CN1675426A - Composition for improving wrinkle resistance in fabrics, wrinkle-reducing active ingredient as used in such a composition, and cartridge containing such composition - Google Patents
Composition for improving wrinkle resistance in fabrics, wrinkle-reducing active ingredient as used in such a composition, and cartridge containing such composition Download PDFInfo
- Publication number
- CN1675426A CN1675426A CNA038196441A CN03819644A CN1675426A CN 1675426 A CN1675426 A CN 1675426A CN A038196441 A CNA038196441 A CN A038196441A CN 03819644 A CN03819644 A CN 03819644A CN 1675426 A CN1675426 A CN 1675426A
- Authority
- CN
- China
- Prior art keywords
- composition
- fabric
- wrinkle
- active component
- filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F75/00—Hand irons
- D06F75/08—Hand irons internally heated by electricity
- D06F75/22—Hand irons internally heated by electricity with means for supplying liquid to the article being ironed
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F75/00—Hand irons
- D06F75/08—Hand irons internally heated by electricity
- D06F75/10—Hand irons internally heated by electricity with means for supplying steam to the article being ironed
- D06F75/14—Hand irons internally heated by electricity with means for supplying steam to the article being ironed the steam being produced from water in a reservoir carried by the iron
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/02—Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Irons (AREA)
Abstract
The invention relates to a composition to improve wrinkle resistance in fabrics, comprising: a wrinkle-reducing active ingredient, comprising at least one fusible elastomer and cross-linked particles, and a liquid carrier for carrying the active ingredient. The invention also relates to a wrinkle-reducing active ingredient as used in such a composition and a cartridge for an iron containing such a composition.
Description
The present invention relates to be used to improve the composition of wrinkle resistance in fabrics, it contains: subtract the wrinkle active component, it contains at least a fusible elastomer; With the liquid-carrier that is used to carry active component.The invention still further relates in this composition, use subtract the wrinkle active component.The invention still further relates to a kind of by using this composition to improve the method for wrinkle resistance in fabrics.
Wear the implication of wrinkle resistance (IWWR), represent the performance of given fabric for example cotton opposing formation fine wrinkle, particularly during wearing fabric as this title.IWWR can detect by the ability that detects given fabric opposing formation fine wrinkle.Wrinkle resistance is recovered angle (WRA) experiment by fine wrinkle usually and is estimated.A known standard test is AATCC method 66-1998.These experimental evaluations be set at open and flat attitude fabric be folded and carrying out short time load, preferred 500g reaches 60 seconds and discharges then to recover the ability of its flattened state.This evaluation by detect preset time (common 5 minutes) recovery angle (WRA) afterwards carry out.This angle is big more, and it is good more to recover.These angles all are to detect on warp-wise and broadwise, and add and lump together, evaluation result to the end.Elastomeric material will obtain 360 ° WRA completely.Cohesive material will obtain 0 ° WRA completely.
It is known being used to reduce the composition that the fabric fine wrinkle forms.U.S. Patent application US5532023 discloses for example a kind of can being administered to and has subtracted the wrinkle composition on the fabric.Said composition contains and subtracts the wrinkle active component, comprises the polysiloxanes of effective dose and the film forming polymer of effective dose, and wherein active component is dispersed in the liquid-carrier.Particularly, disclosed composition is applicable to the ability of giving greasy property or improving fiber slippage in fabric, the particularly clothing.This phorogenesis between the fiber is particularly caused by polysiloxanes.The distortion of clothing has reduced the resistance between the clothes fiber, this cause energy loss on the fiber to reduce usually and (consequent) fiber to the better and easier reversible deformation (recovery) of original state.But the resistance between the clothes fiber reduces the fold state that also will promote to form clothing.Be coated with disclosed composition to cloth and cause about 200 ° WRA at most usually.
The purpose of this invention is to provide a kind of new compositions, it has improved the wrinkle resistance of fabric, and can not promote to form the wrinkled state of fabric.
The objective of the invention is to realize at opening paragraph described composition that it is characterized in that subtracting the wrinkle active component and also contain filler, this filler to small part contains the particle of chemical crosslinking by a kind of.Being used in combination the filler that contains cross-linked particles will obtain to compare significantly higher fabric with the recovery of prior art usually with fusible elastomer and recover.Use and to obtain being significantly higher than 200 ° WRA according to composition of the present invention usually.Particularly, active component according to the present invention will form elastic bridge under normal operation between fabric fibre, makes the distortion of fabric cause the lasting recovery of fiber on its inceptive direction usually.Therefore, crosslinked particle provides at the elastic key that has between the fiber of certain memory with easy cladding polymer, and this makes fiber more easily to recover after crooked or folding.Preferably, crosslinked particle is trapped in the matrix of fusible elastomer.Operable cross-linked particles is for example crosslinked dimethyl silicone polymer of polybutadiene, natural rubber, cross linking polysiloxane for example, and polymer microfibers.The fusible elastomer of using for example can be aliphatic polyester polyurethane, aliphatic polyether polyurethane or have butyl acrylate and acrylic acid acrylate copolymer than reduced TG conversion temperature (Tg) that preferred proportion is 80: 20.The liquid-carrier that uses in the present composition is Aquo System preferably.Randomly, except water, carrier can also comprise another kind of liquid flux soluble in water, for example alcohol.
In a preferred embodiment of the invention, filler is made up of the particle of chemical crosslinking fully or at least mainly.Therefore the elastic performance of cross-linked particles can utilize best.For example can use dimethyl silicone polymer, Dow Corning C1716 for example, it is directly bonding with the matrix that forms by fusible elastomer.
In another preferred embodiment, filler contains the hot plastomer, preferred polymethyl methacrylate (PMMA).In this way, filler is made up of the particle that comprises two kinds of compositions especially at least, promptly provides flexible cross-linked composition to filler, and by the hot plastomer improve being used to of forming filler and the matrix that forms by fusible elastomer between bonding non-crosslinked composition.Filler according to this embodiment can make up in laminated mode, makes every layer to be made up of specific composition.Therefore, can also for example provide so-called " nuclear-shell " filler particles, it at least mainly is made up of the elastic kernel that described cross-linked composition forms, and the non-elastic shell basically that this nuclear is formed by described thermoplastic compounds is centered on.As the cross-linked composition that is used to examine, can use for example carboxylated microballoon of Estapor (Merck) of SBS copolymer.
Preferably, the particle of filler has the shape of substantially spherical at least.But in a preferred embodiment, the particle of filler has basic at least fibrous shape, for example fento.Other shape also can be used to obtain required anti-wrinkle effect.
Active component content in liquid-carrier is 2-60 weight %.Between these values, can obtain and keep the fine dispersion of active component in liquid medium.If it is described 60% that (obviously) surpasses, then obtain the out of contior dispersion that is clamminess usually.Preferably, the filer content in active component is 10-30 weight %, preferred 20 weight %.In this way, can obtain stable fusible elastomer matrix, in this matrix, catch crosslinked fillers.
In an embodiment according to composition of the present invention, elastomer has 50-100 ℃ softening temperature in the presence of water.The elastomeric easier softening yarn that causes acquisition easily to contain the fabric of the present composition usually under higher temperature.The viscosity of the composition that is softened is very low, and for example during the flatiron of described fiber, polymer can not disturb the smoothing wrinkle of fabric in this expression, as long as fabric is warm.When fabric cools down is got off, composition of the present invention be solidificated in around yarn or the single fiber and between form elastic membrane, thereby reduce the elasticity in the processed fabric.This so significantly improved the WRA value.
In another preferred embodiment of the present composition, active component can be removed by washing.If use the fusible elastomer that can remove by washing, then can wash whole active component off usually, comprise crosslinked filler.An example of the easy cladding polymer that can remove by washing is to be made up of butyl acrylate and acrylic acid copolymer substantially, and preferred proportion is 80: 20.But, it is also conceivable that and use more durable active component that it can or not be difficult to be washed off at least.The example of this durability active component is aliphatic polyester polyurethane (Permutex RU13-011) and aliphatic polyester polyurethane (Permutex RU-4049).
Composition of the present invention preferably contains additive, for example surfactant, spices, antibacterial additives, be used to improve the polysiloxanes of slipping property between the fabric fibre etc., as long as this additive can not disturb the major function of polymer.When for example washing machine or flatiron are with described compound administration on fabric the time by apparatus for household use, the use of additive is very useful in the present composition.
The invention still further relates in described composition, use subtract the wrinkle active component, and contain this composition and be applicable to cartridge in the flatiron.
The invention still further relates to a kind of method, may further comprise the steps by the described composition improvement of use wrinkle resistance in fabrics: A) described composition is administered on the fabric, B) removes the fold in the fabric, and C) liquid-carrier to small part is evaporated.Usually the amount of using, particularly spray to the active component on the fabric is the about 10 weight % of about 0.1-of fabric, the more preferably from about about 5 weight % of 0.5-preferably.After the composition of effective dose has been sprayed onto on the fabric, according to step B) stretch or open and flat fabric with pulling.Be administered on the fabric and after preferred the stretching, make liquid, particularly moisture at least significantly evaporate at the composition of effective dose.Evaporation can be undertaken by passive mode and the active mode that improves fabric temperature.The evaporation of moisture is normally suitable, because the particle of fusible elastomer will be sticked together and therefore form the sheath that solidifies around fiber and fabric yarn.In addition, the evaporation of moisture also will cause the stress relaxation in the fabric yarn usually.The reduction of energy storage will keep fiber to be in the state of its setting, promptly smooth state.
Preferably, according to steps A) operation that composition is administered on the fabric realizes by apparatus for household use.The example of this apparatus for household use is washing machine, has the flatiron of composition sprayed holder, and other are used for the flusher of the present composition.
In a preferred embodiment of the invention, according to step B) operation of removing fold in the fabric realizes by the flatiron that is under the high temperature that is higher than environment temperature.In this way, step C) will be usually at step B) during carry out.Therefore, the temperature of raising will cause the accelerated evaporation of used liquid and softening of fusible elastomer.The cooling of fabric causes forming the elastic protective layer usually around the fabric yarn that is stretched, and makes each layer bonded to each other by elastic bridge.After using the inventive method, the distortion of fabric will temporarily prolong described elastic bridge, and this attempts in special time yarn returned to its initial stretching, corrugationless state.
Further specify the present invention with non-limiting example and an accompanying drawing below, accompanying drawing has shown the flatiron with the cartridge that contains described composition.
Embodiment 1
Permutex RU-4049 40% aqueous emulsion and Estapor 10% latex (175-225nm core-shell particles, form by crosslinked elasticity Styrene Butadiene Copolymer nuclear and carboxylated shell) the 12.5 weight % dispersion liquids of mixture in water by with above-mentioned emulsion and water is mixed must, its ratio makes that the amount of Estapor is 10% (promptly 1: 9) with respect to Permutex RU-4049 , thereby is 1.25% with respect to the dispersion liquid gross weight.Then said composition is sprayed onto on a slice fabric (cotton type 407), the feasible amount of obtaining always (pick-up) with respect to the fabric weight meter is 40%.When fabric is when doing, this obtains 5% amount of obtaining of extra fabric weight.Become dry up to fabric with the flatiron flatiron fabric that is set to be suitable for cotton temperature then.After conditioning fabric 24 hours, detect a slice 40mm * WRA of 15mm fabric on warp-wise and broadwise according to standard A ATCC method 66-1998.Result's comparison of the WRA mean value that obtains from the fabric of above-mentioned processing and the fabric of flatiron after the WRA testing result (reference value) of not using the fabric that presses under any additives situation to carry out and the Permutex RU-4049 that only using 5% fabric weight.These results are summarised in the following table, and wherein PermutexRU-4049 is called RU-4049, and Estapor latex is called Estapor.
| Handle | WRA |
| Reference | 140° |
| 5％RU-4049 | 200° |
| 5％(RU-4049+Estapor?9∶1) | 210° |
Embodiment 2
Permutex RU-4049 40% aqueous emulsion and Dow Corning 1716 30% aqueous microemulsions (crosslinked PDMS, dimethyl silicone polymer) the 12.5 weight % dispersion liquids of mixture in water are by mixed with above-mentioned emulsion and water, its ratio makes that the amount of Dow Corning1716 is 20% (promptly 1: 4) with respect to Permutex RU-4049 , thereby is 2.5% with respect to the dispersion liquid gross weight.Then said composition is sprayed onto on a slice fabric (cotton type 407), the feasible amount of obtaining always with respect to the fabric weight meter is 40%.When fabric is when doing, this obtains 5% amount of obtaining of extra fabric weight.Become dry up to fabric with the flatiron flatiron fabric that is set to be suitable for cotton temperature then.After conditioning fabric 24 hours, detect a slice 40mm * WRA of 15mm fabric on warp-wise and broadwise according to standard A ATCC method 66-1998.Result's comparison of the WRA mean value that obtains from the fabric of above-mentioned processing and the fabric of flatiron after the WRA testing result (reference value) of not using the fabric that presses under any additives situation to carry out and the Permutex RU-4049 that only using 5% fabric weight.These results are summarised in the following table, and wherein Permutex RU-4049 is called RU-4049, and Dow Corning 1716 are called DC-1716.
| Handle | WRA |
| Reference | 140° |
| ?5％RU-4049 | 200° |
| ?5％(RU-4049+DC-1716?4∶1) | 225° |
Accompanying drawing has shown the flatiron with the replaceable holder that is used for splendid attire compositions of additives of the present invention.This flatiron comprises shell 1, base plate 2, be used for the heating element heater 3 of heatable soleplate, be used for the replaceable holder and the spray nozzle device 6 of splendid attire compositions of additives 5.Replaceable holder 4 can be a kind of cassette tape or cartridge, has the hard resin shell.The bottom 7 of replaceable holder 4 has the outlet 8 of composition 5.Connector 9 is connected the downside of bottom 7, and this connector has conduit 10, and its inlet is connected with the outlet 8 of holder 4, and its outlet stops at outlet 11 places.In first preferred embodiment, connector 9 can with the cartridge one.Flatiron comprises and is used for composition 5 is transferred to the induction system 12 of spray nozzle device 6 from replaceable holder 4, so that said composition is sprayed onto on the cloth that will press.This induction system comprises first passage 13, and its outlet is connected with electric pump 14 inlets that are arranged in the iron housing inboard; With second channel 15, its inlet is connected with the outlet of pump 14.The inlet of passage 13 has the branch sleeve 16 of the outlet 11 that is used to connect connector 9.The outlet of second channel 15 has branch sleeve 17.According to the present invention, replaceable holder 4 has spray nozzle device 6.This spray nozzle device comprises blast tube 18, and it terminates in the nozzle 19 with hole 20.Blast tube go into interruption-forming tube connector 21, be used to connect the branch sleeve 17 of second channel 15.Replaceable holder 4 can insert the cavity 22 of flatiron.Swivelling cover 23 can be closed cavity 22.When the needs spray composition, the user presses the button 24, opens pump 14.Pump from holder 4 suction passages 13, and is pumped into nozzle 19 via passage 15 and blast tube 18 with compositions of additives 5.The replaceable holder 4 that comprises spray nozzle device 6 can be used as disposable cassette and uses, and makes the spray nozzle device that each new cartridge has cleaning.
Claims (9)
1. be used to improve the composition of wrinkle resistance in fabrics, comprise:
-subtract the wrinkle active component, comprise at least a fusible elastomer and
-be used to carry the liquid-carrier of active component,
It is characterized in that subtracting the wrinkle active component and also comprise the filler that contains the chemical crosslinking particle to small part.
2. according to the composition of claim 1, it is characterized in that filler is made up of the chemical crosslinking particle fully.
3. according to the composition of claim 1, it is characterized in that filler contains the hot plastomer, preferred polymethyl methacrylate (PMMA).
4. according to the composition of one of aforementioned claim, it is characterized in that the content of active component in liquid-carrier is 2-60 weight %.
5. according to the composition of one of aforementioned claim, it is characterized in that the filer content in active component is 5-50 weight %, preferred 10-20 weight %.
6. according to the composition of one of aforementioned claim, it is characterized in that the softening temperature of elastomer in the presence of water is 50-150 ℃.
7. according to the composition of one of aforementioned claim, it is characterized in that said composition contains additive, preferred surfactant or spices.
8. that uses in each composition in according to claim 1-7 subtracts the wrinkle active component.
9. be designed for flatiron and comprise cartridge according to each composition among the claim 1-7.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02078460.9 | 2002-08-21 | ||
| EP02078460 | 2002-08-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1675426A true CN1675426A (en) | 2005-09-28 |
Family
ID=31896926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA038196441A Pending CN1675426A (en) | 2002-08-21 | 2003-08-05 | Composition for improving wrinkle resistance in fabrics, wrinkle-reducing active ingredient as used in such a composition, and cartridge containing such composition |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20060108560A1 (en) |
| EP (1) | EP1532308A1 (en) |
| JP (1) | JP2005536655A (en) |
| CN (1) | CN1675426A (en) |
| AU (1) | AU2003250406A1 (en) |
| WO (1) | WO2004018762A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0515057D0 (en) | 2005-07-22 | 2005-08-31 | Unilever Plc | Improvements relating to domestic laundering |
| JP2015130988A (en) * | 2014-01-14 | 2015-07-23 | 株式会社 ピヨ | Ironing auxiliary tool |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3096524A (en) * | 1961-04-11 | 1963-07-09 | Williamson Dickie Mfg Company | Process for improving crease-retention properties of cotton garments |
| US3434875A (en) * | 1964-06-29 | 1969-03-25 | Burlington Industries Inc | Textile fabric coated with a high molecular weight methylpolysiloxane elastomer polymer |
| CA1061961A (en) * | 1974-11-18 | 1979-09-11 | Strike Corporation (The) | Durable press process |
| US5532023A (en) * | 1994-11-10 | 1996-07-02 | The Procter & Gamble Company | Wrinkle reducing composition |
| US5885303A (en) * | 1997-05-13 | 1999-03-23 | American Laundry Machinery Incorporated | Durable press/wrinkle-free process |
| US6207782B1 (en) * | 1998-05-28 | 2001-03-27 | Cromption Corporation | Hydrophilic siloxane latex emulsions |
| FR2789311B1 (en) * | 1999-02-08 | 2003-09-26 | Oreal | USE OF PARTICLES OF A HYDROPHILIC ORGANOPOLYSILOXANE IN A WATER-RESISTANT MAKE-UP OR CARE COMPOSITION |
| EP1096056A1 (en) * | 1999-10-27 | 2001-05-02 | The Procter & Gamble Company | Wrinkle resistant composition |
| US6221979B1 (en) * | 1999-11-08 | 2001-04-24 | Dow Corning Corporation | Mixtures of silicone elastomers |
| GB9927903D0 (en) * | 1999-11-25 | 2000-01-26 | Unilever Plc | Textile material |
| US6660044B2 (en) * | 2000-03-31 | 2003-12-09 | Kao Corporation | Fiber product-treating agents |
| US7317053B1 (en) * | 2000-07-10 | 2008-01-08 | Hercules Incorporated | Compositions for imparting desired properties to materials |
| US6524598B2 (en) * | 2000-07-10 | 2003-02-25 | The Procter & Gamble Company | Cosmetic compositions |
| EP1201814A1 (en) * | 2000-10-27 | 2002-05-02 | The Procter & Gamble Company | Domestic treatment of fabrics with film-forming materials and blowing agents |
| US6616980B2 (en) * | 2001-04-24 | 2003-09-09 | Crompton Corporation | Emulsion polymerized acrylated silicone copolymer for wrinkle reduction |
-
2003
- 2003-08-05 AU AU2003250406A patent/AU2003250406A1/en not_active Abandoned
- 2003-08-05 CN CNA038196441A patent/CN1675426A/en active Pending
- 2003-08-05 EP EP03792552A patent/EP1532308A1/en not_active Withdrawn
- 2003-08-05 US US10/525,142 patent/US20060108560A1/en not_active Abandoned
- 2003-08-05 JP JP2004530432A patent/JP2005536655A/en not_active Withdrawn
- 2003-08-05 WO PCT/IB2003/003376 patent/WO2004018762A1/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003250406A1 (en) | 2004-03-11 |
| JP2005536655A (en) | 2005-12-02 |
| EP1532308A1 (en) | 2005-05-25 |
| WO2004018762A1 (en) | 2004-03-04 |
| US20060108560A1 (en) | 2006-05-25 |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |