CN1724446A - Material for wall, and method for processing wall brick by said material - Google Patents

Material for wall, and method for processing wall brick by said material Download PDF

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Publication number
CN1724446A
CN1724446A CNA2005100407860A CN200510040786A CN1724446A CN 1724446 A CN1724446 A CN 1724446A CN A2005100407860 A CNA2005100407860 A CN A2005100407860A CN 200510040786 A CN200510040786 A CN 200510040786A CN 1724446 A CN1724446 A CN 1724446A
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mud
materials
wall
water ratio
brick
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CN1323047C (en
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强浩
张俊华
秦卫东
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SAIKELI NOVEL MATERIAL CO Ltd SUZHOU
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SAIKELI NOVEL MATERIAL CO Ltd SUZHOU
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)

Abstract

A material for wall brick is the proportional mixture of mud, silt, powdered coal ash and additive. Said wall brick is prepared through proportionally mixing mud with powdered coal ash, adding de-odoring agent and disinfectant (ClO2), drying, pulverizing, proportionally mixing it with silt, mud, powdered coal ash and additive, grinding, adding de-odoring agent and ClO2, shaping, drying, and calcining at 900-1100 deg. C.

Description

A kind of materials for wall and with the method for this materials processing wall body brick
Technical field
The invention belongs to materials for wall and processing technique field thereof, be specifically a kind of by paper mill sludge and printing and dyeing sludge as the materials for wall of main raw material and with the method for this materials processing wall body brick.
Background technology
In view of conventional clay is raw material with the clay, the havoc good farmland.Be lower than China of world average level for land resources per capita, protection land resources, all kinds of non-clay matter of Development and Production materials for wall, it is inevitable particularly utilizing solid waste to produce materials for wall.Make the strong point that walling unit replaces conventional clay to have the protection good farmland, economize the land resource in view of the flyash that utilizes industrial waste such as fuel-burning power plant again.So Chinese patent CN1398813A discloses the technology enlightenment of making vitrified brick of flyash and wilkinite.But because a lot of regional flyash have belonged to and a day commodity resource category in one's favour at home, raw material sources both can not get ensureing, and price is higher, and wilkinite is a kind of Mineral resources, and the vitrified brick cost that these two kinds of raw materials of applying are processed into is higher.The content of for example having introduced flyash in this technical scheme is 85~95%.Thereby, both be difficult to obtain the flyash source and supported uncontrollable again cost brickmaking manufacturer.Also in view of the mud that is produced for papermaking, dyeing waste water control, treatment process commonly used at present is to adopt sanitary landfill, burning disposal etc., the former had both taken land resources and can cause secondary pollution, the latter except once investing the height, also need consumes energy, working cost is also high, and the residue after burning also need be handled.For this reason, utilize mud and other solid waste, produce materials for wall and be no lack of report in the literature as raw material.
Chinese patent Granted publication CN1217239A has announced the method for utilizing the sludge heat energy baking light bricks, its the instruction people technical scheme be: with sludge dewatering to water content 50~60%, and make the particle of 3~9mm, dry back with 10~30% ratio sneak in the raw clay, base, air-dry, roasting.This method has positive effect to environmental protection.But this method mud handling capacity is not high, and still will consume 60~90% clay, so protection land resources is not brought gratifying positive effect.Mention in the concrete operations step about sludge dewatering: the mud of separating in belt filter press dewaters under<100 ℃ temperature, and this needs consumes energy.
Again; Chinese patent publication number CN1299790A has disclosed the brick-making process that utilizes papermaking waste material; this method be with 10~30% paper mill sludge blending in 60~90% earth or flyash; mixed mutually with 60~90% earth again; protection does not produce significantly achievement to method to land resources; its mud incorporation also is no more than 30% (CN1217239A is similar to notification number), and this method will rely on mould and take the tool kiln-firing, thereby is difficult in actual production even can't implements.
Also; Chinese patent publication number CN1587569A has disclosed the preparation method of full internal combustion light brick; this method has been done objective appraisal to the existing defective of aforesaid CN1299790A in background technology; the paper mill sludge consumption is compared with above-mentioned document in this method; though certain increase is arranged but still below 50%; and still need consume 50~55% clay resource, not obvious to the contribution of protection land resources.And one of the key in this method mud being utilized " mummification " do not set forth, and be very difficult even can't organize production and apply.Because the first step of sludge treatment and resource utilization is exactly mummification, otherwise burns, produce building materials, even landfill all will be difficult to implement.For example: mud state of nature water ratio generally reaches 80%, as without mummification, must cause mixture moisture obviously higher, and can't shaping forming.It is not proper proposing without sterilant in this method.To the sludge disinfection germicidal treatment is conventional requirement, because contain pollutents such as bacterium and organic matter in most mud, as very fast rotten and give an offensive smell without disinfection processing meeting, surrounding environment and operator is produced new pollution.
Again, Chinese patent Granted publication CN1413939A has released production method of sludge baked brick, though this method consumes sludge quantity and still is no more than 50% but exempt from clay thereby the meaning that has more environmental protection and economize the land resource, yet, this method is recommended the shale of using and is subjected to regional restraining factors big, be suitable for being distributed with the area enforcement of shale resource, this method is not discussed a main difficult problem one sludge dewatering of mixing making brick from sludge again, therefore, in actual production, be difficult to carry out, because of this method requires comparatively harshness to the temperature increasing schedule of going into the kiln roasting, be difficult to grasp again.
And then Chinese patent publication number CN1562864A has introduced the method for making clay brick with mud, and this method is utilized the mud brickmaking of river training, lake gained, and waste resource is fully used, and has solved the outlet of mud.But the equipment input cost in comparatively loaded down with trivial details, the whole brickmaking process of the technology that this method is introduced is big, energy consumption is high, be not suitable for suitability for industrialized production.In addition, 250~600 ℃ of the maturing temperatures of mentioning in this method lack technical basis (routine techniques brickmaking sintering temperature is minimum also to be needed more than 850 ℃), can't sintering under this temperature.This method provides the method for drying sewage sludge on the conveying belt in drying room, and this is the progress than above method, but the thermal source of this drying room need consume fuel or.Both increase running cost, caused new topsoil again.
The applicant has noticed the method for the disclosed a kind of firing building material products by utilizing contaminated river bottom mud of CN1371883A, institute's recommended technology scheme is: with consumption greater than 50% river bottom mud, flyash and 0~35% combustion-supporting material, 0~10% flux material, 0~25% agglomerated material less than 45% through fully mixing and stirring, homogenizing is made blank after handling, fire after the drying, wherein after kiln temperature reaches 800 ℃, be warming up to firing temperature, after the insulation cooling, obtain finished product with 10~40 ℃ of unit time.The weak point of this technical scheme is: the one, this technical scheme is recommended be river silt particularly to the method for firing building material products by utilizing contaminated river bottom mud, similar to CN1562864A.And added various types of materials according to the characteristic of contaminated river bottom mud and the requirement of making building material made.Wherein do not address the utilization of papermaking and printing and dyeing sludge.The 2nd, river bottom mud in this method and papermaking, printing and dyeing sludge physical and chemical performance are widely different, and moulding is also different with sintering character, but the water ratio height is a denominator.But this method does not give the technology enlightenment to the mummification in early stage of the high river bottom mud of water ratio, if limiting river bottom mud in it prepares burden greater than 50% ratio, shaping forming moisture must substantially exceed routine techniques sludge blank making moulding moisture should be controlled at 18~22% requirement, can't produce at all.And,, therefore be difficult to even can't in actual production, use in full to the basic not specified (NS) of working method.The 3rd, known to embodiment one, the product of making is haydite goods but not materials for wall, so again from embodiment two as can be known, if will obtain brick product, then still need depend on clay (Instructions Page 3 4~5 is capable); The 4th, if will obtain the brick product, require with per hour 10 ℃ of intensifications, as to rise to 900 ℃ of sintering temperatures, need 90 hours, add insulation, cooling, the cycle of total burnt brick product needs 180 hours.This is meaning just, burns till at the annular kiln of same size, and its output only is 1/4~1/5 of a routine techniques, if fruit burns till in the tunnel furnace of same size, its output only is 1/8~1/10 of routine techniques, must cause the fuel consumption height that yields poorly, so there is not application value.
The applicant has been also noted that Chinese patent publication number CN1408675A has introduced the method for utilizing regenerated papermaking mud to prepare vitrified brick; this method has been done objective appraisal to the existing defective of aforesaid CN1299790A in background technology; and environment protection there is certain active effect; one of but obvious have a following shortcoming,, with regard to vitrified brick composition and proportioning thereof; paper mill sludge is got 10~25 weight parts; it is little of part to show genus, and clay is 70~85% weight parts, belongs to greatly than part.So it is both seriously polluted to digesting, the achievement of the mud that intractability is big is not appeared suddenly, big unfavorable because of the clay consumption again to conservation of resources; Two raw materials in a large amount of clays that use, and ignored the use of mud, if can mud and mud is shared, use and exempt to use clay, then can embody the effect of double gain, this also is the shortcoming of this patented technology scheme, and this may be that this patent main purpose only provides and can partly utilize mud to produce the method for vitrified brick, certainly selected technology the clay of easy enforcement as main raw material.Three, with regard to the preparation method of its introduction, sterilant adopts clorox, because input amount is 0.5~1% of a mud weight, has increased disinfection cost, transfers on the brick product because the cost of bigization will inevitably be pass on, and is difficult to make the brickmaking industry to be accepted; Four, method recommended the drying of mud is adopted air drying, this is a very general indignant thought, and concrete method is not provided, and actual production is lacked directive function; Five, mentioned that at Instructions Page 3 the 5th row the mud consumption too much can make vitrified brick density excessive (ventilation property is poor), yet this instruction is opposite with reality exactly; Six, mention with 600~700 ℃ sintering temperature in this method sintering carried out in adobe, be to lack technical basis equally.
Summary of the invention
So task of the present invention need not be used clay and to be using of raw material is that economize the land resource, that help environment protection, quality is light and heat-proof quality is good materials for wall as the mud of waste, mud will providing a kind of.
Task of the present invention also is to provide a kind of, method of mud, mud being disinfected cost formability low, that can embody mud, mud and processing wall body brick coking property, that can shorten adobe dry combustion method and firing cycle that can accept and use for actual production and that can embody economy to the mummification of mud, mud.
Materials for wall of the present invention is characterised in that, it is that starting material by following weight part ratio constitute: 20~80 parts in mud, 0~60 part in mud, 10~40 parts in flyash, 0~5 part of additive.
Mud of the present invention is the mud that papermaking, dyeing waste water control are produced; And described mud is the mud of river, the pool, lake, damp desilting gained.
Additive of the present invention is industry and the domestic refuse that helps to adjust the wilkinite tankage of plasticity index and help to improve sintering character.
Industrial domestic refuse of the present invention is industry, domestic refuse based on alkalimetal oxide.
Alkalimetal oxide of the present invention is glass cullet.
The method of the above-mentioned materials for wall processing of usefulness provided by the present invention wall body brick may further comprise the steps:
A) general's part water ratio is that 50~82% mud and flyash are 10: 1~8 mixing by weight, add 0 of mud weight~0.01 ‰ reodorant or chlorine dioxide bactericide simultaneously, make mud one coal ash mixed material, again compound is made base substrate, pulverize behind the body drying, it is stand-by to obtain dry powder;
B) again with weight part count 0~45 part in dry powder, water ratio after draining away the water be 28~44% 0~60 part in mud, water ratio be 50~82% 10~40 parts in 0~80 part in mud, flyash, additive mix, grind for 0~5 part practice, broken, the reodorant or the chlorine dioxide bactericide that add 0 of mud weight~0.01 ‰ simultaneously obtain the base material of particle≤2mm;
C) with carrying out drying behind the base material base, deliver to roasting then, 900~1100 ℃ of firing temperatures, roasting time 18~36 hours obtains finished bricks.
In one embodiment of the invention, flyash described in the step a) is dry discharge fly ash, and described reodorant is that DJ-904 reodorant, described body drying are meant by any one mode in seasoning or the artificial seasoning and are dried to water ratio 5~15%.
In an alternative embodiment of the invention, draining described in the step b) is meant that nature drains to add manually and teds.
Among another embodiment of the present invention, the described base of step c) is to use the vacuum extruder extrusion moulding, forming pressure is 2Mpa, vacuum tightness≤0.092Mpa, and described drying is nature or the artificial seasoning of utilizing brick furnace residual heat, and degree of drying is a water ratio 7~8%.
In another embodiment of the present invention, described seasoning is to utilize sun power and natural wind as the dry energy, and described artificial seasoning is to utilize annular kiln or residual heat of tunnel kiln as the dry energy.
One of advantage that compared with the prior art technical scheme disclosed by the invention is had uses sludge quantity big, and environment protecting is remarkable; Two, without clay, economize the land resource; Three, all need processing and the area of resource utilization mud, general equal can the supply on the spot of other raw material, the source is easy to get; Four, the gained texture material is light, makes the brick product of making can embody the effect of lightweight and excellent in heat insulating performance; Five, adopt dry discharge fly ash and with mud and dry discharge fly ash mixing partly and produce dry powder, be equipped with measure such as drain again, have easy, economic effect; Six, with reodorant and disinfection by chlorine dioxide lowization disinfection cost effectively; Seven, all be waste as the wilkinite tankage and the alkalimetal oxide of additive, add the coking property that not only is beneficial to the formability when improving base in the raw material and burns till when, also have the feature of environmental protection; Eight, the drying of adobe and firing period be short, and save energy.
Description of drawings
Accompanying drawing is the process flow sheet of the inventive method.
Embodiment:
Embodiment 1:
A) water ratio is mixed with mixer with 10 parts of dry discharge fly ashes or mixes by artificial at 40 parts of mud of 58~62%, 0.01 ‰ of the dirty weight of adding DJ-904 reodorant (Shanghai Duojia Water Processing Sci-Tech Co., Ltd.'s production and sales) in the batch mixing process, make water ratio at mud-coal ash mixed material of 44~46%, again this compound is made the base substrate of mud flyash with mud extruder, through seasoning to water ratio 8~12%, pulverize with pulverizer, it is stand-by to obtain dry powder;
B) treat that mud is by draining naturally and ted to 28~32%, then with 30 parts in the dry powder in 50 parts in mud and the step a) and add wilkinite tankage by 1 weight part with the industry of being rich in glass cullet of 2 weight parts, 3 parts of the additives of domestic refuse and the DJ-904 reodorant (Shanghai Duojia Water Processing Sci-Tech Co., Ltd.'s production and sales) that adds mud weight 0.01 ‰, with roll crusher, biaxial rneader, wheel roller mix, broken, grind the base material of practicing to particle≤2mm;
C) the base material with step b) adopts vacuum extruder extrusion moulding adobe commonly used in the prior art, forming pressure and vacuum tightness are respectively 2Mpa and 0.092MPa, treat adobe through 7~9 days seasoning to water ratio 7~8%, send into wheel kiln baking then, 930~980 ℃ of firing temperatures, firing period 34~36 hours, kiln discharge gets finished bricks.
Embodiment 2
A) water ratio is mixed with mixer with 20 parts of dry discharge fly ashes or mixes by artificial at 50 parts of mud of 64~66%, 0.01 ‰ of adding mud weight chlorine dioxide bactericide in the batch mixing process, make water ratio at mud-coal ash mixed material of 44~46%, again this compound is made the base substrate of mud-flyash with mud extruder, through seasoning to water ratio 8~12%, pulverize with pulverizer, it is stand-by to obtain dry powder;
B) treat that mud is by draining naturally to 40~44%, then with 42 parts in the dry powder in 30 parts in mud and the step a) and add wilkinite tankage by 1 weight part with the industry of being rich in glass cullet of 3 weight parts, 4 parts of the additives of domestic refuse and the chlorine dioxide bactericide that adds mud weight 0.005 ‰, with roll crusher, biaxial rneader, wheel roller mix, broken, grind the base material of practicing to particle≤2mm;
C) the base material with step b) adopts vacuum extruder extrusion moulding adobe commonly used in the prior art, forming pressure and vacuum tightness are respectively 2Mpa and 0.092MPa, treat adobe through 7~9 days seasoning to water ratio 7~8%, send into the tunnel furnace roasting then, 930~980 ℃ of firing temperatures, firing period 20~22 hours, kiln discharge gets finished bricks.
Embodiment 3
A) water ratio is mixed with mixer with 2 parts of dry discharge fly ashes or mixes by artificial at 10 parts of mud of 54~56%, because of the mud in the present embodiment has added corresponding agent of deodorising and sterilizing in paper mill effluent is handled, so in the batch mixing process, no longer add, make water ratio at mud-coal ash mixed material of 44~46%, again this compound is made the base substrate of mud-flyash with mud extruder,, pulverize with pulverizer to water ratio 8~12% through seasoning, it is stand-by to obtain dry powder;
B) treat that mud is by draining naturally and ted to 30~34%, then with 6.5 parts, 10 parts mud of dry powder and 18 parts of dry discharge fly ashes in 60 parts in mud and the step a), practice base material with roll crusher, biaxial rneader, wheel roller mixing, fragmentation, stone roller to particle≤2mm, because of mud consumption in the present embodiment big, and pollute less, for this reason, need not add additive and disinfectant;
C) the base material with step b) adopts vacuum extruder machine extrusion moulding adobe commonly used in the prior art, forming pressure and vacuum tightness are respectively 2Mpa and 0.092MPa, treat adobe through the artificial seasoning of 12~14h to water ratio 7~8%, send into the tunnel furnace roasting then, 950~980 ℃ of firing temperatures, firing period 18~22 hours, kiln discharge gets finished bricks.
Embodiment 4:
A) save;
B) with water ratio at 80 parts of mud and 20 parts of dry discharge fly ashes of 50~52%, and add the industry of being rich in glass cullet, 5 parts of the additives of domestic refuse and the chlorine dioxide bactericide that adds mud weight 0.01 ‰, use roll crusher, biaxial rneader, wheel roller mixing, fragmentation, grind the base material of practicing to particle≤2mm;
C) with b) the base material adopt vacuum extruder machine extrusion moulding adobe commonly used in the prior art, forming pressure and vacuum tightness are respectively 2Mpa and 0.092MPa, treat adobe through 7~9 days seasoning to water ratio 7~8%, send into wheel kiln baking then, 980~1050 ℃ of firing temperatures, firing period 32~36 hours, kiln discharge gets finished bricks.
Pushed away and as can be known by present embodiment, what adopt because of step b) is 80 parts of mud and 20 parts of dry discharge fly ash proportion relations, does not re-use mud, and promptly mud is realized mummification by mixing with flyash, so directly obtain the base material with this mud-coal ash mixed material.
Embodiment 5:
A) save;
B) with water ratio at 60 parts of mud and 40 parts of dry discharge fly ashes of 75~80%, and add wilkinite tankage by 1 weight part with the industry of being rich in glass cullet of 5 weight parts, 5 parts of the additives of domestic refuse and the chlorine dioxide bactericide that adds mud weight 0.01 ‰, with roll crusher, biaxial rneader, wheel roller mix, broken, grind the base material of practicing to particle≤2mm;
C) the base material with step b) adopts vacuum extruder machine extrusion moulding adobe commonly used in the prior art, forming pressure and vacuum tightness are respectively 2Mpa and 0.092MPa, treat adobe through the artificial seasoning (using the annular kiln waste heat) of 10~12h to water ratio 7~8%, send into wheel kiln baking then, 1000~1100 ℃ of firing temperatures, firing period 30~35 hours, kiln discharge gets finished bricks.
Pushed away and as can be known by present embodiment, what adopt because of step b) is 60 parts of mud and 40 parts of dry discharge fly ash proportion relations, does not re-use mud, and promptly mud is realized mummification by mixing with flyash, so directly obtain the base material with this mud-coal ash mixed material.
Embodiment 6:
A) water ratio is mixed with mixer with 23 parts of dry discharge fly ashes or mixes by artificial at 32 parts of mud of 78~82%, the reodorant that in the batch mixing process, adds dirty weight 0.01 ‰, make water ratio at mud-coal ash mixed material of 44~46%, again this compound is made the base substrate of mud flyash with mud extruder, through seasoning to water ratio 8~12%, pulverize with pulverizer, it is stand-by to obtain dry powder;
B) treat that mud is by draining naturally and ted to 32~35%, then with 33 parts in the dry powder in 45 parts in mud and the step a) and add wilkinite tankage by 1 weight part with the industry of being rich in glass cullet of 1 weight part, 2 parts of the additives of domestic refuse and the reodorant that adds mud weight 0.005 ‰, with roll crusher, biaxial rneader, wheel roller mix, broken, grind the base material of practicing to particle≤2mm;
C) the base material with step b) adopts vacuum extruder machine extrusion moulding adobe commonly used in the prior art, forming pressure and vacuum tightness are respectively 2Mpa and 0.092MPa, treat adobe through 7~9 days seasoning to water ratio 7~8%, send into wheel kiln baking then, 950~980 ℃ of firing temperatures, firing period 32~36 hours, kiln discharge gets finished bricks.
And then ground is pushed away by above-mentioned all embodiment and as can be known, as long as the stock mould of vacuum brick brick extruding machine is changed, just can comply with and need to obtain solid brick, perforated brick or hollow brick.
The advantage that compared with the prior art the present invention has sees the following form.
The contrast project Common clay brick CN1371833A CN1408675A Technical solution of the present invention The comparing result summary
Main raw material Clay Mud and 25% clay The clay of mud and 70-85% Mud and mud 1371833A and 1408675A because of all need with and clay be unfavorable for definitely protecting land resources, and outstanding to the environmental protection contribution; The present invention exempts to use clay fully, and serious mud employing is made a gesture of measuring greatly to environmental influence, and environment protection significance highlights.
Addition material Cinder Cinder Flyash and combustion-supporting material cinder, coal dust, wood chip, chemical dyestuff waste material and flux material iron powder, cinder, coal dust, clay or chemical industry binding agent. Flyash and discarded tankage, industry, domestic refuse when exploiting based on alkalimetal oxide with bentonite ore. The 1371833A composition is assorted, though the 1408675A composition is few, cinder system is generally used for joining the commodity raw material in the clay brick, and price is higher; Interpolation composition of the present invention all is a waste.
Drying method Do not have Do not reach Only mention the dry air notion and do not have the concrete measure instruction. Adopt dry discharge fly ash and mud fly-ash Preparation dry mash. The present invention mixes with dry discharge fly ash and part mud and dry discharge fly ash and produces dry powder, be equipped with measure such as drain again, have easy, economic effect.
The sterilization raw material Do not have Do not reach Clorox or Sodium Silicofluoride or Phaltan etc., throwing amount are the 0.5-1% of mud weight. Reodorant or chlorine dioxide bactericide. The used sterilization raw material of 1408675A is selected the sterilization raw material with the present invention and is compared, and disinfection cost exceeds 2-3 of the present invention doubly, and is uneconomical.
Brick bat drying Seasoning 12-15 days Do not reach the time Seasoning 4 days 7-9 days 1408675A is big than a part clay because of having used, and is not enough to be dried in 4 days according to general knowledge be put to the agglomerating requirement; Time of drying of the present invention is reasonable, effective, is satisfied the sintering requirement.
Artificial seasoning 16-24h Do not reach the time Do not reach 12-14h Shorten time of drying
Roasting time, temperature 24~48h, 900~1000 ℃ The burned brick product are at least 90h (because of general sintering temperature is more than 900 ℃), do not reach concrete sintering temperature, but need insulation 180h. 4~4.5h, 600~700 ℃ 18~36h, 900~1100 ℃ The 1371833A firing time is long, power consumption is big, and soaking time is long, it is tediously long to cause the process-cycle, and the sintering time of 1408675A, temperature are against objective and can't be fired into brick; Roasting time of the present invention is short, and temperature is reasonable.
Volume density 1500-1700Kg/m 3 Do not reach Do not reach 700-1400Kg/m 3 Light weight helps reducing the building loading.
Thermal resistance value 1.4-1.6m 2K/W Do not reach Do not reach 1.7-5.0m 2K/W Heat-proof quality is good.

Claims (10)

1, a kind of materials for wall is characterized in that being made of the starting material of following weight part ratio: 20~80 parts in mud, 0~60 part in mud, 10~40 parts in flyash, 0~5 part of additive.
2, materials for wall according to claim 1 is characterized in that mud is the mud that papermaking, dyeing waste water control are produced; And described mud is the mud of river, the pool, lake, damp desilting gained.
3, materials for wall according to claim 1 is characterized in that additive is industry and the domestic refuse that helps to adjust the wilkinite tankage of plasticity index and help to improve sintering character.
4, materials for wall according to claim 3 is characterized in that industry and domestic refuse are industry and domestic refuse based on alkalimetal oxide.
5, materials for wall according to claim 4 is characterized in that alkalimetal oxide is glass cullet.
6, the method for a kind of usefulness materials for wall processing as claimed in claim 1 wall body brick is characterized in that may further comprise the steps:
A) general's part water ratio is that 50~82% mud and flyash are 10: 1~8 mixing by weight, add 0 of mud weight~0.01 ‰ reodorant or chlorine dioxide bactericide simultaneously, make mud-coal ash mixed material, again compound is made base substrate, pulverize behind the body drying, it is stand-by to obtain dry powder;
B) again the water ratio in 0~45 part in the dry powder of weight part, after draining away the water be 28~44% 0~60 part in mud, water ratio be 50~82% 10~40 parts in 0~80 part in mud, flyash, additive mix, grind for 0~5 part practice, broken, the reodorant or the chlorine dioxide bactericide that add 0 of mud weight~0.01 ‰ simultaneously obtain the base material of particle≤2mm;
C) with carrying out drying behind the base material base, deliver to roasting then, 900~1100 ℃ of firing temperatures, roasting time 18~36 hours obtains finished bricks.
7, the method for materials for wall processing wall body brick according to claim 6, it is characterized in that the flyash described in the step a) is dry discharge fly ash, described reodorant is that DJ-904 reodorant, described body drying are meant by any one mode in seasoning or the artificial seasoning and are dried to water ratio 5~15%.
8, the method for materials for wall according to claim 6 processing wall body brick is characterized in that draining described in the step b) is meant that nature drains to add manually and teds.
9, the method for materials for wall processing wall body brick according to claim 6, it is characterized in that the base described in the step c) is to use the vacuum extruder extrusion moulding, forming pressure is 2Mpa, vacuum tightness≤0.092Mpa, described drying is nature or the artificial seasoning of utilizing brick furnace residual heat, and degree of drying is a water ratio 7~8%.
10, the method for materials for wall processing wall body brick according to claim 7 is characterized in that described seasoning is to utilize sun power and natural wind as the dry energy, and described artificial seasoning is to utilize annular kiln or residual heat of tunnel kiln as the dry energy.
CNB2005100407860A 2005-06-22 2005-06-22 Material for wall, and method for processing wall brick by said material Expired - Fee Related CN1323047C (en)

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CN1724446A true CN1724446A (en) 2006-01-25
CN1323047C CN1323047C (en) 2007-06-27

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Cited By (6)

* Cited by examiner, † Cited by third party
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CN102260067A (en) * 2011-05-25 2011-11-30 江苏龙腾工程设计有限公司 Sintered brick with high content of tap water plant sludge and preparation method thereof
CN102519255A (en) * 2011-12-13 2012-06-27 谭明中 External combustion type calcining device for brick making and green brick calcining method
CN104016601A (en) * 2014-06-20 2014-09-03 淮安市楚城水泥有限公司 Method for producing cement cementing material through industrial waste residue sludge
CN110304940A (en) * 2019-07-29 2019-10-08 叶活耀 A method of using coal ash for manufacturing for lightweight wall plate
CN110317079A (en) * 2019-07-29 2019-10-11 叶活耀 A method of lightweight wall plate is prepared using sludge
CN110344519A (en) * 2019-08-21 2019-10-18 山西天合新材料科技有限公司 A kind of multifunctional ecological exterior wall and preparation method thereof

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CN1223545C (en) * 2001-09-28 2005-10-19 韩晓伟 Sintered brick produced by using paper-making sludge of waste paper and its preparing method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102260067A (en) * 2011-05-25 2011-11-30 江苏龙腾工程设计有限公司 Sintered brick with high content of tap water plant sludge and preparation method thereof
CN102519255A (en) * 2011-12-13 2012-06-27 谭明中 External combustion type calcining device for brick making and green brick calcining method
CN104016601A (en) * 2014-06-20 2014-09-03 淮安市楚城水泥有限公司 Method for producing cement cementing material through industrial waste residue sludge
CN104016601B (en) * 2014-06-20 2018-06-12 淮安市水泥厂有限公司 The method that industrial residue sludge produces cement cementitious material
CN110304940A (en) * 2019-07-29 2019-10-08 叶活耀 A method of using coal ash for manufacturing for lightweight wall plate
CN110317079A (en) * 2019-07-29 2019-10-11 叶活耀 A method of lightweight wall plate is prepared using sludge
CN110344519A (en) * 2019-08-21 2019-10-18 山西天合新材料科技有限公司 A kind of multifunctional ecological exterior wall and preparation method thereof

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