CN1705688A

CN1705688A - Multiple catalyst system for olefin polymerization and polymers produced therefrom

Info

Publication number: CN1705688A
Application number: CN 200380101509
Authority: CN
Inventors: 江培军; A·德克梅日安; J·A·M·卡尼克; C·L·西姆斯; R·阿伯哈里; C·A·加西亚-佛朗哥; D·R·约翰斯拉德
Original assignee: Exxon Chemical Patents Inc
Current assignee: ExxonMobil Chemical Patents Inc
Priority date: 2002-10-15
Filing date: 2003-10-15
Publication date: 2005-12-07
Anticipated expiration: 2023-10-15
Also published as: CN100588663C; CN1820034A; CN1820034B

Abstract

This invention relates to a polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 15 mole % of ehtylene, where the polymer has: a) a Dot T-Peel of 1 Newton or more; and b) a branching index (g') of 0.95 or less measured at the Mz of the polymer; c) an Mw of 100,000 or less and to a continuous process to produce a branched olefin polymer comprising 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less under selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins; 4) at a temperature of greater than 100 DEG C; 5) at a residence time of 120 minutes or less; 6) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1; 7) wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst components; and wherein at least 20% of the olefins are converted to polymer.

Description

Be used for the multi-catalyst system of olefinic polymerization and by the polymer of its production

Relevant case information

The application require the denomination of invention submitted to take on October 15th, 2002 for the provisional application USSN 60/418,482 of " for the multi-catalyst system of olefinic polymerization with by the polymer of its production " as priority. The application also require the denomination of invention submitted to take on April 4th, 2003 as the USSN 60/460,714 of " polyolefin adhesive composition and goods prepared therefrom " as priority.

The US2000000199093P of the USSN 60/199,093 that the application and on April 21st, 2000 submit to and 20 submissions in April calendar year 2001 (requiring with USSN 60/199,093 as priority) is relevant. The application also is correlated with the USSN 60/171,715 that submitted on December 21st, 1999, the USSN 09/745,394 that on December 21st, 2000 was mentioned and the USSN 09/746,332 that mentioned on December 21st, 2000. The application is also relevant with WO 01/81493.

Technical field

The present invention relates to the method for multi-catalyst olefin polymerization with by the polymer of its production. The present invention be more particularly directed to produce the method for polyolefin binding agent and by the binding agent of its production.

Background technology

For some application such as binding agent, single polymers does not have necessary performance combination. The mutual blend of each single polyolefin that usually will have some characteristic is with the useful properties of each one-component of expectation combination. The result is generally the blend of the average behavior of each single performance that presents these single resins. For example EP 0 527 589 discloses the blend of pliability low-molecular-weight amorphous polypropylene and HMW isotactic polypropylene, obtains to have thus balancing machine intensity and flexible composition. The pliability that these compositions display are better than independent isotactic polypropylene, but still lack other physical characteristic. Also there is the problem of compatibility deficiency in the physical blending thing. Unless choose component according to compatibility, otherwise they can be separated or a small amount of component migrates to the surface. Reactor blend, be called again tight blend (being included in the composition of two or more polymer that prepare in same reactor or the series reaction device), usually be used for head it off, yet the catalyst system that will find under identical environment operation to produce different polymer is a challenge.

Past has used the multi-catalyst system to produce the reactor blend of various polymer (being called again tight blend) and other polymer composition. Reactor blend and other still polymer composition are usually thought the physical blending thing that is better than similar polymer. For example US 6,248, and 832 disclose the polymer composition of producing in the presence of one or more Stereoselective metallocene catalyst systems and at least a non-Stereoselective metallocene catalyst system. The performance of resulting polymers is better than the performance of disclosed physical blending thing among EP 0 527 589 and the US 5,539,056.

Therefore exploitation has been that this area is interested for the production of the multi-catalyst system of new polymer composition. US5 for example, 516,848 disclose the different purposes based on the transistion metal compound of cyclopentadienyl group of with aikyiaiurnirsoxan beta or the activation of non-coordination anion two kinds. Especially, embodiment discloses the combination of catalyst compounds, for example uses (the Me of activator such as MAO or four (pentafluorophenyl group) boric acid DMA activation₂Si(Me ₄C ₅)(N-c-C ₁₂H ₂₃)TiCl ₂And racemic-Me₂Si(H ₄Ind)ZrCl ₂, or (Me₂Si(Me ₄C ₅)(N-c-C ₁₂H ₂₃)TiCl ₂And Me₂Si(Ind ₂)HfMe ₂(Ind=indenyl), produce thus have bimodal molecular weight distribution (Mw/Mn), (12 to 52wt % isotactic PP in embodiment 2,3 and 4 product) and weight average molecular weight that isotacticity changes surpass 100,000 and sometimes even up to 1, the polypropylene of 200,000 (for as thermoplastic). Same US6,184,327 disclose a kind of thermoplastic elastomer (TPE) that comprises the branched olefin polymer with crystallization side chain and amorphous main chain, wherein at least the side chain of 90mol% be isotactic or syndiotactic polypropylene and at least the main chain of 80mol% be random polypropylene, this elastomer is produced by the following method: a) under about 90 ℃ to about 120 ℃ of temperature propylene monomer is contacted with the carbon monoxide-olefin polymeric that comprises chirality solid rigid (stereorigid) transition metal catalyst compound that can produce isotactic or syndiotactic polypropylene in solution; B) a) product and propylene and non-essential one or more copolymerisable monomers are carried out copolymerization with the achirality transition-metal catalyst that can produce random polypropylene in polymer reactor; And c) reclaims branched olefin polymer. Similarly, US 6,147, and 180 disclose a kind of synthetic method of thermoplastic polymer composition, said composition is produced by the following method: polymerization single polymerization monomer production at least 40% ethenyl blocking macromonomer at first, and then with this macromonomer and ethylene copolymer. In addition, US6,323,284 disclose a kind of catalyst system copolymerization alpha-olefin and α that passes through with two kinds of separation, and the ω alkadienes is produced the method for thermoplastic compounds (mixture of crystallization and amorphous polyolefin copolymer).

In addition, other people has tested with the new polymer composition of multistage method production. For example EP 0 366 411 disclose by use that two step methods produce have the EPDM main chain and with its polyacrylic graft polymers in the position grafting of one or more diolefinic monomer, this two steps method is used different Ziegler-Natta catalyst systems in each step. This graft polymers allegedly can be used for improving the impact property of co-blend polypropylene composition.

Although disclosed each polymer has the combination of interested performance in the above-mentioned document, but still need to provide other that be suitable for each final use new with the new compositions different performance balance. Especially, also need to find a kind of firm composition that has simultaneously the binding agent characteristic and can use with adhesive techniques and device.

For the general information in this field, can reference:

1. DeSouza and Casagrande deliver the dual catalyst system paper in calendar year 2001: "Recent Advances in Olefin Polymerization Using Binary Catalyst Systems, Macromol.Rapid Commun.2001,22, No.16 (p1293 to 1301). At 1299 pages, they have reported the propylene system of production " gluing " product.

2. the research for the on-the-spot mixture production stereoblock polypropylene that has different stereoselective metallocene catalysts by use of being undertaken by Lieber and Brintzinger recently: " Propene Polymerization with Catalyst Mixtures Containing Different Ansa-Zirconocenes:Chain Transfer to Alkylaluminum Cocatalyst and Formation of Stereoblock Polymers ", Macromolecules 2000,33, No.25 (p 9192-9199). Propylene polymerization uses metallocene catalyst H₄C ₂(Flu) ₂

ZrCl

₂2, racemic-Me₂Si(2-Me-4-tBu-C ₅H ₂) ₂ZrCl ₂And racemic-Me₂Si(2-MeInd) ₂ZrCl ₂At MAO (MAO) or triisobutyl aluminium (AlⁱBu ₃)/triphenylcarbenium four (perfluorophenyl borate) (trityl borate) is carried out under existing as catalyst for copolymerization. Make spent mixed catalyst H₄C ₂(Flu) ₂ZrCl ₂And racemic-Me₂Si(2-MeInd) ₂ZrCl ₂At MAO or AliBu₃Propylene polymerization under/trityl borate exists generates waxy solid, and this solid can be separated into random (ether is solvable) and isotactic (insoluble) fraction fully. Each fraction does not contain any combination of isotactic and random five unit group types, shows that these catalyst mixtures do not form stereoblock polymer.

3. the various polymer of the production delivered of Aggarwal: " Structures and Properties of Block Polymers and Multiphase Polymer Systems:An Overview of Present Status and Future Potential ", S.L.Aggarwal, Sixth Biennial Manchester Polymer Symposium (UMIST Manchester, March 1976).

4. the people such as " adopt in the propylene polymerization that metallocene catalyst carries out selective " Resconi, Chem Rev.2000,100,1253-1345.

None is directly involved in above-mentioned list of references based on the polyolefinic demand that contains simultaneously the binding agent of amorphous and crystallographic component. This type of binding agent of industrial needs is as requiring the obviously substitute of the blend of the hydrocarbon resin tackifier of amount.

Interested other list of references comprises:

1) EP patent: EP 0 619 325 B1, EP 719 802 B1;

2) US patent/open source literature: 6,207,606,6,258,903,6,271,323,6,340,703,6,297,301, US 2001/0007896 A1,6,184,327,6,225,432,6,342,574,6,147,180,6,114,457,6,143,846,5,998,547,5,696,045,5,350,817, US6,569,965;

3) PCT open source literature: WO 00/37514, WO 01/81493, WO 98/49229, WO 98/32784 and WO 01/09200;

4)“Metallocene-Based Branch-Block thermoplastic Elastomers”， Markel，etal.Macromolecules 2000，Volume 33，No.23.pgs. 8541-8548。

Summary of the invention

A kind of polymer that the present invention relates to comprise one or more C3 to C40 alkene, non-essential one or more alkadienes and be lower than 15mol% ethene, wherein this polymer has:

A) some T shape peeling force (Dot T-Peel) 1 newton or larger; With

B) branch index (g ') 0.95 or lower is with the Mz measurement of polymer;

C) Mw 100,000 or lower.

The invention still further relates to and relate to a kind of polymer that comprises one or more C3 to C40 alkene, wherein this polymer has:

A) some T shape peeling force 1 newton on brown paper or larger;

B) branch index (g ') 0.95 or lower is with the Mz measurement of polymer;

C) Mw 10,000 to 100,000; With

D) melting heat 1 is to 70J/g.

A) some T shape peeling force 1 newton on brown paper or larger;

B) branch index (g ') 0.98 or lower is with the Mz measurement of polymer;

C) Mw 10,000 to 60,000; With

D) melting heat 1 is to 50J/g.

The invention still further relates to a kind of homo-polypropylene or propylene and the copolymer of 5mol% ethene at the most, it has:

A) isotactic continuous length (isotactic continuous length (isotactic run length) " IRL " is defined as the percentage of mmmm five unit groups divided by 0.5 * mmmr, five unit group percentages) 1 to 30, preferred 3 to 25, more preferably 4 to 20 is measured by carbon 13 NMR;

B) r two unit group percentages greater than 20%, preferred 20 to 70%, measure by carbon 13 NMR; With

C) melting heat 70J/g or lower, preferred 60J/g or lower, more excellent 1 to 55J/g, more preferably 4 are to 50J/g.

The invention still further relates to the polyolefinic method of a kind of production, comprising:

1) choose the first catalytic component, this catalytic component can be produced under the polymerizing condition of choosing has Mw 100,000 or lower and degree of crystallinity 5% or lower polymer;

2) choose the second catalytic component, this catalytic component can be produced under the polymerizing condition of choosing has Mw 100,000 or lower and degree of crystallinity 20% or larger polymer;

3) these catalytic components are contacted in conversion zone under the condition of choosing with one or more C3 to C40 alkene in the presence of one or more activators;

4) obtain polymer.

The invention further relates to the continuation method of production branched olefin polymer, comprising:

3) these catalytic components are contacted with non-essential one or more alkadienes with one or more C3 to C40 alkene in the presence of one or more activators;

4) be higher than under 100 ℃ in temperature;

5) in 120 minutes time of staying or shorter;

6) wherein the ratio of the first catalyst and the second catalyst is 1: 1 to 50: 1;

7) wherein the activity of catalytic component is 100kg polymer/g catalytic component at least; Wherein at least 20% alkene is converted into polymer.

The accompanying drawing summary

Fig. 1 is for the complex viscosity variation with temperature figure of embodiment 12,22 and 49 when sample is cooled off with 10 ℃/min.

Fig. 2 is for its branch index of polymer g ' of embodiment 4 and 31 productions and the graph of a relation of molecular weight.

Fig. 3 is from the heptane Soxhlet insoluble matter (top trace) of embodiment 4 extractions and the C-13NMR of the solvable fraction of hexane room temperature (bottom trace).

Fig. 4 is that the aPP/scPP branched block is with respect to the C-13 NMR spectrum of scPP and aPP comparison. Comparative sample is once produced with a kind of catalyst; APP is synthetic with the catalyst of regulation, and scPP produces with stereospecific catalyst. Top trace is the aPP comparative sample. Middle trace is the scPP comparative sample, and bottom trace is embodiment 4.

Fig. 5 shows from the temperature of the classification sample of embodiment 31 extractions and the relation between the complex viscosity.

Fig. 6 is the DSC trace of the polymer of embodiment 32 in the table 6.

Technology contents describes in detail

Be explanation the present invention and its claim and easily reference, when relating to the polymer that comprises alkene, the alkene that exists in the polymer is the polymerized form of alkene.

In another embodiment, the polymer that the present invention relates to comprise one or more C3 to C40 alkene (preferred propylene) and be lower than 50mol% ethene, this polymer has:

A) some T shape peeling force 1 to 10,000 newton; With

B) Mz/Mn 2 to 200; And/or

C) Mw is that X and g ' are Y (measuring with the Mz of polymer) according to following table C:

Table C

X(Mw)	Y(g′)
X(Mw)	Y(g′)	100,000 or lower, preferred 80,000 or lower, preferred 70,000 or lower, more preferably 60,000 or lower, more preferably 50,000 or lower, more preferably 40,000 or lower, more preferably 30,000 or lower, more preferably 20,000 or lower, more preferably 10,000 or lower. In some embodiments, X also is at least 7000, more preferably 10,000, more preferably at least 15,000.	0.9 or lower preferred 0.7 or lower preferred 0.5-0.9
75,000 or lower, preferred 70,000 or lower, preferred 60,000 or lower, more preferably 50,000 or lower, more preferably 40,000 or lower, more preferably 30,000 or lower, more preferably 20,000 or lower, more preferably 10,000 or lower. In some embodiments, A also is at least 1000, preferably at least 2000, more preferably at least 3,000, more preferably at least 4,000, more preferably at least 5,000, more preferably at least 7,000, more preferably at least 10,000, more preferably at least 15,000.	0.92 or lower preferred 0.6 or lower preferred 0.4-0.6		0.9 or lower preferred 0.7 or lower preferred 0.5-0.9
	0.92 or lower preferred 0.6 or lower preferred 0.4-0.6	50,000 or lower, more preferably 40,000 or lower, more preferably 30,000 or lower, more preferably 20,000 or lower, more preferably 10,000 or lower. In some embodiments, A also is at least 1000, preferably at least 2000, more preferably at least 3,000, more preferably at least 4,000, more preferably at least 5,000, more preferably at least 7,000, more preferably at least 10,000, more preferably at least 15,000.	0.95 or lower preferred 0.7 or lower preferred 0.5-0.7
30,000 or lower, more preferably 25,000 or lower, more preferably 20,000 or lower, more preferably 15,000 or lower, more preferably 10,000 or lower. In some embodiments, A also is at least 1000, preferably at least 2000, more preferably at least 3,000, more preferably at least 4,000, more preferably at least 5,000, more preferably at least 7,000, more preferably at least 10,000, more preferably at least 15,000.	0.98 or lower preferred 0.7-0.98		0.95 or lower preferred 0.7 or lower preferred 0.5-0.7

In another embodiment, when Mw is 15,000 to 100,000 o'clock, g '＜(10 then^-12Mw ²-10 ^-6Mw+1.0178)。

In some embodiments, g ' is 0.9 or lower, 0.8 or lower, 0.7 or lower, 0.6 or lower, 0.5 or lower, and with the Mz measurement of polymer.

In another embodiment, above-mentioned polymer has 40 to 250 ℃ of peak fusing points (Tm), or 60 to 190 ℃, or 60 to 150 ℃, or 60 to 130 ℃. In some embodiments, the peak fusing point is 60 to 160 ℃. In other embodiments, the peak fusing point is 124-140 ℃. In other embodiments, melting hump is 40-130 ℃.

In another embodiment, above-mentioned polymer also has viscosity (being called again Brookfield viscosity or melt viscosity) 90 under 190 ℃, 000mPasec or lower (measuring according to ASTM D3236 under 190 ℃), or 80,000 or lower, or 70,000 or lower, or 60,000 or lower, or 50,000 or lower, or 40,000 or lower, or 30,000 or lower, or 20,000 or lower, or 10,000 or lower, or 8,000 or lower, or 5000 or lower, or 4000 or lower, or 3000 or lower, or 1500 or lower, or 250 to 6000 mPasec, or 500 to 5500mPasec, or 500 to 3000mPasec, or 500 to 1500mPasec; And/or the viscosity 8000mPasec in the time of 160 ℃ or lower (under 160 ℃, measuring according to ASTM D3236); Or 7000 or lower, or 6000 or lower, or 5000 or lower, or 4000 or lower, or 3000 or lower, or 1500 or lower, or 250 to 6000mPa.sec, or 500 to 5500mPasec, or 500 to 3000mPasec, or 500 to 1500mPasec. In other embodiments, the viscosity in the time of 190 ℃ is 200,000mPasec or lower, depends on application. In other embodiments, viscosity is 50,000mPasec or lower, depends on application.

In another embodiment, above-mentioned polymer also has melting heat of 70J/g or lower, or 60J/g or lower, or 50J/g or lower, or 40J/g or lower, or 30J/g or lower, or 20J/g or lower and greater than 0, or greater than 1J/g, or greater than 10J/g, or be 20 to 50J/g.

In another embodiment, above-mentioned polymer is also had an Xiao A hardness (measuring according to ASTM 2240) 95 or lower, 70 or lower, or 60 or lower, or 50 or lower, or 40 or lower, or 30 or lower, or 20 or lower. In other embodiments, Xiao A hardness is 5 or higher, 10 or higher, or 15 or higher. In some used such as packing material, Xiao A hardness was preferably 60-70.

In another embodiment, polymer of the present invention has Mz/Mn2 to 200, and preferred 2 to 150, preferred 10 to 100.

In another embodiment, above-mentioned polymer also has 200 ℃ or lower of shear bond fail temperatures (SAFT measures according to ASTM 4498), or 40 to 150 ℃, or 60 to 130 ℃, or 65 to 110 ℃, or 70-80 ℃. In certain embodiments, preferred SAFT 130-140 ℃.

In another embodiment, above-mentioned polymer also has T shape peeling force 1 to 10,000 newton, or 3 to 4000 newton, or 5 to 3000 newton, or 10 to 2000 newton, or 15 to 1000 newton. Point T shape peeling force is measured according to ASTM D1876, different is that sample is produced by the following method: (2.54cm * 7.62cm) brown paper basic unit cut substrate is combined with an adhesive dot, and the volume of binding agent is: occupy about 1 square inch (1 inch=2.54cm) area when in 500g load lower compression with two 1 inch * 3 inches. In case after the preparation, all samples (with 2 inches of speed/min) pull open, is recorded the damage and failure power that applies with testing machine in harness test. Record maximum, force that each specimen reaches and it is average, so obtain average maximum, force, it is recorded as a T shape peeling force.

In another embodiment, above-mentioned polymer also has a couple of days to 1 hardening time second, or 60 seconds or shorter, or 30 seconds or shorter, or 20 seconds or shorter, or 15 seconds or shorter, or 10 seconds or shorter, or 5 seconds or shorter, or 4 seconds or shorter, or 3 seconds or shorter, more or 2 seconds or shorter, or 1 second or shorter.

In another embodiment, above-mentioned polymer also has Mw/Mn 2 to 75, or 4 to 60, or 5 to 50, or 6 to 20.

In another embodiment, above-mentioned polymer also has Mz 1,000, and 000 or lower, preferred 15,000 to 1,000,000, or 20,000 to 800,000, or 25,000 to 350,000.

In another embodiment, above-mentioned polymer also can have breaking strain (measuring according to ASTM D-1708) 50 to 1000%, preferred 80 to 200% under 25 ℃. In some of the other embodiments, breaking strain is 100 to 500%.

In another embodiment, polymer described herein has fracture tensile strength (measuring according to ASTM D-1708) 0.5MPa or higher under 25 ℃, or 0.75MPa or higher, or 1.0MPa or higher, or 1.5MPa or higher, or 2.0MPa or higher, or 2.5MPa or higher, or 3.0MPa or higher, or 3.5MPa or higher.

In another embodiment, above-mentioned polymer also has 20 to 110 ℃ of crystalline temperatures (Tc). In some embodiments, Tc is 70 to 100 ℃. In other embodiments, Tc is 30 to 80 ℃. In other embodiments, Tc is 20 to 50 ℃.

In some embodiments, above-mentioned polymer has slope-0.1 or lower in temperature T c+10 ℃ to Tc+40 ℃ scope in as shown in Figure 1 complex viscosity and temperature trace, preferably-0.15 or lower, more preferably-0.25 or lower (under nitrogen atmosphere and 10 ℃/min of cooldown rate by the ARES dynamic mechanically spectrometer measurement with frequency 10rad/s and strain 20% operation). Slope is defined as log (complex viscosity) with respect to the derivative of temperature.

In another embodiment, the Tc of above-mentioned polymer is lower than at least 10 ℃ of Tm, preferably is lower than at least 20 ℃ of Tm, preferably is lower than at least 30 ℃ of Tm, more preferably less than at least 35 ℃ of Tm.

In another embodiment, more above-mentioned polymer have melt index (MI) than (I₁₀/I ₂) 6.5 or lower, preferred 6.0 or lower, preferred 5.5 or lower, preferred 5.0 or lower, preferred 4.5 or lower, preferred 1 to 6.0 (I₁₀And I₂Measure in that 2.16kg and 190 ℃ are lower according to ASTM 1238D).

In another embodiment, more above-mentioned polymer have melt index (MI) (measuring in that 2.16kg and 190 ℃ are lower according to ASTM 1238 D) 25dg/min or higher, preferred 50dg/min or higher, preferred 100dg/min or higher, more preferably 200dg/min or higher, more preferably 500dg/min or higher, more preferably 2000dg/min or higher.

In another embodiment, polymer has melt index (MI) 900dg/min or higher.

In another embodiment, it is wide that above-mentioned polymer has in the DSC trace 10 to 60 ℃ of crystallization ranges, and preferred 20 to 50 ℃, preferred 30 to 45 ℃. Have therein in the DSC trace at two or more non-overlapped peaks, it is wide that each peak has in the DSC trace 10 to 60 ℃ of crystallization ranges, and preferred 20 to 50 ℃, preferred 30 to 45 ℃.

In another embodiment, the polymer that the present invention produces has molecular weight distribution (Mw/Mn) at least 2, and preferably at least 5, preferably at least 10, further more preferably at least 20.

In another embodiment, the polymer of production can have single mode, bimodal or the multi-modal molecular weight distribution (Mw/Mn) of polymer material, measures by size exclusion chromatography (SEC). Bimodal or the multi-modal SEC of referring to trace have more than a peak or flex point. Flex point is the point of the second dervative signal intensity (for example just becoming or on the contrary from negative) of wherein curve.

In another embodiment, above-mentioned polymer has activation energy 8 to 15cal/mol. Activation energy calculates owing to the relation in the zone of fuel factor (being assumed to similar Arrhenius relation) with complex viscosity and therein viscosity rising of temperature.

In another embodiment, polymer of the present invention can have degree of crystallinity at least 5%.

In another embodiment, above-mentioned polymer also can have one or more following performances:

A) the peak fusing point is 60 to 190 ℃, or 60 to 150 ℃, or 80 to 130 ℃; And/or

B) the viscosity 8000mPasec in the time of 190 ℃ or lower (under 190 ℃, measuring according to ASTM D3236), or 5000 or lower, or 4000 or lower, or 3000 or lower, or 1500 or lower, or 250 to 6000mPasec, or 500 to 5500mPasec, or 500 to 3000mPasec, or 500 to 1500mPasec; And/or the viscosity 8000mPasec in the time of 160 ℃ or lower (under 160 ℃, measuring according to ASTM D3236); Or 7000 or lower, or 6000 or lower, or 5000 or lower, or 4000 or lower, or 3000 or lower, or 1500 or lower, or 250 to 6000mPa.sec, or 500 to 5500mPasec, or 500 to 3000mPasec, or 500 to 1500mPasec; And/or

C) Hf (melting heat) 70J/g or lower, or 60J/g or lower, or 50J/g or lower, or 40J/g or lower, or 30J/g or lower, or 20J/g or lower and greater than 0, or greater than 1J/g, or greater than 10J/g, or 20 to 50J/g; And/or

D) Xiao A hardness (measuring according to ASTM 2240) 90 or lower, or 80 or lower, or 70 or lower, or 60 or lower, or 50 or lower, or 40 or lower; And/or

E) shear bond fail temperature (SAFT measures according to ASTM 4498) is 40 to 150 ℃, or 60 to 130 ℃, or 65 to 110 ℃, or 70-80 ℃; And/or

F) some T shape peeling force 1 to 10,000 newton, or 3 to 4000 newton, or 5 to 3000 newton, or 10 to 2000 newton, or 15 to 1000 newton; And/or

G) a couple of days to 0.1 hardening time second, or 60 seconds or shorter, or 30 seconds or shorter, or 20 seconds or shorter, or 15 seconds or shorter, or 10 seconds or shorter, or 5 seconds or shorter, or 4 seconds or shorter, or 3 seconds or shorter, more or 2 seconds or shorter, or 1 second or shorter; And/or

H) Mw/Mn is greater than 1 to 75, or 2 to 60, or 2 to 50, or 3 to 20; And/or

I) Mz 1,000, and 000 or lower, preferred 15,000 to 500,000, or 20,000 to 400,000, or 25,000 to 350,000.

Useful property combination comprises aforesaidly having T shape peeling force 1 to 10,000 newton, or 3 to 4000 newton, or 5 to 3000 newton, or 10 to 2000 newton, or the polymer of 15 to 1000 newton and following performance:

1.Mw 30,000 or lower, 60 to 190 ℃ of peak fusing points, melting heat 1 to 70J/g, branch index (g ') 0.90 or lower (Mz with polymer measures) and the melt viscosity 8000mPasec in the time of 190 ℃ or lower; Or

2.Mz 20,000 to 500,000 and 60 to 150 ℃ of SAFT; Or

3.Mz/Mn 2-200 and hardening time 2 seconds or shorter; Or

(4.Hf melting heat) 20 to 50J/g, Mz20,000-500,000 and Shore hardness 50 or lower; Or

5.Mw/Mn the viscosity 5000mmPasec during greater than 1 to 50,190 ℃ or lower; Or

6.Mw 50,000 or lower, 60 to 190 ℃ of peak fusing points, melting heat 2 to 70J/g, branch index (g ') 0.70 or lower (Mz with polymer measures) and the melt viscosity 8000mPasec in the time of 190 ℃ or lower.

In preferred embodiments, polymer of the present invention comprises amorphous, crystallization and branched block structure.

In preferred embodiments, polymer comprises at least 50wt% propylene, preferably at least 60% propylene, or at least 70% propylene, or at least 80% propylene. In another embodiment, polymer comprises propylene and 15mol% ethene or lower, preferred 10mol% ethene or lower, more preferably 9mol% ethene or lower, more preferably 8mol% ethene or lower, more preferably 7mol% ethene or lower, more preferably 6mol% ethene or lower, more preferably 5mol% ethene or lower, more preferably 4mol% ethene or lower, more preferably 3mol% ethene or lower, more preferably 2mol % ethene or lower, more preferably 1mol% ethene or lower.

In another embodiment, polymer of the present invention comprises and is lower than 5mol% ethene, preferably is lower than 4.5mol% ethene, preferably be lower than 4.0mol% ethene, or be lower than 3.5mol% ethene, or be lower than 3.0mol% ethene, or be lower than 2.5mol% ethene, or be lower than 2.0mol % ethene, or be lower than 1.5mol% ethene, or be lower than 1.0mol% ethene, or be lower than 0.5 mol% ethene, or be lower than 0.25mol% ethene, or be lower than 0mol% ethene.

In another embodiment, the polymer of production has 5 ℃ or lower of glass transition temperatures (Tg), and preferred 0 ℃ or lower, preferred-5 ℃ or lower, or-5 ℃ to-40 ℃, or-5 ℃ to-15 ℃, according to ASTM E 1356 measurements

In another embodiment, polymer of the present invention has amorphous content at least 50%, or at least 60%, or at least 70%, or even 50 to 99%. Amorphous percentage composition is measured according to ASTM E 794-85 with poor formula scanning calorimetry.

In another embodiment, polymer of the present invention has percent crvstallinity 40% or lower, and perhaps 30% or lower, perhaps 20% or lower, or even 10% to 30%. Percent crvstallinity content is measured according to ASTM E 794-85 with poor formula scanning calorimetry. In another embodiment, polymer described herein has percent crvstallinity 5 to 40%, and perhaps 10 to 30%.

In another embodiment, the polymer of producing by the present invention has molecular weight distribution (Mw/Mn) at least 1.5, and preferably at least 2, preferably at least 5, preferably at least 10, or even at least 20. In other embodiments, Mw/Mn is 20 or lower, 10 or lower, even 5 or lower. Molecular weight distribution generally depends on the catalyst of use and process conditions such as temperature, monomer concentration, catalyst ratio (if using multi-catalyst), or the no hydrogen that exists. The consumption of hydrogen can be at the most 2wt%, but is preferably 50 to 500ppm.

In another embodiment, find that the polymer of producing has at least two kinds of molecular weight fractions, its amount is preferably greater than 20wt% greater than 2wt%, separately by polymer weight, passes through gel permeation chromatography. These fractions can be determined by observing two kinds of different molecular weight modes at the GPC trace. Example is to be presented at peak at 20,000Mw place and at the GPC trace at another peak at 50,000Mw place, wherein the representative of the area under first peak is greater than the polymer of 2wt%, and the area representative under second peak is greater than the polymer of 2wt%.

In another embodiment, polymer of the present invention has the solvable fraction of hexane room temperature of 20wt% or higher (based on the weight of starting polymer), with 70wt% or lower, the heptane insolubles that preferred 50wt% or lower Soxhlet seethe with excitement is based on polymer weight. The Soxhlet heptane insolubles refers to wherein a kind of fraction of obtaining during with continuous solvent extraction technology classification when with sample. This classification process carries out in two steps: a step relates to the room temperature solvent extraction, and another step is Soxhlet extractron. In the room temperature solvent extraction, about 1g polymer is dissolved in the 50ml solvent (for example hexane) to separate amorphous or the very low molecular weight material. With this mixture stir about 12 hours at room temperature. Solvable fraction is separated from insoluble matter by filtering under vacuum. Then insoluble matter is carried out Soxhlet extractron technique. This extraction relates to based on it and has boiling point just above the solubility isolating polymer fraction in the various solvents of room temperature to 110 ℃. Will be from the solvent-extracted insoluble matter of room temperature at first with the extraction (Soxhlet) of spending the night of for example hexane and heptane; Weigh by evaporating solvent recovery extracting substance and with residue. Then insoluble sample is extracted with solvent such as heptane with higher boiling temperature, and carry out after the solvent evaporation it being weighed. Will be from the insoluble matter of final step and sleeve pipe in fume hood Air drying to evaporate most of solvent, then dry in the vacuum drying oven of nitrogen purge. Then calculate the amount of insoluble matter remaining in the sleeve pipe, condition is the tare weight of known sleeve.

In another embodiment, the polymer that the present invention produces has heptane insoluble fraction 70wt% or lower, and based on the weight of starting polymer, and the heptane insoluble fraction has branch index g ' 0.9 (preferred 0.7) or lower, measures with the Mz of polymer. In preferred embodiments, this composition has at least solvable fraction of hexane of 20wt%, based on the weight of starting polymer. In another embodiment, the polymer that the present invention produces has heptane insoluble fraction 70wt% or lower, based on the weight of starting polymer, and the Mz 20,000 to 5000,000 of heptane insoluble part. In preferred embodiments, this composition also has at least solvable fraction of hexane of 20wt%, based on the weight of starting polymer. In another embodiment, the polymer of production has at least hexane soluble fraction of 20wt%, based on the weight of starting polymer.

In another embodiment, polymer comprises propylene and 15mol% ethene or lower, preferred 10mol% ethene or lower, more preferably 9mol% ethene or lower, more preferably 8mol% ethene or lower, more preferably 7mol% ethene or lower, more preferably 6mol% ethene or lower, more preferably 5mol% ethene or lower, more preferably 4mol% ethene or lower, more preferably 3mol % ethene or lower, more preferably 2mol% ethene or lower, more preferably 1mol% ethene or lower.

In another embodiment, polymer of the present invention comprises the ethene that is lower than 5mol%, preferably is lower than 4.5mol% ethene, preferably be lower than 4.0mol% ethene, or be lower than 3.5mol% ethene, or be lower than 3.0mol% ethene, or be lower than 2.5mol% ethene, or be lower than 2.0mol % ethene, or be lower than 1.5mol% ethene, or be lower than 1.0mol% ethene, or be lower than 0.5 mol% ethene, or be lower than 0.25mol% ethene, or 0mol% ethene.

Be easy reference, also will be called " semi-crystalline polymer " by the polymer with at least 20% degree of crystallinity of the second Catalyst Production, will be lower than 5% polymer and be called " amorphous polymer " by the degree of crystallinity that has of the first catalytic component production.

In another embodiment of the present invention, the characteristic three district's complex viscosity-temperature graphs of the polymer tool of production, as shown in Figure 1. The temperature dependency of complex viscosity is measured under nitrogen atmosphere and 10 ℃/min of cooldown rate in order to the ARES dynamic mechanically spectrometer of frequency 10rad/s and strain 20% operation. At first with the sample fusing, then be cooled to gradually room temperature, monitor simultaneously the rising of complex viscosity. When being higher than fusing point (this temperature is typical Polymer Processing temperature), complex viscosity relatively low (I district), it reduces gradually rising with temperature. In the II district, when drop in temperature, raising suddenly appears in complex viscosity. The 3rd district (III district) is high complex viscosity district, and it occurs under the lower temperature that is equivalent to application (the final use) temperature. In the III district, complex viscosity is high and further reduce slight the variation with temperature. This complex viscosity pattern is provided at the desirable combination that length under the processing temperature is opened wide time and fast hardening time at a lower temperature in the hot melt binding agent is used.

In preferred embodiments, here the polymer that is lower than 1mol% ethene that has of producing has at least 2mol%, preferred 4mol%, preferred 6mol%, more preferably 8mol%, more preferably 10mol%, more preferably 12mol%, more preferably 15mol%,, more preferably 18mol%, the more preferably (CH of 5mol%₂) ₂The unit is measured by carbon as described below 13 NMR.

In another embodiment, the polymer with 1 to 10mol% ethene of producing here has at least 2+Xmol%, preferred 4+Xmol%, preferred 6+Xmol%, more preferably 8+Xmol%, more preferably 10+Xmol%, more preferably 12+Xmol%, more preferably 15+Xmol%, more preferably 18+Xmol%, more preferably 20+Xmol% (CH₂) ₂The unit, wherein X is the mol% of ethene, (CH₂) ₂The unit is measured by carbon 13NMR as described below.

In preferred embodiments, here the polymer that is lower than 1mol% ethene that has of producing has amorphous component (its be defined as have degree of crystallinity be lower than 5% polymer composition part), and this component comprises at least 3mol%, preferred 4mol%, preferred 6mol%, more preferably 8mol%, more preferably 10mol%, more preferably 12mol%, more preferably 15mol%, more preferably 18mol%, the more preferably (CH of 20mol%₂) ₂The unit is measured by carbon as described below 13 NMR.

In another embodiment, here the polymer with 1 to 10mol% ethene of producing has amorphous component (its be defined as have degree of crystallinity be lower than 20% polymer composition part), this component comprises at least 3+Xmol%, preferred 4+Xmol%, preferred 6+Xmol%, more preferably 8+Xmol%, more preferably 10+Xmol%, more preferably 12+Xmol%,, more preferably 15+X mol%, more preferably 18+Xmol%, more preferably 20+Xmol% (CH₂) ₂The unit, wherein X is the mol% of ethene, (CH₂) ₂The unit is measured by carbon 13 NMR as described below.

Monomer

In preferred embodiments, polymer comprises olefin homo or the copolymer that contains one or more C3 to C40 alhpa olefins. In another preferred embodiment, olefin polymer further comprises one or more alkadienes comonomers, preferably one or more C4 to C40 alkadienes.

In preferred embodiments, polymer comprises olefin homo or copolymer, and it has the 5mol% of being lower than ethene and comprises one or more C3 to C40 alhpa olefins. In another preferred embodiment, have the olefin polymer that is lower than 5mol% ethene, further comprise one or more alkadienes comonomers, preferably one or more C4 to C40 alkadienes.

In preferred embodiments, the polymer of producing here is Noblen or copolymer. Comonomer is preferably C4 to C20 linearity, branching or cyclic monomer, be C4 to C12 linearity or branching alhpa olefin in one embodiment, preferred butylene, amylene, hexene, heptene, octene, nonene, decene, dodecylene, 4-methyl-amylene-1,3-methylpentene-1,3,5,5-trimethyl-hexene-1 etc. The amount of ethene can be 5mol% or lower.

In another embodiment, the polymer of producing here is for one or more linearities or branching C3 to C30 prochirality alpha-olefin that can be by Stereoselective and non-stereospecific catalyst polymerization or contain the alkene of C5 to C30 ring or the copolymer of its combination. Prochirality used herein refers to help to form the monomer of isotactic or syndiotactic polymer when with the stereospecific catalyst polymerization.

The polymerizable olefinic partly can be linearity, branching or contains the mixture of ring or these structures. Preferred linear alpha-alkene comprises C3 to C8 alpha-olefin, more preferably propylene, 1-butylene, 1-hexene and 1-octene, further more preferably propylene or 1-butylene. Preferred branching alpha-olefin comprises 4-methyl isophthalic acid-amylene, 3-Methyl-1-pentene, 3,5,5-trimethyl-1-hexene, 5-ethyl-1-nonene. Preferably contain the aromatic group monomer and comprise at the most 30 carbon atoms. Suitable contain the aromatic group monomer comprise at least one, preferred 1 to 3 aromatic structure, more preferably phenyl, indenyl, fluorenyl or naphthyl moiety. The monomer that contains aromatic group further comprises at least one polymerizable double bond, and after polymerization, aromatic structure will be the side group of auto polymerization owner chain like this. This monomer that contains aromatic group can further be replaced by one or more alkyl (including but not limited to C1 to C10 alkyl). In addition, two adjacent substituting groups can be connected to form ring structure. The monomer that preferably contains aromatic group comprises that at least one is attached to the aromatic structure on the polymerizable olefinic part. Particularly preferred aromatic monomer bag styrene, AMS, to ring-alkylated styrenes, vinyltoluene, vinyl naphthalene, allyl benzene and indenes, particularly styrene, p-methylstyrene, 4-phenyl-1-butylene and allyl benzene.

The monomer that contains non-aromatic cyclic group also is preferred. These monomers can comprise at the most 30 carbon atoms. The suitable monomer that contains non-aromatic cyclic group preferably has at least one polymerizable olefinic group, and this ethylenic group is side group on the ring structure or the part of ring structure. This ring structure also can further be replaced by one or more alkyl (including but not limited to C1 to C10 alkyl). The monomer that preferably contains non-aromatic cyclic group comprises vinyl cyclohexane, VCH, vinyl norbornene, ethylidene norbornene, cyclopentadiene, cyclopentene, cyclohexene, cyclobutane, vinyl adamantane etc.

Can be used for preferred diolefinic monomer of the present invention and comprise any hydrocarbon structure with at least two unsaturated bonds, preferred C4 to C30, wherein at least two unsaturated bonds are introduced in the polymer by Stereoselective or non-stereospecific catalyst easily. Diolefinic monomer further is preferably selected from α, ω-diolefinic monomer (i.e. two-vinyl monomer). Diolefinic monomer is linear two-vinyl monomer more preferably, most preferably is those that contain 4 to 30 carbon atoms. The example of preferred alkadienes comprises butadiene, pentadiene, hexadiene, heptadiene, octadiene, nonadiene, decadinene, 11 carbon diene, 12 carbon diene, oleatridecadiene, 14 carbon diene, 15 carbon diene, 16 carbon diene, 17 carbon diene, 18 carbon diene, 19 carbon diene, 20 carbon diene, 21 carbon diene, 22 carbon diene, two oleatridecadienes, tetracosa carbon diene, 25 carbon diene, 26 carbon diene, heptacosadiene, 28 carbon diene, 29 carbon diene, 30 carbon diene, particularly preferred alkadienes comprises 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadinene, 1,10-11 carbon diene, 1,11-12 carbon diene, 1,12-oleatridecadiene, 1,13-14 carbon diene and low molecular weight polybutadiene (Mw is lower than 1000g/mol). Preferred cyclodiene is included in that each ring position has or cyclopentadiene, vinyl norbornene, norbornadiene, ethylidene norbornene, divinylbenzene, the bicyclopentadiene of unsubstituted or contain the alkadienes of senior ring.

In preferred embodiments, amount in the polymer that one or more alkadienes are here produced for 10wt% at the most, preferred 0.00001 to 1.0wt%, preferred 0.002 to 0.5wt%, further more preferably 0.003 to 0.2wt%, by the gross weight that forms. In some embodiments, with 500pm or still less, preferred 400ppm or still less, preferred 300ppm or alkadienes still less add in the polymerization. In other embodiments, will be at least 50ppm or 100ppm or more or 150ppm or more alkadienes add in the polymerization.

In preferred embodiments, olefin polymer is homo-polypropylene. In another preferred embodiment, olefin polymer comprises propylene, ethene, preferably is lower than 5mol% ethene, and at least a divinyl comonomer. In another preferred embodiment, olefin polymer comprises propylene and at least a divinyl comonomer.

In another embodiment, olefin polymer comprises:

The first monomer, its amount are 40 to 95mol%, preferred 50 to 90mol%, preferred 60 to 80mol%, and

Comonomer, its amount are 5 to 40mol%, preferred 10 to 60mol%, more preferably 20 to 40mol%, and

The 3rd monomer (termonomer), its amount are 0 to 10mol%, more preferably 0.5 to 5mol%, more preferably 1 to 3mol%.

In preferred embodiments, the first monomer comprises one or more arbitrary C3 to C8 linearities, branching or ring-type alpha-olefin, comprises propylene, butylene (with its all isomers), amylene (with its all isomers), hexene (with its all isomers), heptene (with its all isomers) and octene (with its all isomers). Preferred monomer comprises propylene, 1-butylene, 1-hexene, 1-octene etc.

In preferred embodiments, comonomer comprises that one or more arbitrary C2 to C40 linearities, branching or ring-type alpha-olefin are (if condition is to have ethene, its amount is 5mol% or lower), comprise ethene, propylene, butylene, amylene, hexene, heptene, octene, nonene, decene, endecatylene, dodecylene, hexadecene, styrene, 3,5,5-trimethyl hexene-1,3-methylpentene-1,4-methylpentene-1, ENB and cyclopentene.

In preferred embodiments, the 3rd monomer comprises one or more arbitrary C2 to C40 linearities, branching or ring-type alpha-olefin (optimal ethylene, if exist, its amount is 5mol% or lower), include but not limited to ethene, propylene, butylene, amylene, hexene, heptene, octene, nonene, decene, endecatylene, dodecylene, hexadecene, butadiene, 1,5-hexadiene, 1,6-heptadiene, 1,4-pentadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadinene, 1,11-12 carbon diene, styrene, 3,5,5-trimethyl hexene-1,3-methylpentene-1,4-methylpentene-1 and cyclopentadiene.

In preferred embodiments, polymer comprises propylene and 0 to 50mol% ethene, preferred 0 to 30mol% ethene, more preferably 0 to 15mol% ethene, more preferably 0 to 10mol % ethene, more preferably 0 to 5mol% ethene.

In preferred embodiments, polymer comprises propylene and 0 to 50mol% butylene, preferred 0 to 30mol% butylene, more preferably 0 to 15mol% butylene, more preferably 0 to 10mol % butylene, more preferably 0 to 5mol% butylene.

In preferred embodiments, polymer comprises propylene and 0 to 50mol% hexene, preferred 0 to 30mol% hexene, more preferably 0 to 15mol% hexene, more preferably 0 to 10mol % hexene, more preferably 0 to 5mol% hexene.

Method

The invention further relates to the method for producing above-mentioned olefin polymer, comprising:

1) choose the first catalytic component, this component can be produced has Mw100, and 000 or lower and melting heat 10J/g or lower polymer;

2) choose the second catalytic component, this component can be produced has Mw100, and 000 or lower and degree of crystallinity 20% or higher polymer;

3) these catalytic components are contacted in conversion zone with one or more alkene in the presence of one or more activators.

3) these catalytic components are contacted in conversion zone with one or more alkadienes with one or more alkene in the presence of one or more activators.

1) choose the first catalytic component, this component can be produced has Mw100, and 000 or lower and melting heat 70J/g or lower polymer, the macromonomer that can polymerization has reactive terminal;

2) choose the second catalytic component, this component can be produced has reactive terminal, Mw100, and 000 or lower and degree of crystallinity 30% or higher macromonomer;

3) these catalytic components are contacted at conversion zone with non-essential alkadienes with one or more alkene in the presence of one or more activators.

1) choose the first catalytic component, this component can be produced has Mw30, and 000 or lower and melting heat 10J/g or lower polymer, the macromonomer that can polymerization has reactive terminal;

2) choose the second catalytic component, this component can be produced has reactive terminal, Mw30, and 000 or lower and degree of crystallinity 20% or higher macromonomer;

3) these catalytic components are contacted at conversion zone with non-essential other alkene with propylene in the presence of one or more activators.

In another preferred embodiment, the present invention relates to the continuation method of production branched olefin polymer, comprising:

1) chooses the first catalytic component, this component can be produced under the polymerizing condition of choosing has Mw100,000 or lower, preferred 80,000 or lower, preferred 60,000 or lower and degree of crystallinity 5% or lower, preferred 3% or lower, more preferably 2% or lower polymer;

2) choose the second catalytic component, this component can be produced under the polymerizing condition of choosing has Mw 100,000 or lower, preferred 80,000 or lower, preferred 60,000 or lower and degree of crystallinity 20% or higher, preferred 30% or higher, more preferably 40% or higher polymer;

3) under the polymerizing condition of choosing with these catalytic components in the presence of one or more activators with one or more C3 to C40 alkene, preferably one or more C3 to C12 alkene, preferred C3 and one or more ethene with or C4 to C20 comonomer contact with non-essential one or more alkadienes, preferred C4 to C20 alkadienes;

4) temperature be higher than 70 ℃, preferably be higher than 100 ℃, preferably be higher than 105 ℃, more preferably be higher than 110 ℃, more preferably be higher than under 115 ℃;

5) 120 minutes time of staying or shorter, preferred 60 minutes or shorter, preferred 50 minutes or shorter, preferred 40 minutes, preferred 30 minutes or shorter, preferred 25 minutes or shorter, more preferably 20 minutes or shorter, more preferably 15 minutes or shorter, more preferably at 10 minutes or shorter, more preferably 5 minutes or shorter, more preferably 3 minutes or shorter under, or the time of staying can be 60 to 120 minutes;

6) wherein the ratio of the first catalyst and the second catalyst is 1: 1 to 50: 1, preferred 1: 1 to 20: 1, and more preferably 1: 1 to 1: 10;

7) wherein the activity of catalytic component is 3kg at least, preferably at least 50kg, more preferably at least 100kg, more preferably at least 200kg, more preferably 300kg, more preferably 400kg, more preferably 500kg polymer/g catalyst mixture; Wherein at least 80%, preferably at least 85%, more preferably at least 90%,, more preferably at least 95% alkene is converted into polymer.

In another embodiment, the first catalytic component can be produced under the polymerizing condition of choosing has Mw 100,000 or lower and degree of crystallinity 5% or lower polymer, the second catalytic component can be produced under the polymerizing condition of choosing has Mw 100,000 or lower and degree of crystallinity 20% or higher polymer.

In another embodiment, at least 20% more, preferred 20% or more, more preferably 60% or more, more preferably 75% or more, more preferably 85% or more, more preferably 95% or more alkene be converted into polymer.

In preferred embodiments, said method carries out in solution phase, slurry or body phase polymerisation process.

Term refers to continuously in the system that does not operate (or attempting operation) under the interrupting or stopping. The continuation method of for example, producing polymer is the reactant method that adds continuously in one or more reactors and polymeric articles is drawn off continuously wherein.

In another preferred embodiment, in said method, the concentration of reactant is changing 20% or lower, preferred 15% or lower during the time of staying in conversion zone, and more preferably 10% or lower. In preferred embodiments, the concentration of monomer is keeping constant in conversion zone during the time of staying. Monomer concentration advantageous variant 20% or lower, preferred 15% or lower, more preferably 10% or lower, more preferably 5% or lower.

In preferred embodiments, the concentration of catalytic component is keeping constant in conversion zone during the time of staying. The concentration advantageous variant 20% of monomer or lower, preferred 15% or lower, more preferably 10% or lower, more preferably 5% or lower.

In preferred embodiments, the concentration of activator is keeping constant in conversion zone during the time of staying. The concentration advantageous variant 20% of monomer or lower, preferred 15% or lower, more preferably 10% or lower, more preferably 5% or lower.

In another preferred embodiment, in said method, can there be the 3rd catalyst (or more kinds of). The 3rd catalyst can be arbitrary catalytic component of listing here. Preferred the 3rd catalyst comprises the catalyst that can produce wax. Other preferred the 3rd catalyst can comprise any catalyst described herein. Can choose the catalyst that two or more productions have the various macromonomers of reactive terminal, use with catalyst combination that can these macromonomers of polymerization. Two or more catalyst that can the polymerization macromonomer can be chosen and a kind of catalyst of the macromonomer with reactive terminal can be produced. Similarly, also can be chosen at three kinds of catalyst producing different polymer under the identical reaction condition. For example can choose the catalyst of producing slight crystalline polymer, produce the catalyst of highly crystalline polymer and produce the catalyst of amorphous polymer, wherein any catalyst can be produced the polymer that macromonomer with reactive terminal or polymerization have reactive terminal. Similarly, can choose two kinds of catalyst, a kind of production crystalline polymer, a kind of production amorphous polymer is wherein anyly produced the polymer that macromonomer with reactive terminal or polymerization have reactive terminal. Similarly, can choose catalyst, the catalyst of producing wax of producing slight crystalline polymer and the catalyst of producing amorphous polymer, wherein anyly produce the polymer that macromonomer with reactive terminal or polymerization have reactive terminal.

Conversion zone refers to the zone that wherein activating catalyst and monomer can react.

The macromonomer that term has a reactive terminal refers to have 12 or more carbon atoms (preferred 20 or more, more preferably 30 or more, more preferably 12 to 8000 carbon atoms), and have polymerizable and enter vinyl, vinylidene base, 1 in the polymer chain of growing, the polymer of 2-ethenylidene or other end group. The macromonomer that term can polymerization has reactive terminal refers to and the macromonomer (it is tending towards molecular weight greater than typical single monomer such as ethene or propylene) with reactive terminal can be introduced the catalytic component in the polymer chain that grow. The ethenyl blocking chain is general more active than 1,2-ethenylidene or vinylidene base end-blocking chain.

In particularly preferred embodiments, the present invention relates to a kind of olefin polymer, its by in identical polymerisation medium in the presence of at least a stereospecific catalyst system and at least a other catalyst system one or more C of copolymerization₃Or high alpha-olefin and/or one or more di-vinyl monomers and 5mol% ethylene production at the most optionally. This polymerization is preferably carried out in the presence of two kinds of catalyst simultaneously. The polymer of so producing can comprise amorphous polymer chains section and crystalline polymer segment, and wherein at least some segments are connected to each other. Amorphous and crystalline polymer segment is generally one or more alpha-olefins (optionally comprising at the most 5mol% ethene) and/or one or more have the copolymer of the monomer of at least two ethylenic unsaturated bonds. These unsaturated bonds of two classes all are fit to and introduce in the polymer chain of growing by the coordination polymerization of using independently the first or second catalyst system easily, so alkadienes are introduced in the polymer segment by two kinds of Catalyst Production in the hybrid catalyst system of the present invention. In preferred embodiments, these monomers with at least two ethylenic unsaturated bonds are alkadienes, preferred two-vinyl monomer. At least a portion that it is believed that cross-linked polymer segment mixture is to realize by a part two-vinyl comonomer is introduced in two polymer segments between the composition polymerization period, so produces crosslinked between these segments.

In another embodiment, can in single-reactor, prepare and comprise amorphous and polyolefin branch-block compositions aasemi-crystalline component, produce thus required performance balance. Especially, can be in the successive soln reactor spent mixed catalyst and propylene as preferred raw material produced on-site aPP-g-scPP branched structure. In one embodiment, can select Stereoselective bridged bis-indenyl the 4th Catalyst Production hypocrystalline PP of family macromonomer. (all references for the periodic table of elements all refer to the News at Chemical and Engineering, the periodic table of elements of delivering in 63 (5), 27,1985). Bridging list-cyclopentadienyl group hetero atom the 4th family's catalyst can be used for making up amorphous PP (aPP) main chain, introduces simultaneously some hypocrystalline macromonomers (scPP). It is believed that like this and can produce the aPP-g-scPP structure, at least part of grafting of its " g-" expression polymer type. By selecting catalyst, polymeric reaction condition and/or by introducing alkadienes modifier, can be amorphous and the crystallographic component various branches of the production block structure that link together. In the chain that effectively introducing is being grown, preferably has the macromonomer of vinyl end group. Also can use the end of the chain degree of unsaturation (1,2-ethenylidene and vinylidene base) of other type. Under being not wishing to be bound by theory, it is believed that branch-block copolymer comprises the amorphous main chain that has from the crystallization side chain of scPP macromonomer, and it is believed that side chain is polypropylene macromers, it can be by preparing with the catalyst that is fit to preparation isotactic or syndiotactic polypropylene under solution polymerization condition.

The preferred reaction method that production has the polypropylene macromers of high-load terminal ethylenyl groups degree of unsaturation is described in US6, in 117,962. The catalyst that uses be generally solid rigid, chirality or asymmetric bridge metallocenes. For example referring to US4,892,851, US5,017,714, US5,132,281, US5,296,434, US5,278,264, US5,304,614, US5,510,502, WO-A-(PCT/US92/10066), WO-A-93/19103, EP-A2-0577581, EP-A1-0578838 and academic documents " The Influence of Aromatic Substituents on the Polymerization Behavior of Bridged Zirconocene Catalyst ", Spaleck, W. wait the people, Organometallics 1994,13,954-963, with " ansa-Zirconocene Polymerization Catalysts with Annelated Ring Ligands-Effects on Catalytic Activity and Polymer Chain Lengths ", Brinzinger, the people such as H., Organometallics 1994,13,964-970 and the document of wherein quoting.

In some embodiments, it is luxuriant or hafnium is luxuriant to comprise that the first catalyst for the production of the solid rigid transition metal precursors catalyst compounds of hypocrystalline polypropylene macromers of the present invention is selected from two (indenyl) zirconiums of racemic bridging. In another embodiment, the transition metal precursors catalyst compounds is that two (indenyl) zirconiums of racemic-dimetylsilyl-bridging are luxuriant or hafnium is luxuriant. In another embodiment, the transition metal precursors catalyst compounds is two (the 2-methyl 4-phenyl indenyl) zirconium dichlorides of racemic-dimetylsilyl or hafnium or zirconium dimethyl or hafnium. In another preferred embodiment, transition-metal catalyst is two (indenyl) the luxuriant hafniums of racemic-dimetylsilyl-bridging such as two (indenyl) dimethyl of racemic-dimetylsilyl or hafnium dichloride.

It is believed that branch-block fraction and degree of branching depend on the utilizability of the macromonomer with unsaturated end of the chain and the macromonomer introducing performance of special catalyst. For increasing the total amount of aPP-g-scPP branch-block compositions, usually can within being conducive to the method scope of macromonomer production and insertion, operate. These conditions are described in US6,117,962 and the people's such as journal of writings W.Weng Macromol.Rapid Commun., among 2000,21, the 1103-1107 and the embodiment by wherein further specify.

The sum that it is believed that ethenyl blocking scPP macromonomer is higher, and the probability that makes it introduce the aPP main chain is higher, therefore obtain branch-the block sum is higher.

For further increasing the sum of the macromonomer with vinyl chain end, diolefinic monomer can be introduced in the reaction medium. Products obtained therefrom is generally by isotactic polypropylene segment, random polypropylene segment and branch-block species of increasing sum because of the other coupling that brings by the alkadienes crosslinking agent and forms.

Crosslinked generally referring to makes two polymer segments connect by the two keys of each diolefinic monomer are introduced in two different polymer segments. Its degree of crystallinity of polymer segment that so connects can be identical or different. Also can three or more polymer segments be connected by two or more alkadienes on the polymer segment are introduced.

Selecting a kind of consideration of monomer or combination of monomers is that the catalyst system that available two or more that choose are different forms crystallization and amorphous polymer chains section simultaneously. In some embodiments, also need the degree that diolefinic monomer (if existence) is introduced in the crystallization segment is restricted to the amount that does not basically change its degree of crystallinity. It is minimum that the amount of alkadienes coupling agent keeps usually, has viscosity 8000mPa.s or lower to guarantee the entire combination thing for some binding agents application.

As mentioned above, for increasing the total amount of aPP-g-scPP branch-block compositions, usually can within being conducive to the method scope of macromonomer production and insertion, operate. Favourable condition comprises:

1) high concentration catalyst is produced semi-crystalline ethylene base end-blocking macromonomer, and/or

2) regulate the Al/ metal ratio; And/or

3) High Operating Temperature; And/or

4) macromonomer is introduced the catalyst structure with high-affinity; And/or

5) the relatively long time of staying; And/or

6) high monomer conversion ratio (monomer lacks (starvation) condition and strengthens the macromonomer introducing); And/or

7) add modifier rate (alkadienes) to strengthen the total amount of ethenyl blocking macromonomer.

The other method that strengthens aPP-g-scPP branch block compositions is to add therein vinyl is transferred to the chain-transferring agent that the polymer chain end makes the catalyst deactivation simultaneously. These chain-transferring agents include but not limited to vinyl chloride, PVF, bromine ethene. In the method, alkyl aluminum activator such as aikyiaiurnirsoxan beta (the be generally MAO) reactivation of catalyst by existing.

Similarly, fusing and crystallization property can be selected by catalyst, the variation of comonomer adding and process conditions such as temperature and catalyst ratio (if using more than one catalyst) is controlled.

Catalyst compounds

Any catalyst compounds that can produce required polymer material can be used for implementing the present invention. In the description here, transistion metal compound can be described as catalyst precarsor, precursor catalyst compound or catalyst compounds, and these terms can exchange use. Caltalyst is the combination of catalyst precarsor and activator.

Catalyst compounds and selection

Any precursor catalyst compound (catalyst precarsor compound) that can produce required polymer material can be used for implementing the present invention. The precursor catalyst compound that can be used for the inventive method comprises metallocene transistion metal compound (each metallic atom comprises, two or three cyclopentadiene parts), Nonmetallocene early transition metal compound (comprising those with acid amides and/or phenates type part), Nonmetallocene late transition metal compound (comprising those with diimine or diimine pyridyl ligands) and other transistion metal compound.

Usually, can be used for bulky ligand metallocene compound of the present invention (front body catalyst) and comprise half or the full lamellar compound that has with one or more bulky ligand of at least one metallic atom bonding. Typical bulky ligand metallocene compound is generally described as one or more bulky ligand and the one or more leaving group that contains with at least one metallic atom bonding. Bulky ligand generally is combined as representative with one or more openings, the acyclic or ring that condenses or member ring systems or its. These bulky ligand, preferably ring or member ring systems generally are comprised of the periodic table of elements 13 to 16 family's atoms, and these atoms are preferably selected from carbon, nitrogen, oxygen, silicon, sulphur, phosphorus, germanium, boron and aluminium or its combination. The ring or member ring systems most preferably formed by carbon atom, as but be not limited to those cyclopentadienyl ligands or cyclopentadienyl-type ligands structure or other similar functions ligand structure such as pentadienyl, cyclo-octatetraene two bases, cyclobutadiene base or substituted allyl part. Can comprise with other part that cyclopentadienyl-type ligands has a similar functions phenates that acid amides, phosphide, imines, phosphinimine, amidine salt (amidinates) and ortho position replace. Metallic atom is preferably selected from the periodic table of elements 3 to 15 families or group of the lanthanides or actinium series. This metal is preferably and is selected from 3 to 12 families, more preferably 4,5 and 6 group 4 transition metals, and transition metal most preferably is selected from 4 families.

In one embodiment, can be used for one or more bulky ligand metallocene catalyst compounds that carbon monoxide-olefin polymeric of the present invention comprises that following general formula represents:

L ^AL ^BMQ ^* _n (1)

Wherein M is the metallic atom of the periodic table of elements and can be 3 to 12 family's metals or be selected from the metal of group of the lanthanides or the actinium series of the periodic table of elements, and M is preferably 4,5 or 6 group 4 transition metals, and M is 4 group 4 transition metals more preferably, and M is more preferably zirconium, hafnium or titanium further. Bulky ligand L^AAnd L^BFor opening, acyclic or fused rings or member ring systems and be any assistant ligand system, comprise cyclopentadienyl ligands or cyclopentadienyl-type ligands, the hetero atom replacement that does not replace or replace and/or contain heteroatomic cyclopentadienyl-type ligands. The non-limitative example of bulky ligand comprises cyclopentadienyl ligands, ring penta phenanthryl part, indenyl ligands, benzindene ylidene ligands, fluorenyl ligand, dibenzo [b; h] fluorenyl ligand, benzo [b] fluorenyl ligand, cyclo-octatetraene two ylidene ligands, ring penta cyclododecene part, nitrence ylidene ligands, Azulene part, pentalene part, phosphoryl (phosphoyl) part, phosphinimine (WO 99/40125), pyrrole radicals part, pyrazolyl part, carbazyl part, boron benzene part etc.; comprise its hydrogenation variant, such as the tetrahydro indenyl part. In one embodiment, L^AAnd L^BCan be can with any other ligand structure of M π bonding. In another embodiment, L^AOr L^BAtom and molecule amount (MW) surpass 60a.m.u., be preferably greater than 65a.m.u.. In another embodiment, L^AAnd L^BCan comprise being combined with carbon atom forms open, acyclic or the ring that preferably condenses or one or more hetero atoms such as nitrogen, silicon, boron, germanium, sulphur and the phosphorus of member ring systems (helping part such as heterocyclic pentylene Kiev). Other L^AAnd L^BBulky ligand includes but not limited to huge acid amides, phosphide, alkoxide, fragrant oxide, acid imide, carboline (carbolides), borollides, porphyrin, phthalocyanine, corrin and the large ring of other polyazo. Each L^AAnd L^BCan be the bulky ligand with the identical or different type of M bonding independently. In an embodiment of general formula 1, only there is L^AOr L^BIn one.

Each L^AAnd L^BCan be not replace or by all substituent R independently^*Bond replace. Substituent R^*Non-limitative example comprise one or more following groups that are selected from: hydrogen or linearity or branched-alkyl, alkenyl, alkynyl group, cycloalkyl, aryl, acyl group, aroyl, alkoxyl, aryloxy group, alkylthio group, dialkylamino, alkoxy carbonyl, aryloxycarbonyl, carbomoyl, alkyl-or dialkyl-7-amino formoxyl, acyloxy, amino (amido), virtue is amino or its bond. In preferred embodiments, substituent R^*Have at the most 50 non-hydrogen atoms, preferred 1 to 30 carbon atom, it also can be by halogen or hetero atom or the replacement of its analog. Alkyl substituent R^*Non-limitative example comprise methyl, ethyl, propyl group, butyl, amyl group, hexyl, cyclopenta, cyclohexyl, benzyl or phenyl etc., comprise its all isomers such as the tert-butyl group, isopropyls etc. Other alkyl comprises methyl fluoride, fluoro ethyl, and two fluoro ethyls, the iodine propyl group, the bromine hexyl, chlorobenzyl, and the organic quasi-metal group that alkyl replaces comprises trimethyl silyl, trimethyl germyl, methyl diethylsilane base etc.; The organic quasi-metal group that replaces with the halo alkyl comprises three (trifluoromethyl) silicyl, methyl-two (difluoromethyl) silicyl, bromomethyl dimethyl germyl etc.; Comprise for example dimethyl boron with dibasic boryl; Belong to (pnictogen) element group with dibasic phosphorus and comprise dimethyl amine, dimethyl phosphine, diphenylamine, aminomethyl phenyl phosphine, the chalcogen group comprises methoxyl group, ethyoxyl, propoxyl group, phenoxy group, methyl sulphur and ethyl sulphur. Non-hydrogen substituent R^*Comprise atomic carbon, silicon, boron, aluminium, nitrogen, phosphorus, oxygen, tin, sulphur, germanium etc., comprise alkene such as but not limited to the unsaturated substituting group of olefinic, comprise the ethenyl blocking part, such as fourth-3-thiazolinyl, third-2-thiazolinyl, own-5-thiazolinyl etc. In addition, at least two R^*Group, preferred two adjacent R groups are connected to form the ring structure with 3 to 30 atoms that are selected from carbon, nitrogen, oxygen, phosphorus, silicon, germanium, aluminium, boron or its combination. In addition, substituent R^*Also can and form double-basis with the carbon σ key of metal M bonding at one end and L bonding. Other part such as at least one leaving group Q^*Can with the metal M bonding. In one embodiment, Q^*For having the unstable part of single anion with the σ key of M. According to the oxidation state of metal, the numerical value of n is 0,1 or 2, the neutral bulky ligand metallocene catalyst compound of top like this general formula 1 expression. Q^*The non-limitative example of part comprises weak base such as amine, phosphine, ether, carboxylate, alkadienes, has alkyl, hydride or halogen etc. or its combination of 1 to 20 carbon atom. In another embodiment, two or more Q^*Form the part of fused rings or member ring systems. Q^*Other example of part comprises above-mentioned R^*Those substituting groups, comprise cyclobutyl, cyclohexyl, heptyl, tolyl, trifluoromethyl, fourth support base (two Q^*), pentamethylene base (two Q^*), methine (methylidene) (two Q^*), methoxyl group, ethyoxyl, propoxyl group, phenoxy group, two (N-methyl anilides), dimethylformamide, dimethyl phosphide base etc.

In another embodiment, can be used for carbon monoxide-olefin polymeric of the present invention and can comprise one or more bulky ligand metallocene catalyst compounds, the L of its formula of 1^AAnd L^BBy at least one bridged group A^*Mutually bridging represents such as following general formula 2:

L ^AA ^*L ^BMQ ^* _n (2)

The compound of general formula 2 is called bridging bulky ligand metallocene catalyst compound. L^A、L ^B、 M、Q ^*With n be defined above. Bridged group A^*Non-limitative example comprise the bridged group that contains at least one 13 to 16 family's atom, be commonly referred to the divalence structure division, at least a such as but not limited in carbon, oxygen, nitrogen, silicon, aluminium, boron, germanium and tin or its combination. Preferred bridged group A^*Comprise carbon, silicon or germanium atom, A^*Most preferably comprise at least one silicon atom or at least one carbon atom. Bridged group A^*Also can comprise substituent R defined above^*(comprising halogen and iron). Bridged group A^*Non-limitative example can be by R '₂C、R′ ₂CCR′ ₂、R′ ₂Si、R′ ₂SiCR′ ₂、 R′ ₂SiSiR′ ₂R′ ₂Ge, R ' P, R ' N, R ' B represent, wherein R ' is hydride, alkyl, substituted hydrocarbon radical, brine alkyl, replacement brine alkyl, alkyl replacement organic quasi-metal, brine alkyl replacement organic quasi-metal, two replacement boron, two replacement phosphorus genus, replacement chalcogen or halogen group independently, or two or more R ' can be connected to form member ring systems. In one embodiment, the bridging bulky ligand metallocene catalyst compound of general formula 2 has two or more bridged groups A^*(EP 664 301B1). In another embodiment, the bulky ligand metallocene catalyst compound is the bulky ligand L of its formula of 1 and 2^AAnd L^BOn R^*Those that substituting group is replaced by the substituting group of identical or different quantity on each bulky ligand. In another embodiment, general formula 1 and 2 bulky ligand L^AAnd L^BMutually different.

Can be used for other bulky ligand metallocene catalyst compound of the present invention and catalyst system and comprise as describing in the Publication about Document those: US5,064,802,5,145,819,5,149,819,5,243,001,5,239,022,5,276,208,5,296,434,5,321,106,5,329,031,5,304,614,5,677,401,5,723,398,5,753,578,5,854,363,5,856,547,5,858,903,5,859,158,5,900,517 and 5,939,503, with WO93/08221, WO93/08199, WO95/07140, WO98/11144, WO98/41530, WO98/41529, WO98/46650, WO99/02540 and WO99/14221, and EP-A-0 578 838, EP-A-0 638 595, EP-B-0 513 380, EP-A1-0 816 372, EP-A2-0 839 834, EP-B1-0 632 819, EP-B1-0 748 821 and EP-B1-0 757 996, all these documents are incorporated herein by reference here.

In another embodiment, can be used for carbon monoxide-olefin polymeric of the present invention and can comprise bridging hetero atom list bulky ligand metallocene compound. These catalyst and catalyst system type specification are in such as Publication about Document: WO92/00333, WO94/07928, WO 91/04257, WO 94/03506, WO96/00244, WO 97/15602 and WO 99/20637, and US 5,057,475,5,096,867,5,055,438,5,198,401,5,227,440 and 5,264,405, and EP-A-0 420 436, all these documents are incorporated herein by reference here.

In another embodiment, can be used for one or more bulky ligand metallocene catalyst compounds that carbon monoxide-olefin polymeric of the present invention comprises following general formula 3 expressions:

L ^CA ^*J ^*MQ ^* _n (3)

Wherein M is the metallic atom of the periodic table of elements 3 to 16 families or is selected from group of the lanthanides or the metal of actinium series, and M is preferably 3 to 12 group 4 transition metals, and M is 4,5 or 6 group 4 transition metals more preferably, and M most preferably is 4 group 4 transition metals that are in any oxidation state, is in particular titanium; L^CFor with replacement or the unsubstituted bulky ligand of M bonding, J^*With the M bonding; A^*With J^*And L^CBonding; J^*Be the hetero atom assistant ligand; A^*Be bridged group; Q^*Be the monovalent anion part; N is integer 0,1 or 2. In above-mentioned general formula 3, L^C、A ^*And J^*Form the fused rings system. In one embodiment, the L of general formula 3^CFor top to L^ADefinition. A in the general formula 3^*, M and Q^*For what define in the top general formula 1. In general formula 3, J^*For containing heteroatomic part, wherein J^*For being selected from the element with three ligancies of the periodic table of elements 15 families, or be selected from the element with two ligancies of 16 families. J^*Preferably comprise nitrogen, phosphorus, oxygen or sulphur atom, wherein nitrogen is most preferred. In embodiments of the invention, the bulky ligand metallocene catalyst compound is the heterocyclic ligand complex, and wherein bulky ligand is encircled or member ring systems, comprises one or more hetero atoms or its combination. Heteroatomic non-limitative example comprises 13 to 16 family's elements, preferred nitrogen, boron, sulphur, oxygen, aluminium, silicon, phosphorus and tin. The example of these bulky ligand metallocene catalyst compounds is described in as in the Publication about Document: WO 96/33202, WO 96/34021, WO 97/17379 and WO 98/22486, and EP-A1-0 874 005 and US5,637,660,5,539,124,5,554,775,5,756,611,5,233,049,5,744,417 and 5,856,258, all documents are introduced as reference here.

In one embodiment, bulky ligand metallocene compound (front body catalyst) is those complexs based on the bidentate ligand that contains pyridine or quinoline moiety, such as US09/103, those that describe in 620 (applications on June 23rd, 1998), this application is introduced as reference here. In another embodiment, the bulky ligand metallocene catalyst compound is those that describe among WO99/01481 and the WO 98/42664, and these documents all are incorporated herein by reference here.

In another embodiment, the bulky ligand metallocene catalyst compound is metal, preferred transition metal, bulky ligand, preferably replace or unsubstituted π-ligands bound thereto, with the complex of one or more assorted pi-allyl parts, US5,527,752 and 5,747,406 and EP-B1-0 735 057 in describe those, all documents are here as with reference to introducing.

In another embodiment, the bulky ligand metallocene catalyst compound is those that describe among WO 99/01481 and the WO 98/42664, and these documents all are incorporated herein by reference here.

6 useful family's bulky ligand metallocene catalyst systems are described in US5, and in 942,462, the document is incorporated herein by reference here.

Other useful catalyst comprises those Multinuclear metallocene catalysts, and such as WO 99/20665 and 6,010, those that describe in 794, and transition metal metaaracyle structure as describing among EP 0 969 101 A2, are incorporated herein by reference here. Other metallocene catalyst comprises those that describe among EP 0 950 667 A1, double cross connection metallocene catalyst (EP 0 970 074 A1), mooring (tethered) metallocene (EP 970 963 A2) and US6; 008; those sulfonyl catalyst of describing in 394, these documents are incorporated herein by reference here.

Consider that also in one embodiment, above-mentioned bulky ligand metallocene catalyst comprises its structure or optics or enantiomter (meso and racemic isomer for example referring to US5,852,143, are incorporated herein by reference) and its mixture here.

Consider that also above-mentioned arbitrary bulky ligand metallocene catalyst compound has at least one fluoride or fluorine-containing leaving group, such as what describe in the US application serial number 09/191,916 (application on November 13rd, 1998)

The compound that contains 15 family's metals that is used for carbon monoxide-olefin polymeric of the present invention prepares by means known in the art, such as EP 0 893 454 A1, US5,889, in 128 and US5, those that describe in the list of references of quoting in 889,128, all these documents are incorporated herein by reference here. US application serial number 09/312,878 (application on May 17th, 1999) discloses gas or the slurry phase polymerisation process of working load bisamide catalyst, and the document also is incorporated herein by reference here.

Other information for the compound that contains 15 family's metals sees also Mitsui Chemicals, EP 0 893 454 A1 of Inc., and the document discloses is combined the transition metal acid amides for olefin polymerization with activator.

The compound that in one embodiment, will contain 15 family's metals wears out before being used for polymerization. Notice that at least a situation, the freshly prepd catalyst compounds performance of Performance Ratio of this catalyst compounds (aging at least 48 hours) is good.

Also consider and to use bisamide based precursor catalyst. Exemplary compound comprises those that describe in the patent documentation. The people's such as WO 96/23010, WO 97/48735 and Gibson Chem. Comm., pp.849-850 (1998) discloses the part based on diimine of the 8-10 compounds of group that carries out ion activation and olefin polymerization. From the polymerisation catalyst system of 5-10 family metal, wherein the activated centre is described in US5 by high oxidation and stable by low ligancy polyanionic ligand system, in 502,124 and its division US5,504,049. Also can be referring to US5,851,945 5 family's organo-metallic catalyst compound and US6,294,495 contain tridentate ligand 5-10 family organo-metallic catalyst. The 11 family's catalyst precarsor compounds with the activation of ionization co-catalyst that can be used for alkene and vinyl-based polar molecule are described among the WO 99/30822.

Other useful catalyst compounds is EP-A2-0 816 384 and US5, those 5 and 6 family metal imino group complexs of describing in 851,945, and described document is incorporated herein by reference here. In addition, metallocene catalyst comprises bridging two (virtue is amino) 4 compounds of group, is described in Organometallics 1995,14 by people such as D.H. McConville, and among the 5478-5480, the document is incorporated herein by reference here. In addition, two (amino) catalyst compounds of bridging are described in WO 96/27439, and the document is incorporated herein by reference here. The catalyst that other is useful such as US5, two (the hydroxyaromatic nitrogen ligand) described in 852,146, the document is incorporated herein by reference here. Other the useful catalyst that contains one or more 15 family atoms comprises those that describe among the WO 98/46651, and the document is incorporated herein by reference here.

US5,318,935 have described bridging and non-bridged two amino catalyst compounds of 4 family's metals that can carry out alpha-olefine polymerizing. Bridging two (virtue is amino) 4 compounds of group that are used for olefinic polymerization are described in Organometallics 1995,14 by people such as D.H.McConville, among the 5478-5480. The document has provided synthetic method and characterization of compound. Further work appears at the people's such as D.H.McConville Macromolecules 1996,29, among the 5241-5243, this job description as the bridging of 1-hexene oligomerization catalyst two (virtue is amino) 4 compounds of group. Transistion metal compound suitable of the present invention in addition comprises those that describe among the WO 96/40805. Cation 3 families or lanthanide series metal olefinic polymerization complex are disclosed in the unsettled US application serial number 09/408,050 (September 29 1999 applying date). Single anion bidentate ligand and two kinds of single anion ligands are stablized those catalyst precarsors, and this precursor can activate with ion co-catalyst of the present invention.

A lot of extra suitable catalyst precursor compounds have been described on the document. But contain and to capture part or alkylation and make it contain the compound that to capture part to be fit to the present invention. Such as " the The Search for New-Generation Olefin Polymerization Catalysts:Life Beyond Metallocenes " referring to people such as V.C. Gibson, Angew.Chem. Int.Ed., 38,428-447 (1999).

The present invention can also implement such as those disclosed catalyst among EP 0 874 005 A1 with the catalyst that contains the phenates part, and the document is introduced as reference here.

In another embodiment, the conventional type transition-metal catalyst can be used for implementing the present invention. The conventional type transition-metal catalyst is those conventional Ziegler-Natta well known in the art, vanadium and Phillips type catalyst. For example Ziegler-Natta catalyst is described in Ziegler-Natta Catalysts and Polymerizations, John Boor, and Academic Press, New York is in 1979. The example of conventional type transition-metal catalyst also is described in US4, and in 115,639,4,077,904,4,482,687,4,564,605,4,721,763,4,879,359 and 4,960,741, all documents are here as with reference to introducing. Can be used for conventional type transition metal catalyst compound of the present invention comprises and is selected from the periodic table of elements 3 to 17 families, preferred 4 to 12 families, the more preferably transistion metal compound of 4 to 6 families.

Preferred conventional type transition-metal catalyst can be used formula M R_xExpression, wherein M is selected from 3 to 17 families, preferred 4 to 6 families, the more preferably metal of 4 families, most preferably titanium; R is halogen or oxyl; X is the oxidation state of metal M. The non-limitative example of R comprises alkoxyl, phenoxy group, bromide, chloride and fluoride-based. Wherein M is that the limiting examples of the conventional type transition-metal catalyst of titanium comprises TiCl₄、TiBr ₄、Ti(OC ₂H ₅) ₃Cl、Ti(OC ₂H ₅)Cl ₃、Ti(OC ₄H ₉) ₃Cl、 Ti(OC ₃H ₇) ₂Cl ₂、Ti(OC ₂H ₅) ₂Br ₂、TiCl ₃·1/3AlCl ₃And Ti (OC₁₂H ₂₅)Cl ₃。

Can be used for the conventional type transition metal catalyst compound based on magnesium/titanium electron donor complex of the present invention and be described in for example US4, in 302,565 and 4,302,566, the document all is incorporated herein by reference here. MgTiCl particularly preferably₆(ethyl acetate) 4 derivatives.

UK Patent Application 2,105,355 and US5,317,036 (being incorporated herein by reference here) have been described various conventional type vanadium catalyst compounds. The non-limitative example of conventional type vanadium catalyst compound comprises vanadyl trihalid, alkoxy halide and alkoxide such as VOCl₃、 VOCl ₂(OBu), wherein Bu=butyl, and VO (OC₂H ₅) ₃ Four halogenation vanadium and halogenated alkoxy vanadium such as VC_l4And VCl₃(OBu); Vanadium and vanadyl acetylacetonate and chloracetyl acetone solvate such as V (AcAc)₃And VOCl₂(AcAc), wherein (AcAc) is acetylacetonate. Preferred conventional type vanadium catalyst compound is VOCl₃、VCl ₄And VOCl₂-OR, wherein R is alkyl, preferred C₁To C₁₀Aliphatic series or aromatic hydrocarbyl such as ethyl, phenyl, isopropyl, butyl, propyl group, normal-butyl, isobutyl group, the tert-butyl group, hexyl, cyclohexyl, naphthyl etc., and vanadium acetylacetonate.

Be applicable to conventional type chrome catalysts compound of the present invention, be commonly referred to Phillips type catalyst and comprise CrO₃, luxuriant, the silyl chromate of chromium, chromyl chloride (CrO₂Cl ₂), chromium-2-ethyl-caproate, chromium acetylacetonate (Cr (AcAc)₃) etc. Non-limitative example is described in US3, and in 709,853,3,709,954,3,231,550,3,242,099 and 4,077,904, these documents all are incorporated herein by reference here.

Be applicable to other conventional type transition metal catalyst compound of the present invention and catalyst system and be disclosed in US4,124,532,4,302,565,4,302,566,4,376,062,4,379,758,5,066,737,5,763,723,5,849,655,5,852,144,5,854,164 and 5,869,585 and EP-A2 0 416 815 A2 and EP-A1 0 420 436 in, these documents all are incorporated herein by reference here.

Other catalyst can comprise cationic catalyst well known in the art such as AlCl₃, and other cobalt, iron, nickel and palladium catalyst. For example referring to US3,487,112,4,472,559,4,182,814 and 4,689,437, these documents all are incorporated herein by reference here.

Consider that also other catalyst can be combined by the catalyst compounds in being applicable to carbon monoxide-olefin polymeric of the present invention. For example, referring to US4,937,299,4,935,474,5,281,679,5,359,015,5,470,811 and 5,719,241, these documents all are incorporated herein by reference here.

Further contemplate, above-mentioned one or more catalyst compounds or catalyst system can be combined with one or more conventional catalyst compounds or catalyst system. The non-limitative example of mixed catalyst and catalyst system is described in US4, and 159,965,4,325,837,4,701,432,5,124,418,5,077,255,5,183,867,, 5,391,660,5,395,810,5,691,264,5,723,399 and 5,767,031 and WO 96/23010 (open day on August 1st, 1996), all documents are here as with reference to introducing.

The preferred metallocene catalysed agent that is used for the present invention can more specifically represent that by one of following general formula (all references of family are Chemical and Engineering News all, 63 (5), the new family mark of the periodic table of elements of describing in 27,1985):

[{[(A-Cp)MX ₁] ⁺} _d]{[B′] ^d-} (4)

[{[(A-Cp)MX ₁L] ⁺} _d]{[B′] ^d-} (5)

Wherein (A-Cp) is (Cp), (Cp^*) or Cp-A '-Cp^* Cp and Cp^*For " the identical or different cyclopentadienyl rings of replacement; each substituting group S " is alkyl, substituted hydrocarbon radical, brine alkyl, replacement brine alkyl, alkyl replacement organic quasi-metal, brine alkyl replacement organic quasi-metal, two replacement boron, two replacement phosphorus genus, replacement chalcogen or halogen group independently by 0 to 5 substituting group S, or Cp and Cp^*Be cyclopentadienyl rings, wherein " group is connected to form C to any two adjacent S₄To C₂₀Ring obtains saturated or unsaturated many ring cyclopentadienyl ligands thus; Cp and Cp^*Can in ring, there be one or more carbon atoms to be replaced by 15 or 16 family's elements, particularly S, O, N or P;

A ' is bridged group;

(C ₅H _5-y-xS″ _x) " the cyclopentadienyl group that group replaces that is by 0 to 5 S defined above;

X is 0 to 5, the expression substitution value;

M is titanium, zirconium or hafnium;

X ₁Be that hydride group, alkyl, substituted hydrocarbon radical, alkyl replace the organic quasi-metal base or brine alkyl replaces the organic quasi-metal base, these groups can be optionally and one of M and L or both or L ' or all or arbitrary M, S " or S ' covalent bonding, condition is X₁Not for replacing or unsubstituted cyclopentadienyl rings;

(JS′ _z-l-y) be heteroatom ligand, wherein J is the element with ligancy 2 that is selected from the element with ligancy 3 of the periodic table of elements 15 families or is selected from the periodic table of elements 16 families; S ' is following group: alkyl, substituted hydrocarbon radical, brine alkyl, replacement brine alkyl, alkyl replace organic quasi-metal or brine alkyl replaces organic quasi-metal; With z be the ligancy of element J;

Y is 0 or 1;

L is alkene, alkadienes or aryne part. L ' is identical with L, and can be amine, phosphine, ether or sulfide part, or any other neutral Lewis base; L ' also can be the Second Transition compound of same type, such two metal center M and M^*Pass through X₁And X '₁Bridging, wherein M^*Have the implication identical with M, X '₁、X ₂And X '₂Have and X₁Identical implication, wherein these dimer compounds that can be the precursor of catalyst cationic moiety are represented by following general formula:

Wherein w is 0 to 3 integer,

B ' is for having molecular diameter approximately or greater than the chemically stable non-nucleophilic anionic complex of 4 dusts, or from the anion Lewis acid activation agent of the precursors reaction of the cationic moiety of the catalyst system of describing among Lewis acid activation agent and the general formula 1-4. When B ' is the Lewis acid activation agent, X₁Also can be the alkyl that is provided by the Lewis acid activation agent; With

D is the integer of expression B ' electric charge.

Catalyst preferably passes through at least two kinds of components in conjunction with preparation. In a preferred embodiment, the first component is the cyclopentadienyl derivative that contains 4 family's metallic compounds of at least one at least one part that will be combined with second component or its at least a portion such as its cationic moiety. Second component is the ion-exchange compound that comprises cation and non-coordination anion, described cation will with contained at least a part irreversible reaction in described 4 family's metallic compounds (the first component), described non-coordination anion or be comprise metal or the coordination of metalloid atom covalence of a plurality of and center band forms electric charge and shield described atom lipophilic group single coordinate complex or to contain a plurality of boron former in the anion such as polyhedron borine, carborane and metallocarborane.

Usually, can be the anionic complex of any stable and bulkiness with following molecule attribute for the suitable anion of second component: 1) anion should have molecular diameter greater than 4 dusts; 2) anion should form stable ammonium salt; 3) negative electrical charge on the anion answer delocalization on the anionic framework or localization in anion nuclear; 4) anion should be relatively bad nucleopilic reagent; With 5) anion should not be strong reduction or oxidising agent. Satisfy anion such as multinuclear borine, carborane, metallocarborane (metallacarborane), polyoxy anion and the anion binding complex of these standards, fully be described in the Chemistry Literature.

The cationic moiety of second component can comprise Bronsted acid such as proton or protonated lewis base, maybe can comprise lewis acid such as ferricinum ion, _, triphenylcarbenium or silver-colored cation.

In another preferred method, second component be will with the Lewis acid complex of at least one ligand reaction of the first component, thus with capture from the first component now with the part formation general formula 4-6 of second component bonding the ionic species described. Aikyiaiurnirsoxan beta and special MAO, namely trimethyl aluminium reacts the product that forms with stoichiometric water in aliphatic series or aromatic hydrocarbon, is particularly preferred lewis acid second component. Modified alumoxane also is preferred. Aikyiaiurnirsoxan beta is well known in the art and its preparation method is described in US4, in 542,199,4,544,762,5,015,749 and 5,041,585. The technology of preparation modified alumoxane has been described in US5, and 041,584, among EPA0 516 476 and the EPA 0 561 476, these documents are incorporated herein by reference here.

When the first and second components in conjunction with the time, a ligand reaction of second component and the first component, generate thus the anion that consisted of by 4 family's metal cations and above-mentioned anion pair, this anion and compatible and non-with it coordination of 4 family's metal cations that is formed by the first component. The anion of the second compound must be able to be stablized 4 family's metal cation abilities and play catalyst action, and must be sufficiently unstable to allow between polymerization period by alkene, alkadienes or the displacement of acetylene series unsaturated monomer. Catalyst of the present invention can be for support type. US4,808,561 (authorizing day on February 28th, 1989), 4,897,455 (authorizing day January 3 nineteen ninety), 5,057,475 (mandates on October 15th, 1991), US application serial number 459,921 (being disclosed as WO 91/09882), CA1,268,753, US5,240,894 and WO 94 03506 this type of supported catalyst and its production method are disclosed, these documents are incorporated herein by reference here.

Can be used as 4 family's metallic compounds of the first compound (front body catalyst) in the preferred metallocene catalyst of preparation the present invention, namely titanium, zirconium and hafnium metallocene compound are the cyclopentadienyl derivative of titanium, zirconium and hafnium. Usually, useful titanium is luxuriant, zirconium is luxuriant and hafnium is luxuriant expressed by the following formula:

(A-Cp)MX ₁X ₂ (8)

(A-Cp)ML (9)

Wherein (A-Cp) is (Cp) (Cp^*) or Cp-A '-Cp^*, Cp and Cp^*For " the identical or different cyclopentadienyl rings of replacement; each substituting group S " is alkyl, substituted hydrocarbon radical, brine alkyl, replacement brine alkyl, alkyl replacement organic quasi-metal, brine alkyl replacement organic quasi-metal, two replacement boron, two replacement phosphorus genus, replacement chalcogen or halogen group independently by 0 to 5 substituting group S, or Cp and Cp^*Be cyclopentadienyl rings, wherein " group is connected to form C to any two adjacent S₄To C₂₀Ring obtains saturated or unsaturated many ring cyclopentadienyl ligands thus;

A ' is bridged group;

Y is 0 or 1;

X is 0 to 5, the expression substitution value;

L is alkene, alkadienes or aryne part. L ' is identical with L, and can be amine, phosphine, ether or sulfide part, or any other neutral Lewis base; L ' also can be the Second Transition compound of same type, such two metal center M and M^*Pass through X₁And X '₁Bridging, wherein M^*Have the implication identical with M, X '₁Have and X₁Identical implication, X '₂Have and X₂Identical implication, wherein as this dimer compound of the precursor of catalyst cationic moiety by above-mentioned general formula 7 expressions;

W is integer 0 to 3; With

X ₁And X₂Be independently hydride group, alkyl, substituted hydrocarbon radical, brine alkyl, replacement brine alkyl, alkyl-and brine alkyl replace organic quasi-metal, replace phosphorus and belong to base or replace the chalcogen base; Or X₁And X₂Contain the about 3 metallacycle rings to about 20 carbon atoms continuously together and with the formation of metallic atom bonding; Or X₁And X₂Can be together alkene, alkadienes or aryne part; Maybe can be with above-mentioned X when using₁Part gives the Lewis acid activation agent of transition metal component, during such as MAO, and X₁And X₂Can be halogen, alkoxide, fragrant oxide, acid amides, phosphide or other monovalent anion part independently, or X₁And X₂Both also can be connected to form the anion cheland, and condition is X₁And X₂Not for replacing or unsubstituted cyclopentadienyl rings.

Table A has been described the representative component part of the metallocenes of general formula 7-10. This is only enumerated and should not think and limit by any way for illustration purpose. A lot of final components can form by mutual might the making up of conversion component part. When openly comprising the alkyl of alkyl, alkenyl, alkynyl group, cycloalkyl, cycloalkenyl, loop chain alkynyl and aromatic group among the application, this term comprises all isomers. For example, butyl comprises normal-butyl, 2-methyl-propyl, 1-methyl-propyl, the tert-butyl group and cyclobutyl; Amyl group comprises n-pentyl, 1-methyl butyl, 2-methyl butyl, 3-methyl butyl, 1-ethyl propyl, neopentyl, cyclopenta and methyl cyclobutyl; Cyclobutenyl comprises E and the Z-shaped formula of 1-cyclobutenyl, 2-cyclobutenyl, 3-cyclobutenyl, 1-methyl-1-propylene base, 1-methyl-2-acrylic, 2-methyl-1-propylene base and 2-methyl-2-acrylic. This comprises the situation when alkyl and another group bonding, and for example the propyl group cyclopentadienyl group comprises n-pro-pyl cyclopentadienyl group, isopropyl cyclopentadienyl group and cyclopropyl rings pentadienyl. Usually, the part in the Table A or group comprise all isomeric forms. For example, the dimethyl cyclopentadienyl group comprises 1,2-dimethyl cyclopentadienyl group and 1,3-dimethyl cyclopentadienyl group; The methyl indenyl comprises 1-methyl indenyl, 2-methyl indenyl, 3-methyl indenyl, 4-methyl indenyl, 5-methyl indenyl, 6-methyl indenyl and 7-methyl indenyl; The Methylethyl phenyl comprises adjacent Methylethyl phenyl, a Methylethyl phenyl and to the Methylethyl phenyl. The example of concrete catalyst precarsor of the present invention adopts following general formula, and the some of them component is listed in Table A. For the composition of explanation transition metal component, choose any combination of listed material in the Table A. For the name purpose, for bridged group A ', term " silicyl " and " silicylene " commutative use, and expression double-basis material, to bridged group A ', " ethylidene " refers to the link of 1,2-ethylidene and distinguishes with 1,1-ethylidene. Therefore, for bridged group A ', " ethylidene " and " 1,2-ethylidene " commutative use. For the compound with bridged group A ', the bridge location on the cyclopentadienyl type ring is put and is always thought the 1-position. Therefore, for example " 1-fluorenyl " can use with " fluorenyl " exchange.

The illustrative of compounds of general formula 8 types is: two (cyclopentadienyl group) dimethyl hafnium, ethylenebis (tetrahydro indenyl) dihydro (dihidryde) zirconium, two (pentamethyl) diethyl hafnium, dimetylsilyl (1-fluorenyl) (cyclopentadienyl group) titanium chloride etc. The illustrative of compounds of general formula 9 types is two (cyclopentadienyl groups) (1, the 3-butadiene) zirconium, two (cyclopentadienyl group) (2,3-dimethyl-1,3-butadiene) zirconium, two (pentamethyl cyclopentadienyl group) (benzene) zirconium, two (pentamethyl cyclopentadienyl group) ethylidene titanium etc. The illustrative of compounds of general formula 10 types is: dimetylsilyl (tetramethyl-ring pentadienyl) (tert-butyl group is amino) zirconium dichloride, ethylidene (methyl cyclopentadienyl) (phenyl amino) dimethyl titanium, aminomethyl phenyl silicyl (indenyl) (phenyl phosphorus base (phosphido)) dihydro hafnium and (pentamethyl cyclopentadienyl group) (di-t-butyl is amino) dimethoxy hafnium.

The condition that the conditioned disjunction that coordination contains the part of lewis base such as ether forms dimer compound is determined by the spatial volume around the part of metal center. For example, Me₂Si(Me ₄C ₅)(N-t-Bu)ZrCl ₂In the tert-butyl group compare Me₂Si(Me ₄C ₅)(NPh)ZrCl ₂·Et ₂Phenyl among the O has larger space requirement, does not therefore allow the ether coordination of last compound under its solid state. Similarly, because [Me₂Si(Me ₃SiC ₅H ₃)(N-t-Bu)ZrCl ₂] ₂In the trimethyl silyl cyclopentadienyl group with respect to Me₂Si(Me ₄C ₅)(N-t-Bu)ZrCl ₂The tetramethyl-cyclopentadienyl its spatial volume reduction Small, so the former compound is dimeric and the latter is not.

Table A

A’	Cp，Cp ^*, CpR or (C₅H _5-y-xS″ _x)
A’	Cp，Cp ^*, CpR or (C₅H _5-y-xS″ _x)	Dimethyl silylene	Cyclopentadienyl
Diethyl silylene	Methylcyclopentadienyl	Dimethyl silylene	Cyclopentadienyl
Diethyl silylene	Methylcyclopentadienyl	IIC silylene	Dimethyl-cyclopentadienyl
Silyl dibutylsulfoxide	Cyclopentadienyl trimethyl	IIC silylene	Dimethyl-cyclopentadienyl

Diamyl silylene	Tetramethyl cyclopentadienyl
Diamyl silylene	Tetramethyl cyclopentadienyl	Dihexyl silylene	Pentamethylcyclopentadienyl group (non-A ')
Diheptanoate silylene	Ethylcyclopentadienyl	Dihexyl silylene	Pentamethylcyclopentadienyl group (non-A ')
Diheptanoate silylene	Ethylcyclopentadienyl	Two octyl silyl	Diethyl-cyclopentadienyl
Dinonyl silylene	Propylcyclopentadienyl	Two octyl silyl	Diethyl-cyclopentadienyl
Dinonyl silylene	Propylcyclopentadienyl	Didecyl silylene	Dipropyl cyclopentadienyl
II - undecane silylene	Butylcyclopentadienyl	Didecyl silylene	Dipropyl cyclopentadienyl
II - undecane silylene	Butylcyclopentadienyl	II - dodecane silylene	Dibutyl-cyclopentadienyl
Two - tridecane silylene	Pentyl cyclopentadienyl	II - dodecane silylene	Dibutyl-cyclopentadienyl
Two - tridecane silylene	Pentyl cyclopentadienyl	II - tetradecane silylene	Diamyl cyclopentadienyl
II - pentadecyl silylene	Hexyl cyclopentadienyl	II - tetradecane silylene	Diamyl cyclopentadienyl
II - pentadecyl silylene	Hexyl cyclopentadienyl	II - hexadecane silylene	Dihexyl cyclopentadienyl
II - heptadecyl silylene	Heptyl cyclopentadienyl	II - hexadecane silylene	Dihexyl cyclopentadienyl
II - heptadecyl silylene	Heptyl cyclopentadienyl	Two - octadecane silylene	Cyclopentadienyl diheptyl
II - nonacosane silylene	Octylcyclopentadienyl	Two - octadecane silylene	Cyclopentadienyl diheptyl
II - nonacosane silylene	Octylcyclopentadienyl	II - eicosane silylene	Dioctyl cyclopentadienyl
Two - heneicosanoic silylene	Nonyl cyclopentadienyl	II - eicosane silylene	Dioctyl cyclopentadienyl
Two - heneicosanoic silylene	Nonyl cyclopentadienyl	Two - docosanoic silylene	Dinonyl cyclopentadienyl
Two - tricosane silylene	Decyl cyclopentadienyl	Two - docosanoic silylene	Dinonyl cyclopentadienyl
Two - tricosane silylene	Decyl cyclopentadienyl	Two - tetracosanoylaminooctadecane silylene	Didecyl cyclopentadienyl
II - pentacosane silylene	Cyclopentadienyl undecyl	Two - tetracosanoylaminooctadecane silylene	Didecyl cyclopentadienyl
II - pentacosane silylene	Cyclopentadienyl undecyl	Two - hexacosane silylene	Cyclopentadienyl dodecyl
Two - heptacosane silylene	Tridecyl cyclopentadienyl	Two - hexacosane silylene	Cyclopentadienyl dodecyl
Two - heptacosane silylene	Tridecyl cyclopentadienyl	Two - octacosanoic silylene	Cyclopentadienyl tetradecyl
Two - nonacosane silylene	Pentadecyl cyclopentadienyl (without A ')	Two - octacosanoic silylene	Cyclopentadienyl tetradecyl
Two - nonacosane silylene	Pentadecyl cyclopentadienyl (without A ')	II - squalane silylene	Cetyl cyclopentadienyl
Dicyclohexyl silylene	Heptadecyl cyclopentadienyl	II - squalane silylene	Cetyl cyclopentadienyl
Dicyclohexyl silylene	Heptadecyl cyclopentadienyl	Dicyclopentadiene silylene	Octadecyl-cyclopentadienyl
Bicycloheptyl silylene	Cyclopentadienyl nonadecyl	Dicyclopentadiene silylene	Octadecyl-cyclopentadienyl
Bicycloheptyl silylene	Cyclopentadienyl nonadecyl	Ring octyl silyl	Cyclopentadienyl eicosyl
Ring decyl silylene	Cyclopentadienyl Henicosyl	Ring octyl silyl	Cyclopentadienyl eicosyl

Ring dodecane silylene	Docosanyl cyclopentadienyl
Ring dodecane silylene	Docosanyl cyclopentadienyl	Dinaphthyl silylene	Tricosyl cyclopentadienyl
Diphenyl silylene	Tetracosyl group cyclopentadienyl	Dinaphthyl silylene	Tricosyl cyclopentadienyl
Diphenyl silylene	Tetracosyl group cyclopentadienyl	Xylene silylene	Alkyl cyclopentadienyl twenty-five
Dibenzyl silylene	Twenty-six cyclopentadienyl group	Xylene silylene	Alkyl cyclopentadienyl twenty-five
Dibenzyl silylene	Twenty-six cyclopentadienyl group	Diphenylethyl silylene	Alkyl cyclopentadienyl twenty-seven
Bis (phenethyl butyl) silylene	Twenty-eight cyclopentadienyl group	Diphenylethyl silylene	Alkyl cyclopentadienyl twenty-seven
Bis (phenethyl butyl) silylene	Twenty-eight cyclopentadienyl group	Methyl ethyl silylene	Twenty-nine alkyl cyclopentadienyl
Methylpropanesulfonic silylene	Cyclopentadienyl triacontyl	Methyl ethyl silylene	Twenty-nine alkyl cyclopentadienyl
Methylpropanesulfonic silylene	Cyclopentadienyl triacontyl	Methylbut silylene	Cyclohexyl cyclopentadienyl
Methylhexanoic silylene	Phenyl-cyclopentadienyl	Methylbut silylene	Cyclohexyl cyclopentadienyl
Methylhexanoic silylene	Phenyl-cyclopentadienyl	Methyl phenyl silylene	Diphenyl-cyclopentadienyl
Ethylbenzene silylene	Triphenyl cyclopentadienyl	Methyl phenyl silylene	Diphenyl-cyclopentadienyl
Ethylbenzene silylene	Triphenyl cyclopentadienyl	Ethyl propyl silylene	Cyclopentadienyl tetraphenyl
Ethylbutyl silylene	Cyclopentadienyl pentaphenylbenzaldehyde	Ethyl propyl silylene	Cyclopentadienyl tetraphenyl
Ethylbutyl silylene	Cyclopentadienyl pentaphenylbenzaldehyde	Propylbenzene silylene	Cyclopentadienyl toluene
Dimethyl germyl	Benzyl cyclopentadienyl	Propylbenzene silylene	Cyclopentadienyl toluene
Dimethyl germyl	Benzyl cyclopentadienyl	Diethyl germyl	Phenethyl cyclopentadienyl
Germanium group diphenylsilylene	Cyclohexylmethyl cyclopentadienyl	Diethyl germyl	Phenethyl cyclopentadienyl
Germanium group diphenylsilylene	Cyclohexylmethyl cyclopentadienyl	Germanium group Methylphenylsilylene	Naphthyl cyclopentadienyl
Ring four methylene silyl	Cyclopentadienyl methylphenyl	Germanium group Methylphenylsilylene	Naphthyl cyclopentadienyl
Ring four methylene silyl	Cyclopentadienyl methylphenyl	The five methylene silylene	Methyl cyclopentadienyl toluene
CYCLOTRIMETHYLENE a silylene	Methyl ethyl cyclopentadienyl	The five methylene silylene	Methyl cyclopentadienyl toluene
CYCLOTRIMETHYLENE a silylene	Methyl ethyl cyclopentadienyl	Cyclohexyl-N alkanediyl	Methylpropyl cyclopentadienyl
Butyl Prozac two groups	Methylbutyl cyclopentadienyl	Cyclohexyl-N alkanediyl	Methylpropyl cyclopentadienyl
Butyl Prozac two groups	Methylbutyl cyclopentadienyl	Prozac two methyl groups	Methylpentyl cyclopentadienyl
Prozac two phenyl groups	Hexyl methyl cyclopentadienyl	Prozac two methyl groups	Methylpentyl cyclopentadienyl
Prozac two phenyl groups	Hexyl methyl cyclopentadienyl	Prozac perfluorophenyl diyl	Cyclopentadienyl methylheptyl
Methyl phosphine (phosphane) diyl	Cyclopentadienyl methyloctyl	Prozac perfluorophenyl diyl	Cyclopentadienyl methylheptyl
Methyl phosphine (phosphane) diyl	Cyclopentadienyl methyloctyl	Ethyl phosphine two groups	Methyl nonyl cyclopentadienyl
Alkanediyl propyl phosphate	Decyl methyl cyclopentadienyl	Ethyl phosphine two groups	Methyl nonyl cyclopentadienyl

Alkanediyl butyl phosphate	Vinyl cyclopentadienyl
Alkanediyl butyl phosphate	Vinyl cyclopentadienyl	Cyclohexyl phosphine diyl	Propylene-cyclopentadienyl
Phenyl phosphine two groups	Butenyl cyclopentadienyl	Cyclohexyl phosphine diyl	Propylene-cyclopentadienyl
Phenyl phosphine two groups	Butenyl cyclopentadienyl	Borane methyl-diyl	Indenyl
Alkanediyl (phenyl) boron	Methylindenyl	Borane methyl-diyl	Indenyl
Alkanediyl (phenyl) boron	Methylindenyl	Methylene	Dimethylindenyl
Dimethylmethylene	Trimethyl indenyl	Methylene	Dimethylindenyl
Dimethylmethylene	Trimethyl indenyl	Diethyl methyl	Indenyl methylpropyl
Two butylmethylene	Indenyl dimethylpropyl	Diethyl methyl	Indenyl methylpropyl
Two butylmethylene	Indenyl dimethylpropyl	IIC methylene	Methyl propyl indenyl
Diphenylmethylene	Methylethyl indenyl	IIC methylene	Methyl propyl indenyl
Diphenylmethylene	Methylethyl indenyl	Xylene, methylene	Methylbutyl indenyl
Di (tert-butylphenyl) methylene	Ethyl indenyl	Xylene, methylene	Methylbutyl indenyl
Di (tert-butylphenyl) methylene	Ethyl indenyl	Bis (trimethylsilyl alkylphenyl) methylene	Propyl indenyl
Di (alkylphenyl triethylsilyl) methylene	Butylindenyl	Bis (trimethylsilyl alkylphenyl) methylene	Propyl indenyl
Di (alkylphenyl triethylsilyl) methylene	Butylindenyl	Dimethyl dibenzylethylenediamine	Pentyl indenyl
Ring four Asian methylmethylene	Hexyl indenyl	Dimethyl dibenzylethylenediamine	Pentyl indenyl
Ring four Asian methylmethylene	Hexyl indenyl	Pentamethylene ring methylmethylene	Heptyl indenyl
Ethylidene	Octyl indenyl	Pentamethylene ring methylmethylene	Heptyl indenyl
Ethylidene	Octyl indenyl	Methylethylidene	Nonyl indenyl
Dimethylethylene	Decyl indenyl	Methylethylidene	Nonyl indenyl
Dimethylethylene	Decyl indenyl	Three ethylidene	Phenylindenyl
Tetramethylethylenediamine	(Fluorophenyl) indenyl	Three ethylidene	Phenylindenyl
Tetramethylethylenediamine	(Fluorophenyl) indenyl	Cyclopentylene	(Methyl-phenyl)-indenyl
Cyclohexyliene	Indenyl biphenyl	Cyclopentylene	(Methyl-phenyl)-indenyl
Cyclohexyliene	Indenyl biphenyl	Round-heptyl	(Bis (trifluoromethyl) phenyl)-indenyl
Cyclooctylene	Naphthylindenyl	Round-heptyl	(Bis (trifluoromethyl) phenyl)-indenyl
Cyclooctylene	Naphthylindenyl	Propanediyl	Phenanthrylindenyl
Methyl-propane-diyl	Benzyl indenyl	Propanediyl	Phenanthrylindenyl
Methyl-propane-diyl	Benzyl indenyl	Dimethyl-propanediyl	Benzoindenyl
Trimethyl-propanediyl	Cyclohexyl indenyl	Dimethyl-propanediyl	Benzoindenyl

Tetramethyl-propanediyl	Methyl-phenyl-indenyl
Tetramethyl-propanediyl	Methyl-phenyl-indenyl	Pentamethyl propanediyl	Indenyl ethylphenyl
Hexamethyl-propanediyl	Propyl-phenyl-indenyl	Pentamethyl propanediyl	Indenyl ethylphenyl
Hexamethyl-propanediyl	Propyl-phenyl-indenyl	Tetramethyl silylene group	Methyl naphthylindenyl
Vinyl	Ethyl naphthylindenyl	Tetramethyl silylene group	Methyl naphthylindenyl
Vinyl	Ethyl naphthylindenyl	1,1 - ethylene	Propyl naphthylindenyl
Divinyl silylene	(Methyl-phenyl)-indenyl	1,1 - ethylene	Propyl naphthylindenyl
Divinyl silylene	(Methyl-phenyl)-indenyl	Dipropylene silylene	(Dimethyl-phenyl)-indenyl
Dibutylene silylene	(Ethyl-phenyl)-indenyl	Dipropylene silylene	(Dimethyl-phenyl)-indenyl
Dibutylene silylene	(Ethyl-phenyl)-indenyl	Methyl vinyl silylene	(Diethyl-phenyl)-indenyl
Methacrylic silylene	(Propyl-phenyl)-indenyl	Methyl vinyl silylene	(Diethyl-phenyl)-indenyl
Methacrylic silylene	(Propyl-phenyl)-indenyl	Methyl butene silylene	(Dipropyl-phenyl)-indenyl
Dimethylsilyl methylmethylene	Methyltetrahydroindene base	Methyl butene silylene	(Dipropyl-phenyl)-indenyl
Dimethylsilyl methylmethylene	Methyltetrahydroindene base	Butyldiphenylsilyl methylmethylene	Dimethyl tetrahydroindenyl
Dimethylsilyl methylethylidene	Dimethyl-indanyl	Butyldiphenylsilyl methylmethylene	Dimethyl tetrahydroindenyl
Dimethylsilyl methylethylidene	Dimethyl-indanyl	Methylethylidene butyldiphenylsilyl	Dimethyl three hydrogen indenyl
Dimethylsilyl methylpropylene	Methylphenyl tetrahydroindenyl	Methylethylidene butyldiphenylsilyl	Dimethyl three hydrogen indenyl
Dimethylsilyl methylpropylene	Methylphenyl tetrahydroindenyl	Butyldiphenylsilyl methylpropylene	Indanyl methylphenyl
Dimethyl stannyl	Methylphenyl three hydrogen indenyl	Butyldiphenylsilyl methylpropylene	Indanyl methylphenyl
Dimethyl stannyl	Methylphenyl three hydrogen indenyl	Diphenylmethylene stannyl	Ethyl tetrahydro-indenyl
	Propyl-tetrahydroindenyl	Diphenylmethylene stannyl	Ethyl tetrahydro-indenyl
	Propyl-tetrahydroindenyl		Butyl tetrahydroindenyl
	Phenyl-tetrahydroindenyl		Butyl tetrahydroindenyl
	Phenyl-tetrahydroindenyl		Fluorenyl
	Methyl fluorenyl		Fluorenyl
	Methyl fluorenyl		Dimethyl fluorenyl
	Trimethyl-fluorenyl		Dimethyl fluorenyl
	Trimethyl-fluorenyl		Ethyl fluorenyl
	Propyl fluorenyl		Ethyl fluorenyl
	Propyl fluorenyl		Butylfluorenyl
	Dibutyl-fluorenyl		Butylfluorenyl

	Pentyl fluorenyl
	Pentyl fluorenyl		Hexyl fluorenyl
	Heptyl fluorenyl		Hexyl fluorenyl
	Heptyl fluorenyl		Octyl fluorenyl
	Nonyl fluorenyl		Octyl fluorenyl
	Nonyl fluorenyl		Decyl fluorenyl
	Phenylfluorenyl		Decyl fluorenyl
	Phenylfluorenyl		Naphthyl fluorenyl
	Benzyl-fluorenyl		Naphthyl fluorenyl
	Benzyl-fluorenyl		Fluorenyl-methylphenyl
	Fluorenyl ethylphenyl		Fluorenyl-methylphenyl
	Fluorenyl ethylphenyl		Propyl phenylfluorenyl
	Naphthyl methyl fluorenyl		Propyl phenylfluorenyl
	Naphthyl methyl fluorenyl		Naphthyl ethyl fluorenyl
	Naphthyl propyl fluorenyl		Naphthyl ethyl fluorenyl
	Naphthyl propyl fluorenyl		Octahydrofluorenyl
	Tetrahydrofluorenyl		Octahydrofluorenyl
	Tetrahydrofluorenyl		Octamethyloctahydrodibenzo dibenzo [b, h] fluorenyl
	Tetramethyl-benzo [b] fluorenyl		Octamethyloctahydrodibenzo dibenzo [b, h] fluorenyl
	Tetramethyl-benzo [b] fluorenyl		Diphenylmethyl-cyclopentadienyl
	Trimethylsilyl cyclopentadienyl		Diphenylmethyl-cyclopentadienyl
	Trimethylsilyl cyclopentadienyl		Triethylsilyl cyclopentadienyl
	Trimethyl cyclopentadienyl germyl		Triethylsilyl cyclopentadienyl
	Trimethyl cyclopentadienyl germyl		Trimethylstannyl cyclopentadienyl group
	Triethylsilyl lead cyclopentadienyl group		Trimethylstannyl cyclopentadienyl group
	Triethylsilyl lead cyclopentadienyl group		Trifluoromethyl-cyclopentadienyl
	N, N-dimethylamino-cyclopentadienyl		Trifluoromethyl-cyclopentadienyl
	N, N-dimethylamino-cyclopentadienyl		P, P-dimethyl P cyclopentadienyl
	N, N-diethylamino-cyclopentadienyl		P, P-dimethyl P cyclopentadienyl
	N, N-diethylamino-cyclopentadienyl		Methoxy cyclopentadienyl
	Ethoxy-cyclopentadienyl		Methoxy cyclopentadienyl

	Trimethyl siloxane cyclopentadienyl
	Trimethyl siloxane cyclopentadienyl		(N, N-dimethylaminomethyl) cyclopentadiene Base
	Methoxy indenyl		(N, N-dimethylaminomethyl) cyclopentadiene Base
	Methoxy indenyl		Dimethoxy-indenyl
	N, N-dimethylamino-indenyl		Dimethoxy-indenyl
	N, N-dimethylamino-indenyl		Trimethyl siloxane indenyl
	Butyl-dimethyl siloxane indenyl		Trimethyl siloxane indenyl
	Butyl-dimethyl siloxane indenyl		Bis (N, N-dimethylamino)-indenyl
	Bis (trimethyl siloxane) indenyl		Bis (N, N-dimethylamino)-indenyl
	Bis (trimethyl siloxane) indenyl		Bis (butyl-dimethyl siloxane) indenyl
	Fluorenyl methoxy		Bis (butyl-dimethyl siloxane) indenyl
	Fluorenyl methoxy		Dimethoxy fluorenyl
	N, N-dimethylamino fluorenyl		Dimethoxy fluorenyl
	N, N-dimethylamino fluorenyl		Trimethyl siloxane fluorenyl
	Butyl-dimethyl siloxane fluorenyl		Trimethyl siloxane fluorenyl
	Butyl-dimethyl siloxane fluorenyl		Dimethoxy fluorenyl
	Dimethoxy fluorenyl...		Dimethoxy fluorenyl
	Dimethoxy fluorenyl...		Dimethoxy fluorenyl...
	Bis (butyl-dimethyl siloxane) fluorenyl		Dimethoxy fluorenyl...

Table A (Continued)

(JS′ _z-l-y)(y＝1)	X ₁Or X₂	M
(JS′ _z-l-y)(y＝1)	X ₁Or X₂	M	Methylamino	Chloride	Titanium
Ethylamino	Bromide	Zirconium	Methylamino	Chloride	Titanium
Ethylamino	Bromide	Zirconium	Propylamino	Iodide	Hafnium
Butylamino	Fluoride		Propylamino	Iodide	Hafnium
Butylamino	Fluoride		Pentyl group	Hydride	L or L '(non-essential Want)
Hexyl group	Methyl	Ethylene	Pentyl group	Hydride	L or L '(non-essential Want)
Hexyl group	Methyl	Ethylene	Heptyl group	Ethyl	Propylene
Octylamino	Propyl	Butene	Heptyl group	Ethyl	Propylene
Octylamino	Propyl	Butene	Nonylamino	Butyl	Hexene
Decyl group	Pentyl	Styrene	Nonylamino	Butyl	Hexene
Decyl group	Pentyl	Styrene	Eicosyl group	Hexyl	Hexadiene
Henicosyl amino	Heptyl	Butadiene	Eicosyl group	Hexyl	Hexadiene
Henicosyl amino	Heptyl	Butadiene	Twenty-two alkylamino	Helsinki	Dimethyl butadiene
Tricosyl amino	Nonyl	Pentadiene	Twenty-two alkylamino	Helsinki	Dimethyl butadiene
Tricosyl amino	Nonyl	Pentadiene	Tetracosyl group group	Decyl	Methyl-hexadiene
Twenty-five alkylamino	Undecyl	Dimethyl hexadiene	Tetracosyl group group	Decyl	Methyl-hexadiene
Twenty-five alkylamino	Undecyl	Dimethyl hexadiene	Twenty-six alkylamino	Dodecyl	Acetylene
Twenty-seven alkylamino	Tridecyl	Methylacetylene	Twenty-six alkylamino	Dodecyl	Acetylene
Twenty-seven alkylamino	Tridecyl	Methylacetylene	Twenty-eight alkylamino	Tetradecyl	Ethyl acetylene
Twenty-nine alkylamino	Pentadecyl	Benzyne	Twenty-eight alkylamino	Tetradecyl	Ethyl acetylene
Twenty-nine alkylamino	Pentadecyl	Benzyne	Triacontyl group	Hexadecyl	Cyclopentene
Phenylamino	Heptadecyl	Cyclohexene	Triacontyl group	Hexadecyl	Cyclopentene
Phenylamino	Heptadecyl	Cyclohexene	Tolylamino	Octadecyl
Phenethylamino	Nonadecyl	L '(non-essential)	Tolylamino	Octadecyl
Phenethylamino	Nonadecyl	L '(non-essential)	Benzylamino	Eicosyl	Diethyl ether
Cyclobutylamino	Henicosyl	Dimethyl ether	Benzylamino	Eicosyl	Diethyl ether

Cyclopentylamino	Docosanyl	Trimethylamine
Cyclopentylamino	Docosanyl	Trimethylamine	Cyclohexylamino	Tricosyl	Triphenylamine
Cycloheptylamino	Twenty-four alkyl	Triethylamine	Cyclohexylamino	Tricosyl	Triphenylamine
Cycloheptylamino	Twenty-four alkyl	Triethylamine	Cyclooctyl group	Twenty-five alkyl	Tricyclohexylphosphine
Ring nonylamino	Twenty-six alkyl	Triphenylphosphine	Cyclooctyl group	Twenty-five alkyl	Tricyclohexylphosphine
Ring nonylamino	Twenty-six alkyl	Triphenylphosphine	Cyclodecyl group	Twenty-seven alkyl	Trimethylphosphine
Ring dodecylamino	Twenty-eight alkyl	Tetrahydrofuran	Cyclodecyl group	Twenty-seven alkyl	Trimethylphosphine
Ring dodecylamino	Twenty-eight alkyl	Tetrahydrofuran	Adamantyl (adamantyl) amino	Twenty-nine alkyl	Furan
Norbornyl (norbornyl) amino-	Triacontyl	Thiophene	Adamantyl (adamantyl) amino	Twenty-nine alkyl	Furan
Norbornyl (norbornyl) amino-	Triacontyl	Thiophene	Perfluorophenyl group	Phenyl	Dimethylsulfide
Fluorophenylamino	Benzyl	Diphenyl sulfide	Perfluorophenyl group	Phenyl	Dimethylsulfide
Fluorophenylamino	Benzyl	Diphenyl sulfide	Difluorophenylamino	Phenethyl
Oxy	Tolyl		Difluorophenylamino	Phenethyl
Oxy	Tolyl		Thio (sulfido)	Methoxy-
	Ethoxy		Thio (sulfido)	Methoxy-
	Ethoxy		(JS′ _z-l-y)(y＝0)	Propoxy
Methoxy-	Butoxy		(JS′ _z-l-y)(y＝0)	Propoxy
Methoxy-	Butoxy		Ethoxy	Dimethylamino
Phenoxy	Diethylamino		Ethoxy	Dimethylamino
Phenoxy	Diethylamino		Dimethylphenoxy	Methyl-ethylamino
Dipropylphenoxy	Phenoxy		Dimethylphenoxy	Methyl-ethylamino
Dipropylphenoxy	Phenoxy		Methylthio	Benzyloxy
Ethylthio	Allyl		Methylthio	Benzyloxy
Ethylthio	Allyl		Phenylthio
Dimethylphenylthio			Phenylthio
Dimethylphenylthio			Dipropylphenoxy group	X1 and X2 together
	Methine		Dipropylphenoxy group	X1 and X2 together
	Methine			Ethylidenebis
	C-ylidene			Ethylidenebis

	Tetramethylene
	Tetramethylene			Pentamethylene
	Hexamethylene			Pentamethylene
	Hexamethylene			Dihydroxy ethylene
	Butadiene			Dihydroxy ethylene
	Butadiene			-Butadiene
	Dimethyl butadiene			-Butadiene
	Dimethyl butadiene			Pentadiene
	Methylpentadiene			Pentadiene
	Methylpentadiene			Dimethylpentadienyl
	Hexadiene			Dimethylpentadienyl
	Hexadiene			Methyl-hexadiene
	Dimethyl hexadiene			Methyl-hexadiene
	Dimethyl hexadiene

Further preferred catalysts include those described in WO01/48034, which document is incorporated herein Into as a reference. A particularly preferred catalyst compound included in Section 9, line 38 to 25 42 Line 5 to page 28, line 17, page 30, line 37 to page 35 line 28 open Those.

Catalyst activator compounds and activation of

The above described polymerization procatalyst compound is generally activated in different ways, whereby Having a ligand, and the polymerization of olefins into the air with a compound bit. In this patent specification and The appended claims, the term "cocatalyst" and "activator" are used interchangeably here, can be Is defined as the catalyst can be prepared by converting the compound neutral catalytically active catalyst compound cation Catalyst compound to activate any one of these compounds. Non-limiting activators include aluminoxanes , Alkyl aluminum ionizing activator (which may be neutral or ionic), and conventional-type cocatalyst Agent. The preferred activator compounds generally include alumoxane, modified alumoxane compound, to capture a A reactive metal σ-bonded ligand leaving cationic metal complexes and to provide charge balance Non-coordinating or weakly coordinating anions anionic precursor compound. ...

In one embodiment, the activator alumoxane catalyst composition of the present invention is used As an activator. Alumoxane is generally containing-Al (R¹)-O-subunit oligomeric compounds wherein R¹To Group. Examples of the aluminoxane include methylaluminoxane (MAO), modified methylaluminoxane (MMAO), Ethyl aluminoxane and isobutyl aluminoxane. Alkyl alkyl alumoxane and modified alumoxanes suitable as catalyst Agent activators, particularly when the ligand is a halide can be captured, alkoxide or amide. Also available Using different alumoxane and modified alumoxanes mixtures.

Activators include Lewis acids, especially the aluminoxane activator compound is represented by the following general formula in Table Show:

(R ³-Al-O) _p (11)

R ⁴(R ⁵-Al-O) _p-AlR ⁶ ₂ (12)

(M′) ^m+Q′ _m (13)

Alumoxane is generally a mixture of linear and cyclic compounds. In alumoxane formula, R³、 R ⁴、R ⁵And R⁶Independently C₁-C ₃₀Alkyl such as methyl, ethyl, propyl, butyl, pentyl, Hexyl, heptyl, octyl, nonyl, decyl, and "p" is an integer from 1 to about 50. R³、R ⁴、 R ⁵And R⁶And most preferably each methyl, "p" is at least 4. When an alkyl aluminum halide or alkoxide For preparing alumoxane, one or more R^3-6Groups may be halide or alkoxide. M 'is Metal or metalloid, Q 'is partially or fully fluorinated hydrocarbon.

Has recognized Aluminoxanes not abstract substances. A typical alumoxane will contain free Trisubstituted or trialkyl aluminum, tri-substituted or bonded aluminum trialkyl, and the low degree of variation in the aluminum Siloxane molecules. The most preferred methylaluminoxane containing low levels of trimethylaluminum. Low levels of Trimethyl aluminum trimethyl aluminum by the reaction with a Lewis base, or by vacuum distillation or trimethylaluminum Known in the art through any other manner. Also recognize that the transition metal compound anti- Should, some aluminoxane molecule is anionic form, as shown by the equation expressed in the anionic 4-6, Therefore, object of the present invention, are considered "noncoordinating" anion. ...

When the activator is an alumoxane (modified or unmodified), some embodiments select the corresponding The catalyst precursor (per metal catalytic site) 5000-fold molar excess Al / M of the large number of live Agent. Minimum activator and catalyst precursor ratio is 1:1 molar ratio.

Alumoxane by hydrolysis of the corresponding trialkyl aluminum compound production. MMAO by hydrolysis three Methyl and higher trialkyl aluminum such as tri-isobutyl aluminum aluminum production. MMAO generally more soluble in aliphatic solvent Agents and more stable during storage. There are various preparing alumoxane and modified alumoxanes square Method, the non-limiting examples are described in US4, 665,208,4,952,540,5,091,352, 5,206,199,5,204,419,4,874,734,4,924,018,4,908,463,4,968,827, 5,308,815,5,329,032,5,248,801,5,235,081,5,157,137,5,103,031, 5,391,793,5,391,529,5,693,838,5,731,253,5,731,451,5,744,656, 5,847,177,5,854,166,5,856,256 and 5,939,346 and EP-A-0 561 476, EP-B1-0 279 586, EP-A-0 594-218 and EP-B1-0 586 665, and WO 94/10180 And WO 99/15534, all of the documents incorporated by reference herein. Can be used preferably visible Clear methylaluminoxane. May be cloudy or gelled alumoxane filter producing a clear solution, or Turbid solution was decanted from the clear aluminoxane. Another alumoxane is a modified methylaluminoxane (MMAO) Cocatalyst type 3A (commercially available from Akzo Chemicals, Inc., Modified methylaluminoxane tradename Alkyl 3A type, covered by patent US 5,041,584). ...

Ionizing activator

Within the scope of the present invention can be used for ionizing or stoichiometric activator (neutral or ionic), Such as tri (n-butyl) ammonium tetrakis (pentafluorophenyl) boron, tris perfluorophenyl boron metalloid precursor or tri perfluorodecalin Yl boron metalloid precursor, polyhalogenated borane complex anions (WO 98/43983), boric acid (US5, 942, 459) or a combination thereof. Within the scope of the present invention, a neutral or ionic compounds can be used alone or with aluminum Alumoxane or modified alumoxane activators used in combination.

Neutral stoichiometric activators include tri-substituted boron, tellurium, aluminum, gallium and indium, or Mixtures. Three substituents each independently selected from alkyl, alkenyl, halo, substituted alkyl, An aryl group, an aryl halide, alkoxy and halides. The three substituents are preferably independently selected from halo Su, a monocyclic or polycyclic (including halo-substituted) aryl, alkyl and alkenyl compounds and mixtures thereof, Preferably having 1 to 20 carbon atoms, an alkenyl group having 1 to 20 carbon atoms, with Having 1 to 20 carbon atoms, an alkoxy group and having 3 to 20 carbon atoms, an aryl group (including substituted An aryl group), and more preferably in the three groups having 1 to 4 carbon atoms, a phenyl group, a naphthyl group Or mixtures thereof. Three groups and even more preferably a halogenated, preferably fluorinated aryl group. Neutral Most preferably stoichiometric activator three full boron or tri-fluorophenyl group perfluorodecalin boron. ...

Ions by transition metal compound catalyst with some neutral Lewis acids such as B (C₆F ₆) ₃Reaction of the Lewis acid with the transition metal compound of the hydrolyzable ligand (X) reaction, Forming anions such as ([B (C₆F ₅) ₃(X)] ^-), Which stabilize the reaction of the transition metal cation Substances. The catalyst can be used and preferably it is a compound or composition of the ionic activator component system Equipment. However, the present invention also contemplates preparation of compounds with neutral activator.

In the preparation method of the present invention, the catalyst system used as the ionic activator component Compounds include cation and a compatible noncoordinating anion, the cation is preferably able to give Bronsted proton acid, said anion is relatively large (large), and stable in these two Compound with active catalyst material formed when (Group 4 cation), and said anion Sufficiently stable and can be olefinic, diolefinic and acetylenically unsaturated substrates or other Lewis bases such as ethers, Nitriles such replacement. Two compatible noncoordinating anion is disclosed in EPA 277,003 of EPA 277,004 (1988 Public): 1) comprises the center of charged metal or metalloid core covalently Ligand and a plurality of shielding said nuclei lipophilic group anionic coordination complexes, and 2) comprises a plurality of Boron atoms such as carboranes, carboranes and metallic borane anion. ...

(L-H) ⁺ _d(A ^d-) (14)

Wherein L is a neutral Lewis base;

H is hydrogen;

(L-H) ⁺As Bronsted acid

A ^d-Having a charge d-noncoordinating anion;

d is an integer of 1 to 3.

Cationic component (L-H)⁺ _dMay include Bronsted acids such as protons or protonated Lewis bases Or reducible Lewis acids capable of protonated or taken from a large ligand metallocene-containing transition Metal catalyst precursor moiety, such as an alkyl or aryl group, to form a cationic transition metal species.

Activating cation (L-H)⁺ _dFor Bronsted acid capable of giving a proton transition metal The catalyst precursor, thereby obtaining the transition metal cations, including ammonium, oxonium, phosphonium, silyl Yl bromide (silylium) and mixtures thereof, preferably methylamine, aniline, dimethylamine, diethylamine, N- Methyl aniline, diphenylamine, trimethylamine, triethylamine, N, N-dimethylaniline, diphenyl methyl Amine, pyridine, p-bromo-N, N-dimethylaniline, p-nitro-N, N-dimethylaniline ammonium, from Triethyl phosphine, triphenyl phosphine and phosphonium diphenyl phosphine, and from ethers such as dimethyl ether, diethyl ether, Tetrahydrofuran and dioxane oxonium, from sulfides such as diethyl sulfide and tetrahydrothiophene sulfonium, and Mixtures. Activating cation (L-H) ...⁺ _dFor Bronsted acid capable of giving a proton transition metal The catalyst precursor, thereby obtaining the transition metal cations, including ammonium, oxonium, phosphonium, silyl Yl bromide (silylium) and mixtures thereof, preferably methylamine, aniline, dimethylamine, diethylamine, N- Methyl aniline, diphenylamine, trimethylamine, triethylamine, N, N-dimethylaniline, diphenyl methyl Amine, pyridine, p-bromo-N, N-dimethylaniline, p-nitro-N, N-dimethylaniline ammonium, from Triethyl phosphine, triphenyl phosphine and phosphonium diphenyl phosphine, and from ethers such as dimethyl ether, diethyl ether, Tetrahydrofuran and dioxane oxonium, from sulfides such as diethyl sulfide and tetrahydrothiophene sulfonium, and Mixtures. Activating cation (L-H) ...⁺ _dMost preferably triphenyl carbenium Ium.

Anion component A^d-Including having the general formula [M^k+Q _n] ^d-Those, wherein k is an integer from 1 to 3 Number; n is an integer from 2 to 6; nk = d; M is selected from the periodic table group 13 element, preferably Select boron or aluminum, Q is independently a hydride, bridged or unbridged dialkylamino, halide, alkyl Oxides, aryloxide, hydrocarbyl, substituted hydrocarbyl, a halogenated hydrocarbon group, a halogenated hydrocarbon group, and a halogen substituted take Hydrocarbon group, said Q having up to 20 carbon atoms, provided that there is more than 1 times as Q Halides. Each Q is preferably having 1 to 20 carbon atoms, a fluorinated hydrocarbon group, more preferably each Q is Fluorinated aryl group, most preferably each Q pentafluoro-aryl. A suitable^d-Examples include for example, US 5,447,895 diboron compounds disclosed in the documents incorporated by reference herein in its entirety.

In the preparation of the catalyst of the present invention improves the activating cocatalyst as boron compound Illustrative, but non-limiting examples of tri-substituted ammonium salts such as: trimethylammonium tetraphenylborate, tetraphenyl Borate, triethylammonium tetraphenylborate, tripropylammonium tetraphenyl borate, tri (n-butyl) ammonium tetraphenyl Boronic acid tri (t-butyl) ammonium tetraphenylborate, N, N-dimethyl aniline iodide, tetraphenyl borate, N, N- Diethylaniline iodide, tetraphenylborate, N, N-dimethyl - (2,4,6 - trimethyl aniline iodide), four _ Onium phenylboronic acid (tropillium), tetraphenylborate, triphenyl carbenium tetraphenyl borate, tri Tetraphenylphosphonium tetraphenyl borate, triethyl silyl iodide, tetraphenylborate, benzene (diazonium salt), 4 (5 Fluorophenyl) borate, trimethyl ammonium tetrakis (pentafluorophenyl) borate, triethylammonium tetrakis (pentafluorophenyl) boron Acid tripropylammonium tetrakis (pentafluorophenyl) borate, tri (n-butyl) ammonium tetrakis (pentafluorophenyl) borate, tri (sec- Butyl) ammonium tetrakis (pentafluorophenyl) borate, N, N-dimethyl aniline bromide, tetrakis (pentafluorophenyl) borate, N, N- Diethylaniline bromide, tetrakis (pentafluorophenyl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline) chloride, Four (pentafluorophenyl) borate _ onium, four (pentafluorophenyl) borate triphenylcarbonium, four (pentafluorophenyl) Borate, triphenylphosphonium tetrakis (pentafluorophenyl) borate, triethyl silyl bromide, tetrakis (pentafluorophenyl) boron Acid, benzene (diazonium salt), IV - (2,3,4,6 - tetrafluoro-phenyl) borate, trimethyl ammonium tetrakis - (2,3,4, 6 - tetrafluoro-phenyl) borate, triethylammonium tetrakis - (2,3,4,6 - tetrafluoro-phenyl) borate, tripropylammonium IV - (2,3,4,6 - tetrafluoro-phenyl) borate, tri (n-butyl) ammonium tetrakis - (2,3,4,6 - tetrafluoro-phenyl) Acid dimethyl (t-butyl) ammonium tetrakis - (2,3,4,6 - tetrafluoro-phenyl) borate, N, N-dimethyl benzene Amine onium, four - (2,3,4,6 - tetrafluoro-phenyl) borate, N, N-diethylaniline bromide, IV - (2,3,4, 6 - tetrafluoro-phenyl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline iodide), tetrakis - (2,3,4,6 - Tetrafluoro-phenyl) borate _ bromide, IV - (2,3,4,6 - tetrafluoro-phenyl) borate, triphenyl carbenium, IV - (2, 3,4,6 - tetrafluoro-phenyl) borate, triphenylphosphonium, IV - (2,3,4,6 - tetrafluoro-phenyl) borate, triethyl Silyl bromide, IV - (2,3,4,6 - tetrafluoro-phenyl) borate, benzene (diazonium salt), tetrakis (perfluoro-naphthyl Yl) borate, trimethyl ammonium tetrakis (perfluoro-naphthyl) borate, triethylammonium tetrakis (perfluoro-naphthyl) borate Propyl ammonium tetrakis (perfluoro-naphthyl) borate, tri (n-butyl) ammonium tetrakis (perfluoro-naphthyl) borate, tri (tert-butyl Yl) ammonium tetrakis (perfluoro-naphthyl) borate, N, N-dimethyl aniline iodide, tetrakis (perfluoro-naphthyl) borate, N, N- Diethylaniline iodide, tetrakis (perfluoro-naphthyl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline) chloride, Tetrakis (perfluoro-naphthyl) _ onium borate, tetrakis (perfluoro-naphthyl) borate, triphenyl carbenium tetrakis (perfluoro-naphthyl) Borate, triphenylphosphonium tetrakis (perfluoro-naphthyl) borate, triethyl silyl bromide, tetrakis (perfluoro-naphthyl) borate Acid, benzene (diazonium salt), tetrakis (perfluoro-biphenyl) borate, trimethyl ammonium tetrakis (perfluoro-biphenyl) borate, Ethyl ammonium tetrakis (perfluoro-biphenyl) borate, tripropylammonium tetrakis (perfluoro-biphenyl) borate, tri (n-butyl Yl) ammonium tetrakis (perfluoro-biphenyl) borate, tri (tert-butyl) ammonium tetrakis (perfluoro-biphenyl) borate, N, N- Dimethylaniline iodide, tetrakis (perfluoro-biphenyl) borate, N, N-diethylaniline iodide, tetrakis (perfluoro-biphenyl Yl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline) chloride, tetrakis (perfluoro-biphenyl) borate, _ Onium tetrakis (perfluoro-biphenyl) borate, triphenyl carbenium tetrakis (perfluoro-biphenyl) borate, triphenyl phosphonium, Tetrakis (perfluoro-biphenyl) borate, triethyl silyl bromide, tetrakis (perfluoro-biphenyl) borate, benzene (diazonium Salt), tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, trimethyl ammonium tetrakis (3,5 - bis (trifluoromethyl Yl) phenyl) borate, triethylammonium tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, tripropylammonium Tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, tri (n-butyl) ammonium tetrakis (3,5 - bis (trifluoromethyl) Phenyl) borate, tri (tert-butyl) ammonium tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, N, N-dimethyl Aniline bromide, tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, N, N-diethylaniline bromide, four (3,5 - bis (trifluoromethyl) phenyl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline) chloride, Tetrakis (3,5 - bis (trifluoromethyl) phenyl) _ onium borate, tetrakis (3,5 - bis (trifluoromethyl) phenyl) Triphenylcarbenium borate, tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, triphenylphosphonium tetrakis (3,5 - Bis (trifluoromethyl) phenyl) borate, triethyl silyl bromide, tetrakis (3,5 - bis (trifluoromethyl) benzene Yl) borate, benzene (diazonium salt), and dialkyl ammonium salts such as tetra (pentafluorophenyl) borate, ammonium, and diisopropyl Tetrakis (pentafluorophenyl) borate, dicyclohexyl ammonium, and another tri-substituted phosphonium salts such as tetra (pentafluorophenyl) Borate, tri (o-tolyl) phosphonium tetrakis (pentafluorophenyl) borate, tri (2,6 - dimethylphenyl) phosphonium. ...

In the preparation of the catalyst of the present invention improves the activating cocatalyst as boron compound Illustrative, but non-limiting examples of tri-substituted ammonium salts such as: trimethylammonium tetraphenylborate, tetraphenyl Borate, triethylammonium tetraphenylborate, tripropylammonium tetraphenyl borate, tri (n-butyl) ammonium tetraphenyl Boronic acid tri (t-butyl) ammonium tetraphenylborate, N, N-dimethyl aniline iodide, tetraphenyl borate, N, N- Diethylaniline iodide, tetraphenylborate, N, N-dimethyl - (2,4,6 - trimethyl aniline iodide), four _ Onium phenylboronic acid (tropillium), tetraphenylborate, triphenyl carbenium tetraphenyl borate, tri Tetraphenylphosphonium tetraphenyl borate, triethyl silyl iodide, tetraphenylborate, benzene (diazonium salt), 4 (5 Fluorophenyl) borate, trimethyl ammonium tetrakis (pentafluorophenyl) borate, triethylammonium tetrakis (pentafluorophenyl) boron Acid tripropylammonium tetrakis (pentafluorophenyl) borate, tri (n-butyl) ammonium tetrakis (pentafluorophenyl) borate, tri (sec- Butyl) ammonium tetrakis (pentafluorophenyl) borate, N, N-dimethyl aniline bromide, tetrakis (pentafluorophenyl) borate, N, N- Diethylaniline bromide, tetrakis (pentafluorophenyl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline) chloride, Four (pentafluorophenyl) borate _ onium, four (pentafluorophenyl) borate triphenylcarbonium, four (pentafluorophenyl) Borate, triphenylphosphonium tetrakis (pentafluorophenyl) borate, triethyl silyl bromide, tetrakis (pentafluorophenyl) boron Acid, benzene (diazonium salt), IV - (2,3,4,6 - tetrafluoro-phenyl) borate, trimethyl ammonium tetrakis - (2,3,4, 6 - tetrafluoro-phenyl) borate, triethylammonium tetrakis - (2,3,4,6 - tetrafluoro-phenyl) borate, tripropylammonium IV - (2,3,4,6 - tetrafluoro-phenyl) borate, tri (n-butyl) ammonium tetrakis - (2,3,4,6 - tetrafluoro-phenyl) Acid dimethyl (t-butyl) ammonium tetrakis - (2,3,4,6 - tetrafluoro-phenyl) borate, N, N-dimethyl benzene Amine onium, four - (2,3,4,6 - tetrafluoro-phenyl) borate, N, N-diethylaniline bromide, IV - (2,3,4, 6 - tetrafluoro-phenyl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline iodide), tetrakis - (2,3,4,6 - Tetrafluoro-phenyl) borate _ bromide, IV - (2,3,4,6 - tetrafluoro-phenyl) borate, triphenyl carbenium, IV - (2, 3,4,6 - tetrafluoro-phenyl) borate, triphenylphosphonium, IV - (2,3,4,6 - tetrafluoro-phenyl) borate, triethyl Silyl bromide, IV - (2,3,4,6 - tetrafluoro-phenyl) borate, benzene (diazonium salt), tetrakis (perfluoro-naphthyl Yl) borate, trimethyl ammonium tetrakis (perfluoro-naphthyl) borate, triethylammonium tetrakis (perfluoro-naphthyl) borate Propyl ammonium tetrakis (perfluoro-naphthyl) borate, tri (n-butyl) ammonium tetrakis (perfluoro-naphthyl) borate, tri (tert-butyl Yl) ammonium tetrakis (perfluoro-naphthyl) borate, N, N-dimethyl aniline iodide, tetrakis (perfluoro-naphthyl) borate, N, N- Diethylaniline iodide, tetrakis (perfluoro-naphthyl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline) chloride, Tetrakis (perfluoro-naphthyl) _ onium borate, tetrakis (perfluoro-naphthyl) borate, triphenyl carbenium tetrakis (perfluoro-naphthyl) Borate, triphenylphosphonium tetrakis (perfluoro-naphthyl) borate, triethyl silyl bromide, tetrakis (perfluoro-naphthyl) borate Acid, benzene (diazonium salt), tetrakis (perfluoro-biphenyl) borate, trimethyl ammonium tetrakis (perfluoro-biphenyl) borate, Ethyl ammonium tetrakis (perfluoro-biphenyl) borate, tripropylammonium tetrakis (perfluoro-biphenyl) borate, tri (n-butyl Yl) ammonium tetrakis (perfluoro-biphenyl) borate, tri (tert-butyl) ammonium tetrakis (perfluoro-biphenyl) borate, N, N- Dimethylaniline iodide, tetrakis (perfluoro-biphenyl) borate, N, N-diethylaniline iodide, tetrakis (perfluoro-biphenyl Yl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline) chloride, tetrakis (perfluoro-biphenyl) borate, _ Onium tetrakis (perfluoro-biphenyl) borate, triphenyl carbenium tetrakis (perfluoro-biphenyl) borate, triphenyl phosphonium, Tetrakis (perfluoro-biphenyl) borate, triethyl silyl bromide, tetrakis (perfluoro-biphenyl) borate, benzene (diazonium Salt), tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, trimethyl ammonium tetrakis (3,5 - bis (trifluoromethyl Yl) phenyl) borate, triethylammonium tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, tripropylammonium Tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, tri (n-butyl) ammonium tetrakis (3,5 - bis (trifluoromethyl) Phenyl) borate, tri (tert-butyl) ammonium tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, N, N-dimethyl Aniline bromide, tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, N, N-diethylaniline bromide, four (3,5 - bis (trifluoromethyl) phenyl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline) chloride, Tetrakis (3,5 - bis (trifluoromethyl) phenyl) _ onium borate, tetrakis (3,5 - bis (trifluoromethyl) phenyl) Triphenylcarbenium borate, tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, triphenylphosphonium tetrakis (3,5 - Bis (trifluoromethyl) phenyl) borate, triethyl silyl bromide, tetrakis (3,5 - bis (trifluoromethyl) benzene Yl) borate, benzene (diazonium salt), and dialkyl ammonium salts such as tetra (pentafluorophenyl) borate, ammonium, and diisopropyl Tetrakis (pentafluorophenyl) borate, dicyclohexyl ammonium, and another tri-substituted phosphonium salts such as tetra (pentafluorophenyl) Borate, tri (o-tolyl) phosphonium tetrakis (pentafluorophenyl) borate, tri (2,6 - dimethylphenyl) phosphonium. ...⁺ _d(A ^d-) And most preferably tetrakis (perfluorophenyl) borate, N, N- Dimethylaniline iodide, tetrakis (perfluoro-naphthyl) borate, N, N-dimethyl aniline iodide, tetrakis (perfluoro-biphenyl) Borate, N, N-dimethyl aniline iodide, tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, N, N-dimethyl Aniline bromide, tetrakis (perfluoro-naphthyl) borate, triphenyl carbenium tetrakis (perfluoro-biphenyl) borate Carbenium tetrakis (3,5 - bis (trifluoromethyl) phenyl) borate, or triphenylcarbenium tetra (perfluorophenyl) borate, Triphenylcarbenium.

% E5% 9C% A8% E4% B8% 80% E4% B8% AA% E5% AE% 9E% E6% 96% BD% E6% 96% B9% E6% A1% 88% E4% B8% AD% EF % BC% 8C% E4% BD% BF% E7% 94% A8% E4% B8% 8D% E5% 90% AB% E6% B4% BB% E6% 80% A7% E8% B4% A8% E5% AD % 90% E4% BD% 86% E8% 83% BD% E5% A4% 9F% E4% BA% A7% E7% 94% 9F% E5% BA% 9E% E5% A4% A7% E9% 85% 8D % E4% BD% 93% E8% 8C% 82% E9% 87% 91% E5% B1% 9E% 0A% 20% 20% 20% 20% 20% 20% 20% 20% 20% 20% 20% 20 % E5% 82% AC% E5% 8C% 96% E5% 89% 82% E9% 98% B3% E7% A6% BB% E5% AD% 90% E5% 92% 8C% E5% 85% B6% E9 % 9D% 9E% E9% 85% 8D% E4% BD% 8D% E9% 98% B4% E7% A6% BB% E5% AD% 90% E7% 9A% 84% E7% A6% BB% E5% AD % 90% E5% 8C% 96% E7% A6% BB% E5% AD% 90% E5% 8C% 96% E5% 90% 88% E7% 89% A9% E7% 9A% 84% E6% B4% BB % E5% 8C% 96% E6% 96% B9% E6% B3% 95% E4% B9% 9F% E6% 98% AF% 0A% 20% 20% 20% 20% 20% 20% 20% 20% 20 % 20% 20% 20% E8% 80% 83% E8% 99% 91% E7% 9A% 84% EF% BC% 8C% E5% B9% B6% E6% 8F% 8F% E8% BF% B0% E4 % BA% 8EEP-A-0% C2% A0426% C2% A0637% E3% 80% 81EP-A-0% C2% A0573% C2% A0403% E5% 92% 8CUS5% 2C387% 2C568% 0A% 20% 20 % 20% 20% 20% 20% 20% 20% 20% 20% 20% 20% 0A% 09% 09% 09% 09% E4% B8% AD% EF% BC% 8C% E8% BF% 99% E4 % BA% 9B% E6% 96% 87% E7% 8C% AE% E8% BF% 99% E9% 87% 8C% E5% 85% A8% E9% 83% A8% E5% BC% 95% E5% 85 % A5% E4% BD% 9C% E4% B8% BA% E5% 8F% 82% E8% 80% 83% E3% 80% 82

The term "noncoordinating anion" (NCA) is not associated with the cationic ligand or only the male Ions weakly coordinating neutral Lewis base so easily replaced to maintain adequate instability anion. "Compatibility" noncoordinating anions are the initial decomposition of the complex formed is not degraded to neutrality Those. In addition, the anion will not transfer an anionic substituent or fragment to the cation and to Form a neutral four coordinate metallocene compound and a neutral by-product from the anion. Be used in the Noncoordinating anions present invention are compatible, stabilize the metallocene cation (for balancing its ionic state +1 In terms of charge), and is maintained during the polymerization is allowed to be sufficient olefinic or acetylenically unsaturated monomers Those instability replacement anion. These types of cocatalysts sometimes use tri-isobutyl aluminum Or tri-octyl aluminum as a scavenger. ...

The invention compounds may also be used cocatalyst or activator compound, they start the A Lewis acid in the reaction with the compound of the present invention is formed when a cationic metal complexes and Non-coordinating anion or zwitterionic complexes. Such as tris (pentafluorophenyl) boron or aluminum hydrocarbon play win Group or a hydride to produce a ligand metal complexes of the present invention, and stability of the cationic non-coordinating anion Into the action, see EP-A-0 427 697 and EP-A-0 520 732 (similar to illustrate Group 4 metallocene compound). Further, referring to EP-A-0 495 375 a method and compounds. In order to use a similar compound to form a Group 4 zwitterionic complexes, see US5, 624,878, 5,486,632 and 5,527,929. ...

Conventional-type cocatalysts (activator)

Typically, chromium does not include conventional-type transition metal catalyst compound of the catalyst of a conventional By the following general formula with a compound of one or more conventional cocatalysts activation:

M ³M ⁴ _vX ² _cR ² _b-c (15)

Wherein M³1 to 3 of the Periodic Table and Group 12 to 13 metal; M⁴Belonging to the Group Group 1 metal; v is a number of 0 to 1; each X²Is any halogen; c is a number from 0 to 3; each R²Is a monovalent hydrocarbon group or hydrogen; b is a number from 1 to 4; and wherein at least 1 bc. Often used in the above Regulation type transition metal catalysts other conventional-type organometallic cocatalyst compounds of the general formula M³R ² _k, Wherein M³The IA, IIA, IIB or IIIA metal, such as lithium, sodium, beryllium, barium, boron, Aluminum, zinc, cadmium, and gallium; k is equal to 1, 2 or 3, depending on the M³Valence, the valence general and Depending on the M³Belongs to the specific group; each R²May be any monovalent hydrocarbon group.

Can be used for the above conventional-type catalyst compound of the conventional type organometallic cocatalyst compounds Non-limiting examples of compounds include methyl lithium, butyl lithium, mercury dihexyl, magnesium butyl, diethyl cadmium, Benzyl potassium, diethyl zinc and n-butyl aluminum, diisobutyl ethyl boron, cadmium diethyl, di-n-butyl And tri-n-pentyl group zinc boron, particularly alkyl aluminum such as tri-hexyl aluminum, triethyl aluminum, trimethyl aluminum and Triisobutylaluminium. Other conventional-type cocatalyst compounds include 2 single metal organic halide And hydride, and 3 and 13 metals single - or di - organic halides and hydrides. These often Regulation type cocatalyst compounds Non-limiting examples include diisobutyl aluminum bromide, isobutyl dichloride Borane, methyl magnesium chloride, beryllium chloride, ethyl bromide, ethyl calcium hydride, diisobutylaluminum hydride, Methyl cadmium, boron hydride, diethylaluminum hydride, hexyl beryllium hydride, dipropyl boron hydride, octyl, magnesium hydroxide, Of butyl zinc, boron hydride, dichloro-, bromo-aluminum hydride and hydrogenated cadmium bromide. Conventional organic gold Cocatalyst compounds are those known in the art, and a more thorough discussion of these compounds In US3, 221,002 and 5,093,415 found in the literature incorporated herein in its entirety Reference. ...

Other activators include those described in WO98/07515, such as (2,2 ', 2 "- Union nonafluorobutyl Phenyl)-fluoro-aluminate, this publication are incorporated by reference herein in its entirety. Combinations activator The present invention contemplates, for example, alumoxane and ionizing activator combination, see for example EP-B1 0 573 120, WO 94/07928 and WO 95/14044 and US5, 153,157 and 5,453,410, All of which are incorporated by reference herein in its entirety.

Other suitable activators are disclosed in WO 98/09996 (incorporated herein by reference), and This document describes the use perchlorates, periodates and iodates (including its hydrates) activation huge Ligand metallocene catalyst compounds. WO 98/30602 and WO98/30603 (incorporated herein by Reference) describes the use of (2,2 '- biphenyl - twenty-three methyl silicate) as Lithium · 4THF huge ligand Metallocene catalyst activator compound. WO 99/18135 (incorporated herein by reference) describes Described the use of organic boron - aluminum activator. EP-B1-0 781 299 describes the use of a silyl salt And a noncoordinating, compatible anion combinations. In addition, considering for example using radiation (see EP-B1-0 615 981, incorporated herein by reference), electrochemical oxidation methods such as the activation of a neutral Large ligand metallocene catalyst compound or precursor to the polymerization of olefins into a large ligand Mao Method for activating metal cations. Activating ligand metallocene catalyst compound huge additional activation Agents and methods are described for example, in US5, 849,852,5,859,653, and 5,869,723 and WO 98/32775, WO 99/42467 (II - octadecyl methyl ammonium - bis (tris (pentafluorophenyl) boron Alkoxy) alkyl benzimidazole (benzimidazolide)) These documents are incorporated herein by reference. ...

(OX ^e+) _d(A ^d-) _e (16)

Wherein OX^e+E + is a cation having a charge oxidant; e is an integer of 1 to 3; and A^-And d are defined above. Examples of cationic oxidizing agents include: ferrocenium, hydrocarbyl-substituted The ferrocenium, Ag⁺Or Pb⁺²。A ^d-The preferred embodiment of the front against the Bronsted acid containing Activators, especially tetrakis (pentafluorophenyl) borate anions as those defined.

Scope of the invention, the catalyst compound can be used with one or more of the activator or activator side France combined. For example, the combination of an activator have been described in US5, 153,157 and 5,453,410, EP-B1 0 573 120 and WO 94/07928 and WO 95/14044 in the. These documents are discussed On the alumoxane and ionizing activator to a large ligand metallocene catalyst compound used together.

Selection of a transition metal catalyst component

The catalyst system of the present invention including the above two or more transition metal compounds. At least A compound must be capable of producing crystalline poly-α-olefins, preferably has a crystallinity of 40% or more Isotactic polypropylene or syndiotactic polypropylene. Other compounds must be able to produce amorphous poly-α- Olefins, preferably has a crystallinity of 20% or less of the random polypropylene.

Crystalline polymer fraction selected for parts of a transition metal component is a transition metal of equations 8-9 A subset of components. Preferred components are described in the following Equation 17

Wherein A ', M, X₁And X₂As previously defined. Substituent S "_vIs independently defined as such Formula 8-9 S ", where the subscript" v "represents the substituent group bonded thereto on the Cp-ring carbon atoms, Child.

For the production of isotactic having improved properties of poly-α olefin metallocene precursor is preferably such Those of formula 17, wherein S "_vIndependently selected metallocene skeleton makes a) without metal center Plane of symmetry;, and 2) having a center through the metal C₂- Axis of symmetry. These complexes such as foreign Rac-Me₂Si (indenyl)₂ZrMe ₂And rac-Me₂Si (indenyl)₂HfMe ₂Is known in the art, Generally lower than the production of high Symmetric Chiral system stereoregularity isotactic polymers. Furthermore, Applicable to the present invention can produce isotactic polymers Another preferred type of transition metal compound Is US5, 026,798 disclosed monocyclopentadienyl catalyst that, where the paper into As a reference.

According to the present invention, dedicated to the production of isotactic poly-α olefin catalyst system excellent player Of racemic metallocene compounds include the following materials racemic variants:

Dimethylsilyl bis (indenyl) zirconium dichloride, dimethyl silyl bis (indenyl) dimethyl Base zirconium diphenyl silyl pairs (indenyl) zirconium dichloride, diphenyl silyl pairs (indenyl) two Zirconium dimethyl, methyl-phenyl silyl bis (indenyl) zirconium dichloride, methyl phenyl silyl bis (indenyl Yl) zirconium dimethyl, ethylenebis (indenyl) zirconium dichloride, ethylene-bis (indenyl) zirconium dimethyl, Methylene bis (indenyl) zirconium dichloride, methylene bis (indenyl) zirconium dimethyl, dimethyl silyl Pair (indenyl) hafnium dichloride, dimethyl silyl pairs (indenyl) hafnium dimethyl, diphenyl silyl Bis (indenyl) hafnium dichloride, diphenyl silyl bis (indenyl) hafnium dimethyl, methyl-phenyl-methyl Silyl bis (indenyl) hafnium dichloride, methyl phenyl silyl bis (indenyl) hafnium dimethyl, ethylene Bis (indenyl) hafnium dichloride, ethylenebis (indenyl) hafnium dimethyl, methylene bis (indenyl) dichloride Hafnium, methylene bis (indenyl) hafnium dimethyl, dimethylsilyl bis (tetrahydroindenyl) dichloride Zirconium dimethyl silyl bis (tetrahydro-indenyl) zirconium dimethyl, diphenyl silyl bis (tetrahydro- Indenyl) zirconium dichloride, diphenyl silyl bis (tetrahydro-indenyl) zirconium dimethyl, methyl-phenyl-methyl Silyl bis (tetrahydro-indenyl) zirconium dichloride, methyl phenyl silyl bis (tetrahydro-indenyl) dimethyl Zirconium, ethylenebis (tetrahydroindenyl) zirconium dichloride, ethylene-bis (tetrahydroindenyl) zirconium dimethyl, Asia Bis (tetrahydro-indenyl) zirconium dichloride, methylene bis (tetrahydroindenyl) zirconium dimethyl, dimethyl Silyl bis (tetrahydro-indenyl) hafnium dichloride, dimethyl silyl bis (tetrahydro-indenyl) dimethyl Hafnium, diphenyl silyl bis (tetrahydro-indenyl) hafnium dichloride, diphenyl silyl bis (tetrahydro- Indenyl) hafnium dimethyl, methyl-phenyl silyl bis (tetrahydro-indenyl) hafnium dichloride, methylphenyl Silyl bis (tetrahydro-indenyl) hafnium dimethyl, ethylene bis (tetrahydro-indenyl) hafnium dichloride, ethylene Bis (tetrahydro-indenyl) hafnium dimethyl, methylene bis (tetrahydro-indenyl) hafnium dichloride, methylene bis (four Hydrogen indenyl) hafnium dimethyl, dimethylsilyl bis (2 - methyl-indenyl) zirconium dichloride, dimethyl Silyl bis (2 - methyl-indenyl) zirconium dimethyl, diphenyl silyl bis (2 - methyl-indenyl) two Zirconium dichloride, diphenyl silyl bis (2 - methyl-indenyl) zirconium dimethyl, methyl-phenyl silyl Bis (2 - methyl-indenyl) zirconium dichloride, methyl phenyl silyl bis (2 - methyl-indenyl) dimethyl Zirconium, ethylenebis (2 - methyl-indenyl) zirconium dichloride, ethylene-bis (2 - methyl-indenyl) zirconium dimethyl, Methylene-bis (2 - methyl-indenyl) zirconium dichloride, methylene bis (2 - methyl-indenyl) zirconium dimethyl, di Dimethylsilyl bis (2 - methyl-indenyl) hafnium dichloride, dimethyl silyl bis (2 - methyl-indene Yl) hafnium dimethyl, diphenyl silyl bis (2 - methyl-indenyl) hafnium dichloride, diphenyl silyl Alkyl bis (2 - methyl-indenyl) hafnium dimethyl, methyl-phenyl silyl bis (2 - methyl-indenyl) dichloride Hafnium, methyl phenyl silyl bis (2 - methyl-indenyl) hafnium dimethyl, ethylenebis (2 - methyl- Indenyl) hafnium dichloride, ethylene bis (2 - methyl-indenyl) hafnium dimethyl, methylene bis (2 - methyl-indene Yl) hafnium dichloride, methylene bis (2 - methyl-indenyl) hafnium dimethyl, rac - dimethylsilyl Bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, diphenyl silyl bis (2 - methyl-4 - benzene Indenyl) zirconium dimethyl, diphenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, Diphenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl, methyl-phenyl silyl Bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, methyl phenyl silyl bis (2 - methyl - 4 - phenyl Indenyl) zirconium dimethyl, ethylenebis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, ethylenebis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl, methylene bis (2 - methyl - 4 - phenyl-indenyl) dichloride Zirconium, methylene bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl, dimethylsilyl bis (2 - methyl -4 - phenyl-indenyl) hafnium dichloride, dimethyl silyl bis (2 - methyl - 4 - phenyl-indenyl) Hafnium dimethyl, diphenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) hafnium dichloride, diphenylmethyl Silyl bis (2 - methyl - 4 - phenyl-indenyl) hafnium dimethyl, methyl-phenyl silyl bis (2 - methyl- -4 - Phenyl-indenyl) hafnium dichloride, methyl phenyl silyl bis (2 - methyl - 4 - phenyl indenyl) two Hafnium dimethyl, ethylenebis (2 - methyl - 4 - phenyl-indenyl) hafnium dichloride, ethylene bis (2 - methyl - 4 - phenyl indenyl) hafnium dimethyl, methylene bis (2 - methyl - 4 - phenyl indenyl) hafnium dichloride, methylene Bis (2 - methyl - 4 - phenyl-indenyl) hafnium dimethyl, dimethylsilyl bis (4,7 - dimethyl-indene Yl) zirconium dichloride, dimethyl silyl bis (4,7 - dimethyl-indenyl) zirconium dimethyl, diphenyl Silyl bis (4,7 - dimethyl-indenyl) zirconium dichloride, diphenyl silyl bis (4,7 - dimethyl Indenyl) zirconium dimethyl, methyl-phenyl silyl bis (4,7 - dimethyl-indenyl) zirconium dichloride, Methyl-phenyl silyl bis (4,7 - dimethyl-indenyl) zirconium dimethyl, ethylenebis (4,7 - dimethoxyphenyl Indenyl) zirconium dichloride, ethylene-bis (4,7 - dimethyl-indenyl) zirconium dimethyl, methylene bis (4,7 - dimethyl-indenyl) zirconium dichloride, methylene bis (4,7 - dimethyl-indenyl) zirconium dimethyl, di Dimethylsilyl bis (4,7 - dimethyl-indenyl) hafnium dichloride, dimethylsilyl bis (4,7 - Dimethyl-indenyl) hafnium dimethyl, diphenyl silyl bis (4,7 - dimethyl-indenyl) hafnium dichloride, Diphenyl silyl bis (4,7 - dimethyl-indenyl) hafnium dimethyl, methyl-phenyl silyl bis (4,7 - dimethyl-indenyl) hafnium dichloride, methyl phenyl silyl bis (4,7 - dimethyl-indenyl) Hafnium dimethyl, ethylene bis (4,7 - dimethyl-indenyl) hafnium dichloride, ethylene bis (4,7 - dimethyl- Indenyl) hafnium dimethyl, methylene bis (4,7 - dimethyl-indenyl) hafnium dichloride, methylene bis (4,7 - Dimethyl-indenyl) hafnium dimethyl, dimethylsilyl bis (2 - methyl -4 - naphthyl indenyl) dichloride Zirconium dimethyl silyl bis (2 - methyl -4 - naphthyl indenyl) zirconium dimethyl, diphenyl silyl Alkyl bis (2 - methyl -4 - naphthyl indenyl) zirconium dichloride, diphenyl silyl bis (2 - methyl -4 - Naphthyl indenyl) zirconium dimethyl, methyl-phenyl silyl bis (2 - methyl -4 - naphthyl indenyl) dichloride Zirconium methyl phenyl silyl bis (2 - methyl -4 - naphthyl indenyl) zirconium dimethyl, ethylenebis (2 - Methyl-4 - naphthyl indenyl) zirconium dichloride, ethylene-bis (2 - methyl -4 - naphthyl indenyl) zirconium dimethyl, Methylene-bis (2 - methyl -4 - naphthyl indenyl) zirconium dichloride, methylene bis (2 - methyl -4 - naphthylindenyl Yl) zirconium dimethyl, dimethylsilyl bis (2 - methyl -4 - naphthyl indenyl) hafnium dichloride, dimethyl Silyl bis (2 - methyl -4 - naphthyl indenyl) hafnium dimethyl, diphenyl silyl bis (2 - methyl -4 - naphthyl indenyl) hafnium dichloride, diphenyl silyl bis (2 - methyl -4 - naphthyl indenyl) Hafnium dimethyl, methyl-phenyl silyl bis (2 - methyl -4 - naphthyl indenyl) hafnium dichloride, methyl benzene Silyl bis (2 - methyl -4 - naphthyl indenyl) hafnium dimethyl, ethylenebis (2 - methyl -4 - naphthalene Indenyl) hafnium dichloride, ethylene bis (2 - methyl -4 - naphthyl indenyl) hafnium dimethyl, methylene bis (2 - methyl -4 - naphthyl indenyl) hafnium dichloride, methylene bis (2 - methyl -4 - naphthyl indenyl) dimethyl Hafnium dimethyl silyl bis (2,3 - dimethyl-cyclopentadienyl) zirconium dichloride, dimethyl silyl Alkyl bis (2,3 - dimethyl-cyclopentadienyl) zirconium dimethyl, diphenyl silyl bis (2,3 - Methylcyclopentadienyl) zirconium dichloride, diphenyl silyl bis (2,3 - dimethyl-cyclopentadienyl) Zirconium dimethyl, methyl-phenyl silyl bis (2,3 - dimethyl-cyclopentadienyl) zirconium dichloride, methyl -Phenyl silyl bis (2,3 - dimethyl-cyclopentadienyl) zirconium dimethyl, ethylenebis (2,3 - Dimethyl-cyclopentadienyl) zirconium dichloride, ethylene-bis (2,3 - dimethyl-cyclopentadienyl) dimethyl Group zirconium, methylene bis (2,3 - dimethyl-cyclopentadienyl) zirconium dichloride, methylene bis (2,3 - Methylcyclopentadienyl) zirconium dimethyl, dimethylsilyl bis (2,3 - dimethyl-cyclopentadienyl) Hafnium dichloride, dimethyl silyl bis (2,3 - dimethyl-cyclopentadienyl) hafnium dimethyl, diphenyl Silyl bis (2,3 - dimethyl-cyclopentadienyl) hafnium dichloride, diphenyl silyl bis (2,3 - dimethyl-cyclopentadienyl) hafnium dimethyl, methyl-phenyl silyl bis (2,3 - dimethyl- Cyclopentadienyl) hafnium dichloride, methyl phenyl silyl bis (2,3 - dimethyl-cyclopentadienyl) Hafnium dimethyl, ethylene bis (2,3 - dimethyl-cyclopentadienyl) hafnium dichloride, ethylene bis (2,3 - Dimethyl-cyclopentadienyl) hafnium dimethyl, methylene bis (2,3 - dimethyl-cyclopentadienyl) dichloride Hafnium, methylene bis (2,3 - dimethyl-cyclopentadienyl) hafnium dimethyl, dimethylsilyl bis (3 - trimethylsilyl cyclopentadienyl) zirconium dichloride, dimethyl silyl bis (3 - trimethoxyphenyl Silyl cyclopentadienyl) zirconium dimethyl, diphenyl silyl bis (3 - trimethylsilyl Cyclopentadienyl) zirconium dichloride, diphenyl silyl bis (3 - trimethylsilyl cyclopentadienyl group Enyl) zirconium dimethyl, methyl-phenyl silyl bis (3 - trimethylsilyl cyclopentadienyl) Zirconium dichloride, methyl phenyl silyl bis (3 - trimethylsilyl cyclopentadienyl) dimethyl Zirconium, ethylene-bis (3 - trimethylsilyl cyclopentadienyl) zirconium dichloride, ethylene-bis (3 - Trimethylsilyl cyclopentadienyl) zirconium dimethyl, methylene bis (3 - trimethylsilyl group ring Cyclopentadienyl) zirconium dichloride, methylene bis (3 - trimethylsilyl cyclopentadienyl) dimethyl Zirconium dichloride, dimethylsilyl bis (3 - trimethylsilyl cyclopentadienyl) hafnium dichloride, dimethyl Silyl bis (3 - trimethylsilyl cyclopentadienyl) hafnium dimethyl, diphenyl silyl Bis (3 - trimethylsilyl cyclopentadienyl) hafnium dichloride, diphenyl silyl bis (3 - Trimethylsilyl cyclopentadienyl) hafnium dimethyl, methyl-phenyl silyl bis (3 - trimethyl- Silyl cyclopentadienyl) hafnium dichloride, methyl phenyl silyl bis (3 - trimethylsilyl Cyclopentadienyl) hafnium dimethyl, ethylene bis (3 - trimethylsilyl cyclopentadienyl) bis Hafnium dichloride, ethylene bis (3 - trimethylsilyl cyclopentadienyl) hafnium dimethyl, methylene bis (3 - trimethylsilyl cyclopentadienyl) hafnium dichloride, methylene bis (3 - trimethylsilyl Cyclopentadienyl) hafnium dimethyl, ...

Dimethylsilyl bis (indenyl) zirconium dichloride, dimethyl silyl bis (indenyl) dimethyl Base zirconium diphenyl silyl pairs (indenyl) zirconium dichloride, diphenyl silyl pairs (indenyl) two Zirconium dimethyl, methyl-phenyl silyl bis (indenyl) zirconium dichloride, methyl phenyl silyl bis (indenyl Yl) zirconium dimethyl, ethylenebis (indenyl) zirconium dichloride, ethylene-bis (indenyl) zirconium dimethyl, Methylene bis (indenyl) zirconium dichloride, methylene bis (indenyl) zirconium dimethyl, dimethyl silyl Pair (indenyl) hafnium dichloride, dimethyl silyl pairs (indenyl) hafnium dimethyl, diphenyl silyl Bis (indenyl) hafnium dichloride, diphenyl silyl bis (indenyl) hafnium dimethyl, methyl-phenyl-methyl Silyl bis (indenyl) hafnium dichloride, methyl phenyl silyl bis (indenyl) hafnium dimethyl, ethylene Bis (indenyl) hafnium dichloride, ethylenebis (indenyl) hafnium dimethyl, methylene bis (indenyl) dichloride Hafnium, methylene bis (indenyl) hafnium dimethyl, dimethylsilyl bis (tetrahydroindenyl) dichloride Zirconium dimethyl silyl bis (tetrahydro-indenyl) zirconium dimethyl, diphenyl silyl bis (tetrahydro- Indenyl) zirconium dichloride, diphenyl silyl bis (tetrahydro-indenyl) zirconium dimethyl, methyl-phenyl-methyl Silyl bis (tetrahydro-indenyl) zirconium dichloride, methyl phenyl silyl bis (tetrahydro-indenyl) dimethyl Zirconium, ethylenebis (tetrahydroindenyl) zirconium dichloride, ethylene-bis (tetrahydroindenyl) zirconium dimethyl, Asia Bis (tetrahydro-indenyl) zirconium dichloride, methylene bis (tetrahydroindenyl) zirconium dimethyl, dimethyl Silyl bis (tetrahydro-indenyl) hafnium dichloride, dimethyl silyl bis (tetrahydro-indenyl) dimethyl Hafnium, diphenyl silyl bis (tetrahydro-indenyl) hafnium dichloride, diphenyl silyl bis (tetrahydro- Indenyl) hafnium dimethyl, methyl-phenyl silyl bis (tetrahydro-indenyl) hafnium dichloride, methylphenyl Silyl bis (tetrahydro-indenyl) hafnium dimethyl, ethylene bis (tetrahydro-indenyl) hafnium dichloride, ethylene Bis (tetrahydro-indenyl) hafnium dimethyl, methylene bis (tetrahydro-indenyl) hafnium dichloride, methylene bis (four Hydrogen indenyl) hafnium dimethyl, dimethylsilyl bis (2 - methyl-indenyl) zirconium dichloride, dimethyl Silyl bis (2 - methyl-indenyl) zirconium dimethyl, diphenyl silyl bis (2 - methyl-indenyl) two Zirconium dichloride, diphenyl silyl bis (2 - methyl-indenyl) zirconium dimethyl, methyl-phenyl silyl Bis (2 - methyl-indenyl) zirconium dichloride, methyl phenyl silyl bis (2 - methyl-indenyl) dimethyl Zirconium, ethylenebis (2 - methyl-indenyl) zirconium dichloride, ethylene-bis (2 - methyl-indenyl) zirconium dimethyl, Methylene-bis (2 - methyl-indenyl) zirconium dichloride, methylene bis (2 - methyl-indenyl) zirconium dimethyl, di Dimethylsilyl bis (2 - methyl-indenyl) hafnium dichloride, dimethyl silyl bis (2 - methyl-indene Yl) hafnium dimethyl, diphenyl silyl bis (2 - methyl-indenyl) hafnium dichloride, diphenyl silyl Alkyl bis (2 - methyl-indenyl) hafnium dimethyl, methyl-phenyl silyl bis (2 - methyl-indenyl) dichloride Hafnium, methyl phenyl silyl bis (2 - methyl-indenyl) hafnium dimethyl, ethylenebis (2 - methyl- Indenyl) hafnium dichloride, ethylene bis (2 - methyl-indenyl) hafnium dimethyl, methylene bis (2 - methyl-indene Yl) hafnium dichloride, methylene bis (2 - methyl-indenyl) hafnium dimethyl, rac - dimethylsilyl Bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, diphenyl silyl bis (2 - methyl-4 - benzene Indenyl) zirconium dimethyl, diphenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, Diphenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl, methyl-phenyl silyl Bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, methyl phenyl silyl bis (2 - methyl - 4 - phenyl Indenyl) zirconium dimethyl, ethylenebis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, ethylenebis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl, methylene bis (2 - methyl - 4 - phenyl-indenyl) dichloride Zirconium, methylene bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl, dimethylsilyl bis (2 - methyl -4 - phenyl-indenyl) hafnium dichloride, dimethyl silyl bis (2 - methyl - 4 - phenyl-indenyl) Hafnium dimethyl, diphenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) hafnium dichloride, diphenylmethyl Silyl bis (2 - methyl - 4 - phenyl-indenyl) hafnium dimethyl, methyl-phenyl silyl bis (2 - methyl- -4 - Phenyl-indenyl) hafnium dichloride, methyl phenyl silyl bis (2 - methyl - 4 - phenyl indenyl) two Hafnium dimethyl, ethylenebis (2 - methyl - 4 - phenyl-indenyl) hafnium dichloride, ethylene bis (2 - methyl - 4 - phenyl indenyl) hafnium dimethyl, methylene bis (2 - methyl - 4 - phenyl indenyl) hafnium dichloride, methylene Bis (2 - methyl - 4 - phenyl-indenyl) hafnium dimethyl, dimethylsilyl bis (4,7 - dimethyl-indene Yl) zirconium dichloride, dimethyl silyl bis (4,7 - dimethyl-indenyl) zirconium dimethyl, diphenyl Silyl bis (4,7 - dimethyl-indenyl) zirconium dichloride, diphenyl silyl bis (4,7 - dimethyl Indenyl) zirconium dimethyl, methyl-phenyl silyl bis (4,7 - dimethyl-indenyl) zirconium dichloride, Methyl-phenyl silyl bis (4,7 - dimethyl-indenyl) zirconium dimethyl, ethylenebis (4,7 - dimethoxyphenyl Indenyl) zirconium dichloride, ethylene-bis (4,7 - dimethyl-indenyl) zirconium dimethyl, methylene bis (4,7 - dimethyl-indenyl) zirconium dichloride, methylene bis (4,7 - dimethyl-indenyl) zirconium dimethyl, di Dimethylsilyl bis (4,7 - dimethyl-indenyl) hafnium dichloride, dimethylsilyl bis (4,7 - Dimethyl-indenyl) hafnium dimethyl, diphenyl silyl bis (4,7 - dimethyl-indenyl) hafnium dichloride, Diphenyl silyl bis (4,7 - dimethyl-indenyl) hafnium dimethyl, methyl-phenyl silyl bis (4,7 - dimethyl-indenyl) hafnium dichloride, methyl phenyl silyl bis (4,7 - dimethyl-indenyl) Hafnium dimethyl, ethylene bis (4,7 - dimethyl-indenyl) hafnium dichloride, ethylene bis (4,7 - dimethyl- Indenyl) hafnium dimethyl, methylene bis (4,7 - dimethyl-indenyl) hafnium dichloride, methylene bis (4,7 - Dimethyl-indenyl) hafnium dimethyl, dimethylsilyl bis (2 - methyl -4 - naphthyl indenyl) dichloride Zirconium dimethyl silyl bis (2 - methyl -4 - naphthyl indenyl) zirconium dimethyl, diphenyl silyl Alkyl bis (2 - methyl -4 - naphthyl indenyl) zirconium dichloride, diphenyl silyl bis (2 - methyl -4 - Naphthyl indenyl) zirconium dimethyl, methyl-phenyl silyl bis (2 - methyl -4 - naphthyl indenyl) dichloride Zirconium methyl phenyl silyl bis (2 - methyl -4 - naphthyl indenyl) zirconium dimethyl, ethylenebis (2 - Methyl-4 - naphthyl indenyl) zirconium dichloride, ethylene-bis (2 - methyl -4 - naphthyl indenyl) zirconium dimethyl, Methylene-bis (2 - methyl -4 - naphthyl indenyl) zirconium dichloride, methylene bis (2 - methyl -4 - naphthylindenyl Yl) zirconium dimethyl, dimethylsilyl bis (2 - methyl -4 - naphthyl indenyl) hafnium dichloride, dimethyl Silyl bis (2 - methyl -4 - naphthyl indenyl) hafnium dimethyl, diphenyl silyl bis (2 - methyl -4 - naphthyl indenyl) hafnium dichloride, diphenyl silyl bis (2 - methyl -4 - naphthyl indenyl) Hafnium dimethyl, methyl-phenyl silyl bis (2 - methyl -4 - naphthyl indenyl) hafnium dichloride, methyl benzene Silyl bis (2 - methyl -4 - naphthyl indenyl) hafnium dimethyl, ethylenebis (2 - methyl -4 - naphthalene Indenyl) hafnium dichloride, ethylene bis (2 - methyl -4 - naphthyl indenyl) hafnium dimethyl, methylene bis (2 - methyl -4 - naphthyl indenyl) hafnium dichloride, methylene bis (2 - methyl -4 - naphthyl indenyl) dimethyl Hafnium dimethyl silyl bis (2,3 - dimethyl-cyclopentadienyl) zirconium dichloride, dimethyl silyl Alkyl bis (2,3 - dimethyl-cyclopentadienyl) zirconium dimethyl, diphenyl silyl bis (2,3 - Methylcyclopentadienyl) zirconium dichloride, diphenyl silyl bis (2,3 - dimethyl-cyclopentadienyl) Zirconium dimethyl, methyl-phenyl silyl bis (2,3 - dimethyl-cyclopentadienyl) zirconium dichloride, methyl -Phenyl silyl bis (2,3 - dimethyl-cyclopentadienyl) zirconium dimethyl, ethylenebis (2,3 - Dimethyl-cyclopentadienyl) zirconium dichloride, ethylene-bis (2,3 - dimethyl-cyclopentadienyl) dimethyl Group zirconium, methylene bis (2,3 - dimethyl-cyclopentadienyl) zirconium dichloride, methylene bis (2,3 - Methylcyclopentadienyl) zirconium dimethyl, dimethylsilyl bis (2,3 - dimethyl-cyclopentadienyl) Hafnium dichloride, dimethyl silyl bis (2,3 - dimethyl-cyclopentadienyl) hafnium dimethyl, diphenyl Silyl bis (2,3 - dimethyl-cyclopentadienyl) hafnium dichloride, diphenyl silyl bis (2,3 - dimethyl-cyclopentadienyl) hafnium dimethyl, methyl-phenyl silyl bis (2,3 - dimethyl- Cyclopentadienyl) hafnium dichloride, methyl phenyl silyl bis (2,3 - dimethyl-cyclopentadienyl) Hafnium dimethyl, ethylene bis (2,3 - dimethyl-cyclopentadienyl) hafnium dichloride, ethylene bis (2,3 - Dimethyl-cyclopentadienyl) hafnium dimethyl, methylene bis (2,3 - dimethyl-cyclopentadienyl) dichloride Hafnium, methylene bis (2,3 - dimethyl-cyclopentadienyl) hafnium dimethyl, dimethylsilyl bis (3 - trimethylsilyl cyclopentadienyl) zirconium dichloride, dimethyl silyl bis (3 - trimethoxyphenyl Silyl cyclopentadienyl) zirconium dimethyl, diphenyl silyl bis (3 - trimethylsilyl Cyclopentadienyl) zirconium dichloride, diphenyl silyl bis (3 - trimethylsilyl cyclopentadienyl group Enyl) zirconium dimethyl, methyl-phenyl silyl bis (3 - trimethylsilyl cyclopentadienyl) Zirconium dichloride, methyl phenyl silyl bis (3 - trimethylsilyl cyclopentadienyl) dimethyl Zirconium, ethylene-bis (3 - trimethylsilyl cyclopentadienyl) zirconium dichloride, ethylene-bis (3 - Trimethylsilyl cyclopentadienyl) zirconium dimethyl, methylene bis (3 - trimethylsilyl group ring Cyclopentadienyl) zirconium dichloride, methylene bis (3 - trimethylsilyl cyclopentadienyl) dimethyl Zirconium dichloride, dimethylsilyl bis (3 - trimethylsilyl cyclopentadienyl) hafnium dichloride, dimethyl Silyl bis (3 - trimethylsilyl cyclopentadienyl) hafnium dimethyl, diphenyl silyl Bis (3 - trimethylsilyl cyclopentadienyl) hafnium dichloride, diphenyl silyl bis (3 - Trimethylsilyl cyclopentadienyl) hafnium dimethyl, methyl-phenyl silyl bis (3 - trimethyl- Silyl cyclopentadienyl) hafnium dichloride, methyl phenyl silyl bis (3 - trimethylsilyl Cyclopentadienyl) hafnium dimethyl, ethylene bis (3 - trimethylsilyl cyclopentadienyl) bis Hafnium dichloride, ethylene bis (3 - trimethylsilyl cyclopentadienyl) hafnium dimethyl, methylene bis (3 - trimethylsilyl cyclopentadienyl) hafnium dichloride, methylene bis (3 - trimethylsilyl Cyclopentadienyl) hafnium dimethyl, ...₂Zirconium dichloride;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂ η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1 ,3-butadiene;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1 4 - diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1 4 - diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl - 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl - 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indene Yl)₂Dimethyl zirconium; and

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dimethyl; like.

The most preferred material is a racemic substance following variants:

Dimethylsilyl bis (indenyl) zirconium dichloride, dimethyl silyl bis (indenyl) dimethyl Group zirconium, ethylenebis (indenyl) zirconium dichloride, ethylene-bis (indenyl) zirconium dimethyl, dimethyl Silyl bis (tetrahydro-indenyl) zirconium dichloride, dimethylsilyl bis (tetrahydro-indenyl) dimethyl Zirconium, ethylenebis (tetrahydroindenyl) zirconium dichloride, ethylene-bis (tetrahydroindenyl) zirconium dimethyl, di Dimethylsilyl bis (2 - methyl-indenyl) zirconium dichloride, dimethyl silyl bis (2 - methyl-indene Yl) zirconium dimethyl, ethylenebis (2 - methyl-indenyl) zirconium dichloride, ethylene-bis (2 - methyl-indenyl) Zirconium dimethyl, dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, dimethyl Silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl, ethylenebis (2 - methyl - 4 - phenyl- Indenyl) zirconium dichloride, ethylene-bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl dimethylsilyl Alkyl bis (4,7 - dimethyl-indenyl) zirconium dichloride, dimethyl silyl bis (4,7 - dimethyl-indene Yl) zirconium dimethyl ethylene bis (4,7 - dimethyl-indenyl) zirconium dichloride, ethylene bis (4,7 - two Methyl indenyl) zirconium dimethyl, dimethylsilyl bis (indenyl) hafnium dichloride, dimethyl silicone Alkyl bis (indenyl) hafnium dimethyl, ethylene bis (indenyl) hafnium dichloride, ethylene-bis (indenyl) two Hafnium dimethyl, dimethylsilyl bis (tetrahydro-indenyl) hafnium dichloride, dimethyl silyl bis (D Hydrogen indenyl) hafnium dimethyl, ethylenebis (tetrahydroindenyl) hafnium dichloride, ethylene-bis (tetrahydroindenyl) Hafnium dimethyl, dimethylsilyl bis (2 - methyl-indenyl) hafnium dichloride, dimethyl silyl Bis (2 - methyl-indenyl) hafnium dimethyl, ethylenebis (2 - methyl-indenyl) hafnium dichloride, ethylene bis (2 - methyl-indenyl) hafnium dimethyl, dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) dichloride Hafnium, dimethyl silyl bis (2 - methyl - 4 - phenyl-indenyl) hafnium dimethyl, ethylenebis (2 - Methyl-4 - phenyl-indenyl) hafnium dichloride, ethylene bis (2 - methyl - 4 - phenyl-indenyl) hafnium dimethyl, Dimethylsilyl bis (4,7 - dimethyl-indenyl) hafnium dichloride, dimethyl silyl bis (4,7 - dimethyl-indenyl) hafnium dimethyl, ethylene bis (4,7 - dimethyl-indenyl) hafnium dichloride and sodium Bis (4,7 - dimethyl-indenyl) hafnium dimethyl. ...

Dimethylsilyl bis (indenyl) zirconium dichloride, dimethyl silyl bis (indenyl) dimethyl Group zirconium, ethylenebis (indenyl) zirconium dichloride, ethylene-bis (indenyl) zirconium dimethyl, dimethyl Silyl bis (tetrahydro-indenyl) zirconium dichloride, dimethylsilyl bis (tetrahydro-indenyl) dimethyl Zirconium, ethylenebis (tetrahydroindenyl) zirconium dichloride, ethylene-bis (tetrahydroindenyl) zirconium dimethyl, di Dimethylsilyl bis (2 - methyl-indenyl) zirconium dichloride, dimethyl silyl bis (2 - methyl-indene Yl) zirconium dimethyl, ethylenebis (2 - methyl-indenyl) zirconium dichloride, ethylene-bis (2 - methyl-indenyl) Zirconium dimethyl, dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, dimethyl Silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl, ethylenebis (2 - methyl - 4 - phenyl- Indenyl) zirconium dichloride, ethylene-bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl dimethylsilyl Alkyl bis (4,7 - dimethyl-indenyl) zirconium dichloride, dimethyl silyl bis (4,7 - dimethyl-indene Yl) zirconium dimethyl ethylene bis (4,7 - dimethyl-indenyl) zirconium dichloride, ethylene bis (4,7 - two Methyl indenyl) zirconium dimethyl, dimethylsilyl bis (indenyl) hafnium dichloride, dimethyl silicone Alkyl bis (indenyl) hafnium dimethyl, ethylene bis (indenyl) hafnium dichloride, ethylene-bis (indenyl) two Hafnium dimethyl, dimethylsilyl bis (tetrahydro-indenyl) hafnium dichloride, dimethyl silyl bis (D Hydrogen indenyl) hafnium dimethyl, ethylenebis (tetrahydroindenyl) hafnium dichloride, ethylene-bis (tetrahydroindenyl) Hafnium dimethyl, dimethylsilyl bis (2 - methyl-indenyl) hafnium dichloride, dimethyl silyl Bis (2 - methyl-indenyl) hafnium dimethyl, ethylenebis (2 - methyl-indenyl) hafnium dichloride, ethylene bis (2 - methyl-indenyl) hafnium dimethyl, dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) dichloride Hafnium, dimethyl silyl bis (2 - methyl - 4 - phenyl-indenyl) hafnium dimethyl, ethylenebis (2 - Methyl-4 - phenyl-indenyl) hafnium dichloride, ethylene bis (2 - methyl - 4 - phenyl-indenyl) hafnium dimethyl, Dimethylsilyl bis (4,7 - dimethyl-indenyl) hafnium dichloride, dimethyl silyl bis (4,7 - dimethyl-indenyl) hafnium dimethyl, ethylene bis (4,7 - dimethyl-indenyl) hafnium dichloride and sodium Bis (4,7 - dimethyl-indenyl) hafnium dimethyl. ...^*), Both Cp and Cp^*A sufficient volume of space having a cyclopentadienyl ring substituted Cyclopentadienyl group to limit the rotation of the ligand, so satisfy the symmetry conditions. Such preferred Chiral racemic metallocene include bis (tricyclo [5.2.1.0^2，6] Deca-2 ,5 - diene-yl) dimethyl Zirconium and - hafnium, bis ((1R) -9,9 - dimethyl-tricyclo [6.1.1.0^2，6] Deca-2 ,5 - diene-yl) Zirconium dimethyl, bis (tricyclo [5.2.1.0^2，6] Dec-2 ,5,8 - triene-yl) zirconium dimethyl, bis (tricyclo [5.2.2.0^2，6] Undec-2 ,5,8 - triene yl) zirconium dimethyl, and - hafnium and bis ((1R, 8R) 7 ,7,9,9 - tetramethyl-[6.1.1.0^2，6] Deca-2 ,5 - dienyl) zirconium dimethyl and - hafnium.

For the production of syndiotactic properties with enhanced poly-α-olefin is preferably a metallocene precursors Those in Equation 17, where S "is independently selected so that both Cp-ligands have different air Room volume. For the production of syndiotactic polymers, the Cp-ring substituents style is important. Because Herein, where the term spatial differences or differences in the space used to refer to Cp and Cp^*Ring between Spatial characteristic differences, the difference between the respective relative symmetrical bridging group A, but different from each other, such as This control is incorporated into the polymer chain of the monomer unit of the subsequent channels. Cp and Cp^*Space between the rings Difference random play to prevent close proximity effect monomer so the monomers added to the syndiotactic configuration Polymer chain.

For the production of syndiotactic polymers the preferred metallocene precursors are those in Equation 17, the The S "are independently selected such that 1) two Cp-ligands the biggest difference between the space and 2) Equation 17 in the presence of the metal center and across the Cp-ring C₁And C_1′Carbon atoms, a plane of symmetry. Thus, with this symmetrical complexes such Me₂C(□ ⁵-C ₅H ₄) (1 - fluorenyl) MMe₂(Wherein M = Ti, Zr or Hf) is preferred, and with a similar system, but lower than normally produced symmetric With higher stereoregularity of syndiotactic polymers. Further, in the above equation, 1 - fluorenyl Can be 3,8 - di-tert-butyl fluorenyl, octahydrofluorenyl or 3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,10,10,11 -, Octahydro-dibenzo [b, h] fluorene substituted. Since these precursors reminders Agent, the reaction temperature is usually in a high loss of control of the stereoregularity of the polymer capacity, therefore Ensures a high degree of crystallinity in the material, to the lower reactor temperature, preferably below 80 ℃ under Using these catalysts.

Produce lower molecular weight isotactic polypropylene is preferred catalysts US5, 120,867 described in this Those described in the patents incorporated herein by reference. A single reactor can be used together and a series of anti- Reactor configuration, the catalyst also can produce any desired mixtures of polypropylene (including load pressure Agent) can be used in the present invention are blends of the production site. Preferred catalysts include alumoxane and / Or compatible noncoordinating anion combination with cyclopentadienyl transition metal compound and its derivatives Thereof.

Produce crystalline polypropylene further preferred catalysts are disclosed in Chem.rev. 2000,100,1253-1345, the documents incorporated herein by reference.

Amorphous polymer fractions for a preferred selection of the transition metal component is a single Equation 10 - Cyclopentadienyl transition metal component, wherein y is equal to 1. The preferred component such as in the following Type 18 Description:

Wherein A ', J, S', X₁、X ₂, L ', z and w are as previously defined, M is titanium. Replace Base S "_vAs defined in Equation 10 S "of the same, where the subscript" v "represents a substituent bonded to Cyclopentadienyl ring carbon atoms, wherein the cyclopentadienyl ring may have zero, two or four take Substituent S ", condition is a cyclopentadienyl ring is symmetrically substituted. Symmetrically substituted glutaric defined as the Band Alkenyl ring 2 and the 5 - and / or 3 and 4 are about the same volume of space S "group to take Generations. Usually these S "groups differ in size within two carbon atoms and therefore between 2 and 5 minutes Do not be methyl and ethyl group, or in positions 3 and 4 were hexyl and octyl-substituted cyclopentadienyl Group is considered to be symmetrical. Moreover, the cyclopentadienyl ring may be in all four positions S "group to take Generations, as long as the symmetry of a similar volume of space may be regarded as symmetrical. In addition, 3 and 4 Two adjacent bits S "- groups may be linked to form a ring, as long as the new ring is symmetrically substituted Can be. ...

As defined in Equation 10 S "of the same, where the subscript" v "represents a substituent bonded to Cyclopentadienyl ring carbon atoms, wherein the cyclopentadienyl ring may have zero, two or four take Substituent S ", condition is a cyclopentadienyl ring is symmetrically substituted. Symmetrically substituted glutaric defined as the Band Alkenyl ring 2 and the 5 - and / or 3 and 4 are about the same volume of space S "group to take Generations. Usually these S "groups differ in size within two carbon atoms and therefore between 2 and 5 minutes Do not be methyl and ethyl group, or in positions 3 and 4 were hexyl and octyl-substituted cyclopentadienyl Group is considered to be symmetrical. Moreover, the cyclopentadienyl ring may be in all four positions S "group to take Generations, as long as the symmetry of a similar volume of space may be regarded as symmetrical. In addition, 3 and 4 Two adjacent bits S "- groups may be linked to form a ring, as long as the new ring is symmetrically substituted Can be. ...₂) ₂Unit. Such polymers, such poly Characterization of compounds for the production of such polymers and catalyst system are described in US5, 723,560 , This patent is incorporated herein by reference. Lower Mw such polymers by changing variants Process conditions, for example by increasing the reactor temperature was produced.

According to the present invention specifically for the production of poly-α-olefin random catalyst system is preferably Single - cyclopentadienyl transition metal compounds include: dimethylsilyl group (tetramethylcyclopentadienyl Enyl) (cyclododecyl group) titanium dichloride, dimethyl silyl (tetramethylcyclopentadienyl Yl) (cyclohexylamino) titanium dichloride, dimethyl silyl (tetramethyl-cyclopentadienyl) (1 - Gold Just alkylamino) titanium dichloride, dimethyl silyl (tetramethyl-cyclopentadienyl) (tert-butylamino Yl) titanium dichloride, dimethyl silyl (tetramethyl cyclopentadienyl) (sec-butylamino) dichloride Titanium, dimethyl silyl (tetramethyl cyclopentadienyl) (n-butylamino) titanium dichloride, di Dimethylsilyl (tetramethyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, di Triethylsilyl (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dichloride, diethyl Silyl (tetramethyl cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, diethyl Silyl (tetramethyl cyclopentadienyl) (cyclohexylamino) titanium dichloride, diethyl silyl (Tetramethyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, diethyl silyl (d Methyl-cyclopentadienyl) (tert-butylamino) titanium dichloride, methylene (tetramethylcyclopentadienyl Yl) (cyclododecyl group) titanium dichloride, methylene (tetramethyl cyclopentadienyl) (exo-2 - lower Bornyl group) titanium dichloride, methylene (tetramethyl cyclopentadienyl) (cyclohexylamino) dichloride Titanium, methylene (tetramethyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, methylene (Tetramethyl cyclopentadienyl) (tert-butylamino) titanium dichloride, ethylene (tetramethylcyclopentadienyl Yl) (cyclododecyl group) titanium dichloride, ethylene (tetramethyl cyclopentadienyl) (exo-2 - lower Bornyl group) titanium dichloride, ethylene (tetramethyl cyclopentadienyl) (cyclohexylamino) dichloride Titanium, ethylenebis (tetramethyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, ethylene (Tetramethyl cyclopentadienyl) (t-butylamino) titanium dichloride, dimethyl silyl (tetramethyl Cyclopentadienyl) (cyclododecyl) dimethyl titanium, dimethylsilyl (tetramethylcyclopentadienyl Dienyl) (cyclohexylamino) titanium dimethyl, dimethylsilyl group (tetramethylcyclopentadienyl Yl) (1 - adamantyl) dimethyl titanium, dimethylsilyl (tetramethylcyclopentadienyl Yl) (t-butylamino) titanium dimethyl, dimethylsilyl group (tetramethyl cyclopentadienyl) (sec- Yl) dimethyl titanium, dimethylsilyl (tetramethyl-cyclopentadienyl) (n-butylamino) Titanium dimethyl, dimethylsilyl group (tetramethyl cyclopentadienyl) (exo-2 - norbornyl group) Titanium dimethyl, diethyl silyl (tetramethyl cyclopentadienyl) (cyclododecyl group) dimethyl Ti-, diethyl silyl (tetramethyl cyclopentadienyl) (exo-2 - norbornyl group) dimethyl Ti-, diethyl silyl (tetramethyl cyclopentadienyl) (cyclohexylamino) dimethyl titanium, Triethylsilyl (tetramethyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, diethyl Silyl (tetramethyl cyclopentadienyl) (t-butylamino) titanium dimethyl, methylene (tetramethyl Cyclopentadienyl) (ring dodecylamino) titanium dimethyl, methylene (tetramethylcyclopentadienyl Yl) (exo-2 - amino-norbornyl) titanium dimethyl, methylene (tetramethyl cyclopentadienyl) (cyclohexyl Ylamino) titanium dimethyl, methylene (tetramethyl-cyclopentadienyl) (1 - adamantyl group) dimethyl Ti-, methylene (tetramethyl cyclopentadienyl) (t-butylamino) titanium dimethyl, ethylidene (d Methyl-cyclopentadienyl) (ring dodecylamino) titanium dimethyl, ethylene (tetramethylcyclopentadienyl Yl) (exo-2 - amino-norbornyl) titanium dimethyl, ethylidene (tetramethyl cyclopentadienyl) (cyclohexyl Ylamino) titanium dimethyl, ethylidene (tetramethyl-cyclopentadienyl) (1 - adamantyl group) dimethyl Ti-, ethylenebis (tetramethyl cyclopentadienyl) (t-butylamino) titanium dimethyl, dimethylsilyl Alkyl (2,5 - dimethyl-cyclopentadienyl) (cyclododecyl group) titanium dichloride, dimethylsilyl Alkyl (2,5 - dimethyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, dimethyl A silyl group (2,5 - dimethyl-cyclopentadienyl) (cyclohexylamino) titanium dichloride, dimethylsilyl Alkyl (2,5 - dimethyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, dimethylsilyl Alkyl (2,5 - dimethyl-cyclopentadienyl) (t-butylamino) titanium dichloride, dimethyl silyl (3,4 - dimethyl-cyclopentadienyl) (cyclododecyl group) titanium dichloride, dimethyl silyl (3,4 - dimethyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, dimethylsilyl Alkyl (3,4 - dimethyl-cyclopentadienyl) (cyclohexylamino) titanium dichloride, dimethyl silyl (3,4 - dimethyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, dimethyl silyl (3,4 - dimethyl-cyclopentadienyl) (t-butylamino) titanium dichloride, dimethyl silyl group (2 - Ethyl-5 - methyl-cyclopentadienyl) (cyclododecyl group) titanium dichloride, dimethyl silyl (2 - ethyl-5 - methyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, dimethylformamide Silane group (2 - ethyl-5 - methyl-cyclopentadienyl) (cyclohexylamino) titanium dichloride, dimethylformamide Silane group (2 - ethyl-5 - methyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, dimethyl Silyl (2 - ethyl-5 - methyl-cyclopentadienyl) (t-butylamino) titanium dichloride, dimethyl Silyl (3 - ethyl-4 - methyl-cyclopentadienyl) (cyclododecyl group) titanium dichloride, Dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (exo-2 - norbornyl group) two Titanium dichloride, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (cyclohexylamino) Titanium dichloride, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (1 - adamantyl amino Yl) titanium dichloride, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (tert-butylamino Yl) titanium dichloride, dimethyl silyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl cyclopentadiene Enyl) (cyclododecyl group) titanium dichloride, dimethyl silyl group (2 - ethyl - 3 - hexyl-5 - Methyl-4 - octylcyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, dimethylsilyl Group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (cyclohexylamino) dichloride Titanium, dimethyl silyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (1 - Adamantyl group) titanium dichloride, dimethyl silyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - Octyl-cyclopentadienyl) (t-butylamino) titanium dichloride, dimethyl silyl group (2 - tetrahydroindenyl Yl) (cyclododecyl group) titanium dichloride, dimethyl silyl group (2 - tetrahydro-indenyl) (exo-2 - Norbornyl group) titanium dichloride, dimethyl silyl group (2 - tetrahydro-indenyl) (cyclohexylamino) Titanium dichloride, dimethylsilyl group (2 - tetrahydro-indenyl) (1 - adamantyl group) titanium dichloride, Dimethylsilyl group (2 - tetrahydro-indenyl) (t-butylamino) titanium dichloride, dimethyl silyl (2,5 - dimethyl-cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl group (2,5 - dimethyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dimethyl, dimethylsilyl Alkyl (2,5 - dimethyl-cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethylsilyl group (2,5 - dimethyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, dimethylsilyl group (2,5 - dimethyl-cyclopentadienyl) (t-butylamino) titanium dimethyl, dimethylsilyl group (3,4 - dimethyl-cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl group (3,4 - dimethyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dimethyl, dimethylsilyl Alkyl (3,4 - dimethyl-cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethylsilyl group (3,4 - dimethyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, dimethylsilyl group (3,4 - dimethyl-cyclopentadienyl) (t-butylamino) titanium dimethyl, dimethylsilyl group (2 - Ethyl-5 - methyl-cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl Group (2 - ethyl-5 - methyl-cyclopentadienyl) (exo-2 - norbornyl) dimethyl titanium, dimethyl A silyl group (2 - ethyl-5 - methyl-cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethyl A silyl group (2 - ethyl-5 - methyl-cyclopentadienyl) (1 - adamantyl) dimethyl titanium, Dimethylsilyl (2 - ethyl-5 - methyl-cyclopentadienyl) (t-butylamino) dimethyl titanium, Dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (cyclododecyl) dimethyl Titanium, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (exo-2 - norbornyl group) Titanium dimethyl, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (cyclohexylamino) Titanium dimethyl, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (1 - adamantyl amino Yl) titanium dimethyl, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (tert-butylamino Yl) titanium dimethyl, dimethylsilyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl cyclopentadiene Enyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl group (2 - ethyl - 3 - hexyl-5 - Methyl-4 - octylcyclopentadienyl) (exo-2 - amino-norbornyl) titanium dimethyl, dimethylsilyl Group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (cyclohexylamino) dimethyl Ti-, dimethyl silyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (1 - Adamantyl group) titanium dimethyl, dimethylsilyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - Octyl-cyclopentadienyl) (t-butylamino) titanium dimethyl, dimethylsilyl group (2 - tetrahydroindenyl Yl) (cyclododecyl group) titanium dimethyl, dimethylsilyl group (2 - tetrahydro-indenyl) (exo-2 - Norbornyl group) titanium dimethyl, dimethylsilyl group (2 - tetrahydro-indenyl) (cyclohexylamino) Titanium dimethyl, dimethylsilyl group (2 - tetrahydro-indenyl) (1 - adamantyl group) titanium dimethyl, Dimethylsilyl group (2 - tetrahydro-indenyl) (t-butylamino) titanium dimethyl, and the like. ...

The most preferred material is: dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecane Ylamino) titanium dichloride, dimethyl silyl (tetramethyl cyclopentadienyl) (t-butylamino) Titanium dichloride, dimethyl silyl (tetramethyl cyclopentadienyl) (cyclohexylamino) dichloride Titanium, dimethylsilyl (tetramethyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, Dimethylsilyl group (tetramethyl cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, Dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethyl Silyl (tetramethyl cyclopentadienyl) (t-butylamino) titanium dimethyl, dimethylsilyl Group (tetramethyl cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethylsilyl group (tetramethyl Cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, and dimethylsilyl group (tetramethyl Cyclopentadienyl) (exo-2 - norbornyl) dimethyl titanium. ...

Wherein A ', M, X₁And X₂As previously defined. Substituent S "_vAnd S__vIndependently of other 8-9 of the formula S "defined where the subscript" v "represents a substituent bonded to Cp-ring or Flu- Ring (fluorenyl - ring) ring carbon atoms.

(When the reactor at high temperature conditions as the catalyst) is used primarily for production of Characteristics of amorphous poly-α-olefin metallocene precursors Equation 19 is preferably those wherein S__vIndependently selected so that the metallocene framework with a metal center and Flu-and Cp-ring is divided into two Of the symmetry plane. A 'no symmetrical ligands - such as dimethylformamide or methyl phenyl methyl silane Silyl group does not affect the production of the polymer stereochemistry. S_ substituent_vDefinition and equation 8-9 S "of the same, where the subscript" v "represents a substituent bonded to a cyclopentadienyl ring carbon Atoms, of which the cyclopentadienyl rings may have zero, two or four substituents S_, condition The cyclopentadienyl ring is symmetrically substituted. Is defined as the symmetrically substituted cyclopentadienyl ring 2 and 5 Position and / or 3 and 4 are about the same spatial volume S_ substituted. Often these S_ group size difference in the two carbon atom. Therefore, 2 and 5 positions respectively methyl and ethyl Substituted, or in positions 3 and 4 were hexyl and octyl-substituted cyclopentadienyl group is considered to be Known. Moreover, the cyclopentadienyl ring may be in all four positions S_ substituted, as long as the Symmetric a similar volume of space to be considered symmetric. In addition, 3 and 4 in S_ two adjacent groups may form a ring, provided that a new ring can be substituted also symmetric. As the fluorenyl ring S " ..._vDefinition and equation 8-9 S "of the same, where the subscript" v "represents a substituent bonded to a cyclopentadienyl ring carbon Atoms, of which the cyclopentadienyl rings may have zero, two or four substituents S_, condition The cyclopentadienyl ring is symmetrically substituted. Is defined as the symmetrically substituted cyclopentadienyl ring 2 and 5 Position and / or 3 and 4 are about the same spatial volume S_ substituted. Often these S_ group size difference in the two carbon atom. Therefore, 2 and 5 positions respectively methyl and ethyl Substituted, or in positions 3 and 4 were hexyl and octyl-substituted cyclopentadienyl group is considered to be Known. Moreover, the cyclopentadienyl ring may be in all four positions S_ substituted, as long as the Symmetric a similar volume of space to be considered symmetric. In addition, 3 and 4 in S_ two adjacent groups may form a ring, provided that a new ring can be substituted also symmetric. As the fluorenyl ring S " ...

According to the present invention specifically for the production of amorphous or low-crystalline poly-α-olefins catalyzed A preferred surfactant system of the metallocene transition metal compounds include: isopropylidene (cyclopentadienyl Yl) (fluorenyl) zirconium dichloride, isopropylidene (cyclopentadienyl) (fluorenyl) zirconium dimethyl methylene (Cyclopentadienyl) (fluorenyl) zirconium dichloride, methylene (cyclopentadienyl) (fluorenyl) zirconium dimethyl, Diphenylmethylene (cyclopentadienyl) (fluorenyl) zirconium dichloride, diphenylmethylene (cyclopentadienyl Yl) (fluorenyl) zirconium dimethyl, bis (p - triethylsilyl alkylphenyl) methylene (cyclopentadienyl Yl) (fluorenyl) zirconium dichloride, bis (p - triethylsilyl alkylphenyl) methylene (cyclopentadienyl Yl) (fluorenyl) zirconium dimethyl, bis (p - alkylphenyl trimethylsilyl) methylene (cyclopentadienyl Yl) (fluorenyl) zirconium dichloride, bis (p - alkylphenyl trimethylsilyl) methylene (cyclopentadienyl Yl) (fluorenyl) zirconium dimethyl, diphenyl silyl (cyclopentadienyl) (fluorenyl) zirconium dichloride, Diphenylsilyl (cyclopentadienyl) (fluorenyl) zirconium dimethyl, dimethyl silyl (cyclopentadienyl Enyl) (fluorenyl) zirconium dichloride, dimethyl silyl (cyclopentadienyl) (fluorenyl) zirconium dimethyl, Methyl-phenyl silyl (cyclopentadienyl) (fluorenyl) zirconium dichloride, methyl phenyl silyl (Cyclopentadienyl) (fluorenyl) zirconium dimethyl isopropylidene (cyclopentadienyl) (fluorenyl) dichloride Hafnium, isopropylidene (cyclopentadienyl) (fluorenyl) hafnium dimethyl, methylene (cyclopentadienyl) (fluorenyl Yl) hafnium dichloride, methylene (cyclopentadienyl) (fluorenyl) hafnium dimethyl, diphenylmethylene (ring Cyclopentadienyl) (fluorenyl) hafnium dichloride, diphenylmethylene (cyclopentadienyl) (fluorenyl) dimethyl Hafnium, bis (p - triethylsilyl alkylphenyl) methylene (cyclopentadienyl) (fluorenyl) hafnium dichloride, Bis (p - triethylsilyl alkylphenyl) methylene (cyclopentadienyl) (fluorenyl) hafnium dimethyl, di (P - alkylphenyl trimethylsilyl) methylene (cyclopentadienyl) (fluorenyl) hafnium dichloride, bis (p- - Alkylphenyl trimethylsilyl) methylene (cyclopentadienyl) (fluorenyl) hafnium dimethyl, diphenyl methyl Silyl (cyclopentadienyl) (fluorenyl) hafnium dichloride, diphenyl silyl (cyclopentadienyl Yl) (fluorenyl) hafnium dimethyl, dimethyl silyl (cyclopentadienyl) (fluorenyl) hafnium dichloride, Dimethyl silyl (cyclopentadienyl) (fluorenyl) hafnium dimethyl, methyl-phenyl silyl (ring Cyclopentadienyl) (fluorenyl) hafnium dichloride, methyl phenyl silyl (cyclopentadienyl) (fluorenyl) Hafnium dimethyl, isopropylidene (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) zirconium dichloride, isopropylidene Group (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) zirconium dimethyl, methylene (cyclopentadienyl Yl) (3,8 - di-tert-butyl-fluorenyl) zirconium dichloride, methylene (cyclopentadienyl) (3,8 - di-tert-butyl Fluorenyl) zirconium dimethyl, diphenylmethylene (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) dichloride Zirconium, diphenylmethylene (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) zirconium dimethyl, bis (p- - Triethylsilyl alkylphenyl) methylene (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) dichloride Zirconium, di (p - triethylsilyl alkylphenyl) methylene (cyclopentadienyl) (3,8 - di-tert-butyl Fluorenyl) zirconium dimethyl, bis (p - alkylphenyl trimethylsilyl) methylene (cyclopentadienyl Yl) (3,8 - di-tert-butyl-fluorenyl) zirconium dichloride, bis (p - alkylphenyl trimethylsilyl) methylene (Cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) zirconium dimethyl, diphenyl silyl (cyclopentadienyl Enyl) (3,8 - di-tert-butyl-fluorenyl) zirconium dichloride, diphenyl silyl (cyclopentadienyl Yl) (3,8 - di-tert-butyl-fluorenyl) zirconium dimethyl, dimethyl silyl (cyclopentadienyl) (3,8 - Di-tert-butyl-fluorenyl) zirconium dichloride, dimethyl silyl (cyclopentadienyl) (3,8 - di-tert-butyl Fluorenyl) zirconium dimethyl, methyl-phenyl silyl (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) Zirconium dichloride, methyl phenyl silyl (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) dimethyl Zirconium, isopropylidene (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dichloride, isopropylidene (ring Cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dimethyl, methylene (cyclopentadienyl) (3,8 - Di-tert-butyl fluorenyl) hafnium dichloride, methylene (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) Hafnium dimethyl, diphenylmethylene (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dichloride, di Phenyl methyl (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dimethyl, bis (p - triethyl Silyl alkyl) methylene (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dichloride, di (P - triethylsilyl alkylphenyl) methylene (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) Hafnium dimethyl, bis (p - alkylphenyl trimethylsilyl) methylene (cyclopentadienyl) (3,8 - di-tert-butyl Yl fluorenyl) hafnium dichloride, bis (p - alkylphenyl trimethylsilyl) methylene (cyclopentadienyl Yl) (3,8 - di-tert-butyl-fluorenyl) hafnium dimethyl, diphenyl silyl (cyclopentadienyl Yl) (3,8 - di-tert-butyl-fluorenyl) hafnium dichloride, diphenyl silyl (cyclopentadienyl) (3,8 - Di-tert-butyl-fluorenyl) hafnium dimethyl, dimethyl silyl (cyclopentadienyl) (3,8 - di-tert-butyl Fluorenyl) hafnium dichloride, dimethyl silyl (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) Hafnium dimethyl, methyl-phenyl silyl (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) dichloride Hafnium, methyl phenyl silyl (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dimethyl, iso Propylidene group (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - Octahydro-dibenzyl [b, h] fluorenyl) zirconium dichloride, isopropylidene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) zirconium dimethyl, methylene (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - Octahydro-dibenzyl-[b, h] fluorenyl) zirconium dichloride, methylene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) zirconium dimethyl, diphenylmethylene (cyclopentadienyl) (3,3,6,6,9,9,12,12 - bajia Yl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl [b, h] fluorenyl) zirconium dichloride, diphenylsilylene Group (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro Dibenzyl [b, h] fluorenyl) zirconium dimethyl, bis (p - triethylsilyl alkylphenyl) methylene (ring Pentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl [B, h] fluorenyl) zirconium dichloride, bis (p - triethylsilyl alkylphenyl) methylene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) zirconium dimethyl, bis (p - alkylphenyl trimethylsilyl) methylene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) zirconium dichloride, bis (p - alkylphenyl trimethylsilyl) methylene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) zirconium dimethyl, diphenyl silyl (cyclopentadienyl) (3,3,6,6,9,9,12,12 - Octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] fluorenyl) zirconium dichloride, diphenylmethyl Silyl (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - Octahydro-dibenzyl [b, h] fluorenyl) zirconium dimethyl, dimethyl silyl (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) zirconium dichloride, dimethyl silyl (cyclopentadienyl) (3,3,6,6,9,9,12,12 - Octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] fluorenyl) zirconium dimethyl, methyl-phenyl Silyl (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - Octahydro-dibenzyl-[b, h] fluorenyl) zirconium dichloride, methyl phenyl silyl Group (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro Dibenzyl [b, h] fluorenyl) zirconium dimethyl, isopropylidene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) hafnium dichloride, isopropylidene (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - Octahydro-dibenzyl-[b, h] fluorenyl) hafnium dimethyl, methylene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) hafnium dichloride, methylene (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - Octahydro-dibenzyl-[b, h] fluorenyl) hafnium dimethyl, diphenylmethylene (ring Pentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl [B, h] fluorenyl) hafnium dichloride, diphenylmethylene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) hafnium dimethyl, bis (p - triethylsilyl alkylphenyl) methylene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) hafnium dichloride, bis (p - triethylsilyl alkylphenyl) methylene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) hafnium dimethyl, bis (p - alkylphenyl trimethylsilyl) methylene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) hafnium dichloride, bis (p - alkylphenyl trimethylsilyl) methylene (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) hafnium dimethyl, diphenyl silyl (cyclopentadienyl) (3,3,6,6,9,9,12,12 - Octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] fluorenyl) hafnium dichloride, diphenylmethyl Silyl (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - Octahydro-dibenzyl [b, h] fluorenyl) hafnium dimethyl, dimethyl silyl (cyclopentadienyl Yl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] Fluorenyl) hafnium dichloride, dimethyl silyl (cyclopentadienyl) (3,3,6,6,9,9,12,12 - Octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] fluorenyl) hafnium dimethyl, methyl-phenyl Silyl (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - Octahydro-dibenzyl-[b, h] fluorenyl) hafnium dichloride, methyl phenyl silyl Group (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl -4,4,5,5,8,8,9,9 - octahydro Dibenzyl [b, h] fluorenyl) hafnium dimethyl ...

The most preferred materials are: bis (p - triethylsilyl alkylphenyl) methylene (cyclopentadienyl Yl) (3,8 - di-tert-butyl-fluorenyl) zirconium dichloride, bis (p - triethylsilyl alkylphenyl) methylene (Cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dichloride, bis (p - triethylsilyl benzene Yl) methylene (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) zirconium dimethyl, bis (p - triethyl Silyl alkyl) methylene (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dimethyl, di (P - triethylsilyl alkylphenyl) methylene (cyclopentadienyl) (3,3,6,6,9,9,12,12 - Octamethyl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] fluorenyl) zirconium dichloride, bis (p - Triethylsilyl alkylphenyl) methylene (cyclopentadienyl) (3,3,6,6,9,9,12,12 - bajia Yl -4,4,5,5,8,8,9,9 - octahydro-dibenzyl [b, h] fluorenyl) hafnium dichloride, bis (p - triethylamine Silyl group alkylphenyl) methylene (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl - 4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] fluorenyl) zirconium dimethyl, and bis (p - triethyl Silyl alkyl) methylene (cyclopentadienyl) (3,3,6,6,9,9,12,12 - octamethyl - 4,4,5,5,8,8,9,9 - octahydro-dibenzyl-[b, h] fluorenyl) hafnium dimethyl. ...

In this case, S_v"Are independently selected so that the metallocene framework has the M and A 'into Two parts of the plane of symmetry. Substituent S_v"Are independently defined as in Equation 8-9 S" of the same, Where the subscript "v" represents a substituent bonded to a cyclopentadienyl ring carbon atoms, wherein the cyclopentadienyl Cyclopentadienyl ring may have from zero to four substituents S ", provided that the cyclopentadienyl ring is symmetrically taken Generations. Is defined as the symmetrically substituted cyclopentadienyl ring 2 and 2 'and / or 3 and 3' position and / Or 4 and 4 'and / or 5 and 5' position is about the same volume of space S "substituted. Through Usually these S "groups differ in size within two carbon atoms and therefore between 2 and 2 ', respectively, methoxy And ethyl substituted, or 3 and 3 'positions were hexyl and octyl substituted cyclopentadienyl groups are recognized To be symmetrical. Moreover, the cyclopentadienyl ring may be in all four positions S "substituted, only Similar to the symmetry of the volume of the space is considered to be symmetrical. In addition, two adjacent S "- groups may be linked to form a ring, as long as the new ring is symmetrically substituted to these complexes Such as meso-Me ...₂"Are independently defined as in Equation 8-9 S" of the same, Where the subscript "v" represents a substituent bonded to a cyclopentadienyl ring carbon atoms, wherein the cyclopentadienyl Cyclopentadienyl ring may have from zero to four substituents S ", provided that the cyclopentadienyl ring is symmetrically taken Generations. Is defined as the symmetrically substituted cyclopentadienyl ring 2 and 2 'and / or 3 and 3' position and / Or 4 and 4 'and / or 5 and 5' position is about the same volume of space S "substituted. Through Usually these S "groups differ in size within two carbon atoms and therefore between 2 and 2 ', respectively, methoxy And ethyl substituted, or 3 and 3 'positions were hexyl and octyl substituted cyclopentadienyl groups are recognized To be symmetrical. Moreover, the cyclopentadienyl ring may be in all four positions S "substituted, only Similar to the symmetry of the volume of the space is considered to be symmetrical. In addition, two adjacent S "- groups may be linked to form a ring, as long as the new ring is symmetrically substituted to these complexes Such as meso-Me ...₂ZrMe ₂, Meso-CH₂CH ₂(Indenyl)₂ZrCl ₂Company in the art Known, and can be used to produce the present invention is an amorphous polymer.

According to the present invention, dedicated to the production of amorphous poly-α-olefin is preferably a catalyst system Meso - metallocene compounds include the following substances meso variants: dimethylsilyl bis (Indenyl) zirconium dichloride, dimethylsilyl bis (indenyl) zirconium dimethyl, diphenyl silyl Bis (indenyl) zirconium dichloride, diphenyl silyl bis (indenyl) zirconium dimethyl, methyl-phenyl silyl Alkyl bis (indenyl) zirconium dichloride, methyl phenyl silyl bis (indenyl) zirconium dimethyl, ethylene Pair (indenyl) zirconium dichloride, ethylene-bis (indenyl) zirconium dimethyl methylene bis (indenyl) dichloride Zirconium, methylene bis (indenyl) zirconium dimethyl, dimethylsilyl bis (indenyl) hafnium dichloride, di Dimethylsilyl bis (indenyl) hafnium dimethyl, diphenyl silyl bis (indenyl) hafnium dichloride, Diphenylsilyl bis (indenyl) hafnium dimethyl, methyl phenyl silyl pairs (indenyl) dichloride Hafnium, methyl phenyl silyl bis (indenyl) hafnium dimethyl, ethylenebis (indenyl) hafnium dichloride, Ethylene-bis (indenyl) hafnium dimethyl, methylene bis (indenyl) hafnium dichloride, methylene bis (indenyl) Hafnium dimethyl, dimethylsilyl bis (tetrahydro-indenyl) zirconium dichloride, dimethyl silyl bis (Tetrahydro-indenyl) zirconium dimethyl, diphenyl silyl bis (tetrahydro-indenyl) zirconium dichloride, diphenyl Silyl bis (tetrahydro-indenyl) zirconium dimethyl, methyl-phenyl silyl bis (tetrahydroindenyl) dichloride Zirconium dimethyl diphenylsilyl bis (tetrahydro-indenyl) zirconium dimethyl, ethylenebis (tetrahydroindenyl) Zirconium dichloride, ethylene bis (tetrahydro-indenyl) zirconium dimethyl methylene bis (tetrahydro-indenyl) dichloride Zirconium, methylene bis (tetrahydroindenyl) zirconium dimethyl, dimethylsilyl bis (tetrahydro-indenyl) dichloride Hafnium, dimethylsilyl bis (tetrahydro-indenyl) hafnium dimethyl, diphenyl silyl bis (D Hydrogen indenyl) hafnium dichloride, diphenyl silyl bis (tetrahydro-indenyl) hafnium dimethyl, methyl-phenyl Silyl bis (tetrahydro-indenyl) hafnium dichloride, methyl phenyl silyl bis (tetrahydro-indenyl) dimethyl Group hafnium, ethylenebis (tetrahydroindenyl) hafnium dichloride, ethylene bis (tetrahydro-indenyl) hafnium dimethyl, Methylene-bis (tetrahydro-indenyl) hafnium dichloride, methylene bis (tetrahydro-indenyl) hafnium dimethyl, dimethyl Silyl bis (2 - methyl-indenyl) zirconium dichloride, dimethyl silyl bis (2 - methyl-indenyl) two Zirconium dimethyl, diphenyl silyl bis (2 - methyl-indenyl) zirconium dichloride, diphenyl silyl bis (2 - methyl-indenyl) zirconium dimethyl, methyl-phenyl silyl bis (2 - methyl-indenyl) zirconium dichloride, Methyl-phenyl silyl bis (2 - methyl-indenyl) zirconium dimethyl, ethylenebis (2 - methyl-indenyl) Zirconium dichloride, ethylene-bis (2 - methyl-indenyl) zirconium dimethyl, methylene bis (2 - methyl-indenyl) dichloride Zirconium, methylene bis (2 - methyl-indenyl) zirconium dimethyl, dimethylsilyl bis (2 - methyl-indene Yl) hafnium dichloride, dimethyl silyl bis (2 - methyl-indenyl) hafnium dimethyl, diphenyl silyl Alkyl bis (2 - methyl-indenyl) hafnium dichloride, diphenyl silyl bis (2 - methyl-indenyl) dimethyl Hafnium, methyl phenyl silyl bis (2 - methyl-indenyl) hafnium dichloride, methyl phenyl silyl bis (2 - methyl-indenyl) hafnium dimethyl, ethylenebis (2 - methyl-indenyl) hafnium dichloride, ethylene bis (2 - Methyl indenyl) hafnium dimethyl, methylene bis (2 - methyl-indenyl) hafnium dichloride, methylene bis (2 - A Indenyl) hafnium dimethyl, dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, Diphenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl, diphenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, diphenyl silyl bis (2 - methyl - 4 - phenyl-indene Yl) zirconium dimethyl, methyl-phenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, methyl -Phenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl, ethylenebis (2 - methyl- -4 - Phenyl-indenyl) zirconium dichloride, ethylene-bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl, Asia Methyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, methylene bis (2 - methyl - 4 - phenyl-indenyl) Zirconium dimethyl, dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) hafnium dichloride, dimethyl Silyl bis (2 - methyl - 4 - phenyl-indenyl) hafnium dimethyl, diphenyl silyl bis (2 - methyl- -4 - Phenyl-indenyl) hafnium dichloride, diphenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) dimethyl Group hafnium, methyl phenyl silyl bis (2 - methyl - 4 - phenyl-indenyl) hafnium dichloride, methylphenyl Silyl bis (2 - methyl - 4 - phenyl-indenyl) hafnium dimethyl, ethylenebis (2 - methyl - 4 - phenyl- Indenyl) hafnium dichloride, ethylene bis (2 - methyl - 4 - phenyl indenyl) hafnium dimethyl, methylene bis (2 - methyl - 4 - phenyl-indenyl) hafnium dichloride, methylene bis (2 - methyl - 4 - phenyl-indenyl) dimethyl Hafnium dimethyl silyl bis (4,7 - dimethyl-indenyl) zirconium dichloride, dimethyl silyl bis (4,7 - dimethyl-indenyl) zirconium dimethyl, diphenyl silyl bis (4,7 - dimethyl-indenyl) dichloride Zirconium diphenyl silyl bis (4,7 - dimethyl-indenyl) zirconium dimethyl, methyl-phenyl silyl Bis (4,7 - dimethyl-indenyl) zirconium dichloride, methyl phenyl silyl bis (4,7 - dimethyl-indene Yl) zirconium dimethyl ethylene bis (4,7 - dimethyl-indenyl) zirconium dichloride, ethylene bis (4,7 - two Methyl indenyl) zirconium dimethyl methylene bis (4,7 - dimethyl-indenyl) zirconium dichloride, methylene bis (4,7 - dimethyl-indenyl) zirconium dimethyl dimethylsilyl bis (4,7 - dimethyl-indenyl) dichloride Hafnium, dimethylsilyl bis (4,7 - dimethyl-indenyl) hafnium dimethyl, diphenyl silyl Bis (4,7 - dimethyl-indenyl) hafnium dichloride, diphenyl silyl bis (4,7 - dimethyl-indenyl) Hafnium dimethyl, methyl-phenyl silyl bis (4,7 - dimethyl-indenyl) hafnium dichloride, methyl phenyl methyl Silyl bis (4,7 - dimethyl-indenyl) hafnium dimethyl, ethylene bis (4,7 - dimethyl-indenyl) dichloride Hafnium, ethylenebis (4,7 - dimethyl-indenyl) hafnium dimethyl, methylene bis (4,7 - dimethyl-indene Yl) hafnium dichloride, methylene bis (4,7 - dimethyl-indenyl) hafnium dimethyl. ...

The most preferred material is a racemic substance following variants: dimethylsilyl bis (indenyl) Zirconium dichloride, dimethylsilyl bis (indenyl) zirconium dimethyl ethylene bis (indenyl) dichloride Zirconium, ethylenebis (indenyl) zirconium dimethyl, dimethylsilyl bis (indenyl) hafnium dichloride, di Dimethylsilyl bis (indenyl) hafnium dimethyl, ethylene bis (indenyl) hafnium dichloride, ethylene bis (Indenyl) hafnium dimethyl, dimethylsilyl bis (tetrahydro-indenyl) zirconium dichloride, dimethyl silyl Alkyl bis (tetrahydro-indenyl) zirconium dimethyl, ethylenebis (tetrahydroindenyl) zirconium dichloride, ethylenebis (Tetrahydro-indenyl) zirconium dimethyl dimethylsilyl bis (tetrahydro-indenyl) hafnium dichloride, dimethyl Silyl bis (tetrahydro-indenyl) hafnium dimethyl, ethylene bis (tetrahydro-indenyl) hafnium dichloride, ethylene Bis (tetrahydro-indenyl) hafnium dimethyl, dimethyl silyl bis (2 - methyl-indenyl) zirconium dichloride, Dimethylsilyl bis (2 - methyl-indenyl) zirconium dimethyl, ethylenebis (2 - methyl-indenyl) dichloride Zirconium, ethylenebis (2 - methyl-indenyl) zirconium dimethyl, dimethylsilyl bis (2 - methyl-indene Yl) hafnium dichloride, dimethyl silyl bis (2 - methyl-indenyl) hafnium dimethyl, ethylene bis (2 - Methyl-indenyl) hafnium dichloride and ethylenebis (2 - methyl-indenyl) hafnium dimethyl. ...

The most preferred material is a racemic substance following variants: dimethylsilyl bis (indenyl) Zirconium dichloride, dimethylsilyl bis (indenyl) zirconium dimethyl ethylene bis (indenyl) dichloride Zirconium, ethylenebis (indenyl) zirconium dimethyl, dimethylsilyl bis (indenyl) hafnium dichloride, di Dimethylsilyl bis (indenyl) hafnium dimethyl, ethylene bis (indenyl) hafnium dichloride, ethylene bis (Indenyl) hafnium dimethyl, dimethylsilyl bis (tetrahydro-indenyl) zirconium dichloride, dimethyl silyl Alkyl bis (tetrahydro-indenyl) zirconium dimethyl, ethylenebis (tetrahydroindenyl) zirconium dichloride, ethylenebis (Tetrahydro-indenyl) zirconium dimethyl dimethylsilyl bis (tetrahydro-indenyl) hafnium dichloride, dimethyl Silyl bis (tetrahydro-indenyl) hafnium dimethyl, ethylene bis (tetrahydro-indenyl) hafnium dichloride, ethylene Bis (tetrahydro-indenyl) hafnium dimethyl, dimethyl silyl bis (2 - methyl-indenyl) zirconium dichloride, Dimethylsilyl bis (2 - methyl-indenyl) zirconium dimethyl, ethylenebis (2 - methyl-indenyl) dichloride Zirconium, ethylenebis (2 - methyl-indenyl) zirconium dimethyl, dimethylsilyl bis (2 - methyl-indene Yl) hafnium dichloride, dimethyl silyl bis (2 - methyl-indenyl) hafnium dimethyl, ethylene bis (2 - Methyl-indenyl) hafnium dichloride and ethylenebis (2 - methyl-indenyl) hafnium dimethyl. ...¹H or¹³C NMR can be used to determine which transition Metal compounds are compatible.

These transition metal compounds used for the same activator is preferred, however, can be set Using two different co-activators, such as non-coordinating anion activator and an aluminoxane. If one or More transition metal compounds containing not hydride, hydrocarbyl or substituted hydrocarbyl group of X₁Or X₂Ligands, Should be in the inclusion of non-coordinating anion activator alumoxane prior to the transition metal compound.

The transition metal compound is particularly preferred combination comprises:

(1)Me ₂Si(Me ₄C ₅)(N-c-C ₁₂H ₂₃)TiCl ₂And rac-Me₂Si(2-Me-4-PhInd) ₂ ZrCl ₂(2-Me-4-PhInd = 2 - methyl - 4 - phenyl-indenyl group, c-C₁₂H ₂₃= Ring dodecyl, Me₄C ₅- Tetramethyl-cyclopentadienyl), aluminoxane such as methylaluminoxane or modified methylaluminoxane Activity Technology;

(2)Me ₂Si(Me ₄C ₅)(N-c-C ₁₂H ₂₃)TiMe ₂And rac-Me₂Si(2-Me-4-PhInd) ₂ ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or Triphenylphosphonium tetrakis (pentafluorophenyl) boron activator;

(3)Me ₂Si(Me ₄C ₅)(N-c-C ₁₂H ₂₃)TiCl ₂And rac-Me₂Si(2-MeInd) ₂ZrCl ₂(2-MeInd = 2 - methyl - indenyl), such as methyl alumoxane or modified alumoxane methylaluminoxane Alkyl activation;

(4)Me ₂Si(Me ₄C ₅)(N-c-C ₁₂H ₂₃)TiMe ₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or Triphenylphosphonium tetrakis (pentafluorophenyl) boron activator;

(5)Me ₂Si(Me ₄C ₅) (N-1-adamantyl) TiCl₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(6)Me ₂Si(Me ₄C ₅) (N-1-adamantyl) TiMe₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl Yl) boron or triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(7)Me ₂Si(Me ₄C ₅) (N-1-adamantyl) TiCl₂And rac-Me₂Si(2-MeInd) ₂ ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(8)Me ₂Si(Me ₄C ₅) (N-1-adamantyl) TiMe₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or Triphenylphosphonium tetrakis (pentafluorophenyl) boron activator;

(9)Me ₂Si(Me ₄C ₅) (N-t-butyl) TiCl₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(10)Me ₂Si(Me ₄C ₅) (N-tert-butyl) TiMe₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl Yl) boron or triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(11)Me ₂Si(Me ₄C ₅) (N-t-butyl) TiCl₂And rac-Me₂Si (2-MeInd), with Aluminoxane such as methylaluminoxane or modified methylaluminoxane activating;

(12)Me ₂Si(Me ₄C ₅) (N-tert-butyl) TiMe₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or Triphenylphosphonium tetrakis (pentafluorophenyl) boron activator;

(13)Me ₂Si(Me ₄C ₅) (N-outside - norbornyl) TiCl₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(14)Me ₂Si(Me ₄C ₅) (N-outer - norbornyl) TiMe₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) Boron or triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(15)Me ₂Si(Me ₄C ₅) (N-outside - norbornyl) TiCl₂And rac-Me₂Si(2-MeInd) ₂ ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(16)Me ₂Si(Me ₄C ₅) (N-outer - norbornyl) TiMe₂And rac-Me₂Si(2- MeInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) Boron or triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(17)(p-Et ₃SiPh) ₂C(Cp)(3，8-di-t-BuFlu)HfCl ₂And rac-Me₂Si(2- Me-4-PhInd) ₂ZrCl ₂(3,8-di-t-BuFlu = 3,8 - II - tert-butyl fluorenyl, Cp = cyclopentadienyl Diene-based), such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(18)(p-Et ₃SiPh) ₂C(Cp)(3，8-di-t-BuFlu)HfMe ₂And rac-Me₂Si (2-Me-4-PhInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetra (Pentafluorophenyl) boron or triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(19)(p-Et ₃SiPh) ₂C(Cp)(3，8-di-t-BuFlu)HfCl ₂And rac-Me₂Si(2- MeInd) ₂ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(20)(p-Et ₃SiPh) ₂C(Cp)(3，8-di-t-BuFlu)HfMe ₂And rac-Me₂Si(2- MeInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl Yl) boron or triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(21) meso-CH₂CH ₂(Ind) ₂ZrCl ₂And rac-Me₂Si(H ₄Ind) ₂ZrCl ₂(Ind = Indenyl, H₄Ind = tetrahydroindenyl), such as methyl alumoxane or modified alumoxane methylaluminoxane Alkyl activation;

(22) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-Me₂Si(H ₄Ind) ₂ZrMe ₂With Non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or triphenylcarbenium Tetrakis (pentafluorophenyl) boron activator;

(23) meso-CH₂CH ₂(Ind) ₂ZrCl ₂And rac-Me₂Si(2-MeInd) ₂ZrCl ₂, Aluminoxane such as methylaluminoxane or modified methylaluminoxane activating;

(24) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or triphenyl Tetrakis (pentafluorophenyl) boron activator;

(25) meso-Me₂Si(Ind) ₂ZrCl ₂And rac-Me₂Si(H ₄Ind) ₂ZrCl ₂, Aluminum Alumoxane such as methyl alumoxane or modified methyl alumoxane activator;

(26) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-Me₂Si(H ₄Ind) ₂ZrMe ₂, With a non- Coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or triphenylcarbenium tetrakis (Pentafluorophenyl) boron activator;

(27) meso-Me₂Si(Ind) ₂ZrCl ₂And rac-Me₂Si(2-MeInd) ₂ZrCl ₂With Aluminoxane such as methylaluminoxane or modified methylaluminoxane activating;

(28) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or triphenyl Tetrakis (pentafluorophenyl) boron activator;

(29) meso-Me₂Si(2-MeInd) ₂ZrCl ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(30) meso-Me₂Si(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) Boron or triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(31) meso-Me₂Si(2-MeInd) ₂ZrCl ₂And rac-Me₂Si(2-MeInd) ₂ ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(32) meso-Me₂Si(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or Triphenylphosphonium tetrakis (pentafluorophenyl) boron activator;

(33) meso-CH₂CH ₂(2-MeInd) ₂ZrCl ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(34) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) Boron or triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(35) meso-CH₂CH ₂(2-MeInd) ₂ZrCl ₂And rac-Me₂Si(2-MeInd) ₂ ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(36) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or Triphenylphosphonium tetrakis (pentafluorophenyl) boron activator;

(37) meso-Me₂Si(2-Me-4-PhInd) ₂ZrCl ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(38) meso-Me₂Si(2-Me-4-PhInd) ₂ZrMe ₂And rac-Me₂Si(2-Me- 4-PhInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl Yl) boron or triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(39) meso-CH₂CH ₂(2-Me-4-PhInd) ₂ZrCl ₂And rac-CH₂CH ₂(2-Me- 4-PhInd) ₂ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(40) meso-CH₂CH ₂(2-Me-4-PhInd) ₂ZrMe ₂And rac-CH₂CH ₂(2-Me- 4-PhInd) ₂ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl Yl) boron or triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(41) meso-CH₂CH ₂(2-MeInd) ₂ZrCl ₂And rac-CH₂CH ₂(2-MePhInd) ₂ ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(42) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-CH₂CH ₂(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or Triphenylphosphonium tetrakis (pentafluorophenyl) boron activator;

(43) meso-CH₂CH ₂(Ind) ₂ZrCl ₂And rac-CH₂CH ₂(Ind) ₂ZrCl ₂, Aluminum Alumoxane such as methyl alumoxane or modified methyl alumoxane activator;

(44) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-CH₂CH ₂(Ind) ₂ZrMe ₂, With a non- Coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or triphenylcarbenium tetrakis (Pentafluorophenyl) boron activator;

(45) meso-Me₂Si(Ind) ₂ZrCl ₂And rac-Me₂Si(Ind) ₂ZrCl ₂, Aluminum Alumoxane such as methyl alumoxane or modified methyl alumoxane activator;

(46) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-Me₂Si(Ind) ₂ZrMe ₂, With a non- Coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or triphenylcarbenium tetrakis (Pentafluorophenyl) boron activator;

(47) meso-CH₂CH ₂(Ind) ₂ZrCl ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ZrCl ₂ (4，7-Me ₂Ind = 4,7 - dimethyl-indenyl), such as methyl alumoxane or modified methyl aluminoxane Base Aluminoxanes activation;

(48) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or Triphenylphosphonium tetrakis (pentafluorophenyl) boron activator;

(49) meso-Me₂Si(Ind) ₂ZrCl ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator;

(50) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or Triphenylphosphonium tetrakis (pentafluorophenyl) boron activator;

(51) meso-CH₂CH ₂(2-MeInd) ₂ZrCl ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrCl ₂(4，7-Me ₂Ind = 4,7 - dimethyl-indenyl), such as methyl alumoxane or modified alumoxane Activation of methylaluminoxane;

(52) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or Triphenylphosphonium tetrakis (pentafluorophenyl) boron activator;

(53) meso-Me₂Si(2-MeInd) ₂ZrCl ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrCl ₂, Such as methyl alumoxane or modified methyl aluminoxane alumoxane activator; and

(54) meso-Me₂Si(2-MeInd) ₂ZrMe ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrMe ₂, With a non-coordinating anion activators such as N, N-dimethylaniline tetrakis (pentafluorophenyl) boron or Triphenylphosphonium tetrakis (pentafluorophenyl) boron activators.

These two transition metal compound (catalyst precursor) may be used in any proportion. Production of non- Amorphous polymer (A) of the transition metal compound and the production of crystalline polymer (B) a transition metal The preferred molar ratio of compounds falling within the following ranges: (A: B) 1:1000 to 1000:1, or 1:100 to 500:1, or from 1:10 to 200:1 to 100:1 or 1:1, or 1:1 to 75:1, or 5:1 to 50:1. Select a specific ratio depends on the selected specific catalytic precursor Agents, activation methods, and the desired end product. In specific embodiments, when two Catalyst precursor (A-"producing an amorphous polymer precursor catalyst" and B-"Production crystalline polyolefin Compound catalyst "), one of the same Activator both preferred molar percentages The molecular weight of the precursor catalyst at 10 to count less than 0.1至99.9% A 90% B, or 25 to Less than 0.5至99% A 50% B, 99% A or 50 to less than 1至25% B, 99% A or 75 to Less than 1至10% B. ...

In another preferred embodiment, the third catalyst (catalyst precursor with activator) Present in the above method. The third catalyst is listed here either precursor catalyst component. A third preferred catalyst precursor which includes the ability to produce wax. Preferred examples include: Rac - dimethylsilyl bis (4,7 - dimethyl-indenyl) hafnium dichloride, rac - dimethyl Silyl bis (4,7 - dimethyl-indenyl) hafnium dimethyl, rac - dimethylsilyl bis (4,7 - dimethyl-indenyl) zirconium dichloride, rac - dimethylsilyl bis (4,7 - dimethyl-indene Yl) zirconium dimethyl racemic - dimethylsilyl bis (indenyl) hafnium dichloride, rac - two Dimethylsilyl bis (indenyl) hafnium dimethyl, racemic - dimethylsilyl bis (indenyl) two Zirconium dichloride, rac - dimethylsilyl bis (indenyl) zirconium dimethyl, rac - dimethylsilyl Silyl bis (tetrahydro-indenyl) hafnium dichloride, rac - dimethylsilyl bis (tetrahydro-indenyl) Hafnium dimethyl, rac - dimethylsilyl bis (tetrahydro-indenyl) zirconium dichloride, rac - two Synthesis of dimethylsilyl bis (tetrahydro-indenyl) zirconium dimethyl, rac - diphenyl silyl bis (4,7 - Dimethyl-indenyl) hafnium dichloride, rac - diphenyl silyl bis (4,7 - dimethyl-indenyl) Hafnium dimethyl, rac - diphenyl silyl bis (4,7 - dimethyl-indenyl) zirconium dichloride, racemic Rotary - diphenyl silyl bis (4,7 - dimethyl-indenyl) zirconium dimethyl, rac - diphenyl silyl Alkyl bis (indenyl) hafnium dichloride, rac - diphenyl silyl bis (indenyl) hafnium dimethyl, Rac - diphenyl silyl bis (indenyl) zirconium dichloride, rac - diphenyl silyl bis (Indenyl) zirconium dimethyl, rac - diphenyl silyl bis (tetrahydro-indenyl) hafnium dichloride, outside Rac - diphenyl silyl bis (tetrahydro-indenyl) hafnium dimethyl, rac - diphenyl silyl Bis (tetrahydro-indenyl) zirconium dichloride, rac - diphenyl silyl bis (tetrahydro-indenyl) dimethyl Zirconium, rac - methylphenyl silyl bis (4,7 - dimethyl-indenyl) hafnium dichloride, rac - Methyl-phenyl silyl bis (4,7 - dimethyl-indenyl) hafnium dimethyl, rac - Methyl - Silyl bis (4,7 - dimethyl-indenyl) zirconium dichloride, rac - methyl-phenyl silyl bis (4,7 - dimethyl-indenyl) zirconium dimethyl, rac - methyl-phenyl silyl bis (indenyl) dichloride Hafnium, rac - methyl-phenyl silyl bis (indenyl) hafnium dimethyl, rac - methylphenyl Silyl bis (indenyl) zirconium dichloride, rac - methyl-phenyl silyl bis (indenyl) dimethyl Group zirconium, rac - methyl-phenyl silyl bis (tetrahydro-indenyl) hafnium dichloride, rac - methyl Diphenylsilyl bis (tetrahydro-indenyl) hafnium dimethyl, rac - methyl-phenyl silyl bis (D Hydrogen indenyl) zirconium dichloride, rac - methyl-phenyl silyl bis (tetrahydro-indenyl) zirconium dimethyl, Rac - ethylene-bis (4,7 - dimethyl-indenyl) hafnium dichloride, rac - ethylene-bis (4,7 - Dimethyl-indenyl) hafnium dimethyl, rac - ethylene-bis (4,7 - dimethyl-indenyl) zirconium dichloride, Rac - ethylene-bis (4,7 - dimethyl-indenyl) zirconium dimethyl, rac - ethylene-bis (indenyl) Hafnium dichloride, rac - ethylene-bis (indenyl) hafnium dimethyl, rac - ethylene-bis (indenyl) Zirconium dichloride, rac - ethylene-bis (indenyl) zirconium dimethyl, rac - ethylene bis (tetrahydro- Indenyl) hafnium dichloride, rac - ethylene bis (tetrahydro-indenyl) hafnium dimethyl, rac - ethylene Bis (tetrahydro-indenyl) zirconium dichloride, and rac - ethylene-bis (tetrahydroindenyl) zirconium dimethyl. ...

Another preferred catalysts and methods described in US6, 376,410 and 6,380,122, which These patents are incorporated herein by reference.

In another embodiment, the present invention is a catalyst composition comprising a support material or carrier. For example, one or more catalyst components and / or one or more active agent is deposited on to one or Multiple load substances or carriers, or in contact with, together with evaporated to their bonding, or cause Into them, adsorption, or absorbed therein or thereon.

Load material for either a conventional load material. The preferred support material is a porous support material, Such as talc, inorganic oxides and inorganic chlorides. Other support materials include resin materials such as load Polystyrene, functionalized or crosslinked organic supports such as polystyrene divinyl benzene polyolefins or poly Co-type compounds, zeolites, clays, or any other organic or inorganic support materials, etc., or mixtures Thereof.

Preferred support materials are inorganic oxides including 2,3,4,5,13 or 14 of that These metal oxides. Preferred carriers include dehydration or dehydration may be silica, fumed Silica, alumina (WO99/60033), a silicon - aluminum oxide and mixtures thereof. Other useful Supports include magnesia, titania, zirconia, magnesium chloride (US5, 965,477), montmorillonite Stone (EP-B 1 0 511 665), phyllosilicate, zeolites, talc, clay (US6, 034,187) And so on. These loads can also use combinations of materials such as silica - chromium, silica - Oxidation Alumina, silica - titania. Additional support materials may include EP 0 767 184 B1 Those described in the porous acrylic polymer, the paper is incorporated herein by reference. Other negative Containing materials include WO 99/47598 describes nanocomposites, WO 99/48605 describes Airgel, US5, 972,510 and spherulites as described WO 99/50311 describes a polymer Beads, these references are incorporated herein by reference. ...

Preferred support materials are inorganic oxides including 2,3,4,5,13 or 14 of that These metal oxides. Preferred carriers include dehydration or dehydration may be silica, fumed Silica, alumina (WO99/60033), a silicon - aluminum oxide and mixtures thereof. Other useful Supports include magnesia, titania, zirconia, magnesium chloride (US5, 965,477), montmorillonite Stone (EP-B 1 0 511 665), phyllosilicate, zeolites, talc, clay (US6, 034,187) And so on. These loads can also use combinations of materials such as silica - chromium, silica - Oxidation Alumina, silica - titania. Additional support materials may include EP 0 767 184 B1 Those described in the porous acrylic polymer, the paper is incorporated herein by reference. Other negative Containing materials include WO 99/47598 describes nanocomposites, WO 99/48605 describes Airgel, US5, 972,510 and spherulites as described WO 99/50311 describes a polymer Beads, these references are incorporated herein by reference. ...²/ g, a pore volume of about 0.1 to about 4.0cc / g and an average particle size of about 5 to about 500μm. More preferably the surface area of the support material is from about 50 to about 500m²/ g, a pore volume of about 0.5 to about 3.5cc / g and an average particle size of about 10 to about 200μm. The most preferred support material surface About 100 to about 400m²/ g, a pore volume of about 0.8 to about 3.0cc / g and a mean particle size About 5 to about 100μm. Vectors of the invention can be used in the average pore size is usually 10 to 1000 Å, preferably 50 to 500 Angstroms and most preferably about 75 to about 350 Angstroms.

As is known in the art, together with the load to the catalyst can be an inert carrier, or Independently or two catalyst loading and mixing an inert carrier. In both methods, preferably Former method

In another embodiment, the carrier comprises one or more types of different treatment can be negative Containing materials. For example, can be used with different pore sizes or calcined at two different temperatures without With silica. Also useful is a scavenger of the treated silica or other additives and are not Treated silica.

Stereospecific catalysts for the preparation of Mw100, 000 or less, and crystallinity 30% Or more, and preferably a macromonomer having a vinyl end.

As a specific example, a process having a high percentage of vinyl terminal bonds based on C Ene macromonomer method involves:

a) in the solution will be propylene, a small amount of non-essential copolymerizable monomer containing activated stereorigid The transition metal catalyst compound in the catalyst composition to a temperature of about 80 ℃ then under about 140 ℃ Touch; and

b) recovering having a number average molecular weight of about 2,000 to about 30,000 daltons, isotactic or syndiotactic Polypropylene chains.

Solution preferably include hydrocarbon solvents, the hydrocarbon solvent is more preferably an aliphatic or aromatic solvents. Furthermore, Propylene monomer is preferably at temperature of 90 ℃ to 120 ℃ lower contact. More preferably to a temperature 95 ℃ 115 ℃. Most preferably propylene monomer at a temperature of 100 ℃ to 110 ℃ lower contact. Reactor pressure through Often preferably atmospheric pressure to 345MPa to 182MPa vary. Reaction can be batch or continuous Manner. Suitable slurry-type reaction conditions are also suitable and similar conditions with the solution, poly Together generally in a suitable pressure of the polymerization carried out in liquid propylene.

Catalyst selection criteria which have already been discussed. A catalyst is typically a Produced significant amount of vinyl-terminated macromonomer capacity stereospecific catalyst, other Generally for a particular species can be introduced and macromolecular monomer. Generally, it is believed that C₂Symmetrical huge Ligand metallocene catalyst to produce vinyl-terminated macromonomers isotactic polypropylene. Help The elimination of methyl β catalysts generally contribute to the formation of isotactic polypropylene appear macromer. Rac - dimethylsilyl bis (indenyl) hafnium dimethyl, dimethylsilyl bis (2 - methyl- -4 - Phenyl-indenyl) zirconium dichloride, and rac - ethylene-bis (4,7 - dimethyl-indenyl) dimethyl Hafnium is used in the present invention can be produced having a high vinyl chain ends of isotactic polypropylene and catalytic Agent. Temperature, usually higher than 80 ℃, show beneficial effects of vinyl-terminated. Furthermore, Me₂Si(Me ₄C ₅)(N-c-C ₁₂H ₂₃)TiMe ₂And Me₂Si(Me ₄C ₅)(N-c-C ₁₂H ₂₃)TiMe ₂Production may be used in the present invention. The amorphous polypropylene, and it is believed that the introduction of vinyl-terminated macromonomer, thereby producing the same In the amorphous side of the main chain of grafting scPP structure.

In another embodiment, the diene such as 1,9 - decadiene introduced into the reaction section to promote the raw Producing vinyl-terminated macromonomer aPP and scPP, helps increase the macromonomer branch - The total amount of the block material.

Polymerization

The catalysts and catalyst systems suitable for solution, bulk, gas or slurry polymerization process Or a combination thereof, preferably solution phase, bulk phase polymerization process.

In one embodiment the present invention relates to a solution, bulk, slurry or gas phase polymerization, Involving the polymerization of one or more having 3 to 30 carbon atoms, preferably 3-12 carbon atoms, more Preferably 3 to 8 carbon atoms in the monomer. Preferred monomers include one or more of: C Ene, butene-1, pentene-1 - methyl - pentene-1, hexene-1, octene-1, decene-1 - Methyl - pentene-1 and cyclic olefins or a combination thereof. Other monomers can include vinyl monomers, diolefins Hydrocarbons such as dienes, polyenes, norbornene, norbornadiene, vinyl norbornene, ethylidene-drop Norbornene monomer. Preferably propylene homopolymer or copolymer. In another embodiment, While the production of propylene homopolymers and copolymers of propylene with one or more of the above listed monomers. ...

This invention can be used in series or in parallel with one or more reactors. It is believed that the catalyst component And the activator solution or slurry form, or may be separately fed into the reactor and was about to enter the Line into the reactor before the activation, or to activate the pre-activation and the formation of a solution or slurry is pumped into Reactor. The preferred action is the activation of the two solutions online. Catalyst for the introduction of anti-multiple The method of the reactor for more information, see US 6,399,722 and WO0130862A1. Despite These documents may emphasize the gas phase reactor, but the techniques described also apply to other reactors Types, including continuous stirred tank reactors, slurry loop reactors. The polymerization or in the single For reactor operation, in which the monomers, comonomers, catalyst / activator, scavenger And non-essential modifier single reactor continuously, or in series reactor operation the Carried out, in which the above components were added in series connection of the two or more reactors each reactor Medium. The catalyst components may be added to the reactor in series a first reactor. Catalyst component May also be added to the two reactors, wherein one component is added to the first reactor, and the other The other components were added outside the reactor. ...

Gas phase polymerization

Generally, in a gas fluidized bed used in the production method of the polymer, containing one or more single The body of the gas stream in the presence of a catalyst under reaction conditions a continuous loop through the bed. The gas Flow discharged from the fluidized bed and recycled into the reactor. At the same time, the polymer product from the reaction Unloading vessel and adding fresh monomer is substituted polymerizable monomers (see for example US4, 543,399, 4,588,790,5,028,670,5,317,036,5,352,749,5,405,922,5,436,304, 5,453,471,5,462,999,5,616,661 and 5,668,228, all of which this In entirety by reference. )

Slurry phase polymerization

Slurry polymerization is generally in the range of 1 to about 50 atmospheres (15psi to 735psi, 103kPa To 5068kPa) or even greater pressure and temperature 0 ℃ to about 120 ℃ temperature. In slurry polymerization Together, to which the monomer, comonomer and the catalyst is formed in a liquid polymerization diluent medium A suspension of solid particulate polymer. The suspension including diluent from the reactor intermittently or continuously Out, wherein the volatile components separated from the polymer, is not required in the distillation after Recycled to the reactor. Used in the polymerization medium is typically a liquid diluent having 3-7 Alkane carbon atoms, preferably a branched alkane. Polymerization medium used should be a liquid under the reaction conditions And relatively inert. When a propane medium is used, the method must be above the reaction diluent critical Operating temperature and pressure. Preferably hexane or isobutane media. ...

In one embodiment, the polymer used in the present invention, a preferred technique involves particles of poly Together, or slurry, wherein the temperature is kept below the temperature of the polymer into solution. The technology is Known in the art and are described in US 3,248,179, this document is incorporated herein by reference. Method in particle form preferred temperature is about 85 ℃ to about 110 ℃. Two for the slurry process The preferred polymerization method is to use a loop reactor and the use of series, parallel or a combination thereof a plurality of mixing Which mixed reactor. Slurry Non-limiting examples include continuous loop or stirred tank method. In addition, other examples of slurry processes are described in US4, 613,484, this document is incorporated herein by Reference. ...

The reactor was maintained at a pressure and a temperature of about 3620kPa to 4309kPa to about 60 ℃ 104 ℃ lower, depending on the desired polymer melting characteristics. Reaction heat removal through the loop wall, because The reactor is double jacketed many forms. Slurry at regular intervals or continuous flow reactor, Sequentially into the heated low pressure flash vessel, rotary dryer and a nitrogen purge column to remove iso Butane diluent and all unreacted monomer and comonomers. The resulting powder was then compounded hydrocarbon- For a variety of applications.

The reactor was maintained at a pressure and a temperature of about 3620kPa to 4309kPa to about 60 ℃ 104 ℃ lower, depending on the desired polymer melting characteristics. Reaction heat removal through the loop wall, because The reactor is double jacketed many forms. Slurry at regular intervals or continuous flow reactor, Sequentially into the heated low pressure flash vessel, rotary dryer and a nitrogen purge column to remove iso Butane diluent and all unreacted monomer and comonomers. The resulting powder was then compounded hydrocarbon- For a variety of applications....

In another embodiment, in the slurry used in the present invention method, the total reactor pressure of 400 psig (2758kPa) to 800psig (5516kPa), preferably 450psig (3103kPa) To about 700psig (4827kPa), and more preferably 500psig (3448kPa) to about 650psig (4482 kPa), most preferably about 525psig (3620kPa) to 625psig (4309kPa).

In a further embodiment, in the slurry used in the present invention method, the predominant monomer in the reactor Liquid medium to a concentration of from about 1 10wt%, preferably from about 2 to about 7wt%, more preferably about 2.5 to about 6wt%, most preferably from about 3 to about 6wt%.

Another method used in the present invention is a method, wherein the method, the slurry is preferably Lack of or substantially free of any scavengers, such as triethylaluminum, trimethylaluminum, triisobutylaluminum and tri- Hexyl aluminum and diethyl aluminum chloride, dibutyl zinc and the like from under operation. This method is described in WO 96/08520 and US5, 712,352, the documents incorporated herein by reference.

In another embodiment, the method is carried out in the presence of a scavenger. Typical scavenger packet Include trimethyl aluminum and tri-isobutyl aluminum and an excess of alumoxane or modified alumoxane.

Homogeneous, bulk or solution phase polymerization

The catalyst described herein can be advantageously used in homogeneous solution polymerization. This usually involves even Continued polymerization reactor, in which the polymer formed and the addition of the starting monomers and the catalyst timber Stirring material to reduce or avoid concentration gradients. Appropriate methods above the melting point of the polymer 1-3000 bar (10-30,000 MPa) under a high pressure, wherein the monomer diluent for play Or in solution with the solvent used in the polymerization.

Temperature control of the reactor obtained according to the following: by using a reactor jacket or cooling coil cooling The reaction is cooled reactor materials, auto refrigeration, pre-cooling material, evaporating the liquid medium (dilute Release agent, the monomer or solvent) or combinations of these three balancing the heat of polymerization. Can also be used to join the pre- The adiabatic reactor cooling material. The reactor temperature depends on the catalyst. Typically, the reactor Temperature may preferably be about 30 ℃ to about 160 ℃, more preferably from about 90 ℃ to about 150 ℃, most preferably from about 100 ℃ to about 140 ℃. The polymerization temperature can vary depending on the catalyst selected. For example, two imine N i catalyst may be used under 40 ℃, and titanium metallocene catalyst may be 100 ℃ or higher temperature to Purposes. In series operation, the second reactor temperature is preferably higher than the first reactor temperature. In parallel Reactor operation, the temperature of the two reactors are independent. This pressure may be about 1mmHg to 2500 bar (25,000 MPa), preferably from 0.1 bar to 1600 bar (1-16,000 MPa), the optimal Select from 1.0 to 500 bar (10-5000MPa). ...

Each of these methods can be in a single reactor, parallel or series reactor configuration manipulation Purposes. Method comprises a liquid olefin monomer with the catalyst system in a suitable diluent or solvent Into contact, and to the reaction of the monomer sufficient time, thereby producing the desired polymer. Aliphatic And aromatic hydrocarbon solvents are suitable. Preferably alkanes such as hexane, pentane, isopentane, and octane.

Each of these methods can be in a single reactor, parallel or series reactor configuration manipulation Purposes. Method comprises a liquid olefin monomer with the catalyst system in a suitable diluent or solvent Into contact, and to the reaction of the monomer sufficient time, thereby producing the desired polymer. Aliphatic And aromatic hydrocarbon solvents are suitable. Preferably alkanes such as hexane, pentane, isopentane, and octane....

1) the monomers, non-essential solvent, the catalyst and the activator with the reactor system,

2) from the reactor system, the polymer solution is discharged,

3) from the polymer solution to remove at least 10% of the solvent (if present),

4) quenching the reaction,

5) The polymer solution was devolatilized molten polymer is formed,

6) the molten polymer and one or more additives (which as described below) in a mixing Device such as a static mixer together with, (in the preferred embodiment, the tackifier is not added, or The addition amount is less than 30wt%, preferably less than 20wt%, more preferably less than 10wt%),

7) The polymer was removed from the mixer and conjugates, and

8) the polymer conjugates or drum granulation process (drumming);

Wherein step 1) comprises any of the above methods.

In another embodiment, the present invention relates to a continuous process for preparing a binder, comprising:

1) the monomers, non-essential solvent, the catalyst and the activator are mixed in the reactor system,

2) discharged from the reactor system, the polymer solution,

4) quenching the reaction,

5) The polymer solution was devolatilized molten polymer is formed,

6) the molten polymer and one or more additives in a mixer such as a static mixer Results Together,

7) The polymer was removed from the mixer and conjugates, and

8) the polymer conjugates or drum granulation process.

In a particularly preferred embodiment, the present invention relates to a process for preparing a continuous adhesive side Method, comprising:

1) Select the first catalyst component, the catalyst component is capable of polymerization conditions in the selected xiasheng Produced with Mw 100,000 or less and a crystallinity of 20% or less of the polymer;

2) Select the second catalyst component, the catalyst component is capable of polymerization conditions in the selected xiasheng Produced with Mw 100,000 or less and a crystallinity of 40% or more of the polymer;

3) These catalyst components in the selected solvent in the polymerization reaction zone under conditions In one or more of the activating agent in the presence of one or more C3 to C40 olefins and a non-essential Dienes or more kinds of exposure;

4) at a temperature higher than 100 ℃ lower;

5) the dwell time of 120 minutes or less (preferably 60 to 120 minutes) following;

6) wherein the first catalyst and the second catalyst ratio of 1:1 to 50:1;

7) in which the activity of the catalyst component is at least 50kg g polymer / g catalyst component; and its At least 20% of the conversion of the olefin polymer;

8) discharged from the reaction zone of the polymer solution;

9) from the polymer solution to remove at least 10% of the solvent;

10) the reaction was quenched;

11) The devolatilized polymer solution to form a molten polymer;

12) the molten polymer and one or more additives in a mixer such as a static mixer Results Together,

13) The polymer was removed from the mixer and conjugates, and

14) The polymer conjugate or drum granulation process.

3) These catalyst components in the solvent in the reaction zone under polymerization conditions in the selected In one or more of the activating agent in the presence of one or more C3 to C40 olefins and a non-essential Dienes or more kinds of exposure;

4) at a temperature higher than 100 ℃ lower;

5) the residence time of 120 minutes or less under;

6) wherein the first catalyst and the second catalyst ratio of 1:1 to 50:1;

7) in which the activity of the catalyst component is at least 50kg g polymer / g catalyst component; and its At least 50% conversion of the olefin polymer;

8) discharged from the reaction zone of the polymer solution;

9) from the polymer solution to remove at least 10% of the solvent;

10) the reaction was quenched;

11) forming a molten polymer;

Wherein the polymer comprises one or more C3 to C40 olefins and less than 50mol% of ethylene, And wherein the polymer has:

a) Point T-peel force a Newton or higher; and

b) a branching index (g ') 0.95 or lower, the polymer had an Mz measurement; and

c) Mw 100,000 or less; and

13) The polymer was removed from the mixer and conjugates, and

14) The polymer conjugate or drum granulation process.

4) at a temperature higher than 100 ℃ lower;

5) the residence time of 120 minutes or less under;

6) wherein the first catalyst and the second catalyst ratio of 1:1 to 50:1;

8) discharged from the reaction zone of the polymer solution;

9) from the polymer solution to remove at least 10% of the solvent;

10) the reaction was quenched;

11) forming a molten polymer;

Wherein the polymer comprises one or more C3 to C40 olefin (preferably propylene), and less than 50 mol% of ethylene, and wherein the polymer has:

a) point T-peel strength 3 Newton or greater; and

b) a branching index (g ') 0.90 or lower, the polymer had an Mz measurement; and

c) Mw 30,000 or less;

d) the peak melting point 60 至 190 ℃,

e) heat of fusion of 1 to 70J / g,

f) at a melt viscosity of 190 ℃ 8000mPa · sec or less; and

13) The polymer was removed from the mixer and conjugates, and

14) The polymer conjugate or drum granulation process.

1) the monomer, the catalyst and the activator with the reactor system,

2) discharged from the reactor system of the polymer,

3) quenching the reaction,

4) forming a molten polymer,

5) the molten polymer is combined with one or more additives,

6) the polymer conjugates or drum granulation process.

Polymer Ingredients

Here the production of the polymer can be directly used as a binder or blended with other components to form an adhesive Agent.

The polymers of the invention generally do not need to use a tackifier. However, if necessary thickener, can Combining the polymer with a tackifier commonly used in the art which. Examples include, but are not Is limited to aliphatic hydrocarbon resins, aromatic modified aliphatic hydrocarbon resins, hydrogenated dicyclopentadiene resins, poly cyclopentyl Diene resins, gum rosin (gum rosin), gum rosin esters, wood rosin, wood rosin esters, Tall oil rosin, tall oil rosin esters, polyterpenes, aromatic modified polyterpenes, terpene phenol, modified aromatic hydrogen Of dicyclopentadiene resins, hydrogenated aliphatic resin, hydrogenated aliphatic aromatic resins, hydrogenated terpenes and modified Terpenes, and hydrogenated rosin esters. In some embodiments, the tackifier is hydrogenated. In other embodiments, Case, the tackifier is non-polar. (Non-polar tackifier is substantially free of polar groups Monomers. There is preferably a polar group, however, if present, they are preferably up to 5wt %, Preferably not more than 2wt%, still more preferably not more than 0.5wt%). In some embodiments, Case, tackifier having a softening point (Ring & Ball method, measured in accordance with ASTM E-28) 80 ℃ to 150 ℃, preferably from 100 ℃ to 130 ℃. ...

Or as a tackifier is preferably a hydrocarbon resin modifier include:

1 C5/C6 terpene resins such as resins, terpene styrene, α-methyl styrene terpene resins, C9 terpene Resins, aromatic modified C5/C6, aromatic ring-modified resins, aromatic modified dicyclopentadiene-based tree Fat or mixtures thereof. Another preferred resins include WO 91/07472, US 5,571,867, US 5,171,793 and US4, 078,132 which is described. These resins are generally through cationic poly Co-monomers containing one or more of the following compositions obtained: C5 diolefins (such as 1-3 pentadiene, Isoprene, etc.), C5 olefins (such as 2 - methyl-butene, cyclopentene, etc.), C6 olefins (such as hexene), C9 aromatic vinyl monomers (such as styrene, α-methyl styrene, vinyl toluene, indene, methyl Indene, etc.), cyclic monomer (such as dicyclopentadiene, methyl dicyclopentadiene, etc.), and / or terpenes (such as Limonene, carene, etc). ...

If desired, the polymerization and separation of unreacted materials, the resin obtained after hydrogenation. Preferred Examples of the resin include US 4,078,132, WO 91/07472, US 4,994,516, EP 0 046 344 A, EP 0 082 726 A, and which is described in US 5,171,793.

If desired, the polymerization and separation of unreacted materials, the resin obtained after hydrogenation. Preferred Examples of the resin include US 4,078,132, WO 91/07472, US 4,994,516, EP 0 046 344 A, EP 0 082 726 A, and which is described in US 5,171,793....

In another embodiment, the polymer product of the present invention comprises a binder composition further Include typical additives known in the art such as fillers, antioxidants, additives, adhesion promoters, Oil and / or a plasticizer. Preferred fillers include titanium dioxide, calcium carbonate, barium sulfate, silica, Silica, carbon black, sand, glass beads, mineral aggregates, talc, clay. Preferred Antioxidants include phenolic antioxidants such as Irganox 1010, Irganox 1076, were purchased from Ciba-Geigy. Preferred oils include paraffinic or naphthenic oils such as Primol 3 52 or Primol 876, available from ExxonMobil Chemical France, SAin Paris, France. Preferred plasticizers include polybutenes, such as Parapol 950 and Parapol 1300, available from ExxonMobil Chemical Company in Houston Texas. Other preferred additives Including caking agents, anti-caking agents, pigments, processing aids, UV stabilizers, neutralizers, lubricants, Surfactants and / or nucleating agents may also be present in the film layer and / or more layers. Preferred Additives include silicon dioxide, titanium dioxide, polydimethylsiloxane, talc, dyes, wax, Calcium stearate, carbon black, low molecular weight resins and glass beads. Preferred adhesion promoters include polar Acid, polyamino amide (such as Versamid 115,125 and 140, available from Henkel), carbamoyl Esters such as isocyanate / hydroxyl-terminated polyester systems, such as adhesives TN / Mondur Cb-75 (Miles, Inc.), A coupling agent (such as silane ester (Z-6020, available from Dow Corning), titanate Esters (such as Kr-44, available from Kenrich), reactive acrylate monomer (such as sarbox SB-600, Available from Sartomer), metal salts (such as Saret 633, available from Sartomer), polyphenylene ether, Oxidized polyolefin, an acid-modified polyolefin and an acid anhydride-modified polyolefin. ...

Polymer product of the invention may be combined with other non-essential component is a plasticizer or other Additives such as oils, surface active agents, fillers, the masterbatch. Preferred plasticizers include mineral Oil, polybutene, phthalic acid esters. Particularly preferred plasticizers include phthalic esters such as Undecyl phthalate ester (DIUP), diisononyl phthalate (DINP), o Dioctyl phthalate (DOP) and so on. Particularly preferred oils include aliphatic naphthenic oils.

% E5% 8F% AF% E4% B8% 8E% E6% 9C% AC% E5% 8F% 91% E6% 98% 8E% E8% 81% 9A% E5% 90% 88% E7% 89% A9% E4 % BA% A7% E5% 93% 81% E7% BB% 84% E5% 90% 88% E7% 9A% 84% E5% 85% B6% E5% AE% 83% E9% 9D% 9E% E5% BF % 85% E8% A6% 81% E7% BB% 84% E5% 88% 86% E4% B8% BA% E4% BD% 8E% E5% 88% 86% E5% AD% 90% E9% 87% 8F % E4% BA% A7% E5% 93% 81% E5% A6% 82% 0A% 20% 20% 20% 20% 20% 20% 20% 20% 20% 20% 20% 20% 0A% 09% 09 % 09% 09% E8% 9C% A1% E3% 80% 81% E6% B2% B9% E3% 80% 81% E6% 88% 96% E4% BD% 8EMn% E8% 81% 9A% E5% 90 % 88% E7% 89% A9 (% E4% BD% 8E% E6% 98% AF% E6% 8C% 87Mn% E4% BD% 8E% E4% BA% 8E5000% E3% 80% 81% E4% BC% 98% E9% 80% 89% E4% BD% 8E% E4% BA% 8E4000% E3% 80% 81% E6% 9B% B4% E4% BC% 98% E9% 80% 89% 0A% 20% 20% 20% 20% 20% 20% 20% 20% 20% 20% 20% 20% E4% BD% 8E% E4% BA% 8E3000% E3% 80% 81% E8% BF% 9B% E4% B8% 80% E6% AD% A5% E6% 9B% B4% E4% BC% 98% E9% 80% 89% E4% BD% 8E% E4% BA% 8E2500)% E3% 80% 82% E4% BC% 98% E9 % 80% 89% E7% 9A% 84% E8% 9C% A1% E5% 8C% 85% E6% 8B% AC% E6% 9E% 81% E6% 80% A7% E6% 88% 96% E9% 9D % 9E% E6% 9E% 81% E6% 80% A7% E8% 9C% A1% E3% 80% 81% 0A% 20% 20% 20% 20% 20% 20% 20% 20% 20% 20% 20 % 20% E5% AE% 98% E8% 83% BD% E5% 8C% 96% E8% 9C% A1% E3% 80% 81% E8% 81% 9A% E4% B8% 99% E7% 83% AF % E8% 9C% A1% E3% 80% 81% E8% 81% 9A% E4% B9% 99% E7% 83% AF% E8% 9C% A1% E5% 92% 8C% E8% 9C% A1% E6 % 94% B9% E6% 80% A7% E5% 89% 82% E3% 80% 82% E4% BC% 98% E9% 80% 89% E7% 9A% 84% E8% 9C% A1% E5% 8C % 85% E6% 8B% ACESCOMER^TM101. Preferred functionalized wax comprises alcohols, acids, ketones, acid anhydride-modified wax. Examples of preferred Promoters include a methyl ketone, maleic anhydride or maleic acid-modified wax. Preferred oils include aliphatic naphthenic Oil, white oil and so on. Preferred low Mn polymers include lower α-olefins such as propylene, butene, pentene, Hexene polymers. Particularly preferred polymers include a polybutene Mn of less than 1,000. Another example of the polymer is available from ExxonMobil Chemical Company under the trade name PARAPOL^TM950 products. PARAPOL^TMHaving Mn 950 and 950 at 100 ℃ dynamic Viscosity 220cSt (measured by ASTM D 445) of the liquid polybutene. In some embodiments, Case, the polar and non-polar waxes used together in the same composition.

However, in some embodiments, the wax may not be necessary, and which is less than 5wt%, preferably less than 3wt%, more preferably less than 1wt%, more preferably less than 0.5wt%, based The polymer weight.

In another embodiment, the present invention is a polymer having less than 30wt%, preferably less than 25wt%, preferably less than 20wt%, preferably less than 15wt%, preferably less than 10wt%, preferably Select less than 5wt% of the total combination of any of the foregoing additives, based on weight of polymer and additives Volume.

In another embodiment, the present invention is the production of polymers with elastomers (preferably Elastomers include all natural and synthetic rubbers, including those defined in ASTM D1566). In In a preferred embodiment, the elastic body and the polymer blend of the present invention is produced by the formation of rubber toughening Composition. In a particularly preferred embodiment, the rubber toughened composition of two (or multi-) body System, wherein the rubber is a discontinuous phase and the continuous phase polymer. Preferred examples of elastomer Include the following materials in one or more of: ethylene-propylene rubber, ethylene propylene diene monomer rubber Rubber, chloroprene rubber, styrene block copolymer rubber (including SI, SIS, SB, SBS, SIBS Etc.), butyl rubber, halobutyl rubber, isobutylene and p-alkylstyrene copolymer, isobutyryl Ene with ethylene on the alkyl halide copolymers. The blend can be used with the tackifier and / or other Additive combination. ...

In another embodiment, the present invention for the production of polymer blends with polymers. In excellent Alternate embodiment, the blend of two (or multi-) system, wherein the polyester is a discontinuous phase, And the polymer as the continuous phase.

In another embodiment, the present invention for the production of polymer blends with polymers. In excellent Alternate embodiment, the blend of two (or multi-) system, wherein the polyester is a discontinuous phase, And the polymer as the continuous phase....^TM、ACHIEVES ^TMIn another embodiment, the present invention for the production of polymer blends with polymers. In excellent Alternate embodiment, the blend of two (or multi-) system, wherein the polyester is a discontinuous phase, And the polymer as the continuous phase....^TM. For the production of the mPE homopolymers and copolymers of the catalyst / activator for more information See WO94/26816; WO94/03506; EPA277, 003; EPA 277,004; US5, 153,157; US5, 198,401; US5, 240,894; US5, 017,714; CA1, 268,753; US5, 324,800; EPA 129,368; US 5,264,405; EPA 520,732; WO 92 00333; US5, 096,867; US5, 507,475; EPA 426 637; EPA 573 403; EPA 520 732; EPA 495 375; EPA 500 944; EPA 570 982; WO91/09882; WO94/03506 and US5, 055,438.

. For the production of the mPE homopolymers and copolymers of the catalyst / activator for more information See WO94/26816; WO94/03506; EPA277, 003; EPA 277,004; US5, 153,157; US5, 198,401; US5, 240,894; US5, 017,714; CA1, 268,753; US5, 324,800; EPA 129,368; US 5,264,405; EPA 520,732; WO 92 00333; US5, 096,867; US5, 507,475; EPA 426 637; EPA 573 403; EPA 520 732; EPA 495 375; EPA 500 944; EPA 570 982; WO91/09882; WO94/03506 and US5, 055,438....³. For the production of the mPE homopolymers and copolymers of the catalyst / activator for more information See WO94/26816; WO94/03506; EPA277, 003; EPA 277,004; US5, 153,157; US5, 198,401; US5, 240,894; US5, 017,714; CA1, 268,753; US5, 324,800; EPA 129,368; US 5,264,405; EPA 520,732; WO 92 00333; US5, 096,867; US5, 507,475; EPA 426 637; EPA 573 403; EPA 520 732; EPA 495 375; EPA 500 944; EPA 570 982; WO91/09882; WO94/03506 and US5, 055,438....³), Very low density polyethylene (density 0.90 to less than 0.915g/cm³), Micronesia Density polyethylene (density 0.935 to less than 0.945g/cm³), High density polyethylene (density 0.945 To 0.98g/cm³), Ethylene vinyl acetate, ethylene methyl acrylate copolymers, Poly (methyl methacrylate), or by high pressure radical polymerization method can be any other polymers, polychloroprene Ethylene, polybutene-1, isotactic polybutene, ABS resins, elastomers such as ethylene - propylene rubber (EPR), Vulcanized EPR, EPDM, block copolymer elastomers such as SBS, nylon (polyamide), polycarbonate, PET resins, crosslinked polyethylene, copolymers of ethylene and vinyl alcohol (EVOH), aromatic monomer Materials such as polystyrene, poly-1-esters, having a density of 0.94 to 0.98g/cm³High molecular weight polyethylene Ene, having a density of 0.94 to 0.98g/cm³The low molecular weight polyethylene, the graft copolymer generally Material, polyacrylonitrile homopolymer or copolymers, thermoplastic polyamides, polyacetal, polyethylene fluoride and its It fluorinated elastomers, polyethylene glycols and polyisobutylene.

In a preferred embodiment, the present invention is an olefin polymer, preferably polypropylene of the present invention, Polymer in the blend in an amount, based on the weight of the polymer blend, 10 to 99wt%, preferably 20 to 95wt%, still more preferably at least 30 to 90wt%, further Further more preferably at least 40 to 90wt%, still more preferably at least 50 to 90wt%, further Further more preferably at least 60 to 90wt%, still more preferably at least 70 to 90wt%.

The blends can be produced by the following method: the mixing together of two or more polymers, Together through the series of reactors or reactor blend was prepared in the same reactor, by Using more than one catalyst producing a variety of polymers. These polymers can be added to the extruder before a Mixed together or mixed in an extruder.

Can be any of the above polymers (including polymers produced by this invention) functionalized. Preferred Functional groups include maleic acid and maleic anhydride. Means that the polymer is functionalized with an unsaturated acid or Anhydride contacts. Preferred unsaturated acids or anhydrides include at least one double bond and containing at least one carbonyl group, Any unsaturated organic compound. Representative acids include carboxylic acids, anhydrides, esters and other metals and non- Metal salt. Preferably the organic compound contains a carbonyl group (-C = O)-conjugated ethylenic unsaturation. Example Include maleic acid, fumaric acid, acrylic acid, methacrylic acid, itaconic acid, crotonic acid, α-methyl- Crotonic acid, and cinnamic acid is extremely anhydride, ester and salt derivatives. Maleic anhydride is particularly preferred. Unsaturated Acid or anhydride is preferably present in an amount of from about 0.1wt% to about 10wt%, preferably from about 0.5wt% to about 7wt%, still more preferably from about 1 to about 4wt%, based on the hydrocarbon resin and the unsaturated acid or anhydride Weight. ...

Application

In the present invention and claims, the use of the following tests, unless otherwise noted.

Tensile strength

Tensile strength and elongation at break measured according to ASTM D 1708. Elongation at break, also known as Fracture strain or elongation percentage.

Peel strength-ASTM D-1876 (also known as the 180 ° peel adhesion of the strip, 180 ° peel strength, 180 ° peel adhesion, T-shaped - peel strength, T-shaped - peel force).

Dynamic storage modulus (also known as storage modulus) of G '.

Creep Resistance ASTM D-2293

Rolling ball tack (Rolling Ball Tack) PSTC 6

Hot shear strength MYLAR polyester film by self-25mm broadband measurement suspension 1000g weight Volume, the polyester film coated with a polymer or adhesive ingredients, the contact area of 12.5mm × 25mm to With stainless steel plate adhesion. The sample was placed in 40 ℃ ventilated oven, the recording time until the present stress Damage so far.

Probe tack (also known Polyken probe tack) ASTM D 2979

Adhesion (holding power)-PSTC7, also known as the shear bond strength or shear strength.

Density-ASTM D792, measured at 25 ℃.

Gardner color value ASTM D 1544-68.

SAFT also known as heat resistance.

At 100% elongation modulus, tensile strength and Young's modulus measured according to ASTM E-1876.

Luminance of the CIE color coordinates of the reflectance of "Y" (measured by ASTM D 1925) Divided by 100.

The polymer products or ingredients of the invention can be applied directly to the substrate or can be sprayed thereon, Generally the polymer melt. Spraying is defined to include atomizing, such as to produce uniform dot pattern, spiral spraying Coating such as Nordson Controlled Fiberization or oscillating stretched filaments, as in the ITW Dynafiber / Omega heads or Summit technology (from Nordson) carried out, and Melt blown technology. Melt blown techniques are defined to include US5, 145,689 describes a method, or in which Air stream used to break the extrudate filaments, broken filaments then deposited on a substrate of any Methods. Generally, melt-blown technology for the use of air spinning hot melt adhesive fibers and transported to stick The method of co-substrates. By changing the ratio of the melt and the air can easily be controlled fiber size 20 to 200 micrometers. Melt blown adhesive applicator as the inherent stability, produce little, Preferably spurious fibers. The UV light, the presentation rules, smooth, stretched dot pattern in the form of Bonding. For the use of air-atomized spray of a hot melt adhesive and a very small dot to be transported A substrate bonding method. ...

The binder of the present invention can be used in any adhesive application, including but not limited to disposable products Products, packaging materials, laminated products, pressure sensitive adhesives, tapes labels, wood binding, paper binding, Nonwovens, road signs, reflective coatings.

In a preferred embodiment, the present invention can be used in disposable diapers and adhesive sanitary napkins Underlying structure, the one-time items, processing, packaging, labeling, binding, woodworking or It is the elastic link assembly applications. Particularly preferred applications include: baby diaper leg elastic band, Tape before the diaper, the diaper standing leg cuff, diapers underlying structure of the diaper core stabilization, diapers liquid Body transfer layer, diaper cover laminated, elastic cuffs stacked diapers, sanitary napkins, core stability Technology, women's sanitary napkins adhesive strip, industrial filtration bonding, industrial filter stack, filters mask Laminated, laminated surgical coat, surgical drapes and perishable product packaging laminate. ...

In a preferred embodiment, the present invention can be used in disposable diapers and adhesive sanitary napkins Underlying structure, the one-time items, processing, packaging, labeling, binding, woodworking or It is the elastic link assembly applications. Particularly preferred applications include: baby diaper leg elastic band, Tape before the diaper, the diaper standing leg cuff, diapers underlying structure of the diaper core stabilization, diapers liquid Body transfer layer, diaper cover laminated, elastic cuffs stacked diapers, sanitary napkins, core stability Technology, women's sanitary napkins adhesive strip, industrial filtration bonding, industrial filter stack, filters mask Laminated, laminated surgical coat, surgical drapes and perishable product packaging laminate. ..._x) Coating), foam, rock, ceramics, films, polymer foams (such as polyurethane Foams), and the coating of the ink, dyes, pigments, PVDC and other substrates or combinations thereof.

Another preferred substrates include polyethylene, polypropylene, polyacrylates, acrylics, poly Polyethylene terephthalate, or the polymer blend suitable for use as any combination thereof.

Either the substrate and / or the polymer of the present invention may be subjected to corona treatment, flame treatment, Electron beam radiation, γ radiation, microwave radiation or silanized.

Here the production of adhesive when applied in accordance with certain styles between the two adherends, preferably by In such a manner, that is similar to the structure of the standard instructions or standard adhesive materials compared to those Material held together with a sufficient style.

Polymer product can be used with the present invention WO 97/33921 describes a polymer composition or instead of The polymer described in any of the binder is used in which the application is described.

The polymer product of the present invention alone or with other polymers and / or additives can also be combined In the formation of WO 02/35956 describes a hook and loop fastenings (fasteners).

Characterization and Testing

Molecular weight (number average molecular weight (Mn), weight average molecular weight (Mw) and z-average molecular weight (Mz)) with With differential refractive index detector (DRI), a low angle light scattering line (LALLS) detector and a viscosity Instrument (VIS) is Waters150 size exclusion chromatography (SEC) was measured. Detector calibration details Has been described in other literature [References: T.Sun, P.Brant, RRChance and WWGraessley, Macromolecules, Volume 34, Number19 ,6812-6820, (2001)]; following note is a brief description of its components.

With three Polymer Laboratories PLgel 10mm Mixed-B columns, nominal Velocity 0.5cm3/min and nominal injection volume 300 microliters SEC configurations of the two detectors is Common. The various transmission lines, pillars and differential refractometer (DRI detector, mainly for Elution solution concentration measurement) placed in an oven maintained 135 ℃.

LALLS detector for the 2040 dual-angle light scattering photometer (Precision Detector Inc.). SEC oven which is located on the fluid chamber using 690nm diode laser Light source and collected 15 and 90 ° scattered light at two angles. Only 15 ° output for these implementations Experiment. Its signal into the data collection board (National Instruments), the collection plate To 16 / sec collected readings. The lowest of the four readings mean, then a proportion of the letter Number into SEC-LALLS-VIS computer. LALLS detector is set in the SEC columns, but before the Viscometer before.

High temperature 150R type viscometer (Viscotek Corporation). It consists in a Wheatstone Bridge configuration arranged in four capillary and two pressure sensor. An edge detection sensor The total pressure drop measured, the other sides of the bridge situated between the differential pressure measurement. Calculated by output Flowing a solution viscometer viscosity. Viscometer in the SEC oven, located LALLS detection After the device, but before the DRI detector.

A solvent for the SEC experiment by 6g as an antioxidant butylated hydroxytoluene (BHT) added with 1,2,4 - trichlorobenzene (TCB) (Aldrich reagent grade) 4-liter bottles and other BHT is prepared to be dissolved. The TCB mixture was then 0.7μm filters glass preform, Then through 0.1μm Teflon filter. In the high-pressure pump with the SEC column exists between Another line 0.7 micron glass pre-filter / a 0.22 micron Teflon filter assembly. Next, the TCB with online degasser (Phenomenex, Model DG-4000) degassing, and then into the Into the SEC.

Polymer solution was prepared by the following method: The dried polymer was put in a glass container, Add the desired amount of TCB, and the mixture heated at 160 ℃ while continuously stirring for about 2 hours. Analysis of all the amount of weight. TCB is used to represent the density of polymer concentration (mass / volume) At room temperature 1.463g/ml, at 135 ℃ under 1.324g/ml. Injection concentration ranging 1.0 to 2.0mg/ml, in which a lower concentration for higher molecular weight samples.

In operation each of the samples prior to DRI detector and injector purge. Then the instrument The flow rate was increased to 0.5ml/min, the injection before the first sample that DRI stable 8-9 hours. Argon ion lasers will open from 1 to 1.5 hours, which passed before the operation in idle mode, the sample 20-30 minutes running laser, then the light adjustment mode is switched to full power.

The branching index online viscometer fitted with SEC (SEC-VIS) measurements and record tracks SEC The molecular weight of the line g '. The branching index g 'is defined as;

g′＝η _b/η _l

Where η_bIs a branched polymer has an intrinsic viscosity, η_lBranched polymers with the same viscosity-average Molecular weight (M_v) Of the intrinsic viscosity of the linear polymer. η_l＝KM _v ^αWherein K and α is a linear polymer Was measured values, and should be used for the branching index in the same measurement SEC-DRI-LS-VIS instrument Obtained on. Prepared in the present invention, polypropylene samples, using K = 0.0002288, and α = 0. 705. SEC-DRI-LS-VIS method does not require a polydispersity of correction, since the intrinsic viscosity And the molecular weight of the respective elution volume is measured, can be considered which includes a narrow distribution polymer. Select Comparison of the standards as the linear polymer should have the same viscosity-average molecular weight and comonomer Content. Monomers containing C2 to C10 linear polymer characteristics of the Carbon-13 by Randall NMR methods confirmed (Rev.Macromol.Chem.Phys., C29 (2 & 3), p.285-297).

C11 and the linearity of the monomer by using a GPC MALLS analysis confirmed the detector. For example, the propylene copolymer, NMR comonomers should not show greater degree of branching (i.e. if the total Poly-butene monomers, there should be no more than 2 carbon atoms, a branched chain). For a propylene homopolymer, GPC should not show more than one branched-chain carbon atoms. When one or more comonomers poly C9 Compounds require linear standards, reference T.Sun, P.Brant, RRChance, and W. W.Graessley, Macromolecules, Volume 34, Number19 ,6812-6820, (2001) Determination of those polymers in the standard solutions. The syndiotactic polymer, and the standard Should have a comparable measure of syndiotactic by Carbon 13 NMR measurements. ...

In another embodiment, the production of the polymer may have a single-mode polymer substance, bis Modal or multi-modal molecular weight distribution (Mw / Mn), by size exclusion chromatography (SEC) was measured. Bimodal or multi-modal SEC traces means having one or more peaks or inflection point. Inflection point as one song The second derivative signal line change (for example, from negative to positive or opposite) points.

Peak melting point (Tm), peak crystallization temperature (Tc), heat of fusion and crystallization in accordance with ASTM E 794-85 Measured using the following procedure. Differential scanning calorimetry (DSC) data of a TA Instruments Co. 2920 machine to obtain. The weighing of about 7-10mg of sample sealed in aluminum sample pan. DSC number According to the record by the following method; first sample was cooled to -50 ℃, and then at a rate of 10 ℃ / Min and gradually heated to 200 ℃. The sample was kept at 200 ℃ for 5 minutes, then applied to Secondary cooling - heating cycle. Record the first and second cycles of thermal processes. Measured under the curve Area, for measuring the heat of fusion and crystallinity. Crystallinity percentage using the formula [surface under the curve Plot (J / g) / B (J / g)] * 100 calculation, where B is the main monomer component melting homopolymer Heat. These B values from Polymer Handbook, Fourth Edition, John Wiley and Sons out Edition, New York 1999 obtained. Numerical 189J / g (B) for 100% crystalline polypropylene Heat of fusion. For displaying a plurality of polymer melting or crystallization peak, the maximum of the melting peak as Melting peak, the highest peak crystallization temperature as the crystallization peak. ...

Will be used to¹³C NMR spectrum of the polymer sample was dissolved in d ₂1,1,2,2 - tetrachloroethane, and With 75 or a 100MHz NMR spectrometer sample was recorded at 125 ℃. Polymer formant involved And mmmm = 21.8ppm. In the polymer characterization by NMR for the calculation involved in follow F. A.Bovey in "Polymer Conformation and Configuration", Academic Press, New York 1969 and J.Randall in "Polymer Sequence Determination, Carbon-13 NMR Me thod ", Academic Press, New York, 1977 work in progress. Length sequence two methylene percentage,% (CH₂) ₂, In accordance with such The following calculations: In the 14-18ppm integration between the methyl carbon atoms (concentration equal to two methylene The length of the sequence number) is divided by 45-49ppm of a methylene group between the length of the sequence of points and 14-18ppm integration between the sum of the methyl carbon atoms and multiplied by 100. This is two or more More methylene groups contained in the sequence of the calculated minimum amount of methylene, because more than two methylene Methylene sequences have been ruled out. This description is based on HNCheng and JAEwen, Makromol. Chem.1989, 190,1931.

The ethylene content of the polymer can be determined as follows. At a temperature of about 150 ℃ or higher were pressed under a thin Uniform film, and then placed in the Perkin Elmer PE 1760 infrared spectrometer. Record Samples from 600cm^-1To 4000cm^-1Full-spectrum, and in accordance with the following formula wt ethylene monomer % Content: Ethylene wt% = 82.585-111.987X +30.045 X²Wherein X is 1155cm^-1The peak height and 722cm^-1Office or 732cm^-1Peak height (select whichever is higher peaks) of Ratio. Other monomers in the polymer concentration can be calculated in this way.

Binder test

SAFT (revised D4498) measurements in order to pull the adhesive shear mode at constant force under sticky Junction bear the 10 ° F (5.5 ℃) / 15min the temperature rise performance. Bonding at the above parties Formula to form (1 in. × 3 in. (2.5cm × 7.6cm) (in kraft) would, in its bottom Load 500g Load sample vertically suspended in the oven at room temperature. Record the weight of the whereabouts of Temperature (when the occasional sample reaches a temperature above the oven above the allowed tolerance (> 265 ° F (129 ℃)) when Terminated and the final temperature in the average of the other samples).

Curing time is defined as the bonding substrate structure strong enough to suppress fixed together to make separate Caused when the substrate fiber tear, so that the adhesive can be removed even strong enough to suppress the time. Bond Can be enhanced by further cooling, however, no need to suppress. These curing time by, for example Under way to measure; melting point of the binder system fixed on the platform placed in the folder where the substrate surface On. 3 seconds after the point to place the folder binder clip (file folder tab) (1 英寸 × 3 英寸 (2.5cm × 7.6cm) with 500g heavy repression. The weight stays about 0.5 To about 10 seconds. The structure thus formed apart to check that they have produced a substrate fiber tear Good enough degree of adhesion. Record generate the minimum time required for good adhesion when used as curing Room. The method was calibrated with a standard substance. ...

Shore A hardness measured according to ASTM 2240. Air cooling the binder acupuncture points, Recorded by the scale deflection.

Shore A hardness measured according to ASTM 2240. Air cooling the binder acupuncture points, Recorded by the scale deflection....

Peel strength (modified ASTMD1876): the base material (1 × 3 英寸 (25 × 76mm)) With an adhesive film (5mil (130μm) thick) at 135 ℃ and 40psi (0.28MPa) Pressure Under seal 1-2 seconds. The bonded specimen in the tensile tester at a constant crosshead speed of 2 in / min (51mm/min) for reverse peel. Record the adhesive (5 samples) separated from the The average force required.

Peel strength (modified ASTMD1876): the base material (1 × 3 英寸 (25 × 76mm)) With an adhesive film (5mil (130μm) thick) at 135 ℃ and 40psi (0.28MPa) Pressure Under seal 1-2 seconds. The bonded specimen in the tensile tester at a constant crosshead speed of 2 in / min (51mm/min) for reverse peel. Record the adhesive (5 samples) separated from the The average force required....

Peel adhesion failure temperature (PAFT) with the following in accordance with TAPPI T814 PM-77 repair process Determination reform process. 177 ℃ with a heating of the molten adhesive to the two pieces of the 6 "× 12" cowhide Paper laminated together. Trimming the laminate and cut into 1 - inch wide strips. Will be having to divest Means hanging 100-g weight of these pieces into the oven. Temperature of the oven at a rate of 30 ℃ / hr increased. The samples were hung on a switch, this switch in the sample will be destroyed in order to remember the trip Damage recorded temperature.

Substrate temperature fiber tear: According to the step "(b)" Preparation of kraft agglutinated. The sticky Results of test specimens placed in the freezer or refrigerator to obtain the desired test temperature. Hands of the bonding material Open and observe the destruction of the type measured. Substrate fiber tear volume expressed as a percentage. "SF" indicates Substrate damage.

By the binder blend is heated to melt the adhesive 121 ℃ and small beads (about 1g) ASTM thermometer ball onto the cloud point determination. Then pay attention to the temperature of the molten binder muddy. These measurements of cloud point values provide the overall compatibility of the hot-melt, which means that each component represents the mutual compatibility of Shown.

Compression molding: Carver hydraulic press repression in suitable physical performance test boards. The 6.5g Polymer lined with Teflon^TMCopper coated aluminum foil (0.05 "thick) between the molding would have 4 "× 4" square openings of 0.033 "thick frame (chase) for controlling the thickness of the sample in Minimum pressure at 170 ℃ or 180 ℃ preheating 1 minute, the hydraulic load was gradually raised to about 10,000-15,000 lb, to be maintained at this pressure for 3 minutes. Subsequently the sample and molding plates At about 10,000 to 15,000 lb loads in platen presses interstage cooling water for 3 minutes. Will The balance plate at room temperature for a minimum of 2 days, and then tested for physical properties.

Uniaxial tensile test: hammer pressure die from compression molded plates cut out for tensile testing eight Word test block. The size of the specimen specified in ASTM D 1708 those. An Instron tensile properties^TMUniaxial tensile test: hammer pressure die from compression molded plates cut out for tensile testing eight Word test block. The size of the specimen specified in ASTM D 1708 those. An Instron tensile properties...

Uniaxial tensile test: hammer pressure die from compression molded plates cut out for tensile testing eight Word test block. The size of the specimen specified in ASTM D 1708 those. An Instron tensile properties...

Example

General introduction

All polymerization in liquid-filled single-stage continuous reactor using mixed metallocene catalyst Agent system for. Reactor 0.5 liter stainless steel autoclave reactor equipped with a stirrer, with a temperature Degree of control of water cooling / heating elements and steam pressure control device. First, with purified through three lines System the solvent, propylene and comonomer (such as butene and hexene) (if present) purification. Purification system Statistics from the Oxiclear column (Model # RGP-R1-500, purchased from Labclear), then in the subsequent Surface 5A and 3A molecular sieve column components. When there is an indication that the polymerization of low activity, the purification column set Of regeneration. 3A and 5A molecular sieves under nitrogen internally in each set temperature of 260 ℃ and 315 ℃ under regeneration. Molecular sieve materials were purchased from Aldrich. Oxiclear column in the initial manufacturing Regeneration. The purified material from the internal supply manifold ethylene added, and the reaction via Brookfleld material flow controller. Ethylene solvent to dissolve in a cold / monomer mixture Transported in gaseous form. And then the solvent and the monomer purified by means of the refrigerator is cooled to about -15 ℃, then through the reactor manifold. The solvent and the monomer mixture in the manifold and through the single tube Added to the reactor. All liquid flow meter or materials are used Brooksfield Micro-Motion Coriolis flowmeter measurement ...

For the production of semi-crystalline polypropylene catalyst compound is racemic - dimethylsilyl group Bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, rac - dimethylsilyl bis (2 - methyl- -4 - Phenyl-indenyl) zirconium dimethyl, rac - dimethylsilyl bis (2 - methyl-indenyl) dimethyl Group zirconium, rac - dimethylsilyl bis (indenyl) hafnium dimethyl, and rac-1 ,2 - 2nd Ethyl - bis (4,7 - dimethyl-indenyl) hafnium dimethyl (purchased from Boulder Scientific Company).

For the production of semi-crystalline polypropylene catalyst compound is racemic - dimethylsilyl group Bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride, rac - dimethylsilyl bis (2 - methyl- -4 - Phenyl-indenyl) zirconium dimethyl, rac - dimethylsilyl bis (2 - methyl-indenyl) dimethyl Group zirconium, rac - dimethylsilyl bis (indenyl) hafnium dimethyl, and rac-1 ,2 - 2nd Ethyl - bis (4,7 - dimethyl-indenyl) hafnium dimethyl (purchased from Boulder Scientific Company)....

Dimethyl silyl (tetramethyl cyclopentadienyl) (ring dodecylamino) titanium dichloride According to US5, 057,475 in the embodiment of the production. The variant dimethyl dimethyl dichloride by Compounds variants available.

Rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride and dimethyl Silyl (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dichloride with MAO (methyl Base Aluminoxanes) activation. Rac-1 ,2 - ethylene-bis (4,7 - dimethyl-indenyl) hafnium dimethyl with three Benzyl tetrakis (pentafluorophenyl) borate (purchased from Single-Site Catalysts, LLC) Pre Activation. The remaining catalyst tetrakis (pentafluorophenyl) borate, N, N-dimethylaniline bromide (available from Albemarle) pre-activated. For pre-activated catalyst system, before the polymerization reaction, the Catalyst promoter at a molar ratio of 1:1 to 1:1.1 in the activation of at least 700ml of toluene 10 minutes. The catalyst system was then diluted with toluene to a concentration of 0.2 to 1.4mg/ml The catalyst concentration. The catalyst solution is used on the same day in all the polymerization experiments. When the day is consumed 700ml ml catalyst solution over the catalyst solution prepared at the new batch. Each of the catalyst solution pumped through a separate line. The catalyst was mixed in the manifold, and then by a single A line to the reactor. Of methyl alumoxane activated system, the trimethylaluminum 280ml Alumoxane (MAO, in toluene 10wt.%, Purchased from Albemarle) diluted in toluene 1000ml Release, and the solution was stored at 5 l stainless steel bottle. The catalyst was diluted to a concentration in toluene 0.2 to 1.4mg/ml. Each of the catalyst solution and methyl aluminoxane solution via respective lines Pumped. The catalyst and MAO in the manifold are mixed and then added to the reactor through a single line in the. Catalyst inlet manifold between the reactor tube is about 1m in length connection. ...

As impurity scavenger, the 55ml triisobutylaluminum (25wt.%, in toluene, Akzo Noble) in 22.83kg hexane dilution. The diluted solution of triisobutylaluminum in a nitrogen blanket Stored under 37.9 liters bottle. The polymerization solution was used in all experiments up to about 90% of consumption, Then prepare a new batch. Triisobutylaluminum solution was pumped into the polymerization reaction rate varies with, Can range from 0 (no scavenger) to 4ml/min.

As impurity scavenger, the 55ml triisobutylaluminum (25wt.%, in toluene, Akzo Noble) in 22.83kg hexane dilution. The diluted solution of triisobutylaluminum in a nitrogen blanket Stored under 37.9 liters bottle. The polymerization solution was used in all experiments up to about 90% of consumption, Then prepare a new batch. Triisobutylaluminum solution was pumped into the polymerization reaction rate varies with, Can range from 0 (no scavenger) to 4ml/min....

First, by the maximum allowable temperature (about 150 ℃) under solvent (e.g., hexane) and cleared In addition to agents continuously pumped through the reactor system is at least one hour to clean the reactor. After cleaning, the anti- Used to be flowing through the reactor jacket water / steam mixture is heated / cooled to the desired temperature and pass Solvent flow control by controlling the reactor at the set pressure. Then, when the operation reaches a steady state The monomer and catalyst solution is added to the reactor. Automatic temperature control system for the reaction Is controlled and maintained at the set temperature. Viscous products, and by observing the water - vapor mixture drop Low temperature to determine the polymerization activity begins. Once the active and the system reaches equilibrium, the closing Sample collection under conditions established by the continuous operation of the system is at least five times the average residence time Time, the reactor was marked (lined out). When the system reaches steady state operation, the Collected in collection tank containing mainly solvent, polymer and unreacted monomers resulting mixture. Will receive The sample was first set in the hood to evaporate most of the solvent was air-dried, and then in a vacuum oven At a temperature of about 90 ℃ dried for about 12 hours. The vacuum oven dried sample is weighed to obtain Yield. All reactions are 2.41MPa-g pressure and temperature of 45 至 130 ℃ temperature. ...

Using rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and di Dimethylsilyl (tetramethyl-cyclopentadienyl) (cyclododecyl) dimethyl titanium at a temperature of 115 ℃ the scale range of the catalyst prepared in four samples. Polymerization in accordance with the general work Sequence proceed. The detailed experimental conditions and results are given in Table 1.

Table 1
Table 1					Example	1	2	3	4
Catalyst # 1	A	A	A	A	Example	1	2	3	4
Catalyst # 1	A	A	A	A	Catalyst # 1 feed rate (mol / min)	4.83E-06	3.66E-06	3.00E-06	2.68E-06
Catalyst # 2	B	B	B	B	Catalyst # 1 feed rate (mol / min)	4.83E-06	3.66E-06	3.00E-06	2.68E-06
Catalyst # 2	B	B	B	B	Catalyst #
2 feed rate (mol / min)	3.64E-07	3.64E-07	3.64E-07	3.64E-07	Catalyst #
2 feed rate (mol / min)	3.64E-07	3.64E-07	3.64E-07	3.64E-07	Propylene feed rate (g / min)	14	14	14	14
Hexane feed rate (ml / min)	90	90	90	90	Propylene feed rate (g / min)	14	14	14	14
Hexane feed rate (ml / min)	90	90	90	90	Polymerization temperature (℃)	115	115	115	115
Mn(kg/mol)	19.1	18.2	16.4	16.9	Polymerization temperature (℃)	115	115	115	115
Mn(kg/mol)	19.1	18.2	16.4	16.9	Mw(kg/mol)	31	28.3	25.7	26.7
Mz(kg/mol)	66.1	52.4	46.9	53.1	Mw(kg/mol)	31	28.3	25.7	26.7
Mz(kg/mol)	66.1	52.4	46.9	53.1	g′@Mz	1.02	0.99	0.96	0.9
Tc(℃)	90.5	98.8	97.7	97.1	g′@Mz	1.02	0.99	0.96	0.9
Tc(℃)	90.5	98.8	97.7	97.1	Tm(℃)	140.5	143.2	143.8	142.8
Tg(℃)	-17.7	-10.4	-10.4	-11.3	Tm(℃)	140.5	143.2	143.8	142.8
Tg(℃)	-17.7	-10.4	-10.4	-11.3	Heat of fusion (J / g)	21.7	25.7	34.7	35.1
Viscosity @ 190 ℃ (cps)	1540	1340	1240	798	Heat of fusion (J / g)	21.7	25.7	34.7	35.1
Viscosity @ 190 ℃ (cps)	1540	1340	1240	798	Conversion Rate (%)	95.3	89.6	87.1	92.8
Catalyst activity (kg polymer / g catalyst)	5.7	6.9	8.0	9.4	Conversion Rate (%)	95.3	89.6	87.1	92.8
Catalyst activity (kg polymer / g catalyst)	5.7	6.9	8.0	9.4	Catalyst:
A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl					Catalyst:
					B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl

Examples 5-8

Using rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and di Dimethylsilyl (tetramethyl-cyclopentadienyl) (t-butylamino) titanium dimethyl at temperature 100 ℃ Proportion of the catalyst within the four samples prepared. Polymerization conducted in accordance with the general procedure.

The detailed experimental conditions and results are given in Table 2.

Table 2
Table 2					Example	5	6	7	8
Catalyst # 1	F	F	F	F	Example	5	6	7	8
Catalyst # 1	F	F	F	F	Catalyst # 1 feed rate (mol / min)	4.92E-06	4.92E-06	4.92E-06	4.92E-06
Catalyst # 2	B	B	B	B	Catalyst # 1 feed rate (mol / min)	4.92E-06	4.92E-06	4.92E-06	4.92E-06
Catalyst # 2	B	B	B	B	Catalyst #
2 feed rate (mol / min)	5.67E-07	8.50E-07	1.13E-06	1.42E-06	Catalyst #
2 feed rate (mol / min)	5.67E-07	8.50E-07	1.13E-06	1.42E-06	Propylene feed rate (g / min)	14	14	14	14
Hexane feed rate (ml / min)	90	90	90	90	Propylene feed rate (g / min)	14	14	14	14
Hexane feed rate (ml / min)	90	90	90	90	Polymerization temperature (℃)	100	100	100	100
Mn(kg/mol)	12.1	11.9	8.8	12.4	Polymerization temperature (℃)	100	100	100	100
Mn(kg/mol)	12.1	11.9	8.8	12.4	Mw(kg/mol)	29.4	30.7	26.3	28
Mz(kg/mol)	84.3	81.6	8 0.7	84.7	Mw(kg/mol)	29.4	30.7	26.3	28
Mz(kg/mol)	84.3	81.6	8 0.7	84.7	g′@Mz	0.93	0.88	0.87	0.84
Tc(℃)	95.8	98.4	96.1	95.8	g′@Mz	0.93	0.88	0.87	0.84
Tc(℃)	95.8	98.4	96.1	95.8	Tm(℃)	145.2	145.7	143.3	14 3.0
Tg(℃)	-9.6	-10.4	-11.1	-10.0	Tm(℃)	145.2	145.7	143.3	14 3.0
Tg(℃)	-9.6	-10.4	-11.1	-10.0	Heat of fusion (J / g)	21.4	32.4	30.0	33.0
Viscosity @ 190 ℃ (cps)	1100	1040	840	675	Heat of fusion (J / g)	21.4	32.4	30.0	33.0
Viscosity @ 190 ℃ (cps)	1100	1040	840	675	Conversion Rate (%)	88.63	91.73	68.09	77.23
Catalyst activity (kg polymer / g catalyst)	6.38	6.08	4.18	4.42	Conversion Rate (%)	88.63	91.73	68.09	77.23
Catalyst activity (kg polymer / g catalyst)	6.38	6.08	4.18	4.42	Catalyst:
B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl					Catalyst:
					F = dimethylsilyl group (tetramethyl cyclopentadienyl) (t-butylamino) titanium dimethyl

Example 9-15

With dimethylsilyl bis (indenyl) hafnium dimethyl and dimethyl silyl (tetramethylcyclopropanecarboxylate Pentadienyl) (cyclododecyl) dimethyl titanium ratio of the catalyst under about 80.0mol% Prepared within a temperature range of seven samples. Polymerization conducted in accordance with the general procedure. Detailed The experimental conditions and results are given in Table 3. These data show that the temperature on the crystallinity, Mw, Mw / Mn And has a significant effect on the amount of branching. The reaction temperature can be controlled by the total amount, this is because each catalyst The reaction kinetics of the polymerization temperature has a unique response.

Table 3
Table 3								Example	9	10	11	12	13	14	15
Catalyst # 1	A	A	A	A	A	A	A	Example	9	10	11	12	13	14	15
Catalyst # 1	A	A	A	A	A	A	A	Catalyst # 1 feed rate (mol / min)	5.22E-06	5.22E-06	5.22E-06	5.22E-06	5.22E-06	5.22E-06	5.22E-06
Catalyst # 2	C	C	C	C	C	C	C	Catalyst # 1 feed rate (mol / min)	5.22E-06	5.22E-06	5.22E-06	5.22E-06	5.22E-06	5.22E-06	5.22E-06
Catalyst # 2	C	C	C	C	C	C	C	Catalyst # 2 feed rate (mol / min)	1.31E-06	1.31E-06	1.31E-06	1.31E-06	1.31E-06	1.31E-06	1.31E-06
Propylene feed rate (g / min)	14	14	14	14	14	14	14	Catalyst # 2 feed rate (mol / min)	1.31E-06	1.31E-06	1.31E-06	1.31E-06	1.31E-06	1.31E-06	1.31E-06
Propylene feed rate (g / min)	14	14	14	14	14	14	14	Hexane feed rate (ml / min)	90	90	90	90	90	90	90
Polymerization temperature (℃)	110	105	100	95	90	85	80	Hexane feed rate (ml / min)	90	90	90	90	90	90	90
Polymerization temperature (℃)	110	105	100	95	90	85	80	Mn(kg/mol)	8.5	8.2	9.8	11.1	22.5	26.6	30.9
Mw(kg/mol)	15.7	17.1	19.8	23.5	41.1	46.9	55.8	Mn(kg/mol)	8.5	8.2	9.8	11.1	22.5	26.6	30.9
Mw(kg/mol)	15.7	17.1	19.8	23.5	41.1	46.9	55.8	Mz(kg/mol)	30.6	37.9	42.2	40.4	79.8	84.8	95.5
g@Mz	1	0.97	0.95	0.97	0.98	0.97	0.98	Mz(kg/mol)	30.6	37.9	42.2	40.4	79.8	84.8	95.5
g@Mz	1	0.97	0.95	0.97	0.98	0.97	0.98	Tc(℃)	22.8	31.6	40.5	47.8	53.5	61.0	64.8
Tm(℃)	74.7	82.3	87.4	94.3	103.3	107.7	113.7	Tc(℃)	22.8	31.6	40.5	47.8	53.5	61.0	64.8
Tm(℃)	74.7	82.3	87.4	94.3	103.3	107.7	113.7	Tg(℃)	-15.5	-13.0	-12.0	-10.0	-7.5	-7.5	-6.0
Heat of fusion (J / g)	14.4	16.6	21.5	26.0	21.0	27.8	26.7	Tg(℃)	-15.5	-13.0	-12.0	-10.0	-7.5	-7.5	-6.0
Heat of fusion (J / g)	14.4	16.6	21.5	26.0	21.0	27.8	26.7	Viscosity @ 190 ℃ (cps)	227	272	441	813	5280	7250	15400
Catalyst:								Viscosity @ 190 ℃ (cps)	227	272	441	813	5280	7250	15400
Catalyst:								A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl
C = rac - dimethylsilyl bis (indenyl) zirconium dimethyl

Examples 16-19

Using rac - dimethylsilyl bis (indenyl) hafnium dimethyl and dimethylsilyl group (Tetramethyl cyclopentadienyl) (cyclododecyl) dimethyl titanium under various temperature 100 ℃ Catalyst ratio of four samples were prepared. Polymerization conducted in accordance with the general procedure. Detailed Experimental conditions and results are given in Table 4. These data show that the catalysts of the crystallinity ratio, Mw, Mw / Mn and the amount of branching has a significant effect. The reaction temperature can be controlled by the total amount, which is due to the Reaction kinetics of the polymerization catalyst temperature has a unique response.

Table 4
Table 4					Example	16	17	18	19
Catalyst # 1	A	A	A	A	Example	16	17	18	19
Catalyst # 1	A	A	A	A	Catalyst # 1 feed rate (mol / min)	8.49E-07	8.49E-07	8.49E-07	8.49E-07
Catalyst # 2	C	C	C	C	Catalyst # 1 feed rate (mol / min)	8.49E-07	8.49E-07	8.49E-07	8.49E-07
Catalyst # 2	C	C	C	C	Catalyst #
2 feed rate (mol / min)	5.51E-07	8.26E-07	1.28E-06	1.93E-06	Catalyst #
2 feed rate (mol / min)	5.51E-07	8.26E-07	1.28E-06	1.93E-06	Propylene feed rate (g / min)	14	14	14	14
Hexane feed rate (ml / min)	90	90	90	90	Propylene feed rate (g / min)	14	14	14	14
Hexane feed rate (ml / min)	90	90	90	90	Polymerization temperature (℃)	100	100	100	100
Mn(kg/mol)	17.1	14.1	9.6	7.3	Polymerization temperature (℃)	100	100	100	100
Mn(kg/mol)	17.1	14.1	9.6	7.3	Mw(kg/mol)	28	20.7	14.3	10.6
Mz(kg/mol)	65	37.6	24.9	18.2	Mw(kg/mol)	28	20.7	14.3	10.6
Mz(kg/mol)	65	37.6	24.9	18.2	g′@Mz	1.05	0.97	0.92	0.94
Tc(℃)	61.2	55.2	30.8	28.8	g′@Mz	1.05	0.97	0.92	0.94
Tc(℃)	61.2	55.2	30.8	28.8	Tm(℃)	107.3	97.6	76.9	64.3
Tg(℃)	-8.9	-14.5	-15.3	-14.6	Tm(℃)	107.3	97.6	76.9	64.3
Tg(℃)	-8.9	-14.5	-15.3	-14.6	Heat of fusion (J / g)	29.9	31.2	19.9	7.6
Viscosity @ 190 ℃ (cps)	1355	41 2	165	87	Heat of fusion (J / g)	29.9	31.2	19.9	7.6
Viscosity @ 190 ℃ (cps)	1355	41 2	165	87	Conversion Rate (%)	86.20	91.89	100.56	97.90
Catalyst activity (kg polymer / g catalyst)	18.74	16.49	13.97	10.34	Conversion Rate (%)	86.20	91.89	100.56	97.90
Catalyst activity (kg polymer / g catalyst)	18.74	16.49	13.97	10.34	Catalyst:
A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl					Catalyst:
					C = rac - dimethylsilyl bis (indenyl) hafnium dimethyl

Examples 20-34

Using rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and di Dimethylsilyl (tetramethyl-cyclopentadienyl) (cyclododecyl) dimethyl titanium catalyst Prepared according to the above general procedure 15 samples, except that the small amounts of a diene monomer 1,9 - decadiene, and a propylene-α-olefin monomers joined together. The detailed experimental conditions and results In Tables 5 and 6 gives the.

Table 5
Table 5						Example	20	21	22	23	24
Catalyst # 1	A	A	A	A	A	Example	20	21	22	23	24
Catalyst # 1	A	A	A	A	A	Catalyst # 1 feed rate (mol / min)	6.53E-06	6.53E-06	6.53E-06	6.53E-06	6.53E-06
Catalyst # 2	B	B	B	B	B	Catalyst # 1 feed rate (mol / min)	6.53E-06	6.53E-06	6.53E-06	6.53E-06	6.53E-06
Catalyst # 2	B	B	B	B	B	Catalyst # 2 feed rate (mol / min)	6.92E-07	3.64E-07	3.64E-07	2.19E-07	2.19E-07
Propylene feed rate (g / min)	14	14	14	8.3	10	Catalyst # 2 feed rate (mol / min)	6.92E-07	3.64E-07	3.64E-07	2.19E-07	2.19E-07
Propylene feed rate (g / min)	14	14	14	8.3	10	1,9 - decadiene feed rate (ml / min)	0.19	0.19	0.19	0.13	0.13
Hexane feed rate (ml / min)	90	90	90	90	90	1,9 - decadiene feed rate (ml / min)	0.19	0.19	0.19	0.13	0.13
Hexane feed rate (ml / min)	90	90	90	90	90	Polymerization temperature (℃)	120	125	120	120	110
Mn(kg/mol)	15.6	14.7	14.3	-	-	Polymerization temperature (℃)	120	125	120	120	110
Mn(kg/mol)	15.6	14.7	14.3	-	-	Mw(kg/mol)	23	24.6	29.5	-	-
Mz(kg/mol)	55.2	64.2	85	-	-	Mw(kg/mol)	23	24.6	29.5	-	-
Mz(kg/mol)	55.2	64.2	85	-	-	g′@Mz	0.85	0.91	0.85	-	-
Tc(℃)	86.5	91.8	91.8	86.5	87.6	g′@Mz	0.85	0.91	0.85	-	-
Tc(℃)	86.5	91.8	91.8	86.5	87.6	Tm(℃)	116.6	128.7	129.7	128.8	137.6
Tg(℃)	-10.6	-11.1	-9.7	-9.4	-7.5	Tm(℃)	116.6	128.7	129.7	128.8	137.6
Tg(℃)	-10.6	-11.1	-9.7	-9.4	-7.5	Heat of fusion (J / g)	31.8	32.1	26.0	17.0	19.4
Viscosity @ 190 ℃ (cps)	721	725	1240	448	2240	Heat of fusion (J / g)	31.8	32.1	26.0	17.0	19.4
Viscosity @ 190 ℃ (cps)	721	725	1240	448	2240	Conversion Rate (%)	93.32	77.57	81.12	77.49	85.13
Catalyst activity (kg polymer / g catalyst)	4.00	3.54	3.70	2.15	2.85	Conversion Rate (%)	93.32	77.57	81.12	77.49	85.13
Catalyst activity (kg polymer / g catalyst)	4.00	3.54	3.70	2.15	2.85	Catalyst:
A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl						Catalyst:
						B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl

Table 5 (continued)
Table 5 (continued)						Example	25	26	27	28	29
Catalyst # 1	A	A	A	A	A	Example	25	26	27	28	29
Catalyst # 1	A	A	A	A	A	Catalyst # 1 feed rate (mol / min)	5.22E-06	5.22E-06	5.22E-06	6.53E-06	6.53E-06
Catalyst # 2	B	B	B	B	B	Catalyst # 1 feed rate (mol / min)	5.22E-06	5.22E-06	5.22E-06	6.53E-06	6.53E-06
Catalyst # 2	B	B	B	B	B	Catalyst # 2 feed rate (mol / min)	7.65E-07	7.65E-07	7.65E-07	2.19E-07	4.74E-07
Propylene feed rate (g / min)	14	14	14	10	14	Catalyst # 2 feed rate (mol / min)	7.65E-07	7.65E-07	7.65E-07	2.19E-07	4.74E-07
Propylene feed rate (g / min)	14	14	14	10	14	1,9 - decadiene feed rate (ml / min)	0.24	2.24	0.19	0.13	0.19
Hexane feed rate (ml / min)	09	90	90	90	90	1,9 - decadiene feed rate (ml / min)	0.24	2.24	0.19	0.13	0.19
Hexane feed rate (ml / min)	09	90	90	90	90	Polymerization temperature (℃)	115	117	110	125	115
Mn(kg/mol)	20		23		17.3	Polymerization temperature (℃)	115	117	110	125	115
Mn(kg/mol)	20		23		17.3	Mw(kg/mol)	36.7		45.5		34.5
Mz(kg/mol)	111.9		104		97.1	Mw(kg/mol)	36.7		45.5		34.5
Mz(kg/mol)	111.9		104		97.1	g′@Mz	0.68		0.75		0.75
Tc(℃)	91.1	87.0	96.8	77.3	88.5	g′@Mz	0.68		0.75		0.75
Tc(℃)	91.1	87.0	96.8	77.3	88.5	Tm(℃)	136.6	133.7	134.2	130.0	136.3
Tg(℃)	-9.6	-10.7	-9.7	-11.2	-12.4	Tm(℃)	136.6	133.7	134.2	130.0	136.3
Tg(℃)	-9.6	-10.7	-9.7	-11.2	-12.4	Heat of fusion (J / g)	51.5	39.5	42.5	15.1	35.8
Viscosity @ 190 ℃ (cps)	880	518	1850	661	1040	Heat of fusion (J / g)	51.5	39.5	42.5	15.1	35.8
Viscosity @ 190 ℃ (cps)	880	518	1850	661	1040	Conversion Rate (%)	92.20	89.30	96.84	80.62	91.15
Catalyst activity (kg polymer / g catalyst)	4.72	4.57	4.96	2.70	4.07	Conversion Rate (%)	92.20	89.30	96.84	80.62	91.15
Catalyst activity (kg polymer / g catalyst)	4.72	4.57	4.96	2.70	4.07	Catalyst:
A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl						Catalyst:
						B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl

Table 6
Table 6						Example	30	31	32	33	34
Catalyst # 1	A	A	A	A	A	Example	30	31	32	33	34
Catalyst # 1	A	A	A	A	A	Catalyst # 1 feed rate (mol / min)	1.02E-06	5.22E-06	6.53E-06	6.53E-06	6.53E-06
Catalyst # 2	B	B	B	B	B	Catalyst # 1 feed rate (mol / min)	1.02E-06	5.22E-06	6.53E-06	6.53E-06	6.53E-06
Catalyst # 2	B	B	B	B	B	Catalyst # 2 feed rate (mol / min)	1.13E-07	7.65E-07	4.74E-07	6.20E-07	3.64E-07
Propylene feed rate (g / min)	14	14	14	14	14	Catalyst # 2 feed rate (mol / min)	1.13E-07	7.65E-07	4.74E-07	6.20E-07	3.64E-07
Propylene feed rate (g / min)	14	14	14	14	14	1,9 - decadiene feed rate (ml / min)	0.19	0.24	0.19	0.19	0.19
Hexane feed rate (ml / min)	90	90	90	90	90	1,9 - decadiene feed rate (ml / min)	0.19	0.24	0.19	0.19	0.19
Hexane feed rate (ml / min)	90	90	90	90	90	Polymerization temperature (℃)	115	115	110	110	115
Mn(kg/mol)	20.3	14.9	13.6	16.1	17.6	Polymerization temperature (℃)	115	115	110	110	115
Mn(kg/mol)	20.3	14.9	13.6	16.1	17.6	Mw(kg/mol)	96.2	34.3	30.2	30.4	36.5
Mz(kg/mol)	636.2	114.8	67.6	68.7	91.5	Mw(kg/mol)	96.2	34.3	30.2	30.4	36.5
Mz(kg/mol)	636.2	114.8	67.6	68.7	91.5	g′@Mz	0.46	0.72	0.95	0.88	0.85
Tc(℃)		91.4	91.8	94.3	84.4	g′@Mz	0.46	0.72	0.95	0.88	0.85
Tc(℃)		91.4	91.8	94.3	84.4	Tm(℃)		129.3	140.5	140.6	137.2
Tg(℃)		-10.0	-11.2	-8.9	-8.2	Tm(℃)		129.3	140.5	140.6	137.2
Tg(℃)		-10.0	-11.2	-8.9	-8.2	Heat of fusion (J / g)		46.9	28.3	38.4	20.8
Viscosity @ 190 ℃ (cps)		1030	1870	1360	2470	Heat of fusion (J / g)		46.9	28.3	38.4	20.8
Viscosity @ 190 ℃ (cps)		1030	1870	1360	2470	Conversion Rate (%)	56.38	95.32	97.29	97.24	87.82
Catalyst activity (kg polymer / g catalyst)	15.44	4.88	4.34	4.23	4.00	Conversion Rate (%)	56.38	95.32	97.29	97.24	87.82
Catalyst activity (kg polymer / g catalyst)	15.44	4.88	4.34	4.23	4.00	Catalyst:
A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl						Catalyst:
						B = rac - dimethylsilyl bis (2 - methyl) 4 - phenyl-indenyl) zirconium dimethyl

Examples 35-39

With dimethylsilyl bis (indenyl) hafnium dimethyl and dimethyl silyl (tetramethylcyclopropanecarboxylate Pentadienyl) (cyclododecyl) dimethyl titanium catalyst in the catalyst the ratio of 75mol% At a temperature within the range 85 至 105 ℃ prepared according to the general procedure of five samples, the difference is A small amount of a diene monomer, 1,9 - decadiene, and a propylene-α-olefin monomers added together Into. The detailed experimental conditions and results are given in Table 7.

Table 7
Table 7						Example	35	36	37	38	39
Catalyst # 1	A	A	A	A	A	Example	35	36	37	38	39
Catalyst # 1	A	A	A	A	A	Catalyst # 1 feed rate (mol / min)	5.22E-0 6	5.22E-0 6	5.22E-0 6	5.22E-0 6	5.22E-0 6
Catalyst # 2	C	C	C	C	C	Catalyst # 1 feed rate (mol / min)	5.22E-0 6	5.22E-0 6	5.22E-0 6	5.22E-0 6	5.22E-0 6
Catalyst # 2	C	C	C	C	C	Catalyst # 2 feed rate (mol / min)	1.75E-0 6	1.75E-0 6	1.75E-0 6	1.75E-0 6	1.75E-0 6
Propylene feed rate (g / min)	14	14	14	14	14	Catalyst # 2 feed rate (mol / min)	1.75E-0 6	1.75E-0 6	1.75E-0 6	1.75E-0 6	1.75E-0 6
Propylene feed rate (g / min)	14	14	14	14	14	1,9 - decadiene feed rate (ml / min)	0.24	0.24	0.24	0.24	0.24
Hexane feed rate (ml / min)	90	90	90	90	90	1,9 - decadiene feed rate (ml / min)	0.24	0.24	0.24	0.24	0.24
Hexane feed rate (ml / min)	90	90	90	90	90	Polymerization temperature (℃)	105	100	95	90	85
Mn(kg/mol)	9.6	15.7	14.1	15.2	29.3	Polymerization temperature (℃)	105	100	95	90	85
Mn(kg/mol)	9.6	15.7	14.1	15.2	29.3	Mw(kg/mol)	16.5	24.6	30	40.4	69.1
Mz(kg/mol)	33.4	48.4	70.7	103.1	222.6	Mw(kg/mol)	16.5	24.6	30	40.4	69.1
Mz(kg/mol)	33.4	48.4	70.7	103.1	222.6	g′@Mz	0.89	0.81	0.8	0.76	0.66
Tc(℃)	25.2	29.4	30.9	41.8	53.5	g′@Mz	0.89	0.81	0.8	0.76	0.66
Tc(℃)	25.2	29.4	30.9	41.8	53.5	Tm(℃)	67.3	76.1	81.2	91.3	102.3
Tg(℃)	-15.4	-13.3	-13.1	-8.1	-7.4	Tm(℃)	67.3	76.1	81.2	91.3	102.3
Tg(℃)	-15.4	-13.3	-13.1	-8.1	-7.4	Heat of fusion (J / g)	13.4	19.5	20.9	25.7	33.3
Viscosity @ 190 ℃ (cps)	194	291	568	1650	5210	Heat of fusion (J / g)	13.4	19.5	20.9	25.7	33.3
Viscosity @ 190 ℃ (cps)	194	291	568	1650	5210	Catalyst:
A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl						Catalyst:
						C = rac - dimethylsilyl bis (indenyl) hafnium dimethyl

Examples 40-43

Using rac - dimethylsilyl bis (indenyl) hafnium dimethyl and dimethylsilyl group (Tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl prepared according to the general procedure Four samples prepared, except that the small amount of a diene monomer 1,9 - decadiene, and as α- Propylene olefin monomers joined together. The detailed experimental conditions and results are given in Table 8.

Table 8
Table 8					Example	40	41	42	43
Catalyst # 1	A	A	A	A	Example	40	41	42	43
Catalyst # 1	A	A	A	A	Catalyst # 1 feed rate (mol / min)	8.49E-07	8.49E-07	8.49E-07	5.22E-07
Catalyst # 2	C	C	C	C	Catalyst # 1 feed rate (mol / min)	8.49E-07	8.49E-07	8.49E-07	5.22E-07
Catalyst # 2	C	C	C	C	Catalyst #
2 feed rate (mol / min)	8.26E-07	5.51E-07	5.51E-07	5.82E-07	Catalyst #
2 feed rate (mol / min)	8.26E-07	5.51E-07	5.51E-07	5.82E-07	Propylene feed rate (g / min)	14	14	14	14
1,9 - decadiene feed rate (ml / min)	0.05	0.02	0.05	0.19	Propylene feed rate (g / min)	14	14	14	14
1,9 - decadiene feed rate (ml / min)	0.05	0.02	0.05	0.19	Hexane feed rate (ml / min)	90	90	86	90
Polymerization temperature (℃)	100	95	90	95	Hexane feed rate (ml / min)	90	90	86	90
Polymerization temperature (℃)	100	95	90	95	Mn(kg/mol)	10.5	16.1	23	28.3
Mw(kg/mol)	19.5	24.4	39.4	94.8	Mn(kg/mol)	10.5	16.1	23	28.3
Mw(kg/mol)	19.5	24.4	39.4	94.8	Mz(kg/mol)	38	44.3	71.3	455.2
g′@Mz	0.92	0.93	0.93	0.54	Mz(kg/mol)	38	44.3	71.3	455.2
g′@Mz	0.92	0.93	0.93	0.54	Tc(℃)	47.7	53.7	71.0	37.4
Tm(℃)	94.4	98.6	112.5	101.2	Tc(℃)	47.7	53.7	71.0	37.4
Tm(℃)	94.4	98.6	112.5	101.2	Tg(℃)	-12.3	-11.1	-24.6	-10.3
Heat of fusion (J / g)	30.8	31.6	44.6	22.4	Tg(℃)	-12.3	-11.1	-24.6	-10.3
Heat of fusion (J / g)	30.8	31.6	44.6	22.4	Viscosity @ 190 ℃ (cps)	327	625	2370	-
Conversion Rate (%)	93.80	-	98.62	-	Viscosity @ 190 ℃ (cps)	327	625	2370	-
Conversion Rate (%)	93.80	-	98.62	-	Catalyst activity (kg polymer / g catalyst)	16.83	-	21.44	-
Catalyst:					Catalyst activity (kg polymer / g catalyst)	16.83	-	21.44	-
Catalyst:					A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl
C = rac - dimethylsilyl bis (indenyl) hafnium dimethyl

Examples 44-47

With rac-1 ,2 - ethylene - bis (4,7 - dimethyl-indenyl) hafnium dimethyl and dimethyl Silane group - (tetramethyl-cyclopentadienyl) (cyclododecyl) dimethyl titanium temperature 110 ℃ And a certain percentage range of the catalyst prepared in four samples. Examples 44-47 the condition (package Diolefins including added) in accordance with the general procedure, except that the small amount of a diene monomer, 1,9 - decadiene, and a propylene-α-olefin monomers joined together. The detailed experimental conditions and results Are given in Table 9.

Table 9
Table 9					Example	44	45	46	47
Catalyst # 1	A	A	A	A	Example	44	45	46	47
Catalyst # 1	A	A	A	A	Catalyst # 1 feed rate (mol / min)	6.5 3E-06	3.79E-06	2.74E-06	2.09E-06
Catalyst # 2	D	D	D	D	Catalyst # 1 feed rate (mol / min)	6.5 3E-06	3.79E-06	2.74E-06	2.09E-06
Catalyst # 2	D	D	D	D	Catalyst # 2 feed rate (mol / min)	4.25E-07	4.25E-07	4.2 5E-07	4.25E-07
Propylene feed rate (g / min)	14	14	14	14	Catalyst # 2 feed rate (mol / min)	4.25E-07	4.25E-07	4.2 5E-07	4.25E-07
Propylene feed rate (g / min)	14	14	14	14	1,9 - decadiene feed rate (ml / min)	0.09	0.09	0.09	0.09
Hexane feed rate (ml / min)	90	90	90	90	1,9 - decadiene feed rate (ml / min)	0.09	0.09	0.09	0.09
Hexane feed rate (ml / min)	90	90	90	90	Polymerization temperature (℃)	115	115	115	115
Mn(kg/mol)	21.5	20	21.2	16.1	Polymerization temperature (℃)	115	115	115	115
Mn(kg/mol)	21.5	20	21.2	16.1	Mw(kg/mol)	36.2	32.7	34	33.5
Mz(kg/mol)	100.1	95.6	123.7	128.8	Mw(kg/mol)	36.2	32.7	34	33.5
Mz(kg/mol)	100.1	95.6	123.7	128.8	Tc(℃)	41.0	51.5	59.8	74.4
Tm(℃)	94.3	97.6	103.4	109.4	Tc(℃)	41.0	51.5	59.8	74.4
Tm(℃)	94.3	97.6	103.4	109.4	Tg(℃)	-22.8	-23.8	-12.5	-18.9
Heat of fusion (J / g)	4.1	6.8	11.3	15.8	Tg(℃)	-22.8	-23.8	-12.5	-18.9
Heat of fusion (J / g)	4.1	6.8	11.3	15.8	Viscosity @ 190 ℃ (cps)	2090	1750	1570	1230
Conversion Rate (%)	83.58	83.95	71.84	63.10	Viscosity @ 190 ℃ (cps)	2090	1750	1570	1230
Conversion Rate (%)	83.58	83.95	71.84	63.10	Catalyst activity (kg polymer / g catalyst)	3.80	6.26	7.08	7.78
Catalyst:					Catalyst activity (kg polymer / g catalyst)	3.80	6.26	7.08	7.78
Catalyst:					A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl
D = rac-1 ,2 - ethylene-bis (4,7 - dimethyl-indenyl) hafnium dimethyl

Examples 48-51

Using rac - dimethylsilyl bis (2 - methyl-indenyl) zirconium dimethyl and dimethylsilyl Alkyl (tetramethyl cyclopentadienyl) (cyclododecyl) dimethyl titanium catalyst at temperature 80 ℃ and Agent ratio within the range 74 to 84mol% was prepared according to the general procedure four samples, the different Is a small amount of a diene monomer, 1,9 - decadiene, and a propylene-α-olefin monomer with Join. The detailed experimental conditions and results are given in Table 10.

Table 10
Table 10					Example	48	49	50	51
Catalyst # 1	A	A	A	A	Example	48	49	50	51
Catalyst # 1	A	A	A	A	Catalyst # 1 feed rate (mol / min)	6.5 3E-06	6.53E-06	6.53E-06	6.53E-06
Catalyst # 2	E	E	E	E	Catalyst # 1 feed rate (mol / min)	6.5 3E-06	6.53E-06	6.53E-06	6.53E-06
Catalyst # 2	E	E	E	E	Catalyst #
2 feed rate (mol / min)	1.23E-06	1.57E-06	1.92E-06	2.26E-06	Catalyst #
2 feed rate (mol / min)	1.23E-06	1.57E-06	1.92E-06	2.26E-06	Propylene feed rate (g / min)	14	14	14	14
1,9 - decadiene feed rate (ml / min)	0.14	0.14	0.14	0.14	Propylene feed rate (g / min)	14	14	14	14
1,9 - decadiene feed rate (ml / min)	0.14	0.14	0.14	0.14	Hexane feed rate (ml / min)	90	90	90	90
Polymerization temperature (℃)	80	80	80	80	Hexane feed rate (ml / min)	90	90	90	90
Polymerization temperature (℃)	80	80	80	80	Mn(kg/mol)	19.9	16	11.4	10
Mw(kg/mol)	43.8	36.9	25.9	19.2	Mn(kg/mol)	19.9	16	11.4	10
Mw(kg/mol)	43.8	36.9	25.9	19.2	Mz(kg/mol)	106.3	72.3	54.5	38.8
g′@Mz	0.88	0.93	0.93	0.93	Mz(kg/mol)	106.3	72.3	54.5	38.8
g′@Mz	0.88	0.93	0.93	0.93	Tc(℃)	49.0	53.3	58.6	53.1
Tm(℃)	109.9	107.8	103.2	102.0	Tc(℃)	49.0	53.3	58.6	53.1
Tm(℃)	109.9	107.8	103.2	102.0	Tg(℃)	-10.7	-7.4	-9.1	-9.6
Heat of fusion (J / g)	25.8	29.4	31.4	37.7	Tg(℃)	-10.7	-7.4	-9.1	-9.6
Heat of fusion (J / g)	25.8	29.4	31.4	37.7	Viscosity @ 190 ℃ (cps)	4680	2040	952	464
Catalyst:					Viscosity @ 190 ℃ (cps)	4680	2040	952	464
Catalyst:					A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl
E = rac - dimethylsilyl bis (2 - methyl-indenyl) zirconium dimethyl

Examples 52-57

Using rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and di Dimethylsilyl (tetramethyl-cyclopentadienyl) (cyclododecyl) dimethyl titanium at a temperature of 80 至 95 ℃ ratio of about 87mol% and a catalyst in accordance with the general process of the preparation of 6 samples, The difference is that (1) a small amount of a diene feedstock 1,9 - decadiene, and as the α-olefin monomer Propylene join; (2) a small amount of hydrogen is also added to the reactor. Detailed experimental conditions and results Results are given in Table 11. Example 52-57 shows: In addition to the catalyst and process conditions selected Items such as temperature outside the control of access of hydrogen added can effectively operate Mw, Mw / Mn, crystallization Degree of crystalline phase and an amorphous phase ratio. ...

Using rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and di Dimethylsilyl (tetramethyl-cyclopentadienyl) (cyclododecyl) dimethyl titanium at a temperature of 80 至 95 ℃ ratio of about 87mol% and a catalyst in accordance with the general process of the preparation of 6 samples, The difference is that (1) a small amount of a diene feedstock 1,9 - decadiene, and as the α-olefin monomer Propylene join; (2) a small amount of hydrogen is also added to the reactor. Detailed experimental conditions and results Results are given in Table 11. Example 52-57 shows: In addition to the catalyst and process conditions selected Items such as temperature outside the control of access of hydrogen added can effectively operate Mw, Mw / Mn, crystallization Degree of crystalline phase and an amorphous phase ratio. ...
							Example	52	53	54	55	56	57
Catalyst # 1	A	A	A	A	A	A	Example	52	53	54	55	56	57
Catalyst # 1	A	A	A	A	A	A	Catalyst # 1 feed rate (mol / min)	6.10E-06	6.10E-06	6.10E-06	6.10E-06	6.10E-06	6.10E-06
Catalyst # 2	B	B	B	B	B	B	Catalyst # 1 feed rate (mol / min)	6.10E-06	6.10E-06	6.10E-06	6.10E-06	6.10E-06	6.10E-06
Catalyst # 2	B	B	B	B	B	B	Catalyst # 2 feed rate (mol / min)	2.83E-07	2.83E-07	2.83E-07	2.83E-07	1.98E-07	1.98E-07
Propylene (g / min)	14	14	14	14	14	14	Catalyst # 2 feed rate (mol / min)	2.83E-07	2.83E-07	2.83E-07	2.83E-07	1.98E-07	1.98E-07
Propylene (g / min)	14	14	14	14	14	14	1,9 - decadiene feed rate (ml / min)	0.19	0.19	0.19	0.19	0.19	0.19
H2 feed rate (cc / min)	50	50	50	50	70	70	1,9 - decadiene feed rate (ml / min)	0.19	0.19	0.19	0.19	0.19	0.19
H2 feed rate (cc / min)	50	50	50	50	70	70	Hexane feed rate (ml / min)	90	90	90	90	90	90
Polymerization temperature (℃)	95	90	85	80	90	80	Hexane feed rate (ml / min)	90	90	90	90	90	90
Polymerization temperature (℃)	95	90	85	80	90	80	Mn(kg/mol)	12.6	11	12.5	15.7	18.1	11.7
Mw(kg/mol)	27.5	43.2	42.3	85.3	34	29.8	Mn(kg/mol)	12.6	11	12.5	15.7	18.1	11.7
Mw(kg/mol)	27.5	43.2	42.3	85.3	34	29.8	Mz(kg/mol)	72.2	127	153.4	468.3	126	99
g@Mz	0.82	0.74	0.8	0.66	0.8	0.84	Mz(kg/mol)	72.2	127	153.4	468.3	126	99
g@Mz	0.82	0.74	0.8	0.66	0.8	0.84	Tc(℃)	95.7	95.8	97.4	97.0	98.9	97.7
Tm(℃)	141.0	145.1	145.8	147.0	144.5	145.1	Tc(℃)	95.7	95.8	97.4	97.0	98.9	97.7
Tm(℃)	141.0	145.1	145.8	147.0	144.5	145.1	Tg(℃)	-14.6	-13.3	-12.3	-9.8	-17.2	-14.8
Heat of fusion (J / g)	38.5	45.4	35.9	35.4	49.3	39.2	Tg(℃)	-14.6	-13.3	-12.3	-9.8	-17.2	-14.8
Heat of fusion (J / g)	38.5	45.4	35.9	35.4	49.3	39.2	Viscosity @ 190 ℃ (cps)	668	1049	2148	16090	810	822
Catalyst:							Viscosity @ 190 ℃ (cps)	668	1049	2148	16090	810	822
Catalyst:							A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl
B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl

Examples 58-60

Using rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and di Dimethylsilyl (tetramethyl-cyclopentadienyl) (cyclododecyl) dimethyl titanium at a temperature of 115 ℃ and catalyst ratio within the range of about 87mol% was prepared according to the general procedure 3 samples, The difference is that (1) adding a small amount of 1,9 - decadiene as diene monomer; (2) of rac - dimethyl Silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and dimethyl silyl (tetramethyl Cyclopentadienyl) (cyclododecyl) dimethyl titanium catalyst pre-mixed and diluted in toluene Release, and then added under preactivated catalyst without the manifold; (3) the tetrakis (pentafluorophenyl) borate, N, N- Dimethylaniline iodide diluted in toluene, and then adding the catalyst manifold; (4) the catalyst manifold Start a catalyst activation. The detailed experimental conditions and results are given in Table 12. Example 58-60 show that the catalyst can be added to the reactor just before the online activation and activity in the reactor Technology. ...

Using rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and di Dimethylsilyl (tetramethyl-cyclopentadienyl) (cyclododecyl) dimethyl titanium at a temperature of 115 ℃ and catalyst ratio within the range of about 87mol% was prepared according to the general procedure 3 samples, The difference is that (1) adding a small amount of 1,9 - decadiene as diene monomer; (2) of rac - dimethyl Silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and dimethyl silyl (tetramethyl Cyclopentadienyl) (cyclododecyl) dimethyl titanium catalyst pre-mixed and diluted in toluene Release, and then added under preactivated catalyst without the manifold; (3) the tetrakis (pentafluorophenyl) borate, N, N- Dimethylaniline iodide diluted in toluene, and then adding the catalyst manifold; (4) the catalyst manifold Start a catalyst activation. The detailed experimental conditions and results are given in Table 12. Example 58-60 show that the catalyst can be added to the reactor just before the online activation and activity in the reactor Technology. ...
				Example	58	59	60
Catalyst # 1	A	A	A	Example	58	59	60
Catalyst # 1	A	A	A	Catalyst # 1 feed rate (mol / min)	4.06E-06	2.54E-06	1.52E-06
Catalyst # 2	B	B	B	Catalyst # 1 feed rate (mol / min)	4.06E-06	2.54E-06	1.52E-06
Catalyst # 2	B	B	B	Catalyst #
2 feed rate (mol / min)	2.95E-07	1.84E-07	1.11E-07	Catalyst #
2 feed rate (mol / min)	2.95E-07	1.84E-07	1.11E-07	Propylene (g / min)	14	14	14
1,9 - decadiene feed rate (ml / min)	0.14	0.14	0.14	Propylene (g / min)	14	14	14
1,9 - decadiene feed rate (ml / min)	0.14	0.14	0.14	Hexane feed rate (ml / min)	90	90	90
Polymerization temperature (℃)	115	115	115	Hexane feed rate (ml / min)	90	90	90
Polymerization temperature (℃)	115	115	115	Mn(kg/mol)	13.2	18.2	24.2
Mw(kg/mol)	34.5	50.8	69.9	Mn(kg/mol)	13.2	18.2	24.2
Mw(kg/mol)	34.5	50.8	69.9	Mz(kg/mol)	99.6	169	248.6
g′@Mz	0.79	0.72	0.69	Mz(kg/mol)	99.6	169	248.6
g′@Mz	0.79	0.72	0.69	Tc(℃)	90.6	92.9	93.0
Tm(℃)	137.0	139.6	142.6	Tc(℃)	90.6	92.9	93.0
Tm(℃)	137.0	139.6	142.6	Tg(℃)	-10.8	-10.0	-8.7
Heat of fusion (J / g)	32.5	32.9	28.4	Tg(℃)	-10.8	-10.0	-8.7
Heat of fusion (J / g)	32.5	32.9	28.4	Viscosity @ 190 ℃ (cps)	1657	3170	11600
Conversion Rate (%)	89.64	77.50	95.59	Viscosity @ 190 ℃ (cps)	1657	3170	11600
Conversion Rate (%)	89.64	77.50	95.59	Catalyst activity (kg polymer / g catalyst)	6.43	8.90	18.29
Catalyst:				Catalyst activity (kg polymer / g catalyst)	6.43	8.90	18.29
Catalyst:				A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl
B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl

Examples 61-66

With dimethyl silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and dimethylsilyl Alkyl (tetramethyl cyclopentadienyl) (cyclododecyl) dimethyl titanium at a temperature of 105-130 ℃ ratio of about 84.6mol% and the catalyst under the general procedure of Preparation 6 according to the above samples, different Is (1) adding a small amount of 1,9 - decadiene as diene monomer; (2) ethylene to the reactor Medium. The detailed experimental conditions and results are given in Table 13. The ethylene content of the polymer by Fourier transform infrared analysis (FTIR) obtained.

Table 13
Table 13							Example	61	62	63	64	65	66
Catalyst # 1	A	A	A	A	A	A	Example	61	62	63	64	65	66
Catalyst # 1	A	A	A	A	A	A	Catalyst # 1 feed rate (mol / min)	1.02E-06	1.02E-06	1.02E-06	1.02E-06	1.02E-06	1.02E-06
Catalyst # 2	B	B	B	B	B	B	Catalyst # 1 feed rate (mol / min)	1.02E-06	1.02E-06	1.02E-06	1.02E-06	1.02E-06	1.02E-06
Catalyst # 2	B	B	B	B	B	B	Catalyst # 2 feed rate (mol / min)	1.84E-07	1.84E-07	1.84E-07	1.84E-07	1.84E-07	1.84E-07
Propylene feed rate (g / min)	20	20	20	20	20	20	Catalyst # 2 feed rate (mol / min)	1.84E-07	1.84E-07	1.84E-07	1.84E-07	1.84E-07	1.84E-07
Propylene feed rate (g / min)	20	20	20	20	20	20	1,9 - decadiene feed rate (ml / min)	0.186	0.186	0.186	0.186	0.186	0.186
Ethylene feed rate (SLPM)	0.2	0.2	0.2	0.2	0.2	0.2	1,9 - decadiene feed rate (ml / min)	0.186	0.186	0.186	0.186	0.186	0.186
Ethylene feed rate (SLPM)	0.2	0.2	0.2	0.2	0.2	0.2	Hexane feed rate (ml / min)	90	90	90	90	90	90
Polymerization temperature (℃)	130	125	120	115	110	105	Hexane feed rate (ml / min)	90	90	90	90	90	90
Polymerization temperature (℃)	130	125	120	115	110	105	Mn(kg/mol)	13.1	12.3	11.8	15.1	15.3	17.7
Mw(kg/mol)	37.3	36.2	40.5	47.7	45.2	53.8	Mn(kg/mol)	13.1	12.3	11.8	15.1	15.3	17.7
Mw(kg/mol)	37.3	36.2	40.5	47.7	45.2	53.8	Mz(kg/mol)	149.2	122	132.1	153.9	206.8	180.7
g@Mz	0.67	0.65	0.63	0.61	0.56	0.56	Mz(kg/mol)	149.2	122	132.1	153.9	206.8	180.7
g@Mz	0.67	0.65	0.63	0.61	0.56	0.56	Tc(℃)	80.4	79.6	84.6	85.5	87.7	86.6
Tm(℃)	121.8	121.9	124.6	125.2	126.1	126.2	Tc(℃)	80.4	79.6	84.6	85.5	87.7	86.6
Tm(℃)	121.8	121.9	124.6	125.2	126.1	126.2	Tg(℃)	-15.0	-15.2	-14.9	-14.8	-15.0	-15.6
Heat of fusion (J / g)	32.4	43.3	51.7	50.5	50.4	49.7	Tg(℃)	-15.0	-15.2	-14.9	-14.8	-15.0	-15.6
Heat of fusion (J / g)	32.4	43.3	51.7	50.5	50.4	49.7	Viscosity @ 190 ℃ (cps)	1440	977	1090	1510	1530	1720
Ethylene content from FTIR (wt%)	4.3	3.5	3	2.6	2.9	2.9	Viscosity @ 190 ℃ (cps)	1440	977	1090	1510	1530	1720
Ethylene content from FTIR (wt%)	4.3	3.5	3	2.6	2.9	2.9	Conversion Rate (%)	68.11	82.57	89.87		92.79	92.18
Catalyst activity (kg polymer / g catalyst)	24.92	30.21	32.88		33.95	33.73	Conversion Rate (%)	68.11	82.57	89.87		92.79	92.18
Catalyst activity (kg polymer / g catalyst)	24.92	30.21	32.88		33.95	33.73	Catalyst:
A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl							Catalyst:
							B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl

Examples 67-71

With dimethyl silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and dimethylsilyl Alkyl (tetramethyl cyclopentadienyl) (cyclododecyl) dimethyl titanium at a temperature of 105 to 115 ℃ lower (except Example 69 above) by the general procedure in accordance with all of these samples were prepared, not With the (1) in Example 67 using a small amount of dicyclopentadiene (purchased from the dicyclopentadiene aldrich,, is first dissolved in toluene. And then the solution was subjected to a high temperature under nitrogen Activated alumina, and then under nitrogen at high temperature after the activation of the molecular sieve purification); (2) in Examples 68 and 70 using 1 - butene; (3) in Example 71 was added 1,9 - decane Dienes and 1 - hexene were used as diene monomer and comonomer. Example 69 with dimethylformamide Silyl group (tetramethyl cyclopentadienyl) (cyclododecyl) dimethyl titanium and rac - dimethyl Silyl bis (2 - methyl-indenyl) zirconium dimethyl catalyst. Detailed experimental conditions and results Results are given in Table 14. ...

With dimethyl silyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and dimethylsilyl Alkyl (tetramethyl cyclopentadienyl) (cyclododecyl) dimethyl titanium at a temperature of 105 to 115 ℃ lower (except Example 69 above) by the general procedure in accordance with all of these samples were prepared, not With the (1) in Example 67 using a small amount of dicyclopentadiene (purchased from the dicyclopentadiene aldrich,, is first dissolved in toluene. And then the solution was subjected to a high temperature under nitrogen Activated alumina, and then under nitrogen at high temperature after the activation of the molecular sieve purification); (2) in Examples 68 and 70 using 1 - butene; (3) in Example 71 was added 1,9 - decane Dienes and 1 - hexene were used as diene monomer and comonomer. Example 69 with dimethylformamide Silyl group (tetramethyl cyclopentadienyl) (cyclododecyl) dimethyl titanium and rac - dimethyl Silyl bis (2 - methyl-indenyl) zirconium dimethyl catalyst. Detailed experimental conditions and results Results are given in Table 14. ...
						Example	67	68	69	70	71
Catalyst # 1	A	A	A	A	A	Example	67	68	69	70	71
Catalyst # 1	A	A	A	A	A	Catalyst # 1 feed rate (mol / min)	5.22E-06	5.22E-06	2.09E-06	5.22E-06	5.22E-06
Catalyst # 2	B	B	E	B	B	Catalyst # 1 feed rate (mol / min)	5.22E-06	5.22E-06	2.09E-06	5.22E-06	5.22E-06
Catalyst # 2	B	B	E	B	B	Catalyst # 2 feed rate (mol / min)	7.65E-07	7.65E-07	4.25E-07	7.65E-07	7.65E-07
Propylene feed rate (g / min)	14	14	14	14	14	Catalyst # 2 feed rate (mol / min)	7.65E-07	7.65E-07	4.25E-07	7.65E-07	7.65E-07
Propylene feed rate (g / min)	14	14	14	14	14	Comonomer	Dicyclopentadiene	Butene-1	-	Butene-1	1,9 - decadiene
Comonomer feed rate (ml / min)	0.23	0.6	-	2.5	0.206	Comonomer	Dicyclopentadiene	Butene-1	-	Butene-1	1,9 - decadiene
Comonomer feed rate (ml / min)	0.23	0.6	-	2.5	0.206	1 - hexene flow rate (ml / min)	-	-	-	-	3.29
Hexane feed rate (ml / min)	90	90	90	90	90	1 - hexene flow rate (ml / min)	-	-	-	-	3.29
Hexane feed rate (ml / min)	90	90	90	90	90	Polymerization temperature (℃)	110	115	110	105	115
Mn(kg/mol)	-	-	12.2	-	-	Polymerization temperature (℃)	110	115	110	105	115
Mn(kg/mol)	-	-	12.2	-	-	Mw(kg/mol)	-	-	30.6	-	-
Mz(kg/mol)	-	-	84.3	-	-	Mw(kg/mol)	-	-	30.6	-	-
Mz(kg/mol)	-	-	84.3	-	-	Tc(℃)	-	-	72.3	86.0	42.6
Tm(℃)	-	-	112.1	124.8	89.8	Tc(℃)	-	-	72.3	86.0	42.6
Tm(℃)	-	-	112.1	124.8	89.8	Tg(℃)	-	-	-22.4	-12.3	-15.2
Heat of fusion (J / g)	-	-	23.3	38.4	27.0	Tg(℃)	-	-	-22.4	-12.3	-15.2
Heat of fusion (J / g)	-	-	23.3	38.4	27.0	Viscosity @ 190 ℃ (cps)	665	563	1420	1100	524
Conversion Rate (%)	74.40	98.07	65.78	-	98.98	Viscosity @ 190 ℃ (cps)	665	563	1420	1100	524
Conversion Rate (%)	74.40	98.07	65.78	-	98.98	Catalyst activity (kg polymer / g catalyst)	3.81	5.15	8.11	-	5.77
Catalyst:						Catalyst activity (kg polymer / g catalyst)	3.81	5.15	8.11	-	5.77
Catalyst:						A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl
B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl

Example 72

Example 72 in 500-ml autoclave batch reactor. First 125ml pure Of toluene into a stainless steel autoclave reactor, followed by adding 0.1ml of triisobutylaluminum (TIBAL) Solution (25wt.% TIBAL, in 5ml toluene diluted). The mixture was then stirred and added Heat to 120 ℃ until the pressure stability. The reactor was maintained at a slight positive pressure. Followed by stirring for Added 125ml prepurification propylene. The reaction mixture was heated to 120 ℃. In this reactor, Temperature premixed with nitrogen 1.5ml preactivated catalyst solution and by inserting the sleeve Tube into the reactor. The catalyst solution consisted of 32mg dimethylsilyl group (tetramethylcyclopentadienyl Dienyl) (cyclododecyl) dimethyl titanium, 1.9mg rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl and 1.6mg dimethylsilyl bis (indenyl) dimethyl Hafnium-based composition, and 62.1mg tetrakis (pentafluorophenyl) borate, N, N-dimethylaniline in 50ml of iodide Toluene. The polymerization was carried out for 15 minutes. Then the reactor was cooled to the atmospheric vent. In Collected in collection tank containing mainly solvent, polymer and unreacted monomers resulting mixture, and the First, the mixture was air-dried in a fume hood to evaporate most of the solvent, and then in a vacuum oven Dried at about 90 ℃ about 12 hours. The resulting polymer (12.79g) shows the peak crystallization temperature 102.9 ℃ (measured by DSC), glass transition temperature (Tg) -8.7 ℃ and a heat of fusion 51.9 J / g. Average molecular weight Mn / Mw / Mz is 33825/66387/267680. ...

Using rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl or di Dimethylsilyl (tetramethyl cyclopentadienyl) (ring dodecylamino) titanium dimethyl follow on General preparation procedure above three samples, the difference is only a catalyst. The racemic - two Dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl for the preparation of isotactic polypropylene, And the dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl For the preparation of amorphous polypropylene. The experimental conditions of the polymer sample and viscosity are given in Table 15.

Table 15
Table 15				Example	73	74	75
Catalyst	A	A	B	Example	73	74	75
Catalyst	A	A	B	Catalyst feed rate (mol / min)	5.08E-06	5.08E-06	5.67E-07
Propylene feed rate (g / min)	14	14	14	Catalyst feed rate (mol / min)	5.08E-06	5.08E-06	5.67E-07
Propylene feed rate (g / min)	14	14	14	Hexane feed rate (ml / min)	90	90	90
Polymerization temperature (℃)	130	125	110	Hexane feed rate (ml / min)	90	90	90
Polymerization temperature (℃)	130	125	110	Viscosity @ 190 ℃ (cps)	1132	2220	328
Catalyst:				Viscosity @ 190 ℃ (cps)	1132	2220	328
Catalyst:				A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl
B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl

From the previous embodiments in several samples analyzed to determine its degree of branching. In the present Description, the crystallinity of a branching index g 'is the value of a branched polymer molecular weight Mz measured. Result In Tables 1 to 13 are given.

Examples 4 and described in Examples 31-34 with solvent extraction of the sample classification. The results in Table 16 are given. With the selected classification level of GPC-DRI-VIS-LS and DSC. From these The analysis results are also given in Table 17. From Example 31 as described in the hierarchical level of the sample The complex viscosity range at 80 至 130 ℃ range measurements are given in Figure 5.

As described in Example 4 from the sample and the extraction solvent extraction fractions of a 13C NMR Analysis.

mm triad percentage of C-13 NMR spectrum of direct measurement; assumes that the mixture mm triple cell group depends only on the sample of aPP and scPP ("atactic polypropylene, respectively, and Semi-crystalline polypropylene ") the amounts of components through the known pure components aPP and scPP tacticity (Mm) volume ratio of each component can be calculated, which corresponds to the observed amount of the mixture mm. Next The values given display surface isotactic triad-based polymers, and three kinds of whole ungraded fractions Percentages. Calculated data generated using the following assumptions: isotactic and atactic polymer is a block reference Polymer chain segment of the regularity of the symbol. Using methyl three cell groups, we calculate isotactic poly reference Composition has 94.7% mm, atactic polymer contained 13.6% reference. ...

mm triad percentage of C-13 NMR spectrum of direct measurement; assumes that the mixture mm triple cell group depends only on the sample of aPP and scPP ("atactic polypropylene, respectively, and Semi-crystalline polypropylene ") the amounts of components through the known pure components aPP and scPP tacticity (Mm) volume ratio of each component can be calculated, which corresponds to the observed amount of the mixture mm. Next The values given display surface isotactic triad-based polymers, and three kinds of whole ungraded fractions Percentages. Calculated data generated using the following assumptions: isotactic and atactic polymer is a block reference Polymer chain segment of the regularity of the symbol. Using methyl three cell groups, we calculate isotactic poly reference Composition has 94.7% mm, atactic polymer contained 13.6% reference. ...	％mm	% Calculated isotactic polymers
	％mm	% Calculated isotactic polymers	Unrated polymer	68	66
Hexane-soluble fraction	16	About 2%	Unrated polymer	68	66
Hexane-soluble fraction	16	About 2%	Heptane-soluble fraction	76	76
Heptane-insoluble fraction	89	93	Heptane-soluble fraction	76	76

Table 16
Table 16					Sample	Example 31	Example 33	Example 32	Example 34
Hexane solubles at room temperature, wt%	29.17	42.52	55.39	74.4	Sample	Example 31	Example 33	Example 32	Example 34
Hexane solubles at room temperature, wt%	29.17	42.52	55.39	74.4	Soxhlet hexane solubles, wt%	25.14	15.17	10.55	6.93
Soxhlet heptane solubles, wt%	7.88	7.1	8.53	0.44	Soxhlet hexane solubles, wt%	25.14	15.17	10.55	6.93
Soxhlet heptane solubles, wt%	7.88	7.1	8.53	0.44	Soxhlet heptane insolubles, wt%	35.32	35	25.15	17.8

Table 17
Table 17					Example 4
	Hexane at room temperature can be Solubles	Heptane SOGREAH Special solubles	Heptane SOGREAH Special solubles		Example 4
	Hexane at room temperature can be Solubles	Heptane SOGREAH Special solubles	Heptane SOGREAH Special solubles		Mn(kg/mol)	6.6	10.3	16.5	-
Mw(kg/mol)	14.3	30.2	31.3	-	Mn(kg/mol)	6.6	10.3	16.5	-
Mw(kg/mol)	14.3	30.2	31.3	-	Mz(kg/mol)	32.2	58.5	53.2	-
g′@Mz	1.16	0.86	0.87	-	Mz(kg/mol)	32.2	58.5	53.2	-
g′@Mz	1.16	0.86	0.87	-	Tc(℃)	-	105.2	112.8	-
Tm(℃)	-	138.2	145.2	-	Tc(℃)	-	105.2	112.8	-
Tm(℃)	-	138.2	145.2	-	Tg(℃)	-11.1	-	-	-
Heat of fusion (J / g)	0.0	68.6	108.9	-	Tg(℃)	-11.1	-	-	-
Heat of fusion (J / g)	0.0	68.6	108.9	-
Example 31
Example 31						Hexane at room temperature can be Solubles	Soxhlet has Alkyl solubles	Soxhlet Geng Alkyl solubles	Soxhlet Geng Insoluble alkyl
Mn(kg/mol)	9.5	20.9	20.1	20.8		Hexane at room temperature can be Solubles	Soxhlet has Alkyl solubles	Soxhlet Geng Alkyl solubles	Soxhlet Geng Insoluble alkyl
Mn(kg/mol)	9.5	20.9	20.1	20.8	Mw(kg/mol)	12.7	48	56.3	47.4
Mz(kg/mol)	25	131.5	148.8	150.2	Mw(kg/mol)	12.7	48	56.3	47.4
Mz(kg/mol)	25	131.5	148.8	150.2	g′@Mz	1.08	0.68	0.64	0.63
Tc(℃)	-	93.3	101.4	105.2	g′@Mz	1.08	0.68	0.64	0.63
Tc(℃)	-	93.3	101.4	105.2	Tm(℃)	-	128.2	133.5	138.3
Tg(℃)	-11.8	-8.3	-	-	Tm(℃)	-	128.2	133.5	138.3
Tg(℃)	-11.8	-8.3	-	-	Heat of fusion (J / g)	0.0	52.5	66.1	70.7

Examples 12, 22 and 49 of the viscosity of the product at a temperature within Range 80 至 130 ℃ measured. The complex viscosity is given in outline in Figure 1. These data demonstrate that the above three paragraphs characteristics.

With selected samples and their blends tested adhesive properties. The pure polymer and a tackifier, Oils or waxes and stabilizers to form a hot melt adhesive compounding blends. These polymers and their blends Performance relative to typical commercially available from Henkel and Chief of the EVA blends tested. Blending in Low shear under high temperature to form a fluid melt. The mixing temperature may be about 130-190 ℃.

Escorez ^TM5637 dicyclopentadiene raw materials by having a ring and ball softening point of 130 ℃ Hydrogenated aromatic modified resin, commercially available from ExxonMobil Chemical Company in Houston, Texas.

Paraflint H-1 as the Fisher-Tropsch wax, is displayed at 250 ° F melt viscosity 10mpa · sec, purchased from Moore and Munger.

Aristowax 165 as refined paraffin wax, purchased from Frank B Ross Co in Jersey City New Jersey. It is separated from the oil, with a temperature 158 至 165 ° F.

Henkel Hot Melt 80-8368 for commercial hot-melt, the EVA, tackifiers and waxes Blend made available from Henkel Corp.

MAPP 40 is maleic anhydride modified polypropylene having an acid value of 50, a viscosity at 190 ℃ 300cp and a softening point of 149 ℃, purchased from Chusei, USA.

Chief Hot Melt 268 for commercial hot melt from EVA, tackifiers and waxes, shopping Since Chief Adhesives.

KAYDOL_ refined white mineral oil is high, the saturated aliphatic and alicyclic non-polar hydrocarbons, A pour point of -20 ℃, at 40 ℃ with a dynamic viscosity 64 to 70cSt, available from Witco.

Licomont AR 504 is maleic anhydride-grafted polypropylene wax having an acid value 41, at 190 ℃, viscosity 373mPas and the softening point 156 ℃, purchased from Clarient.

AC 540 is an ethylene acrylic acid copolymer with an acid value of 40, a viscosity at 575 at 140 ℃ And drop point 105 ℃, purchased from Honeywell.

Polywax 2000 as polyethylene wax, available from Baker Petrolite Plain BOPP (bi- Biaxially oriented polypropylene film), a film thickness of 28 micron available from Mobil Films.

Corona treated BOPP (biaxially oriented polypropylene film), a film thickness of 28 microns was purchased from Mobil Films.

Cardboard 84A as having 20% recycled fiber gray Poster Board 20 pt paper system Into cardboard, purchased from Huckster Packaging and supply, Inc.in Houston, Texas.

84B as an ordinary cardboard cardboard poster clay coated newsprint (poster board clay coated news print), purchased from Huckster packaging and supply, Inc.in Houston, Texas.

84C as an ordinary cardboard corrugated cardboard 200 # blanks purchased from Huckster packaging and supply, Inc.in Houston, Texas.

Product name	Description	Source
Product name	Description	Source	Tackifier
Escorez_1102RM	C5 tackifier	ExxonMobil Chemical Company	Tackifier
Escorez_1102RM	C5 tackifier	ExxonMobil Chemical Company	Escorez_2203	Low aromatic modified hydrocarbon resin, having a narrow molecular Weight distribution, the C5, C6 and C9 olefins and two Olefin feedstock production, with the ball softening point of about 95 ℃	ExxonMobil Chemical Company
Escorez_2393	High aromatic modified hydrocarbon resin, the C5, C6 And C9 olefins and diolefins raw materials, with a There are global softening point of about 93 ℃	ExxonMobil Chemical Company	Escorez_2203		ExxonMobil Chemical Company
Escorez_2393		ExxonMobil Chemical Company	Escorez_2596	Low aromatic modified hydrocarbon resin, having a broad molecular Weight distribution, the C5, C6 and C9 olefins and two Olefin feedstock production, with the ball softening point of about 96 ℃	ExxonMobil Chemical Company
Escorez_5637	Hydrogenated aromatic modified resin, the dicyclopentadiene Ene raw materials production, display ball softening point of 130 ℃	ExxonMobil Chemical Company	Escorez_2596		ExxonMobil Chemical Company
Escorez_5637		ExxonMobil Chemical Company	Escorez_5690	Hydrogenated aromatic modified resin, the dicyclopentadiene Ene raw materials production, display ball softening point of 130 ℃	ExxonMobil Chemical Company
Oil			Escorez_5690		ExxonMobil Chemical Company
Oil			Primol 352	Hydrogenated paraffinic oils	ExxonMobil Chemical Company
Primol 876	Naphthenic oil	ExxonMobil Chemical Company	Primol 352	Hydrogenated paraffinic oils	ExxonMobil Chemical Company
Primol 876	Naphthenic oil	ExxonMobil Chemical Company	Flexon 876	Naphthenic oil	ExxonMobil Chemical Company
Kadol oil	Refined white mineral oil	Witco	Flexon 876	Naphthenic oil	ExxonMobil Chemical Company
Kadol oil	Refined white mineral oil	Witco	Polymer / binder

Escorene UL 7720	The ethylene-vinyl acetate copolymer having about 29wt% of vinyl acetate and a melt index 150dg/min.	ExxonMobil Chemical Company
Escorene UL 7720		ExxonMobil Chemical Company	NSC Easymelt	Hot melt adhesives for nonwoven applications	National Starch，Bound Brook，NJ
Henkel Hot Melt 80-8368	Commercially available EVA, tackifier and wax binder	Henkel Corp	NSC Easymelt	Hot melt adhesives for nonwoven applications	National Starch，Bound Brook，NJ
Henkel Hot Melt 80-8368	Commercially available EVA, tackifier and wax binder	Henkel Corp	Chief Hot Melt 268	Commercially available EVA, tackifier and wax binder	Chief Adhesives
Advantra 9250	Commercially available ethylene / octene-1 metallocene polymerization Material, a tackifier and a wax binder	Fuller	Chief Hot Melt 268	Commercially available EVA, tackifier and wax binder	Chief Adhesives
Advantra 9250		Fuller	Tite Bond Wood Glue	Water-based adhesives	Home Depot，Houston Texas
Dap Glue	Solvent-based wood glue	Home Depot，Houston Texas	Tite Bond Wood Glue	Water-based adhesives	Home Depot，Houston Texas
Dap Glue	Solvent-based wood glue	Home Depot，Houston Texas	Wax
Aristowax 165	Refined petroleum wax, melting temperature :158-165 ° F	Frank B Ross，Jersey City，NJ	Wax
Aristowax 165	Refined petroleum wax, melting temperature :158-165 ° F	Frank B Ross，Jersey City，NJ	AC 8 lot 500081EQ	Polyethylene wax	Honeywell，New Jersey
Paraflint H-1	Fisher-Tropsch wax, 10mPa @ 250 ° F	Moore and Munger	AC 8 lot 500081EQ	Polyethylene wax	Honeywell，New Jersey
Paraflint H-1	Fisher-Tropsch wax, 10mPa @ 250 ° F	Moore and Munger	AR-504	Maleated PE wax, acid value and viscosity 373 41 mPa @ 190 ℃	Clarient
AC-540	Ethylene acrylic acid copolymer having an acid value of 40 And viscosity of 575cps @ 140 ℃	Honeywell，New Jersey	AR-504		Clarient
AC-540		Honeywell，New Jersey	Polywax 2000	Polyethylene wax	Baker Petrolite
AC-1302P	Maleated polypropylene	Honeywell	Polywax 2000	Polyethylene wax	Baker Petrolite
AC-1302P	Maleated polypropylene	Honeywell	P-C80	Fisher-Tropsch wax grading	Moore and Munger
MAPP-40	Maleic acid-modified polypropylene having an acid value of 50 And viscosity of 300cps @ 190 ℃	Chusei，Pasadena Texas	P-C80	Fisher-Tropsch wax grading	Moore and Munger
MAPP-40		Chusei，Pasadena Texas	Antioxidants and other additives
Irganox 1010	Phenolic antioxidant	Ciba-Geigy	Antioxidants and other additives
Irganox 1010	Phenolic antioxidant	Ciba-Geigy	Dolomite 16 mesh	Sand	Fordamin Company Ltd(UK)
Microcarb MC 50F	Calcium carbonate	Microfine Minerals Ltd(UK)	Dolomite 16 mesh	Sand	Fordamin Company Ltd(UK)
Microcarb MC 50F	Calcium carbonate	Microfine Minerals Ltd(UK)	Glass beads of 3F type	Glass Beads	Sovitec SA (Belgium)
TiO2 Lot：TR92	Titania	Hunstman Tioxide Ltd(UK)	Glass beads of 3F type	Glass Beads	Sovitec SA (Belgium)
TiO2 Lot：TR92	Titania	Hunstman Tioxide Ltd(UK)	Test surface
Metalized acrylic coating	Cereal boxes for the metallization of an acrylic Buka coated paperboard	General Mills	Test surface
Metalized acrylic coating		General Mills	Uncoated CB testliner	1250gr/m2, used vegetable tray	Kappa，Holland
Cardboard 84A	Gray poster 20pt paper made from paper Board, with 20% recycled content	Huckster Packaging and Supply， Houston，TX	Uncoated CB testliner	1250gr/m2, used vegetable tray	Kappa，Holland

Cardboard 84B	Clay coated paperboard ordinary newsprint posters	Huckster Packaging and Supply， Houston，TX
Cardboard 84B	Clay coated paperboard ordinary newsprint posters	Huckster Packaging and Supply， Houston，TX	Cardboard 84C	200 # ordinary corrugated cardboard blanks	Huckster Packaging and Supply， Houston，TX
Inland Paper Board	Performance Containerboard	Inland Paper Board and Packaging Companyl of Rome	Cardboard 84C	200 # ordinary corrugated cardboard blanks	Huckster Packaging and Supply， Houston，TX
Inland Paper Board	Performance Containerboard	Inland Paper Board and Packaging Companyl of Rome	Black White Fabric	Printed stretch 100% cotton, with a Thread Count 17 × 13/cm², More relaxed weave woven Matter	High Fashion Fabrics，Houston Texas
Formica	Clip (Tabs) by a standard sheet of Formica Composition.	Lowe’s Hardware，Houston Texas	Black White Fabric		High Fashion Fabrics，Houston Texas
Formica	Clip (Tabs) by a standard sheet of Formica Composition.	Lowe’s Hardware，Houston Texas	Blue fabric	Clip (Tabs) by the Blue Stock 038COTP 100% cotton (Thread Count 21x 45/cm²With weight 0.022g/cm², A Kind of dense weave cotton fabric) composition.	High Fashion Fabrics，Houston Texas.
Catalog paper	Hot melt adhesive through law books of paper (by checking Test OK)	Seton Catalog	Blue fabric		High Fashion Fabrics，Houston Texas.
Catalog paper		Seton Catalog	NWC	Nonwoven Coverstock, Paratherm PT 120/20	Lohmann，Germany
PE	Polyethylene, white opaque micro-embossed CO / EX Film (rubberized inside), Reference #: CM001ARIE000757-C	Tacolin Ltd，UK	NWC	Nonwoven Coverstock, Paratherm PT 120/20	Lohmann，Germany
PE		Tacolin Ltd，UK	Polyester (PET) structure	Polyester structure
BOPP	Biaxially oriented polypropylene film, 28μm	Mobil Films，Rochester，NY	Polyester (PET) structure	Polyester structure
BOPP	Biaxially oriented polypropylene film, 28μm	Mobil Films，Rochester，NY	Corona treated BOPP	Corona treatment, a biaxially oriented polypropylene film, 28μm	Mobil Films，Rochester，NY
PP cast film structure	Cast film		Corona treated BOPP		Mobil Films，Rochester，NY

REXTAC RT 2730 as propylene, butene and ethylene copolymers, having about 67.5mol % Propylene, butylene about 30.5mol% ethylene and about 2mol% by Huntsman, Company Health Production. The copolymer has about 15mol% BB two cell groups, about 43mol% PB two cell groups and About 43mol% PP two groups of units. A melting point of 70 ℃ (with melting range 25 至 116 ℃), Tg of -25 ℃, a crystallinity of about 7%, enthalpy 10J / g (measured by DSC). Mn, 8260, Mw of 59100 and Mz of 187900 (measured by GPC). Mw / Mn of 7.15.

REXTAC RT 2715 as propylene, butene and ethylene copolymers, having about 67.5mol % Propylene, butylene about 30.5mol% ethylene and about 2mol% by Huntsman, Company Health Production. The copolymer has about 11mol% BB two cell groups, about 40mol% PB two cell groups and About 49mol% PP two groups of units. A melting point of 76 ℃ (with melting Area 23 至 124 ℃), Tg of -22 ℃, a crystallinity of about 7%, enthalpy 11J / g (measured by DSC). Mn, 6630, Mw of 51200 and Mz of 166,700 (measured by GPC). Mw / Mn of 7.7.

All ingredients are by wt% binder total, except in Table 18 to Table 50 are listed in the composition Otherwise noted.

Table 18 Applications formula (percentage) and performance values
							Formula	A	B	C	D	E	F
Example 42	80						Formula	A	B	C	D	E	F
Example 42	80						Escorez ^TM5637	7	7	13	10	10
Paraflint H-1	13	13	7	10			Escorez ^TM5637	7	7	13	10	10
Paraflint H-1	13	13	7	10			Example 27		80	80	80	80
Aristowax 165					10		Example 27		80	80	80	80
Aristowax 165					10		Henkel standard Hot Melt 80-8368						100
The time at 190 ℃ Viscosity (cps)	1091	870	1152	1000	945	700	Henkel standard Hot Melt 80-8368						100
The time at 190 ℃ Viscosity (cps)	1091	870	1152	1000	945	700	SAFT，F(℃)	233 (112)	253 (123)	257 (125)	253 (123)	259 (126)	182 (83)
Curing time (sec)	1.5	1.5	2	1	2.5	1	SAFT，F(℃)	233 (112)	253 (123)	257 (125)	253 (123)	259 (126)	182 (83)
Curing time (sec)	1.5	1.5	2	1	2.5	1	Percentage of the matrix fiber tear Temperature -12 ℃, the folder	0	80	95	10	100	100

Table 19 blend aPP / scPP and branched aPP-g-scPP contrast
Table 19 blend aPP / scPP and branched aPP-g-scPP contrast								Burden	A	B	C	D	E	F	G
Example 73	100			5				Burden	A	B	C	D	E	F	G
Example 73	100			5				Example 74		100		39
Example 75			100	39				Example 74		100		39
Example 75			100	39				Example 29					82
Irganox 1010				1	1			Example 29					82
Irganox 1010				1	1			MAPP 40				5	5
Escorez ^TM 5637				7	5			MAPP 40				5	5
Escorez ^TM 5637				7	5			Paraflint H-1				5	7
Henkel Standard Hot Melt 80-8368						100		Paraflint H-1				5	7
Henkel Standard Hot Melt 80-8368						100		Chief Standard Hot Melt 268							100
The time at 190 ℃ Viscosity (cps)	1132	2220	328	711	812	807	1055	Chief Standard Hot Melt 268							100
The time at 190 ℃ Viscosity (cps)	1132	2220	328	711	812	807	1055	SAFT，F(℃)	-	-	-	263 (128)	266 (130)	173 (78)	175 (79)
Curing time (sec)	＞6	6	Unbonded	1.5-2.0	1.5	1	1.5	SAFT，F(℃)	-	-	-	263 (128)	266 (130)	173 (78)	175 (79)
Curing time (sec)	＞6	6	Unbonded	1.5-2.0	1.5	1	1.5	Percentage of the matrix fiber tear Low temperature -12 ℃, cardboard	100	100	0	100	85	100	100
Percentage of the matrix fiber tear Temperature 20-25 ℃, the folder	0	5	0	100	100	100	100		100	100	0	100	85	100	100

Table 20 branching aPP-g-scPP and propylene / ethylene copolymer Comparison
												Burden	A	B	C	D	E	F	G	H	I	J	K
Example 41	100	90	90									Burden	A	B	C	D	E	F	G	H	I	J	K
Example 41	100	90	90									Example 16				100	90	90
C3/C2							100	90	90			Example 16				100	90	90
C3/C2							100	90	90			Escorez 5637		7	3		7	3		7	3
Paraflint H-1		3	7		3	7		3	7			Escorez 5637		7	3		7	3		7	3
Paraflint H-1		3	7		3	7		3	7			Henkel Standard Hot Melt 80-8368										100
Chief Standard Hot Melt 268											100	Henkel Standard Hot Melt 80-8368										100
Chief Standard Hot Melt 268											100	SAFT，°F	204	195	198	215	198	200	198	199	179	171	185
Curing time (sec)	6	5	2	＞6	6	1.5	6	3	＞6	2	1	SAFT，°F	204	195	198	215	198	200	198	199	179	171	185
Curing time (sec)	6	5	2	＞6	6	1.5	6	3	＞6	2	1	Percentage of the matrix fiber tear Temperature -12 ℃, the folder	0	100	0	100	100	0	100	60	0	100	100

For the C3/C2 ratio. The polymer having an ethylene content of about 10wt% of an ethylene / propylene Copolymer. The polymer racemic - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) Zirconium dimethyl at a polymerization temperature under 70 ℃ according to the above general procedure of Example 1 was prepared, the type of Using only a catalyst. The polymer having a peak melting temperature 95 ℃ and 190 ℃ Viscosity at 1368cps.

Table 21 of aPP-g-scPP variety of polymers and polymer blends oil
											Burden	A	B	C	D	E	F	G	H	I	J
Example 26	74	69			78	72					Burden	A	B	C	D	E	F	G	H	I	J
Example 26	74	69			78	72					Example 25			74	69			78	72
Example 23					5	9	5	9			Example 25			74	69			78	72
Example 23					5	9	5	9			Irganox 1010	1	1	1	1	1＜	1＜	1＜	1＜
Kaydol oil	10	10	10	10	5	9	5	9			Irganox 1010	1	1	1	1	1＜	1＜	1＜	1＜
Kaydol oil	10	10	10	10	5	9	5	9			Escorez ^TM 5637	10	10	10	10	7	6	7	6
Paraflint H-1	5	10	5	10	5	4	5	4			Escorez ^TM 5637	10	10	10	10	7	6	7	6
Paraflint H-1	5	10	5	10	5	4	5	4			Henkel Standard Hot Melt 80-8368									100
Chief Standard Hot Melt 268										100	Henkel Standard Hot Melt 80-8368									100
Chief Standard Hot Melt 268										100	The time at 190 ℃ Viscosity (cps)	315	120	525	445	358	262	888	724	1002	732
SAFT，F(℃)											The time at 190 ℃ Viscosity (cps)	315	120	525	445	358	262	888	724	1002	732
SAFT，F(℃)											Curing time (sec)	3	1.5	1.5	1	1.5	1.5	3	3	1.5	1.0
Percentage of the matrix fiber tear Temperature 20-25 ℃, the folder	100	20	100	100	100	100	100	100	100	100	Curing time (sec)	3	1.5	1.5	1	1.5	1.5	3	3	1.5	1.0
	100	20	100	100	100	100	100	100	100	100	Percentage of the matrix fiber tear Temperature 5 ℃, the folder	-	-	-	-	100	100	100	100	100	100

Table 22 branching aPP-g-scPP comparison of the various formulations
										Burden	A	B	C	D	E	F	G	H	I
Example 25	92.5	78.6	78.6							Burden	A	B	C	D	E	F	G	H	I
Example 25	92.5	78.6	78.6							Example 69		5	5
Example 29				82	84.5	82	82			Example 69		5	5
Example 29				82	84.5	82	82			Escorez ^TM5400						5	7
AR 504		5								Escorez ^TM5400						5	7
AR 504		5								MAPP 40			5	5	2.5	5	5
Irganox 1010	.5	.4	.4	1	1	1	1			MAPP 40			5	5	2.5	5	5
Irganox 1010	.5	.4	.4	1	1	1	1			Kaydol oil		5	5
Escorez(tm)5637	2	1.7	1.7	5	5					Kaydol oil		5	5
Escorez(tm)5637	2	1.7	1.7	5	5					Paraflint H-1	5	4.3	4.3	7	7	7	5
Henkel Standard Hot Melt 80-8368								100		Paraflint H-1	5	4.3	4.3	7	7	7	5
Henkel Standard Hot Melt 80-8368								100		Chief Standard Hot Melt 268									100
The viscosity at 190 ℃ (cps)	790	695	688	688	758	750	830	834	1050	Chief Standard Hot Melt 268									100
The viscosity at 190 ℃ (cps)	790	695	688	688	758	750	830	834	1050	SAFT，°F	263	＞250	＞250	265	266	265	265	184	171
Curing time (sec)	2.5	2	2	1.5	1.5	1.5	1.75	1	1.5	SAFT，°F	263	＞250	＞250	265	266	265	265	184	171
Curing time (sec)	2.5	2	2	1.5	1.5	1.5	1.75	1	1.5	Percentage of the matrix fiber tear Low temperature -12 ℃, cardboard	10	98	100	75	60	90	100	100	100
Percentage of the matrix fiber tear Temperature 20-25 ℃, the folder	34	100	100	100	100	100	100	100	100		10	98	100	75	60	90	100	100	100

Table 23 has Escorez (tm) 5400 of the hard and soft aPP-g-scPP Mixture
										Burden	A	B	C	D	E	F	G	H	I
Example 28	9	9	9	9	9	9	9			Burden	A	B	C	D	E	F	G	H	I
Example 28	9	9	9	9	9	9	9			Example 17	78
Example 40		78								Example 17	78
Example 40		78								Example 21			78
Example 20				78						Example 21			78
Example 20				78						Example 67					78
Example 25						78				Example 67					78
Example 25						78				Example 26							78
Irganox 1010	1	1	1	1	1	1	1			Example 26							78
Irganox 1010	1	1	1	1	1	1	1			Escorez ^TM5400	7	7	7	7	7	7	7
Paraflint H-1	5	5	5	5	5	5	5			Escorez ^TM5400	7	7	7	7	7	7	7
Paraflint H-1	5	5	5	5	5	5	5			Henkel Standard Hot Melt 80-8368								100
Chief Standard Hot Melt 268									100	Henkel Standard Hot Melt 80-8368								100
Chief Standard Hot Melt 268									100	The viscosity at 190 ℃ (cps)	344	306	548	505	521	1185	404	783	1090
SAFT，(°F)										The viscosity at 190 ℃ (cps)	344	306	548	505	521	1185	404	783	1090
SAFT，(°F)										Curing time (sec)	3	3.5	3.5	2.5	1.5	＞2	1.5	1	1.5
Percentage of the matrix fiber tear Temperature 5 ℃, the folder	50	50	90	65	100	100	100	100	100	Curing time (sec)	3	3.5	3.5	2.5	1.5	＞2	1.5	1	1.5
	50	50	90	65	100	100	100	100	100	Percentage of the matrix fiber tear Temperature 20-25 ℃, the folder	100	100	100	100	100	100	100	100	100
Shore A hardness	74	77	54	63	76	76	76	80	85		100	100	100	100	100	100	100	100	100

No Table 24.

Table 25 types of wax and contrast two types of polymers
Table 25 types of wax and contrast two types of polymers												Burden	A	B	C	D	E	F	G	H	I	J	K
Paraflint H-1	0	10	0	0	0	0	10	0	0			Burden	A	B	C	D	E	F	G	H	I	J	K
Paraflint H-1	0	10	0	0	0	0	10	0	0			Example 29	82	82	82	82	0	0	0	0	0
Example 62					82	82	82	82	82			Example 29	82	82	82	82	0	0	0	0	0
Example 62					82	82	82	82	82			Escorez ^TM5637	7	7	7	7	7	7	7	7	7
Irganox 1010	1	1	1	1	1	1	1	1	1			Escorez ^TM5637	7	7	7	7	7	7	7	7	7
Irganox 1010	1	1	1	1	1	1	1	1	1			AC 540				10	10				5
Poly wax 2000	10							10	5			AC 540				10	10				5
Poly wax 2000	10							10	5			Licowax PP 230			10			10
Henkel Standard Hot Melt 80-8368										100		Licowax PP 230			10			10
Henkel Standard Hot Melt 80-8368										100		Chief Standard Hot Melt 268											100
The time at 190 ℃ Viscosity (cps)	820	763	1140	1254	848	977	588	691	715	765	1131	Chief Standard Hot Melt 268											100
The time at 190 ℃ Viscosity (cps)	820	763	1140	1254	848	977	588	691	715	765	1131	Curing time (sec)	0.5	1	4	2	1.5	4+	1	0.5	1	1	1.5
Percentage of the matrix fiber tear Low temperature -12 ℃, cardboard	0	0	95	50	70	100	0	0	50	100	100	Curing time (sec)	0.5	1	4	2	1.5	4+	1	0.5	1	1	1.5
	0	0	95	50	70	100	0	0	50	100	100	Percentage of the matrix fiber tear Temperature 20-25 ℃, the folder	100	0	98	100	100	100	0	5	100	100	100

Table 26 butene modified aPP-g-scPP ratio of response
Table 26 butene modified aPP-g-scPP ratio of response						Burden	A	B	C	D	E
Example 68	100		93			Burden	A	B	C	D	E
Example 68	100		93			Example 70		100		93
Escorez ^TM5637			2	2		Example 70		100		93
Escorez ^TM5637			2	2		Paraflint H-1			5	5
Henkel Standard Hot Melt 80-8368					100	Paraflint H-1			5	5
Henkel Standard Hot Melt 80-8368					100	The time at 190 ℃ Viscosity (cps)	563	1100	485	1140	750
Curing time (sec)	2.5	＞3	1.5	2	1	The time at 190 ℃ Viscosity (cps)	563	1100	485	1140	750
Curing time (sec)	2.5	＞3	1.5	2	1	Percentage of the matrix fiber tear Temperature 20-25 ℃, the folder	100	100	88	70	100

Table 27 with and goes dicyclopentadiene-modified olefin aPP-g-scPP comparison
							Burden	A	B	C	D	E	F
Example 28	93	100	80				Burden	A	B	C	D	E	F
Example 28	93	100	80				Example 71				100	93
Escorez ^TM5637	2		20		2		Example 71				100	93
Escorez ^TM5637	2		20		2		Paraflint H-1	5				5
Henkel Standard Hot Melt 80-8368						100	Paraflint H-1	5				5
Henkel Standard Hot Melt 80-8368						100	The time at 190 ℃ Viscosity (cps)	390	661	205	524	502	-
Shore A hardness	22	34	45	-	-	-	The time at 190 ℃ Viscosity (cps)	390	661	205	524	502	-
Shore A hardness	22	34	45	-	-	-	Curing time (sec)	3	4	2.5	3.5	2	1
Percentage of the matrix fiber tear Temperature 20-25 ℃, the folder	50	80	90	80	90	90	Curing time (sec)	3	4	2.5	3.5	2	1

Table 28 comparison of the various aPP-g-scPP and binder blends
												Burden	A	B	C	D	E	F	G	H	I	J	K
Example 12	100	93										Burden	A	B	C	D	E	F	G	H	I	J	K
Example 12	100	93										Example 24			100	93
Example 22					100	93	88					Example 24			100	93
Example 22					100	93	88					Example 37								100	93
Escorez ^TM5637		2		2		2	4		2			Example 37								100	93
Escorez ^TM5637		2		2		2	4		2			Paraflint H-1		5		5		5	8		5
Henkel Standard Hot Melt 80-8368										100		Paraflint H-1		5		5		5	8		5
Henkel Standard Hot Melt 80-8368										100		Chief Standard Hot Melt 268											100
The time at 190 ℃ Viscosity (cps)	813	875	2240	1527	1240	950	797	568	497	730	1027	Chief Standard Hot Melt 268											100
The time at 190 ℃ Viscosity (cps)	813	875	2240	1527	1240	950	797	568	497	730	1027	Curing time (sec)	3	3	3	3	3.5	2.5	1.5	3.5	2.5	1	1.5
Percentage of the matrix fiber tear Temperature 20-25 ℃, the folder	85	95	95	95	90	90	90	90	95	90	10	Curing time (sec)	3	3	3	3	3.5	2.5	1.5	3.5	2.5	1	1.5

Table 29 for the various embodiments of the surface of the adhesive test
					Burden	78% Example 29,5% Licomont AR504, 7% Escorez 5637,5% Paraflint H-1, 5% Kaydol Oil copolymer. The 1% Irganox 1010 was added to the blend		Henkel 80-8368 Hot Melt
	Maximum average power, T-shaped strip passing through the point Off force test, (Newton / lbs)	Type of failure	Maximum average power, Through the point T-shaped Peel strength test, (Newton / lbs)	Type of failure	Burden			Henkel 80-8368 Hot Melt
		Type of failure		Type of failure	Surface
Cardboard 84C	24.25.4	Substrate damage	16.43.7	Substrate damage	Surface
Cardboard 84C	24.25.4	Substrate damage	16.43.7	Substrate damage	BOPP film (corona Li)	19.24.3	Cohesive failure	1.00.2	Complex jerkiness (complex jerking)
PP flat film	13.73.1	Several types of	1.00.2	Complex jerkiness	BOPP film (corona Li)	19.24.3	Cohesive failure	1.00.2	Complex jerkiness (complex jerking)
PP flat film	13.73.1	Several types of	1.00.2	Complex jerkiness	Cardboard 84B	6.01.3	Substrate damage	5.31.2	Substrate damage
Cardboard 84A	4.71.1	Substrate damage	4.61.0	Substrate damage	Cardboard 84B	6.01.3	Substrate damage	5.31.2	Substrate damage
Cardboard 84A	4.71.1	Substrate damage	4.61.0	Substrate damage	Foil	3.20.7	Cohesive failure	1.30.3	Cohesive failure

Examples EX1-EX13

The following sample under temperature of 70 至 125 ℃ prepared according to the above general procedure, the different Are: (1) In Example EX1-EX3, EX5 and EX9 added a small amount of 1,9 - decadiene as a two- Olefin monomer; (2) in Example EX13-EX17 in the ethylene. Detailed experimental conditions and Results are given in Table 30, 31 and 32.

Table 30
Table 30							Example	EX1	EX2	EX3	EX4	EX5	EX6
Catalyst # 1	A	A	A	A	A	G	Example	EX1	EX2	EX3	EX4	EX5	EX6
Catalyst # 1	A	A	A	A	A	G	Catalyst # 1 feed rate (mol / min)	5.22E-06	5.88E-06	6.10E-06	3.91E-06	1.82E-06	9.89E-07
Catalyst # 2	B	E	B	C	B	C	Catalyst # 1 feed rate (mol / min)	5.22E-06	5.88E-06	6.10E-06	3.91E-06	1.82E-06	9.89E-07
Catalyst # 2	B	E	B	C	B	C	Catalyst # 2 feed rate (mol / min)	7.65E-07	2.62E-06	2.83E-07	9.86E-07	9.45E-08	2.22E-07
Propylene feed rate (g / min)	14	14	14	14	14	14	Catalyst # 2 feed rate (mol / min)	7.65E-07	2.62E-06	2.83E-07	9.86E-07	9.45E-08	2.22E-07
Propylene feed rate (g / min)	14	14	14	14	14	14	1,9 - decadiene feed rate (ml / min)	0.09	0.10	0.19	0.00	0.01	0.00
H2 feed rate (cc / min)	0	0	30	0	0	0	1,9 - decadiene feed rate (ml / min)	0.09	0.10	0.19	0.00	0.01	0.00
H2 feed rate (cc / min)	0	0	30	0	0	0	Hexane feed rate (ml / min)	90	90	90	90	90	90
Polymerization temperature (℃)	95	75	70	92	100	105	Hexane feed rate (ml / min)	90	90	90	90	90	90
Polymerization temperature (℃)	95	75	70	92	100	105	Mn(kg/mol)	28.1	-	15.8	-	33	-
Mw(kg/mol)	63	-	58.3	-	67.7	-	Mn(kg/mol)	28.1	-	15.8	-	33	-
Mw(kg/mol)	63	-	58.3	-	67.7	-	Mz(kg/mol)	168.3	-	203.7	-	136.4	-
g′@Mz	0.81	-	0.78	-	-	-	Mz(kg/mol)	168.3	-	203.7	-	136.4	-
g′@Mz	0.81	-	0.78	-	-	-	Tc(℃)	100.7	74.8	91.9	54.6	86.4	60.1
Tm(℃)	146.1	113.8	148.9	103.0	149.4	102.9	Tc(℃)	100.7	74.8	91.9	54.6	86.4	60.1
Tm(℃)	146.1	113.8	148.9	103.0	149.4	102.9	Tg(℃)	-7.6	-8.2	-7.1	-8.3	-6.7	-8.2
Heat of fusion (J / g)	36.5	27.8	19.3	23.9	12.5	35.8	Tg(℃)	-7.6	-8.2	-7.1	-8.3	-6.7	-8.2
Heat of fusion (J / g)	36.5	27.8	19.3	23.9	12.5	35.8	Viscosity @ 190 ℃ (cps)	11200	4940	10100	2940	54870	5340
Catalyst:							Viscosity @ 190 ℃ (cps)	11200	4940	10100	2940	54870	5340
Catalyst:							A = dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl
B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl
							C = rac - dimethylsilyl bis (indenyl) hafnium dimethyl
E = rac - dimethylsilyl bis (2 - methyl-indenyl) zirconium dimethyl							C = rac - dimethylsilyl bis (indenyl) hafnium dimethyl
							G = di (p - triethylsilyl alkylphenyl) methylene] (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dimethyl

Table 31
Table 31								Example	EX7	EX8	EX9	EX10	EX11	EX12	EX13
Catalyst # 1	G	G	G	G	G	G	G	Example	EX7	EX8	EX9	EX10	EX11	EX12	EX13
Catalyst # 1	G	G	G	G	G	G	G	Catalyst # 1 feed rate (mol / min)	1.65E-06	1.65E-06	1.77E-06	2.35E-06	1.65E-06	9.89E-07	1.77E-06
Catalyst # 2	B	B	B	B	B	C	B	Catalyst # 1 feed rate (mol / min)	1.65E-06	1.65E-06	1.77E-06	2.35E-06	1.65E-06	9.89E-07	1.77E-06
Catalyst # 2	B	B	B	B	B	C	B	Catalyst # 2 feed rate (mol / min)	7.09E-08	4.72E-08	1.42E-07	5.74E-08	7.09E-08	3.70E-07	1.42E-07
Propylene feed rate (g / min)	14	14	14	14	14	14	14	Catalyst # 2 feed rate (mol / min)	7.09E-08	4.72E-08	1.42E-07	5.74E-08	7.09E-08	3.70E-07	1.42E-07
Propylene feed rate (g / min)	14	14	14	14	14	14	14	Ethylene feed rate (SLPM)	-	-	-	-	-	-	0.2
1,9 - decadiene feed rate (ml / min)	-	-	0.02	-	-	-	-	Ethylene feed rate (SLPM)	-	-	-	-	-	-	0.2
1,9 - decadiene feed rate (ml / min)	-	-	0.02	-	-	-	-	Hexane feed rate (ml / min)	90	90	90	90	90	90	90
Polymerization temperature (℃)	110	115	125	130	120	105	110	Hexane feed rate (ml / min)	90	90	90	90	90	90	90
Polymerization temperature (℃)	110	115	125	130	120	105	110	Mn(kg/mol)	22.5	-	17.7	-	-	-	-
Mw(kg/mol)	68.6	-	35.9	-	-	-	-	Mn(kg/mol)	22.5	-	17.7	-	-	-	-
Mw(kg/mol)	68.6	-	35.9	-	-	-	-	Mz(kg/mol)	132.4	-	67.8	-	-	-	-
G′@Mz	-	-	0.82	-	-	-	-	Mz(kg/mol)	132.4	-	67.8	-	-	-	-
G′@Mz	-	-	0.82	-	-	-	-	Tc(℃)	96.0	81.6	82.5	81.0	96.5	54.2	56.9
Tm(℃)	147.9	142.6	124.9	134.1	144.7	94.5	113.5	Tc(℃)	96.0	81.6	82.5	81.0	96.5	54.2	56.9
Tm(℃)	147.9	142.6	124.9	134.1	144.7	94.5	113.5	Tg(℃)	-3.3	-2.8	-6.3	-3.9	-4.2	-10.5	-9.6
Heat of fusion (J / g)	40.7	15.2	37.2	17.1	40.0	32.7	21.7	Tg(℃)	-3.3	-2.8	-6.3	-3.9	-4.2	-10.5	-9.6
Heat of fusion (J / g)	40.7	15.2	37.2	17.1	40.0	32.7	21.7	Viscosity @ 190 ℃ (cps)	45400	47500	1180	8325	7957	1157	7975
Catalyst:								Viscosity @ 190 ℃ (cps)	45400	47500	1180	8325	7957	1157	7975
Catalyst:								B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl
C = rac - dimethylsilyl bis (indenyl) hafnium dimethyl
C = rac - dimethylsilyl bis (indenyl) hafnium dimethyl								G = di (p - triethylsilyl alkylphenyl) methylene] (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dimethyl

Table 32
Table 32					Example	EX14	EX15	EX16	EX17
Catalyst # 1	G	G	G	G	Example	EX14	EX15	EX16	EX17
Catalyst # 1	G	G	G	G	Catalyst # 1 feed rate (mol / min)	1.77E-06	1.77E-06	1.77E-06	1.77E-06
Catalyst # 2	B	B	B	B	Catalyst # 1 feed rate (mol / min)	1.77E-06	1.77E-06	1.77E-06	1.77E-06
Catalyst # 2	B	B	B	B	Catalyst # 2 feed rate (mol / min)	3.12E-07	3.12E-07	3.12E-07	3.12E-07
Propylene feed rate (g / min)	14	14	10	10	Catalyst # 2 feed rate (mol / min)	3.12E-07	3.12E-07	3.12E-07	3.12E-07
Propylene feed rate (g / min)	14	14	10	10	Ethylene feed rate (SLPM)	1.5	0.8	0.8	1.5
Hexane feed rate (ml / min)	90	90	90	90	Ethylene feed rate (SLPM)	1.5	0.8	0.8	1.5
Hexane feed rate (ml / min)	90	90	90	90	Polymerization temperature (℃)	80	80	105	105
Mn(kg/mol)					Polymerization temperature (℃)	80	80	105	105
Mn(kg/mol)					Mw(kg/mol)
Mz(kg/mol)					Mw(kg/mol)
Mz(kg/mol)					g′@Mz
Tc(℃)	28.7	58.0	19.1	-	g′@Mz
Tc(℃)	28.7	58.0	19.1	-	Tm(℃)	73.7	99.3	57.6	-47.8
Tg(℃)	-26.3	-19.4	-26.8	-19.5	Tm(℃)	73.7	99.3	57.6	-47.8
Tg(℃)	-26.3	-19.4	-26.8	-19.5	Heat of fusion (J / g)	14.8	29.6	8.0	3.7
Viscosity @ 190 ℃ (cps)	23400	37120	495	481	Heat of fusion (J / g)	14.8	29.6	8.0	3.7
Viscosity @ 190 ℃ (cps)	23400	37120	495	481	Ethylene content (mol%)	16.9	10.7
Catalyst:					Ethylene content (mol%)	16.9	10.7
Catalyst:					B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl
G = di (p - triethylsilyl alkylphenyl) methylene] (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dimethyl

Polymerization conditions

Will be added to the propylene feed rate 8lb/hr and hexane added to 17lb/hr combined form A raw material solution 25lb/hr reactor. In hexane 3wt.% Solution in three N-octyl aluminum (TNOA) (available from Albemarle) is introduced into the stream at a rate 0.0006lb/hr Medium.

The catalyst and the activator from a separate inlet to the reactor. The catalyst solution by two (P - triethylsilyl alkylphenyl) methylene] (cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) Hafnium dimethyl (Catalyst G) and rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) Zirconium dimethyl (catalyst B) a mixture composed of 97mol% of which has a catalyst G. Through Over the catalyst dissolved in toluene to form a mixture solution of 0.5wt% catalyst solution was prepared. Activator feedstream comprises four (pentafluorophenyl) borate, N, N-dimethylaniline 0.2 bromide in toluene wt% solution composition. Catalyst and the activator are purchased from Albemarle. The catalyst and activator Pipeline materials can be assembled to the reactor immediately upstream of mixing in the pipeline, of which an estimated exposure Time of 2-4 minutes. Catalyst feed rate and the activator and 0.1 respectively 0.04g/hr g / hr. ...

The two flash stages (each stage has a preheater) molten polymer recovered from the solution. Stage (20psig) the polymer comprises from about 2% solvent, the second phase (50 Torr vacuum) into approximately 800ppm volatiles. Water into the second stage flash (devolatilizers) compound to quench residual catalyst Agent and supplemented by solvent stripping. And the final properties of the binder polymer are summarized in Table 33.

Table 33
Table 33									Example #	PP1	PP2	PP3	PP4	PP5	PP6	PP7	PP8
Polymerization temperature (℃)	132	135	135	135	135	134	133	137	Example #	PP1	PP2	PP3	PP4	PP5	PP6	PP7	PP8
Polymerization temperature (℃)	132	135	135	135	135	134	133	137	The catalyst in the catalyst blend 1 (mol%)	96	93	93	93	93	93	96	93
The catalyst in the reactor feed (wppm)	3.20	4.17	4.17	4.17	4.17	4.17	4.17	3.8	The catalyst in the catalyst blend 1 (mol%)	96	93	93	93	93	93	96	93
The catalyst in the reactor feed (wppm)	3.20	4.17	4.17	4.17	4.17	4.17	4.17	3.8	Propylene in reactor feed (wt%)	28.00	29.17	29.17	29.17	29.17	28.0	28.0	30.0
Scavenger (wppm)	7.44	25	25	25	25	24	24	24	Propylene in reactor feed (wt%)	28.00	29.17	29.17	29.17	29.17	28.0	28.0	30.0
Scavenger (wppm)	7.44	25	25	25	25	24	24	24	Quenched with water (wt%)	1.82	0.86	0.86	0.86	0.62	1.4	2.8	0
Mn(kg/mol)	18.3	17.1	13	16.7	12.3	11.4	17.3	18.5	Quenched with water (wt%)	1.82	0.86	0.86	0.86	0.62	1.4	2.8	0
Mn(kg/mol)	18.3	17.1	13	16.7	12.3	11.4	17.3	18.5	Mw(kg/mol)	41.7	36.6	32.5	34.4	32.3	31.9	38.5	34.1
Mz(kg/mol)	76.4	68.1	61.9	61.7	64.6	61.6	71.4	69.6	Mw(kg/mol)	41.7	36.6	32.5	34.4	32.3	31.9	38.5	34.1
Mz(kg/mol)	76.4	68.1	61.9	61.7	64.6	61.6	71.4	69.6	g′@Mz	-	0.83	0.85	0.83	0.81	0.83	0.94	0.89
Tc(℃)	69.2	79.8	80.6	78.4	63.8	71.8	62.8	85	g′@Mz	-	0.83	0.85	0.83	0.81	0.83	0.94	0.89
Tc(℃)	69.2	79.8	80.6	78.4	63.8	71.8	62.8	85	Tm(℃)	131	1 34	136	137	130	132	137	136
Heat of fusion (J / g)	15.9	25.7	30.7	28.7	38	28.2	9.5	38.6	Tm(℃)	131	1 34	136	137	130	132	137	136
Heat of fusion (J / g)	15.9	25.7	30.7	28.7	38	28.2	9.5	38.6	Viscosity @ 190 ℃ (cps)	2300	1992	1382	1527	1211	1340	4235	1270
Catalyst:									Viscosity @ 190 ℃ (cps)	2300	1992	1382	1527	1211	1340	4235	1270
Catalyst:									B = rac - dimethylsilyl bis (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl
G = di (p - triethylsilyl alkylphenyl) methylene]-cyclopentadienyl) (3,8 - di-tert-butyl-fluorenyl) hafnium dimethyl

All documents described herein, including any priority documents and / or test procedures for the introduction of Reference. As apparent from the above general description and specific embodiments evident, although the present In a form that has been illustrated and described, it may be made without departing from the spirit and scope of the present invention into the OK various improvements. Therefore. The invention is not limited by these forms.

Claims

A method comprising at least 50mol% of one or more C3 to C40 olefin polymer, Wherein the polymer has:

a) a point on the kraft T-peel force of 1 Newton or greater; and

b) a branching index (g ') of 0.95 or lower, the polymer had an Mz measurement;

c) Mw of 100,000 or less.
(2) comprising at least 50mol% of one or more C3 to C40 olefin polymer, Wherein the polymer has:

a) a point on the kraft T-peel force of 1 Newton or more;

b) a branching index (g ') of 0.98 or lower, the polymer had an Mz measurement;

c) Mw of 10,000 to 60,000; and

d) a heat of fusion of 1 to 50J / g.
3 A homopolypropylene or propylene with at most 5mol% ethylene copolymer comprising:

a) isotactic continuous length of 1 to 30;

b) r diad percentage is greater than 20%; and

c) melting heat is 70J / g or lower.
The process of claim 1 or 3, polymer, wherein the polymer has Mw of 10,000 to 100,000 And a heat of fusion of 1 to 70J / g.
The process of claim 1 or 2, polymer, wherein the polymer comprises propylene.
The process of claim 1 or 2, a polymer, wherein the polymer comprises less than 15mol% of B Ene.
7 to any one of the preceding claims polymer, wherein the polymer in the melt 190 ℃ Body viscosity 7000mPa · sec or less.
8 any one of the preceding claims polymer, wherein the polymer in the melt 190 ℃ Body viscosity 5000mPa.sec or less.
9 to any one of the preceding claims polymer, wherein the polymer in the melt 190 ℃ Body viscosity 3000mPa.sec or less.
10 any one of the preceding claims polymer, wherein the polymer in the melt 190 ℃ Viscosity of 500 to 3000mPa · sec.
11 any one of the preceding claims polymer, wherein the polymer has a Tg of 0 ℃ or Lower.
12 any one of the preceding claims polymer, wherein the polymer has a Tg of -10 ℃ or lower.
13 any one of the preceding claims polymer, wherein the composition of the branching index (g ') Is 0.90 or lower, the polymer had an Mz measurements.
14 any one of the preceding claims polymer, wherein the polymer has Mw of 50,000 Or less and a branching index of 0.7 or lower.
15 any one of the preceding claims polymer, wherein the polymer for double or SEC Multimodal.
16 any one of the preceding claims polymer, wherein the amorphous content of the polymer At least 50%.
17 any one of the preceding claims polymer, wherein the polymer has a melting point of 60 peak To 190 ℃.
18 any one of the preceding claims polymer, wherein the polymer has a molecular weight distribution (Mw / Mn) of at least 5.
19 any one of the preceding claims polymer, wherein the polymer has a crystallinity of at least 30%.
20. Any one of the preceding claims polymer, wherein the polymer has a 20wt.% Or Higher temperature hexane soluble fraction and 50wt% or less Soxhlet heptane-insoluble fraction.
21 any one of the preceding claims polymer, wherein the polymer comprises less than 3.0 mol% of ethylene.
22 any one of the preceding claims polymer, wherein the polymer comprises a diene.
23 any one of the preceding claims polymer, wherein the polymer is selected from the group including 1,6 - Heptadiene, 1,7 - octadiene, 1,8 - nonadiene, 1,9 - decadiene, 1,10 - undecadiene, 1,11 - dodecadiene, 1,12 - tridecadiene, 1,13 - tetradecadiene, cyclopentadiene, Vinyl norbornene, norbornadiene, ethylidene norbornene, divinylbenzene, dicyclopentadiene Dienes and polybutadiene Mw less than 1000g/mol diene, or combinations thereof.
24. Any one of the preceding claims polymer, wherein the polymer Mz / Mn of from 2 to 200.
25. Any one of the preceding claims polymer, wherein the polymer is 15,000 Mz To 500,000.
26 any one of the preceding claims polymer, wherein the polymer is 50 to SAFT 150 ℃.
27 any one of the preceding claims polymer, wherein the polymer has a Shore A hardness of 95 or less.
28. Any one of the preceding claims polymer, wherein the curing time of the polymer is 5 Seconds or less.
29 any one of the preceding claims polymer, wherein the polymer has Mw / Mn of from 2 to 75.
30. Any one of the preceding claims polymer, wherein the polymer tensile strength at break Is 0.5MPa or higher.
31. Any one of the preceding claims polymer, wherein the polymer has a melt index of 900dg/min or higher.
32 any one of the preceding claims polymer, wherein the polymer is a propylene homopolymer and / Or propylene with butene, pentene, hexene, octene, nonene and decene in one or more of Copolymers, wherein the copolymer comprises less than 10mol% of ethylene and wherein the homopolymer or copolymer The point T-peel strength of 3 Newtons or higher; viscosity at 190 ℃ or more 8000mPa/sec Low; branching index (g ') of 0.85 or lower, the polymer had an Mz measurement;, and a Mw of 100,000 Or lower.
33 any one of the preceding claims polymer, wherein the polymer comprises propylene, 0 to 5mol% of ethylene, 0 to 40mol% C5 to C12 olefins and dienes 0 to 10mol%.
34 any one of the preceding claims polymer, wherein the polymer comprises less than 1mol % Ethylene and having at least 2mol% (CH₂) ₂Unit.
35. Claimed in any one of claim 1 through 34 of the polymer, wherein the polymer has at least 4 mol% (CH₂) ₂Unit.
36. Claimed in any one of claim 1 through 34 of the polymer, wherein the polymer has at least 8 mol% (CH₂) ₂Unit.
37. Claimed in any one of claim 1 through 34 of the polymer, wherein the polymer has at least 15 mol% (CH₂) ₂Unit.
38. Claimed in any one of claim 1-33 polymer, wherein the polymer comprises from 1 to 10 mol% of ethylene and wherein the polymer has at least 2 + Xmol% (CH₂) ₂Unit wherein X is mol % Ethylene.
39 claimed in any one of claim 1-33 polymer, wherein the polymer comprises from 1 to 10 mol% of ethylene and wherein the polymer has at least 4 + Xmol% (CH₂) ₂Unit.
40. Claimed in any one of claim 1-33 polymer, wherein the polymer comprises from 1 to 10 mol% of ethylene and wherein the polymer has at least 10 + Xmol% (CH₂) ₂Unit.
41. Claimed in any one of claim 1-33 polymer, wherein the polymer comprises from 1 to 10 mol% of ethylene and wherein the polymer has at least 15 + Xmol% (CH₂) ₂Unit.
42 claimed in any one of claim 1-41 polymer, wherein the polymer is a point T-peel From force of 5 N or higher.
43. Claimed in any one of claim 1-42 polymer, wherein the polymer is a point T-peel 10-2000 from Newton force.
44. Claimed in any one of claim 1-43 polymer, wherein the polymer is a point T-peel From 15 to about 1000 Newton force.
45. Claimed in any one of claim 1-43 polymer, wherein the polymer having an amorphous Component which comprises at least 3mol% (CH₂) ₂Unit.
46. Claimed in any one of claim 1-43 polymer, wherein the polymer having an amorphous Component which comprises at least 6mol% (CH₂) ₂Unit.
47. Claimed in any one of claim 1-43 polymer, wherein the polymer having an amorphous Component which contains at least 10mol% (CH₂) ₂Unit.
48. Claimed in any one of claim 1-43 polymer, wherein the polymer having an amorphous Component which contains at least 15mol% (CH₂) ₂Unit.
49 The polymer of claim 109, wherein the amorphous component containing at least 20mol% (CH₂) ₂Unit.
50 A method of claims 1-49 comprising any one or more of the hydrocarbon polymer and a The resin composition of the hydrocarbon resin is selected from aliphatic hydrocarbon resins, aromatic modified aliphatic hydrocarbon resins, hydrogenated Dicyclopentadiene resins, dicyclopentadiene resins, gum rosin, gum rosin esters, wood rosin, Ester of wood rosin, tall oil rosin, tall oil rosin esters, polyterpenes, aromatic modified polyterpenes, terpene phenol, Hydrogenated aromatic-modified dicyclopentadiene resins, hydrogenated aliphatic resin, hydrogenated aliphatic aromatic resins, hydrogen Of terpenes and modified terpenes and hydrogenated rosin esters.
51 The composition of claim 50, wherein the presence of 1wt% to about 80wt% of the hydrocarbon resin.
52 The composition of claim 50, wherein there is less than 5% of the hydrocarbon resin.
53 A beads, including the claims 1-49 in any one polymer.
54 A beads, including the claims 50-52 The composition of any one.
55 A process for producing any of claims 1-49 in a continuous process of the polymer, including Including:

1) Select the first catalyst component, the catalyst component is capable of polymerization conditions in the selected xiasheng Mw of 100,000 or less produced and the degree of crystallinity of 5% or less of the polymer;

2) Select the second catalyst component, the catalyst component is capable of polymerization conditions in the selected Production Mw of 100,000 or less and a crystallinity of 20% or more of the polymer;

3) The catalyst component of one or more activating agent in the presence of one or more C3 Exposure to C40 olefins; and

4) at a temperature higher than 100 ℃ lower;

5) the dwell time of 120 minutes or less following;

6) wherein the first catalyst and the second catalyst ratio of 1:1 to 50:1;

7) in which the activity of the catalyst component is at least 50kg g polymer / g catalyst compound; and Wherein at least 80% of the olefin conversion to polymer.
56 The method of claim 55, wherein the first catalyst component comprises a stereospecific metallocene Metal catalyst compounds.
57 The method of claim 55, wherein the first catalyst component comprises a non-stereospecific Mao Metal catalyst compound.
58. Claimed in claim 55, 56 or 57, wherein the second catalyst component comprises a three-dimensional There are optional metallocene catalyst compounds.
59 The method of claim 55, wherein the first catalyst component comprises one or more of the following Materials: dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) dichloride Titanium, dimethylsilyl (tetramethyl-cyclopentadienyl) (cyclohexylamino) titanium dichloride, dimethyl Silyl (tetramethyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, dimethylformamide Silyl group (tetramethyl cyclopentadienyl) (t-butylamino) titanium dichloride, dimethyl silyl (Tetramethyl cyclopentadienyl) (sec-butylamino) titanium dichloride, dimethyl silyl (tetramethyl Cyclopentadienyl) (n-butylamino) titanium dichloride, dimethyl silyl (tetramethylcyclopentadienyl Yl) (exo-2 - amino-norbornyl) titanium dichloride, diethyl silyl (tetramethylcyclopentadienyl Yl) (ring dodecylamino) titanium dichloride, diethyl silyl (tetramethylcyclopentadienyl Yl) (exo-2 - amino-norbornyl) titanium dichloride, diethyl silyl (tetramethylcyclopentadienyl Yl) (cyclohexylamino) titanium dichloride, diethyl silyl (tetramethyl-cyclopentadienyl) (1 - Gold Just alkylamino) titanium dichloride, methylene (tetramethyl cyclopentadienyl) (cyclododecyl group) Titanium dichloride, methylene (tetramethyl cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, Methylene (tetramethyl cyclopentadienyl) (cyclohexylamino) titanium dichloride, methylene (tetramethylcyclopropanecarboxylate Pentadienyl) (1 - adamantyl group) titanium dichloride, dimethyl silyl (tetramethylcyclopentadienyl Enyl) (cyclododecyl) dimethyl titanium, dimethylsilyl (tetramethylcyclopentadienyl Yl) (exo-2 - norbornyl) dimethyl titanium, dimethylsilyl (tetramethylcyclopentadienyl Yl) (cyclohexyl) dimethyl titanium, dimethylsilyl (tetramethyl-cyclopentadienyl) (1 - Gold Just alkylamino) titanium dimethyl, dimethylsilyl group (2,5 - dimethyl-cyclopentadienyl) (ten ring Dialkylamino) titanium dichloride, dimethyl silyl group (2,5 - dimethyl-cyclopentadienyl) (outside -2 - Amino-norbornyl) titanium dichloride, dimethyl silyl group (2,5 - dimethyl-dicyclopentadiene Yl) (cyclohexylamino) titanium dichloride, dimethyl silyl group (2,5 - dimethyl-dicyclopentadiene Yl) (1 - adamantyl group) titanium dichloride, dimethyl silyl group (3,4 - dimethyl-dicyclopentadiene Yl) (cyclododecyl group) titanium dichloride, dimethyl silyl group (3,4 - dimethyl-dicyclopentadiene Yl) (exo-2 - amino-norbornyl) titanium dichloride, dimethyl silyl group (3,4 - dimethyl-cyclopentyl Dienyl) (cyclohexylamino) titanium dichloride, dimethyl silyl group (3,4 - dimethyl-dicyclopentadiene Yl) (1 - adamantyl group) titanium dichloride, dimethyl silyl group (2 - ethyl-5 - methyl-cyclopentyl Dienyl) (cyclododecyl group) titanium dichloride, dimethyl silyl group (2 - ethyl-5 - methyl- Cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, dimethyl silyl group (2 - ethyl- -5 - Methyl-cyclopentadienyl) (cyclohexylamino) titanium dichloride, dimethyl silyl group (2 - ethyl- -5 - Methyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, dimethylsilyl (3 - Ethyl-4 - methyl-cyclopentadienyl) (cyclododecyl group) titanium dichloride, dimethyl silyl (3 - ethyl-4 - methyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, dimethylformamide Silyl group (3 - ethyl-4 - methyl-cyclopentadienyl) (cyclohexylamino) titanium dichloride, dimethylformamide Silyl group (3 - ethyl-4 - methyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, dimethyl Silyl (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (cyclododecyl Amino) titanium dichloride, dimethyl silyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl cyclopentyl Dienyl) (exo-2 - amino-norbornyl) titanium dichloride, dimethyl silyl group (2 - ethyl - 3 - hexyl -5 - methyl - 4 - octyl-cyclopentadienyl) (cyclohexylamino) titanium dichloride, dimethylsilyl Group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (1 - adamantyl group) dichloride Titanium, dimethyl silyl group (2 - tetrahydro-indenyl) (cyclododecyl group) titanium dichloride, dimethyl Silyl (2 - tetrahydro-indenyl) (cyclohexylamino) titanium dichloride, dimethyl silyl group (2 - Tetrahydro-indenyl) (1 - adamantyl group) titanium dichloride, dimethyl silyl group (2 - tetrahydroindenyl Yl) (exo-2 - amino-norbornyl) titanium dichloride, dimethyl silyl (tetramethylcyclopentadienyl Yl) (cyclododecyl) dimethyl titanium, dimethylsilyl (tetramethylcyclopentadienyl Yl) (cyclohexyl) dimethyl titanium, dimethylsilyl (tetramethyl-cyclopentadienyl) (1 - Gold Just alkylamino) titanium dimethyl, dimethylsilyl group (tetramethyl-cyclopentadienyl) (tert-butylamino Yl) dimethyl titanium, dimethylsilyl (tetramethyl-cyclopentadienyl) (sec-butylamino) dimethyl Ti-, dimethyl silyl (tetramethyl cyclopentadienyl) (n-butylamino) dimethyl titanium, Dimethylsilyl (tetramethyl-cyclopentadienyl) (exo-2 - norbornyl) dimethyl titanium, Triethylsilyl (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl, diethyl Silyl (tetramethyl cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dimethyl, diethyl Silyl (tetramethyl cyclopentadienyl) (cyclohexylamino) titanium dimethyl, diethyl silyl (Tetramethyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, methylene (tetramethylcyclopentadienyl Dienyl) (cyclododecyl group) titanium dimethyl, methylene (tetramethyl cyclopentadienyl) (outside -2 - Amino-norbornyl) titanium dimethyl, methylene (tetramethyl cyclopentadienyl) (cyclohexylamino) Titanium dimethyl, methylene (tetramethyl-cyclopentadienyl) (1 - adamantyl) dimethyl titanium, Dimethylsilyl (tetramethyl-cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethyl Silyl (tetramethyl cyclopentadienyl) (exo-2 - norbornyl) dimethyl titanium, dimethyl Silyl (tetramethyl cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethylsilyl group (Tetramethyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, dimethylsilyl group (2,5 - dimethyl-cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl group (2,5 - dimethyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dimethyl, dimethylsilyl Alkyl (2,5 - dimethyl-cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethylsilyl group (2,5 - dimethyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, dimethylsilyl group (3,4 - dimethyl-cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl group (3,4 - dimethyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dimethyl, dimethylsilyl Alkyl (3,4 - dimethyl-cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethylsilyl group (3,4 - dimethyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, dimethylsilyl group (2 - ethyl-5 - methyl-cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl Group (2 - ethyl-5 - methyl-cyclopentadienyl) (exo-2 - norbornyl) dimethyl titanium, dimethyl Silyl (2 - ethyl-5 - methyl-cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethyl Silyl (2 - ethyl-5 - methyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, Dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (cyclododecyl) dimethyl Titanium, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (exo-2 - norbornyl group) Titanium dimethyl, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (cyclohexylamino) Titanium dimethyl, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (1 - adamantyl Amino) titanium dimethyl, dimethylsilyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl cyclopentyl Dienyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl group (2 - ethyl - 3 - hexyl -5 - Methyl - 4 - octylcyclopentadienyl) (exo-2 - norbornyl) dimethyl titanium, dimethylformamide Silane group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (cyclohexylamino) dimethyl Ti-, dimethyl silyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (1 - Adamantyl group) titanium dimethyl, dimethylsilyl group (2 - tetrahydro-indenyl) (ring dodecylammoniomethyl Yl) titanium dimethyl, dimethylsilyl group (2 - tetrahydro-indenyl) (cyclohexylamino) titanium dimethyl, Dimethylsilyl group (2 - tetrahydro-indenyl) (1 - adamantyl) dimethyl titanium and dimethylformamide Silane group (2 - tetrahydro-indenyl) (exo-2 - norbornyl) dimethyl titanium. ...
59 The method of claim 55, wherein the first catalyst component comprises one or more of the following Materials: dimethylsilyl group (tetramethyl cyclopentadienyl) (cyclododecyl group) dichloride Titanium, dimethylsilyl (tetramethyl-cyclopentadienyl) (cyclohexylamino) titanium dichloride, dimethyl Silyl (tetramethyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, dimethylformamide Silyl group (tetramethyl cyclopentadienyl) (t-butylamino) titanium dichloride, dimethyl silyl (Tetramethyl cyclopentadienyl) (sec-butylamino) titanium dichloride, dimethyl silyl (tetramethyl Cyclopentadienyl) (n-butylamino) titanium dichloride, dimethyl silyl (tetramethylcyclopentadienyl Yl) (exo-2 - amino-norbornyl) titanium dichloride, diethyl silyl (tetramethylcyclopentadienyl Yl) (ring dodecylamino) titanium dichloride, diethyl silyl (tetramethylcyclopentadienyl Yl) (exo-2 - amino-norbornyl) titanium dichloride, diethyl silyl (tetramethylcyclopentadienyl Yl) (cyclohexylamino) titanium dichloride, diethyl silyl (tetramethyl-cyclopentadienyl) (1 - Gold Just alkylamino) titanium dichloride, methylene (tetramethyl cyclopentadienyl) (cyclododecyl group) Titanium dichloride, methylene (tetramethyl cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, Methylene (tetramethyl cyclopentadienyl) (cyclohexylamino) titanium dichloride, methylene (tetramethylcyclopropanecarboxylate Pentadienyl) (1 - adamantyl group) titanium dichloride, dimethyl silyl (tetramethylcyclopentadienyl Enyl) (cyclododecyl) dimethyl titanium, dimethylsilyl (tetramethylcyclopentadienyl Yl) (exo-2 - norbornyl) dimethyl titanium, dimethylsilyl (tetramethylcyclopentadienyl Yl) (cyclohexyl) dimethyl titanium, dimethylsilyl (tetramethyl-cyclopentadienyl) (1 - Gold Just alkylamino) titanium dimethyl, dimethylsilyl group (2,5 - dimethyl-cyclopentadienyl) (ten ring Dialkylamino) titanium dichloride, dimethyl silyl group (2,5 - dimethyl-cyclopentadienyl) (outside -2 - Amino-norbornyl) titanium dichloride, dimethyl silyl group (2,5 - dimethyl-dicyclopentadiene Yl) (cyclohexylamino) titanium dichloride, dimethyl silyl group (2,5 - dimethyl-dicyclopentadiene Yl) (1 - adamantyl group) titanium dichloride, dimethyl silyl group (3,4 - dimethyl-dicyclopentadiene Yl) (cyclododecyl group) titanium dichloride, dimethyl silyl group (3,4 - dimethyl-dicyclopentadiene Yl) (exo-2 - amino-norbornyl) titanium dichloride, dimethyl silyl group (3,4 - dimethyl-cyclopentyl Dienyl) (cyclohexylamino) titanium dichloride, dimethyl silyl group (3,4 - dimethyl-dicyclopentadiene Yl) (1 - adamantyl group) titanium dichloride, dimethyl silyl group (2 - ethyl-5 - methyl-cyclopentyl Dienyl) (cyclododecyl group) titanium dichloride, dimethyl silyl group (2 - ethyl-5 - methyl- Cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, dimethyl silyl group (2 - ethyl- -5 - Methyl-cyclopentadienyl) (cyclohexylamino) titanium dichloride, dimethyl silyl group (2 - ethyl- -5 - Methyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, dimethylsilyl (3 - Ethyl-4 - methyl-cyclopentadienyl) (cyclododecyl group) titanium dichloride, dimethyl silyl (3 - ethyl-4 - methyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dichloride, dimethylformamide Silyl group (3 - ethyl-4 - methyl-cyclopentadienyl) (cyclohexylamino) titanium dichloride, dimethylformamide Silyl group (3 - ethyl-4 - methyl-cyclopentadienyl) (1 - adamantyl group) titanium dichloride, dimethyl Silyl (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (cyclododecyl Amino) titanium dichloride, dimethyl silyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl cyclopentyl Dienyl) (exo-2 - amino-norbornyl) titanium dichloride, dimethyl silyl group (2 - ethyl - 3 - hexyl -5 - methyl - 4 - octyl-cyclopentadienyl) (cyclohexylamino) titanium dichloride, dimethylsilyl Group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (1 - adamantyl group) dichloride Titanium, dimethyl silyl group (2 - tetrahydro-indenyl) (cyclododecyl group) titanium dichloride, dimethyl Silyl (2 - tetrahydro-indenyl) (cyclohexylamino) titanium dichloride, dimethyl silyl group (2 - Tetrahydro-indenyl) (1 - adamantyl group) titanium dichloride, dimethyl silyl group (2 - tetrahydroindenyl Yl) (exo-2 - amino-norbornyl) titanium dichloride, dimethyl silyl (tetramethylcyclopentadienyl Yl) (cyclododecyl) dimethyl titanium, dimethylsilyl (tetramethylcyclopentadienyl Yl) (cyclohexyl) dimethyl titanium, dimethylsilyl (tetramethyl-cyclopentadienyl) (1 - Gold Just alkylamino) titanium dimethyl, dimethylsilyl group (tetramethyl-cyclopentadienyl) (tert-butylamino Yl) dimethyl titanium, dimethylsilyl (tetramethyl-cyclopentadienyl) (sec-butylamino) dimethyl Ti-, dimethyl silyl (tetramethyl cyclopentadienyl) (n-butylamino) dimethyl titanium, Dimethylsilyl (tetramethyl-cyclopentadienyl) (exo-2 - norbornyl) dimethyl titanium, Triethylsilyl (tetramethyl cyclopentadienyl) (cyclododecyl group) titanium dimethyl, diethyl Silyl (tetramethyl cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dimethyl, diethyl Silyl (tetramethyl cyclopentadienyl) (cyclohexylamino) titanium dimethyl, diethyl silyl (Tetramethyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, methylene (tetramethylcyclopentadienyl Dienyl) (cyclododecyl group) titanium dimethyl, methylene (tetramethyl cyclopentadienyl) (outside -2 - Amino-norbornyl) titanium dimethyl, methylene (tetramethyl cyclopentadienyl) (cyclohexylamino) Titanium dimethyl, methylene (tetramethyl-cyclopentadienyl) (1 - adamantyl) dimethyl titanium, Dimethylsilyl (tetramethyl-cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethyl Silyl (tetramethyl cyclopentadienyl) (exo-2 - norbornyl) dimethyl titanium, dimethyl Silyl (tetramethyl cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethylsilyl group (Tetramethyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, dimethylsilyl group (2,5 - dimethyl-cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl group (2,5 - dimethyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dimethyl, dimethylsilyl Alkyl (2,5 - dimethyl-cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethylsilyl group (2,5 - dimethyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, dimethylsilyl group (3,4 - dimethyl-cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl group (3,4 - dimethyl-cyclopentadienyl) (exo-2 - amino-norbornyl) titanium dimethyl, dimethylsilyl Alkyl (3,4 - dimethyl-cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethylsilyl group (3,4 - dimethyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, dimethylsilyl group (2 - ethyl-5 - methyl-cyclopentadienyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl Group (2 - ethyl-5 - methyl-cyclopentadienyl) (exo-2 - norbornyl) dimethyl titanium, dimethyl Silyl (2 - ethyl-5 - methyl-cyclopentadienyl) (cyclohexylamino) titanium dimethyl, dimethyl Silyl (2 - ethyl-5 - methyl-cyclopentadienyl) (1 - adamantyl group) titanium dimethyl, Dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (cyclododecyl) dimethyl Titanium, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (exo-2 - norbornyl group) Titanium dimethyl, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (cyclohexylamino) Titanium dimethyl, dimethylsilyl (3 - ethyl-4 - methyl-cyclopentadienyl) (1 - adamantyl Amino) titanium dimethyl, dimethylsilyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl cyclopentyl Dienyl) (cyclododecyl group) titanium dimethyl, dimethylsilyl group (2 - ethyl - 3 - hexyl -5 - Methyl - 4 - octylcyclopentadienyl) (exo-2 - norbornyl) dimethyl titanium, dimethylformamide Silane group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (cyclohexylamino) dimethyl Ti-, dimethyl silyl group (2 - ethyl - 3 - hexyl-5 - methyl - 4 - octyl-cyclopentadienyl) (1 - Adamantyl group) titanium dimethyl, dimethylsilyl group (2 - tetrahydro-indenyl) (ring dodecylammoniomethyl Yl) titanium dimethyl, dimethylsilyl group (2 - tetrahydro-indenyl) (cyclohexylamino) titanium dimethyl, Dimethylsilyl group (2 - tetrahydro-indenyl) (1 - adamantyl) dimethyl titanium and dimethylformamide Silane group (2 - tetrahydro-indenyl) (exo-2 - norbornyl) dimethyl titanium. ...

Dimethylsilyl group (2 - methyl - 4 - phenyl-indenyl) zirconium dichloride,

Dimethylsilyl group (2 - methyl - 4 - phenyl-indenyl) zirconium dimethyl,

Dimethylsilyl group (2 - methyl - 4 - phenyl-indenyl) hafnium dichloride,

Dimethylsilyl group (2 - methyl - 4 - phenyl-indenyl) hafnium dimethyl,

Dimethylsilyl bis (indenyl) hafnium dimethyl,

Dimethylsilyl bis (indenyl) hafnium dichloride,

Dimethylsilyl bis (indenyl) zirconium dimethyl,

Dimethylsilyl bis (indenyl) zirconium dichloride;

The following materials racemic isomer:

Dimethylsilanediyl bis (2 - methyl) metal dichloride;

Dimethylsilanediyl bis (indenyl) metal dichloride;

Dimethylsilanediyl bis (indenyl) dimethyl metal;

Dimethylsilanediyl bis (tetrahydro-indenyl) metal dichloride;

Dimethylsilanediyl bis (tetrahydro-indenyl) dimethyl metal;

Dimethylsilanediyl bis (indenyl) diethyl metal; and

Dibenzyl silanediylbis (indenyl) dimethyl metal;

Wherein the metal is selected from Zr, Hf or Ti.
61. Claimed in any one of claim 55 to 60, wherein the activator comprises aluminum oxide.
62. Claimed in any one of claim 55-61, wherein the activator comprises ionization of Thereof.
63. Claimed in any one of claim 55-62, wherein the activator comprises a non-coordinating shade Ions.
64. Claimed in any one of claim 55 to 60, wherein the activating agent include the following materials In one or more of:

Methylaluminoxane,

Trimethylammonium tetraphenylborate,

Triethylammonium tetraphenylborate,

Tripropylammonium tetraphenylborate,

Tetraphenyl borate, tri (n-butyl) ammonium,

Tetraphenyl borate, tri (t-butyl) ammonium,

Tetraphenyl borate, N, N-dimethylaniline bromide,

Tetraphenylborate, N, N-diethylaniline bromide,

Tetraphenyl borate, N, N-dimethyl - (2,4,6 - trimethyl aniline) chloride,

Tetrakis (pentafluorophenyl) borate, trimethylammonium,

Tetrakis (pentafluorophenyl) borate, triethylammonium,

Tetrakis (pentafluorophenyl) borate, tripropylammonium

Tetrakis (pentafluorophenyl) borate, tri (n-butyl) ammonium,

Tetrakis (pentafluorophenyl) borate, tri (sec-butyl) ammonium,

Tetrakis (pentafluorophenyl) borate, N, N-dimethylaniline bromide,

Four (pentafluorophenyl) borate, N, N-diethylaniline bromide,

Tetrakis (pentafluorophenyl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline) chloride,

IV - (2,3,4,6 - tetrafluoro-phenyl) borate, trimethyl ammonium,

IV - (2,3,4,6 - tetrafluoro-phenyl) borate, triethylammonium,

IV - (2,3,4,6 - tetrafluoro-phenyl) borate, tripropylammonium

IV - (2,3,4,6 - tetrafluoro-phenyl) borate, tri (n-butyl) ammonium,

IV - (2,3,4,6 - tetrafluoro-phenyl) borate, dimethyl (t-butyl) ammonium,

IV - (2,3,4,6 - tetrafluoro-phenyl) borate, N, N-dimethylaniline bromide,

IV - (2,3,4,6 - tetrafluoro-phenyl) borate, N, N-diethylaniline bromide,

IV - (2,3,4,6 - tetrafluoro-phenyl) borate, N, N-dimethyl - (2,4,6 - trimethyl aniline Onium),

Tetrakis (pentafluorophenyl) borate, diisopropyl ammonium,

Tetrakis (pentafluorophenyl) borate, dicyclohexyl ammonium,

Tetrakis (pentafluorophenyl) borate, triphenyl phosphonium,

Tetrakis (pentafluorophenyl) borate, tri (o-tolyl) phosphonium, and

Tetrakis (pentafluorophenyl) borate, tri (2,6 - dimethylphenyl) phosphonium.
65. Claimed in any one of claim 55-64, wherein the first catalyst component is capable of Polymer having an active end of the macromonomer; second component having an active end to produce a large Macromer.
66. Claimed in any one of claim 55 to 65, further including two olefins.
67. Claimed in any one of claim 55 to 65, further comprising one or more C4 to C40 diene.
68. Claimed in any one of claim 55 to 65, further including a selected from Or more of dienes: 1,6 - heptadiene, 1,7 - octadiene, 1,8 - nonadiene, 1,9 - decadiene, 1,10 - undecadiene, 1,11 - dodecadiene, 1,12 - tridecadiene, 1,13 - fourteen carbon , Cyclopentadiene, vinyl norbornene, norbornadiene, ethylidene norbornene, two Divinylbenzene, dicyclopentadiene, and Mw less than 1000g/mol polybutadiene or a combination thereof.
69 claimed in any one of claim 55 to 65, further including a selected from Or more of dienes: 1,6 - heptadiene, 1,7 - octadiene, 1,8 - nonadiene, 1,9 - decadiene, 1,10 - undecadiene, 1,11 - dodecadiene, 1,12 - tridecadiene, 1,13 - fourteen carbon , Cyclopentadiene, vinyl norbornene, norbornadiene, ethylidene norbornene, two Divinylbenzene, dicyclopentadiene, and Mw less than 1000g/mol polybutadiene or a combination thereof.
70. Claimed in any one of claim 55-69, wherein the reaction zone is a gas phase reactor.
72. Claimed in any one of claim 55-69, wherein the reaction zone of a solution-phase reaction Makers.
73. Claimed in any one of claim 55-69, wherein the reaction zone of the reaction slurry phase Makers.
74. Claimed in any one of claim 55-69, wherein the reaction zone of a solution-phase reaction Makers.
75. Claimed in any one of claim 55-74, wherein the catalyst composition comprising In one or more (wherein Me equals methyl, Ph equals phenyl group, Et is equal to ethyl, Cp, etc. The cyclopentadienyl,3,8-di-t-BuFlu equal to 3,8 - di-tert-butyl-fluorenyl,2-Me-4-PhInd Is 2 - methyl - 4 - phenyl-indenyl,2-MeInd is 2 - methyl indenyl, cC₁₂H ₂₃Equal to the ring THF, Me₄C ₅Equals four methylcyclopentadienyl, H₄Ind Ind equal tetrahydroindenyl group and other The indenyl):

(1)Me ₂Si(Me ₄C ₅)(N-c-C ₁₂H ₂₃)TiCl ₂And rac-Me₂Si(2-Me-4-PhInd) ₂ ZrCl ₂, Alumoxane activation;

(2)Me ₂Si(Me ₄C ₅)(N-C-C ₁₂H ₂₃)TiMe ₂And rac-Me₂Si(2-Me-4-PhInd) ₂ ZrMe ₂, With a non-coordinating anion activator activator;

(2a)Me ₂Si(Me ₄C ₅)(N-C-C ₁₂H ₂₃)TiMe ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or tetrakis triphenyl (Pentafluorophenyl) boron activator;

(3)Me ₂Si(Me ₄C ₅)(N-C-C ₁₂H ₂₃)TiCl ₂And rac-Me₂Si(2-MeInd) ₂ZrCl ₂, Alumoxane activation;

(4)Me ₂Si(Me ₄C ₅)(N-c-C ₁₂H ₂₃)TiMe ₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activator activator;

(4a)Me ₂Si(Me ₄C ₅)(N-C-C ₁₂H ₂₃)TiMe ₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl Yl) boron activator;

(5)Me ₂Si(Me ₄C ₅) (N-1-adamantyl) TiCl₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrCl ₂, Alumoxane activation;

(6)Me ₂Si(Me ₄C ₅) (N-1-adamantyl) TiMe₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(6a)Me ₂Si(Me ₄C ₅) (N-1-adamantyl) TiMe₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or tetrakis triphenyl (Pentafluorophenyl) boron activator;

(7)Me ₂Si(Me ₄C ₅) (N-1-adamantyl) TiCl₂And rac-Me₂Si(2-MeInd) ₂ ZrCl ₂, Alumoxane activation;

(8)Me ₂Si(Me ₄C ₅) (N-1-adamantyl) TiMe₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activator activator;

(8a)Me ₂Si(Me ₄C ₅) (N-1-adamantyl) TiMe₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl Yl) boron activator;

(9)Me ₂Si(Me ₄C ₅) (N-t-butyl) TiCl₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrCl ₂, Alumoxane activation;

(10)Me ₂Si(Me ₄C ₅) (N-tert-butyl) TiMe₂And rac-Me₂Si (2-Me-4-PhInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(10a)Me ₂Si(Me ₄C ₅) (N-tert-butyl) TiMe₂And rac-Me₂Si (2-Me-4-PhInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or tri- Triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(11)Me ₂Si(Me ₄C ₅) (N-t-butyl) TiCl₂And rac-Me₂Si (2-MeInd), with Aluminoxanes activation;

(12)Me ₂Si(Me ₄C ₅) (N-tert-butyl) TiMe₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activator activator;

(12a)Me ₂Si(Me ₄C ₅) (N-tert-butyl) TiMe₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluoro- Phenyl) boron activator;

(13)Me ₂Si(Me ₄C ₅) (N-outside - norbornyl) TiCl₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrCl ₂, Alumoxane activation;

(14)Me ₂Si(Me ₄C ₅) (N-outer - norbornyl) TiMe₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(14a)Me ₂Si(Me ₄C ₅) (N-outer - norbornyl) TiMe₂And rac-Me₂Si(2-Me-4 -PhInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbonium Tetrakis (pentafluorophenyl) boron activator;

(15)Me ₂Si(Me ₄C ₅) (N-outside - norbornyl) TiCl₂And rac-Me₂Si(2-MeInd) ₂ ZrCl ₂, Alumoxane activation;

(16)Me ₂Si(Me ₄C ₅) (N-outer - norbornyl) TiMe₂And rac-Me₂Si (2-MeInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(16a)Me ₂Si(Me ₄C ₅) (N-outer - norbornyl) TiMe₂And rac-Me₂Si (2-MeInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbonium Tetrakis (pentafluorophenyl) boron activator;

(17)(p-Et ₃SiPh) ₂C(Cp)(3，8-di-t-BuFlu)HfCl ₂And rac-Me₂Si (2-Me-4-PhInd) ₂ZrCl ₂, Alumoxane activation;

(18)(p-Et ₃SiPh) ₂C(Cp)(3，8-di-t-BuFlu)HfMe ₂And rac-Me₂Si (2-Me-4-PhInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(18a)(p-Et3SiPh) ₂C(Cp)(3，8-di-t-BuFlu)HfMe ₂And rac-Me₂Si (2-Me-4-PhInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or tri- Triphenylcarbenium tetrakis (pentafluorophenyl) boron activator;

(19)(p-Et ₃SiPh) ₂C(Cp)(3，8-di-t-BuFlu)HfCl ₂And rac-Me₂Si (2-MeInd) ₂ZrCl ₂, Alumoxane activation;

(20)(p-Et ₃SiPh) ₂C(Cp)(3，8-di-t-BuFlu)HfMe ₂And rac-Me₂Si (2-MeInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(20a)(p-Et ₃SiPh) ₂C(Cp)(3，8-di-t-BuFlu)HfMe ₂And rac-Me₂Si (2-MeInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbonium Tetrakis (pentafluorophenyl) boron activator;

(21) meso-CH₂CH ₂(Ind) ₂ZrCl ₂And rac-Me₂Si(H ₄Ind) ₂ZrCl ₂With Aluminoxanes activation;

(22) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-Me₂Si(H ₄Ind) ₂ZrMe ₂, With a non- Activator-coordinating anion;

(22a) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-Me₂Si(H ₄Ind) ₂ZrMe ₂With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl) boron Activity Technology;

(23) meso-CH₂CH ₂(Ind) ₂ZrCl ₂And rac-Me₂Si(2-MeInd) ₂ZrCl ₂With Aluminoxanes activation;

(24) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(24a) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl) boron Activation;

(25) meso-Me₂Si(Ind) ₂ZrCl ₂And rac-Me₂Si(H ₄Ind) ₂ZrCl ₂, Aluminum Siloxane activation;

(26) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-Me₂Si(H ₄Ind) ₂ZrMe ₂, With a non- Activator-coordinating anion;

(26a) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-Me₂Si(H ₄Ind) ₂ZrMe ₂With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl) boron Activity Technology;

(27) meso-Me₂Si(Ind) ₂ZrCl ₂And rac-Me₂Si(2-MeInd) ₂ZrCl ₂, Alumoxane activation;

(28) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(28a) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ZrMe ₂With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl) boron Activation;

(29) meso-Me₂Si(2-MeInd) ₂ZrCl ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrCl ₂, Alumoxane activation;

(30) meso-Me₂Si(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(30a) meso-Me₂Si(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or tetrakis triphenyl (Pentafluorophenyl) boron activator;

(31) meso-Me₂Si(2-MeInd) ₂ZrCl ₂And rac-Me₂Si(2-MeInd) ₂ ZrCl ₂, Alumoxane activation;

(32) meso-Me₂Si(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activator activator;

(32a) meso-Me₂Si(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl Yl) boron activator;

(33) meso-CH₂CH ₂(2-MeInd) ₂ZrCl ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrCl ₂, Alumoxane activation;

(34) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(34a) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-Me-4- PhInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or tetrakis triphenyl (Pentafluorophenyl) boron activator;

(35) meso-CH₂CH ₂(2-MeInd) ₂ZrCl ₂And rac-Me₂Si(2-MeInd) ₂ ZrCl ₂, Alumoxane activation;

(36) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activator activator;

(36a) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-Me₂Si(2-MeInd) ₂ ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl Yl) boron activator;

(37) meso-Me₂Si(2-Me-4-PhInd) ₂ZrCl ₂And rac-Me₂Si(2-Me- 4-PhInd) ₂ZrCl ₂, Alumoxane activation;

(38) meso-Me₂Si(2-Me-4-PhInd) ₂ZrMe ₂And rac-Me₂Si(2-Me- 4-PhInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(38a) meso-Me₂Si(2-Me-4-PhInd) ₂ZrMe ₂And rac-Me₂Si(2-Me -4-PhInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbonium Tetrakis (pentafluorophenyl) boron activator;

(39) meso-CH₂CH ₂(2-Me-4-PhInd) ₂ZrCl ₂And rac-CH₂CH ₂ (2-Me-4-PhInd) ₂ZrCl ₂, Alumoxane activation;

(40) meso-CH₂CH ₂(2-Me-4-PhInd) ₂ZrMe ₂And rac-CH₂CH ₂ (2-Me-4-PhInd) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(40a) meso-CH₂CH ₂(2-Me-4-PhInd) ₂ZrMe ₂And rac-CH₂CH ₂ (2-Me-4-PhInd) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenylmethyl Carbon tetrakis (pentafluorophenyl) boron activator;

(41) meso-CH₂CH ₂(2-MeInd) ₂ZrCl ₂And rac-CH₂CH ₂(2-MePhInd) ₂ ZrCl ₂, Alumoxane activation;

(42) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-CH₂CH ₂(2-MeInd) ₂ ZrMe ₂, With a non-coordinating anion activator activator;

(42a) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-CH₂CH ₂(2-MeInd) ₂ ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluoro- Phenyl) boron activator;

(43) meso-CH₂CH ₂(Ind) ₂ZrCl ₂And rac-CH₂CH ₂(Ind) ₂ZrCl ₂, Aluminum Siloxane activation;

(44) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-CH₂CH ₂(Ind) ₂ZrMe ₂, With a non- Activator-coordinating anion;

(44a) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-CH₂CH ₂(Ind) ₂ZrMe ₂With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl) boron Activity Technology;

(45) meso-Me₂Si(Ind) ₂ZrCl ₂And rac-Me₂Si(Ind) ₂ZrCl ₂, Aluminum Siloxane activation;

(46) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-Me₂Si(Ind) ₂ZrMe ₂, With a non- Activator-coordinating anion;

(46a) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-Me₂Si(Ind) ₂ZrMe ₂With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl) boron Activity Technology;

(47) meso-CH₂CH ₂(Ind) ₂ZrCl ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrCl ₂(4，7-Me ₂Ind = 4,7 - dimethyl-indenyl), alumoxane activated;

(48) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrMe ₂, With a non-coordinating anion activator activator;

(48a) meso-CH₂CH ₂(Ind) ₂ZrMe ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl Yl) boron activator;

(49) meso-Me₂Si(Ind) ₂ZrCl ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrCl ₂, Alumoxane activation;

(50) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrMe ₂, With a non-coordinating anion activator activator;

(50a) meso-Me₂Si(Ind) ₂ZrMe ₂And rac-CH₂CH ₂(4，7-Me ₂Ind) ₂ ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl carbenium tetrakis (pentafluorophenyl Yl) boron activator;

(51) meso-CH₂CH ₂(2-MeInd) ₂ZrCl ₂And rac-CH₂CH ₂ (4，7-Me ₂Ind) ₂ZrCl ₂(4，7-Me ₂Ind = 4,7 - dimethyl-indenyl), alumoxane activated;

(52) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-CH₂CH ₂ (4，7-Me ₂Ind) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(52a) meso-CH₂CH ₂(2-MeInd) ₂ZrMe ₂And rac-CH₂CH ₂ (4，7-Me ₂Ind) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl Tetrakis (pentafluorophenyl) boron activator;

(53) meso-Me₂Si(2-MeInd) ₂ZrCl ₂And rac-CH₂CH ₂ (4，7-Me ₂Ind) ₂ZrCl ₂, Alumoxane activation;

(54) meso-Me₂Si(2-MeInd) ₂ZrMe ₂And rac-CH₂CH ₂ (4，7-Me ₂Ind) ₂ZrMe ₂, With a non-coordinating anion activator activator;

(54a) meso-Me₂Si(2-MeInd) ₂ZrMe ₂And rac-CH₂CH ₂ (4，7-Me ₂Ind) ₂ZrMe ₂, With N, N-dimethylaniline tetrakis (pentafluorophenyl) boron and / or triphenyl Tetrakis (pentafluorophenyl) boron activators.
76. Claimed in any one of claim 55 to 75, wherein the second catalyst sub-group Including the following materials in one or more of:

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - Silicon fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Hafnium;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Hafnium;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5' - bis - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5' - bis - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dichloride;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Hafnium dimethyl;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂ η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1 ,3-butadiene;

Dimethylsilyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Dimethylsilyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylsilyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylsilyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

9 - sila-fluorene-diyl group (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl - 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl - 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

9 - sila-fluorene-diyl group (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - butyl 4 - [3, 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Dimethylamino borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Dimethylamino borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dichloride;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dichloro- Zirconium;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dichloride Zirconium;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂η ⁴-1,4 - Diphenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Diphenyl -1,3 - Butadiene;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂η ⁴-1,4 - Two Phenyl-1 ,3 - butadiene;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Zirconium dimethyl;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di-tert-butylphenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl]-indenyl)₂Dimethyl Base zirconium;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Borane diisopropylamide (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Borane diisopropylamide (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - butyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Borane diisopropylamide (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indenyl)₂Dimethyl Zirconium;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dichloride;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-di - isopropyl-phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂η ⁴-1,4 - Diphenyl 1,3 - butadiene;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di-t-butyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5' II - t-butylphenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-bis - (trifluoromethyl) phenyl] Indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-diisopropyl-phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - methyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - ethyl 4 - [3 ', 5'-di - phenyl] indenyl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-propyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - isopropyl-4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - n-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - iso-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dimethyl;

Bis (trimethylsilyl) amino-borane (2 - butyl 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dimethyl; or

Bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl] indene Yl)₂Zirconium dimethyl.
77. Claimed in any one of claim 55 to 75, wherein the second catalyst component comprises One or more of bis (trimethylsilyl) amino-borane (2 - tert-butyl, 4 - [3 ', 5'-di - phenyl -Phenyl] indenyl)₂Zirconium dimethyl.
78 A continuous process for preparing a binder, comprising:

1) the monomers, solvent, catalyst and the activator with the reactor system,

2) from the reactor system, the polymer solution is discharged,

3) is removed from the polymer solution, at least 10% solvent,

4) quenching the reaction,

5) The polymer solution was devolatilized molten polymer is formed,

6) the molten polymer and one or more additives in a static mixer to combine,

7) is removed from the static mixer the polymer conjugate, and

8) the polymer conjugates or drum granulation process.
79 A method for producing a continuous branched olefin polymer, comprising:

1) Select the first catalyst component, the catalyst component is capable of polymerization conditions in the selected xiasheng Producing a Mw of 80,000 or less and a crystallinity of 15% or less of the polymer;

2) Select the second catalyst component, the catalyst component is capable of polymerization conditions in the selected xiasheng Producing a Mw of 80,000 or less and a crystallinity of 50% or more of the polymer;

3) The catalyst component of one or more activating agent in the presence of propylene and one or Variety of C4 to C20 olefins and one or more non-essential C4 to C20 dienes in contact;

4) at a temperature above 105 ℃ under;

5) the dwell time of 120 minutes or less within;

6) wherein the first catalyst and the second catalyst ratio of 1:1 to 20:1;

7) in which the activity of the catalyst component is at least 100kg g polymer / g catalyst compound; And wherein at least 80% of the olefin conversion to polymer.
80. The method of claim 79, wherein

a) the olefin comprises propylene and butene, pentene, hexene, heptene, octene, nonene, decene Alkenyl, dodecene in one or more of; and

b) temperature is higher than 110 ℃; and

c) a residence time of 60-120 minutes; and

d) the first catalyst and the second catalyst ratio of 1:1 to 1:10.
81. Claimed in claim 79 or 80, wherein the presence of diene and selected from 1,6 - pimelic Ene, 1,7 - octadiene, 1,8 - nonadiene, 1,9 - decadiene, 1,10 - undecadiene, 1,11 - Dodecadiene, 1,12 - tridecadiene, 1,13 - tetradecadiene, cyclopentadiene, vinyl Norbornene, norbornadiene, ethylidene norbornene, divinylbenzene, dicyclopentadiene, Mw less than 1000g/mol polybutadiene, butadiene, pentadiene, hexadiene, pentadecadiene, Sixteen carbon diene heptadecadienyl, octadecadienoic, nineteen carbon diene, twenty carbon diene, two Undecadiene, two dodecadiene twenty three-carbon diene tetracosenic diene, xxv carbon Diene, hexacosene diene, two heptadecadienyl, two octadecadienoic, 29 carbon diene, Thirty carbon, cyclopentadiene, vinyl norbornene, norbornadiene, ethylidene-norbornene Ene, divinylbenzene, dicyclopentadiene, or combinations thereof. ...
81. Claimed in claim 79 or 80, wherein the presence of diene and selected from 1,6 - pimelic Ene, 1,7 - octadiene, 1,8 - nonadiene, 1,9 - decadiene, 1,10 - undecadiene, 1,11 - Dodecadiene, 1,12 - tridecadiene, 1,13 - tetradecadiene, cyclopentadiene, vinyl Norbornene, norbornadiene, ethylidene norbornene, divinylbenzene, dicyclopentadiene, Mw less than 1000g/mol polybutadiene, butadiene, pentadiene, hexadiene, pentadecadiene, Sixteen carbon diene heptadecadienyl, octadecadienoic, nineteen carbon diene, twenty carbon diene, two Undecadiene, two dodecadiene twenty three-carbon diene tetracosenic diene, xxv carbon Diene, hexacosene diene, two heptadecadienyl, two octadecadienoic, 29 carbon diene, Thirty carbon, cyclopentadiene, vinyl norbornene, norbornadiene, ethylidene-norbornene Ene, divinylbenzene, dicyclopentadiene, or combinations thereof. ...
83 A continuous process for preparing a binder, comprising:

1) Select the first catalyst component, the catalyst component is capable of polymerization conditions in the selected xiasheng Mw of 100,000 or less produced and the degree of crystallinity of 5% or less of the polymer;

2) Select the second catalyst component, the catalyst component is capable of polymerization conditions in the selected xiasheng Mw of 100,000 or less produced, and a crystallinity of 20% or more of the polymer;

3) These catalyst components in the solvent in the reaction zone under polymerization conditions in the selected In one or more of the activating agent in the presence of one or more C3 to C40 olefins and a non-essential Dienes or more kinds of exposure;

4) at a temperature higher than 100 ℃ lower;

5) the residence time of 120 minutes or less under;

6) wherein the first catalyst and the second catalyst ratio of 1:1 to 50:1;

7) in which the activity of the catalyst component is at least 50kg g polymer / g catalyst compound; and Wherein at least 80% of the conversion of the olefin polymer;

8) discharged from the reaction section of the polymer solution;

9) is removed from the polymer solution, at least 10% solvent;

10) the reaction was quenched;

11) from the devolatilized polymer solution to form a molten polymer;

12) the molten polymer and one or more additives in a static mixer combined;

13) is removed from the static mixer the polymer conjugate; and

14) The polymer conjugate or drum granulation process.