CN100457845C - Composite waterproof bridge paint and its prepn process - Google Patents

Composite waterproof bridge paint and its prepn process Download PDF

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Publication number
CN100457845C
CN100457845C CNB200410029771XA CN200410029771A CN100457845C CN 100457845 C CN100457845 C CN 100457845C CN B200410029771X A CNB200410029771X A CN B200410029771XA CN 200410029771 A CN200410029771 A CN 200410029771A CN 100457845 C CN100457845 C CN 100457845C
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China
Prior art keywords
emulsion
kilograms
bridge floor
waterproofing paint
filler
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CNB200410029771XA
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CN1673303A (en
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宋晓燕
原健安
赵可
杜月宗
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TIANJIN MUNICIPAL ENGINEERING INST
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TIANJIN MUNICIPAL ENGINEERING INST
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Abstract

The present invention is composite waterproof bridge paint and its preparation process. The paint contains asphalt, water, stuffing and emulsifier as well as two or more of butadiene benzene emulsion, acrylic emulsion, styrene acrylic emulsion and neoprene emulsion. The paint consists of asphalt 20-40 weight portions, butadiene benzene emulsion 0-10 weight portions, neoprene emulsion 0-20 weight portions, styrene acrylic emulsion 0-10 weight portions, acrylic emulsion 0-10 weight portions, water 40-50 weight portions, stuffing 1-3 weight portions, penetrating agent 3-5 weight portions, and stabilizer 1-3 weight portions, and is compounded through certain technological process. The paint has high shearing resistance, great adhesion strength and fast coating drying speed.

Description

Compound bridge floor waterproofing paint and preparation method thereof
Technical field that the present invention belongs to
The invention belongs to building class waterproof paint field, it is the strong compound bridge floor waterproofing paint of a kind of perviousness and cohesiveness.
The prior art background
Cement concrete material is a water-resistant material, and wet condition is that the cement concrete material early strength forms external conditions.But a host of facts prove, do not take the bad bridge of waterproof measure and waterproof system performance before reaching working life far away, and the damage by water that will take place in various degree is bad.Moisture is penetrated in the concrete slit by the bad floor system of waterproof, and various diseases take place, as steel bar corrosion, concrete alkali aggregate reaction, lime blooming etc.
For solving the bridge seepage problem, the technical measures that adopt are that various types of bridge surface waterproof layers are set at present, and concrete and water are kept apart, and make it not possess the condition that reacts.Waterproof layer is except having waterproof action, and another effect is exactly for a good bonding transition layer is provided between decking and the oil mat, and two-layer one-tenth is as a whole about making.
At present, the defective of a maximum of bridge floor waterproofing paint is coating and bilevel cohesive force deficiency, the bonding force of interlayer is poor because if bituminous concrete and bridge deck concrete are mated formation, and is then totally unfavorable to the weather resistance of bridge floor, the serious destruction that must quicken bridge deck pavement.
The purpose and the content of invention
The object of the present invention is to provide the bridge floor waterproofing paint that a kind of slip resistance is big and cohesiveness is strong, make the cement concrete bridge deck plate become as a whole with bituminous concrete.
The bridge floor waterproofing paint that another object of the present invention is to provide, drying and forming-film is fast, as early as possible open to traffic.
It is as follows to reach above-mentioned purpose technical scheme of the present invention:
Waterproof paint of the present invention is characterized in that its recipe ingredient (meter by weight) contains:
90 #0~10 part of 20~40 parts of styrene-butadiene emulsion of petroleum pitch
0~10 part of 0~20 part of propyl benzene emulsion of neoprene emulsion
3~5 parts of 0~10 part of defoamers of acrylic acid emulsion
40~50 parts in 1~3 part of water of emulsifying agent
1~5 part of 1~3 part of infiltration accelerating agent of filler
1~3 part of stablizer
Used emulsifying agent is a kind of quaternary amine emulsifying agent that contains hydroxyl, and filler can be one or more in light calcium carbonate, talcum powder, the sepiolite, and infiltration accelerating agent contains naphthenic oil.Compound method is to get 90 #Petroleum pitch, water, styrene-butadiene emulsion, propyl benzene emulsion, emulsifying agent, defoamer, stablizer, infiltration accelerating agent, that filler carries out mixing manufacture is as follows:
(1) with 90 #Petroleum pitch is heated to 100~180 ℃;
(2) add infiltration accelerating agent and pitch blend heating;
(3) the latex pre-treatment is cation emulsion, adds latex cylinder;
(4) stablizer, defoamer, filler are added in the entry, and be preheating to 50~90 ℃;
Raw material in step (1), (2), (3, (4)) is carried out uniform mixing by colloidal mill in the lump, and mixed emulsified bitumen injects finished cylinder
The salient features test index sees the following form.
Table 1 composite water-proof paint salient features
Index name Index
Outward appearance Stirring the back is black or blue brown liquid, no obvious particle on the stirring rod
Solid content >50%
Extensibility (non-processor) 11mm
Low temperature flexibility At-20 ± 2 ℃, around diameter 10mm mandrel rod half cycle, film does not have check crack, peeling phenomenon
Thermotolerance At 160 ℃, test specimen is vertically placed, and constant temperature 6h does not have trickling, comes off and the downslide phenomenon.
Cohesive strength At 20 ± 2 ℃, with ten from interior extrapolation side cohesive strength 〉=0.4Mpa.
Slip resistance At 20 ± 2 ℃, slip resistance 〉=0.2Mpa.
Acid resistance In 1% sulphuric acid soln, soak 15d, do not have peel off, foaming, layering, phenomenon such as wrinkling.
Alkali resistance Under 20 ± 2 ℃, in saturated calcium hydroxide aqueous solution, soak 15d, do not have peel off, foaming, layering, phenomenon such as wrinkling.
Drying property Surface drying 1h5min does solid work 3h20min
Watertightness Under 20 ± 2 ℃, moving hydraulic pressure 〉=0.1Mpa, film is waterproof in the 30min.
The advantage of invention
The invention has the advantages that: (1) safety non-toxic, pollution-free; (2) easy to operate, dried coating film is fast, and the engineering time shortens; (3) film alkali resistance, water tolerance, good permeability can be used in the cement concrete basic unit of finish-drying not; (4) cheap, slip resistance and cohesive strength height; (5) high temperature does not trickle, not embrittlement of low temperature.
Embodiment
Embodiment 1:
Get 90 #500 kilograms in petroleum pitch, 340 kilograms in water, 80 kilograms of styrene-butadiene latexes, 80 kilograms of propyl benzene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of light calcium carbonates, making method is as follows:
(1) with 90 #Petroleum pitch is heated to 100 ℃;
(2) add infiltration accelerating agent and pitch blend and be heated to 140 ℃;
(3) the latex pre-treatment is cation emulsion, adds latex cylinder;
(4) stablizer, defoamer, filler are added in the entry, and be preheating to 90 ℃;
Raw material in step (1), (2), (3, (4)) is carried out uniform mixing by colloidal mill in the lump, and mixed emulsified bitumen injects finished cylinder.
Embodiment 2:
Get 500 kilograms in 90# petroleum pitch, 360 kilograms in water, 60 kilograms of acrylic latexs, 80 kilograms of propyl benzene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of talcum powder.Making method is as follows:
(1) pitch is heated to 160 ℃;
(2) add infiltration accelerating agent and pitch blend;
(3) the latex pre-treatment is cation emulsion, adds latex cylinder;
(4) stablizer, defoamer, filler are added in the entry, and be preheating to 50 ℃;
Raw material in step (1), (2), (3, (4)) is carried out uniform mixing by colloidal mill in the lump, and mixed emulsified bitumen injects finished cylinder.
The pitch and the aqueous solution, latex carry out uniform mixing by colloidal mill in the lump, and mixed emulsified bitumen injects finished cylinder.
Embodiment 3:
Get 90 #500 kilograms in petroleum pitch, 360 kilograms in water, 60 kilograms of acrylic latexs, 80 kilograms of neoprene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of sepiolites, making method is as follows:
(1) pitch is heated to 180 ℃;
(2) add infiltration accelerating agent and pitch blend;
(3) the latex pre-treatment is cation emulsion, adds latex cylinder;
(4) stablizer, defoamer, filler are added in the entry, and be preheating to 50 ℃;
Raw material in step (1), (2), (3, (4)) is carried out uniform mixing by colloidal mill in the lump, and mixed emulsified bitumen injects finished cylinder.
Embodiment 4:
Get 90 #500 kilograms in petroleum pitch, 360 kilograms in water, 60 kilograms of styrene-butadiene latexes, 80 kilograms of neoprene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of light calcium carbonates carry out being mixed as embodiment 1 same technology and make.
Embodiment 5:
Get 90 #500 kilograms in petroleum pitch, 360 kilograms in water, 60 kilograms of acrylic latexs, 80 kilograms of neoprene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of sepiolites carry out being mixed as embodiment 2 same technologies and make.
Embodiment 6:
Get 90 #500 kilograms in petroleum pitch, 340 kilograms in water, 110 kilograms of styrene-butadiene latexes, 50 kilograms of propyl benzene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of light calcium carbonates carry out being mixed as embodiment 3 same technologies and make.
Embodiment 7:
Get 90 #400 kilograms in petroleum pitch, 440 kilograms in water, 110 kilograms of styrene-butadiene latexes, 50 kilograms of propyl benzene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of light calcium carbonates carry out being mixed as embodiment 1 same technology and make.
Embodiment 8:
Get 90 #400 kilograms in petroleum pitch, 400 kilograms in water, 100 kilograms of acrylic latexs, 100 kilograms of propyl benzene emulsions,, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of light calcium carbonates carry out being mixed as embodiment 2 same technologies and make.
Embodiment 9:
Get 90 #450 kilograms in petroleum pitch, 400 kilograms in water, 70 kilograms of styrene-butadiene latexes, 80 kilograms of neoprene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of sepiolites carry out being mixed as embodiment 1 same technology and make.
Embodiment 10:
Get 90 #450 kilograms in petroleum pitch, 390 kilograms in water, 80 kilograms of acrylic latexs, 80 kilograms of neoprene emulsions, 20 kilograms of emulsifying agents, 30 kilograms of defoamers, 10 kilograms of stablizers, 20 kilograms of infiltration accelerating agents, 10 kilograms of talcum powder carry out being mixed as embodiment 3 same technologies and make.
Utilizing present embodiment gained coating is that a kind of slip resistance height, cohesive strength are big, the bridge floor waterproofing paint that film forming is fast.

Claims (10)

1. a compound bridge floor waterproofing paint contains 90 #Petroleum pitch, water, filler and emulsifying agent is characterized in that also containing two or more emulsions in styrene-butadiene emulsion, ACRYLIC EMULSION, propyl benzene emulsion, the neoprene emulsion, and the recipe ingredient of this bridge floor waterproofing paint (by weight) comprises:
90 #0~10 part of 20~40 parts of styrene-butadiene emulsion of petroleum pitch
0~10 part of 0~20 part of propyl benzene emulsion of neoprene emulsion
3~5 parts of 0~10 part of defoamers of ACRYLIC EMULSION
40~50 parts in 1~3 part of water of emulsifying agent
1~5 part of 1~3 part of infiltration accelerating agent of filler
1~3 part of stablizer
2. bridge floor waterproofing paint according to claim 1 is characterized in that, described emulsifying agent is a kind of quaternary amine emulsifying agent that contains hydroxyl.
3. bridge floor waterproofing paint according to claim 1 is characterized in that, described filler is one or more in light calcium carbonate, talcum powder, the sepiolite.
4. bridge floor waterproofing paint according to claim 1 is characterized in that used infiltration accelerating agent contains naphthenic oil.
5. the making method of a bridge floor waterproofing paint as claimed in claim 1 is characterized in that, gets 90 #Two or more emulsions in petroleum pitch, water and styrene-butadiene emulsion, propyl benzene emulsion, ACRYLIC EMULSION, the neoprene emulsion, emulsifying agent, defoamer, stablizer, infiltration accelerating agent, that filler carries out mixing manufacture is as follows:
(1) with 90 #Petroleum pitch is heated to 100~180 ℃;
(2) add infiltration accelerating agent and pitch blend heating;
(3) the emulsion pre-treatment is cation emulsion, adds latex cylinder;
(4) stablizer, defoamer, filler are added in the entry, and be preheating to 50~90 ℃;
Raw material in step (1), (2), (3), (4) is carried out uniform mixing by colloidal mill in the lump, and mixed emulsified bitumen injects finished cylinder.
6. bridge floor waterproofing paint making method according to claim 5 is characterized in that, it is 140 ℃ 90 that infiltration accelerating agent is joined temperature #In the petroleum pitch.
7. bridge floor waterproofing paint making method according to claim 5 is characterized in that, styrene-butadiene emulsion, propyl benzene emulsion, ACRYLIC EMULSION, neoprene emulsion is carried out pre-treatment be cation emulsion.
8. bridge floor waterproofing paint making method according to claim 5 is characterized in that 90 #The petroleum pitch temperature is 100 ℃, and the water temp that contains stablizer, defoamer, filler is 90 ℃.
9. bridge floor waterproofing paint making method according to claim 5 is characterized in that 90 #The petroleum pitch temperature is 160 ℃, and the water temp that contains stablizer, defoamer, filler is 50 ℃.
10. bridge floor waterproofing paint making method according to claim 5 is characterized in that 90 #The petroleum pitch temperature is 180 ℃, and the water temp that contains stablizer, defoamer, filler is 50 ℃.
CNB200410029771XA 2004-03-26 2004-03-26 Composite waterproof bridge paint and its prepn process Expired - Lifetime CN100457845C (en)

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Application Number Priority Date Filing Date Title
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CN100457845C true CN100457845C (en) 2009-02-04

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CN101787215B (en) * 2010-01-25 2011-09-21 重庆鹏方路面工程技术研究院有限公司 Spraying modified salinized emulsified asphalt for preventing icing on road surface and preparing method thereof
CN102433047A (en) * 2010-09-29 2012-05-02 梁博颖 Waterproof coating
CN102604538A (en) * 2012-03-30 2012-07-25 北京华辰德创化工技术有限公司 Road and bridge waterproof coating of multi-polymer modified emulsified asphalt and preparation process
CN102675889B (en) * 2012-05-22 2014-04-02 山西明科斯科技有限公司 Polymer modified emulsified asphalt composition and preparation method thereof
CN102690601A (en) * 2012-06-19 2012-09-26 唐山德生防水材料有限公司 Low temperature resisting polymer modified emulsified asphalt waterproof coating
CN103045025A (en) * 2012-11-30 2013-04-17 康力电梯股份有限公司 Waterproof material for staircase
CN103468139A (en) * 2013-08-16 2013-12-25 安徽快来防水防腐有限公司 Flame retardant waterproof coating
CN103614077A (en) * 2013-10-28 2014-03-05 蚌埠市时代电子有限公司 Waterproof asphalt coating
CN105237840A (en) * 2014-07-12 2016-01-13 卢桂才 Reactive rubber waterproof sealant containing isocyanate bridging agent and preparation method for reactive rubber waterproof sealant
CN105505017A (en) * 2015-11-26 2016-04-20 王学素 Exterior wall osmol waterproof material
CN105419517A (en) * 2015-12-21 2016-03-23 潍坊市宏源防水材料有限公司 Polymer emulsion architectural waterproof coating modified by emulsified asphalt and preparation method of coating
CN106320185A (en) * 2016-10-11 2017-01-11 常州市鼎日环保科技有限公司 Method for preparing water-resistant self-repairing bridge deck pavement material
CN108047951A (en) * 2017-11-21 2018-05-18 广西武宣金牌防水材料科技有限公司 Flame-retardant modified asphalt waterproofing paint and its production method
CN108003791A (en) * 2017-11-21 2018-05-08 广西武宣金牌防水材料科技有限公司 A kind of asphalt waterproofing paint and its production method
CN107955535A (en) * 2017-11-21 2018-04-24 广西武宣金牌防水材料科技有限公司 Mould-proof-type modified waterproof asphalt material and its production method
CN107987725A (en) * 2017-11-21 2018-05-04 广西武宣金牌防水材料科技有限公司 A kind of bridge floor waterproofing paint and its production method
CN107987726A (en) * 2017-11-21 2018-05-04 广西武宣金牌防水材料科技有限公司 A kind of pitch mildewproof waterproof coating and its production method for bridge construction
CN108047952A (en) * 2017-11-21 2018-05-18 广西武宣金牌防水材料科技有限公司 A kind of modified waterproof asphalt material for building and its production method
CN107936839B (en) * 2017-12-14 2020-01-14 沧州市临港隆达化工有限公司 High-elasticity rubber asphalt waterproof coating and preparation method thereof
CN110408274A (en) * 2019-08-23 2019-11-05 山东北方创信防水科技股份有限公司 A kind of single-component water-based rubber asphalt quick-drying water-repellent paint

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CN1267695A (en) * 2000-04-14 2000-09-27 天津市禹王防水公司 Waterproof paint specially for bridge surface
CN1269389A (en) * 1999-04-02 2000-10-11 周万成 Waterproof paint of polymer and asphalt and its preparation and use

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1096527A (en) * 1993-06-18 1994-12-21 中国石化齐鲁石油化工公司 Method for preparing thick modified asphalt waterproof paint
CN1269389A (en) * 1999-04-02 2000-10-11 周万成 Waterproof paint of polymer and asphalt and its preparation and use
CN1267695A (en) * 2000-04-14 2000-09-27 天津市禹王防水公司 Waterproof paint specially for bridge surface

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