CN1736927A - Sunshine control film glass series of three-layer film structure - Google Patents
Sunshine control film glass series of three-layer film structure Download PDFInfo
- Publication number
- CN1736927A CN1736927A CN 200510028802 CN200510028802A CN1736927A CN 1736927 A CN1736927 A CN 1736927A CN 200510028802 CN200510028802 CN 200510028802 CN 200510028802 A CN200510028802 A CN 200510028802A CN 1736927 A CN1736927 A CN 1736927A
- Authority
- CN
- China
- Prior art keywords
- layer
- snox
- glass
- tin
- sputter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims abstract description 29
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910006854 SnOx Inorganic materials 0.000 claims abstract description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012528 membrane Substances 0.000 claims abstract description 8
- 239000000758 substrate Substances 0.000 claims abstract description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 14
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 229910052786 argon Inorganic materials 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910001220 stainless steel Inorganic materials 0.000 claims description 5
- 239000010935 stainless steel Substances 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- VVTSZOCINPYFDP-UHFFFAOYSA-N [O].[Ar] Chemical compound [O].[Ar] VVTSZOCINPYFDP-UHFFFAOYSA-N 0.000 claims description 3
- 229910001882 dioxygen Inorganic materials 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 229910001256 stainless steel alloy Inorganic materials 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 2
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 2
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 claims 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052709 silver Inorganic materials 0.000 abstract description 3
- 239000004332 silver Substances 0.000 abstract description 3
- PWKWDCOTNGQLID-UHFFFAOYSA-N [N].[Ar] Chemical compound [N].[Ar] PWKWDCOTNGQLID-UHFFFAOYSA-N 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 13
- 239000010408 film Substances 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 4
- 238000002310 reflectometry Methods 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229910000498 pewter Inorganic materials 0.000 description 1
- 239000010957 pewter Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Surface Treatment Of Glass (AREA)
- Physical Vapour Deposition (AREA)
Abstract
The invention provides a sunshine control membrane glass of triplex-layer membrane series. Wherein, from glass substrate to exterior, it is glass, SnOx to sputter at mixed argon-nitrogen by tin target of plane DC cathode and/or rotation DC cathode, SSTNx to sputter at pure nitrogen atmophere by 316L of plane DC cathode, and SnOx to sputter at pure oxygen atmosphere by tin target of rotation DC cathode. The product shows modern silver gray, has proper permeance rate and soft color and well other performances.
Description
Technical field
The present invention is a kind of serial solar control film glass that is coated with three layers of different thin-film material.
Background technology
Traditional solar control film glass is with low transmitance, high reflectivity is main, after entering 21 century, there has been new requirement in market to the application of solar control film: 1) traditional low light transmission, dark color, high reflective mirror surface type glass are replaced 2 by high pass printing opacity, glass that tone is soft gradually) people pay attention to avoiding strong reflection light stimulus, indoor abundant natural illumination, insulation, energy-conservation more.Solar control film glass that market is common or color are blue partially, though it is too low that color is silver gray light-permeable rate, it is oppressive that the occupant feels in doors, sight line is interfered, and it seems that the not only outward appearance that none is more suitable present the silver gray of modern sense but also make indoor occupant feel penetrating comfortable solar control film glass.We think that visible light transmissivity of exploitation is moderate, and reflection colour is moderate has the silver-gray serial solar control film glass of modern sense, can satisfy this demand in market.
Summary of the invention
The invention provides the serial solar control film glass that a kind of trilamellar membrane is, outwards be followed successively by from glass substrate: be coated with the film of three layers of differing materials on glass substrate, each layer structure is as follows:
Glass/SnOx/SSTNx/SnOx promptly plates stannic oxide, nitrogen stainless Steel Alloy (316L), stannic oxide successively on glass substrate.
The process for plating of each rete is:
(1) the first layer SnOx: by metal tin target sputter in the argon oxygen gas mixture of direct current negative electrode, argon, oxygen are 0-30%Ar than just, 100-70%O
2, thicknesses of layers is 8-35mm, can increase transmitance in the certain thickness scope, reduces reflectivity, makes reflection colour be neutral gray, and is strong with glass attachment power.
(2) second layer nitrided stainless steel layer SSTNx: by Stainless Steel Alloy target (316L) sputter in pure nitrogen gas of direct current negative electrode, thicknesses of layers is 8-30mm, utilize its spectral absorption characteristics to reduce transmitance, make the rete transmission present neutral pewter partially, give a kind of soft, refrigerant comfortable visual experience of people, have the sun shading and energy-saving effect.
(3) the 3rd layers of stannic oxide layer SnOx: by metal tin target sputter (100%O in purity oxygen of direct current negative electrode
2), thicknesses of layers is 15-30mm, protective layer, and the wear resisting property and the acid-proof alkaline of raising rete are regulated its thickness simultaneously and can be adjusted the rete reflected colour.This layer adopts the pure oxygen sputtering technology, can guarantee the SnOx rete almost with the form deposition of 100%SnO2.Than the argon oxygen gas mixture sputtering technology (containing SnO) that generally adopts, the SnO2 purity of rete is higher, has better acid and alkali-resistance and anti-nonferromagnetic substance, and weathering resistance is also better.
Embodiment
Embodiments of the invention are: adopt horizontal both-end continous way coating equipment, comprise 6 rotation direct current negative electrodes, 9 plane direct current negative electrodes.When producing, use two plane direct current negative electrodes, four rotation direct current negative electrodes.Following table has been listed the processing parameter of the serial solar control film glass of making trilamellar membrane of the present invention system.
Be coated with the serial solar control film glass of SnOx/SSTNx/SnOx trilamellar membrane
Target position distributes and processing parameter
| The target position sequence number | Cathode type | Target material | Sputtering technology air pressure (h Pa) | The process gas composition | Thicknesses of layers (nm) |
| 1# | Plane direct current negative electrode | Tin | 3.3×10 -3 | Nitrogen: argon=(100-70): (0-30) | 8-35 |
| 2# | Rotation direct current negative electrode | Tin | 4.1×10 -3 | Oxygen: argon=(100-70): (0-30) | |
| 3# | Rotation direct current negative electrode | Tin | 4.1×10 -3 | Oxygen: argon=(100-70): (0-30) | |
| 4# | Plane direct current negative electrode | Stainless steel (316L) | 2.9×10 -3 | Purity nitrogen | 8-30 |
| 5# | Rotation direct current negative electrode | Tin | 4.1×10 -3 | Pure oxygen | 15-50 |
| 6# | Rotation direct current negative electrode | Tin | 4.1×10 -3 | Pure oxygen |
The optical property of the solar control film glass made from above-mentioned processing parameter is as follows:
The visible light transmissivity T=25-50% of coated glass,
Visible light glass surface reflectivity Rg=20-32%
Visible light glass surface chromaticity coordinates a
*Value=-2--3
Chromaticity coordinates b
*Value=-3.0--7.
Claims (2)
1, a kind of serial solar control film glass of trilamellar membrane architecture is characterized in that:
Be coated with the rete of three-decker at glass substrate, each tunic layer structure outwards is followed successively by from glass substrate:
Glass/tin layer SnOx/ nitrided stainless steel layer SSTNx/ tin layer SnOx;
Wherein: younger brother's one deck tin thickness is 8-35mm, and second layer nitrided stainless steel layer thickness is 8-30mm, and the 3rd layer of tin thickness is 15-50mm.
2, a kind of serial solar control film glass producing process of trilamellar membrane architecture is characterized in that each layer coating process is respectively:
The first layer stannic oxide layer SnOx: by metal tin target sputter in the argon oxygen gas mixture of direct current negative electrode, argon, oxygen proportion are 0-30%Ar, 100-70%O2;
Second layer nitrided stainless steel layer SSTNx: by Stainless Steel Alloy target 316L sputter in pure nitrogen gas of direct current negative electrode;
The 3rd layer of stannic oxide layer SnOx: by metal tin target sputter in purity oxygen of direct current negative electrode.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100288024A CN100345787C (en) | 2005-08-15 | 2005-08-15 | Sunshine control film glass series of three-layer film structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100288024A CN100345787C (en) | 2005-08-15 | 2005-08-15 | Sunshine control film glass series of three-layer film structure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1736927A true CN1736927A (en) | 2006-02-22 |
| CN100345787C CN100345787C (en) | 2007-10-31 |
Family
ID=36079915
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100288024A Expired - Fee Related CN100345787C (en) | 2005-08-15 | 2005-08-15 | Sunshine control film glass series of three-layer film structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100345787C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101670743B (en) * | 2008-09-10 | 2012-09-26 | 比亚迪股份有限公司 | Bicolor basal plate and method for preparing same |
| CN106565113A (en) * | 2016-11-03 | 2017-04-19 | 武汉理工大学 | Colorful non-conducting metallic luster printed and film-coated ornamental glass and preparation method therefor |
| CN113998900A (en) * | 2021-11-30 | 2022-02-01 | 太仓耀华玻璃有限公司 | Method for manufacturing magnetron sputtering solar control film toughened glass |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1117175C (en) * | 1999-09-09 | 2003-08-06 | 苏州华东镀膜玻璃有限公司 | Process for coating on glass to simulate low-radiation film and able to be thermally treated |
| CN2397111Y (en) * | 1999-10-19 | 2000-09-20 | 洛阳晶润镀膜玻璃有限公司 | Purple coated glass with composite film layer |
-
2005
- 2005-08-15 CN CNB2005100288024A patent/CN100345787C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101670743B (en) * | 2008-09-10 | 2012-09-26 | 比亚迪股份有限公司 | Bicolor basal plate and method for preparing same |
| CN106565113A (en) * | 2016-11-03 | 2017-04-19 | 武汉理工大学 | Colorful non-conducting metallic luster printed and film-coated ornamental glass and preparation method therefor |
| CN113998900A (en) * | 2021-11-30 | 2022-02-01 | 太仓耀华玻璃有限公司 | Method for manufacturing magnetron sputtering solar control film toughened glass |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100345787C (en) | 2007-10-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: TIANJIN YAOPI ENGINEERING GLASS CO., LTD. Free format text: FORMER OWNER: SHANGHAI YAOHUA PILKINGTON GLASS CO., LTD. Effective date: 20091120 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C56 | Change in the name or address of the patentee | ||
| CP03 | Change of name, title or address |
Address after: 75, Kang Liu Road, Cambridge Industrial Area, Pudong, Shanghai, zip code: 201315 Co-patentee after: SHANGHAI YAOPI BUILDING GLASS Co.,Ltd. Patentee after: Shanghai Yaohua Pilkington Glass Co.,Ltd. Address before: 75, Kang Liu Road, Cambridge Industrial Area, Pudong, Shanghai, zip code: 201315 Co-patentee before: Shanghai Sunshine Coated Glass Co.,Ltd. Patentee before: Shanghai Yaohua Pilkington Glass Co.,Ltd. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20091120 Address after: 1, Huatai Road, Beichen science and Technology Park, Tianjin, China: 300409 Patentee after: TIANJIN SYP ENGINEERING GLASS GROUP Co.,Ltd. Address before: 75, Kang Liu Road, Cambridge Industrial Area, Pudong, Shanghai, zip code: 201315 Co-patentee before: SHANGHAI YAOPI BUILDING GLASS Co.,Ltd. Patentee before: Shanghai Yaohua Pilkington Glass Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20071031 Termination date: 20200815 |
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| CF01 | Termination of patent right due to non-payment of annual fee |