CN1673303A - Composite waterproof bridge paint and its prepn process - Google Patents
Composite waterproof bridge paint and its prepn process Download PDFInfo
- Publication number
- CN1673303A CN1673303A CN 200410029771 CN200410029771A CN1673303A CN 1673303 A CN1673303 A CN 1673303A CN 200410029771 CN200410029771 CN 200410029771 CN 200410029771 A CN200410029771 A CN 200410029771A CN 1673303 A CN1673303 A CN 1673303A
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- Prior art keywords
- emulsion
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- bridge floor
- waterproofing paint
- filler
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- 239000003973 paint Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 11
- 239000002131 composite material Substances 0.000 title abstract 2
- 239000000839 emulsion Substances 0.000 claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 20
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 11
- 239000010426 asphalt Substances 0.000 claims abstract description 10
- 230000008595 infiltration Effects 0.000 claims description 22
- 238000001764 infiltration Methods 0.000 claims description 22
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 claims description 22
- 229920000126 latex Polymers 0.000 claims description 21
- 239000011295 pitch Substances 0.000 claims description 19
- 238000004078 waterproofing Methods 0.000 claims description 17
- 239000004816 latex Substances 0.000 claims description 16
- 239000000945 filler Substances 0.000 claims description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 14
- 239000011301 petroleum pitch Substances 0.000 claims description 12
- 239000002174 Styrene-butadiene Substances 0.000 claims description 11
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 11
- 239000011115 styrene butadiene Substances 0.000 claims description 11
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 11
- 239000013530 defoamer Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 150000001768 cations Chemical group 0.000 claims description 6
- 238000002203 pretreatment Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 235000019355 sepiolite Nutrition 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000004113 Sepiolite Substances 0.000 claims description 2
- 150000001412 amines Chemical group 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910052624 sepiolite Inorganic materials 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 8
- 238000001035 drying Methods 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- 229920001909 styrene-acrylic polymer Polymers 0.000 abstract 2
- 230000000149 penetrating effect Effects 0.000 abstract 1
- 238000010008 shearing Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000004567 concrete Substances 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 7
- 235000010216 calcium carbonate Nutrition 0.000 description 6
- 239000004568 cement Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002982 water resistant material Substances 0.000 description 1
Abstract
The present invention is composite waterproof bridge paint and its preparation process. The paint contains asphalt, water, stuffing and emulsifier as well as two or more of butadiene benzene emulsion, acrylic emulsion, styrene acrylic emulsion and neoprene emulsion. The paint consists of asphalt 20-40 weight portions, butadiene benzene emulsion 0-10 weight portions, neoprene emulsion 0-20 weight portions, styrene acrylic emulsion 0-10 weight portions, acrylic emulsion 0-10 weight portions, water 40-50 weight portions, stuffing 1-3 weight portions, penetrating agent 3-5 weight portions, and stabilizer 1-3 weight portions, and is compounded through certain technological process. The paint has high shearing resistance, great adhesion strength and fast coating drying speed.
Description
Technical field that the present invention belongs to
The invention belongs to building class waterproof paint field, it is the strong compound bridge floor waterproofing paint of a kind of perviousness and cohesiveness.
The prior art background
Cement concrete material is a water-resistant material, and wet condition is that the cement concrete material early strength forms external conditions.But a host of facts prove, do not take the bad bridge of waterproof measure and waterproof system performance before reaching working life far away, and the damage by water that will take place in various degree is bad.Moisture is penetrated in the concrete slit by the bad floor system of waterproof, and various diseases take place, as steel bar corrosion, concrete alkali aggregate reaction, lime blooming etc.
For solving the bridge seepage problem, the technical measures that adopt are that various types of bridge surface waterproof layers are set at present, and concrete and water are kept apart, and make it not possess the condition that reacts.Waterproof layer is except having waterproof action, and another effect is exactly for a good bonding transition layer is provided between decking and the oil mat, and two-layer one-tenth is as a whole about making.
At present, the defective of a maximum of bridge floor waterproofing paint is coating and bilevel cohesive force deficiency, the bonding force of interlayer is poor because if bituminous concrete and bridge deck concrete are mated formation, and is then totally unfavorable to the weather resistance of bridge floor, the serious destruction that must quicken bridge deck pavement.
The purpose and the content of invention
The object of the present invention is to provide the bridge floor waterproofing paint that a kind of slip resistance is big and cohesiveness is strong, make the cement concrete bridge deck plate become as a whole with bituminous concrete.
The bridge floor waterproofing paint that another object of the present invention is to provide, drying and forming-film is fast, as early as possible open to traffic.
It is as follows to reach above-mentioned purpose technical scheme of the present invention:
Waterproof paint of the present invention is characterized in that its recipe ingredient (meter by weight) contains:
0~10 part of 20~40 parts of styrene-butadiene latex of pitch
0~10 part of 0~20 part of propyl benzene emulsion of polychloroprene latex
3~5 parts of 0~10 part of defoamers of acrylic acid emulsion
40~50 parts in 1~3 part of water of emulsifying agent
1~5 part of 1~3 part of infiltration accelerating agent of filler
1~3 part of stablizer
Used emulsifying agent is a kind of quaternary amine emulsifying agent that contains hydroxyl, and filler can be one or more in light calcium carbonate, talcum powder, the sepiolite, and infiltration accelerating agent contains naphthenic oil.Compound method is to get 90
#Petroleum pitch, water, styrene-butadiene emulsion, propyl benzene emulsion, emulsifying agent, defoamer, stablizer, infiltration accelerating agent, that filler carries out mixing manufacture is as follows:
(1) pitch is heated to 100~180 ℃;
(2) add infiltration accelerating agent and pitch blend heating;
(3) the latex pre-treatment is cation emulsion, adds latex cylinder;
(4) stablizer, defoamer, filler are added in the entry, and be preheating to 50~90 ℃;
The pitch and the aqueous solution, latex carry out uniform mixing by colloidal mill in the lump, and mixed emulsified bitumen injects finished cylinder.
The salient features test index sees the following form:
Index name | Index |
Outward appearance | Stirring the back is black or blue brown liquid, no obvious particle on the stirring rod |
Solid content | >50% |
Extensibility (non-processor) | 11mm |
Low temperature flexibility | At-20 ± 2 ℃, around diameter 10mm mandrel rod half cycle, film does not have check crack, peeling phenomenon |
Thermotolerance | At 160 ℃, test specimen is vertically placed, and constant temperature 6h does not have trickling, comes off and the downslide phenomenon. |
Cohesive strength | At 20 ± 2 ℃, with ten from interior extrapolation side cohesive strength 〉=0.4Mpa. |
Slip resistance | At 20 ± 2 ℃, slip resistance 〉=0.2Mpa. |
Acid resistance | In 1% sulphuric acid soln, soak 15d, do not have peel off, foaming, layering, phenomenon such as wrinkling. |
Alkali resistance | Under 20 ± 2 ℃, in saturated calcium hydroxide aqueous solution, soak 15d, do not have peel off, foaming, layering, phenomenon such as wrinkling. |
Drying property | Surface drying 1h5min does solid work 3h20min |
Watertightness | Under 20 ± 2 ℃, moving hydraulic pressure 〉=0.1Mpa, film is waterproof in the 30min. |
The advantage of invention
The invention has the advantages that: (1) safety non-toxic, pollution-free; (2) easy to operate, dried coating film is fast, and the engineering time shortens; (3) film alkali resistance, water tolerance, good permeability can be used in the cement concrete basic unit of finish-drying not; (4) cheap, slip resistance and cohesive strength height; (5) high temperature does not trickle, not embrittlement of low temperature.
Embodiment
Embodiment 1:
Get 500 kilograms in 90# petroleum pitch, 340 kilograms in water, 80 kilograms of styrene-butadiene latexes, 80 kilograms of propyl benzene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of light calcium carbonates, making method is as follows:
(1) pitch is heated to 100 ℃;
(2) add infiltration accelerating agent and pitch blend and be heated to 140 ℃;
(3) the latex pre-treatment is cation emulsion, adds latex cylinder;
(4) stablizer, defoamer, filler are added in the entry, and be preheating to 90 ℃;
The pitch and the aqueous solution, latex carry out uniform mixing by colloidal mill in the lump, and mixed emulsified bitumen injects finished cylinder.
Embodiment 2:
Get 500 kilograms in 90# petroleum pitch, 360 kilograms in water, 60 kilograms of acrylic latexs, 80 kilograms of propyl benzene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of talcum powder.Making method is as follows:
(1) pitch is heated to 160 ℃;
(2) add infiltration accelerating agent and pitch blend;
(3) the latex pre-treatment is cation emulsion, adds latex cylinder;
(4) stablizer, defoamer, filler are added in the entry, and be preheating to 50 ℃;
The pitch and the aqueous solution, latex carry out uniform mixing by colloidal mill in the lump, and mixed emulsified bitumen injects finished cylinder.
Embodiment 3:
Get 500 kilograms in 90# petroleum pitch, 360 kilograms in water, 60 kilograms of acrylic latexs, 80 kilograms of neoprene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of sepiolites, making method is as follows:
(1) pitch is heated to 180 ℃;
(2) add infiltration accelerating agent and pitch blend;
(3) the latex pre-treatment is cation emulsion, adds latex cylinder;
(4) stablizer, defoamer, filler are added in the entry, and be preheating to 50 ℃;
The pitch and the aqueous solution, latex carry out uniform mixing by colloidal mill in the lump, and mixed emulsified bitumen injects finished cylinder.
Embodiment 4:
Get 500 kilograms in 90# petroleum pitch, 360 kilograms in water, 60 kilograms of styrene-butadiene latexes, 80 kilograms of neoprene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of light calcium carbonates carry out being mixed as embodiment 1 same technology and make.
Embodiment 5:
Get 500 kilograms in 90# petroleum pitch, 360 kilograms in water, 60 kilograms of acrylic latexs, 80 kilograms of neoprene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of sepiolites carry out being mixed as embodiment 2 same technologies and make.
Embodiment 6:
Get 500 kilograms in 90# petroleum pitch, 340 kilograms in water, 110 kilograms of styrene-butadiene latexes, 50 kilograms of propyl benzene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of light calcium carbonates carry out being mixed as embodiment 3 same technologies and make.
Embodiment 7:
Get 400 kilograms in 90# petroleum pitch, 440 kilograms in water, 110 kilograms of styrene-butadiene latexes, 50 kilograms of propyl benzene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of light calcium carbonates carry out being mixed as embodiment 1 same technology and make.
Embodiment 8:
Get 400 kilograms in 90# petroleum pitch, 400 kilograms in water, 100 kilograms of acrylic latexs, 100 kilograms of propyl benzene emulsions,, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of light calcium carbonates carry out being mixed as embodiment 2 same technologies and make.
Embodiment 9:
Get 450 kilograms in 90# petroleum pitch, 400 kilograms in water, 70 kilograms of styrene-butadiene latexes, 80 kilograms of neoprene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of sepiolites carry out being mixed as embodiment 1 same technology and make.
Embodiment 10:
Get 450 kilograms in 90# petroleum pitch, 390 kilograms in water, 80 kilograms of acrylic latexs, 80 kilograms of neoprene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of talcum powder carry out being mixed as embodiment 3 same technologies and make.
Utilizing present embodiment gained coating is that a kind of slip resistance height, cohesive strength are big, the bridge floor waterproofing paint that film forming is fast.
Claims (10)
1. compound bridge floor waterproofing paint, contain pitch, water, filler and emulsifying agent, it is characterized in that also containing two or more emulsions in styrene-butadiene emulsion, ACRYLIC EMULSION, propyl benzene emulsion, the neoprene emulsion, the recipe ingredient of this bridge floor waterproofing paint (by weight) comprises:
0~10 part of 20~40 parts of styrene-butadiene emulsion of pitch
0~10 part of 0~20 part of propyl benzene emulsion of neoprene emulsion
3~5 parts of 0~10 part of defoamers of ACRYLIC EMULSION
40~50 parts in 1~3 part of water of emulsifying agent
1~5 part of 1~3 part of infiltration accelerating agent of filler
1~3 part of stablizer
2. bridge floor waterproofing paint according to claim 1 is characterized in that, described emulsifying agent is a kind of quaternary amine emulsifying agent that contains hydroxyl.
3. bridge floor waterproofing paint according to claim 1 is characterized in that, described filler can be one or more in light calcium carbonate, talcum powder, the sepiolite.
4. bridge floor waterproofing paint according to claim 1 is characterized in that used infiltration accelerating agent contains naphthenic oil.
5. the compound method of employing such as the described bridge floor waterproofing paint of claim 1~4 is characterized in that, gets 90
#Petroleum pitch, water, styrene-butadiene emulsion, propyl benzene emulsion, emulsifying agent, defoamer, stablizer, infiltration accelerating agent, that filler carries out mixing manufacture is as follows:
(1) pitch is heated to 100~180 ℃;
(2) add infiltration accelerating agent and pitch blend heating;
(3) the emulsion pre-treatment is cation emulsion, adds latex cylinder;
(4) stablizer, defoamer, filler are added in the entry, and be preheating to 50~90 ℃;
The pitch and the aqueous solution, latex carry out uniform mixing by colloidal mill in the lump, and mixed emulsified bitumen injects finished cylinder.
6. bridge floor waterproofing paint making method according to claim 5 is characterized in that, it is in 140 ℃ of pitches that infiltration accelerating agent is joined temperature.
7. bridge floor waterproofing paint according to claim 5 is characterized in that, styrene-butadiene emulsion, ACRYLIC EMULSION, propyl benzene emulsion, neoprene emulsion is carried out pre-treatment be cation emulsion.
8. bridge floor waterproofing paint making method according to claim 5 is characterized in that asphalt temperature is 100 ℃, and the water temp that contains stablizer, defoamer, filler is 90 ℃.
9. bridge floor waterproofing paint making method according to claim 5 is characterized in that asphalt temperature is 160 ℃, and the water temp that contains stablizer, defoamer, filler is 50 ℃.
10. bridge floor waterproofing paint making method according to claim 5 is characterized in that asphalt temperature is 180 ℃, and the water temp that contains stablizer, defoamer, filler is 50 ℃.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB200410029771XA CN100457845C (en) | 2004-03-26 | 2004-03-26 | Composite waterproof bridge paint and its prepn process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CNB200410029771XA CN100457845C (en) | 2004-03-26 | 2004-03-26 | Composite waterproof bridge paint and its prepn process |
Publications (2)
Publication Number | Publication Date |
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CN1673303A true CN1673303A (en) | 2005-09-28 |
CN100457845C CN100457845C (en) | 2009-02-04 |
Family
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CNB200410029771XA Expired - Lifetime CN100457845C (en) | 2004-03-26 | 2004-03-26 | Composite waterproof bridge paint and its prepn process |
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CN (1) | CN100457845C (en) |
Cited By (20)
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CN101787215B (en) * | 2010-01-25 | 2011-09-21 | 重庆鹏方路面工程技术研究院有限公司 | Spraying modified salinized emulsified asphalt for preventing icing on road surface and preparing method thereof |
CN102433047A (en) * | 2010-09-29 | 2012-05-02 | 梁博颖 | Waterproof coating |
CN102604538A (en) * | 2012-03-30 | 2012-07-25 | 北京华辰德创化工技术有限公司 | Road and bridge waterproof coating of multi-polymer modified emulsified asphalt and preparation process |
CN102675889A (en) * | 2012-05-22 | 2012-09-19 | 山西明科斯科技有限公司 | Polymer modified emulsified asphalt composition and preparation method thereof |
CN102690601A (en) * | 2012-06-19 | 2012-09-26 | 唐山德生防水材料有限公司 | Low temperature resisting polymer modified emulsified asphalt waterproof coating |
CN103045025A (en) * | 2012-11-30 | 2013-04-17 | 康力电梯股份有限公司 | Waterproof material for staircase |
CN103468139A (en) * | 2013-08-16 | 2013-12-25 | 安徽快来防水防腐有限公司 | Flame retardant waterproof coating |
CN103614077A (en) * | 2013-10-28 | 2014-03-05 | 蚌埠市时代电子有限公司 | Waterproof asphalt coating |
CN105237840A (en) * | 2014-07-12 | 2016-01-13 | 卢桂才 | Reactive rubber waterproof sealant containing isocyanate bridging agent and preparation method for reactive rubber waterproof sealant |
CN105419517A (en) * | 2015-12-21 | 2016-03-23 | 潍坊市宏源防水材料有限公司 | Polymer emulsion architectural waterproof coating modified by emulsified asphalt and preparation method of coating |
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CN106320185A (en) * | 2016-10-11 | 2017-01-11 | 常州市鼎日环保科技有限公司 | Method for preparing water-resistant self-repairing bridge deck pavement material |
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CN1109083C (en) * | 1999-04-02 | 2003-05-21 | 周万成 | Waterproof paint of polymer and asphalt and its preparation and use |
CN1267695A (en) * | 2000-04-14 | 2000-09-27 | 天津市禹王防水公司 | Waterproof paint specially for bridge surface |
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2004
- 2004-03-26 CN CNB200410029771XA patent/CN100457845C/en not_active Expired - Lifetime
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CN101787215B (en) * | 2010-01-25 | 2011-09-21 | 重庆鹏方路面工程技术研究院有限公司 | Spraying modified salinized emulsified asphalt for preventing icing on road surface and preparing method thereof |
CN102433047A (en) * | 2010-09-29 | 2012-05-02 | 梁博颖 | Waterproof coating |
CN102604538A (en) * | 2012-03-30 | 2012-07-25 | 北京华辰德创化工技术有限公司 | Road and bridge waterproof coating of multi-polymer modified emulsified asphalt and preparation process |
CN102675889A (en) * | 2012-05-22 | 2012-09-19 | 山西明科斯科技有限公司 | Polymer modified emulsified asphalt composition and preparation method thereof |
CN102690601A (en) * | 2012-06-19 | 2012-09-26 | 唐山德生防水材料有限公司 | Low temperature resisting polymer modified emulsified asphalt waterproof coating |
CN103045025A (en) * | 2012-11-30 | 2013-04-17 | 康力电梯股份有限公司 | Waterproof material for staircase |
CN103468139A (en) * | 2013-08-16 | 2013-12-25 | 安徽快来防水防腐有限公司 | Flame retardant waterproof coating |
CN103614077A (en) * | 2013-10-28 | 2014-03-05 | 蚌埠市时代电子有限公司 | Waterproof asphalt coating |
CN105237840A (en) * | 2014-07-12 | 2016-01-13 | 卢桂才 | Reactive rubber waterproof sealant containing isocyanate bridging agent and preparation method for reactive rubber waterproof sealant |
CN105505017A (en) * | 2015-11-26 | 2016-04-20 | 王学素 | Exterior wall osmol waterproof material |
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