CN1690177A - Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same - Google Patents

Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same Download PDF

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Publication number
CN1690177A
CN1690177A CN 200410013731 CN200410013731A CN1690177A CN 1690177 A CN1690177 A CN 1690177A CN 200410013731 CN200410013731 CN 200410013731 CN 200410013731 A CN200410013731 A CN 200410013731A CN 1690177 A CN1690177 A CN 1690177A
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China
Prior art keywords
oil
crude oil
emulsified
orinoco crude
minutes
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CN 200410013731
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Chinese (zh)
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李英华
李冰
李文龙
刘贵臣
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Priority to CN 200410013731 priority Critical patent/CN1690177A/en
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Abstract

A modifying additive of soluble oil, modifying bunker fuel oil, and the manufacturing technique. Soluble oil is used early at home and abroad, but poor stability, being easily layered and demulsified in use affects the service effect. The component of modifying additive of soluble oil contains naphthenic acid, and the related additive also contains oleic acid, carbonyl amine, triethanolamine, isoamyl alcohol or methanol, kalii permangana, spans-80, and the weight ratio being that, naphthenic acid 39, oleic acid 15, carbonyl amine 5, triethanolamine 8 to 15, isoamyl alcohol or methanol 12 to 20, kalii permangana 5, and spans-80 10 to 15. The product can apply in bunker fuel.

Description

Emulsified orinoco crude oil property-modifying additive, modification marine fuel oil and manufacture craft
Technical field: the present invention relates to a kind of emulsified orinoco crude oil property-modifying additive and modification marine fuel oil thereof, also comprise the complete processing of this additive and oil fuel.
Background technology: oil in water emulsion is at home and abroad early utilized, and in use there is poor stability in oil in water emulsion, and easily layering, breakdown of emulsion influence result of use.
Summary of the invention: the purpose of this invention is to provide a kind of good stability, not stratified, not the emulsified orinoco crude oil property-modifying additive of breakdown of emulsion, modification marine fuel oil and manufacture craft.
The object of the present invention is achieved like this:
The emulsified orinoco crude oil property-modifying additive, its composition comprises: naphthenic acid, described additive also comprises oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80, and its ratio of weight and number is naphthenic acid 39, oleic acid 15, carboxamide 5, trolamine 8~15, primary isoamyl alcohol or methyl alcohol 12~20, potassium permanganate 5, Arlacel-80 10~15.
The complete processing of above-mentioned emulsified orinoco crude oil property-modifying additive, successively naphthenic acid, oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80 are poured in the tempering tank by above-mentioned described parts by weight, under 10 ℃~30 ℃ temperature, stirred 10 minutes, its temperature is risen between 50 ℃~80 ℃, static 30 minutes, filter.
Above-mentioned emulsified orinoco crude oil is in the application of making on the modification marine fuel oil, and the main raw material of described oil fuel comprises emulsified orinoco crude oil, 0 #Solar oil, oli oil property-modifying additive, its ratio of weight and number are emulsified orinoco crude oil 75.8,0 #Solar oil 22.7, oli oil property-modifying additive 1.5.
The complete processing of above-mentioned emulsified orinoco crude oil modification marine fuel oil, described emulsified orinoco crude oil are filtered earlier before entering synthesis reactor, fine filtering again, leach diameter and be the particle between 10 μ m~30 μ m, smart more at last filter is by the pressure forced filtration of filter, make its particle diameter between 1 μ m~5 μ m, by above-mentioned described parts by weight each raw material is added in synthesis reactor, through high-speed shearing machine continuously stirring 10 minutes, promptly synthetic water-in-oil emulsified fuel, static depositing 30 minutes filtered.
The invention has the advantages that:
1. emulsified orinoco crude oil property-modifying additive of the present invention is mainly used to allocate the emulsified orinoco crude oil modification marine diesel fuel that Venezuela produces, it is water in oil liquid that the emulsified orinoco crude oil property-modifying additive can change emulsified orinoco crude oil oil-in-water liquid modifying, improve intensity of combustion, be convenient to igniting.
2. this product uses this fuel not only capable of saving fuel, but also can improve mechanical efficiency as marine diesel fuel, reduces exhaust emissions.
3. the complete processing of this additive is simple, easily operation, and by the oil fuel good stability that this additive is made, surpass 1 year its steady time, and have and never degenerate, and not stratified, breakdown of emulsion can not reduce characteristics such as oil pour point.
The specific embodiment of the present invention:
Embodiment 1:
Emulsified orinoco crude oil property-modifying additive and complete processing thereof, its composition comprises: naphthenic acid, described additive also comprises oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80, its ratio of weight and number is a naphthenic acid 39, oleic acid 15, carboxamide 5, trolamine 8, primary isoamyl alcohol or methyl alcohol 12, potassium permanganate 5, Arlacel-80 10, its complete processing is: press above-mentioned described parts by weight successively with naphthenic acid, oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80 is poured in the tempering tank, under 10 ℃ temperature, stirred 10 minutes, its temperature is risen to 50 ℃, static 30 minutes, filter barrelling.
Embodiment 2:
Emulsified orinoco crude oil property-modifying additive and complete processing thereof, its composition comprises: naphthenic acid, described additive also comprises oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80, its ratio of weight and number is a naphthenic acid 39, oleic acid 15, carboxamide 5, trolamine 15, primary isoamyl alcohol or methyl alcohol 20, potassium permanganate 5, Arlacel-80 15, its complete processing is: press above-mentioned described parts by weight successively with naphthenic acid, oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80 is poured in the tempering tank, under 30 ℃ temperature, stirred 10 minutes, its temperature is risen to 80 ℃, static 30 minutes, filter barrelling.
Embodiment 3:
Emulsified orinoco crude oil property-modifying additive and complete processing thereof, its composition comprises: naphthenic acid, described additive also comprises oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80, its ratio of weight and number is a naphthenic acid 39, oleic acid 15, carboxamide 5, trolamine 12, primary isoamyl alcohol or methyl alcohol 16, potassium permanganate 5, Arlacel-80 13, its complete processing is: press above-mentioned described parts by weight successively with naphthenic acid, oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80 is poured in the tempering tank, under 20 ℃ temperature, stirred 10 minutes, its temperature is risen to 70 ℃, static 30 minutes, filter barrelling.
Embodiment 4:
Emulsified orinoco crude oil modification marine fuel oil and complete processing thereof, the main raw material of described oil fuel comprises emulsified orinoco crude oil, 0 #Solar oil, oli oil property-modifying additive, its ratio of weight and number are emulsified orinoco crude oil 75.8,0 #Solar oil 22.7, oli oil property-modifying additive 1.5, its complete processing is: described emulsified orinoco crude oil filters earlier before entering synthesis reactor, fine filtering leaches the particle that diameter is 10 μ m again, smart more at last filter, pressure forced filtration by filter, making its particle diameter is 1 μ m, by above-mentioned described parts by weight each raw material is added in synthesis reactor, through high-speed shearing machine continuously stirring 10 minutes, promptly synthetic water-in-oil emulsified fuel, static depositing 30 minutes filtered barrelling.
Embodiment 5:
Emulsified orinoco crude oil modification marine fuel oil and complete processing thereof, the main raw material of described oil fuel comprises emulsified orinoco crude oil, 0 #Solar oil, oli oil property-modifying additive, its ratio of weight and number are emulsified orinoco crude oil 75.8,0 #Solar oil 22.7, oli oil property-modifying additive 1.5, its complete processing is: described emulsified orinoco crude oil filters earlier before entering synthesis reactor, fine filtering leaches the particle that diameter is 30 μ m again, smart more at last filter, pressure forced filtration by filter, making its particle diameter is 5 μ m, by above-mentioned described parts by weight each raw material is added in synthesis reactor, through high-speed shearing machine continuously stirring 10 minutes, promptly synthetic water-in-oil emulsified fuel, static depositing 30 minutes filtered barrelling.
Embodiment 6:
Emulsified orinoco crude oil modification marine fuel oil and complete processing thereof, the main raw material of described oil fuel comprises emulsified orinoco crude oil, 0 #Solar oil, oli oil property-modifying additive, its ratio of weight and number are emulsified orinoco crude oil 75.8,0 #Solar oil 22.7, oli oil property-modifying additive 1.5, its complete processing is: described emulsified orinoco crude oil filters earlier before entering synthesis reactor, fine filtering leaches the particle that diameter is 20 μ m again, smart more at last filter, pressure forced filtration by filter, making its particle diameter is 3 μ m, by above-mentioned described parts by weight each raw material is added in synthesis reactor, through high-speed shearing machine continuously stirring 10 minutes, promptly synthetic water-in-oil emulsified fuel, static depositing 30 minutes filtered barrelling.

Claims (4)

1. emulsified orinoco crude oil property-modifying additive, its composition comprises: naphthenic acid, it is characterized in that: described additive also comprises oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80, and its ratio of weight and number is naphthenic acid 39, oleic acid 15, carboxamide 5, trolamine 8~15, primary isoamyl alcohol or methyl alcohol 12~20, potassium permanganate 5, Arlacel-80 10~15.
2. the complete processing of the described emulsified orinoco crude oil property-modifying additive of claim 1, it is characterized in that: successively naphthenic acid, oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80 are poured in the tempering tank by above-mentioned described parts by weight, under 10 ℃~30 ℃ temperature, stirred 10 minutes, its temperature is risen between 50 ℃~80 ℃, static 30 minutes, filter.
3. the described emulsified orinoco crude oil of claim 1 is in the application of making on the modification marine fuel oil, and it is characterized in that: the main raw material of described oil fuel comprises emulsified orinoco crude oil, 0 #Solar oil, oli oil property-modifying additive, its ratio of weight and number are emulsified orinoco crude oil 75.8,0 #Solar oil 22.7, oli oil property-modifying additive 1.5.
4. the complete processing of the described emulsified orinoco crude oil modification of claim 3 marine fuel oil, it is characterized in that: described emulsified orinoco crude oil is before entering synthesis reactor, filter earlier, fine filtering again, leach diameter and be the particle between 10 μ m~30 μ m, smart more at last filter, pressure forced filtration by filter, make its particle diameter between 1 μ m~5 μ m, by above-mentioned described parts by weight each raw material is added in synthesis reactor, through high-speed shearing machine continuously stirring 10 minutes, promptly synthetic water-in-oil emulsified fuel, static depositing 30 minutes filtered.
CN 200410013731 2004-04-30 2004-04-30 Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same Pending CN1690177A (en)

Priority Applications (1)

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CN 200410013731 CN1690177A (en) 2004-04-30 2004-04-30 Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7854774B2 (en) 2006-05-26 2010-12-21 Amyris Biotechnologies, Inc. Fuel components, fuel compositions and methods of making and using same
CN101323802B (en) * 2008-07-25 2011-06-08 西安祺祥能源科技发展有限公司 Stable synergistic of methanol diesel for vehicle
US9200296B2 (en) 2006-05-26 2015-12-01 Amyris Inc. Production of isoprenoids

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7854774B2 (en) 2006-05-26 2010-12-21 Amyris Biotechnologies, Inc. Fuel components, fuel compositions and methods of making and using same
US9200296B2 (en) 2006-05-26 2015-12-01 Amyris Inc. Production of isoprenoids
US10106822B2 (en) 2006-05-26 2018-10-23 Amyris, Inc. Production of isoprenoids
CN101323802B (en) * 2008-07-25 2011-06-08 西安祺祥能源科技发展有限公司 Stable synergistic of methanol diesel for vehicle

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