CN1679508B

CN1679508B - Composition for use on skin, lip, nail and/or hair

Info

Publication number: CN1679508B
Application number: CN 200510063516
Authority: CN
Inventors: 克里斯托弗·迪穆索克斯
Original assignee: LOreal SA
Current assignee: LOreal SA
Priority date: 2004-04-08
Filing date: 2005-04-08
Publication date: 2010-04-14
Anticipated expiration: 2025-04-08
Also published as: CN1679508A; BRPI0501247A; BRPI0501247B1; FR2868694B1; ES2428359T3; FR2868694A1; JP5291500B2; JP2009120622A; EP1588687B1; EP1588687A1

Abstract

A composition for application to the skin, the lips, the nails, and/or hair is disclosed, wherein the composition comprises at least one first coloring agent in an amount sufficient to color the composition, comprising particles of at least one composite pigment, the particles comprising an inorganic core at least partially coated with at least one organic coloring substance, and at least one second coloring agent in an amount sufficient to produce a specific optical effect in the composition which is visibly perceptible to a human observer.

Description

Be used to be applied to the compositions of skin, lip, fingernail and/or hair

Technical field

The present invention relates to be used to be applied to skin, comprise mucosa particularly lip, fingernail or hair, particularly eyelashes, the make-up composition of eyebrow and hair.

Background technology

The preparation of compositions that comprises coloring agent is known, and this coloring agent can reflected light and/or the vision of modifying make-up composition.With this colorant combination, the organic or inorganic properties of combination thing pigment that mixes purified form is known, and this pigment has the shortcoming that reduces the compositions transparency, therefore can not enjoy the maximum benefit of the optical effect that is produced by described coloring agent.

Need have satisfied color and the make-up composition that comprises coloring agent, this coloring agent can produce fully visual particular optical effect.

Summary of the invention

The present invention has satisfied this needs.

The invention provides the compositions that is used to be applied to skin, lip, fingernail and/or hair, said composition comprises:

At least a first coloring agent presents in an amount at least sufficient to compositions dyeing, and this coloring agent comprises the granule of at least a composite pigment, and described granule comprises:

Inorganic core; With

At least the partial coating of at least a organic coloring substance; With

Said composition also comprises:

At least a second kind of coloring agent presents in an amount at least sufficient to produce the noticeable particular optical effect of naked eyes in compositions.

The particular optical effect can be the optical effect of flash effect, direction finding color (goniochromatic) effect, speckle effect or any other expectation.

For example, compare with ambient color, flash effect can draw in compositions and add bright spot.For example, can cause the described bright spot that adds by reflective particles.

The direction finding color effect is because viewing angle causes change color.

The speckle effect can produce has the compositions that presents the color speckle therein, and eyes can be observed this color speckle, for example, because thin slice or fiber produce described speckle.

By the inventive method, can obtain so a kind of compositions, said composition has color, and because the existence of first kind of coloring agent has macroscopic optical effect.

The first kind of coloring agent that exists in the compositions provides color, preserved needed transparency of compositions or translucence simultaneously, so the visible second kind of optical effect that coloring agent provided of naked eyes.

In the compositions weight range of first kind of coloring agent account for total composition weight about 0.1% to about 20% weight, perhaps account for total composition weight about 0.1% to about 10%, 0.5% to 5% weight for example.

In the exemplary embodiment, the amount of first kind of coloring agent can be less than the amount of second kind of coloring agent.

Preferably, composite pigment is not a coated interference pigment.

Organic coloring substance can be different from melanin.

For example, interfering dyestuff is such pigment, and this pigment comprises selected fixed thickness material layer stack to produce optical interference.The example of coated interference pigment is disclosed in US 6,428 773.

The saturation C* of composite pigment can be about more than 30, measures described saturation C* according to following method.

Measure the method for composite pigment saturation

As follows, measure colour a* and b* in the composite pigment CIE L*a*b* colour space.

By applying 100 bar pressures, the composite pigment in the previous status is compressed in 2 * 1.5cm yardstick, and in the rectangle cup of dark 3mm.

Under luminous body irradiation with median pore radius, discharge under the mode of direct reflection, utilize the a* and the b* value of Minolta 3700d spectrophotometer measurement compression pigment.Saturation computation is: C*=(a ^{* 2}+ b ^{* 2}) 1/2.

In the compositions weight range of second kind of coloring agent account for total composition weight about 0.1% to about 50% weight, perhaps account for total composition weight about 0.5% to about 40%, 1% to 20% weight for example.

Coloring agent is about 0.1 to about 50, perhaps about 0.5 to about 30, for example about 1 to about 10 with respect to the weight rate scope of first kind of coloring agent in second.

Can in all sorts of ways, for example by mixing composite pigment of the present invention and/or by having a large amount of organic coloring substances in composite pigment or the pigment core coating, obtain suitable tone, described pigment has different colors, described organic coloring substance mixed or be in coating each the layer in.

Used term among the present invention " partial coating at least " means all or part of of coating inorganic core.

Compositions of the present invention can comprise the physiology and go up acceptable medium.

Term " the last acceptable medium of physiology " means the nontoxic medium that can be applied on human skin, lip, fingernail or the hair.Physiology's acceptable medium will be suitable for will spread compositions surface nature, be suitable for the form that compositions will be packaged, particularly gentle solid of depressing of temperature or liquid form around.

Term " make-up composition " means defined compositions in the indication 93/35/EEC of committee on June 14th, 1993.

The composite pigment of first kind of coloring agent

Structure

The composite pigment of first kind of coloring agent of the present invention can comprise granule, and this granule comprises:

Inorganic core; With

At least the partial coating of at least a organic coloring substance.

At least a binding agent can advantageously be fixed to organic coloring substance on the inorganic core.

The granule of composite pigment can have different shapes, and especially, described granule can be flake shape or spherical shape, is spherical especially and can be for hollow or solid.Term " flake shape " is meant that full-size and thickness ratio are 5 or bigger granule.

Composite pigment of the present invention, for example, can have scope is 1m ²/ g (meters squared per gram) is to 1000m ²/ g is in particular about 10m ²/ g is to 600m ²/ g and especially for about 20m ²/ g is to 400m ²The specific surface area of/g.The numerical value of specific surface area for adopting BET (Brunauer-Emmett-Teller) method to measure.

The mass ratio of core can surpass 50% of composite pigment gross weight in the composite pigment, and for example scope is in 50% to 70% weight, for example 60% to 70% weight.

Compositions can only comprise one or more composite pigment of mentioned kind, or in version, the pigment that it can comprise one or more other composite pigments and have non-composite construction, coloring earth, color lake or organic pigment in particular.Especially, compositions can be the TiO of coating nothing but ₂Granule.

Composite pigment of the present invention is different from the second kind of coloring agent that is suitable for producing the particular optical effect in compositions.Therefore, composite pigment can be different from coated interference pigment.

Inorganic core

Inorganic core can have and is suitable for the fixedly particulate Any shape of organic coloring substance, for example is spherical, spherical, graininess, polyhedron, needle-like, spindle, the combination of the lamella shape of flattening, grain of rice shape or flakey and these shapes.Above-mentioned be listed as nonrestrictive.

Preferably, core full-size and its minimum dimension ratio ranges are 1 to 50.

Inorganic core can have scope from about 1nm (nanometer) to 100nm, or from about 5nm to about 75nm, mean size for example from about 10nm to about 50nm.

Term " mean size " is meant 50% when overall, the size that the particle size distribution curve of statistics provides, and term is D50.The draw size can be the digital averaging value of measuring according to graphical analysis (ultramicroscope).

Inorganic core can form by being selected from the following non-limiting material of listing: metallic salt and metal-oxide are the oxide of titanium, zirconium, cerium, zinc, ferrum, ferrum orchid, aluminum and chromium especially, Alumina, glass, pottery, graphite, Silicon stone, silicate, particularly aluminosilicate and borosilicate, synthetic mica, and their mixture.

Titanyl compound is titanium dioxide especially, and the oxide of ferrum is Fe especially ₂O ₃, the oxide of cerium, zinc and aluminum, Silicon stone and silicate especially aluminosilicate and borosilicate are particularly suitable.

Inorganic core can have the specific surface area that adopts the BET method to measure, and this specific surface area scope is from about 1m ²/ g is to about 1000m ²/ g is preferably from about 10m ²/ g is to about 600m ²/ g is for example from about 20m ²/ g is to 400m ²/ g.

In the time of suitably, inorganic core can dye.

Organic coloring substance

For example, organic coloring substance can contain at least a organic pigment and/or at least a organic color lake.

For example, organic coloring substance can be selected from and can accept insoluble specific compound in the medium on the compositions physiology.

For example, organic coloring substance can comprise pigment or the organic color lake that is selected from following compounds and its mixture:

Alkermes;

The organic pigment of azo, anthraquinone, indigo, xanthene, pyrene, quinoline, tritan., or fluoran dyes;

The insoluble salt of organic color lake or sodium, potassium, calcium, barium, aluminum, zirconium, strontium, titanium, or acid stain such as azo, anthraquinone, indigo, xanthene, pyrene, quinoline, tritan., or the insoluble salt of difluoride dye, these dyestuffs can contain at least one carboxyl or sulfonic group.

The organic pigment that can mention comprises the pigment with following name: D﹠amp; C blue No.4, D﹠amp; The brown No.1 of C, D﹠amp; The green No.5 of C, D﹠amp; The green No.6 of C, D﹠amp; C orange No.4, D﹠amp; C orange No.5, D﹠amp; C orange No.10, D﹠amp; C orange No.11, D﹠amp; The red No.6 of C, D﹠amp; The red No.7 of C, D﹠amp; The red No.17 of C, D﹠amp; The red No.21 of C, D﹠amp; The red No.22 of C, D﹠amp; The red No.27 of C, D﹠amp; The red No.28 of C, D﹠amp; The red No.30 of C, D﹠amp; The red No.31 of C, D﹠amp; The red No.33 of C, D﹠amp; The red No.34 of C, D﹠amp; The red No.36 of C, D﹠amp; C purple No.2, D﹠amp; C yellow No.7, D﹠amp; C yellow No.8, D﹠amp; C yellow No.10, D﹠amp; C yellow No.11, FD﹠amp; C blue No.1, FD﹠amp; The green No.3 of C, FD﹠amp; The red No.40 of C, FD﹠amp; C yellow No.5, FD﹠amp; The yellow No.6 of C.

For example, organic coloring substance can comprise the organic color lake by the organic carrier carrying, organic carrier such as Colophonium (colophane) or aluminum benzoate.

The special organic color lake that can mention comprises the organic color lake with following name: D﹠amp; The red No.2 aluminum of C color lake, D﹠amp; The red No.3 aluminum of C color lake, D﹠amp; The red No.4 aluminum of C color lake, D﹠amp; The red No.6 aluminum of C color lake, D﹠amp; The red No.6 barium of C color lake, D﹠amp; The red No.6 barium of C/strontium color lake, D﹠amp; The red No.6 strontium of C color lake, D﹠amp; The red No.6 potassium of C color lake, D﹠amp; The red No.7 aluminum of C color lake, D﹠amp; The red No.7 barium of C color lake, D﹠amp; The red No.7 calcium of C color lake,, D﹠amp; The red No.7 calcium of C/strontium color lake,, D﹠amp; The red No.7 zirconium of C color lake, D﹠amp; The red No.8 sodium of C color lake, D﹠amp; The red No.9 aluminum of C color lake, D﹠amp; The red No.9 barium of C color lake, D﹠amp; The red No.9 barium of C/strontium color lake, D﹠amp; The red No.9 zirconium of C color lake, D﹠amp; The red No.10 sodium of C color lake, D﹠amp; The red No.19 aluminum of C color lake, D﹠amp; The red No.19 barium of C color lake, D﹠amp; The red No.19 zirconium of C color lake, D﹠amp; The red No.21 aluminum of C color lake, D﹠amp; The red No.21 zirconium of C color lake, D﹠amp; The red No.22 aluminum of C color lake, D﹠amp; The red No.27 aluminum of C color lake, D﹠amp; The red No.27 aluminum/titanium of C/zirconium color lake, D﹠amp; The red No.27 barium of C color lake, D﹠amp; The red No.27 calcium of C color lake, D﹠amp; The red No.27 zirconium of C color lake, D﹠amp; The red No.28 aluminum of C color lake, D﹠amp; The red No.30 of C color lake, D﹠amp; The red No.31 calcium of C color lake, D﹠amp; The red No.33 aluminum of C color lake, D﹠amp; The red No.34 calcium of C color lake, D﹠amp; The red No.36 of C color lake, D﹠amp; The red No.40 aluminum of C color lake, D﹠amp; The blue No.1 aluminum of C color lake, D﹠amp; The green No.3 aluminum of C color lake, D﹠amp; C orange No.4 aluminum color lake, D﹠amp; C orange No.5 aluminum color lake, D﹠amp; C orange No.5 zirconium color lake, D﹠amp; C orange No.10 aluminum color lake, D﹠amp; C orange No.17 barium color lake, D﹠amp; The yellow No.5 aluminum of C color lake, D﹠amp; The yellow No.5 zirconium of C color lake, D﹠amp; The yellow No.6 aluminum of C color lake, D﹠amp; The yellow No.7 zirconium of C color lake, D﹠amp; The yellow No.10 aluminum of C color lake, FD﹠amp; The blue No.1 aluminum of C color lake, FD﹠amp; The red No.4 aluminum of C color lake, FD﹠amp; The red No.40 aluminum of C color lake, FD﹠amp; The yellow No.5 aluminum of C color lake, FD﹠amp; The yellow No.6 aluminum of C color lake.

With the above-mentioned listed corresponding chemical compound of each organic coloring substance is to mention in 371 pages to 386 pages and 524 pages to 528 pages in the works of " international cosmetic ingredients dictionary and handbook; 1997 editions (International Cosmetic Ingredient Dictionaryand Handbook) " at the title of being published by " cosmetics, cosmetics apparatus and fragrance association (The Cosmetic; Toiletry; and Fragrance Association) ", its content is incorporated as list of references here.

The weight ratio scope of organic coloring substance can be per 100 parts of weight inorganic cores about 10 to about 500 weight portions, or about 20 to about 250 weight portions, for example, per 100 parts of weight inorganic cores about 40 are to about 125 weight portions.

The ratio of organic coloring substance can surpass 30% of composite pigment gross weight in the composite pigment, and for example scope is 30% to 50%, and for example 30% to 40%.

Binding agent

Binding agent can be an any kind, as long as it allows organic coloring substance to adhere to the surface of inorganic core.

Especially, binding agent can be selected from the following non-limiting tabulation of listing: silicone compounds, polymerization, oligomeric or similar compounds, be selected from the organosilicon alkanes of organosilicon alkanes, fluoro-alkylization and polysiloxane-based especially, polymethyl hydrogen siloxane for example, and various coupling agents, as coupling agent based on silane, titanate, aluminate, zirconates, and their mixture.

Silicone compounds can be selected from following nonrestrictive listing:

The organosilicon alkanes (1) that from alkoxy silane, obtains;

Be selected from following non-limiting listing, alternatively polysiloxane-based (2) of modification:

Modified polyorganosiloxane class (2A), it comprises at least a free radical (hereinafter referred to as " modified polyorganosiloxane ") that is selected from polyethers, polyester and epoxide especially;

Polysiloxane-based (2B) is selected from following non-limiting listing being arranged in to have on the silicon atom of its polymer end: at least one group of carboxylic acids, alcohols and hydroxyl; With

The organic silane compound of fluoro-alkylization (3), it obtains from the fluoroalkyl silanes apoplexy due to endogenous wind.Organic silane compound (1) can obtain from the alkoxysilane compound containing trialkylsilyl group in molecular structure with molecular formula (I) expression.

R ¹ _aSiX _4-a(I)

In the formula:

-R ¹Represent C ₆H ₅-, (CH ₃) ₂CH-CH ₂-or C _bH _2b+1The free radical of-type (wherein the scope of b is 1 to 18);

-X represents CH ₃O-or C ₂H ₅O-; With

-a scope is 0 to 3.

The object lesson of alkoxysilane compound containing trialkylsilyl group in molecular structure can comprise the alkoxyl silicone alkanes, it is selected from MTES, dimethyldiethoxysilane, phenyl triethoxysilane, the diphenyl diethoxy silane, MTMS, dimethyldimethoxysil,ne, phenyltrimethoxysila,e, dimethoxydiphenylsilane, the isobutyl group trimethoxy silane, decyl trimethoxy silane or the like, be selected from MTES especially, phenyl triethoxysilane, MTMS, dimethyldimethoxysil,ne, the isobutyl group trimethoxy silane more preferably is selected from MTES, MTMS and phenyl triethoxysilane.

Especially, polysiloxane-based (2) can have structural formula (II):

R wherein ²Represent H-or CH ₃-, and the d scope is 15 to 450.

Preferred R ²Represent the polysiloxanes of H.

Especially, modified polyorganosiloxane class (2A) can have following structural formula (III):

-(a ¹) be with the modified polyorganosiloxane class of polyethers to represent with structural formula (III):

R wherein ³Representative-(CH ₂) _h-; R ⁴Representative-(CH ₂) _i-CH ₃R ⁵Representative-OH ,-COOH ,-CH=CH ₂,-C (CH ₃)=CH ₂Or-(CH ₂) _j-CH ₃R ⁶Representative-(CH ₂) _k-CH ₃G and h scope separately are 1 to 15; J and k scope separately are 0 to 15; The e scope be 1 to 50 and the f scope be 1 to 300;

-(a ²) be with the modified polyorganosiloxane class of polyester to represent with structural formula (IV):

R wherein ⁷, R ⁸And R ⁹Representative-(CH respectively ₂) _q-; R ¹⁰Representative-OH ,-COOH ,-CH=CH ₂,-C (CH ₃)=CH ₂Or-(CH ₂) _r-CH ₃R ¹¹Representative-(CH ₂) _s-CH ₃N and q scope respectively are 1 to 15, and r and s scope respectively are 0 to 15; The e scope be 1 to 50 and the f scope be 1 to 300;

-(a ³) the modified polyorganosiloxane class of band oxygen-derived free radicals represents with the structure formula V:

R wherein ¹²Representative-(CH ₂) _v-; The v scope is 1 to 15; The t scope be 1 to 50 and the u scope be 1 to 300; Or their mixture.

Preferred modified polyorganosiloxane (2A) is the modified polyorganosiloxane with band polyethers of structural formula (III).

Can have structural formula (VI) at whole terminal-modified polysiloxanes (2B):

R wherein ¹³And R ¹⁴Can represent independently of each other separately-OH, R ¹⁶-OH or R ¹⁷-COOH; R ¹⁵Representative-CH ₃Or-C ₆H ₅R ¹⁶And R ¹⁷Representative-(CH ₂) _y-; The y scope is 1 to 15; The w scope is l to 200; With the x scope be 0 to 100.

Comprise at least one terminal-modified preferred polysiloxanes and to have at least one free radical (R ¹⁶And R ¹⁷) polysiloxanes, this free radical has hydroxy-acid group at least one terminal silicon atom.

The organic silane compound of fluoro-alkylization (3) can be obtained by the fluoroalkyl silanes class of molecular formula (VII) expression:

CF ₃(CF ₂) _zCH ₂CH ₂(R ¹⁸) _aSiX _4-a (VII)

Wherein:

-R ¹⁸Represent CH ₃-, C ₂H ₅-, CH ₃O-or C ₂H ₅O-;

-X represents CH ₃O-or C ₂H ₅O-;

-z scope is 0 moving 15, and a scope is 0 to 3.

Especially, the fluoroalkyl silanes class can be selected from following non-limiting listing: three fluoro propyl trimethoxy silicanes, 13 fluoro octyl group trimethoxy silanes, 17 fluoro decyl trimethoxy silanes, 17 fluoro decyl methyl dimethoxysilanes, three fluoro propyl-triethoxysilicanes, 13 fluoro octyl group triethoxy-silicanes, 17 fluoro decyl triethoxysilanes, 17 fluoro decyl methyldiethoxysilane or the like, be three fluoro propyl trimethoxy silicanes especially, 13 fluoro octyl group trimethoxy silanes and 17 fluoro decyl trimethoxy silanes and more preferably be three fluoro propyl trimethoxy silicanes and 13 fluoro octyl group trimethoxy silanes.

Coupling agent based on silane can be selected from following non-limiting listing: vinyltrimethoxy silane, VTES, gamma-amino propyl group-triethoxysilane, γ-(+)-2,3-Epoxy-1-propanol oxygen propyl trimethoxy silicane, γ-Qiu Jibingjisanjiayangjiguiwan, γ-methacryloxypropyl trimethoxy silane, N-β (aminoethyl)-gamma-amino propyl trimethoxy silicane, γ-(+)-2,3-Epoxy-1-propanol oxygen propyl group methyl dimethoxysilane, γ-r-chloropropyl trimethoxyl silicon etc.

Coupling agent based on titanate can be selected from following: isopropyl stearyl titanate esters, isopropyl three (dioctyl ester pyrophosphoric acid) titanate esters, isopropyl three (N-aminoethyl-aminoethyl) titanate esters, two (phosphoric acid double tridecyl ester) titanate esters, four (2,2-two aryloxy group methyl-1-butyl) two (double tridecyl) titanium phosphate acid esters of four octyl groups, two (dioctyl pyrophosphate) metatitanic acid fluoroacetic acid ester, two (dioctyl pyrophosphate) metatitanic acid vinyl acetate or the like.

Coupling agent based on aluminate can be selected from diisopropanol acetyl aluminum alkoxide, diisopropoxy single acetyl ethyl acetate aluminum, tri ethylacetoacetate aluminum, praseodynium aluminum or the like.

Coupling agent based on zirconates can be selected from following: tetrem acyl acetone zirconium, dibutoxy bis-acetylacetonate zirconium, four ethyl acetoacetate zirconiums, three butoxy single acetyl ethyl acetate zirconiums, three butoxy acetylacetone,2,4-pentanedione zirconiums or the like.

It is 300 to 100000 molal weight that the chemical compound that uses as binding agent can have scope.

In order evenly to spread upon the coating on the inorganic core in acquisition, preferably, binding agent is liquid, perhaps at water soluble or other solvent.

The weight range of binding agent accounts for 0.01% to 15% of the particle weight that comprises core and binding agent, is 0.02% to 12.5% especially and more particularly is 0.03% to 10% (calculating with regard to C or Si).Can in patent application EP1184426 A2, find about the calculating of binding agent relative quantity in more detail.

The amount of binding agent can less than the composite pigment gross weight 5% or less than 3%.

The composite pigment preparation

Can make composite pigment with any suitable method, described method be the method for for example mechanochemistry or in solution sedimentary method, simultaneously core surfaces dissolving organic coloring substance and precipitation they.

Can use or not use binding agent.

Method preferably is the method that comprises mechanical mixture organic pigment and inorganic core.Before introducing organic coloring substance, can add binding agent, and mix with inorganic core.

For example, can utilize a kind of method in the method described in European patent application EP 1184426 and the EP1217046, and advantageously produce composite pigment with the method described in the EP1184426, the content of described patent application is incorporated as list of references.

In one embodiment, the granule that is intended for forming inorganic core at first mixes with binding agent.

Thereby binding agent can adhere on the surface of inorganic core equably, preferably, earlier described granule is made the granule depolymerization by mill when beginning.

Select to mix and stirring condition, make core scribble binding agent equably.Controlled condition make the linear load scope be 19.6N/cm (newton/centimetre) to 19160N/cm, especially for 98N/cm to 14170N/cm with more preferably arrive 980N/cm for 147N/cm; Processing time is 5 minutes to 24 hours, more preferably is 10 minutes to 20 hours; The range of speeds can arrive 1000rpm for 2rpm (revolutions per minute), and more preferably arrives 1000rpm and more preferably arrive 800rpm for 10rpm for 5rpm.

After with binding agent coating inorganic core, add organic coloring substance, and mix, it is adhered on the adhesive phase.

The example of adding method is a large amount of or a small amount of continuous charging.

No matter be inorganic core and the mixing and stirring of binding agent, or the mixing and stirring of organic coloring substance and the inorganic core that scribbles binding agent, can carry out by use device that this device adopts strong shear and/or pressure makes powder mixes.The example of this type device is cylinder mixer, blade paddle mixer or the like.Cylinder mixer is particularly suitable.In EP1184426 A2, listed the device that is fit to.

Described the other method of preparation composite pigment in Japan Patent JP3286463, it discloses a kind of method of solution precipitation.

Organic coloring substance is dissolved in ethanol, then inorganic core is scattered in the described alcoholic solution.

Aqueous based solution with sodium carbonate or potassium carbonate joins in this mixture lentamente then, slowly adds the ethanol calcium chloride solution at last again, continues in these processes to stir.

Second kind of coloring agent

Second kind of coloring agent can produce the particular optical effect in compositions.

Therefore, second kind of coloring agent especially can comprise reflection grain, Concha Margaritifera agent (or " Concha Margaritifera ") and/or direction finding color (goniochromatic) coloring agent.

In any case second kind of coloring agent can comprise the granule that has lamella shape or can be spherical shape

Second kind of coloring agent can have multiwalled structure.

In this case, second kind of coloring agent can comprise substrate, and this substrate comprises metal, metal-oxide or polymer at least, and listed herein is nonrestrictive.

Second kind of coloring agent can comprise Muscovitum, synthetic mica, Talcum, Silicon stone or Alumina at least.

Second kind of coloring agent can comprise the granule of granule based on glass, surface metalation or comprise metallic particle, and this metal is selected from aluminum, bronze, copper and their alloy.

Reflection grain

The term of Cai Yonging " reflection grain " is meant granule within the scope of the present invention, and its size and structure are especially formed particulate one or more layers thickness and its physics and chemical property and its apparent condition and allowed granule reflection incident illumination.In the time of suitably, described reflection has enough intensity and add bright spot to produce on present composition surface, and when compositions being applied on the surface that will make up, this bright spot that adds is that naked eyes are visual, that is to say that these points compare brighter with its surrounding and appear to luminous.

In the time of suitably, when moving by make up surface and observer, adding bright spot can occur or disappearance with random fashion, prevents to pin observer's eyes, and reflection grain can cover the vision of the surperficial curvature of making up wittingly like this.

Can also select reflection grain, make it can not change the coloring effect of uniting first kind of coloring agent generation of use with it significantly, perhaps even according to the generation of color optimize this effect.More particularly, they can have the flash of light of yellow, pink, redness, bronze colour, orange, brown and/or coppery.

Employed reflection grain must be consistent with cosmetic use, and it must be present in the last acceptable medium of physiology; Especially, they needn't be dissolved in wherein, or they needn't fully be dissolved in wherein in any case.

Described solid particle can be a different shape.Especially, described granule can be a lamella shape, maybe can be spherical, and is spherical in particular.

Granule with flat substantially outer surface also is fit to, because if their size, structure and apparent condition allow reflex time, they are easy to generate intensive direct reflection.Common " mirror effect " said that Here it is.

For this granule, basically, it equals the angle of incident illumination and normal at the reflected light of a direction and the angle of reflecting surface normal, and does not have the scattered light from each other direction, thereby allows described granule to occur as highlight point.

The expectation reflection grain is not diffusion and lacklustre.

Wish that also reflection grain can not change the color of make-up composition basically.

In this respect, it is particularly suitable allowing the reflection grain of incident illumination metallic reflection.At all events plant shape when reflection grain and all allow in layer of metal, for example silver is gone up reflex time, just this situation particularly.

As for the color of compositions, described granule relatively presents neutrality.

For example, being suitable for that the scope of the invention uses and have the reflection grain of metal or white flash can catoptrical visual field all the components, absorbs one or more wavelength not obviously.The spectral reflectivity of described reflection grain for example, arrives the 700nm scope greater than 70% at 400nm, is preferably at least 80%, or even 90% or 95%.

When glistening for metal, the light that is reflected by reflection grain needs not to be irised especially.

Irrelevant with their shape, reflection grain has multiple structure alternatively; In the situation of multiple structure, for example, it can have one deck homogeneous thickness at least, particularly one deck reflecting material at least.

When reflection grain does not have multiple structure, for example, they can comprise metal-oxide, for example, by the synthetic titanium that obtains or the oxide of ferrum, thereby granule has flat substantially surface, this surface has and is not unglazed, for example, do not have the apparent condition of diffusion, allow enough specular light reflections in make-up composition, to obtain to add bright spot.

When reflection grain had multiple structure, for example, they can comprise natural or synthetic substrate, particularly use one deck reflecting material at least, and especially at least a metal or metallic compound be the synthetic substrate of partial coating at least.It can be homogenous material or multiple material that substrate can be, organic and/or inorganic, solid or hollow.

No matter which kind of shape reflection grain is, when its when being synthetic, produce substrate with a kind of like this shape, this shape particularly deposits the formation of one deck reflecting material rear reflective surface after promoting coating.As an example, substrate can have plane surface, and layer of reflective material can have the thickness of basic homogeneous.

More particularly, substrate can be selected from glass, pottery, graphite, metal-oxide, Alumina, Silicon stone, silicate particularly aluminosilicate and borosilicate, Talcum, Muscovitum, synthetic mica, metal and above-mentioned mixture, and these are enumerated as nonrestrictive.

Reflecting material can comprise layer of metal or layer of metal chemical compound.

Metal level or metal compound layer can fully apply substrate alternatively, and metal level can be scribbled other material of one deck, for example material transparent at least in part.More preferably, metal or metal compound layer directly or indirectly coat substrate fully, coat indirectly and just insert at least one intermediate layer, and alternatively, this intermediate layer can be a metal.

For instance, metal can be selected from Ag, Au, Cu, Al, Ni, Sn, Mg, Cr, Mo, Ti, Pt, Va, Rb, W, Zn, Ge, Te and Se, and their mixture.Preferred metal is Ag, Au, Al, Zn, Ni, Mo, Cr and Cu, and their alloy (for example bronze and pyrite).

For example, scribble at matrix granule under the situation of silver or gold, the metal level weight of existence can account for 0.1% to 50% of total particle weight, or is 1% to 20%.

Described the glass particle that scribbles metal level in Japanese documentation JP-A-09188830, JP-A-10158450, JP-A-10158541, JP-A-07258460 and JP-A-05017710, its content is incorporated as list of references.

Can mention, other example that comprises the reflection grain of the mineral substrate that scribbles metal level is the granule that comprises the borosilicate substrate that scribbles silver, its be otherwise known as " venezuelan mother (white nacres) ".

The lamella shape of selling with trade name MICROGLASS METASHINE REFSX 2025 PS as TOYAL scribbles silver-colored glass matrix granule.As TOYAL company with trade name CRYSTAL STAR GF 550, the glass matrix granule that scribbles nickel/chromium/molybdenum alloy that GF2525 sells.As the spherical glass matrix granule thing that alternatively scribble metal of PRIZMALITE INDUSTRIES with trade name PRIZMALITE MICROSPHERE sale.

The lamella shape of selling with trade name VISIONAIRE with ECKART of selling with trade name STARBRITE as SILBERLINE such as aluminum, copper and bronze metal matrix granule.

The reflection grain of Any shape also can be selected from the synthetic substrate granule, and this matrix granule scribbles one deck at least a metallic compound, particularly metal-oxide at least at least in part, for example is selected from titanyl compound, particularly TiO ₂, ferrum oxide Fe particularly ₂O ₃, the oxide of stannum, the oxide of chromium, barium sulfate, and following compounds: MgF ₂, CrF ₃, ZnS, ZnSe, SiO ₂, Al ₂O ₃, MgO, Y ₂O ₃, SeO ₃, SiO, HfO ₂, ZrO ₂, CeO ₂, Nb ₂O ₅, Ta ₂O ₅, MoS ₂, and their mixture or alloy.

This particulate example that can mention is: comprise the granule of synthetic mica substrate, scribble titanium dioxide on the synthetic mica; Or scribble in brown iron oxide, titanium oxide, the stannum oxide glass particle of any or a kind of their mixture, for example by ENGELHARD with trade name The glass particle of selling.

The METASHINE 1080R serial pigment that NIPPON SHEET GLASS CO.LTD sells also is suitable.Described pigment, the pigment described in Japan Patent JP2001-11340 is to comprise to scribble one deck rutile-type titanium dioxide attitude (TiO in particular ₂) 65% to 72%SiO ₂The C-GLASS glass flake.Described glass particle has 1 micron (μ m) and average thickness is 80 μ m mean sizes, and the mean size that provides/average thickness ratio is 80.According to TiO ₂The difference of layer thickness, they have blueness, green, yellow or silver color flash of light.

The granule that can also mention is that NIHON KOKEN sells with trade name PROMINENCE, and having size range is the granules of 80 μ m to 100 μ m, and it comprises synthetic mica (fluorophologopite) substrate, scribbles the titanium dioxide that accounts for total particle weight 12% on the substrate.

Reflection grain can also be selected from the granule that has the two-layer at least formation of different refractivity by stack.

Described layer can be polymer or metal in nature, and they comprise one layer of polymeric at least especially.

Reflection grain can be the granule that derives from multi-layer polymer film.

In international and United States Patent (USP) WO99/36477, US6299979 and US6387498, this granule is described especially.

The non-limiting example material that can constitute different layers in the multiple structure is following mentioning: polyethylene naphthalenedicarboxylate (polyethylene naphthalate) (PEN) and its isomers, for example 2,6-, 1,4-, 1,5-, 2,7-and 2,3-PEN, the polyalkylene terephthalate, polyimides, Polyetherimide, random polystyrene, Merlon, polyisobutylene acid esters and alkyl polyacrylate, syndiotactic polytyrene (sPS), between advise poly alpha methylstyrene, between advise polydichlorstyrene, the copolymer of above-mentioned polystyrene and mixture, cellulose derivative, the polyalkylene fluidized polymer, fluorinated polymer, chlorinated polymeric, polysulfones, polyether sulfone, polyacrylonitrile, polyamide, silicone resin, epoxy resin, polyvinyl acetate, polyethers amide, ionomer resin, elastomer and polyurethane.Copolymer also is fit to, as the PEN copolymer, and for example 2,6-, 1,4-, 1,5-, 2,7-and/or 2,3-naphthalenedicarboxylic acid copolymer or its esters and following copolymer (a) terephthalic acids or its esters; (b) isophthalic acid or its esters; (c) phthalic acid or its esters; (d) alkyl glycol; (e) cycloalkane ethylene glycol (for example cyclohexanedimethanol dihydroxylic alcohols); (f) alkane dicarboxylic acids; And/or (g) cycloalkane dicarboxylic acids, the copolymer of polyalkylene terephthalate, and styrol copolymer.In addition, each independent layer can comprise the mixture of two or more above-mentioned polymer or copolymer.

Clearly select to constitute the material of different layers in the multiple structure, on formed granule, to obtain desired reflection appearance.

3M sells with trade name MIRROR GLITTER and comprises the laminated reflection grain of two layers of polymers at least.Described granule comprises 2 of 80/20 weight ratio, and 6-PEN layer and polyisobutylene acid esters layer have been described this granule among the US-A-5825643.

Concha Margaritifera

Second kind of coloring agent can comprise Concha Margaritifera.

Term " Concha Margaritifera " is meant the coloured particle of Any shape, and it can be iridescent colors alternatively, and as output in some Mollusca shell, perhaps it can be synthetic, and it demonstrates " as the Concha Margaritifera " coloring effect by the interference of light.

Concha Margaritifera can be selected from Concha Margaritifera pigment, as scribbles the odenite of ferrum oxide, scribbles the Muscovitum of chlorine oxygen bismuth, scribbles the odenite of chromium oxide, scribbles the odenite of the above-mentioned type toner and based on the Concha Margaritifera pigment of chlorine oxygen bismuth.They can also be mica particles, the metal-oxide and/or the organic coloring substance of stack at least two pantostrats on mica surface.

The example of the Concha Margaritifera that can mention is the natural mica that scribbles titanium oxide, ferrum oxide, natural pigment or bismuth oxychloride.

The suitable commercial available Concha Margaritifera that can mention is: sell (based on micaceous) Concha Margaritifera TIMICA, FLAMENCO and DUOCHROME by ENGELHARD, MERCK sells the TIMIRON Concha Margaritifera, the SUNSHINE that the PRESTIGE that ECKART sells sells based on micaceous Concha Margaritifera and SUN CHEMICAL is based on the Concha Margaritifera of synthetic mica.

More particularly, Concha Margaritifera can have yellow, pink, redness, bronze colour, orange, brown, gold and/or aeneous color or flash of light.

The Concha Margaritifera example that is suitable for scope of the invention use and can mentions is golden Concha Margaritifera, particularly the golden Concha Margaritifera of being sold with trade name Brillant gold 212G (Timica), Gold 222C (Cloisonne), Sparklegold (Timica), Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne) by ENGELHARD; Bronze Concha Margaritifera, particularly by MERCK with trade name Bronze fine (17384) (Colorona) and Bronze (17353) (Colorona) sell and by the bronze Concha Margaritifera of ENGELHARD with trade name Super bronze (Cloisonne) sale; Orange Concha Margaritifera, the orange Concha Margaritifera of particularly selling with trade name Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and (Microna) selling with trade name Passion orange (Colorona) and Matte orange (17449) by MERCK by ENGELHARD; By the Concha Margaritifera of ENGELHARD with the brown color of trade name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite) sale; The Concha Margaritifera that ENGELHARD sells with trade name Copper 340A (Timica) with coppery flash of light; Concha Margaritifera with red flash of light, particularly the Concha Margaritifera of (Colorona) selling with trade name Sienna fine (17386) by MERCK with red flash of light; Concha Margaritifera with yellow flash, especially the Concha Margaritifera of (Chromalite) selling with trade name Yellow (4502) by ENGELHARD with yellow flash; Red Concha Margaritifera with golden flash of light, especially the red Concha Margaritifera of selling with trade name Sunstone G012 (Gemtone) by ENGELHARD with golden flash of light; Pink Concha Margaritifera, the especially pink Concha Margaritifera of selling with trade name Tan opale G005 (Gemtone) by ENGELHARD; Black Concha Margaritifera with golden flash of light, especially the black Concha Margaritifera of selling with trade name Nu antique bronze240AB (Timica) by ENGELHARD with golden flash of light; Blue Concha Margaritifera, the especially blue Concha Margaritifera of (Microna) selling with trade name Matte blue (17433) by MERCK; White pearl mother with silver color flash of light, especially the white pearl mother who sells with trade name Xirona Silver by MERCK with silver color flash of light; With orange-pink, green-golden highlight Concha Margaritifera and their mixture sold with trade name Indian summer (Xirona) by MERCK.

Direction finding colour coloring agent (Goniochromatic coloring agents)

Second kind of coloring agent can comprise the agent of at least a direction finding colour coloring, thereby when compositions being applied to its surperficial going up, it produces coloured substrate, and the color of substrate changes with viewing angle.Direction finding colour coloring agent in the present invention allows the color that observes to change with the variation of viewing angle, be called " color triggers (colorflop) " again, and the change color that observes is greater than the variation of Concha Margaritifera.Be simple and easy enforcement, can use independent direction finding colour coloring agent.

Thereby can select the agent of direction finding colour coloring to make its variation demonstrate big relatively change color with viewing angle.

Therefore, can select the agent of direction finding colour coloring, like this under 45 ° of irradiations, change for 0 ° of viewing angle to 80 ° of scopes, the make-up composition color amount of change Δ E that observes is 2 at least, wherein as 1976 CIE (International Commission on Illumination) than measuring this amount of change Δ E in the colour space.

Also can select the agent of direction finding colour coloring, like this under 45 ° of irradiations, for 0 ° of variation to 80 ° of scope viewing angles, the make-up composition hue angle amount of change Δ h that can observe in CIE 1976 planes is at least 30 °, or at least 40 °, or at least 60, or at least 100 °.

The agent of direction finding colour coloring for example can be selected from multi-coated interference structure and liquid crystal coloring agent.

For example, multiple structure can comprise two-layer at least, by at least a each layer that following material production is independent of or is different from other layer: the MgF that is selected from ₂, CeF ₃, ZnS, ZnSe, Si, SiO ₂, Ge, Te, Fe ₂O ₃, Pt, Va, Al ₂O ₃, MgO, Y ₂O ₃, S ₂O ₃, SiO, HfO ₂, ZrO ₂, CeO ₂, Nb ₂O ₅, Ta ₂O ₅, TiO ₂, Ag, Al, Au, Cu, Rb, Ti, Ta, W, Zn, MoS ₂, cryolite, alloy, polymer and their combinations.

Aspect the chemical property of accumulation horizon, alternatively, multiple structure can be symmetrical in the intermediate layer.

It is as follows to be suitable for the symmetrical multi-coated interference example of structure used in the compositions that the present invention produces: Al/SiO ₂/ Al/SiO ₂/ Al, the pigment that DUPONT DE NEMOURS sells with this structure; Cr/MgF ₂/ Al/MgF ₂/ Cr, the pigment that FLEX sells with trade name CHROMAFLAIR with this structure; MoS ₂/ SiO ₂/ Al/SiO ₂/ MoS ₂Fe ₂O ₃/ SiO ₂/ Al/SiO ₂/ Fe ₂O ₃And Fe ₂O ₃/ SiO ₂/ Fe ₂O ₃/ SiO ₂/ Fe ₂O ₃, the pigment that BASF sells with trade name SICOPEARL with these structures; MoS ₂/ SiO ₂/ Muscovitum-oxide/SiO ₂/ MoS ₂Fe ₂O ₃/ SiO ₂/ Muscovitum-oxide/SiO ₂/ Fe ₂O ₃TiO ₂/ SiO ₂/ TiO ₂And TiO ₂/ Al ₂O ₃/ TiO ₂, SnO/TiO ₂/ SiO ₂/ TiO ₂/ SnO; Fe ₂O ₃/ SiO ₂/ Fe ₂O ₃The SnO/ Muscovitum-/TiO ₂/ SiO ₂/ TiO ₂/ Muscovitum/SnO, the pigment that MERCK (Darmstadt) sells with trade name XIRONA with these structures.

The pigment that the example of described pigment has MERCK to sell with trade name XIRONA MAGIC with Silicon stone/titanium oxide/stannum oxide structure; The pigment of brown Silicon stone/ferrum oxide structure that MERCK sells with trade name XIRONA INDIAN SUMMER and the pigment that MERCK sells with trade name XIRONA CARRIBEAN BLUE with Silicon stone/titanium oxide/Muscovitum/stannum oxide structure.That also can mention has " INFINITE COLORS " pigment that comes from SHISEIDO.Thickness and character according to different layers can obtain different effects.Therefore, structure Fe ₂O ₃/ SiO ₂/ Al/SiO ₂/ Fe ₂O ₃, work as SiO ₂When the thickness of layer changes to 350nm by 320nm, become ash-redness by green-gold; Work as SiO ₂When the thickness of layer changes to 400nm by 380nm, become gold by redness; Work as SiO ₂When the thickness of layer changes to 420nm by 410nm, become green by purple; With work as SiO ₂When the thickness of layer changes to 440nm by 430nm, become redness by the seed coppery.

Can also use the direction finding colour coloring agent with multiple structure, this multiple structure comprises alternative polymeric layer, for example, and polyethylene naphthalenedicarboxylate and polyethylene terephthalate type.Described preparation had been described in WO-A-96/19347 and WO-A-99/36478.

The pigment example with polymer multi-layer structure that can mention is the pigment of being sold with commodity COLOR GLITTER by 3M.

For example, the liquid crystal coloring agent silicone or the cellulose ethers of mesomorphic group that comprised on it grafting.

The example of the liquid crystal direction finding color particle that is fit to sell by CHENIX and by WACKER with trade name

The liquid crystal direction finding color particle of selling.

Compositions can also comprise dispersive direction finding color fiber.For example, can to have scope be that 50 μ m are to 700 μ m, the size of for example about 300 μ m to described fiber.

Especially, can use interference fibers with multiple structure.In EP-A-0 921 217, EP-A-0 686 858 and US-A-5 472 798, the fiber with polymer multi-layer structure has been described.Multiple structure can comprise two-layer at least, can be independent of or be different from each layer of other layer from least a synthesized polymer deposits yields.The polymer that exists in the fiber can have 1.30 to 1.82, preferably 1.35 to 1.75 refractive index.The preferred polymers that is used for fiber is polyester such as polyethylene terephthalate, polyethylene naphthalenedicarboxylate ester, Merlon; Acrylate copolymer is the polyisobutylene acid esters for example; With polyamide-based.

The direction finding color fiber that TEIJIN sells with trade name MORPHOTEX with double-layer polyethylene terephthalate/nylon-6 structure.

Other composition

Solvent

Compositions can comprise at least a water or organic solvent.

When compositions comprised one or more organic solvents, the amount that described solvent exists can account for 0.1% to 99% of composition total weight.

Usually, the amount of solvent, especially organic solvent will depend on the character that compositions will be smeared the surface.

For example, under the nial polish situation, the weight of organic solvent can account for 30% to 99% of composition total weight in the compositions, and preferably 60% to 90%.

Compositions can comprise and is selected from following at least a organic solvent:

At room temperature be the ketone of liquid, for example butanone, methylisobutylketone, diisobutyl ketone, isophorone, Ketohexamethylene or acetone;

At room temperature be the alcohols of liquid, for example ethanol, isopropyl alcohol, diacetone alcohol, butoxy ethanol or Hexalin;

At room temperature be the di-alcohols of liquid, for example ethylene glycol, propylene glycol, pentanediol or glycerol;

At room temperature be the propylene glycol ethers of liquid, for example propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate or dipropylene glycol monobutyl ether;

Short chain esters (containing 3 to 8 carbon atoms altogether), for example ethyl acetate, methyl acetate, propyl acetate, butyl acetate or isoamyl acetate; With

At room temperature be the hydro carbons of liquid, for example decane, heptane, dodecane or cyclohexane extraction.

Compositions can also comprise the mixture of water or water and hydrophilic organic solvent, hydrophilic organic solvent is normally used in cosmetics, alcohols for example contains the low-grade monobasic alcohol class of the straight or branched of 2 to 5 carbon atoms, for example ethanol, isopropyl alcohol or normal propyl alcohol especially; Polyalcohols is glycerol, diglycerol, propylene glycol, sorbitol, pentanediol or Polyethylene Glycol for example.Compositions can also comprise hydrophilic C ₂Ethers and C ₂-C ₄Aldehydes.

The mixture of water or water and hydrophilic organic solvent can account for 0% to 90% weight of composition total weight in the compositions, and be 0.1% to 90% weight especially and be preferably 0% to 60% weight, be 0.1% to 60% weight best.

Oil phase

Especially, when compositions is used to be applied on the lip, compositions can contain oil phase and especially in room temperature (25 ℃) down at least a fat of liquid and/or at room temperature be solid fat, for example wax class, paste fat, natural gum and their mixture.Oil phase also can contain lipophilic organic solvent.

For example, compositions can have oil-continuous phase, and this oil phase contains less than its gross weight 5%, especially less than the water of its gross weight 1% with it can be an anhydrous form especially.

At room temperature be commonly called " oil " for the fat of liquid, that can mention has: the hydrocarbon that contains vegetable oil, the liquid fatty acid triglycerin esters that for example contains 4 to 10 carbon atoms, for example enanthic acid or sad triglyceride, or Oleum helianthi, Semen Maydis oil, soybean oil, Oleum Vitis viniferae, Oleum sesami, almond oil, macadimia nut oil, Semen Ricini or American Avocado Tree oil, caprylic/capric triglycerin esters, Jojoba oil, shea nut Adeps Bovis seu Bubali, lanoline, acetylated lanolin; Straight or branched hydro carbons with mineral or synthetic source, for example petrolatum and its derivant, vaseline, the poly decene class, Parleam is Parleam for example; Synthetic esters or ethers are fatty acid especially, Purcellin oil for example, isopropyl myristate, Palmic acid 2-ethyl hexyl ester, stearic acid 2-octyl group dodecyl fat, sinapic acid 2-octyl group dodecyl ester, isostearic acid iso stearyl ester; The hydroxylating esters, as the different stearyl ester of lactic acid, octyl group hydroxy stearic acid ester, octyl group dodecyl hydroxy stearic acid ester, two iso stearyl malates, three different palmityl citrates, the heptanoate of aliphatic alcohol, caprylate or decanoin; Isononyl isononanoate, isopropyl lanolate, trimellilate tridecyl ester, two iso stearyl malates; The polyhydric alcohol esters, as the propylene glycol dicaprylate, neopentyl ethylene glycol bisthioglycolate heptanoate, diethylene glycol two different pelargonates; And pentaerythritol ester; The aliphatic alcohol that contains 12 to 26 carbon atoms is as octyl dodecanol, 2-butyl capryl alcohol, 2-hexyldecanol, 2-undecyl pentadecanol or oleyl alcohol; The fluorinated oil of part hydrocarbonylation and/or siliconization; The volatility of liquid state or pasty state or non-volatile, straight chain or annular polymethyl siloxane (PDMS) under silicone oil such as the room temperature, as Cyclomethicone or dimethicone, comprise phenyl alternatively, as phenyl trimethyl silicone oil, phenyl trimethylsiloxy diphenyl siloxane, diphenyl methyl dimethyl trisiloxanes, the diphenyl dimethicone, phenyl dimethicone, PSI; And their mixture.Weight of oil can account for 0.01% to 90% of composition total weight, is preferably 0.1% to 85%.

Paste fat is generally the chemical compound of hydrocarbonaceous, its melting range is 25 ℃ to 60 ℃, is preferably 30 ℃ to 45 ℃, and/or has the hardness range of 0.001MPa (MPa) to 0.5MPa, preferably 0.005Mpa is to the 0.4Mpa hardness range, for example lanoline and its derivant.

The wax class can be solid under room temperature (25 ℃), and has reversible solid-liquid state-transition, and fusing point is greater than 30 ℃, and up to 200 ℃, hardness has the aeolotropic crystal structure greater than 0.5MPa under solid-state.Especially, wax can have greater than 25 ℃, is preferably more than 45 ℃ fusing point.Wax can be hydrocarbonaceous, fluorizated and/or silication, and can be animal, mineral, plant and/or synthetic source.The suitable wax class that can mention has Cera Flava, Brazil wax or candelilla wax, paraffin, microwax, ceresin or ceresine; Synthetic wax as Tissuemat E or Fischer-Tropsch wax or siloxane wax, as contains the alkyl of 16 to 45 carbon atoms-or alkoxyl dimethicone.Compositions can contain cured with respect to composition total weight 0% to 50% weight or the wax of 1% to 30% weight.

The normally high-molecular weight polydimethylsiloxane of natural gum (PDMS) or cellulose gum or the polysaccharide that are fit to.

Film forming polymer

For example, compositions can also comprise the film forming polymer that is used for mascara or nial polish especially.Term " film forming polymer " is meant a kind of energy self ground or has the polymer that forms continuous film under the situation at film former that this film adheres to the surface, especially on the keratin material.

Operable film forming polymer comprises the synthetic polymer of free radical type or condensation polymer type in the compositions of the present invention that can mention, natural polymer, for example nitrocellulose or cellulose esters and their mixture.

Especially, the film forming polymer of free radical type can be polyvinyl or copolymer, especially acrylate copolymer.

The vinyl film forming polymer can be formed by the esters of the monomer with ethylenic unsaturated bond that contains at least one acidic group and/or these acid monomers and/or the amide-type polymerization of these acid monomers, for example these monomers can be α, β-ethylenically unsaturated carboxylic acids class such as acrylic acid, methacrylate .beta.-methylacrylic acid, maleic acid or itaconic acid.

The vinyl film forming polymer can also be made by the monomer that is selected from vinyl esters and styrene monomer homopolymerization and copolymerization, for example, the vinyl esters monomer can be vinyl acetate base ester, neodecanoic acid vinyl esters, neopentanoic acid vinyl esters, benzoic acid vinyl esters and p t butylbenzoic acid vinyl esters; Styrene monomer can give an example styrene and α-Jia Jibenyixi.

The film forming condensation polymer limiting examples that can mention comprises polyurethane class, polyester, polyester amide class, polyamide-based and polyureas.

The polymer of natural origin that alternatively can modification can be selected from lac resin, gummy sandarac, Dammar, Canarium luzonicum Elemi, Resin copal, cellulosic polymer class such as nitrocellulose, ethyl cellulose, perhaps the nitrocellulose ester for example is selected from cellulose acetate, cellulose acetobutyrateate and acetyl cellulose propionate and their mixture.

Film forming polymer can adopt the form of solid particle to be present in water or the oil dispersion, is commonly called latex or false latex.Film forming polymer can comprise one or more stable dispersions that the physiology goes up the common spherical polymer particles of one or more polymer in the acceptable liquid oil phase.Compare with the latex of aqueous polymerization thing dispersion, described dispersion is commonly called polymer NADs (nonaqueous phase dispersion).Described dispersion can be the form of nanoparticles of polymer in the stabilising dispersions in the described oil phase.Preferably, the nano-particle magnitude range is that 5nm is to 600nm.The technology for preparing described dispersion is well-known to those skilled in the art.

Operable water film forming polymer dispersion is acrylic acid dispersion or water polyurethane dispersion.Acrylic acid dispersion such as AVECIA-NEORESINS company are with trade name NEOCRYL

NEOCRYL NEOCRYL

NEOCRYL

NEOCRYL

And NEOCRYL

Product sold, the DOW LATEX of DOW CHEMICAL company

The DAITOSOL 5000 of commodity and DAITO KASEY KOGYO company Product; Polyurethane aqueous dispersion body such as AVECIA-NEORESINS company with trade name NEOREZ And NEOREZ Product sold, GOODRICH company is with title AVALURE AVALURE

AVALURE AVALURE

SANCURE SANCURE

SANCURE

And SANCURE

Product sold, the IMPRANIL of BAYER company

The AQUAMERE of HYDROMER company

Can also comprise that sulfo-polyesters such as Eastman Chemical Products company are with trade name Eastman Product sold.

Can also comprise coalescents in the compositions of the present invention, it can promote the formation of film forming polymer film.

Filler

Compositions can also comprise filler.Term " filler " is meant any type of granule, and it all is insoluble in the compositions medium regardless of the temperature of preparation of compositions.It is rheology or the structure of revising compositions that described filler mainly acts on.The character of solid matter and quantity become with needed mechanical performance and structure.

The filler example that can mention comprises the powder of Talcum, Muscovitum, Silicon stone, Kaolin and sericite and polyamide, polyethylene, politef, polymethyl methacrylate or polyurethane, powdered starch and silicones pearl.

Other coloring material

Compositions can also comprise the other coloring material that is different from composite pigment used herein.

Other coloring material can be selected from coloring earth, organic pigment and fat-soluble or water-soluble colorant.

Coloring earth can be white or colored, and alternatively coating can be arranged.That can mention is as follows: can be by surface-treated titanium dioxide; The oxide of zirconium or cerium; The oxide of ferrum or chromium; Manganese violet; The group is blue; Chromic oxide gel; And barba hispanica.Pigment weight can account for 0% to 40% of composition total weight, is preferably 1% to 35% and more preferably be 2% to 25%.

That can mention in the organic pigment has white carbon black, a D﹠amp; The pigment of C type and based on the color lake of carmine, barium, strontium, calcium or aluminum.

The example of fat-soluble coloring agent is: tonyred, green No. 6 of red No. 17 of DC, DC, beta-carotene, soybean oil, brown, the D﹠amp of the Sudan; C yellow No. 11, D﹠amp; C purple No. 2, D﹠amp; C orange No. 5, D C Yellow No. 10.

The example of water-soluble colorant has beet root juice and methylene blue.

Coloring agent (if there is) weight can account for 0.1% to 20% of composition weight, is preferably 0.1% to 6%.

Other component

Compositions can comprise at least a cosmetic or Dermatology active component.The cosmetic, Dermatology, hygiology or the pharmacologic activity component of using in the compositions of the present invention that can mention that are fit to has wetting agent (polyalcohols such as glycerol), vitamin (C, A, E, F, B or PP), essential fatty acid class, essential oils, ceramide type, sphingolipid, fat-soluble or the opacifier of nano-particle and specific skin treatment active component (protective agent, antibacterial, anti-wrinkle agent etc.).For example, the operable amount of described active component is 0% to 20% of a compositions gross weight, is 0.001% to 15% especially.

Make-up composition can also be included in the normal component of using in the cosmetics, for example thickening agent, surfactant, trace element, wetting agent, softening agent, interleaving agent, spice, alkalization or acidulant, antiseptic, antioxidant, ultraviolet filtering agent, coloring agent, or their mixture.

According to contemplated application, the present composition can comprise this area and consider the composition that uses usually, and its quantity is suitable for desired dosage or " galenic " form.

The galenic form

According to its purpose, compositions can have various forms.Therefore, compositions can be any galenic form that normally is used for partial smearing, anhydrous form particularly, oil or aqueous solution form, oil or form of hydrogels, O/w emulsion form, water-in-oil emulsion form, water bag wax or wax bag aqueous emulsion form, multiple emulsion form or owing to be positioned at the oil in water dispersion of the bubble formation on the oil-water interfaces.

Compositions can be cast article, particularly bar-shaped in lip pomade or lip care product situation.

Compositions can also be various other forms, for example has higher or more low viscous liquid, gel or ointment.

Compositions can also be a solid form, for example, allows the rod of its decomposition thereby get wet in use.

Cosmetic composition can constitute cosmetic composition, foundation cream, concealer or the informer's product, eyeliner, mascara, nial polish, eye shadow, health or hair cosmetic product or the sunscreen product that comprise lipstick, liquid coloured silk, lip pomade, kermes, lip gloss, solid or liquid, or dye product.

The present invention also provides the lip pomade that comprises above-mentioned definitions section compound, and it can be a liquid or solid.

The present invention also provides the foundation cream that comprises above-mentioned definitions section compound.

The present invention also provides the nial polish that comprises above-mentioned definitions section compound.

The present invention also provides the mascara that comprises above-mentioned definitions section compound.

The present invention also provides and has comprised above-mentioned definitions section compound and be used for the hair fiber pigmented product.

The present invention also provides the method for cosmetic skin, lip, fingernail or hair, and this method comprises above-mentioned definitions section compound is applied on skin, lip or the hair.

Embodiment

By example, preparation has the cosmetic composition that comprises first kind and second kind coloring agent of following prescription, and described compositions adopts conventional cosmetics preparation method to make.

Embodiment 1,2 and Comparative Examples 1: lip pomade

Embodiment 1:

Preparation has the lip pomade (amount that % represents is the weight that accounts for composition total weight) of the following present composition:

Tissuemat E 10

Elefac I 205 47.1

Hydrogenated polybutene 20

Phenyl trimethylsiloxy trisiloxanes 15

The direction finding color pigments

(SICOPEARL?Fantastico?Green(BASF)) 5.5

Silicon stone/D﹠amp; The red No.7 of C ¹Composite pigment 2.4

¹Composite pigment is that 15nm and specific surface area are 200m by the mean size that has of per 100 parts of weight ²The organosilicon lithophysa heart of/g and the D﹠amp of 50 parts of weight; C Red No.7 forms, and the employing polymethyl hydrogen siloxane is a binding agent.

Embodiment 2:

Tissuemat E 10

Elefac I 205 47.1

Hydrogenated polybutene 20

Phenyl trimethylsiloxy trisiloxanes 15

The direction finding color pigments

(SICOPEARL?Fantastico?Green(BASF)) 5.5

TiO ₂/ D﹠amp; The red No.7 of C ²Composite pigment 2.4

²Composite pigment is that 20nm and specific surface area are 50m by the mean size that has of per 100 parts of weight ²The inorganic titanium dioxide of/g and the D﹠amp of 50 parts of weight; The red No.7 of C forms, and the employing polymethyl hydrogen siloxane is a binding agent.

Comparative Examples 1:

The lip pomade that preparation has following compositions, wherein compositions is not compositions of the present invention (amount that % represents is the weight that accounts for composition total weight) owing to do not contain composite pigment:

Tissuemat E 10

Elefac I 205 48.7

Hydrogenated polybutene 20

Phenyl trimethylsiloxy trisiloxanes 15

The direction finding color pigments

(SICOPEARL?Fantastico?Green(BASF)) 5.5

D﹠amp; The red No.7 of C ³Organic pigment 0.8

³The called after D﹠amp of organic pigment; The red No.7 of C.

Adopt automatic distributor that the lip pomade of embodiment 1,2 and Comparative Examples 1 is deposited on the black background of the type 24/5ERICSEN contrast card that comprises black background and white background, deposit thickness is 100 μ m.

Adopt NIPPON DENSHOKU KOGYO GC-5000 spectrum direction finding color instrument (spectrogoniocolorimeter) then, at incident angle is 45 ° and view angle when being 0 ° to 70 °, and reflection measurement is in the color path of 1976CIE than colour space a*b* plane each sample of kind.

Compare with 2 with embodiment 1, Comparative Examples 1 does not show the green composition of pigment and has " color triggering " effect of minimizing.

Embodiment 3: liquid foundation

Utilize following preparation of compositions liquid foundation of the present invention (amount that % represents is the weight that accounts for composition total weight):

Simethicone polyol 5

Simethicone 4

Cyclomethicone 15

Fancol ID 10

Bentonite gel 10

Nylon powder 2

PMMA powder 2

Iron oxide yellow 4

TiO ₂/ D﹠amp; The red No.7 composite pigment 1 of C

Muscovitum/bismuth oxychloride/brown iron oxide ⁴Pigment 5

Water 31.2

Butanediol 10

Magnesium sulfate 0.8

Sell by ENGELHARD ⁴Chroma-Lite Brown

Embodiment 4: nial polish

With following preparation of compositions nial polish of the present invention: (amount that % represents is the weight that accounts for composition total weight):

Nitrocellulose 19

N-ethyl-o, p-toluenesulfonamide 6

Tributyl 2-acetylcitrate 6

Rheological agent (Strese Hofmann's hectorite .) 1.2

Silicon stone/D﹠amp; The red N of C ° of 7 composite pigments 3

Scribble the glass particle of silver ⁵6

Isopropyl alcohol 8

Ethyl acetate/butyl acetate qsp 100

Sell by TOYAL ⁵Metashine REFSX2040 PS.

Observe with the glass particle that is coated with silver and have relevant flash effect.

Significantly, the present invention is not restricted to the above-mentioned example that provides.

Unless otherwise indicated,, comprise in claims that statement " comprise/comprise a kind of/one " is interpreted as and " comprise/comprise an at least a/" synonym in whole description.

Unless additionally explanation, the scope of being given is interpreted as comprising their boundary value.

Claims

1. compositions that is used to be applied to skin, lip, fingernail and/or hair, said composition comprises:

At least a first kind of coloring agent, its weight range accounts for 0.1% to 20% of composition total weight, and this coloring agent comprises the granule of at least a non-interference composite pigment, and described granule comprises:

With at least a organic coloring substance inorganic core of partial coating at least; This inorganic core comprises at least a material that is selected from titanium dioxide and Silicon stone; This organic coloring substance comprises and is selected from following organic pigment: D﹠amp; C blue No.4, D﹠amp; The brown No.1 of C, D﹠amp; The green No.5 of C, D﹠amp; The green No.6 of C, D﹠amp; C orange No.4, D﹠amp; C orange No.5, D﹠amp; C orange No.10, D﹠amp; C orange No.11, D﹠amp; The red No.6 of C, D﹠amp; The red No.7 of C, D﹠amp; The red No.17 of C, D﹠amp; The red No.21 of C, D﹠amp; The red No.22 of C, D﹠amp; The red No.27 of C, D﹠amp; The red No.28 of C, D﹠amp; The red No.30 of C, D﹠amp; The red No.31 of C, D﹠amp; The red No.33 of C, D﹠amp; The red No.34 of C, D﹠amp; The red No.36 of C, D﹠amp; C purple No.2, D﹠amp; C yellow No.7, D﹠amp; C yellow No.8, D﹠amp; C yellow No.10, D﹠amp; C yellow No.11, FD﹠amp; C blue No.1, FD﹠amp; The green No.3 of C, FD﹠amp; The red No.40 of C, FD﹠amp; Yellow No.5 of C and FD﹠amp; The yellow No.6 of C;

With

At least a second kind of coloring agent, it comprises reflection grain, Concha Margaritifera and/or the agent of direction finding colour coloring, and its weight range accounts for 1% to 50% of composition total weight;

The weight rate scope of second kind of coloring agent and first kind of coloring agent is 0.1 to 50.

2. compositions according to claim 1 is characterized in that the weight range of first kind of coloring agent in the compositions accounts for 0.1% to 10% of composition total weight.

3. compositions according to claim 2 is characterized in that the weight range of first kind of coloring agent in the compositions accounts for 0.5% to 5% of composition total weight.

4. compositions according to claim 1 is characterized in that the weight range of second kind of coloring agent in the compositions accounts for 1% to 40% of composition total weight.

5. compositions according to claim 4 is characterized in that the weight range of second kind of coloring agent in the compositions accounts for 1% to 20% of composition total weight.

6. compositions according to claim 1, the weight rate scope that it is characterized in that second kind of coloring agent and first kind of coloring agent is 0.5 to 30.

7. compositions according to claim 6, the weight rate scope that it is characterized in that second kind of coloring agent and first kind of coloring agent is 1 to 10.

8. compositions according to claim 1, the mean size scope that it is characterized in that inorganic core is that 1nm is to 100nm.

9. compositions according to claim 8, the mean size scope that it is characterized in that inorganic core is that 5nm is to 75nm.

10. compositions according to claim 9, the mean size scope that it is characterized in that inorganic core is that 10nm is to 50nm.

11. compositions according to claim 1 is characterized in that the specific surface area scope of inorganic core is 1m ²/ g is to 1000m ²/ g.

12. want 10 described compositionss according to right, it is characterized in that the specific surface area scope of inorganic core is 10m ²/ g is to 600m ²/ g.

13. compositions according to claim 11 is characterized in that the specific surface area scope of inorganic core is 20m ²/ g is to 400m ²/ g.

14. compositions according to claim 1 is characterized in that the shape of inorganic core is selected from following: sphere, polyhedron, needle-like, spindle shape and flat.

15. compositions according to claim 1, the part by weight scope that it is characterized in that organic coloring substance are the organic coloring substances of 10 to 500 parts of weight of inorganic core correspondence of per 100 parts of weight.

16. compositions according to claim 15, the part by weight scope that it is characterized in that organic coloring substance are the organic coloring substances of 20 to 250 parts of weight of inorganic core correspondence of per 100 parts of weight.

17. compositions according to claim 16, the part by weight scope that it is characterized in that organic coloring substance are the organic coloring substances of 40 to 125 parts of weight of inorganic core correspondence of per 100 parts of weight.

18. compositions according to claim 1 is characterized in that composite pigment comprises at least a binding agent.

19. compositions according to claim 18, it is characterized in that at least a binding agent comprises at least a silicone compounds that is selected from, polymer compound, the chemical compound of oligomeric compound, this chemical compound comprises organosilan, polysiloxanes and the coupling agent of at least a organosilan, fluoro-alkyl organosilan.

20. compositions according to claim 19 is characterized in that at least a coupling agent is based at least a chemical compound that is selected from silane, titanate, aluminate and zirconates.

21. compositions according to claim 18, wherein this binding agent is organic.

22. compositions according to claim 19 is characterized in that binding agent comprises at least a silicone compounds.

23. compositions according to claim 22 is characterized in that binding agent comprises polymethyl hydrogen siloxane.

24. compositions according to claim 1 is characterized in that inorganic core is colored.

25. compositions according to claim 1 is characterized in that described compositions does not comprise the not titanium dioxide granule of coating.

26. compositions according to claim 1 is characterized in that at least a second kind of coloring agent comprises the granule of sheet form.

27. compositions according to claim 1 is characterized in that at least a second kind of coloring agent comprises the granule with balled form.

28. compositions according to claim 1 is characterized in that at least a second kind of coloring agent has multiwalled structure.

29. compositions according to claim 28 is characterized in that at least a second kind of coloring agent comprises substrate, this substrate is selected from least a in metal, metal-oxide and the polymer.

30. compositions according to claim 1 is characterized in that at least a second kind of coloring agent comprises Concha Margaritifera.

31. compositions according to claim 30 is characterized in that at least a second kind of coloring agent comprises at least a chemical compound that is selected from Muscovitum, synthetic mica, Talcum, Silicon stone and Alumina.

32. compositions according to claim 1 is characterized in that at least a second kind of coloring agent comprises the granule based on glass.

33. compositions according to claim 1 is characterized in that at least a second kind of coloring agent comprises the agent of at least a direction finding colour coloring.

34. compositions according to claim 1, wherein at least a second kind of coloring agent comprises the metallic particles that is selected from aluminum, bronze, copper and their alloys.

35. compositions according to claim 1 is characterized in that at least a second kind of coloring agent comprises reflection grain.

36. compositions according to claim 1 is characterized in that second kind of coloring agent comprises the granule of surface metalation.

37. compositions according to claim 1 is characterized in that second kind of coloring agent comprises granule, this granule comprises the metal that is selected from aluminum, bronze, copper and their alloys.

38. compositions according to claim 30 is characterized in that Concha Margaritifera has yellow, pink, redness, bronze colour, orange, brown, gold and/or aeneous color or flash of light.

39. compositions according to claim 35 is characterized in that reflection grain comprises the granule that contains natural or synthetic substrate, this substrate is coated with at least a metal of one deck or metallic compound at least at least in part.

40., it is characterized in that this substrate is selected from homogenous material substrate, many matrix of materials, organic substrate and inorganic matrix according to the described compositions of claim 39.

41., it is characterized in that this substrate is selected from glass, pottery, graphite, metal-oxide, Alumina, Silicon stone, silicate, Talcum, Muscovitum, synthetic mica, metal and their mixture according to the described compositions of claim 40

42., it is characterized in that this substrate is selected from aluminosilicate and borosilicate according to the described compositions of claim 41.

43., it is characterized in that metallic compound is selected from the oxide of titanium oxide, ferrum oxide, stannum or chromium, barium sulfate, and following compounds: MgF according to the described compositions of claim 39 ₂, CrF ₃, ZnS, ZnSe, SiO ₂, Al ₂O ₃, MgO, Y ₂O ₃, SeO ₃, SiO, HfO ₂, ZrO ₂, CeO ₂, Nb ₂O ₅, Ta ₂O ₅, MoS ₂, and their mixture or alloy.

44., it is characterized in that metallic compound is Fe according to the described compositions of claim 43 ₂O ₃

45. compositions according to claim 30 is characterized in that Concha Margaritifera is selected from golden Concha Margaritifera, bronze Concha Margaritifera, orange Concha Margaritifera, brownish Concha Margaritifera has the Concha Margaritifera that coppery is glistened, Concha Margaritifera with red flash of light, Concha Margaritifera with yellow flash has the golden red Concha Margaritifera that glistens, pink Concha Margaritifera, the black Concha Margaritifera of golden flash of light, blue Concha Margaritifera, orange-pink, green-golden Concha Margaritifera, and their mixture.

46. according to the described compositions of claim 39, it is characterized in that metal is selected from Ag, Au, Cu, Al, Zn, Ni, Mo, Cr and their mixture or alloy.

47. compositions according to claim 35 is characterized in that reflection grain comprises the stacking granule that forms that adds that has different refractivity by two-layer at least at least in part.

48., it is characterized in that having the two-layer at least of different refractivity is two layers of polymers according to the described compositions of claim 47.

49. compositions according to claim 33 is characterized in that the agent of at least a direction finding colour coloring is selected from liquid crystal coloring agent and multiwalled interference structure.

50. according to the described compositions of claim 49, it is characterized in that the agent of at least a direction finding colour coloring comprises the multi-coated interference structure, this multi-coated interference structure is selected from down array structure: Al/SiO ₂/ Al/SiO ₂/ Al; Cr/MgF ₂/ Al/MgF ₂/ Cr; MoS ₂/ SiO ₂/ Al/SiO ₂/ MoS ₂Fe ₂O ₃/ SiO ₂/ Al/SiO ₂/ Fe ₂O ₃Fe ₂O ₃/ SiO ₂/ Fe ₂O ₃/ SiO ₂/ Fe ₂O ₃MoS ₂/ SiO ₂/ Muscovitum-oxide/SiO ₂/ MoS ₂Fe ₂O ₃/ SiO ₂/ Muscovitum-oxide/SiO ₂/ Fe ₂O ₃TiO ₂/ SiO ₂/ TiO ₂TiO ₂/ Al ₂O ₃/ TiO ₂SnO/TiO ₂/ SiO ₂/ TiO ₂/ SnO; Fe ₂O ₃/ SiO ₂/ Fe ₂O ₃With SnO/ Muscovitum/TiO ₂/ SiO ₂/ TiO ₂/ Muscovitum/SnO..

51. compositions according to claim 1 is characterized in that it comprises the other coloring material that is different from least a composite pigment.

52., it is characterized in that other coloring material is selected from coloring earth, organic pigment, fat-soluble coloring agent and water-soluble colorant according to the described compositions of claim 51.

53. compositions according to claim 1 is characterized in that it contains at least a cosmetic or dermatologic active ingredient.

54. compositions according to claim 1 is characterized in that it contains at least a fat, wax, natural gum or film forming polymer.

55. compositions according to claim 1 is characterized in that it is a solid form.

56. compositions according to claim 1 is characterized in that it is liquid, paste or gel form.

57. compositions according to claim 1, wherein the saturation C* of composite pigment is greater than 30.

58. a compositions that is used to be applied to skin, lip, fingernail and/or hair, said composition comprises:

At least a first kind of coloring agent, its weight range accounts for 0.1% to 20% of composition total weight, and this coloring agent comprises the granule of at least a composite pigment, and described granule comprises: with at least a organic coloring substance inorganic core of partial coating at least; This inorganic core comprises at least a material that is selected from titanium dioxide and Silicon stone; This organic coloring substance comprises and is selected from following organic pigment: D﹠amp; C blue No.4, D﹠amp; The brown No.1 of C, D﹠amp; The green No.5 of C, D﹠amp; The green No.6 of C, D﹠amp; C orange No.4, D﹠amp; C orange No.5, D﹠amp; C orange No.10, D﹠amp; C orange No.11, D﹠amp; The red No.6 of C, D﹠amp; The red No.7 of C, D﹠amp; The red No.17 of C, D﹠amp; The red No.21 of C, D﹠amp; The red No.22 of C, D﹠amp; The red No.27 of C, D﹠amp; The red No.28 of C, D﹠amp; The red No.30 of C, D﹠amp; The red No.31 of C, D﹠amp; The red No.33 of C, D﹠amp; The red No.34 of C, D﹠amp; The red No.36 of C, D﹠amp; C purple No.2, D﹠amp; C yellow No.7, D﹠amp; C yellow No.8, D﹠amp; C yellow No.10, D﹠amp; C yellow No.11, FD﹠amp; C blue No.1, FD﹠amp; The green No.3 of C, FD﹠amp; The red No.40 of C, FD﹠amp; Yellow No.5 of C and FD﹠amp; The yellow No.6 of C; With

Wherein the mean size scope of inorganic core is that 1nm is to 100nm;

59. according to the described compositions of claim 58, wherein the mean size scope of inorganic core is that 10nm is to 50nm.

60. according to the described compositions of claim 59, wherein the BET specific surface area scope of inorganic core is 20m ²/ g is to 400m ²/ g.

61. according to the described compositions of claim 60, wherein inorganic core comprises titanium dioxide.

62. according to the described compositions of claim 58, wherein composite pigment comprises at least a binding agent.

63. according to the described compositions of claim 62, wherein at least a binding agent comprises at least a silicone compounds.

64. according to the described compositions of claim 62, wherein the part by weight of binding agent accounts for the gross weight of composite pigment less than 5%.

65. the method for a cosmetic skin, lip, fingernail or hair, this method comprise the described compositions of claim 1 is applied on skin, lip, fingernail or the hair.

66. a lip pomade, it comprises the described compositions of claim 1.

67. a foundation cream, it comprises the described compositions of claim 1.

68. a nial polish, it comprises the described compositions of claim 1.

69. a mascara, it comprises the described compositions of claim 1.

70. one is used for the product of pigmented hair fiber, described product comprises the described compositions of claim 1.