CN1690177A - Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same - Google Patents

Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same Download PDF

Info

Publication number
CN1690177A
CN1690177A CN 200410013731 CN200410013731A CN1690177A CN 1690177 A CN1690177 A CN 1690177A CN 200410013731 CN200410013731 CN 200410013731 CN 200410013731 A CN200410013731 A CN 200410013731A CN 1690177 A CN1690177 A CN 1690177A
Authority
CN
China
Prior art keywords
orimulsion
oil
minutes
additive
triethanolamine
Prior art date
Application number
CN 200410013731
Other languages
Chinese (zh)
Inventor
李英华
李冰
李文龙
刘贵臣
Original Assignee
李英华
李文龙
刘贵臣
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 李英华, 李文龙, 刘贵臣 filed Critical 李英华
Priority to CN 200410013731 priority Critical patent/CN1690177A/en
Publication of CN1690177A publication Critical patent/CN1690177A/en

Links

Abstract

A modifying additive of soluble oil, modifying bunker fuel oil, and the manufacturing technique. Soluble oil is used early at home and abroad, but poor stability, being easily layered and demulsified in use affects the service effect. The component of modifying additive of soluble oil contains naphthenic acid, and the related additive also contains oleic acid, carbonyl amine, triethanolamine, isoamyl alcohol or methanol, kalii permangana, spans-80, and the weight ratio being that, naphthenic acid 39, oleic acid 15, carbonyl amine 5, triethanolamine 8 to 15, isoamyl alcohol or methanol 12 to 20, kalii permangana 5, and spans-80 10 to 15. The product can apply in bunker fuel.

Description

奥里乳化油改性添加剂、改性船用燃料油及制作工艺 Orimulsion modifying additive, marine fuel oil, and a modified production process

技术领域 FIELD

:本发明涉及一种奥里乳化油改性添加剂及其改性船用燃料油,还包括该添加剂和燃料油的加工工艺。 : The present invention relates to an Orimulsion modifying additive and a modified marine fuel, further comprising processing the additive and fuel oil.

背景技术 Background technique

:乳化油在国内外已被较早利用,而乳化油在使用中存在稳定性差,易分层、破乳,影响使用效果。 : Emulsified oil at home and abroad have earlier been utilized, while the oil emulsion in the presence of poor stability in use, and easy delamination and demulsification, affect the results.

发明内容 SUMMARY

:本发明的目的是提供一种稳定性好,不分层,不破乳的奥里乳化油改性添加剂、改性船用燃料油及制作工艺。 : Object of the present invention is to provide a good stability, non-hierarchical, no demulsification of Orimulsion modifying additive, marine fuel oil, and a modified production process.

本发明的目的是这样实现的:奥里乳化油改性添加剂,其组成包括:环烷酸,所述的添加剂还包括油酸、碳酰胺、三乙醇胺、异戊醇或甲醇、高锰酸钾、司盘-80,其重量份数比为环烷酸39、油酸15、碳酰胺5、三乙醇胺8~15、异戊醇或甲醇12~20、高锰酸钾5、司盘-80 10~15。 The object of the present invention is implemented: Orimulsion modifying additive, a composition comprising: a naphthenic acid, said additive further comprises oleic acid, carboxamide, triethanolamine, isoamyl alcohol or methanol, potassium permanganate , Span -80 in a weight ratio of naphthenic parts 39, 15 of oleic acid, 5-carboxamide, triethanolamine, 8 to 15, isoamyl alcohol or methanol 12 to 20, 5 potassium permanganate, Span -80 10 to 15.

上述的奥里乳化油改性添加剂的加工工艺,按上述所述的重量份数依次将环烷酸、油酸、碳酰胺、三乙醇胺、异戊醇或甲醇、高锰酸钾、司盘-80倒入调合罐内,在10℃~30℃的温度下,搅拌10分钟,将其温度上升至50℃~80℃之间,静止30分钟,过滤。 The above-described process Orimulsion modifying additives, in parts by weight of the above-described sequentially naphthenic acid, oleic acid, carboxamide, triethanolamine, isoamyl alcohol or methanol, potassium permanganate, Span - 80 was poured into the blending tank, at a temperature of 10 ℃ ~ 30 ℃, stirred for 10 minutes, the temperature raised to between 50 ℃ ~ 80 ℃, rest 30 minutes and filtered.

上述的奥里乳化油在制作改性船用燃料油上的应用,所述的燃料油的主要原料包括奥里乳化油、0#轻柴油、奥里油改性添加剂,其重量份数比为奥里乳化油75.8、0#轻柴油22.7、奥里油改性添加剂1.5。 Application of the above-described Orimulsion in the production of modified marine fuel, the main raw material include Orimulsion fuel oil, light diesel # 0, Orimulsion modifying additive in a weight ratio of parts of Austria in the light diesel oil emulsion # 75.8,0 22.7, 1.5 Orimulsion modifying additive.

上述的奥里乳化油改性船用燃料油的加工工艺,所述的奥里乳化油在进入合成釜前,先过滤,再细滤,滤出直径为10μm~30μm之间的颗粒,最后再精滤,通过过滤机的压力强制过滤,使其颗粒直径在1μm~5μm之间,按上述所述的重量份数将各原料加入合成釜内,经高速剪切机连续搅拌10分钟,即合成油包水乳化燃料,静止存放30分钟,过滤。 Orimulsion above modified process of marine fuel oil, Orimulsion said synthesis reactor before entering the first filter, fine filter and then filtered out particles having a diameter between 10μm ~ 30μm, and finally fine filtration, forced filtration by filter press, making the particle diameter between 1μm ~ 5μm, parts by weight of the above-described respective raw materials added to the synthesis reactor, subjected to high shear stirring was continued for 10 minutes, or synthetic oils The water emulsion fuel, stationary storage 30 minutes and filtered.

本发明的优点在于:1.本发明的奥里乳化油改性添加剂主要用来调配委内瑞拉生产的奥里乳化油改性船用柴油机燃料,奥里乳化油改性添加剂可改变奥里乳化油水包油液体改性为油包水的液体,提高燃烧强度,便于点火。 Advantage of the present invention is that: 1 Orimulsion modifying additive formulations of the present invention is mainly used Orimulsion modified marine diesel fuel produced in Venezuela, Orimulsion modifying additives may be water-in-oil change Orimulsion liquid modifier is a liquid oil-in-water, improved combustion intensity, to facilitate ignition.

2.本产品用作船用柴油机燃料,使用该燃料不仅可节约燃料,而且还可提高机械效率,减少尾气排放。 2. The product is used marine diesel fuel, the fuel used not only fuel savings, but also improves the mechanical efficiency and reduce emissions.

3.该添加剂的加工工艺简单,容易操作,由该添加剂制成的燃料油稳定性好,其稳定时间超过一年,并具有不变质,不分层,不破乳,可降低油品倾点等特点。 3. The additive process is simple, easy to operate, good stability formed by the fuel oil additive, its stable for more than one year, and having a non-degenerate, no delamination, no emulsion breaking, and the like can reduce the pour point oil features.

本发明的具体实施方式:实施例1:奥里乳化油改性添加剂及其加工工艺,其组成包括:环烷酸,所述的添加剂还包括油酸、碳酰胺、三乙醇胺、异戊醇或甲醇、高锰酸钾、司盘-80,其重量份数比为环烷酸39、油酸15、碳酰胺5、三乙醇胺8、异戊醇或甲醇12、高锰酸钾5、司盘-80 10,其加工工艺是:按上述所述的重量份数依次将环烷酸、油酸、碳酰胺、三乙醇胺、异戊醇或甲醇、高锰酸钾、司盘-80倒入调合罐内,在10℃的温度下,搅拌10分钟,将其温度上升至50℃,静止30分钟,过滤,装桶。 DETAILED DESCRIPTION embodiment of the present invention: Orimulsion modifying additive and its production process, the composition comprising:: a naphthenic embodiments, the additive further comprises oleic acid, carboxamide, triethanolamine, or isoamyl alcohol methanol, potassium permanganate, Span -80 in a weight ratio of naphthenic parts 39, 15 of oleic acid, 5-carboxamide, 8 triethanolamine, isoamyl alcohol or methanol 12, 5 potassium permanganate, Span -8010, which process is: parts by weight of the above-described sequentially naphthenic acid, oleic acid, carboxamide, triethanolamine, isoamyl alcohol or methanol, potassium permanganate, Span -80 transferred into the tank together, at the temperature 10 ℃, stirred for 10 minutes, its temperature was raised to 50 ℃, rest 30 minutes, filtered, barreling.

实施例2:奥里乳化油改性添加剂及其加工工艺,其组成包括:环烷酸,所述的添加剂还包括油酸、碳酰胺、三乙醇胺、异戊醇或甲醇、高锰酸钾、司盘-80,其重量份数比为环烷酸39、油酸15、碳酰胺5、三乙醇胺15、异戊醇或甲醇20、高锰酸钾5、司盘-80 15,其加工工艺是:按上述所述的重量份数依次将环烷酸、油酸、碳酰胺、三乙醇胺、异戊醇或甲醇、高锰酸钾、司盘-80倒入调合罐内,在30℃的温度下,搅拌10分钟,将其温度上升至80℃,静止30分钟,过滤,装桶。 Example 2: Orimulsion modifying additive and its production process, the composition comprising: a naphthenic acid, said additive further comprises oleic acid, carboxamide, triethanolamine, isoamyl alcohol or methanol, potassium permanganate, Span -80 in a weight ratio of naphthenic parts 39, 15 of oleic acid, 5-carboxamide, triethanolamine 15, 20 isoamyl alcohol or methanol, potassium permanganate 5, Span 15 -80, which process is: parts by weight of the above-described sequentially naphthenic acid, oleic acid, carboxamide, triethanolamine, isoamyl alcohol or methanol, potassium permanganate, Span -80 poured into blending tank, at 30 deg.] C at a temperature, stirred for 10 minutes, its temperature was raised to 80 ℃, rest 30 minutes, filtered, barreling.

实施例3:奥里乳化油改性添加剂及其加工工艺,其组成包括:环烷酸,所述的添加剂还包括油酸、碳酰胺、三乙醇胺、异戊醇或甲醇、高锰酸钾、司盘-80,其重量份数比为环烷酸39、油酸15、碳酰胺5、三乙醇胺12、异戊醇或甲醇16、高锰酸钾5、司盘-80 13,其加工工艺是:按上述所述的重量份数依次将环烷酸、油酸、碳酰胺、三乙醇胺、异戊醇或甲醇、高锰酸钾、司盘-80倒入调合罐内,在20℃的温度下,搅拌10分钟,将其温度上升至70℃,静止30分钟,过滤,装桶。 Example 3: Orimulsion modifying additive and its production process, the composition comprising: a naphthenic acid, said additive further comprises oleic acid, carboxamide, triethanolamine, isoamyl alcohol or methanol, potassium permanganate, Span -80 in a weight ratio of naphthenic parts 39, 15 of oleic acid, 5-carboxamide, triethanolamine 12, 16 isoamyl alcohol or methanol, potassium permanganate 5, Span -8013, which process They are: parts by weight of the above-described sequentially naphthenic acid, oleic acid, carboxamide, triethanolamine, isoamyl alcohol or methanol, potassium permanganate, Span -80 poured into blending tank, at 20 ℃ at a temperature, stirred for 10 minutes, its temperature was raised to 70 ℃, rest 30 minutes, filtered, barreling.

实施例4:奥里乳化油改性船用燃料油及其加工工艺,所述的燃料油的主要原料包括奥里乳化油、0#轻柴油、奥里油改性添加剂,其重量份数比为奥里乳化油75.8、0#轻柴油22.7、奥里油改性添加剂1.5,其加工工艺是:所述的奥里乳化油在进入合成釜前,先过滤,再细滤,滤出直径为10μm的颗粒,最后再精滤,通过过滤机的压力强制过滤,使其颗粒直径为1μm,按上述所述的重量份数将各原料加入合成釜内,经高速剪切机连续搅拌10分钟,即合成油包水乳化燃料,静止存放30分钟,过滤,装桶。 Example 4: Modification of marine fuel oil Orimulsion and processing technology, the main raw material comprises the Orimulsion fuel oil, light diesel # 0, Orimulsion modifying additive in a weight ratio of parts Orimulsion light diesel # 75.8,0 22.7, 1.5 Orimulsion modifying additive, which process is: the Orimulsion before entering the synthesis reactor, the first filtered, fine filter, having a diameter of 10μm was filtered off particles, and finally fine filtration, forced filtration by filter press, the particle diameter of 1 m so that, according to the above-mentioned parts by weight of the respective raw materials added to the synthesis reactor, subjected to high shear stirring was continued for 10 minutes, that is synthetic water-emulsion fuel, a stationary storage 30 minutes, filtered, barreling.

实施例5:奥里乳化油改性船用燃料油及其加工工艺,所述的燃料油的主要原料包括奥里乳化油、0#轻柴油、奥里油改性添加剂,其重量份数比为奥里乳化油75.8、0#轻柴油22.7、奥里油改性添加剂1.5,其加工工艺是:所述的奥里乳化油在进入合成釜前,先过滤,再细滤,滤出直径为30μm的颗粒,最后再精滤,通过过滤机的压力强制过滤,使其颗粒直径为5μm,按上述所述的重量份数将各原料加入合成釜内,经高速剪切机连续搅拌10分钟,即合成油包水乳化燃料,静止存放30分钟,过滤,装桶。 Example 5: Modification of marine fuel oil Orimulsion and processing technology, the main raw material comprises the Orimulsion fuel oil, light diesel # 0, Orimulsion modifying additive in a weight ratio of parts Orimulsion light diesel # 75.8,0 22.7, 1.5 Orimulsion modifying additive, which process is: the Orimulsion before entering the synthesis reactor, the first filtered, fine filter, having a diameter of 30μm was filtered off particles, and finally fine filtration, forced filtration by filter press, the particle diameter of 5 m so that, according to the above-mentioned parts by weight of the respective raw materials added to the synthesis reactor, subjected to high shear stirring was continued for 10 minutes, that is synthetic water-emulsion fuel, a stationary storage 30 minutes, filtered, barreling.

实施例6:奥里乳化油改性船用燃料油及其加工工艺,所述的燃料油的主要原料包括奥里乳化油、0#轻柴油、奥里油改性添加剂,其重量份数比为奥里乳化油75.8、0#轻柴油22.7、奥里油改性添加剂1.5,其加工工艺是:所述的奥里乳化油在进入合成釜前,先过滤,再细滤,滤出直径为20μm的颗粒,最后再精滤,通过过滤机的压力强制过滤,使其颗粒直径为3μm,按上述所述的重量份数将各原料加入合成釜内,经高速剪切机连续搅拌10分钟,即合成油包水乳化燃料,静止存放30分钟,过滤,装桶。 Example 6: Modification of marine fuel oil Orimulsion and processing technology, the main raw material comprises the Orimulsion fuel oil, light diesel # 0, Orimulsion modifying additive in a weight ratio of parts Orimulsion light diesel # 75.8,0 22.7, 1.5 Orimulsion modifying additive, which process is: the Orimulsion before entering the synthesis reactor, the first filtered, fine filter, having a diameter of 20μm was filtered off particles, and finally fine filtration, forced filtration by filter press, the particle diameter of 3 m so that, according to the above-mentioned parts by weight of the respective raw materials added to the synthesis reactor, subjected to high shear stirring was continued for 10 minutes, that is synthetic water-emulsion fuel, a stationary storage 30 minutes, filtered, barreling.

Claims (4)

1.一种奥里乳化油改性添加剂,其组成包括:环烷酸,其特征是:所述的添加剂还包括油酸、碳酰胺、三乙醇胺、异戊醇或甲醇、高锰酸钾、司盘-80,其重量份数比为环烷酸39、油酸15、碳酰胺5、三乙醇胺8~15、异戊醇或甲醇12~20、高锰酸钾5、司盘-80 10~15。 A Orimulsion modifying additive, a composition comprising: a naphthenic acid, wherein: said additive further comprises oleic acid, carboxamide, triethanolamine, isoamyl alcohol or methanol, potassium permanganate, Span -80 in a weight ratio of naphthenic parts 39, 15 of oleic acid, 5-carboxamide, triethanolamine, 8 to 15, isoamyl alcohol or methanol 12 to 20, 5 potassium permanganate, Span -8010 to 15.
2.一种权利要求1所述的奥里乳化油改性添加剂的加工工艺,其特征是:按上述所述的重量份数依次将环烷酸、油酸、碳酰胺、三乙醇胺、异戊醇或甲醇、高锰酸钾、司盘-80倒入调合罐内,在10℃~30℃的温度下,搅拌10分钟,将其温度上升至50℃~80℃之间,静止30分钟,过滤。 Orimulsion modifying additive is 2. A process as claimed in claim 1, characterized in that: parts by weight of the above-described sequentially naphthenate, oleic acid, carboxamide, triethanolamine, isopentyl alcohol or methanol, potassium permanganate, Span -80 poured into blending tank, at a temperature of 10 ℃ ~ 30 ℃, stirred for 10 minutes, the temperature raised to between 50 ℃ ~ 80 ℃, rest 30 minutes ,filter.
3.一种权利要求1所述的奥里乳化油在制作改性船用燃料油上的应用,其特征是:所述的燃料油的主要原料包括奥里乳化油、0#轻柴油、奥里油改性添加剂,其重量份数比为奥里乳化油75.8、0#轻柴油22.7、奥里油改性添加剂1.5。 An application Orimulsion claimed in claim 1 in the production of modified marine fuel, characterized in that: the main raw material include Orimulsion fuel oil, light diesel oil # 0, Orinoco oil-modified additive parts by weight ratio of Orimulsion light diesel # 75.8,0 22.7, 1.5 Orimulsion modifying additive.
4.一种权利要求3所述的奥里乳化油改性船用燃料油的加工工艺,其特征是:所述的奥里乳化油在进入合成釜前,先过滤,再细滤,滤出直径为10μm~30μm之间的颗粒,最后再精滤,通过过滤机的压力强制过滤,使其颗粒直径在1μm~5μm之间,按上述所述的重量份数将各原料加入合成釜内,经高速剪切机连续搅拌10分钟,即合成油包水乳化燃料,静止存放30分钟,过滤。 Orimulsion modified Marine fuel 4. A process as claimed in claim 3, wherein: said Orimulsion before entering the synthesis reactor, the first filter, fine filter and then filtered off diameter of particles between 10μm 30μm ~, and finally fine filtration, forced filtration by filter press, making the particle diameter between 1μm ~ 5μm, parts by weight of the above-described respective raw materials added to the synthesis reactor, by high shear machine continuously stirred for 10 minutes, i.e., synthetic water-emulsion fuel, a stationary storage 30 minutes and filtered.
CN 200410013731 2004-04-30 2004-04-30 Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same CN1690177A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200410013731 CN1690177A (en) 2004-04-30 2004-04-30 Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200410013731 CN1690177A (en) 2004-04-30 2004-04-30 Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same

Publications (1)

Publication Number Publication Date
CN1690177A true CN1690177A (en) 2005-11-02

Family

ID=35345937

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200410013731 CN1690177A (en) 2004-04-30 2004-04-30 Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same

Country Status (1)

Country Link
CN (1) CN1690177A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7854774B2 (en) 2006-05-26 2010-12-21 Amyris Biotechnologies, Inc. Fuel components, fuel compositions and methods of making and using same
CN101323802B (en) 2008-07-25 2011-06-08 西安祺祥能源科技发展有限公司 Stable synergistic of methanol diesel for vehicle
US9200296B2 (en) 2006-05-26 2015-12-01 Amyris Inc. Production of isoprenoids

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7854774B2 (en) 2006-05-26 2010-12-21 Amyris Biotechnologies, Inc. Fuel components, fuel compositions and methods of making and using same
US9200296B2 (en) 2006-05-26 2015-12-01 Amyris Inc. Production of isoprenoids
US10106822B2 (en) 2006-05-26 2018-10-23 Amyris, Inc. Production of isoprenoids
CN101323802B (en) 2008-07-25 2011-06-08 西安祺祥能源科技发展有限公司 Stable synergistic of methanol diesel for vehicle

Similar Documents

Publication Publication Date Title
Fattah et al. Impact of various biodiesel fuels obtained from edible and non-edible oils on engine exhaust gas and noise emissions
Giakoumis et al. Exhaust emissions with ethanol or n-butanol diesel fuel blends during transient operation: a review
CN1084377C (en) Aqueous fuel for internal combustion engine and its producing process
Pandey et al. Impact of alternative fuel properties on fuel spray behavior and atomization
CN1659258B (en) Synthetic fuel with reduced particulate matter emissions and a method of operating a compression ignition engine using said fuel in conjunction with oxidation catalysts
KR20010089492A (en) Diesel fuel composition
JP2002530515A (en) Diesel fuel composition
CN1795258A (en) Process to upgrade kerosenes and a gasoils from naphthenic and aromatic crude petroleum sources
CN1720318A (en) Diesel fuel compositions
JP2005023136A (en) Gas oil composition
US1423049A (en) Fuel of liquid type
EP0587654A1 (en) Fuel mixture, method of producing it, and its use.
Adelman Alcohols in Diesel Engines-A Review
WO2009068540A1 (en) Fuel formulations
Mondal et al. Direct use of vegetable oil and animal fat as alternative fuel in internal combustion engine
RU2008109201A (en) The fuel compositions
JP2013533914A (en) Diesel fuel additive
JPH11515037A (en) Using an emulsion fuel and the gas turbine
CN100357405C (en) Gasoline composition
TW200702433A (en) Biofuel conversion process
WO2007138776A1 (en) Gas oil composition
KR20090098702A (en) Fuel for homogeneous charge compression ignition engine
DE19622601C1 (en) Biofuel used in diesel engines
Johnson et al. Emissions from Fischer-Tropsch diesel fuels
EA201070308A1 (en) A method for producing diesel fuel

Legal Events

Date Code Title Description
C06 Publication
C10 Request of examination as to substance
C02 Deemed withdrawal of patent application after publication (patent law 2001)