CN1673296A - Nano bactericidal negative ion alkyd enamel - Google Patents

Nano bactericidal negative ion alkyd enamel Download PDF

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Publication number
CN1673296A
CN1673296A CN 200410098766 CN200410098766A CN1673296A CN 1673296 A CN1673296 A CN 1673296A CN 200410098766 CN200410098766 CN 200410098766 CN 200410098766 A CN200410098766 A CN 200410098766A CN 1673296 A CN1673296 A CN 1673296A
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negative ion
weight part
nano
weight
powder
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CN 200410098766
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CN100439461C (en
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许绍凰
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Abstract

The nanometer bactericidal negative ion alkyd enamel consists of alkyd resin, defoaming agent A, defoaming agent B, RE material, cobalt material, antiskinning agent, composite nanometer bactericidal powder, composite nanometer negative ion powder, dull powder, No. 200 solvent, and one or several of floating color preventer, leveling agent A, leveling agent B, titanium dioxide, French blue, aluminum stearate, carbon black, dispresant A, dispersant B, lithopone, lead monoxide and talcum powder in certain proportion. The nanometer bactericidal negative ion alkyd enamel has no toxicity and smell, has powerful bactericidal and mildewproof functions and can release negative ion to purify air.

Description

Nano bactericidal negative ion alkyd enamel
Technical field
The present invention relates to a kind of paint, the nano bactericidal negative ion alkyd enamel of mildew-resistant of particularly a kind of tool strong disinfecting and sustainable release anion fine-purification air effect.
Background technology
At present, the coating variety of selling on the market is many, purposes is wide, especially door and window tailor-made paint, the multiple function of each tool, but when using all kinds of synthesis material, generally all contain harmful material, and discharge peculiar smell, as formaldehyde, VOC (volatile organic compounds), heavy metal, benzene etc. exceed standard and then environment and HUMAN HEALTH are produced a large amount of the murder by poisoning, virus and bacterium are always to have in our living space in addition, ubiquitous, the physical and mental health that everybody is perplexed always and threatened to the existence of virus and bacteria to the hazard rating of human body is as intestinal bacteria, streptococcus aureus, candida albicans, withered grass gemma etc. can cause infectation of bacteria to spread disease; In addition, a large amount of household electrical appliance enter ordinary people family, cause the environment negative ion concentration to reduce when using air-conditioning, influence the healthy of people.
In view of this, in order to address the above problem, this creator is according to oneself practical experience and technical concept, and test has the present invention to produce eventually after deliberation.
Summary of the invention
The present invention will provide a kind of nano bactericidal negative ion alkyd enamel, makes the technical problem of its fungus and mildew resistance and sustainable release anion fine-purification air with solution.
It is such solving the problems of the technologies described above the technical scheme that is adopted:
A kind of nano bactericidal negative ion alkyd enamel is characterized in that: the base stock and the weight ratio of its prescription are:
Synolac 650~900 weight parts, defoamer A 0.6~2 weight part,
Defoamer B 0.6~2 weight part, rare earth siccative 46~50 weight parts,
Cobalt siccative 14~26 weight parts, anti 0.6~2 weight part,
Composite Nano sterilization powder 0.05~25 weight part, composite Nano negative ion powder 0.05~25 weight part,
Flatting silica 0~40 weight part, 200# solvent 1~90 weight part.
Wherein add the loose colour that grows dim and prevent that agent 0.6~2 weight part, flow agent A 1.5~3.5 weight parts and flow agent B 0.5~2.5 weight part from constituting the clear enamel paint of the transparent external application of nano bactericidal negative ion alkyd;
Wherein add the loose colour that grows dim and prevent that agent 0.6~2 weight part from constituting the transparent blending varnish of nano bactericidal negative ion alkyd;
Wherein add flow agent A 1.5~3.5 weight parts, flow agent B 0.5~2.5 weight part, titanium dioxide 230~250 weight parts, ultramarine 0.12~0.14 weight part and aluminum stearate 1~3 weight part constitute the ultrawhite enamel paint of using of nano bactericidal negative ion alkyd;
Wherein add flow agent A 1.5~3.5 weight parts, flow agent B 0.5~2.5 weight part, carbon black 15~35 weight parts, dispersant A 0.5~2.5 weight part and dispersant B 0.5~2.5 weight part and constitute nano bactericidal negative ion alkyd infrablack enamel paint;
Wherein add flow agent A 1.5~3.5 weight parts, flow agent B 0.5~2.5 weight part, titanium dioxide 90~110 weight parts, ultramarine 0.12~0.14 weight part, aluminum stearate 1~3 weight part, zinc sulfide white 130~150 weight parts and yellow lead 0.07~0.09 weight part and constitute the white ready-mixed paint of nano bactericidal negative ion alkyd;
Wherein add carbon black 15~35 weight parts, aluminum stearate 1~3 weight part, dispersant A 0.5~2.5 weight part, dispersant B 0.5~2.5 weight part and talcum powder 50~70 weight parts and constitute nano bactericidal negative ion alkyd black ready-mixed paint;
The active ingredient of above-mentioned composite Nano sterilization powder is the combination of nanometer silver, copper, zinc, manganese, the multiple metal particle of iron, its carrier is titanium phosphate, zirconium phosphate or zeolite powder body material, the composite Nano negative ion powder is the silicate minerals powder with the photocatalyst material modification, defoamer A is poly-methyl alkyl siloxane solution, defoamer B is not for containing organic-silicon-modified broken bubble polymers soln, the rare earth siccative is a mishmetal, the cobalt siccative is a cobalt naphthenate, anti is a methylethylketone, flatting silica is a silicon-dioxide, and the 200# solvent is an aromatic solvent naphtha; Dispersant A is an anionic property polymer interfacial activity, and dispersant B is the unsaturated polynary hydroxy acid polymkeric substance of negatively charged ion lower molecular weight; Flow agent A is a polyethers polydimethylsiloxane solution, and flow agent B is polyether-modified polydimethylsiloxane solution.
Above-mentioned flatting silica is 0~40 weight part, and wherein working as flatting silica is that 40 weight parts constitute mute light type, when flatting silica is that 20 weight parts constitute half light type, is highlight type and do not add flatting silica.
The present invention has adopted composite Nano sterilization powder and composite Nano negative ion powder to add in the paint, make this paint have strong disinfecting mildew-resistant and the lasting effect that discharges negative ion, purify air, improve the human body respiration environment, useful HUMAN HEALTH, thus the technical problem that makes its fungus and mildew resistance and sustainable release anion fine-purification air solved.
Advantage of the present invention is as follows:
1, product strong covering power of the present invention is constructed easily, and is nonpoisonous and tasteless, and the tool feature of environmental protection.
2, tool brute force of the present invention, lasting fungus and mildew resistance effect all reach more than 99.5% as the sterilizing rate to streptococcus aureus, intestinal bacteria, candida albicans and withered grass gemma.
3, the sustainable release negative ion of product japanning of the present invention self, 443/cm of its negative ion generation average out to 3, can dispel obnoxious flavour and peculiar smell such as formaldehyde in the air, ammonia, benzene, thereby purify air, improve people's living environment, useful HUMAN HEALTH.
4, scrubbing resistance of the present invention is good, and be widely used in furniture, woodwork, cement products etc. and decorate finish paint, and the tool practicality.
Embodiment
The invention will be further described below by embodiment:
Embodiment 1, and its prescription is: Synolac 900kg, defoamer A 1kg, defoamer B 1kg, the loose colour that grows dim prevents agent 1kg, flow agent A 2.5kg, flow agent B 1.5kg, rare earth siccative 48kg, cobalt siccative 16kg, anti 1kg, composite Nano sterilization powder 8kg, composite Nano negative ion powder 10kg, flatting silica 0~40kg, 200# solvent 69.82kg constitutes the clear enamel paint of the transparent external application of nano bactericidal negative ion alkyd.
Embodiment 2, and its prescription is: Synolac 900kg, defoamer A 1kg, defoamer B 1kg, the loose colour that grows dim prevents agent 1kg, rare earth siccative 48kg, cobalt siccative 16kg, anti 1kg, composite Nano sterilization powder 8kg, composite Nano negative ion powder 10kg, flatting silica 0~40kg, 200# solvent 14kg constitutes the transparent blending varnish of nano bactericidal negative ion alkyd.
Embodiment 3, and its prescription is: Synolac 650kg, defoamer A 1kg, defoamer B 1kg, flow agent A 2.5kg, flow agent B 1.5kg, rare earth siccative 48kg, cobalt siccative 18kg, anti 1kg, composite Nano sterilization powder 8kg, composite Nano negative ion powder 10kg, flatting silica 0~40kg, 200# solvent 86.64kg, titanium dioxide 240kg, ultramarine 0,13kg, aluminum stearate 2kg constitutes the ultrawhite enamel paint of using of nano bactericidal negative ion alkyd.
Embodiment 4, and its prescription is: Synolac 880kg, defoamer A 1kg, defoamer B 1kg, flow agent A 2.5kg, flow agent B 1.5kg, rare earth siccative 48kg, cobalt siccative 24kg, anti 1kg, composite Nano sterilization powder 8kg, composite Nano negative ion powder 10kg, flatting silica 0~40kg, 200# solvent 5kg, carbon black 25kg, dispersant A 1.5kg, dispersant B 1.5kg constitute nano bactericidal negative ion alkyd infrablack enamel paint.
Embodiment 5, and its prescription is: Synolac 650kg, defoamer A 1kg, defoamer B 1kg, flow agent A 2.5kg, flow agent B 1.5kg, rare earth siccative 48kg, cobalt siccative 18kg, anti 1kg, composite Nano sterilization powder 8kg, composite Nano negative ion powder 10kg, flatting silica 0~40kg, 200# solvent 6.64kg, titanium dioxide 100kg, ultramarine 0.13kg, aluminum stearate 2kg, zinc sulfide white 140kg, yellow lead 0.08kg constitutes the white ready-mixed paint of nano bactericidal negative ion alkyd
Embodiment 6, and its prescription is: Synolac 820kg, defoamer A 1kg, defoamer B 1kg, rare earth siccative 48kg, cobalt siccative 20kg, anti 1kg, composite Nano sterilization powder 8kg, composite Nano negative ion powder 10kg, flatting silica 0~40kg, 200# solvent 1kg, aluminum stearate 2kg, carbon black 25kg, dispersant A 1.5kg, dispersant B 1.5kg, talcum powder 60kg constitute nano bactericidal negative ion alkyd black ready-mixed paint.
The active ingredient of above-mentioned composite Nano sterilization powder is the combination of nanometer silver, copper, zinc, manganese, the multiple metal particle of iron, its carrier is titanium phosphate, zirconium phosphate or zeolite powder body material, the composite Nano negative ion powder is the silicate minerals powder with the photocatalyst material modification, defoamer A is poly-methyl alkyl siloxane solution, defoamer B is not for containing organic-silicon-modified broken bubble polymers soln, the rare earth siccative is a mishmetal, the cobalt siccative is a cobalt naphthenate, anti is a methylethylketone, flatting silica is a silicon-dioxide, and the 200# solvent is an aromatic solvent naphtha; This dispersant A is an anionic property polymer interfacial activity, and dispersant B is the unsaturated polynary hydroxy acid polymkeric substance of negatively charged ion lower molecular weight; This flow agent A is a polyethers polydimethylsiloxane solution, and flow agent B is polyether-modified polydimethylsiloxane solution, and titanium dioxide is a titanium dioxide powder.
Flatting silica in the foregoing description is 0~40kg, and wherein working as flatting silica is that 40kg constitutes mute light type, when flatting silica is that 20kg constitutes half light type, is highlight type and do not add flatting silica.
Preparation method of the present invention comprises: stir, grind, high speed dispersion is filtered, check, packing.
In sum, effect of the present invention has tangible lifting, and the effect tool practicality of its strong disinfecting and sustainable release anion fine-purification air meets each important document of patent of invention, so propose application for a patent for invention in accordance with the law.

Claims (10)

1, a kind of nano bactericidal negative ion alkyd enamel is characterized in that: the base stock and the weight ratio of its prescription are:
Synolac 650~900 weight parts, defoamer A 0.6~2 weight part,
Defoamer B 0.6~2 weight part, rare earth siccative 46~50 weight parts,
Cobalt siccative 14~26 weight parts, anti 0.6~2 weight part,
Composite Nano sterilization powder 0.05~25 weight part, composite Nano negative ion powder 0.05~25 weight part,
Flatting silica 0~40 weight part, 200# solvent 1~90 weight part.
2, nano bactericidal negative ion alkyd enamel according to claim 1 is characterized in that: wherein add the loose colour that grows dim and prevent that agent 0.6~2 weight part, flow agent A 1.5~3.5 weight parts and flow agent B0.5~2.5 weight parts from constituting the clear enamel paint of the transparent external application of nano bactericidal negative ion alkyd.
3, nano bactericidal negative ion alkyd enamel according to claim 1 is characterized in that: wherein add the loose colour that grows dim and prevent that agent 0.6~2 weight part from constituting the transparent blending varnish of nano bactericidal negative ion alkyd.
4, nano bactericidal negative ion alkyd enamel according to claim 1, it is characterized in that: wherein add flow agent A 1.5~3.5 weight parts, flow agent B 0.5~2.5 weight part, titanium dioxide 230~250 weight parts, ultramarine 0.12~0.14 weight part and aluminum stearate 1~3 weight part constitute the ultrawhite enamel paint of using of nano bactericidal negative ion alkyd.
5, nano bactericidal negative ion alkyd enamel according to claim 1 is characterized in that: wherein add flow agent A 1.5~3.5 weight parts, flow agent B 0.5~2.5 weight part, carbon black 15~35 weight parts, dispersant A 0.5~2.5 weight part and dispersant B 0.5~2.5 weight part and constitute nano bactericidal negative ion alkyd infrablack enamel paint.
6, nano bactericidal negative ion alkyd enamel according to claim 1 is characterized in that: wherein add flow agent A 1.5~3.5 weight parts, flow agent B 0.5~2.5 weight part, titanium dioxide 90~110 weight parts, ultramarine 0.12~0.14 weight part, aluminum stearate 1~3 weight part, zinc sulfide white 130~150 weight parts and yellow lead 0.07~0.09 weight part and constitute the white ready-mixed paint of nano bactericidal negative ion alkyd.
7, nano bactericidal negative ion alkyd enamel according to claim 1 is characterized in that: wherein add carbon black 15~35 weight parts, aluminum stearate 1~3 weight part, dispersant A 0.5~2.5 weight part, dispersant B 0.5~2.5 weight part and talcum powder 50~70 weight parts and constitute nano bactericidal negative ion alkyd black ready-mixed paint.
8, according to any described nano bactericidal negative ion alkyd enamel in the claim 1 to 7, it is characterized in that: the active ingredient of this composite Nano sterilization powder is a nanometer silver, copper, zinc, manganese, the combination of the multiple metal particle of iron, its carrier is a titanium phosphate, zirconium phosphate or zeolite powder body material, the composite Nano negative ion powder is the silicate minerals powder with the photocatalyst material modification, defoamer A is poly-methyl alkyl siloxane solution, defoamer B is not for containing organic-silicon-modified broken bubble polymers soln, the rare earth siccative is a mishmetal, the cobalt siccative is a cobalt naphthenate, anti is a methylethylketone, flatting silica is a silicon-dioxide, and the 200# solvent is an aromatic solvent naphtha.
9, according to claim 5 or 7 to described nano bactericidal negative ion alkyd enamel, it is characterized in that: this dispersant A is an anionic property polymer interfacial activity, dispersant B is the unsaturated polynary hydroxy acid polymkeric substance of negatively charged ion lower molecular weight.
10, according to claim 2,4,5 or 6 to described nano bactericidal negative ion alkyd enamel, it is characterized in that: this flow agent A is a polyethers polydimethylsiloxane solution, flow agent B is polyether-modified polydimethylsiloxane solution.
CNB2004100987664A 2004-12-16 2004-12-16 Nano bactericidal negative ion alkyd enamel Expired - Fee Related CN100439461C (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101747827B (en) * 2008-12-10 2012-07-04 上海海悦涂料有限公司 Environment-friendly alkyd coating
CN101760117B (en) * 2009-11-06 2012-08-22 黄宏亭 Antibiotic-aldehyde removing type wood paint
CN102985366A (en) * 2010-05-07 2013-03-20 伊格内茨格·莫希齐茨基亚格教授工业化工研究院 Method of manufacturing silica nanopowders with fungicidal properties, especially for polymer composites
CN104118257A (en) * 2014-07-28 2014-10-29 贵州航天风华精密设备有限公司 Method for imitating antenna at antenna groove part of casting
CN104170820A (en) * 2013-05-22 2014-12-03 上海奇维纺织科技有限公司 Nano-zinc protective silver ion-containing inorganic antibacterial powder and preparation method
CN107868595A (en) * 2017-12-14 2018-04-03 莆田市涵江区初日化工有限公司 A kind of nanoscale has the anion alkyd paint of sterilizing function

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6140370A (en) * 1998-09-21 2000-10-31 Troy Technology Corporation, Inc. Stabilized alkyd based compositions containing halopropynl compounds
CN1106433C (en) * 2000-12-14 2003-04-23 薛峻峰 Nm-class Ti polymer paint
CN1242009C (en) * 2002-04-15 2006-02-15 上海金樱环保科技有限公司 Health pollution-free oily coating
CN1204214C (en) * 2002-07-08 2005-06-01 北京市建筑涂料厂 Inner wall paint and putty capable of producing negative air ion

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101747827B (en) * 2008-12-10 2012-07-04 上海海悦涂料有限公司 Environment-friendly alkyd coating
CN101760117B (en) * 2009-11-06 2012-08-22 黄宏亭 Antibiotic-aldehyde removing type wood paint
CN102985366A (en) * 2010-05-07 2013-03-20 伊格内茨格·莫希齐茨基亚格教授工业化工研究院 Method of manufacturing silica nanopowders with fungicidal properties, especially for polymer composites
CN104170820A (en) * 2013-05-22 2014-12-03 上海奇维纺织科技有限公司 Nano-zinc protective silver ion-containing inorganic antibacterial powder and preparation method
CN104118257A (en) * 2014-07-28 2014-10-29 贵州航天风华精密设备有限公司 Method for imitating antenna at antenna groove part of casting
CN104118257B (en) * 2014-07-28 2016-09-14 贵州航天风华精密设备有限公司 Method copied by the antenna at a kind of foundry goods antenna slot position
CN107868595A (en) * 2017-12-14 2018-04-03 莆田市涵江区初日化工有限公司 A kind of nanoscale has the anion alkyd paint of sterilizing function

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Assignee: ZHANGZHOU SANDELI PAINT & COATING CO., LTD.

Assignor: Xu Shaohuang

Contract fulfillment period: 2009.1.6 to 2019.1.5

Contract record no.: 2009990000385

Denomination of invention: Nano bactericidal negative ion alkyd enamel

Granted publication date: 20081203

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Record date: 20090428

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.1.6 TO 2019.1.5; CHANGE OF CONTRACT

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