CN1730557A - Resin and plastic belt pulley and its manufacturing method - Google Patents

Resin and plastic belt pulley and its manufacturing method Download PDF

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Publication number
CN1730557A
CN1730557A CN 200510029568 CN200510029568A CN1730557A CN 1730557 A CN1730557 A CN 1730557A CN 200510029568 CN200510029568 CN 200510029568 CN 200510029568 A CN200510029568 A CN 200510029568A CN 1730557 A CN1730557 A CN 1730557A
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China
Prior art keywords
resin
belt pulley
plastic belt
cladding material
resol
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CN 200510029568
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Chinese (zh)
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CN100412134C (en
Inventor
王东川
柯枫
罗思东
刘启志
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SAIC Motor Corp Ltd
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SAIC Motor Corp Ltd
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Abstract

Disclosed is a resin and plastic belt pulley and its manufacturing method, wherein the belt sheave includes an inner layer and an outer layer, the outer layer is made of materials including phenol resin, inorganic powder, fortifying fiber and demoulding agent. The inorganic filler is preferably nano silicon oxide, the fortifying fiber is preferably glass fiber, the phenolic resin is preferably linear phenolic resin or soluble phenolic resin.

Description

Resin and plastic belt pulley and manufacture method thereof
Technical field
The present invention relates to a kind of belt pulley and manufacture method thereof, particularly a kind of engine the surrounding area resin and plastic belt pulley and manufacture method thereof of recovery easily of being used for.
Background technology
Common automobile-used belt pulley mainly contains two kinds of steel belt pulley and plastic belt pulleys.The steel belt pulley is owing to the reason of weight and noise is progressively replaced by plastic belt pulley.The material of plastic belt pulley is generally the galss fiber reinforced resin material, wherein resin can be resol and nylon etc., and resol is thermosetting material, is difficult to reclaim, and glass strengthens resol must make phenolic resin curing in moulding, reduced production efficiency; Nylon belongs to thermoplastic material, reclaims easily, and glass fiber enhanced nylon also can be processed by common injection moulding, but its dimensional stability, wearability and thermotolerance all strengthen resol not as glass.
Report among the Japanese Patent JP8-159244, in resol, add the resin pulley that a kind of inorganic powder in lime carbonate, clay and the wollastonite and mica powder and glass fibre constitute, because the abrasion resistance properties of inorganic powder shown in above-mentioned and mica powder is relatively poor, especially in dust atmosphere.Glass described in the Chinese patent 03157726.1 strengthens the resol belt pulley and has good dimensional precision, high strength and excellent in abrasion resistance, select linear phenolic resin or solvable type resol for use, its number-average molecular weight should be limited between 600~900, but is difficult to injection-molded moulding, and resol is thermosetting material in addition, be difficult to reclaim, and glass strengthens resol after injection molding, must make phenolic resin curing, influenced its processing characteristics.Therefore, though the phenolic plastics belt pulley has been realized the lightweight of belt pulley, be difficult to reclaim, and be difficult for forming process.
Summary of the invention
The purpose of this invention is to provide a kind of its excellent in abrasion resistance, have good dimensional precision, in light weight, low-cost and easy recycling resin and plastic belt pulley and manufacture method thereof.
For achieving the above object, resin and plastic belt pulley of the present invention is divided into inside and outside two-layer, wherein,
Inner layer material is: nylon 66 accounts for 20~40 weight %, lime carbonate 1~10 weight %, glass fibre 10~30 weight %.
Cladding material is: resol 20~40 weight %, inorganic powder 0.5~5 weight %, fortifying fibre 10~30 weight % and remover 0.5~5 weight %.
Among the present invention, also a metal core be can fix in the middle of the described resin and plastic belt pulley, thereby dimensional precision, intensity and shock resistance improved.
A kind of manufacture method of resin and plastic belt pulley may further comprise the steps,
At first, prepare above-mentioned inner layer material and cladding material,
Secondly, inner layer material injected in injection moulding forming machine charge into mould, behind overcooling, demoulding, described parts are put among another die casting that is heated to the cladding material solidification value in advance, this mould has and the corresponding die cavity of the shape of resin pulley main body, is full of cladding material in die cavity, close die, pressurization makes the cladding material curing molding.
The process of wherein making inner layer material can be, earlier whole inner layer materials placed homogenizer, heats and stirs.Preferred 120 ℃ of the temperature of wherein said heating.
In addition, also can fix a metal core in described mould central authorities, and make parts by embedding methods such as moulding, behind overcooling, demoulding, described parts are put among another die casting that is heated to the cladding material solidification value in advance again, and be fixed on the centre, this mould has and the corresponding die cavity of the shape of resin pulley main body, in die cavity, be full of cladding material, close die, pressurize, and be retained to solidification value for some time of cladding material resin, make the cladding material curing molding obtain resin and plastic belt pulley.
Among the present invention, described resol, preferred linear phenolic resin or solvable type resol.
Among the present invention, the preferred nano-silica powder of described inorganic powder end owing to little, the easy dispersion of nano-silica powder end particle, can be evenly dispersed in the resin and plastic belt pulley material, thereby improves the abrasion resistance properties of plastic belt pulley.
Among the present invention, described fortifying fibre preferred glass fibers, thereby Reinforced Nylon 66 better improve dimensional precision, intensity and the shock resistance of plastic belt pulley.
Resin and plastic belt pulley provided by the invention, its excellent in abrasion resistance has good dimensional precision, and is in light weight, low cost, and recycling easily.And this belt pulley has thermoplastic plastic belt pulley and thermosetting resin belt pulley advantage concurrently.
Embodiment
Following examples are only for further specifying the present invention, are not violating under the purport of the present invention, and the present invention should be not limited to the content that following experimental example is specifically expressed.
Resin and plastic belt pulley in the listed examples of the present invention comprises inside and outside two-layer, wherein,
Inner layer material: nylon 66 accounts for 20~40 weight %, lime carbonate 1~10 weight %, glass fibre 10~30 weight %.
Cladding material: resol 20~40 weight %, nano silicon 0.5~5 weight %, glass fibre 10~30 weight % and remover 0.5~5 weight %.
As resol, preferred linear phenolic resin and/or solvable type resol.(among the embodiment, specify,, its ratio separately be described then) if two kinds of compositions all have to any
In the manufacturing processed, in advance nylon 66 is put into baking oven and dried 4h down at 100 ℃, nylon 66 and glass fibre (ratio is 50 weight %) place homogenizer then, then are heated to 120 ℃ to stir preparation glass fiber enhanced nylon 66 moulding compound.
Then glass fiber reinforced nylon 66 moulding compounds are injected in injection moulding forming machine and charged into mould, this mould central authorities fixing metal fuse, make parts by embedding methods such as moulding, through overcooling, behind the demoulding, described parts are put among another die casting that is heated to the cladding material solidification value in advance, and be fixed on the centre, this mould has and the corresponding die cavity of the shape of resin pulley main body, in die cavity, be full of cladding material, close die, pressurize, and be retained to solidification value for some time of cladding material resin, make the cladding material curing molding obtain resin and plastic belt pulley.
Embodiment 1~5 is each components contents of belt pulley for a change, makes resin and plastic belt pulley by above-mentioned identical mode.
Wear-resistant test: will wait that the belt pulley that tries embodiment is assemblied on the test support, at tensile force 1922N, under the condition of rotating speed 6000RPM, rotates 3 * 10 continuously 7Inferior, observe the fatigue failure phenomenon whether occurs.Simultaneously, measure the wearing and tearing thickness (mm) of pulley surface, and estimate the abrasion resistance properties of belt pulley in view of the above, the result is as shown in table 1.
Table 1
Embodiment
1 2 3 4 5
Component (weight percent) Internal layer Nylon 66 20 20 30 40 20
Glass fibre 20 20 20 10 20
Lime carbonate 4.5 3 5 10 5
Outer Resol resin 30 40 20 20 20
Glass fibre 20 10 20 15 30
Nano silicon 0.5 5 3 3 4.5
Releasing agent 5 2 2 2 0.5
Evaluation result Whether fatigue failure Not Not Not Not Not
Wearing and tearing thickness (mm) 0.33 0.20 0.23 0.23 0.21
Table 2
Prior art products embodiment
6 7
Component Resol resin 45 50
Amorphous silica powder 5 7
Glass fibre 45 40
Releasing agent 5 3
Evaluation result Whether fatigue failure Be Be
Wearing and tearing thickness 0.52 0.48
Table 2 is the usual production that prior art is produced, and can obviously find out from table 1 and table 2, adopts belt pulley that the present invention program makes than prior art products antifatigue more, and its wear resisting property is excellent more.

Claims (10)

1. resin and plastic belt pulley is characterized in that: comprise inside and outside two-layerly, inner layer material component and weight percent thereof be, nylon 66 accounts for 20~40%, lime carbonate 1~10%, glass fibre 10~30%; Cladding material component and weight percent thereof are resol 20~40%, inorganic powder 0.5~5%, fortifying fibre 10~30% and remover 0.5~5%.
2. resin and plastic belt pulley according to claim 1 is characterized in that: also fix a metal core in the middle of the described resin and plastic belt pulley.
3. resin and plastic belt pulley according to claim 1 and 2 is characterized in that: described mineral filler is a nano silicon.
4. resin and plastic belt pulley according to claim 1 and 2 is characterized in that: described fortifying fibre is a glass fibre.
5. resin and plastic belt pulley according to claim 1 and 2 is characterized in that: described resol is linear phenolic resin and/or solvable type resol.
6. the manufacture method of a resin and plastic belt pulley may further comprise the steps,
At first, preparation inner layer material and cladding material, wherein said inner layer material component and weight percent thereof be, nylon 66 accounts for 20~40%, lime carbonate 1~10%, glass fibre 10~30%; Cladding material component and weight percent thereof are resol 20~40%, inorganic powder 0.5~5%, fortifying fibre 10~30% and remover 0.5~5%;
Secondly, inner layer material injected in injection moulding forming machine charge into mould, behind overcooling, demoulding, described parts are put among another die casting that is heated to the cladding material solidification value in advance, this mould has and the corresponding die cavity of the shape of resin pulley main body, is full of cladding material in die cavity, close die, pressurization makes the cladding material curing molding.
7. the manufacture method of resin and plastic belt pulley according to claim 6 is characterized in that: in making and the process of cladding material for whole internal layers and cladding material are placed homogenizer respectively, heat and stir.
8. the manufacture method of resin and plastic belt pulley according to claim 7, it is characterized in that: the temperature of wherein said heating is 120 ℃.
9. according to the manufacture method of claim 6,7 or 8 described resin and plastic belt pulleys, it is characterized in that: also be fixed with a metal core in described mould central authorities, again inner layer material injected in injection moulding forming machine afterwards and charged into mould.
10. according to the manufacture method of claim 6,7 or 8 described resin and plastic belt pulleys, it is characterized in that: described mineral filler is a nano silicon, described fortifying fibre is a glass fibre, described mineral filler is a nano silicon, and described resol is linear phenolic resin and/or solvable type resol.
CNB2005100295687A 2005-09-12 2005-09-12 Resin and plastic belt pulley and its manufacturing method Active CN100412134C (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102922639A (en) * 2012-11-23 2013-02-13 昆山博爱模具开发有限公司 Mold core for injection mold of belt pulley
CN103252896A (en) * 2012-02-20 2013-08-21 武云 Glass fiber reinforced plastic product processing process and device
CN104017359A (en) * 2014-06-19 2014-09-03 王茜南 Nano-modified nylon material and preparation method thereof
CN105605195A (en) * 2016-03-18 2016-05-25 营口金辰机械股份有限公司 Plastic synchronous pulley and manufacturing process thereof
CN111133230A (en) * 2018-06-19 2020-05-08 阪东化学株式会社 Toothed belt wheel
CN112105843A (en) * 2018-05-22 2020-12-18 舍弗勒技术股份两合公司 Pulley decoupler with injection molded belt track, plain bearing and axial friction ring and method of making same

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JPS5615334A (en) * 1979-07-19 1981-02-14 Mitsubishi Chem Ind Ltd Injection forming of polyamide resin
CN1045937A (en) * 1989-03-30 1990-10-10 彭培德 Phenoplasts polishing wheel (rod) and manufacture method and former
JP3032584B2 (en) * 1990-12-28 2000-04-17 三菱化学株式会社 Method for improving appearance of fiber-reinforced thermoplastic resin molded product
US5922626A (en) * 1994-12-14 1999-07-13 Hp-Chemie Research And Development Ltd. Self-adhering reinforcing material for nonwoven textile fabrics
CN1109001A (en) * 1994-12-30 1995-09-27 北京云港特种塑料制品公司 Engineering plastic products
DE19532720A1 (en) * 1995-09-05 1997-03-06 Basf Ag Flame retardant thermoplastic molding compounds
JPH10330613A (en) * 1997-05-30 1998-12-15 Asahi Chem Ind Co Ltd Glass fiber reinforced polyamide resin for welding
JP3406816B2 (en) * 1997-11-19 2003-05-19 カネボウ株式会社 Thermoplastic resin composition
CN2687428Y (en) * 2003-06-21 2005-03-23 重庆市泰伯铸型尼龙有限责任公司 High strength modified nylon mould compound wheel

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103252896A (en) * 2012-02-20 2013-08-21 武云 Glass fiber reinforced plastic product processing process and device
CN102922639A (en) * 2012-11-23 2013-02-13 昆山博爱模具开发有限公司 Mold core for injection mold of belt pulley
CN104017359A (en) * 2014-06-19 2014-09-03 王茜南 Nano-modified nylon material and preparation method thereof
CN105605195A (en) * 2016-03-18 2016-05-25 营口金辰机械股份有限公司 Plastic synchronous pulley and manufacturing process thereof
CN105605195B (en) * 2016-03-18 2018-06-26 营口金辰机械股份有限公司 A kind of manufacture craft of plastics synchronous pulley
CN112105843A (en) * 2018-05-22 2020-12-18 舍弗勒技术股份两合公司 Pulley decoupler with injection molded belt track, plain bearing and axial friction ring and method of making same
CN111133230A (en) * 2018-06-19 2020-05-08 阪东化学株式会社 Toothed belt wheel
US10808823B2 (en) 2018-06-19 2020-10-20 Bando Chemical Industries, Ltd. Toothed pulley
CN111133230B (en) * 2018-06-19 2021-04-09 阪东化学株式会社 Toothed belt wheel

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