CN1664010A - Halogen-free composite flame retardant for rubber members on rail vehicle - Google Patents
Halogen-free composite flame retardant for rubber members on rail vehicle Download PDFInfo
- Publication number
- CN1664010A CN1664010A CN 200510038307 CN200510038307A CN1664010A CN 1664010 A CN1664010 A CN 1664010A CN 200510038307 CN200510038307 CN 200510038307 CN 200510038307 A CN200510038307 A CN 200510038307A CN 1664010 A CN1664010 A CN 1664010A
- Authority
- CN
- China
- Prior art keywords
- parts
- flame retardant
- halogen
- silicone resin
- aluminium hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 24
- 229920001971 elastomer Polymers 0.000 title claims abstract description 21
- 239000002131 composite material Substances 0.000 title claims abstract description 18
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 16
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims abstract description 32
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 30
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 30
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 235000019359 magnesium stearate Nutrition 0.000 claims abstract description 20
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920002050 silicone resin Polymers 0.000 claims description 29
- 239000004615 ingredient Substances 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 description 8
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000003610 charcoal Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- YPUVTLQZHBUGSK-UHFFFAOYSA-K aluminum;trihydroxide;trihydrate Chemical compound O.O.O.[OH-].[OH-].[OH-].[Al+3] YPUVTLQZHBUGSK-UHFFFAOYSA-K 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a halogen-free composite flame retardant for rubber members on rail vehicle, which is prepared from the weight portions of the following active ingredients, silicon resin 10-30 parts, magnesium stearate 2-7 parts, zinc borate 5-30 parts, coated red phosphorus 5-25 parts, aluminium hydroxide 20-80 parts.
Description
Technical field:
The present invention relates to a kind of fire retardant, relate in particular to a kind of halogen-free composite flame retardant for rubber members on rail vehicle.Be mainly used in door and window, air-conditioning system and floor rubber seal and shock absorber part fire-retardant of subway, light rail and high-speed railway railway car.
Background technology:
At present, be usually used in fire retardant decabromodiphynly oxide (DBDPO), DCRP (DCRP), hexabromocyclododecane (HBCD), clorafin (CP) of rubber members on rail vehicle etc., composite flame-retardant agent mainly comprises antimonous oxide (Sb
2O
3) with decabromodiphynly oxide (DBDPO), antimonous oxide (Sb
2O
3) and hexabromocyclododecane (HBCD) and antimonous oxide (Sb
2O
3) antimony-halogen flame is composite forms with clorafin (CP) etc.Though its flame retardant resistance is good, has the following disadvantages: produce during by the rubber members on rail vehicle burning that adds above two based flame retardants that smog is big, hydrogenchloride (HCL), hydrogen bromide (HBr) and other poisonous chlorine-containing organic compounds of strong toxicity.Human health and environment are worked the mischief.
Goal of the invention:
The objective of the invention is to overcome above-mentioned deficiency, a kind of not halogen-containing halogen-free composite flame retardant for rubber members on rail vehicle is provided.
The object of the present invention is achieved like this: a kind of halogen-free composite flame retardant for rubber members on rail vehicle is characterized in that it is to form by the weight part of following effective ingredient is composite:
10～30 parts of silicone resin
2～7 parts of Magnesium Stearates
5～30 parts of zinc borates
5～25 parts of encapsulated red phosphorus
20～80 parts in aluminium hydroxide.
More preferably composite weight part of the present invention is:
20～30 parts of silicone resin
5～7 parts of Magnesium Stearates
5～15 parts of zinc borates
10～15 parts of encapsulated red phosphorus
30～50 parts in aluminium hydroxide.
Most preferably composite weight part of the present invention is:
10～20 parts of silicone resin
4～6 parts of Magnesium Stearates
20～25 parts of zinc borates
20～25 parts of encapsulated red phosphorus
50～70 parts in aluminium hydroxide.
The effect and the beneficial effect of the each component among the present invention see the following form
| Chemical name | Effect | Effect |
| Silicone resin | Silicone resin can form the charcoal layer with rubber, and then stops the development of smoke and fire flame.The consistency of silicone resin and rubber is fine simultaneously, can improve the consistency of other fire retardant and rubber, to improve the physical and mechanical properties of material.The silicone resin consumption must be greater than 7 parts, otherwise it is inoperative, but consumption too much (above 35 parts) not only can not improve the flame retardant properties of material, and can cause the material heat resisting temperature to reduce, mobile high and be difficult to processing. | Oxygen index |
| 4 parts of 10 part of 24 Magnesium Stearates of 0 part of silicone resin of 10 part of 22 Magnesium Stearate of 0 part of silicone resin of 0 part of 18 Magnesium Stearate of silicone resin | ||
| Magnesium Stearate | Be used in combination with silicone resin, promote the dispersion of silicone resin in material, with the charcoal layer structure of optimization silicone resin formation, and improve processing characteristics.But behind the consumption too much (more than 10 parts), inoperative to flame retardant resistance, and can make rubber cross soft and easy incipient scorch. | |
| Aluminium hydroxide | Oxygen index |
| Aluminium hydroxide and silicone resin have synergistic effect.When aluminium hydroxide and silicone resin are shared, aluminium hydroxide press down cigarette and fire retardation better, silicone resin can improve the consistency of aluminium hydroxide and rubber, improve mechanical property, silicone resin can solve sizing material bad problem of rubber mobility after having added more aluminium hydroxide.Aluminium hydroxide must be greater than 20 parts, otherwise it is inoperative, but consumption is (more than 70 parts) too much, physical and mechanical properties descends too many, and flowability is too poor. | 60 part 26 in 30 part of 25 aluminium hydroxide of 0 part of 24 aluminium hydroxide of 4 parts of aluminium hydroxides of 10 parts of Magnesium Stearates of silicone resin | |
| Zinc borate | Under flame interaction, melt, form the coating layer of vitreous state, and dehydration at high temperature, evaporation of water heat absorption impelling burning is from putting out.Zinc borate after the dehydration promotes into charcoal simultaneously, the charcoal layer not only is difficult to light and burn, and descends owing to its isolation action makes the formation speed of polymer unwinds and inflammable gas.Zinc borate can improve the flame retardant properties of aluminium hydroxide, reduces the generation of smog simultaneously. | 30 part 28 100 of 10 parts of 27/Firebrake ZB of 5 parts of 26.5/Firebrake ZBs of 0 part of 26 120 Firebrake ZB of 30 parts of Firebrake ZBs of 4 parts of aluminium hydroxides of 10 parts of dolomols of oxygen index (OI) smoke density silicones |
| Encapsulated red phosphorus | Form white phosphorus 400 ℃-500 ℃ following red phosphorus depolymerization, white phosphorus is oxidized to the oxygen acid of the phosphorus of viscosity, it both can be covered in by the fire retardant material surface, can quicken dehydration carbonization at material surface again, the liquid film of formation and charcoal layer just can be with the oxygen of outside, volatile fuel and heat separate to interrupt burning with the superpolymer matrix of inside.It can improve the thermostability of rubber simultaneously, with the generation of minimizing volatile fuel, thereby suppresses burning.Encapsulated red phosphorus and aluminium hydroxide have synergistic effect, encapsulated red phosphorus can improve the fire retardation of aluminium hydroxide, aluminium hydroxide can reduce the living cigarette of encapsulated red phosphorus, thereby learn from other's strong points to offset one's weaknesses mutually, form a flame retardancy and smoke suppression system efficiently.Encapsulated red phosphorus consumption excessive (more than 30 parts) can reduce flame retardant properties on the contrary. | 10 part 33 of 5 part of 29 encapsulated red phosphorus of 0 part of 27 encapsulated red phosphorus of 5 parts of encapsulated red phosphorus of 30 parts of Firebrake ZBs of 4 parts of aluminium hydroxides of 10 parts of dolomols of oxygen index (OI) silicones |
Net effect: because the present invention's Halogen not, produce when therefore adding the rubber members on rail vehicle burning of this fire retardant that smog is very little, toxicity is extremely low, can not work the mischief to human health and environment.The rubber parts flame retardant properties that adds this fire retardant reaches the requirement of normes Francaises NF F16-101 " rail vehicles-combustionproperty-material is selected ".That is:
Embodiment:
Example 1:
Respectively get silicone resin 10kg, Magnesium Stearate 4kg, zinc borate 5kg, encapsulated red phosphorus 10kg and aluminium hydroxide 30kg mixing and stirring by proportioning and be re-dubbed halogen-free composite flame retardant for rubber members on rail vehicle.
Example 2:
Respectively get silicone resin 15kg, Magnesium Stearate 5kg, zinc borate 10kg, encapsulated red phosphorus 15kg and aluminium hydroxide 40kg by proportioning, all the other are with example 1.
Example 3:
Respectively get silicone resin 10kg, Magnesium Stearate 3kg, zinc borate 15kg, encapsulated red phosphorus 20kg and aluminium hydroxide 30kg by proportioning, all the other are with example 1.
Example 4:
Respectively get silicone resin 20kg, Magnesium Stearate 6kg, zinc borate 10kg, encapsulated red phosphorus 20kg and aluminium hydroxide 50kg by proportioning, all the other are with example 1.
Example 5:
Respectively get silicone resin 30kg, Magnesium Stearate 7kg, zinc borate 30kg, encapsulated red phosphorus 25kg and aluminium hydroxide 60kg by proportioning, all the other are with example 1.
Example 6:
Respectively get silicone resin 10kg, Magnesium Stearate 2kg, zinc borate 20kg, encapsulated red phosphorus 25kg and aluminium hydroxide 80kg by proportioning, all the other are with example 1.
Example 7:
Respectively get silicone resin 30kg, Magnesium Stearate 7kg, zinc borate 30kg, encapsulated red phosphorus 5kg and aluminium hydroxide 20kg by proportioning, all the other are with example 1.
Example 8:
Respectively get silicone resin 10kg, Magnesium Stearate 2kg, zinc borate 25kg, encapsulated red phosphorus 25kg and aluminium hydroxide 70kg by proportioning, all the other are with example 1.
Claims (3)
1, a kind of halogen-free composite flame retardant for rubber members on rail vehicle is characterized in that it is to form by the weight part of following effective ingredient is composite:
10～30 parts of silicone resin
2～7 parts of Magnesium Stearates
5～30 parts of zinc borates
5～25 parts of encapsulated red phosphorus
20～80 parts in aluminium hydroxide.
2, a kind of halogen-free composite flame retardant for rubber members on rail vehicle according to claim 1 is characterized in that it is to form by the weight part of following effective ingredient is composite:
20～30 parts of silicone resin
5～7 parts of Magnesium Stearates
5～15 parts of zinc borates
10～15 parts of encapsulated red phosphorus
30～50 parts in aluminium hydroxide.
3, a kind of halogen-free composite flame retardant for rubber members on rail vehicle according to claim 1 is characterized in that it is to form by the weight part of following effective ingredient is composite:
10～20 parts of silicone resin
4～6 parts of Magnesium Stearates
20～25 parts of zinc borates
20～25 parts of encapsulated red phosphorus
50～70 parts in aluminium hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510038307 CN1269906C (en) | 2005-02-07 | 2005-02-07 | Halogen-free composite flame retardant for rubber members on rail vehicle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510038307 CN1269906C (en) | 2005-02-07 | 2005-02-07 | Halogen-free composite flame retardant for rubber members on rail vehicle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1664010A true CN1664010A (en) | 2005-09-07 |
| CN1269906C CN1269906C (en) | 2006-08-16 |
Family
ID=35035330
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510038307 Expired - Fee Related CN1269906C (en) | 2005-02-07 | 2005-02-07 | Halogen-free composite flame retardant for rubber members on rail vehicle |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1269906C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008037168A1 (en) * | 2006-09-28 | 2008-04-03 | Shenzhen Oceanpower Industrial Co., Ltd. | A flame retardant modifier for asphalt |
| CN102134353A (en) * | 2011-03-17 | 2011-07-27 | 江阴海达橡塑股份有限公司 | Extruded flame-retarding environmentally-friendly ethylene propylene diene monomer rubber damping pad for rail car |
| CN102220066A (en) * | 2011-05-16 | 2011-10-19 | 南京赢嘉包装有限责任公司 | Wood-plastic composite inflaming-retarding coating containing inorganic fire retardant |
| CN104231630A (en) * | 2014-09-20 | 2014-12-24 | 来安县亨通橡塑制品有限公司 | Modified flame retardant for rubber floor |
| CN109438784A (en) * | 2018-12-24 | 2019-03-08 | 常州轻工职业技术学院 | Primary spring fire-retardant rubber material based on railcar |
-
2005
- 2005-02-07 CN CN 200510038307 patent/CN1269906C/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008037168A1 (en) * | 2006-09-28 | 2008-04-03 | Shenzhen Oceanpower Industrial Co., Ltd. | A flame retardant modifier for asphalt |
| CN102134353A (en) * | 2011-03-17 | 2011-07-27 | 江阴海达橡塑股份有限公司 | Extruded flame-retarding environmentally-friendly ethylene propylene diene monomer rubber damping pad for rail car |
| CN102220066A (en) * | 2011-05-16 | 2011-10-19 | 南京赢嘉包装有限责任公司 | Wood-plastic composite inflaming-retarding coating containing inorganic fire retardant |
| CN102220066B (en) * | 2011-05-16 | 2014-11-12 | 南京赢嘉包装有限责任公司 | Wood-plastic composite inflaming-retarding coating containing inorganic fire retardant |
| CN104231630A (en) * | 2014-09-20 | 2014-12-24 | 来安县亨通橡塑制品有限公司 | Modified flame retardant for rubber floor |
| CN109438784A (en) * | 2018-12-24 | 2019-03-08 | 常州轻工职业技术学院 | Primary spring fire-retardant rubber material based on railcar |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1269906C (en) | 2006-08-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: JIANGYIN HAIDA RUBBER AND PLASTIC CO., LTD. Free format text: FORMER NAME OR ADDRESS: JIANGYIN HAIDA RUBBER + PLASTIC GROUP |
|
| CP01 | Change in the name or title of a patent holder |
Address after: Jiangsu province Jiangyin city Zhouzhuang town Hai Da Lu No. 1 Patentee after: Jiangyin Haida Rubber & Plastic Co., Ltd. Address before: Jiangsu province Jiangyin city Zhouzhuang town Hai Da Lu No. 1 Patentee before: Jiangyin Haida Rubber-Plastic Group Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060816 Termination date: 20170207 |