CN1668725A - Fuel composition - Google Patents

Fuel composition Download PDF

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Publication number
CN1668725A
CN1668725A CN 02829604 CN02829604A CN1668725A CN 1668725 A CN1668725 A CN 1668725A CN 02829604 CN02829604 CN 02829604 CN 02829604 A CN02829604 A CN 02829604A CN 1668725 A CN1668725 A CN 1668725A
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China
Prior art keywords
fuel composition
additive
compound
aliphatic
composition
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Granted
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CN 02829604
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CN100357407C (en
Inventor
查尔斯·A·斯托克斯
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Dometic AG
Dometic AB
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Dometic AB
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/003Marking, e.g. coloration by addition of pigments
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1608Well defined compounds, e.g. hexane, benzene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1616Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • C10L1/1881Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/224Amides; Imides carboxylic acid amides, imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/24Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2406Organic compounds containing sulfur, selenium and/or tellurium mercaptans; hydrocarbon sulfides

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

Liquid fuel composition for domestic use, in particular for a stove or a burner in the house-hold, comprising at least one organic compound in which essentially all carbon atoms are already attached to at least one oxygen atom so that during burning of the compound essentially carbon dioxide and water are merely formed thereby avoiding the formation of carbon to carbon bonds in the combustion products, particularly methanol, and one or more additives for providing at least one of the properties including flame colour, an unpleasant and preferably sharp odor, fuel color and a repugnant taste.

Description

Fuel composition
Technical field
The present invention relates to not have cigarette ash, liquid fuel pollution-free, safe in utilization, in particular for the liquid fuel of the ORIGO type stove that has no leaked fuel jar.
Background technology
As everyone knows, the solid inferior and the use of liquid fuel have become about 2,000,000,000 people's burden, the solid of described poor quality and liquid fuel have caused a large amount of diseases and premature death, simultaneously, for the amount of the net heat that is used to cook with respect to recovery, this class A fuel A discharges excessive carbon dioxide and other greenhouse gases.
In the developing country that uses inferior fuel, solve the room air pollution problem and to make progress aspect the greenhouse gas emission rate be valuable reducing, so that arrival along with the carbon transaction, developing country can obtain credit, even this credit can not the absolute payment stove and the expense of fuel, also can pay most of this expense.In addition; stop using the ecosystem that timber not only can conserve forests and these countries are very valuable as domestic fuel; and the trees of saving thus and shrub can continued growth and absorbing carbon dioxide for many years, at last again with its felling to make the usefulness of timber, paper and fiber.
Summary of the invention
Therefore, an object of the present invention is to provide no cigarette ash, liquid fuel combination pollution-free, safe in utilization.Purpose of the present invention is also in that a kind of liquid fuel combination is provided, and especially in developing country, this fuel can obtain in a large number with reasonable price.
Liquid fuel combination of the present invention has been realized above-mentioned purpose.The present invention also provides preferred embodiment.
Have now found that needed fuel should be the liquid that is easy to transport, and must have such chemical property, promptly when it burns, can not form carbon bond in the by product that why not needs in office.In fact, it must have such character: for all practical purposes, can not form removing carbon dioxide and water other products in addition.As if this mean that the fuel based on organic compound should not contain the carbon atom that is not connected on single Sauerstoffatom or a plurality of Sauerstoffatom.
Such compound quantity is very limited, and those described compounds that can find must prepare originally with relatively low one-tenth, and these compounds must come from the great basic resource of quantity the remaining useful life of having for many years.After careful consideration, preferably with alcohols, especially methyl alcohol is as this compound, and finds that it can satisfy requirement of the present invention.Investigated all firing systems and to its test after, find that so-called ORIGO type stove is best comprehensive cooking system, and test proof this point is unquestionable.
Yet, has realized that preferably and methyl alcohol can be mixed with Virahol mutually with other Fatty Alcohol(C12-C14 and C12-C18), especially ethanol to a certain extent, and it still has suitable combustion characteristic.
People also recognize, because methyl alcohol is poisonous, methyl alcohol and small quantity of material can be mixed mutually so that colored flame, unpleasant especially violent pungent smell, fuel color and disgusting taste to be provided.Therefore, fuel of the present invention is preferably the propellant combination based on methyl alcohol.
In order to realize the purpose of this fuel invention, should manage to seek the important compound family that is suitable for use as additive most, described additive is used for giving more perfect functions of fuel in family expenses.In addition, people are also seeking synergistic effect,, can maybe can also provide the odorant of peculiar smell for flame provides the odorant of color that is.
Simultaneously, people are also seeking the substitute that provides enough, satisfying chemical in the limitation aspect the being easy to get property of developing country, and are suitable for family expenses.For example, for flame color, the invention provides and contain sodium organometallic compound family.Sodium acetate only is the sodium salt of the acid in the vinegar, and sodium is common in food, and certainly, sodium also is contained in the salt.Therefore, these compounds are suitable for family expenses.
In addition, also make great efforts in other respects to explore, that is, described material, must can obtain and can bear on price on the concentration level that uses except nontoxic at least at related concentration level.
Below, will be described preferable additives, described additive can be used as single additive or combined additive uses.
Odorant
About odorant, selected the compound family of seven class particularly suitables.These compounds are the thio-alcohols that start from thiomethyl alcohol, comprise ethyl, propyl group and butylation compound, especially isopropyl mercaptan, because it has extremely low odor threshold.Although hundreds of mercaptan is arranged, only minority mercaptan comes into operation, and the described mercaptan that comes into operation can fully volatilize emitting their smell, and can fully obtain supply and come into operation at an easy rate.
Second compounds is undersaturated mono carboxylic lipid acid, wherein preferably uses isovaleric acid.It is a kind of compound that has distinctive odor in rubbish gas and body odor.
The 3rd compounds can have synergy with flame color and taste.These compounds are aliphatic amide.Be preferably single methylamine and Trimethylamine 99.In some cases, Trimethylamine 99 can provide enough peculiar smell, flame color and taste, thereby makes a kind of reagent can realize three kinds of functions.
The 4th compounds is an aliphatic ketone, preferred here acetone and methylethylketone.Same, selected these aliphatic ketones, the especially latter can provide flame color, can cause flue dust sedimentary concentration on pot but be lower than.
The 5th class odorant is an aliphatic ether, wherein preferable methyl tertbutyl ether (MTBE, methyltertiary isobutyl ether).It has unique peculiar smell and some flame colors can be provided.It can obtain in the consumer's goods (gasoline) widely, and cost is very low, and cost is similar to premium motor fuel approximately.
The 6th class odorant is aliphatic saturated and unsaturated alcohol.Some selected members in this two family has very high peculiar smell, and has enough volatility to burn the absorption agent in the container.For example, can use amyl alcohol mixture or vinyl carbinol.They can provide flame color and have abominable taste.
The 7th compounds is an aliphatic acetates.Here be preferably ethyl acetate and pentyl acetate.
At last, can use the mixture class material that is mainly aliphatic hydrocarbon or alkene, wherein contain a spot of sulphur compound usually.Therefore, a kind of selection is to use gasoline, and this gasoline is by handling to use cracking process to make before removing sulphur compound.This material can provide peculiar smell, abominable taste and flame color, thereby makes its application have high synergetic effect.
Taste
Here, being difficult to find with seldom amount just can provide enough sharp flavours, and be easy to obtain, cheap and safe material.The preferred compound of selling with trade(brand)name BITREX is a denatonium benzoate at this compound chemically.
Yet,, can also use isovaleric acid in order to produce taste and to work in coordination with mutually with comprising peculiar smell and flame color.
Similarly, for these three kinds of functions, can also use amine.
This body colour
Here, the sapphirine that preferably on color, is different from any straight juice or soft drink or wine.Do not have blue straight juice, and have only few soft drink to have this blueness, even in this case, do not have the soft drink of mazarine and sapphirine yet.Can select to be called as the spirit soluble dyestuffs of Bayer (Bayer) company of SPECIALBRILLIANT BLUE FFR Liquid 40%01.Therefore be necessary strictly to select dyestuff, this dyestuff is pure dissolubility, and very strong, uses when a small amount of, for example can use as few as 0.01%, or this dyestuff of 0.01%~0.05%, just can form clarifying light tone, but not the muddy color of seizure light.This indicates this bottle liquid is cooking fuel, but not some other household product.
Flame color
Here, thus preferably be used for family, avoided toxic single arene compound of benzene by being substituted with methyl and/or ethyl.Preferred compound is toluene and ethylbenzene in such.Both all can extensively obtain and be with low cost.They can provide tangible flame color at weight or meausurement percentage ratio for 1%~3% very little consumption.Yet, also can use the simplification compound in the Bicyclic hydro carbons, i.e. naphthalene.A spot of naphthalene, promptly 0.5%~2%, just can produce unique peculiar smell and intense flame color.Can also use methylnaphthalene separately or use its mixture of isomers.In addition, can also use the toluene naphthalene.
For same case, aromatic hydrocarbon is unsuitable for family expenses.In the case, for flame color, can select to be easy to be dissolved in the sodium acetate of methyl alcohol.Also can use strontium acetate to obtain orange flame color.
Embodiment
(1), can use based on Bayer Brilliant Blue Dye FFR Liquid 40%, the Bitrex of 30ppm (weight) of 0.01 weight % of activeconstituents and the Trimethylamine of 39ppm (weight) when flame color when not being essential.Should be appreciated that owing to cost reason or other such as reasons such as statutory regulations, this tittle can be in variation in ± 39% the scope approximately.
(2) when flame color when being essential, can in composition (1), add the mixed methylnaphthalene of 1 weight %~3 weight % weight.
(3) using usually in the country of smelly oxidizing gases of mercaptan and/or liquefied petroleum gas (LPG) (LPG), in composition (1) or (2), can replace Trimethylamine with 10ppm~30ppm (weight) methyl mercaptan, wherein said variation must be satisfied suitable peculiar smell level.For example, the outdoor cooking needs 30ppm, and the indoor cooking only needs 10ppm.
(4), can preferably use the compd A stra Malachite Green S of 0.01 weight % so if in particular country, make blue fuel color improper for a certain reason.
(5) if the use of Bitrex is too expensive or do not needing under the stable condition, preferably add single methylamine of 10ppm~50ppm (weight), so that fishy smell flavor and fishy smell road to be provided.In the case, because a kind of material can satisfy two purposes, thereby can exempt the use of Trimethylamine 99.
(6) if in particular country, can't obtain mixed methylnaphthalene, can use surrogate that flame color is provided, depend on the degree of required flame color, can use 2%~5% toluene.

Claims (12)

1. stove or the employed liquid fuel combination of burner in the civil liquid fuel composition, particularly family, said composition contains:
At least a organic compound, in described compound, all basically carbon atoms all have been connected at least one Sauerstoffatom, so that during the burning of compound, basically only form carbonic acid gas and water, thus in products of combustion, avoided C-C formation and
One or more additives, described additive are used to provide at least a following feature: flame color, unpleasant and preferred violent pungent smell, fuel color and abominable taste.
2. fuel composition as claimed in claim 1 is characterized in that described organic compound is a methyl alcohol.
3. fuel composition as claimed in claim 1 or 2, it is characterized in that described organic compound also contain to a certain degree ethanol and Virahol at least a.
4. as the described fuel composition of above-mentioned arbitrary claim, it is characterized in that described fuel composition mainly based on other Fatty Alcohol(C12-C14 and C12-C18) blended methyl alcohol, described other Fatty Alcohol(C12-C14 and C12-C18) specifically are ethanol and Virahol, are preferably the methyl alcohol of 60 volume %~80 volume % and ethanol and/or the Virahol of 40 volume %~20 volume %.
5. as the described fuel composition of above-mentioned arbitrary claim, it is characterized in that described fuel composition contains is useful on the additive that peculiar smell is provided, this peculiar smell additive is at least a kind of in the following material: mercaptan, methyl mercaptan particularly, ethyl, propyl group and butylation compound, particularly isopropyl mercaptan; Unsaturated monocarboxylic lipid acid, preferred isovaleric acid; Aliphatic amide, preferred single methylamine and Trimethylamine 99; Aliphatic ketone, preferred acetone and methylethylketone; Aliphatic ether, the preferable methyl tertbutyl ether; Aliphatic saturated alcohols and unsaturated alcohol, preferred mixed amyl alcohol and vinyl carbinol; Aliphatic acetates, ethyl acetate and pentyl acetate; And aliphatic hydrocarbon and alkene, described aliphatic hydrocarbon and alkene use separately or use in the mixture that particularly contains a small amount of sulphur compound, preferably pass through the prepared gasoline of cracking process before removing sulphur compound.
6. fuel composition as claimed in claim 5 is characterized in that the content of described peculiar smell additive in described composition is 1ppm~30ppm, particularly 5ppm~20ppm, preferred 5ppm~10ppm.
7. as the described fuel composition of above-mentioned arbitrary claim, it is characterized in that described fuel composition contains is useful on the additive that taste is provided, this flavor additives is at least a kind of in the following material: denatonium benzoate, isovaleric acid, aliphatic amide and aliphatic hydrocarbon and alkene, preferred single methylamine of described aliphatic amide and Trimethylamine 99, described aliphatic hydrocarbon and alkene use separately or use with mixture.
8. fuel composition as claimed in claim 7 is characterized in that the content of described flavor additives in described composition is 1ppm~10ppm.
9. as the described fuel composition of above-mentioned arbitrary claim, it is characterized in that described fuel composition contains the additive that is used to described composition that color (this body colour or fuel color) is provided, described body colour additive is preferably the SPECIALBRILLANT BLUE FFR Liquid 40%0.1 of the spirit soluble dyestuffs of sapphirine, particularly Beyer Co., Ltd or the ASTRA BLUE BASE of Bayer.
10. fuel composition as claimed in claim 9 is characterized in that the content of described dyestuff in described composition is 0.01 weight %~0.1 weight %, is preferably 0.01 weight %~0.05 weight %.
11. as the described fuel composition of above-mentioned arbitrary claim, it is characterized in that described fuel composition comprises the additive that is used to flame that color (flame color) is provided, described flame color additive is at least a kind of in the following material: arene compound, especially be substituted with single arene compound of methyl and/or ethyl for fear of the toxicity of benzene, preferred toluene and ethylbenzene; Di-aromatics is preferably naphthalene, most preferably is the independent methylnaphthalene that uses or is the methylnaphthalene of isomer mixture; Sodium acetate; Strontium acetate; Isovaleric acid; And aliphatic hydrocarbon and alkene, described aliphatic hydrocarbon and alkene use separately or use with mixture.
12. fuel composition as claimed in claim 11 is characterized in that the content of described flame color additive in described composition is 10ppm~3 volume %, preferred 30ppm~3 volume %, most preferably 0.5~3 volume %, particularly 1~2 volume %.
CNB028296044A 2002-09-13 2002-10-24 Fuel composition Expired - Fee Related CN100357407C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02020685.0 2002-09-13
EP02020685 2002-09-13

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CN1668725A true CN1668725A (en) 2005-09-14
CN100357407C CN100357407C (en) 2007-12-26

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AU (1) AU2002354197A1 (en)
WO (1) WO2004024849A1 (en)
ZA (1) ZA200409613B (en)

Cited By (3)

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CN103087786A (en) * 2011-11-07 2013-05-08 陈华添 Synthetic liquid fuel and synthetic method thereof
TWI583782B (en) * 2013-04-22 2017-05-21 碧氫科技開發股份有限公司 Low carbon liquid fuel composition
USD1043243S1 (en) 2021-08-16 2024-09-24 Dometic Sweden Ab Cooktop grate

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LT2643437T (en) * 2010-11-25 2018-04-10 Gane Energy & Resources Pty Ltd Use of a methanol containing fuel composition and prozess for powering a compression ignition engine
US20130312728A1 (en) * 2012-05-25 2013-11-28 Green Hydrotec Inc. Liquid Fuel Combustion System
CN102732335A (en) * 2012-07-20 2012-10-17 天津林苑科技有限公司 Novel environment-friendly energy-saving biological alcohol oil
CN106369594A (en) * 2015-07-22 2017-02-01 郭成利 Boiler using alcohol-based liquid fuel
CN105733697A (en) * 2016-02-27 2016-07-06 安徽海德石油化工有限公司 Environment-friendly graft chloroprene rubber and corn oil hybrid fuel oil and preparation method thereof

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU903377A1 (en) * 1980-06-04 1982-02-07 Всесоюзный Научно-Исследовательский Институт Природных Газов "Вниигаз" Denaturating additive
DE3307091A1 (en) * 1983-03-01 1984-09-06 Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln FUEL AND USE THEREOF
US4932979A (en) * 1987-08-27 1990-06-12 Xl, Inc. Methanol fuel mixture
JPH06108065A (en) * 1992-01-31 1994-04-19 Mitsubishi Oil Co Ltd Gasoline/methanol-blended fuel for internal combustion engine
WO1998011176A1 (en) * 1996-09-11 1998-03-19 Tokai Corporation Liquid fuel for combustors, and combustor
PL187600B1 (en) * 1997-06-09 2004-08-31 Shell Int Research Liquefied natural gas composition
DE19956375C2 (en) * 1999-11-24 2001-10-25 Xcellsis Gmbh Flame dye additive for methanol to operate a fuel cell system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103087786A (en) * 2011-11-07 2013-05-08 陈华添 Synthetic liquid fuel and synthetic method thereof
TWI583782B (en) * 2013-04-22 2017-05-21 碧氫科技開發股份有限公司 Low carbon liquid fuel composition
USD1043243S1 (en) 2021-08-16 2024-09-24 Dometic Sweden Ab Cooktop grate

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