CN1727456A - Agent for repairing abrasion resistance of metal - Google Patents

Agent for repairing abrasion resistance of metal Download PDF

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Publication number
CN1727456A
CN1727456A CN 200510041221 CN200510041221A CN1727456A CN 1727456 A CN1727456 A CN 1727456A CN 200510041221 CN200510041221 CN 200510041221 CN 200510041221 A CN200510041221 A CN 200510041221A CN 1727456 A CN1727456 A CN 1727456A
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oxide
metal
abrasion resistance
agent
lubricating oil
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CN1321170C (en
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谢传林
眭晔
谢荣顺
徐建国
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Abstract

An antiwear repairing agent for the worn metallic object or part is proportionally prepared from silicon oxide, magnesium oxide, aluminum oxide, iron oxide, sodium oxide, nickel oxide, chromium oxide, phosphorus oxide, calcium oxide and lubricating oil through proportional mixing and grinding.

Description

Agent for repairing abrasion resistance of metal
Technical field
Agent for repairing abrasion resistance of metal of the present invention relates to is a kind of metal anti-attrition, fall mill, wear-resistant repair materials, can be widely used in industry, agricultural and military affairs, ocean industry, all kinds of car, ship, mould, machinofacture, processing industry etc., all exist in the metal object, parts of frictional dissipation.
Background technology
It is eternal topic of human scientific research field that mill falls in anti-attrition, and frictional dissipation is low more, and mechanical power is just strong more, and the product benefit also can increase greatly, and the anti-attrition of scientific research field is at present fallen the mill means and mainly contained following 3 points: 1. improve product structure design; 2. select suitable high-abrasive material, especially consider the life-span that is equal to of friction pair material; 3. product surface easy to wear is strengthened.China never ends for example 1. generation of sintering metal technology and application in the research and the application of high-abrasive material and wear-resistant technical elements in recent decades.Heterogeneous matrix material that sintering metal is made up of pottery and bonded metal.Pottery mainly is refractory oxide or their sosoloid such as aluminum oxide, zirconium white, and bonded metal mainly is refractory metals such as chromium, molybdenum, tungsten, titanium.Pottery and bonded metal ground and mixed is even, after the moulding in torpescence atmosphere sintering, just can make sintering metal.Sintering metal has the advantage of metal and pottery concurrently, its density is little, hardness is high, wear-resisting, thermal conductivity good, can be because of quenching or shock heating and embrittlement.In addition, be coated with the ceramic coating that one deck resistance to air loss is good, fusing point is high, heat transfer property is very poor in the metallic surface, also can prevent metal or alloy oxidation at high temperature or corrosion.Sintering metal is widely used in the shell of rocket, guided missile, supersonic plane, the flame jet of combustion chamber etc. and locates.But,, can not be widely used in industrial production because the fragility of stupalith has often limited in the range of application that has under the impact condition.2. " iron despot ", " An Naichi " with the U.S. is example in the product of import; the abrasion resistance of metal oil dope that these two kinds of worlds are famous; automobile has many good qualities after using; as reducing exhaust emissions, save oil consumption, improving power etc.; but they remain petroleum product; formed plastic membrane protective layer; after use after a while, come off easily; the cylinder head of automobile and the main oil gallery on the cylinder body stop up easily; need routine cleaning engine and element of oil filter, if filter core is crossed dirty then renew cartridge more.And the imported product price is higher, also is unfavorable for popularizing.
Summary of the invention
The present invention seeks to provides a kind of agent for repairing abrasion resistance of metal at above-mentioned weak point; by using invention; in the process of metal friction, progressively form protective layer and fill up the concave surface that has worn and torn automatically; produce a kind of brand-new " metalloid wearing-resistant layer " at last; play anti-attrition, fall mill, wear-resistant repair, reduce wearing and tearing, reduce vibrating noise, save energy, raising mechanokinetic purpose thereby reach.
Agent for repairing abrasion resistance of metal is to take following scheme to realize: agent for repairing abrasion resistance of metal is formed by the proportioning ground and mixed by silicon oxide, magnesium oxide, aluminum oxide, ferric oxide, sodium oxide, nickel oxide, chromic oxide, phosphorus oxide, calcium oxide, lubricating oil, and its various composition weight percent proportionings are:
Silicon oxide 15-28%
Magnesium oxide 10-28%
Aluminum oxide 0.05-2.1%
Ferric oxide 0.05-2.8%
Sodium oxide 0.05-2.1%
Nickel oxide 0.005-0.35%
Chromic oxide 0.005-0.35%
Phosphorus oxide 0.05-3.5%
Calcium oxide 0.05-5.6%
The lubricating oil surplus
Lubricating oil can adopt mineral lubricating oils, vegetable lhybricant.Mineral lubricating oils can be used mineral lubricating oil, lubricating mineral grease, and vegetable lhybricant can be selected Viscotrol C etc. for use.
Manufacturing process:
Press said ratio with silicon oxide, magnesium oxide, aluminum oxide, ferric oxide, sodium oxide, nickel oxide, chromic oxide, phosphorus oxide, calcium oxide pressed powder and lubricating oil, putting into super grinder ground 65-180 minute, grind to form and mix superfine powder (0.1--1 μ m) lubricating fluid, after being cooled to normal temperature, after filtration, canned, promptly be made into agent for repairing abrasion resistance of metal.
Characteristics of the present invention:
The present invention is significantly different with other wear preventive additives; it is not to produce the tetrafluoroethylene protective membrane at metal friction surface; neither form the soft protective membrane of metal; more not to pass through molybdenum; the organic compound that boron is dissolved in behind the lubricating oil contains molybdenum in the metal friction surface generation; the chemical bond framework of boron; but utilization novel process; the agent for repairing abrasion resistance of metal superfine powder (0.1--1 μ m) of development meticulously is sent to surface of friction pair by medium (liquid); through infiltration; absorption; the TRANSIENT HIGH TEMPERATURE heating (utilizes frictionwork; the TRANSIENT HIGH TEMPERATURE that frictional energy produces); progressively produce protective layer in the metallic surface; and repair the concave surface of galling automatically; when the friction gap reaches the most rational state; frictionwork; frictional energy also reduces thereupon, until final formation a kind of superhard (about HV1500); superslide (about frictional coefficient 0.003); anticorrosive; firmly; crash-proof " metalloid wearing-resistant layer ".Breakthrough and development have been realized to original sintering metal technology.Agent for repairing abrasion resistance of metal of the present invention is the anti-attrition of a kind of ideal metal, fall mill, wear-resistant repair materials, can be widely used in industry, agricultural and military affairs, ocean industry, all kinds of car, ship, mould, machinofacture, processing industry etc., all exist in the metal object, parts of frictional dissipation.
Embodiment
Embodiment 1, making agent for repairing abrasion resistance of metal 100Kg
By proportioning raw materials weighing silicon oxide 15Kg (15%), magnesium oxide 28Kg (28%), aluminum oxide 0.05Kg (0.05%), ferric oxide 0.05Kg (0.05%), sodium oxide 0.05Kg (0.05%), nickel oxide 0.35Kg (0.35%), chromic oxide 0.005Kg (0.005%), phosphorus oxide 0.05Kg (0.05%), calcium oxide 5.6Kg (5.6%) pressed powder, lubricating oil 50.84Kg (50.845%); Lubricating oil can adopt mineral lubricating oils, vegetable lhybricant.Mineral lubricating oils can be used mineral lubricating oil, lubricating mineral grease, and vegetable lhybricant can be selected Viscotrol C etc. for use;
With above-mentioned proportioning raw materials weighing silicon oxide, magnesium oxide, aluminum oxide, ferric oxide, sodium oxide, nickel oxide, chromic oxide, phosphorus oxide, calcium oxide pressed powder and the lubricating oil pressed, putting into super grinder ground 65-180 minute, grind to form and mix superfine powder (0.1-1 μ m) lubricating fluid, after being cooled to normal temperature, after filtration, canned, promptly be made into agent for repairing abrasion resistance of metal.
Embodiment 2, making agent for repairing abrasion resistance of metal 100Kg
By proportioning raw materials weighing silicon oxide 15Kg (15%), magnesium oxide 10Kg (10%), aluminum oxide 2.1Kg (2.1%), ferric oxide 2.8Kg (2.8%), sodium oxide 2.1Kg (2.1%), nickel oxide 0.005Kg (0.005%), chromic oxide 0.35Kg (0.35%), phosphorus oxide 3.5Kg (3.5%), calcium oxide 0.05Kg (0.05%) pressed powder, lubricating oil 64.095Kg (64.095%); Lubricating oil can adopt mineral lubricating oils, vegetable lhybricant.Mineral lubricating oils can be used mineral lubricating oil, lubricating mineral grease, and vegetable lhybricant can be selected Viscotrol C etc. for use;
With above-mentioned proportioning raw materials weighing silicon oxide, magnesium oxide, aluminum oxide, ferric oxide, sodium oxide, nickel oxide, chromic oxide, phosphorus oxide, calcium oxide pressed powder and the lubricating oil pressed, putting into super grinder ground 65-180 minute, grind to form and mix superfine powder (0.1-1 μ m) lubricating fluid, after being cooled to normal temperature, after filtration, canned, promptly be made into agent for repairing abrasion resistance of metal.
Embodiment 3, making agent for repairing abrasion resistance of metal 100Kg
By proportioning raw materials weighing silicon oxide 22Kg (22%), magnesium oxide 20Kg (20%), aluminum oxide 1Kg (1%), ferric oxide 1.4Kg (1.4%), sodium oxide 1Kg (1%), nickel oxide 0.18Kg (0.18%), chromic oxide 0.18Kg (0.18%), phosphorus oxide 0.2Kg (0.2%), calcium oxide 2.8Kg (2.8%) pressed powder, lubricating oil 51.24Kg (51.24%); Lubricating oil can adopt mineral lubricating oils, vegetable lhybricant.Mineral lubricating oils can be used mineral lubricating oil, lubricating mineral grease, and vegetable lhybricant can be selected Viscotrol C etc. for use;
With above-mentioned proportioning raw materials weighing silicon oxide, magnesium oxide, aluminum oxide, ferric oxide, sodium oxide, nickel oxide, chromic oxide, phosphorus oxide, calcium oxide pressed powder and the lubricating oil pressed, putting into super grinder ground 65-180 minute, grind to form and mix superfine powder (0.1-1 μ m) lubricating fluid, after being cooled to normal temperature, after filtration, canned, promptly be made into agent for repairing abrasion resistance of metal.
Using method:
Each use the present invention can pass through following four steps, can reach best result of use.
Step 1, friction pair preheating are about 20 minutes.
The agent for repairing abrasion resistance of metal that step 2, filling have been made started friction pair about 30 minutes.
Step 3, shutdown about 5 minutes.
Step 4, start are more than 30 minutes.
Can normally use then.
After tested, the friction of metallic surface can reduce to more than 95% behind use the present invention, after using as the automobile engine oil additive, vehicle cylinder is pressed obviously and is risen, and saves on average that oil consumption 5-28% is above, tail gas reduces more than 40%, after mechanical means is used, vibrating noise obviously reduces, operating temperature lowers more than 30%, and machine tool accuracy can return to the precision of dispatching from the factory (for example grinder head precision etc.), is prolonged mechanical life 100%, and toxicological harmless, pollution-free, environmental protection and energy saving.
The explanation of agent for repairing abrasion resistance of metal trial state:
1, agent for repairing abrasion resistance of metal is made the timesharing repairing test on the outer garden universal grinder of the M1432 lathe that Shanghai Machine Tool Plant in 1980 of Nanjing factory produces, and this lathe bistrique precision of dispatching from the factory is 8 microns of axial runouts, surveys 17 microns.Inject 75 milliliters of agent for repairing abrasion resistance of metal, bistrique rotation (1500/ minute), it is 13 microns that the detection of stopping after 67 minutes is beated.Surveying after 3 hours is 11 microns, and after 7 hours, survey is 10 microns.Recover to dispatch from the factory precision after 3 days.
2, agent for repairing abrasion resistance of metal is repaired on dispatching from the factory the M1420 outer circular end grinding machine of producing in Nanjing company nineteen eighty-three Shanghai, 8 microns of precision bistrique axial runouts dispatch from the factory before on probation, survey 15 microns, inject 40 milliliters of agent for repairing abrasion resistance of metal, after 3 days, return to below 8 microns at the survey axial runout.
3, agent for repairing abrasion resistance of metal is on probation on homemade " five water chestnuts " board mini van of buying in January, 2000 of Zhejiang company, this car has travelled 80,000 kilometers before using this agent for repairing abrasion resistance, 80 kilometers/hour of F-Zeros, oil consumption is 320 kilometers/every case (about 27 liters), and noise is big, over-emitting black exhaust during exhaust emissions.This car has added 100 milliliters of this agent for repairing abrasion resistance in 4 liters of engine motor oils, use the back car noise obviously to reduce, and has not also had black smoke during exhaust emissions, and one case same oil can drive to 395 kilometers in the urban district, and oil consumption reduces by 23.44%.Once more behind the top off, running car 450 kilometers (wherein the urban district is travelled 250 kilometers, and motorway has travelled 200 kilometers) oil consumption before using agent for repairing abrasion resistance, reduce by 40.63%.And the running car F-Zero reaches 100 kilometers/hour, and the speed of a motor vehicle improves 25% than original.

Claims (2)

1, a kind of agent for repairing abrasion resistance of metal is characterized in that being formed by the proportioning ground and mixed by silicon oxide, magnesium oxide, aluminum oxide, ferric oxide, sodium oxide, nickel oxide, chromic oxide, phosphorus oxide, calcium oxide, lubricating oil, and its various composition weight percent proportionings are:
Silicon oxide 15-28%
Magnesium oxide 10-28%
Aluminum oxide 0.05-2.1%
Ferric oxide 0.05-2.8%
Sodium oxide 0.05-2.1%
Nickel oxide 0.005-0.35%
Chromic oxide 0.005-0.35%
Phosphorus oxide 0.05-3.5%
Calcium oxide 0.05-5.6%
The lubricating oil surplus.
2,, it is characterized in that lubricating oil adopts mineral lubricating oils, vegetable lhybricant according to right 1 described agent for repairing abrasion resistance of metal.
CNB2005100412214A 2005-07-28 2005-07-28 Agent for repairing abrasion resistance of metal Active CN1321170C (en)

Priority Applications (1)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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CN1321170C CN1321170C (en) 2007-06-13

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101164969B (en) * 2006-10-20 2011-08-17 天津阿尔普材料科技有限公司 Metal friction surface restoring agent
CN102465049A (en) * 2011-07-15 2012-05-23 刘永斌 Metal wear self-repairing protective agent
CN101412943B (en) * 2008-11-27 2012-07-04 黑龙江圣龙金属磨损自修复材料有限公司 Composition for repairing surfaces of metallic rubbing pairs and preparation thereof
CN102634403A (en) * 2011-02-15 2012-08-15 周晓 Nano self-repairing material with stable dispersity
CN103131523A (en) * 2013-02-04 2013-06-05 大连海事大学 Novel DAH medium-load rotary-type air compressor oil composition, manufacture method thereof and application
CN103789075A (en) * 2014-02-26 2014-05-14 北京科技大学 High-concentration composite nano TiO2/ZnO lubricating additive and preparation method
CN107384512A (en) * 2017-07-20 2017-11-24 瑙gぜ Micro-nano intelligent Base Metal abrasion self-repair material and its preparation and application
CN108059994A (en) * 2017-12-05 2018-05-22 杭州启俄科技有限公司 It is a kind of to repair secondary composition of friction and its preparation method and application
CN110129114A (en) * 2019-06-04 2019-08-16 王保亮 A kind of Motor Protect
CN111100723A (en) * 2019-03-27 2020-05-05 南京金魔节能工程有限公司 Preparation method of metal friction pair rapid wear-resistant repair material
CN111607447A (en) * 2020-06-30 2020-09-01 张长军 Metal wear-resistant repair lubricating grease and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2219305A (en) * 1988-05-31 1989-12-06 Ipari Fejlesztesi Bank Rt Oil-based lubricant for lubricating and/or sliding surfaces containing aluminium oxide powder
CN1058984C (en) * 1998-10-08 2000-11-29 中国科学院兰州化学物理研究所 Nano size rare earth hydroxide lubricant oil additive
CN1115396C (en) * 2000-07-25 2003-07-23 中国石油天然气股份有限公司兰州炼化分公司 Composition for antiwear hydraulic lubricant oil additive
JP4816008B2 (en) * 2005-11-02 2011-11-16 パナソニック株式会社 Receiver

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101164969B (en) * 2006-10-20 2011-08-17 天津阿尔普材料科技有限公司 Metal friction surface restoring agent
CN101412943B (en) * 2008-11-27 2012-07-04 黑龙江圣龙金属磨损自修复材料有限公司 Composition for repairing surfaces of metallic rubbing pairs and preparation thereof
CN102634403A (en) * 2011-02-15 2012-08-15 周晓 Nano self-repairing material with stable dispersity
CN102634403B (en) * 2011-02-15 2013-11-06 周晓 Nano self-repairing material with stable dispersity
CN102465049A (en) * 2011-07-15 2012-05-23 刘永斌 Metal wear self-repairing protective agent
CN103131523B (en) * 2013-02-04 2014-10-22 乐道战略材料有限公司 Novel DAH medium-load rotary-type air compressor oil composition, manufacture method thereof and application
CN103131523A (en) * 2013-02-04 2013-06-05 大连海事大学 Novel DAH medium-load rotary-type air compressor oil composition, manufacture method thereof and application
CN103789075A (en) * 2014-02-26 2014-05-14 北京科技大学 High-concentration composite nano TiO2/ZnO lubricating additive and preparation method
CN103789075B (en) * 2014-02-26 2015-05-13 北京科技大学 High-concentration composite nano TiO2/ZnO lubricating additive and preparation method
CN107384512A (en) * 2017-07-20 2017-11-24 瑙gぜ Micro-nano intelligent Base Metal abrasion self-repair material and its preparation and application
CN108059994A (en) * 2017-12-05 2018-05-22 杭州启俄科技有限公司 It is a kind of to repair secondary composition of friction and its preparation method and application
CN111100723A (en) * 2019-03-27 2020-05-05 南京金魔节能工程有限公司 Preparation method of metal friction pair rapid wear-resistant repair material
CN111100723B (en) * 2019-03-27 2023-08-22 南京金魔节能工程有限公司 Preparation method of rapid wear-resistant repair material for metal friction pair
CN110129114A (en) * 2019-06-04 2019-08-16 王保亮 A kind of Motor Protect
CN111607447A (en) * 2020-06-30 2020-09-01 张长军 Metal wear-resistant repair lubricating grease and preparation method thereof

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