CN111057369A - Carbon fiber reinforced polyamide composite material pre-soaked basalt fiber cloth and preparation method thereof - Google Patents
Carbon fiber reinforced polyamide composite material pre-soaked basalt fiber cloth and preparation method thereof Download PDFInfo
- Publication number
- CN111057369A CN111057369A CN201911275824.9A CN201911275824A CN111057369A CN 111057369 A CN111057369 A CN 111057369A CN 201911275824 A CN201911275824 A CN 201911275824A CN 111057369 A CN111057369 A CN 111057369A
- Authority
- CN
- China
- Prior art keywords
- carbon fiber
- composite material
- reinforced polyamide
- fiber reinforced
- polyamide composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2477/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/40—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
Abstract
The invention discloses a carbon fiber reinforced polyamide composite material pre-infiltrated basalt fiber cloth and a preparation method thereof, wherein a basalt fiber cloth base cloth is prepared by pre-infiltrating the carbon fiber reinforced polyamide composite material and then rolling and drawing; the carbon fiber reinforced polyamide composite material is composed of the following raw materials: PA66, PA6, chopped carbon fibers, a toughening agent, a compatilizer, a filling modifier, an antioxidant, a lubricant and a dispersant. The carbon fiber reinforced polyamide composite material is used for replacing the traditional thermosetting resin pre-soaked basalt fiber cloth, so that the production cost and the forming period are reduced, and the carbon fiber reinforced polyamide composite material can be recycled; the chopped carbon fibers have a riveting effect between the fiber cloth and the polyamide resin, so that the interlayer strength is increased. The basalt fiber cloth has higher strength than glass fiber cloth and much lower price than carbon fiber cloth, and is a new inorganic material with high cost performance.
Description
Technical Field
The invention belongs to the field of carbon fiber reinforced thermoplastic composite materials, and particularly relates to carbon fiber reinforced polyamide composite material pre-infiltrated basalt fiber cloth and a preparation method thereof.
Background
With the development of light weight of automobile products and light weight, portability and high strength of electronic products, thermosetting polymer pre-impregnated carbon fiber composite materials and part of thermoplastic polymer pre-impregnated carbon fiber composite materials develop faster. The light weight technology becomes an important way for realizing energy conservation and emission reduction and improving the endurance capacity of new energy automobiles, and the carbon fiber composite material is an important basic material for light weight of automobiles. The carbon fiber composite materials used in the automobile industry at present are mainly carbon fiber reinforced thermosetting resin composite materials and a small amount of carbon fiber reinforced thermoplastic composite materials, and spray forming, sheet pressing forming, resin transfer compression molding (RTM), winding forming, injection molding and the like are adopted according to different forming modes. Electronic products such as high-end notebooks and mobile phones have the use of thermosetting resin pre-impregnated carbon fiber sheets, which can greatly reduce the thickness of the products and improve the strength of the materials, so that the electronic products are increasingly lighter, thinner and more portable. The thermosetting carbon fiber composite material has high strength, but the development of the thermosetting carbon fiber composite material in the future is limited due to the defects of complex forming, long period, environmental pollution, incapability of recycling and the like, and the thermoplastic carbon fiber reinforced composite material is an important direction for the development of lightweight automobiles and steel replacement by plastics in the future.
Although the thermoplastic carbon fiber reinforced composite material has great advantages in the molding process and the production process compared with the traditional thermosetting resin pre-impregnated carbon fiber composite material, the price of the carbon fiber cloth is high, so that the composite material has no great competitive advantage. The basalt fiber cloth is woven by basalt fibers, the basalt fibers not only have the advantages of excellent strength, high temperature resistance, acid and alkali resistance, easy infiltration and the like, but also have lower price, and the development of a thermoplastic polymer pre-infiltrated basalt fiber cloth composite material with high strength and low cost is a new development direction. At present, two main defects of thermoplastic pre-impregnated carbon fiber cloth need to be improved: (1) the thermoplastic pre-infiltrated carbon fiber cloth is not fully infiltrated, the surface of the fiber cloth is easy to damage, and an infiltrated layer is easy to fall off; (2) the thermoplastic pre-infiltrated carbon fiber cloth has no lower cost advantage in application because the market price of the carbon fiber is higher.
Disclosure of Invention
The invention aims to provide carbon fiber reinforced polyamide composite material pre-impregnated basalt fiber cloth and a preparation method thereof, so as to overcome the defect of thermoplastic resin pre-impregnated carbon fiber cloth, reduce the cost of a composite material and improve the strength of the pre-impregnated carbon fiber cloth.
The purpose of the invention is realized by the following technical scheme:
a carbon fiber reinforced polyamide composite material pre-infiltrated basalt fiber cloth is prepared by pre-infiltrating a basalt fiber cloth base cloth with a carbon fiber reinforced polyamide composite material and then rolling and drawing; the carbon fiber reinforced polyamide composite material is prepared from the following raw materials in parts by weight:
in a further scheme, the basalt fiber cloth base cloth is twistless coarse sand checkered cloth.
Further, the relative viscosity of the PA66 is 2.4-2.7, and the relative viscosity of the PA6 is 2.7-3.4.
Further, the carbon fiber is chopped carbon fiber with the length of 1mm-20 mm.
In a further scheme, the toughening agent is a mixture of POE and nano montmorillonite in a mass ratio of 4: 1; the compatilizer is maleic anhydride grafted POE.
In a further scheme, the filling modifier is a mixture of modified glass powder and silicon dioxide according to the weight ratio of 1:1-2: 1. The modified glass powder is glass powder modified by a coupling agent; the processing method comprises the following steps: adding the glass powder and the coupling agent into a high-speed mixer at 100 ℃, and uniformly mixing and stirring, wherein the mass of the coupling agent is 0.5-1% of that of the glass powder, and specifically can be 0.5%, 0.8%, 1% and the like.
In a further scheme, the antioxidant is a mixture composed of hindered phenols and phosphites; the lubricant is at least 2 of stearate, modified bisstearamide or polyethylene wax
In a further scheme, the dispersing agent is one of a polar copolymer product and silicone master batch.
The invention also aims to provide a preparation method of the carbon fiber reinforced polyamide composite material pre-infiltrated basalt fiber cloth, which comprises the following steps:
(1) adding PA66, PA6, a toughening agent, a compatilizer, a filling modifier, a lubricant, a dispersant and an antioxidant into a high-speed mixer according to a proportion, mixing, and cooling to room temperature to obtain a mixture;
(2) putting the mixture into a double-screw extruder from a main feeding port, adding the short carbon fibers into the double-screw extruder from a side feeding port, preparing the carbon fiber reinforced polypropylene composite material through melting and blending, and conveying the carbon fiber reinforced polyamide composite material into a melt pool; wherein the extrusion temperature of the double-screw extruder is 230-280 ℃, the screw rotating speed is 350-420r/min, and the vacuum degree is less than-0.06 MPa;
(3) after strong acid oxidation treatment, washing and drying the basalt fiber cloth base cloth, and treating the surface of the basalt fiber cloth base cloth by using a coupling agent to obtain pretreated basalt fiber cloth; and (3) infiltrating the pretreated basalt fiber cloth in a melt pool containing the carbon fiber reinforced polyamide composite material in the step (2), and rolling and drawing to prepare the carbon fiber reinforced polyamide composite material preimpregnated basalt fiber cloth.
In the step (3), the acid used in the strong acid oxidation treatment is 20-40% by mass of sulfuric acid, and the mass fraction of the sulfuric acid may be 20%, 30% or 40%.
Compared with the prior art, the invention has the beneficial effects that:
(1) the carbon fiber reinforced polyamide composite material is used for replacing the traditional thermosetting resin impregnated fiber cloth, so that the forming period is shortened, the pollution is reduced, and the carbon fiber reinforced polyamide composite material can be recycled, the short carbon fibers in the composite material have a riveting effect between the basalt fiber cloth and the polyamide resin, the interlayer strength is increased, and the surface defects of the fiber cloth are repaired. And the preparation process is simple and the production cost is low.
(2) The basalt fiber cloth is used as the base cloth, so that the basalt fiber cloth has the advantages of high strength, good heat resistance, acid and alkali resistance and lower price, and can greatly improve the product performance and reduce the production cost. Before the basalt fiber cloth base cloth is soaked with the carbon fiber reinforced polyamide composite material, the surface of the basalt fiber cloth base cloth is treated by a coupling agent to obtain the pretreated basalt fiber cloth, so that the surface polarity of the base cloth is increased, and the bonding strength of the basalt fiber cloth base cloth with polyamide and a filling modifier in the composite material is enhanced.
(3) According to the invention, the mixture of glass powder and silicon dioxide is used as a filling modifier, and the structure of the hard ultrafine particles of the Ammi micro-nano cube has super-strong dispersing ability and anti-settling property in a polymer melt, so that the hard ultrafine particles are very high in hardness and are easily dispersed in the chopped carbon fibers, the aggregation of the chopped carbon fibers is reduced, the carbon fibers are arranged in an anisotropic manner, and the dispersing ability of the carbon fibers in polyamide resin is improved. Meanwhile, the higher polarity plays a role in improving the bonding strength of the carbon fiber reinforced polyamide composite material and the basalt fiber cloth in the infiltration process.
Detailed Description
The present invention will be further described with reference to the following examples. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The types and suppliers of reagents used in the following examples were as follows: the polar copolymer is KF-027 produced by Jiangzhou Jiahua refined company Limited), the silane coupling agent is KH550 produced by Nanjing eosin fine chemical industry Limited), and the glass powder is FR-01 produced by Guangzhou Songliner; the modified glass powder is glass powder modified by a silane coupling agent KH550, and the mass of the KH550 is 1% of that of the glass powder.
The reagents are provided only for illustrating the sources and components of the reagents used in the experiments of the present invention, so as to be fully disclosed, and do not indicate that the present invention cannot be realized by using other reagents of the same type or other reagents supplied by other suppliers.
Example 1:
the carbon fiber reinforced polyamide composite material is prepared from the following raw materials in parts by weight:
the basalt fiber cloth base cloth is selected from 600g/m2And large-tow checkered cloth.
Example 2:
the carbon fiber reinforced polyamide composite material is prepared from the following raw materials in parts by weight:
the basalt fiber cloth base cloth is selected from 600g/m2And large-tow checkered cloth.
Example 3:
the carbon fiber reinforced polyamide composite material is prepared from the following raw materials in parts by weight:
the basalt fiber cloth base cloth is selected from 600g/m2And large-tow checkered cloth.
Example 4:
the carbon fiber reinforced polyamide composite material is prepared from the following raw materials in parts by weight:
the basalt fiber cloth base cloth is selected from 600g/m2And large-tow checkered cloth.
The preparation method of the carbon fiber reinforced polyamide composite material pre-infiltrated basalt fiber cloth in the above embodiment comprises the following steps:
(1) adding the components into a high-speed mixer according to a ratio, mixing at a high speed of 80 ℃ for 5 minutes to form a uniformly dispersed mixture, opening the high-speed mixer, discharging air, and cooling to room temperature to obtain the mixture;
(2) putting the mixture into a double-screw extruder from a main feeding port, adding the chopped carbon fibers into the double-screw extruder from a side feeding port, preparing the carbon fiber reinforced polyamide composite material through melting and blending, and conveying the carbon fiber reinforced polyamide composite material into a melt pool; wherein, the extrusion temperature of the double-screw extruder is 230 ℃ in a first zone, 270 ℃ in a second zone, 280 ℃ in a third zone, 280 ℃ in a fourth zone, 270 ℃ in a fifth zone, 260 ℃ in a sixth zone, 250 ℃ in a seventh zone, 240 ℃ in an eighth zone, 230 ℃ in a ninth zone, 270 ℃ in a machine head, the rotating speed of the screw is 400RPM, and the vacuum degree is less than-0.06 MPa;
(3) acidifying the basalt fiber cloth base cloth by using 30% concentrated sulfuric acid aqueous solution for 15 minutes, then washing the basalt fiber cloth base cloth by using deionized water, drying the basalt fiber cloth base cloth, spraying 1kg of silane coupling agent to each square meter of basalt fiber cloth base; and (3) infiltrating the pretreated basalt fiber cloth in a melt pool containing the carbon fiber reinforced polyamide composite material in the step (2), and rolling and drawing to prepare the carbon fiber reinforced polyamide composite material preimpregnated basalt fiber cloth.
Comparative example 1
Comparative example 2
Except for the above-described composition differences, the preparation methods of comparative examples 1 and 2 were the same as those in the examples.
Table 1: EXAMPLES comparison of prepreg Wet cloth Strength
Remarking: the instrument used for detection is a microcomputer-controlled universal testing machine, and the size of the test sample strip is as follows: the length is 170mm, the end width is 20mm, the narrow width is 10mm, and the thickness is 4 mm; the tensile strength and tensile modulus were measured at a tensile rate of 50 mm/min.
As can be seen from table 1, the carbon fiber reinforced polyamide composite material pre-impregnated basalt fiber cloth prepared in the examples has very high strength, because the carbon fiber reinforced polyamide composite material of the present invention contains chopped carbon fibers, a compatibilizer, and a filling modifier, the acting force between the composite material and the basalt fiber cloth base cloth is greatly improved, and meanwhile, the thermoplastic resin selected from polyamide engineering plastics has very high strength compared with common thermoplastic resins such as polypropylene, polycarbonate, and the like. In comparison with example 4, the tensile strength of the material is reduced by 30MPa and the modulus is reduced by 9GPa after the filling modifier is removed, so that the filling modifier has great effect. Compared with the embodiment 3, the short carbon fiber is removed in the comparative example 2, the material reduction is large, and the scientific short carbon fiber has good riveting and reinforcing effects.
The carbon fiber reinforced polyamide pre-infiltrated basalt fiber cloth prepared by the invention has higher strength, and the basalt fiber cloth with high strength and low cost is selected when a workpiece is molded by hot pressing, so that the cost of the composite material is greatly reduced.
It should be noted that, on the basis of the above embodiments, those skilled in the art add other functional additives such as fillers, color masterbatches, functional masterbatches, antistatic agents, scratch resistance agents, etc. to the preparation components, so that the composite material has corresponding characteristics, which also belongs to the protection scope of the present invention.
Claims (10)
1. A carbon fiber reinforced polyamide composite material pre-infiltrated basalt fiber cloth is characterized in that: pre-infiltrating basalt fiber cloth base cloth with a carbon fiber reinforced polyamide composite material, and then rolling and drawing to prepare the basalt fiber cloth base cloth; the carbon fiber reinforced polyamide composite material is prepared from the following raw materials in parts by weight:
PA 6640-60 parts by weight,
the weight ratio of the PA to the total weight of the rubber is 610-20 parts,
3-5 parts of a compatilizer,
3-5 parts of toughening agent
5-10 parts of a filling modifier,
0.2 to 0.5 portion of antioxidant,
10-30 parts of carbon fiber
0.5 to 1 portion of lubricant,
0.5-1 part of dispersant.
2. The carbon fiber reinforced polyamide composite material pre-impregnated basalt fiber cloth of claim 1, wherein: the basalt fiber cloth base cloth is twistless coarse sand check cloth.
3. The carbon fiber reinforced polyamide composite material pre-impregnated basalt fiber cloth of claim 1, wherein: the relative viscosity of the PA66 is 2.4-2.7, and the relative viscosity of the PA6 is 2.7-3.4.
4. The carbon fiber reinforced polyamide composite material pre-impregnated basalt fiber cloth of claim 1, wherein: the carbon fiber is chopped carbon fiber with the length of 1mm-20 mm.
5. The carbon fiber reinforced polyamide composite material pre-impregnated basalt fiber cloth of claim 1, wherein: the toughening agent is a mixture of POE and nano montmorillonite in a mass ratio of 4: 1; the compatilizer is maleic anhydride grafted POE.
6. The carbon fiber reinforced polyamide composite material pre-impregnated basalt fiber cloth of claim 1, wherein: the filling modifier is a mixture of modified glass powder and silicon dioxide according to the weight ratio of 1:1-2: 1; the modified glass powder is glass powder modified by a coupling agent.
7. The carbon fiber reinforced polyamide composite material pre-impregnated basalt fiber cloth of claim 1, wherein: the antioxidant is a mixture of hindered phenols and phosphites; the lubricant is at least 2 of stearate, modified bisstearamide or polyethylene wax.
8. The carbon fiber reinforced polyamide composite material pre-impregnated basalt fiber cloth of claim 1, wherein: the dispersing agent is one of a polar copolymer product and silicone master batch.
9. The method for preparing the carbon fiber reinforced polyamide composite material pre-impregnated basalt fiber cloth according to any one of claims 1 to 8, characterized in that: the method comprises the following steps:
(1) adding PA66, PA6, a toughening agent, a compatilizer, a filling modifier, a lubricant, a dispersant and an antioxidant into a high-speed mixer according to a proportion, mixing, and cooling to room temperature to obtain a mixture;
(2) putting the mixture into a double-screw extruder from a main feeding port, adding carbon fibers into the double-screw extruder from a side feeding port, preparing a carbon fiber reinforced polypropylene composite material through melting and blending, and conveying the carbon fiber reinforced polyamide composite material into a melt pool; wherein the extrusion temperature of the double-screw extruder is 230-280 ℃, the screw rotating speed is 350-420r/min, and the vacuum degree is less than-0.06 MPa;
(3) after strong acid oxidation treatment, washing and drying the basalt fiber cloth base cloth, and treating the surface of the basalt fiber cloth base cloth by using a coupling agent to obtain pretreated basalt fiber cloth; and (3) infiltrating the pretreated basalt fiber cloth in a melt pool containing the carbon fiber reinforced polyamide composite material in the step (2), and rolling and drawing to prepare the carbon fiber reinforced polyamide composite material preimpregnated basalt fiber cloth.
10. The method of claim 9, wherein: in the step (3), the acid used for the strong acid oxidation treatment is sulfuric acid with the mass fraction of 20-40%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911275824.9A CN111057369A (en) | 2019-12-12 | 2019-12-12 | Carbon fiber reinforced polyamide composite material pre-soaked basalt fiber cloth and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911275824.9A CN111057369A (en) | 2019-12-12 | 2019-12-12 | Carbon fiber reinforced polyamide composite material pre-soaked basalt fiber cloth and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111057369A true CN111057369A (en) | 2020-04-24 |
Family
ID=70300735
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911275824.9A Pending CN111057369A (en) | 2019-12-12 | 2019-12-12 | Carbon fiber reinforced polyamide composite material pre-soaked basalt fiber cloth and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111057369A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111518389A (en) * | 2020-05-25 | 2020-08-11 | 苏州旭光聚合物有限公司 | Toughened nylon for low temperature |
| CN111808418A (en) * | 2020-07-23 | 2020-10-23 | 咸阳新德安新材料科技有限公司 | Flexible composite high-pressure pipe material for alcohol injection and composite high-pressure pipe |
| CN114957975A (en) * | 2022-07-06 | 2022-08-30 | 连云港爱仕沃玛技术纺织有限公司 | Environment-friendly waterproof outdoor cloth and preparation method thereof |
| CN115612127A (en) * | 2022-11-02 | 2023-01-17 | 常州市宏发纵横新材料科技股份有限公司 | Recycled carbon fiber reinforced material and preparation method thereof |
| CN116285352A (en) * | 2023-03-15 | 2023-06-23 | 青岛中宝塑业有限公司 | High-performance modified PPS plastic, preparation method and application thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850784A (en) * | 2012-09-06 | 2013-01-02 | 江苏兆鋆新材料科技有限公司 | Nylon 6 modified material and preparation method thereof |
| WO2015011001A1 (en) * | 2013-07-22 | 2015-01-29 | Rhodia Operations | Stabilised polyamide composition |
| CN105694444A (en) * | 2016-04-05 | 2016-06-22 | 中北大学 | Long basalt fiber reinforced PA6 composite material and melt impregnation preparation method thereof |
| CN105924953A (en) * | 2016-05-20 | 2016-09-07 | 中北大学 | High-strength and high-tenacity long-basalt-fiber-reinforced nylon-6 composite and preparing thereof |
| US20170145212A1 (en) * | 2009-06-19 | 2017-05-25 | Rhodia Operations | Composition of a blend of polyamide and polyester resins |
| CN106751777A (en) * | 2016-12-19 | 2017-05-31 | 东莞市基核材有限公司 | Based on enhanced high intensity PA6 composites of basalt fibre and preparation method thereof |
| CN107840975A (en) * | 2017-10-26 | 2018-03-27 | 长沙五犇新材料科技有限公司 | A kind of preparation method of continuous fibre reinforced nylon composite |
| CN109134900A (en) * | 2017-06-27 | 2019-01-04 | 深圳光启高等理工研究院 | A kind of prepreg and preparation method thereof |
| CN109337192A (en) * | 2018-07-27 | 2019-02-15 | 会通新材料股份有限公司 | A kind of PP composite material and preparation method thereof |
| CN110283384A (en) * | 2019-07-17 | 2019-09-27 | 苏州禾润昌新材料有限公司 | A kind of high glaze high-strength basalt reinforced polypropylene compound material and preparation method |
-
2019
- 2019-12-12 CN CN201911275824.9A patent/CN111057369A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20170145212A1 (en) * | 2009-06-19 | 2017-05-25 | Rhodia Operations | Composition of a blend of polyamide and polyester resins |
| CN102850784A (en) * | 2012-09-06 | 2013-01-02 | 江苏兆鋆新材料科技有限公司 | Nylon 6 modified material and preparation method thereof |
| WO2015011001A1 (en) * | 2013-07-22 | 2015-01-29 | Rhodia Operations | Stabilised polyamide composition |
| CN105694444A (en) * | 2016-04-05 | 2016-06-22 | 中北大学 | Long basalt fiber reinforced PA6 composite material and melt impregnation preparation method thereof |
| CN105924953A (en) * | 2016-05-20 | 2016-09-07 | 中北大学 | High-strength and high-tenacity long-basalt-fiber-reinforced nylon-6 composite and preparing thereof |
| CN106751777A (en) * | 2016-12-19 | 2017-05-31 | 东莞市基核材有限公司 | Based on enhanced high intensity PA6 composites of basalt fibre and preparation method thereof |
| CN109134900A (en) * | 2017-06-27 | 2019-01-04 | 深圳光启高等理工研究院 | A kind of prepreg and preparation method thereof |
| CN107840975A (en) * | 2017-10-26 | 2018-03-27 | 长沙五犇新材料科技有限公司 | A kind of preparation method of continuous fibre reinforced nylon composite |
| CN109337192A (en) * | 2018-07-27 | 2019-02-15 | 会通新材料股份有限公司 | A kind of PP composite material and preparation method thereof |
| CN110283384A (en) * | 2019-07-17 | 2019-09-27 | 苏州禾润昌新材料有限公司 | A kind of high glaze high-strength basalt reinforced polypropylene compound material and preparation method |
Non-Patent Citations (2)
| Title |
|---|
| TAE WON LEE ET AL.,: "Mechanical, thermomechanical, and local anisotropy analyses of long basalt fiber reinforced polyamide 6 composites", 《COMPOSITE STRUCTURES》 * |
| 杨智明 等: "玄武岩纤维布增强不同树脂基体复合材料的制备与力学性能", 《北京理工大学学报》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111518389A (en) * | 2020-05-25 | 2020-08-11 | 苏州旭光聚合物有限公司 | Toughened nylon for low temperature |
| CN111808418A (en) * | 2020-07-23 | 2020-10-23 | 咸阳新德安新材料科技有限公司 | Flexible composite high-pressure pipe material for alcohol injection and composite high-pressure pipe |
| CN111808418B (en) * | 2020-07-23 | 2023-04-07 | 咸阳新德安新材料科技有限公司 | Flexible composite high-pressure pipe material for alcohol injection and composite high-pressure pipe |
| CN114957975A (en) * | 2022-07-06 | 2022-08-30 | 连云港爱仕沃玛技术纺织有限公司 | Environment-friendly waterproof outdoor cloth and preparation method thereof |
| CN115612127A (en) * | 2022-11-02 | 2023-01-17 | 常州市宏发纵横新材料科技股份有限公司 | Recycled carbon fiber reinforced material and preparation method thereof |
| CN116285352A (en) * | 2023-03-15 | 2023-06-23 | 青岛中宝塑业有限公司 | High-performance modified PPS plastic, preparation method and application thereof |
| CN116285352B (en) * | 2023-03-15 | 2023-12-19 | 青岛中宝塑业有限公司 | High-performance modified PPS plastic, preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111057369A (en) | Carbon fiber reinforced polyamide composite material pre-soaked basalt fiber cloth and preparation method thereof | |
| CN105199379B (en) | A kind of continuous long carbon fiber enhancing nanocomposite and its preparation method and application | |
| EP3789456B1 (en) | Polyamide resin composition having high metal texture and preparation method of polyamide resin composition | |
| CN101580636B (en) | Warpage resistance nylon 6 composite material for vehicle air conditioning air door and preparation method thereof | |
| CN105504803B (en) | A kind of high fluidity fiber reinforced nylon composite material and preparation method thereof | |
| CN105733096B (en) | A kind of long carbon fiber enhancing thermoplastic composite and preparation method thereof | |
| CN103937093B (en) | A kind of long glass fiber reinforced polypropylene composite material and preparation method thereof | |
| CN106046776A (en) | High flow carbon fiber reinforced nylon composite material with fine surface and preparation method thereof | |
| CN103554904A (en) | Recovered carbon fiber-reinforced nylon composite material as well as preparation method thereof | |
| CN101412845A (en) | High performance fiber reinforced nylon composite material and preparation thereof | |
| CN105524398A (en) | ABS rapid prototyping material used for 3D printing, and preparation method thereof | |
| CN105038217A (en) | Carbon fiber reinforced nylon micro-foaming material and preparation method thereof | |
| CN111057346B (en) | Carbon fiber reinforced PEEK unidirectional tape and preparation method thereof | |
| CN112961420B (en) | Graphene modified high-density polyethylene composite material for carrier roller and preparation method thereof | |
| CN104530695A (en) | Wear-resistant nylon composite material and preparation method thereof | |
| CN105566937A (en) | Fiberglass reinforced wood-plastic composite material and preparation method thereof | |
| CN104669636B (en) | A kind of preparation method of assorted fibre RPP high strength composite | |
| CN106883542A (en) | A kind of heat-resisting antistatic regeneration HIPS of super high impact is material modified and preparation method thereof | |
| CN106009246A (en) | Organic fiber reinforced polypropylene composite material and LFT-D forming process thereof | |
| CN105647172A (en) | Wear-resistant long basalt fiber-reinforced PA6 composite material and preparation method thereof | |
| CN104356585A (en) | High-performance continuous carbon fiber reinforced ABS composite material and preparation method thereof | |
| CN109749241A (en) | Low smell Long Glass Fiber Reinforced PP Composite of a kind of good degree of impregnation and preparation method thereof | |
| CN106589920A (en) | Carbon fiber-reinforced nylon 6 composite material with high flowability and good surface and preparation method thereof | |
| CN106519661A (en) | Nylon PA66 material suitable for water-oil environment and preparation method thereof | |
| CN106751761A (en) | High rigidity high glaze carbon fiber reinforced polyamide composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| AD01 | Patent right deemed abandoned |
Effective date of abandoning: 20220614 |
|
| AD01 | Patent right deemed abandoned |