NL2008052C2 - A fuel composition. - Google Patents

A fuel composition. Download PDF

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Publication number
NL2008052C2
NL2008052C2 NL2008052A NL2008052A NL2008052C2 NL 2008052 C2 NL2008052 C2 NL 2008052C2 NL 2008052 A NL2008052 A NL 2008052A NL 2008052 A NL2008052 A NL 2008052A NL 2008052 C2 NL2008052 C2 NL 2008052C2
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Netherlands
Prior art keywords
oxygenate
fuel composition
fuel
composition according
iii
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NL2008052A
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Dutch (nl)
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Michael Dirk Boot
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Michael Dirk Boot
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1832—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/043—Kerosene, jet fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/0438—Middle or heavy distillates, heating oil, gasoil, marine fuels, residua
    • C10L2200/0446—Diesel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/0453—Petroleum or natural waxes, e.g. paraffin waxes, asphaltenes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C10L2200/0476—Biodiesel, i.e. defined lower alkyl esters of fatty acids first generation biodiesel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C10L2200/0484—Vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C10L2200/0492—Fischer-Tropsch products

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Description

Title: A fuel composition.
The present invention relates to a fuel composition, a method of operating an engine with a fuel composition and to an engine operated with a fuel composition, as well as to a 5 method for the preparation of a fuel composition.
US 2001/0232165 relates to a fuel that can be used as a replacement for conventional fossil-based fuels. The composition disclosed therein comprises mid flash point to low flashpoint naphtha; at least one alcohol having a ratio of between about 1 to about 4 carbon atoms to 1 hydroxyl functional group (-OH); at least one lubricating oil; and at least one oxygenated natural 10 aromatic compound. Examples of the oxygenated natural aromatic compound are methyl salicylate, eugenol, salicylic acid, cinnamaldehyde, thymol, benzaldehyde, salicylaldehyde, eugenol and their synthetic or natural analogues and derivatives. The amount of alcohol in the fuel is 10 -45 %.
US 2004/0088909 relates to a method for increasing combustion in an internal 15 combustion engine of a fuel to water and carbon dioxide, and reducing particulates from the combustion, which comprises: providing a composition which comprises: a liquid hydrocarbon as the fuel and between 0.1 and 30 percent by weight of diethyl succinate as a primary organic oxygenation source to run the engine so as to increase the combustion and reduce the particulates from the combustion.
20 US Patent No. 4,378,973 relates to a hydrocarbon base diesel fuel composition containing a minor, particulate-reducing amount of an additive consisting of a mixture of cyclohexane and an oxygenated compound which readily gives up oxygen during diesel engine combustion conditions. Examples of oxygenated compounds are aldehydes and ketones having from 3 to 16 carbon atoms such as acetone, isobutyl heptyl ketone, propionaldehyde, ethers 25 and cycloethers containing from 2 to 16 carbon atoms such as tetrahydrofuran, 1,2-butylene oxide and dimethyl ether, alcohols containing from 2 to 26 carbon atoms such as ethanol and 2-ethylhexanol.
US 2004/0128905 relates to a diesel base fuel that can be blended with certain combinations of fuel components to achieve an overall fuel composition having not only a 30 neutral or close to neutral density compared to the base fuel alone, but also neutral or close to neutral elastomer swell effects and/or neutral or better emissions (in particular NOx and/or particulate emissions) performance, said fuel composition comprising (i) a base fuel, (ii) a Fischer-Tropsch derived gas oil and (iii) an oxygenate. The oxygenate is an oxygen containing compound, preferably containing only carbon, hydrogen and oxygen, and may be a compound 2 containing one or more hydroxyl groups -OH, and/or one or more carbonyl groups C-O, and/or one or more ether groups -0-, and/or one or more ester groups -0(0)0-, containing from 1 to 18 carbon atoms. The Fischer-Tropsch derived component (ii) will be present at from 5 to 40% v/v of the overall composition and the oxygenate (iii) will be present at from 0.1 to 30% v/v of the 5 overall composition.
The present inventors found that a high amount of C1-C4 alcohols (e.g. methanol, ethanol, butanol) in a fuel composition has an adverse impact on the performance of the fuel, especially regarding the caloric value.
The object of the present invention is to provide a fuel composition in which the caloric 10 value meets the industrial standards.
Another object of the present invention is to provide a fuel composition in which compounds of natural origin can be blended without deteriorating the combustion properties.
The present invention relates to a fuel composition comprising i) a base fuel, ii) a C1-C4 alcohol or mixtures thereof, and iii) an oxygenate, wherein the iii) oxygenate is preferably a 15 natural oxygenate.
In an embodiment of the present invention the iii) oxygenate is chosen from the group of essential oils and derivatives of essential oils. An essential oil is a concentrated hydrophobic liquid containing volatile aroma compounds from plants. Essential oils are also known as volatile oils, ethereal oils or aetherolea, or simply as the "oil of' the plant from which they were 20 extracted, such as oil of clove. An oil is "essential" in the sense that it carries a distinctive scent, or essence, of the plant. Essential oils do not form a distinctive category for any medical, pharmacological, or culinary purpose.
Essential oils are generally extracted by distillation. Other processes include expression, or solvent extraction. They are used in perfumes, cosmetics, soaps and other products, for 25 flavoring food and drink, and for adding scents to incense household cleaning products.
In an embodiment according to the present invention the iii) oxygenate has a minimum higher heating value of 30 MJ/liter (MJ/I). The term “higher heating value” means here a value measured according to ASTM D 240 and is expressed in MJ/I. Such a higher heating value will have a positive influence on the distance that can be traveled in a vehicle on one liter of fuel, 30 when compared to C1-C4 alcohols.
The i) base fuel according to the present invention is chosen from the group of diesel fuel, jet fuel, kerosene, gasoline, bunker fuel, synthetic or Fischer-Tropsch fuels, vegetable oils (including from algae) or esterified derivatives thereof, and mixtures thereof.
In the present invention the composition of the fuel composition is preferably as follows: 3 i) base fuel being present in amount of 70 vol.% or higher, based on the final fuel composition, ii) C1-C4 alcohols or mixtures thereof being present in amount of 9.9 vol.% or less, based on the final fuel composition, 5 iii) oxygenate being present in amount of 2 - 30 vol. %, based on the final fuel composition.
Examples of preferred oxygenates are cyclic essential oils or cyclic components or cyclic derivatives thereof, especially orange oil, guaiac wood oil, cinnamon oil, anise oil, anisole, cinnamaldehyde, benzaldehyde, benzylalcohol, guaiacol, phenethylalcohol, acetophenone, or the mixtures thereof. In an embodiment of mixtures of pure essential oils, at least 50 vol.% of 10 the compounds must be of cyclic character, based on the final fuel composition.
The present invention furthermore relates to a method for operating an internal combustion engine with a fuel composition wherein said engine is operated with the present fuel composition as discussed before.
In addition, the present invention relates to a method for the preparation of a fuel 15 composition, wherein said method comprises blending a base fuel, comprising a C1-C4 alcohol or mixtures thereof, with an oxygenate, especially said oxygenate is chosen from the group of essential oils and derivatives of essential oils, as discussed before.
The present invention will be further understood from the following examples, which illustrate the effects of blending a base fuel with an oxygenate, especially said oxygenate is 20 chosen from the group of essential oils and derivatives of essential oils, on the properties and engine performance of the resultant fuel composition as compared to those of the base fuel alone.
The sole Figure is a graph showing soot (expressed in Filter Smoke Number(FSN)) and Nox (expressed in g/kWh) emissions.
25 Example 1
The Higher Heating Values (H.H.V.) of a number of neat aroma compounds, ethanol and gasoline have been measured according to ASTM D 240 (Table 1).
The Research Octane Number (R.O.N.) of a number of aroma compounds and ethanol in a 10 vol.-% solution in gasoline have been measured according to ASTM D2699 (Table 1).
30 All aroma compounds have a higher H.H.V. than gasoline and a significantly higher value than ethanol (at least 37% higher). When added to gasoline, all studied aroma compounds and ethanol, increased the R.O.N. of the resulting blend.
4
Table 1 below relates to H.H.V. of various neat aroma compounds and ethanol. R.O.N. of various aroma compounds and ethanol blended to a 10 vol.-% solution in commercial gasoline
Table 1.
Name CAS no. H.H.V. [MJ/I] R.O.N. of 10 vol.-% of neat compound in compound gasoline
Anisole 100-66-3 34.8 97.4
Benzaldehyde 100-52-7 34.6 98.5
Benzylalcohol 100-51-6 36.1 96.9
Phenethylethanol 60-12-8 36.5 96.9
Acetophenone 98-86-2 35.5 96.1
Cinnamaldehyde 104-55-2 36.9 96.3
Ethanol 64-17-5 23.4 98.3
Gasoline - 33.1 95.0 (reference) 5
Example 2
The Figure shows the soot (expressed in Filter Smoke Number) and NOx (expressed in g/kWh) emissions of a heavy-duty diesel engine operating at a load close to that of highway 10 cruising for various fuel injection timings (SOI).
From the Figure it is clear that when three specific oxygenates according to the present invention are added to diesel fuel at concentration of around 15 vol.-% (dissolved in the base diesel fuel), each results in a considerably more favorable soot-NOx trade-off than is the case for the base diesel fuel.
15

Claims (15)

1. Brandstofsamenstelling, omvattende i) een basisbrandstof ii) een C1-C4 alcohol of mengsels hiervan en iii) een oxygenaat.A fuel composition comprising i) a base fuel ii) a C 1 -C 4 alcohol or mixtures thereof and iii) an oxygenate. 2. Brandstofsamenstelling volgens conclusie 1, met het kenmerk, dat het iii) oxygenaat een natuurlijk oxygenaat is.Fuel composition according to claim 1, characterized in that the iii) oxygenate is a natural oxygenate. 3. Brandstofsamenstelling volgens een of meer van de voorgaande conclusies, met het kenmerk, dat het iii) oxygenaat een minimum hogere verwarmingswaarde van 30 MJ/I gemeten volgens ASTM D240, bezit.Fuel composition according to one or more of the preceding claims, characterized in that the iii) oxygenate has a minimum higher heating value of 30 MJ / I measured according to ASTM D240. 4. Brandstofsamenstelling volgens een of meer van de voorgaande conclusies, met het kenmerk, dat het iii) oxygenaat is gekozen uit de groep van essentiële oliën en afgeleiden van essentiële oliën.Fuel composition according to one or more of the preceding claims, characterized in that the iii) oxygenate is selected from the group of essential oils and derivatives of essential oils. 5. Brandstofsamenstelling volgens een of meer van de voorgaande conclusies, met het kenmerk, dat de i) basisbrandstof is gekozen uit de groep van 15 dieselbrandstof, vliegtuigbrandstof, kerosine,, benzine, bunkerbrandstof, synthetische of Fischer-Tropsch brandstof, plantaardige oliën (inclusief afkomstig van algen) of veresterde afgeleiden hiervan, en mengsels hiervan.5. Fuel composition according to one or more of the preceding claims, characterized in that the i) base fuel is selected from the group of diesel fuel, aircraft fuel, kerosene, gasoline, bunker fuel, synthetic or Fischer-Tropsch fuel, vegetable oils (including derived from algae) or esterified derivatives thereof, and mixtures thereof. 6. Brandstofsamenstelling volgens een of meer van de voorgaande conclusies, met het kenmerk, dat de basisbrandstof aanwezig is in een hoeveelheid 20 van 70 vol.% of hoger, op basis van de uiteindelijke brandstofsamenstelling.6. Fuel composition according to one or more of the preceding claims, characterized in that the base fuel is present in an amount of 70% by volume or higher, based on the final fuel composition. 7. Brandstofsamenstelling volgens een of meer van de voorgaande conclusies, met het kenmerk, dat de ii) C1-C4 alcohol of mengsels hiervan aanwezig is in een hoeveelheid van 9,9 vol.% of minder, op basis van de uiteindelijke brandstofsamenstelling.Fuel composition according to one or more of the preceding claims, characterized in that the ii) C 1 -C 4 alcohol or mixtures thereof is present in an amount of 9.9% by volume or less, based on the final fuel composition. 8. Brandstofsamenstelling volgens een of meer van de voorgaande conclusies, met het kenmerk, dat het oxygenaat een cyclische structuur bezit.Fuel composition according to one or more of the preceding claims, characterized in that the oxygenate has a cyclic structure. 9. Brandstofsamenstelling volgens een of meer van de voorgaande conclusies, met het kenmerk, dat het iii) oxygenaat aanwezig is in een hoeveelheid van 2-30 vol.%, op basis van de uiteindelijke brandstofsamenstelling.Fuel composition according to one or more of the preceding claims, characterized in that the iii) oxygenate is present in an amount of 2-30% by volume, based on the final fuel composition. 10. Brandstofsamenstelling volgens een of meer van de voorgaande conclusies, met het kenmerk, dat het iii) oxygenaat is gekozen uit de groep van sinaasappelolie, guaiac hout olie, kaneelolie, anijsolie, anisol, kaneelaldehyde, benzaldehyde, benzylalcohol, guaiacol, fenethylalcohol en acetofenon, of mengsels 2008052 hiervan.Fuel composition according to one or more of the preceding claims, characterized in that the iii) oxygenate is selected from the group of orange oil, guaiac wood oil, cinnamon oil, anise oil, anisol, cinnamaldehyde, benzaldehyde, benzyl alcohol, guaiacol, phenethyl alcohol and acetophenone or mixtures 2008052 thereof. 11. Werkwijze voor het bedrijven van een inwendige verbrandingsmotor met een brandstofsamenstelling, met het kenmerk, dat de motor wordt bedreven met een brandstofsamenstelling volgens een of meer van de voorgaande conclusies.A method for operating an internal combustion engine with a fuel composition, characterized in that the engine is operated with a fuel composition according to one or more of the preceding claims. 12. Werkwijze voor de bereiding van een brandstofsamenstelling, met het kenmerk, dat de werkwijze omvat het mengen van een basisbrandstof, omvattende een C1-C4 alcohol of mengsels hiervan, met een oxygenaat, waarbij het oxygenaat een natuurlijk oxygenaat is.A method for the preparation of a fuel composition, characterized in that the method comprises mixing a base fuel comprising a C 1 -C 4 alcohol or mixtures thereof with an oxygenate, wherein the oxygenate is a natural oxygenate. 13. Werkwijze volgens conclusie 12, met het kenmerk, dat het 10 oxygenaat een minimum hogere verwarmingswaarde van 30 MJ/I, gemeten volgens ASTM D 240, bezit.13. Method according to claim 12, characterized in that the oxygenate has a minimum higher heating value of 30 MJ / I, measured according to ASTM D 240. 14. Werkwijze volgens een of meer van de voorgaande conclusies 12-13, met het kenmerk, dat het oxygenaat is gekozen uit de groep van essentiële oliën en afgeleiden van essentiële oliën.Method according to one or more of the preceding claims 12-13, characterized in that the oxygenate is selected from the group of essential oils and derivatives of essential oils. 15. Werkwijze volgens een of meer van de conclusies 12-14, met het kenmerk, dat het oxygenaat is gekozen uit de groep van sinaasappelolie, guaiac hout olie, kaneelolie, anijsolie, anisol, kaneelaldehyde, benzaldehyde, benzylalcohol, guaiacol, fenethylalcohol en acetofenon, of mengsels hiervan. 20 2008052Process according to one or more of claims 12 to 14, characterized in that the oxygenate is selected from the group of orange oil, guaiac wood oil, cinnamon oil, anise oil, anisol, cinnamaldehyde, benzaldehyde, benzyl alcohol, guaiacol, phenethyl alcohol and acetophenone , or mixtures thereof. 20, 2008052
NL2008052A 2011-12-29 2011-12-29 A fuel composition. NL2008052C2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190136145A1 (en) * 2016-04-26 2019-05-09 Neste Oyj Fuel blend comprising a mixture of aryl ethers

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190136145A1 (en) * 2016-04-26 2019-05-09 Neste Oyj Fuel blend comprising a mixture of aryl ethers
US11401477B2 (en) * 2016-04-26 2022-08-02 Neste Oyj Fuel blend comprising a mixture of aryl ethers

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