CN1740116A - Ceramic tile making process - Google Patents
Ceramic tile making process Download PDFInfo
- Publication number
- CN1740116A CN1740116A CN 200410051225 CN200410051225A CN1740116A CN 1740116 A CN1740116 A CN 1740116A CN 200410051225 CN200410051225 CN 200410051225 CN 200410051225 A CN200410051225 A CN 200410051225A CN 1740116 A CN1740116 A CN 1740116A
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- CN
- China
- Prior art keywords
- porcelain brick
- manufacture method
- preparation
- micro powder
- powder material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000000034 method Methods 0.000 title claims abstract description 33
- 239000000919 ceramic Substances 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 27
- 239000000843 powder Substances 0.000 claims abstract description 27
- 238000005516 engineering process Methods 0.000 claims abstract description 15
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 238000005498 polishing Methods 0.000 claims abstract description 6
- 230000003373 anti-fouling effect Effects 0.000 claims abstract description 3
- 238000005453 pelletization Methods 0.000 claims abstract 2
- 239000011449 brick Substances 0.000 claims description 44
- 229910052573 porcelain Inorganic materials 0.000 claims description 44
- 239000002245 particle Substances 0.000 claims description 28
- 238000002360 preparation method Methods 0.000 claims description 27
- 238000004519 manufacturing process Methods 0.000 claims description 18
- 239000003595 mist Substances 0.000 claims description 14
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 12
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 12
- -1 frit Substances 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 9
- 239000011707 mineral Substances 0.000 claims description 9
- 238000012545 processing Methods 0.000 claims description 8
- 239000004744 fabric Substances 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 7
- 238000000748 compression moulding Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 3
- 238000012805 post-processing Methods 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims 1
- 239000002002 slurry Substances 0.000 claims 1
- 239000000047 product Substances 0.000 abstract description 3
- 238000003825 pressing Methods 0.000 abstract 1
- 239000011265 semifinished product Substances 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 239000004575 stone Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 239000003086 colorant Substances 0.000 description 16
- 239000005995 Aluminium silicate Substances 0.000 description 8
- 235000012211 aluminium silicate Nutrition 0.000 description 8
- 239000004927 clay Substances 0.000 description 8
- 239000010433 feldspar Substances 0.000 description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 8
- 239000010453 quartz Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000000454 talc Substances 0.000 description 8
- 235000012222 talc Nutrition 0.000 description 8
- 229910052623 talc Inorganic materials 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 238000012216 screening Methods 0.000 description 6
- 238000000498 ball milling Methods 0.000 description 4
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 238000010298 pulverizing process Methods 0.000 description 4
- 229910021532 Calcite Inorganic materials 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
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- Compositions Of Oxide Ceramics (AREA)
Abstract
The ceramic tile making process has the micro powder technology, pattern permeating technology and crystallizing grain technology combined together. The ceramic tile making process includes the following steps: preparing micro powder material; preparing crystallizing grains and glaze grains; preparing melt block grains; mixing the micro powder material, crystallizing grains, glaze grains and melt block grains, and pressing the mixture to form, drying, permeating pattern, sintering and cooling to obtain semi-finished product; and edge cutting, polishing, and antifouling treatment to obtain the ceramic tile product. The crystallizing grains are made through dry pelletizing. The ceramic tile product has rich color and varying pattern similar to that of natural stone material.
Description
Technical field
The present invention relates to a kind of manufacture method of porcelain brick, refer in particular to a kind of in conjunction with micro mist, the manufacture method of oozing the flower and the polished brick in porcelain character of granule technology.
Background technology
As everyone knows, can be made into color and luster difference, porcelain brick that texture is different according to different complete processings.Traditional porcelain brick is mostly by becoming glaze with the thickening of the micro mist coloring ion aqueous solution, utilize the screen printing technology to be printed on the ceramic body surface then, spray enough sepages that helps again, with the coloring metal iontophoretic injection to briquet inside, fired at last, polishing forms, but only the porcelain brick pattern that productive technology makes is stereotyped by oozing, color is limited by coloring ion, and decorative effect does not still reach nature, smoothness.Therefore, in order to produce rich color, the diversified porcelain brick of pattern, people have added in the complete processing of porcelain brick oozes flower process, forms the decorative pattern of nature coating on porcelain brick, make porcelain brick have the art effect of broken sense, but still lack the natural texture and the texture of lithotome.
Therefore, provide a kind of production method of making rich color, pattern variation, not having the polished brick in porcelain character of repetition and the approximate lithotome of effect, very necessary with the shortcoming that overcomes prior art.
Summary of the invention
The object of the present invention is to provide a kind of production method of making rich color, pattern variation, not having the polished brick in porcelain character of repetition and the approximate lithotome of effect.
A kind of manufacture method of porcelain brick is characterized in that: it comprises the following steps:
(1) preparation micro powder material;
(2) preparation crystallographic texture particle and glaze grain;
(3) preparation frit grain;
(4) with oozing flower after the compression moulding drying behind micro powder material, crystallographic texture particle, glaze grain and the frit grain mixing cloth, burn till, get the porcelain brick work in-process after the cooling; Again it is carried out can obtaining the porcelain brick finished product after the aftertreatment.
Wherein, the preparation technology of micro powder material is as follows: at first prepare burden, adopt ceramic raw material mineral such as feldspar, quartz, clay, kaolin, Wingdale, talcum, thinner to mix, weigh by proportioning, to satisfy following chemical constitution (weight percent):
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO+MgO K
2O+Na
2O I.L
65～72％ 17～23％ 0～2％ 0～2％ ＜2％ 4.5～6.5％ ＜6％
Add various colorants 0～10%, wherein can select for use several colorants to mix.Then, to required fineness, through screening out iron, stock tank is old with the powder ball milling, spray pulverization, and it is old standby to put in storage at last.
Wherein, the crystallographic texture particle adopts the dry method granulation processes preparation of micro mist batch mixing secondary rolled, its preparation technology is as follows: at first prepare burden, adopt ceramic raw material mineral such as feldspar, quartz, clay, kaolin, Wingdale, talcum, thinner to mix, weigh by proportioning, to satisfy following chemical constitution (weight percent):
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO+MgO K
2O+Na
2O I.L
60～72％ 12～23％ 0～2％ 0～2％ ＜3.5％ 4～14％ ＜6％
Add various colorants 0～10%, wherein can select for use several colorants to mix.Standby by the powder process of micro powder material technology, then powder is polished into micro mist and mixes, through pre-press fit texture once, secondary rolled is promptly plastic, it is crushed to the particle of required size again, and getting size after screening is that 3～20 purpose particles put in storage standby.
Wherein, the preparation of glaze grain is identical with the preparation method of micro powder material, at first prepares burden, and adopts ceramic raw material mineral such as feldspar, quartz, clay, kaolin, Wingdale, talcum, thinner to mix, weigh by proportioning, to satisfy following chemical constitution (weight percent):
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO+MgO K
2O+Na
2O I.L
60～72％ 12～23％ 0～2％ 0～2％ ＜3.5％ 4～14％ ＜6％
Add various colorants 0～10%, wherein can select for use several colorants to mix, then, to required fineness, through screening out iron, stock tank is old with the powder ball milling, the spray pulverization granulation, and it is old standby to put in storage at last.
Wherein, the preparation technology of frit is as follows: at first prepare burden, adopt ceramic raw material mineral such as feldspar, quartz, clay, kaolin, Wingdale, talcum, thinner, calcite, lime carbonate, cobalt oxide, borax, barium carbonate to mix, weigh by proportioning, to satisfy following chemical constitution (weight percent):
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO MgO K
2O+Na
2O
55～63％ 6～10％ 0～0.5％ 0～0.5％ 6～18.5％ 0～3.5％ 3～7％
BaO BO ZnO ZrO
2 I.L
0～5％ 0～3％ 3～15％ 0～8％ ＜0.15％
Add various colorants 0～10%, wherein can select for use several colorants to mix, at 1430 ℃～1500 ℃ fusings, the sudden one-tenth particle of water frit, then the raw material frit of selecting for use is crushed to 10～100 orders, carry out iron removal step behind the thorough mixing, it is standby to put in storage.
Compared with prior art, the manufacture method of porcelain brick of the present invention has integrated single micro mist or has oozed productive technology, and produce the crystal grain that can produce natural texture with a kind of technology of creating, by the collocation of multiple color and specific processing parameter control cloth pattern, make micro mist, ooze flower and the combination each other of three kinds of technologies of particle, permeate each other, reached in appearance and compared the effect that is difficult to differentiate with lithotome, rich color, pattern variation, nothing repeat, the clear exquisiteness of superficial makings, well arranged, and the physicochemical property aspect has surmounted lithotome far away.
Description of drawings
Fig. 1 is the schema of micro powder material preparation of the present invention.
Fig. 2 is the schema of crystallographic texture granules preparation of the present invention.
Fig. 3 is the schema of porcelain brick preparation of the present invention.
Embodiment
Further set forth the present invention below in conjunction with accompanying drawing.
One, preparation micro powder material:
With reference to figure 1,11 prepare burden set by step, adopt ceramic raw material mineral such as feldspar, quartz, clay, kaolin, Wingdale, talcum, thinner to mix, weigh by proportioning, to satisfy following chemical constitution (weight percent):
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO+MgO K
2O+Na
2O I.L
65～72％ 17～23％ 0～2％ 0～2％ ＜2％ 4.5～6.5％ ＜6％
Add various colorants 0～10%, wherein can select for use several colorants to mix.
Next, carry out ball milling to required fineness according to step 12-16 in regular turn, through screening out iron, stock tank is old, spray pulverization, and it is old standby to put in storage at last.
Two, preparation crystallographic texture particle:
Adopt the dry method granulation processes of micro mist batch mixing secondary rolled to prepare the crystallographic texture particle, with reference to figure 2,21 prepare burden set by step, adopt ceramic raw material mineral such as feldspar, quartz, clay, kaolin, Wingdale, talcum, thinner to mix, weigh by proportioning, to satisfy following chemical constitution (weight percent):
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO+MgO K
2O+Na
2O I.L
60～72％ 12～23％ 0～2％ 0～2％ ＜3.5％ 4～14％ ＜6％
Add various colorants 0～10%, wherein can select for use several colorants to mix, prepare powder by technique for producing miropowder.
Next, according to step 22-27 the toner material is polished into micro mist in regular turn, then by the said ratio thorough mixing, through pre-press fit texture once, formation is similar to the texture of lithotome, it is promptly plastic to pass through secondary rolled again, it is crushed to the particle of required size again, and getting size after screening is that 3～20 purpose particles put in storage standby.
Three, preparation glaze grain:
The preparation of glaze grain is identical with the preparation method of micro powder material, with reference to figure 1,11 prepare burden set by step, adopt ceramic raw material mineral such as feldspar, quartz, clay, kaolin, Wingdale, talcum, thinner to mix, weigh by proportioning, to satisfy following chemical constitution (weight percent):
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO+MgO K
2O+Na
2O I.L
60～72％ 12～23％ 0～2％ 0～2％ ＜3.5％ 4～14％ ＜6％
Add various colorants 0～10%, wherein can select for use several colorants to mix.
Next, carry out ball milling to required fineness according to step 12-16 in regular turn, through screening out iron, stock tank is old, the spray pulverization granulation, and it is old standby to put in storage at last.
Four, preparation frit:
Adopt ceramic raw material mineral such as feldspar, quartz, clay, kaolin, Wingdale, talcum, thinner, calcite, lime carbonate, cobalt oxide, borax, barium carbonate to mix, weigh by proportioning, to satisfy following chemical constitution (weight percent):
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO MgO K
2O+Na
2O
55～63％ 6～10％ 0～0.5％ 0～0.5％ 6～18.5％ 0～3.5％ 3～7％
BaO BO ZnO ZrO
2 I.L
0～5％ 0～3％ 3～15％ 0～8％ ＜0.15％
Add various colorants 0～10%, wherein can select for use several colorants to mix, 1430 ℃～1500 ℃ fusings, the sudden one-tenth particulate state of water frit.Frit is crushed to 8～20 orders, carries out iron removal step behind the thorough mixing, it is standby to put in storage.
Five, preparation porcelain brick:
In the present embodiment, micro powder material is selected three kinds of toners for use, and it is formed and proportioning is: pale red material: 30%, and white material: 13%, pale yellow material: 50%; The crystallographic texture particle is selected two kinds of particles for use: it is formed and proportioning is: white particle: 2%, and pale yellow particle: 2%; In addition, the frit proportioning is 2%, glaze grain 1%.
With reference to figure 3, at first set by step 30 pale red material, white material, pale yellow material with above-mentioned micro powder material on request the powder feeding polishing to 20～250 orders, simultaneously, with fully mixing the back cloth by said ratio feeding to press cloth system without the white material particle in the crystallographic texture particle of polishing and pale yellow particle, frit and glaze grain; The porcelain brick of the required specification of compression moulding in press die, step 31; Again with the porcelain brick drying machine drying, the drifting dust that are shaped, step 32; Next, by printing machine porcelain brick is carried out stamp and handle, form various floral designs, step 33; Afterwards, on porcelain brick, spray water or help sepage to help and ooze, make the coloring metal ion-transfer, be penetrated on the ceramic briquet step 34; Then porcelain brick was burnt till under 1190～1210 ℃ temperature 60～75 minutes, step 35, i.e. formation has micro mist, oozes flower and crystallographic texture particulate porcelain brick; At last, 36-39 carries out postprocessing working procedures set by step, with packing warehouse-in after its cooling, side cut, polishing, the antifouling processing.
In the present invention, in the porcelain brick manufacturing processing technic, add the overall aesthetic that the particle with crystallization and grain effect has increased porcelain brick, wherein crystallographic texture particulate color spot has transparent or semitransparent texture, the natural and tripping distribution of its texture, the utmost point is like the natural texture of lithotome, broken aesthetic feeling is arranged, and rich color, pattern variation, do not have and repeat.
In another embodiment of the present invention, in mix, can not add frit.
In yet another embodiment of the present invention, also can omit and ooze flower processing technique, formation has micro mist and crystallographic texture particulate porcelain brick.
In yet another embodiment of the present invention, also can omit crystallographic texture particle complete processing, do not add the crystallographic texture particle in mix, formation has micro mist and oozes colored porcelain brick.
Above disclosed only is preferred embodiment of the present invention, can not limit the present invention's interest field certainly with this, and therefore the equivalent variations of being done according to the present patent application claim still belongs to the scope that the present invention is contained.
Claims (10)
1. the manufacture method of a porcelain brick, it is characterized in that: it comprises the following steps:
(1) preparation micro powder material;
(2) preparation crystallographic texture particle and glaze grain;
(3) preparation frit grain;
(4) with compression moulding behind micro powder material, crystallographic texture particle, glaze grain and the frit grain mixing cloth, ooze flower after the drying, burn till, get the porcelain brick work in-process after the cooling; Again it is carried out can obtaining the porcelain brick finished product after the aftertreatment.
2. the manufacture method of a kind of porcelain brick according to claim 1, it is characterized in that: described porcelain brick preparation method further comprises the preparation frit.
3. the manufacture method of a kind of porcelain brick according to claim 1 is characterized in that: the non-slurry pelletizing of described crystallographic texture particle employing micro mist batch mixing secondary rolled.
4. according to the manufacture method of claim 1 or 3 described a kind of porcelain brick, it is characterized in that: described crystallographic texture granule preparing process is as follows: (1) selects the powder process of preparing burden of ceramic raw material mineral for use; (2) powder is polished into micro mist, mixes by a certain percentage; (3) micro mist is through pre-press fit texture; (4) through the roll forming briquet; (5) the moulding briquet is broken into the particle of certain order number.
5. the manufacture method of a kind of porcelain brick according to claim 2, it is characterized in that: the preparation technology of described porcelain brick is as follows: after (1) will polish micro powder material mix with glaze grain, crystallographic texture particle, frit, cloth; (2) with mix compression moulding; (3) drying; (4) stamp; (5) water spray helps and oozes; (6) under 1190～1210 ℃ temperature, burnt till 60～75 minutes; (7) cooling; Postprocessing working procedures such as (8) polishing, side cut, antifouling processing.
6. the manufacture method of a kind of porcelain brick according to claim 1 is characterized in that: described crystallographic texture particulate composition range, and weight percent, as follows:
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO+MgO K
2O+Na
2O I.L
60～72％ 12～23％ 0～2％ 0～2％ ＜3.5％ 4～14％ ＜6％
7. the manufacture method of a kind of porcelain brick according to claim 1 is characterized in that: the composition range of described micro powder material, and weight percent, as follows:
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO+MgO K
2O+Na
2O I.L
65～72％ 17～23％ 0～2％ 0～2％ ＜2％ 4.5～6.5％ ＜6％
8. the manufacture method of a kind of porcelain brick according to claim 1 is characterized in that: the composition range of described glaze grain, and weight percent, as follows:
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO+MgO K
2O+Na
2O I.L
60～72％ 12～23％ 0～2％ 0～2％ ＜3.5％ 4～14％ ＜6％
9. the manufacture method of a kind of porcelain brick according to claim 1 is characterized in that: the composition range of described frit, and weight percent, as follows:
SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO MgO K
2O+Na
2O
55～63％ 6～10％ 0～0.5％ 0～0.5％ 6～18.5％ 0～3.5％ 3～7％
BaO BO ZnO ZrO
2 I.L
0～5％ 0～3％ 3～15％ 0～8％ ＜0.15％
10. the manufacture method of a porcelain brick, it is characterized in that: it comprises the following steps:
(1) preparation micro powder material;
(2) preparation crystallographic texture particle;
(5) with oozing flower after the compression moulding drying behind micro powder material and the crystallographic texture particle mixing cloth, burn till, get the porcelain brick work in-process after the cooling; Again it is carried out can obtaining the porcelain brick finished product after the aftertreatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100512256A CN1300059C (en) | 2004-08-26 | 2004-08-26 | Ceramic tile making process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100512256A CN1300059C (en) | 2004-08-26 | 2004-08-26 | Ceramic tile making process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1740116A true CN1740116A (en) | 2006-03-01 |
| CN1300059C CN1300059C (en) | 2007-02-14 |
Family
ID=36092671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100512256A Active CN1300059C (en) | 2004-08-26 | 2004-08-26 | Ceramic tile making process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1300059C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008011786A1 (en) * | 2006-07-20 | 2008-01-31 | Guangdong Dongpeng Ceramic Company Limited | Preparation method of a tile with solid pores as decoration and its product |
| CN101805209A (en) * | 2010-04-21 | 2010-08-18 | 伟业陶瓷有限公司 | Matt porcelain glaze prepared by using waste porcelains and production method thereof |
| CN102219382A (en) * | 2011-03-31 | 2011-10-19 | 广东道氏技术股份有限公司 | Frit for full polish and preparation method thereof |
| CN101177352B (en) * | 2006-11-10 | 2011-11-23 | 霍炳祥 | Method for solving glaze lamination of ceramic products |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1226228C (en) * | 2003-02-21 | 2005-11-09 | 中国地质大学（武汉） | Gangue ceramic brick and making method thereof |
| CN1208172C (en) * | 2003-07-18 | 2005-06-29 | 范玉容 | Method for manufacturing ceramic bricks possessing transparent or semitransparent colour spots or color lamps |
-
2004
- 2004-08-26 CN CNB2004100512256A patent/CN1300059C/en active Active
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008011786A1 (en) * | 2006-07-20 | 2008-01-31 | Guangdong Dongpeng Ceramic Company Limited | Preparation method of a tile with solid pores as decoration and its product |
| EP2053031A1 (en) * | 2006-07-20 | 2009-04-29 | Guangdong Dongpeng Ceramic Company Limited | Preparation method of a tile with solid pores as decoration and its product |
| AU2007278700B2 (en) * | 2006-07-20 | 2010-09-23 | Dongpeng Holdings Company Limited | Preparation method of a tile with solid pores as decoration and its product |
| EP2053031A4 (en) * | 2006-07-20 | 2011-06-08 | Guangdong Dongpeng Ceramic Company Ltd | Preparation method of a tile with solid pores as decoration and its product |
| KR101086292B1 (en) | 2006-07-20 | 2011-11-24 | 광동 동펭 쎄라믹 컴퍼니 리미티드 | Preparation method of a tile with solid pores as decoration and its product |
| CN101177352B (en) * | 2006-11-10 | 2011-11-23 | 霍炳祥 | Method for solving glaze lamination of ceramic products |
| CN101805209A (en) * | 2010-04-21 | 2010-08-18 | 伟业陶瓷有限公司 | Matt porcelain glaze prepared by using waste porcelains and production method thereof |
| CN101805209B (en) * | 2010-04-21 | 2012-01-04 | 伟业陶瓷有限公司 | Matt porcelain glaze prepared by using waste porcelains and production method thereof |
| CN102219382A (en) * | 2011-03-31 | 2011-10-19 | 广东道氏技术股份有限公司 | Frit for full polish and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1300059C (en) | 2007-02-14 |
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