products good result.
It is raw material that raw material adopts elasticity islands-in-sea type fibre and non-resilient islands-in-sea type fibre, be island fiber with figured sea-island and not island fiber with figured sea-island mixing, being the island of deciding the island by polyurethane promptly, also is the two kinds of composite fibres in island on indefinite island with polyamide, and they all are to be the component in sea with the polyethylene.The sea of this islands-in-sea type fibre is the removable polymer of a kind of solvent.
Elasticity and non-elastic fiber are that elastic polyurethane is to decide the island, and non-resilient polyamide is that two kinds of islands-in-sea type fibre purposes on indefinite island are the needed raw materials of this method.Selecting the island of deciding the island for use is the 16-37 island, and the island numerical control on indefinite island is built in the 200-250 island, and thin island be distributed in fiber around, and thick island concentrates near the center of fiber; The thick island average fineness on indefinite island should be within limits with the fiber number of deciding the island, and the average fineness of deciding the thick island of fiber number and indefinite island on island is 1: 1～10.The ratio of elastomer and non-elastic fiber is (20: 80)～(80: 20).On technology, take as accompanying drawing 1 described technology.
Except special description, the inventive method and technology all are to adopt method in common and technology.
In the method for the present invention, shrinking process is that needle-punching substrate is placed hot water, vapours, hot blast, makes base cloth be subjected to thermal contraction, and the shrinkage factor of base cloth is generally in 10%～30%.The elasticity needle-punching substrate is shunk through 90～98 ℃, 5～15 minutes hot water.
Last water-soluble paste is a base cloth after shrinking, and pads water-soluble paste entirely, by roll control starching amount, makes surface of semi-finished smooth, is convenient to fluffing.Be padded in last water-soluble paste in the polyvinyl alcohol water solution that contains 5～15% weight entirely by roller mill.
Sanding first, the sanding suggestion adopts 60～100
#Rubber paper carries out one side or two-sided sanding on roughing-up machine.
Last adhesive is meant out that fine preceding base cloth floods with the aqueous solution that contains acrylate 15～35% weight, fits surface hairiness again.
Before destarch, carry out sanding once more, with 160～200
#The sanding of rubber paper, on roughing-up machine, carry out one side or two-sided sanding.
Fiber opening process is in organic solvent, pads the polyethylene of removing in the fiber with the padder with No. 5～20 rolls.
The sea component in the fiber is removed in destarch, is to handle 5～20 minutes in 90～95 ℃ water-soluble, removes remaining polyvinyl alcohol pulp.
Rub and fluff leather sprays silicone oil before dyeing after, sanding is with 400 once more
#Rubber paper carries out one side or two-sided sanding on roughing-up machine.Silicone oil makes final products smooth, and sanding is easy.
Embodiment 1
Polyurethane (PU) section 50% be the island, the islands-in-sea type fibre that polyethylene (PE) 50% obtains for extra large figured type composite spinning, through drawing-off, curl, cut off fiber number 3.2dtex, crispation number be 7/time, length is the elastic polyurethane islands-in-sea type fibre A of 51mm.
Polyamide (PA) section 50% is the island, polyethylene (PE) 50% obtains not figured type islands-in-sea type fibre for the not figured type co-blended spinning in sea, through drawing-off, curl, cut off fiber number 5.6dtex, crispation number be 15/time, length is the non-resilient sea-island staple fiber B of the polyamide of 51mm.
A fiber 30 mixes with the weight ratio of B fiber 70, shredding, combing, lapping, acupuncture, fibre web grammes per square metre 360g/m
2, needling density 800 thorn/cm
2, elasticity acupuncture base-→ 95 ℃, 10 minutes hot water shrink---→ be immersed in after doing and carry out starching in the 10%PVA solution---→ do the back with 80
#Rubber paper carries out one side or two-sided sanding---and 30% impregnation of → soft type acrylate solid content, the rate of sizing is 25%---→ do then through padding repeatedly polyethylene is extracted in 80 ℃ of toluene solvants---behind → drying 180
#Rubber paper sanding → 90 ℃ of PVA that decorporate---→---→ spray silicone oil---→ 400 of rubbing leather
#Rubber paper sanding---→ dyeing---→ whole hair---→ grammes per square metre 240g/m
2, the artificial sueded leather of thick 0.8mm.
Soft, smooth, the filoplume density of product is big, filoplume good evenness, crease resistance are fabulous.
Embodiment 2
Polyurethane (PU) section 50% be the island, and polyethylene (PE) 50% spins the islands-in-sea type fibre that obtains for extra large figured type composite spinning, through drawing-off, curl, cut off fiber number 3.2dtex, crispation number be 7/time, length is the elastic polyurethane islands-in-sea type fibre A of 51mm.
Polyamide (PA) section 50% is the island, polyethylene (PE) 50% obtains not figured type islands-in-sea type fibre for the not figured type co-blended spinning in sea, through drawing-off, curl, cut off fiber number 5.6dtex, crispation number be 15/time, length is the non-resilient sea-island staple fiber B of the polyamide of 51mm.
A fiber 50 mixes with the weight ratio of B fiber 50, and percentage reduction of area is 22.5%, and all the other conditions are identical with embodiment 1.The feel of product is very soft, and elasticity spy is good, the filoplume densification, and evenly, wrinkle resistance is strong, the outward appearance grace.
Comparative example
With the---→ impregnation soft type acroleic acid resin---extraction of → toluene---→ rub leather---→ 400 in the example through the good elasticity needle-punching substrate of acupuncture
#Rubber paper sanding---→ dyeing---→ whole hair (condition is identical with embodiment) gained artificial sueded leather Boardy Feeling, retractility is bad, the cortex sense is poor, and the filoplume uniformity of product is poor, bad order.
Claims (9)
1, a kind of raising method of elastic non-woven base fabric, it is characterized in that the island number is the elasticity islands-in-sea type fibre of 16-37 and the non-resilient not figured type islands-in-sea type fibre that the island number is the 200-250 island, its weight ratio is that (20: 80)～mix (80: 20), shredding, combing, lapping, acupuncture, obtain elasticity leather base cloth, and then shrink, go up water-soluble paste, sanding, go up adhesive, open fibre, sanding, destarch, rub leather, sanding, dyeing and whole hair.
2, the raising method of a kind of elastic non-woven base fabric as claimed in claim 1 is characterized in that described elasticity islands-in-sea type fibre is that polyurethane is that island, the polyethylene of deciding the island is the fiber of sea component; Described non-resilient islands-in-sea type fibre is to be that island, the polyethylene on indefinite island is the fiber of sea component with polyamide.
3, the raising method of a kind of elastic non-woven base fabric as claimed in claim 1, it is characterized in that described as the elasticity islands-in-sea type fibre fiber number and the thicker average fineness on the indefinite island of non-resilient islands-in-sea type fibre be 1: 1～10.
4, the raising method of a kind of elastic non-woven base fabric as claimed in claim 1 is characterized in that described contraction is that the elasticity needle-punching substrate shrinks through 90～98 ℃, 5～15 minutes hot water.
5, the raising method of a kind of elastic non-woven base fabric as claimed in claim 1 is characterized in that described upward water-soluble paste is the base cloth after shrinking, and is padded in the polyvinyl alcohol water solution that contains 5～15% weight entirely by roller mill.
6, the raising method of a kind of elastic non-woven base fabric as claimed in claim 1, the sanding after it is characterized in that described sanding first, open the sanding behind the fibre and rubbing leather is to adopt 60～100 successively respectively
#Rubber paper, 160～200
#Rubber paper sanding and 300～400
#Rubber paper carries out one side or two-sided sanding on roughing-up machine.
7, the raising method of a kind of elastic non-woven base fabric as claimed in claim 1 is characterized in that described upward adhesive is meant out that the aqueous solution that fine preceding base cloth solid content is 30% acrylate, 15～35% weight soaks.
8, the raising method of a kind of elastic non-woven base fabric as claimed in claim 1 is characterized in that the described fibre of opening is in organic solvent, pads the polyethylene of removing in the fiber with the padder with No. 5～20 rolls.
9, the raising method of a kind of elastic non-woven base fabric as claimed in claim 1 is characterized in that described destarch is 90～95 ℃ water-soluble poval destarch 1～15 minute.
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| CNB2005100305439A CN100350090C (en) | 2005-10-14 | 2005-10-14 | Raising method for elastic non-woven base fabric |
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| CNB2005100305439A CN100350090C (en) | 2005-10-14 | 2005-10-14 | Raising method for elastic non-woven base fabric |
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| CN100350090C CN100350090C (en) | 2007-11-21 |
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| CN100441765C (en) * | 2006-06-22 | 2008-12-10 | 时准 | High performance fibre nonwoven fabric and mfg. method thereof |
| CN102168345A (en) * | 2011-04-09 | 2011-08-31 | 浙江禾欣实业集团股份有限公司 | Method for preparing composite superfine fiber artificial leather base fabric |
| CN102704140A (en) * | 2012-06-05 | 2012-10-03 | 深圳圣龙实业发展有限公司 | Chemical fiber fabric and preparation method thereof |
| CN102797167A (en) * | 2012-09-10 | 2012-11-28 | 青岛新宇田化工有限公司 | Method for preparing ultra-fiber napped leather with directed fluff effect |
| CN103161029A (en) * | 2013-04-02 | 2013-06-19 | 大连华纶化纤工程有限公司 | Preparation method of composite non-woven fabrics fibrous membranes |
| CN104480693A (en) * | 2014-11-20 | 2015-04-01 | 江苏金太阳纺织科技有限公司 | Method for processing soft fluffy all-cotton sanded fabric |
| WO2015058568A1 (en) * | 2013-10-27 | 2015-04-30 | 江苏国信合成革有限公司 | Aqueous impregnated base fabric and preparation method thereof |
| CN105401336A (en) * | 2015-12-03 | 2016-03-16 | 怡星(无锡)汽车内饰件有限公司 | Vehicle carpet using unfigured island non-woven open-edge waste material |
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| JPH06293117A (en) * | 1993-02-09 | 1994-10-21 | Kanebo Ltd | Stretchable leather-like sheet article |
| JP2766474B2 (en) * | 1996-04-23 | 1998-06-18 | 鐘紡株式会社 | Polyurethane elastic fiber non-woven fabric |
| KR20010031584A (en) * | 1997-10-31 | 2001-04-16 | 야스이 쇼사꾸 | Nonwoven fabric, and sheetlike materials and synthetic leathers made by using the same |
| CN1074796C (en) * | 1999-03-11 | 2001-11-14 | 昌邑市无纺布厂 | Bundle superfine fibre polyurethane clothing shell material and its production method |
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| CN100441765C (en) * | 2006-06-22 | 2008-12-10 | 时准 | High performance fibre nonwoven fabric and mfg. method thereof |
| CN102168345A (en) * | 2011-04-09 | 2011-08-31 | 浙江禾欣实业集团股份有限公司 | Method for preparing composite superfine fiber artificial leather base fabric |
| CN102704140A (en) * | 2012-06-05 | 2012-10-03 | 深圳圣龙实业发展有限公司 | Chemical fiber fabric and preparation method thereof |
| CN102704140B (en) * | 2012-06-05 | 2014-11-26 | 深圳圣龙实业发展有限公司 | Chemical fiber fabric and preparation method thereof |
| CN102797167A (en) * | 2012-09-10 | 2012-11-28 | 青岛新宇田化工有限公司 | Method for preparing ultra-fiber napped leather with directed fluff effect |
| CN103161029B (en) * | 2013-04-02 | 2016-01-20 | 大连华纶化纤工程有限公司 | The preparation method of compound nonwoven cloth tunica fibrosa |
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| WO2015058568A1 (en) * | 2013-10-27 | 2015-04-30 | 江苏国信合成革有限公司 | Aqueous impregnated base fabric and preparation method thereof |
| CN104480693A (en) * | 2014-11-20 | 2015-04-01 | 江苏金太阳纺织科技有限公司 | Method for processing soft fluffy all-cotton sanded fabric |
| CN105401336A (en) * | 2015-12-03 | 2016-03-16 | 怡星(无锡)汽车内饰件有限公司 | Vehicle carpet using unfigured island non-woven open-edge waste material |
| CN107019958A (en) * | 2016-02-02 | 2017-08-08 | 东丽纤维研究所（中国）有限公司 | A kind of conducting filtration material and its production method |
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| CN110871604A (en) * | 2019-10-18 | 2020-03-10 | 南通亿华塑胶有限公司 | Flame-retardant automotive interior leather and preparation method thereof |
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