JPH0610268A - Fiber treating agent composition and treated fiber - Google Patents
Fiber treating agent composition and treated fiberInfo
- Publication number
- JPH0610268A JPH0610268A JP5043329A JP4332993A JPH0610268A JP H0610268 A JPH0610268 A JP H0610268A JP 5043329 A JP5043329 A JP 5043329A JP 4332993 A JP4332993 A JP 4332993A JP H0610268 A JPH0610268 A JP H0610268A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- fine powder
- resin emulsion
- synthetic resin
- hydrophilic organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、繊維処理剤組成物に関
する。くわしくは、繊維そのものの通気性を損なわず、
繊維に吸放湿性と天然素材感を付与し、あるいはこれら
を向上させることができる繊維処理剤組成物に関する。FIELD OF THE INVENTION The present invention relates to a fiber treating composition. In detail, without impairing the breathability of the fiber itself,
The present invention relates to a fiber treatment composition capable of imparting moisture absorbing / releasing properties to a fiber and imparting a natural material feeling thereto or improving them.
【０００２】[0002]
【従来の技術】従来、各種繊維および織物の風合い加工
分野において、素材に柔軟性、伸縮性、防シワ性等を付
与するため、シリコン樹脂、ポリウレタン樹脂、ポリア
クリル系樹脂、フッソ系樹脂等が使用されている。なか
でも、超ソフト加工にはシリコン樹脂、ポリウレタン樹
脂が用いられ、風合い加工の主流をなしている。シリコ
ン樹脂としてはアミノ変性シリコンが柔軟効果に優れ、
超ソフト感、ドレ−プ性、ストレッチバック性を示すこ
とからよく用いられ、ボリュ−ム感、反発感、ドライ感
を付与する目的でポリウレタン樹脂が用いられている。2. Description of the Related Art Conventionally, in the field of texture processing of various fibers and fabrics, silicone resins, polyurethane resins, polyacrylic resins, and fluorine resins have been used to impart flexibility, elasticity, and wrinkle resistance to materials. It is used. Above all, silicone resin and polyurethane resin are used for ultra-soft processing, which is the mainstream of texture processing. As a silicone resin, amino-modified silicone is excellent in softening effect,
Polyurethane resin is often used because it exhibits super soft feeling, drape property and stretch back property, and polyurethane resin is used for the purpose of imparting volume feeling, repulsion feeling and dry feeling.
【０００３】しかし、アミノ変性シリコン系仕上剤は吸
水阻害が強く、素材の吸汗性を低下させてしまう。ま
た、吸水効果に優れるものに、エチレンオキサイドを付
加したタイプや乳化剤を添加したタイプがあるが、耐久
性が得られなかったり、エチレンオキサイド鎖や乳化剤
の影響で良好な柔軟性が得られないものが多い。さらに
耐久性を上げるため、メチロ−ル基を導入したものもあ
るが、ホルマリンを含むため、直接肌に触れる素材には
適さない。このような吸汗性の低下などを補う目的で一
般柔軟剤が併用されたり、ドライ感を付与する目的で硬
仕上剤が併用されたりしている。However, the amino-modified silicone-based finishing agent has a strong water absorption inhibition property and reduces the sweat absorption of the material. In addition, there are types that have excellent water absorption effects, such as a type with ethylene oxide added and a type with an emulsifier added, but durability cannot be obtained, or good flexibility cannot be obtained due to the influence of the ethylene oxide chain or emulsifier. There are many. In order to further increase durability, some have introduced a methylol group, but since they contain formalin, they are not suitable for materials that come into direct contact with the skin. A general softener is used together with the purpose of compensating for such a decrease in sweat absorption, and a hard finish is used together with the purpose of giving a dry feeling.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、吸放湿性と
耐久性に優れ、繊維素材に天然素材様のドライタッチ感
を付与することができる繊維処理剤を提供せんとするも
のである。DISCLOSURE OF THE INVENTION The present invention is to provide a fiber treating agent which is excellent in moisture absorption and desorption and durability and which can impart a dry touch feeling to a fiber material like a natural material.
【０００５】[0005]
【課題を解決するための手段】すなわち、本発明は合成
樹脂エマルジョンおよび親水性有機系天然物微粉末から
なる繊維処理剤組成物およびこれにより処理された繊維
である。That is, the present invention provides a fiber treatment agent composition comprising a synthetic resin emulsion and a fine powder of a hydrophilic organic natural product, and a fiber treated with the composition.
【０００６】本発明に用いる合成樹脂エマルジョンは、
シリコン樹脂、ポリウレタン樹脂、ポリアクリル系樹脂
やフッソ系樹脂のエマルジョンタイプ、あるいは、これ
ら各樹脂の混合エマルジョンタイプのものであり、シリ
コン樹脂はアミノ変性したもの、なかでもシリコンの固
形分がフイルム化するタイプ（一般のアミノ変性シリコ
ンはオイル状である）のものがさらに好ましく、親水性
有機系天然物微粉末の粉落ち防止性、すなわち、繊維に
対する付着力、繊維の耐洗濯性に優れる。The synthetic resin emulsion used in the present invention is
Silicone resin, polyurethane resin, polyacrylic resin or fluorine resin emulsion type, or mixed emulsion type of these resins, the silicone resin is amino-modified, especially the solid content of silicon becomes film. A type (general amino-modified silicone is oily) is more preferable, and it is excellent in the powder-falling-preventing property of the hydrophilic organic natural product fine powder, that is, the adhesive force to the fiber and the washing resistance of the fiber.
【０００７】親水性有機系天然物微粉末は、動物性タン
パク質微粉末用にコラ−ゲン類、エラスチン、ケラチ
ン、シルクパウダ−、海綿パウダ−等の硬タンパク質や
羊毛を、植物微粉末用に木綿、麻、パルプ、海藻等のセ
ルロ−スをそれぞれ用いる。これら微粉末の粒径は、標
準偏差３μｍで平均粒径が７μｍ以下である。なお、好
ましくは平均粒径が４μｍ以下であり、これにより繊維
に対する付着性が向上し、タッチ感に優れたものが得ら
れる。平均粒径が７μｍを越えるときは、繊維に対する
付着性が低下し、ざらつき感が生じて好ましくない。天
然タンパク質微粉末の色彩は、好ましくは、平均粒径５
μｍの微粉末の場合、白色度７０％以上の白色である。
同じ微粉末であっても、平均粒径の大小により白色度は
異なる。微粉末自体に色付きがあると、繊維あるいは織
物の白さを損なう。The hydrophilic organic natural product fine powders are hard proteins and wool such as collagen, elastin, keratin, silk powder and sponge powder for animal protein fine powders and cotton for plant fine powders. Celluloses such as hemp, pulp and seaweed are used. The particle size of these fine powders is 3 μm in standard deviation and the average particle size is 7 μm or less. The average particle size is preferably 4 μm or less, whereby the adhesion to the fiber is improved, and the one having an excellent touch feeling can be obtained. If the average particle size exceeds 7 μm, the adhesion to the fiber is reduced and a rough feeling occurs, which is not preferable. The color of the natural protein fine powder preferably has an average particle size of 5
In the case of a fine powder of μm, the whiteness is 70% or more.
Even with the same fine powder, the whiteness varies depending on the size of the average particle size. The coloring of the fine powder itself impairs the whiteness of the fiber or fabric.
【０００８】繊維処理剤組成物としては、合成樹脂エマ
ルジョン９０〜９９重量部、親水性有機系天然物微粉末
１〜１０重量部からなるものを、たとえばボ−ルミルに
より攪拌、分散処理して用いる。合成樹脂エマルジョン
は、親水性有機系天然物微粉末重量の８倍以上の重量の
水成分で構成されているものを用いる。水成分が８倍以
下だと、親水性有機系天然物微粉末がこれを吸水するた
め膨潤し、２成分を混合したときにエマルジョンを得る
ことができない。これら２成分を通常の攪拌程度で混合
しただけでは、微粉末の分散がわるく、微粉末の凝集物
を生じたり、繊維から脱落を生じやすく不充分である。
しかるに、これら２成分に対してボ−ルミルによる処理
を施したものは、微粉末の分散性に優れ、また、微粉末
に圧力が加えられることにより、合成樹脂成分の微粉末
への浸透あるいは密着性が促進され、さらに繊維への付
着性が向上する。また、ボ−ルミルにより処理すること
で、原料の親水性有機系天然物微粉末がより細かくな
り、風合いの向上にもつながる。As the fiber treating agent composition, 90 to 99 parts by weight of a synthetic resin emulsion and 1 to 10 parts by weight of a fine powder of a hydrophilic organic natural product are used, for example, by stirring and dispersing with a ball mill. . As the synthetic resin emulsion, an emulsion composed of a water component whose weight is 8 times or more the weight of the hydrophilic organic natural product fine powder is used. If the water component is 8 times or less, the hydrophilic organic natural product fine powder absorbs water and swells, and an emulsion cannot be obtained when the two components are mixed. The mixing of these two components only under ordinary stirring is not sufficient because the fine powder is not well dispersed, aggregates of the fine powder are generated, and the fine powder is likely to fall off.
However, those obtained by treating the two components with a ball mill are excellent in dispersibility of the fine powder, and when pressure is applied to the fine powder, the synthetic resin component permeates or adheres to the fine powder. Property is promoted and the adhesion to the fiber is further improved. Further, by treating with a ball mill, the hydrophilic organic natural product fine powder as a raw material becomes finer, leading to an improvement in texture.
【０００９】このようにして得られた繊維処理剤組成物
は、パッド法、スプレ−法等により繊維あるいは織物に
塗布し、乾燥工程にかける。The fiber treatment composition thus obtained is applied to the fiber or the woven fabric by the pad method, the spray method or the like, and then subjected to the drying step.
【００１０】乾燥温度は８０℃以上、１６０℃以下で、
好ましくは、１００℃以上、１２０℃以下である。親水
性有機系天然物は含水状態で乾燥温度が高いと、加水分
解が促進され、異臭を放ったり、色変化を生じる。乾燥
温度が低すぎると、乾燥時間が長くなり、作業性が低下
する。The drying temperature is above 80 ° C and below 160 ° C,
It is preferably 100 ° C. or higher and 120 ° C. or lower. When the hydrophilic organic natural product is in a water-containing state and has a high drying temperature, hydrolysis is promoted, which gives off an offensive odor or causes a color change. If the drying temperature is too low, the drying time will be long and the workability will be reduced.
【００１１】[0011]
【実施例】以下、実施例および比較例により本発明をさ
らに具体的に説明する。 （実施例１）固形分がフイルム化するアミノ変性シリコ
ン系樹脂のエマルジョンタイプとして、シリコンＡＭＺ
（合成樹脂成分１３％、日華化学製）１００ｇに水２４
７ｇを添加し希釈して得られたエマルジョン溶液に、平
均粒径５μｍのコラ−ゲン微粉末１３ｇを加え、この混
合物をボ−ルミル（セイシン企業製、遊星ボ−ルミル）
を用いて、回転数１５０ｒｐｍにて１０分間処理をおこ
なった。ナイロン製のストッキング用素材２７ｇ分を、
このボ−ルミル処理した混合物に含浸させ、ロ−ル間圧
力１ｋｇ／ｃｍ2 のマングル（一方が金属ロ−ル、他方
がゴムロ−ルで構成された２本のロ−ル間に濡れたもの
を挿入し、水を絞り出す絞り機）を通し余分な処理剤を
排除した（パッド法）。この結果、ストッキング用素材
に被覆された処理剤の量は３６ｇ（固形分２．６ｇ）で
あった。得られたストッキング用素材を乾燥機に入れ、
１２０℃で５分間乾燥させた。EXAMPLES The present invention will be described in more detail with reference to Examples and Comparative Examples. (Example 1) Silicon AMZ is used as an emulsion type of amino-modified silicone resin in which solid content is formed into a film.
(Synthetic resin component 13%, manufactured by Nika Kagaku) 100 g of water 24
To an emulsion solution obtained by adding 7 g and diluting, 13 g of collagen fine powder having an average particle size of 5 μm was added, and this mixture was ball-milled (made by Seishin Enterprise Co., Ltd. planetary ball-mill).
Was used for 10 minutes at a rotation speed of 150 rpm. 27g of nylon stocking material,
This ball-milled mixture was impregnated and the mangle with a roll-to-roll pressure of 1 kg / cm 2 (wet between two rolls, one of which was a metal roll and the other of which was a rubber roll) Was inserted and the excess treating agent was removed through a squeezing machine that squeezes out water (pad method). As a result, the amount of the treatment agent coated on the stocking material was 36 g (solid content 2.6 g). Put the obtained stocking material in a dryer,
It was dried at 120 ° C. for 5 minutes.
【００１２】（実施例２〜１７、比較例１〜１０）他の
実施例および比較例についても実施例１と同様におこな
い、ストッキング用素材の処理をおこなった。これらの
内容を第１表および第２表に示す。実施例３では、実施
例１のパッド法による含浸処理にかえて、霧吹きにて、
処理剤が垂れない程度にスプレ−コ−トをおこなった
（スプレ−法）。被覆された処理剤の量は３６ｇであっ
た。実施例で使用した他の合成樹脂エマルジョンを下記
する。 アミノ変性シリコン樹脂 ＳＭ８７０２：（東レ・ダウ
コ−ニング・シリコ−ン製） アミノ変性していないシリコン樹脂 ＳＨ８７１０：
（東レ・ダウコ−ニング・シリコ−ン製） ポリウレタン樹脂 ス−パ−フレックスＥ２０００：
（第一工業製薬製） アクリル樹脂 ビニブラン１２２５：（日信化学工業
製） フッ素系樹脂 ＮＫガ−ドＦＧ−２７０（日華化学製） ポリエステル・ポリウレタン樹脂 エバファノ−ルＮ−
２０：（日華化学製）(Examples 2 to 17 and Comparative Examples 1 to 10) The stocking material was treated in the same manner as in Example 1 for the other Examples and Comparative Examples. The contents of these are shown in Tables 1 and 2. In Example 3, instead of the impregnation treatment by the pad method of Example 1, by spraying,
Spray coating was performed to such an extent that the treatment agent did not drip (spray method). The amount of treatment applied was 36 g. Other synthetic resin emulsions used in the examples are described below. Amino-modified silicone resin SM8702: (manufactured by Toray Dow Corning Silicone) Amino-unmodified silicone resin SH8710:
(Toray Dow Corning Silicone) Polyurethane resin Superflex E2000:
(Manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.) Acrylic resin VINYBRAN 1225: (manufactured by Nisshin Chemical Co., Ltd.) Fluorine-based resin NK GARD FG-270 (manufactured by NISSA CHEMICAL CO., LTD.) Polyester / Polyurethane resin Evaphanol N-
20: (Nichika Chemical)
【００１３】[0013]
【表１】 [Table 1]
【００１４】[0014]
【表２】 [Table 2]
【００１５】以上の実施例および比較例により得られた
ストッキング用素材について、評価をおこない、結果を
第３表に示す。評価項目のなかで処理剤の分散性は、処
理剤を２００メッシュフィルタ−でろ過し、フィルタ−
上の残存パウダ−量で評価した。付着性は、処理後の試
料を黒紙の上で指で強くはじき、どの程度粉落ちするか
で評価した。タッチ性は天然素材感をドライ感で、また
シリコン独自の風合いをぬめり感として１０人の官能評
価にもとずいて求めた。判定の値は、良い順に、５（か
なり良い）、４（やや良い）、３（普通）、２（やや悪
い）、１（かなり悪い）とした。吸放湿性については、
４０℃、９０％ＲＨ（吸湿条件）と２３℃、３０％ＲＨ
（放湿条件）でそれぞれをおこない、評価はブランクを
３とした。The stocking materials obtained in the above Examples and Comparative Examples were evaluated and the results are shown in Table 3. Among the evaluation items, the dispersibility of the treatment agent is determined by filtering the treatment agent with a 200-mesh filter.
The amount of residual powder above was evaluated. Adhesion was evaluated by how much the treated sample was strongly repelled with a finger on black paper, and how much the powder fell off. The touch was determined based on the sensory evaluation of 10 people, with a natural feel of material as a dry feel and the unique texture of silicone as a slimy feel. The judgment values were 5 (very good), 4 (somewhat good), 3 (normal), 2 (somewhat bad), and 1 (pretty bad) in order of goodness. For moisture absorption and desorption,
40 ° C, 90% RH (hygroscopic condition) and 23 ° C, 30% RH
Each was performed under (moisture releasing conditions), and the evaluation made the blank be 3.
【００１６】[0016]
【表３】 [Table 3]
【００１７】第３表によれば、一般の実施例（１、３、
５〜９、１１〜１７）では、すべてきわめて良好な結果
が得られた。ただし、通常の攪拌をおこなった実施例２
では、付着性とタッチ性がわずか劣り、微粉末の平均粒
径が大きかった実施例４では付着性が、繊維の処理後、
乾燥温度が高かった実施例１０では色変化が、それぞれ
わずか劣ったものの、これらも良好な結果が得られた。
これに対し、親水性有機系天然物微粉末を使用しなかっ
たもの（比較例１）や、繊維処理剤組成物を一切使用し
なかったもの（比較例２）、微粉末の平均粒径が大きす
ぎたもの（比較例３、４）、合成樹脂エマルジョンとし
て水分の少なかったもの（比較例６）、繊維を処理後、
乾燥温度が高すぎたり、低すぎたもの（比較例７〜１
０）はいずれも良好な結果が得られなかった。ただし、
微粉末の量が多すぎたもの（比較例５）はやや良好であ
ったが、効果のない量であった。According to Table 3, the general examples (1, 3,
5-9, 11-17), very good results were obtained. However, Example 2 in which normal stirring was performed
In Example 4, the adhesiveness and touch were slightly inferior, and the average particle size of the fine powder was large.
In Example 10 in which the drying temperature was high, the color change was slightly inferior, but good results were obtained.
On the other hand, the one in which the hydrophilic organic natural product fine powder was not used (Comparative Example 1) or the one in which no fiber treatment agent composition was used (Comparative Example 2) had an average particle size of fine powder. Too large (Comparative Examples 3 and 4), synthetic resin emulsion with low water content (Comparative Example 6), after treating the fiber,
Those whose drying temperature was too high or too low (Comparative Examples 7-1)
No good results were obtained for 0). However,
The amount of fine powder which was too large (Comparative Example 5) was slightly good, but the amount was ineffective.
【００１８】[0018]
【発明の効果】本発明の繊維処理剤組成物は、繊維に対
する付着性が高く、繊維そのものに天然素材様のドライ
タッチ感や吸放湿性を付与する。しかも、繊維や織物の
通気性を損なわない。繊維に対する付着性が高いこと
は、耐久性のあることを意味し、吸放湿性は吸汗、放汗
性に等しい。よって、衣料のほか、塩ビや合成皮革、人
工皮革のレザ−製品に、あるいは基布、自動車内装材、
ストッキング等にも広く利用することができる。EFFECTS OF THE INVENTION The fiber treatment composition of the present invention has high adhesiveness to fibers and imparts a dry touch feeling and moisture absorption / release property to the fibers themselves. Moreover, the breathability of the fiber or fabric is not impaired. High adhesiveness to fibers means durability, and moisture absorption / release is equal to sweat absorption and sweat release. Therefore, in addition to clothing, it can be used for leather products such as PVC, synthetic leather, artificial leather, base fabric, automobile interior materials,
It can be widely used for stockings.
フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｄ０６Ｎ 3/14 １０２ 7141−4Ｆ // Ｄ０６Ｍ 23/08 7199−3Ｂ Ｄ０６Ｍ 21/00 Ｚ Continuation of front page (51) Int.Cl. 5 Identification code Internal reference number FI Technical display location D06N 3/14 102 7141-4F // D06M 23/08 7199-3B D06M 21/00 Z
Claims (5)
系天然物微粉末からなる繊維処理剤組成物。1. A fiber treatment composition comprising a synthetic resin emulsion and a fine powder of a hydrophilic organic natural product.
と親水性有機系天然物微粉末１〜１０重量部とからな
り、合成樹脂エマルジョン中の水分が平均粒径７μｍ以
下の親水性有機系天然物微粉末の８倍以上の重量となっ
ており、両者の混合がボ−ルミルによりおこなわれるこ
とからなる請求項１記載の繊維処理剤組成物。2. A hydrophilic organic natural product comprising 90 to 99 parts by weight of a synthetic resin emulsion and 1 to 10 parts by weight of a fine powder of a hydrophilic organic natural product, wherein the water content in the synthetic resin emulsion is 7 μm or less in average particle size. The fiber treatment agent composition according to claim 1, wherein the weight of the fine powder is 8 times or more, and the mixing of both is performed by a ball mill.
マルジョンおよびポリウレタン樹脂エマルジョンのいず
れかである請求項１又は２記載の繊維処理剤組成物。3. The fiber treatment composition according to claim 1, wherein the synthetic resin emulsion is either a silicone resin emulsion or a polyurethane resin emulsion.
成物により処理された繊維。4. A fiber treated with the fiber treatment composition according to claim 1.
温度８０〜１６０℃で処理された請求項４記載の繊維。5. The fiber according to claim 4, which is treated at a drying temperature of 80 to 160 ° C. after the fiber treating agent composition is attached to the fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5043329A JP2970794B2 (en) | 1992-02-19 | 1993-02-09 | Textile material fabric |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4-69762 | 1992-02-19 | ||
| JP6976292 | 1992-02-19 | ||
| JP5043329A JP2970794B2 (en) | 1992-02-19 | 1993-02-09 | Textile material fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0610268A true JPH0610268A (en) | 1994-01-18 |
| JP2970794B2 JP2970794B2 (en) | 1999-11-02 |
Family
ID=26383085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5043329A Expired - Lifetime JP2970794B2 (en) | 1992-02-19 | 1993-02-09 | Textile material fabric |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2970794B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5622531A (en) * | 1995-08-10 | 1997-04-22 | Kurashiki Boseki Kabushiki Kaisha | Polyurethane fiber-containing textile product improved in sweat absorption/exhalation properties, and production thereof |
| EP1010800A4 (en) * | 1997-01-17 | 2000-06-21 | Idemitsu Petrochemical Co | Skin-contacting articles |
| JP2008174868A (en) * | 2007-01-19 | 2008-07-31 | Toray Ind Inc | Method for producing sheet-formed article, and sheet-formed article |
| JP2012046863A (en) * | 2011-10-28 | 2012-03-08 | Toray Ind Inc | Sheet-like article |
| JP4918481B2 (en) * | 2005-03-28 | 2012-04-18 | 出光テクノファイン株式会社 | Fiber fabric and fiber processing method |
| CN115478441A (en) * | 2022-05-13 | 2022-12-16 | 温州同赢科技有限公司 | Elastic soft synthetic leather |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49118998A (en) * | 1973-03-28 | 1974-11-13 | ||
| JPS5530434A (en) * | 1978-08-21 | 1980-03-04 | Kanebou Kenshi Kk | Silk fibroinnpolyurethane finished silk yarn and method |
| JPH01192874A (en) * | 1988-01-22 | 1989-08-02 | Ain Kk | Moisture-permeable and waterproof cloth |
| JPH0351370A (en) * | 1989-04-19 | 1991-03-05 | Kanebo Ltd | Coated fabric with dry tough |
-
1993
- 1993-02-09 JP JP5043329A patent/JP2970794B2/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49118998A (en) * | 1973-03-28 | 1974-11-13 | ||
| JPS5530434A (en) * | 1978-08-21 | 1980-03-04 | Kanebou Kenshi Kk | Silk fibroinnpolyurethane finished silk yarn and method |
| JPH01192874A (en) * | 1988-01-22 | 1989-08-02 | Ain Kk | Moisture-permeable and waterproof cloth |
| JPH0351370A (en) * | 1989-04-19 | 1991-03-05 | Kanebo Ltd | Coated fabric with dry tough |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5622531A (en) * | 1995-08-10 | 1997-04-22 | Kurashiki Boseki Kabushiki Kaisha | Polyurethane fiber-containing textile product improved in sweat absorption/exhalation properties, and production thereof |
| EP1010800A4 (en) * | 1997-01-17 | 2000-06-21 | Idemitsu Petrochemical Co | Skin-contacting articles |
| EP1010800A1 (en) * | 1997-01-17 | 2000-06-21 | Idemitsu Petrochemical Co., Ltd. | Skin-contacting articles |
| JP4918481B2 (en) * | 2005-03-28 | 2012-04-18 | 出光テクノファイン株式会社 | Fiber fabric and fiber processing method |
| JP2008174868A (en) * | 2007-01-19 | 2008-07-31 | Toray Ind Inc | Method for producing sheet-formed article, and sheet-formed article |
| JP2012046863A (en) * | 2011-10-28 | 2012-03-08 | Toray Ind Inc | Sheet-like article |
| CN115478441A (en) * | 2022-05-13 | 2022-12-16 | 温州同赢科技有限公司 | Elastic soft synthetic leather |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2970794B2 (en) | 1999-11-02 |
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