CN1653166A - Cold rolling oil composition - Google Patents
Cold rolling oil composition Download PDFInfo
- Publication number
- CN1653166A CN1653166A CNA038107759A CN03810775A CN1653166A CN 1653166 A CN1653166 A CN 1653166A CN A038107759 A CNA038107759 A CN A038107759A CN 03810775 A CN03810775 A CN 03810775A CN 1653166 A CN1653166 A CN 1653166A
- Authority
- CN
- China
- Prior art keywords
- oil composition
- diester
- rolling
- lubricating oil
- aliphatic dicarboxylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 42
- 239000010731 rolling oil Substances 0.000 title abstract description 10
- 238000005097 cold rolling Methods 0.000 title abstract description 4
- 150000005690 diesters Chemical class 0.000 claims abstract description 29
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002199 base oil Substances 0.000 claims abstract description 8
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 7
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 7
- -1 phosphorus series compound Chemical class 0.000 claims description 41
- 239000010687 lubricating oil Substances 0.000 claims description 25
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 18
- 125000001931 aliphatic group Chemical group 0.000 claims description 14
- 150000002191 fatty alcohols Chemical class 0.000 claims description 10
- 235000011007 phosphoric acid Nutrition 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 7
- 238000009432 framing Methods 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 abstract description 45
- GHYOCDFICYLMRF-UTIIJYGPSA-N (2S,3R)-N-[(2S)-3-(cyclopenten-1-yl)-1-[(2R)-2-methyloxiran-2-yl]-1-oxopropan-2-yl]-3-hydroxy-3-(4-methoxyphenyl)-2-[[(2S)-2-[(2-morpholin-4-ylacetyl)amino]propanoyl]amino]propanamide Chemical compound C1(=CCCC1)C[C@@H](C(=O)[C@@]1(OC1)C)NC([C@H]([C@@H](C1=CC=C(C=C1)OC)O)NC([C@H](C)NC(CN1CCOCC1)=O)=O)=O GHYOCDFICYLMRF-UTIIJYGPSA-N 0.000 abstract 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 15
- 238000007761 roller coating Methods 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 7
- 239000007769 metal material Substances 0.000 description 7
- 238000003801 milling Methods 0.000 description 6
- 239000002480 mineral oil Substances 0.000 description 6
- 235000010446 mineral oil Nutrition 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- VDTIMXCBOXBHER-UHFFFAOYSA-N hydroxy-bis(sulfanyl)-sulfanylidene-$l^{5}-phosphane Chemical compound OP(S)(S)=S VDTIMXCBOXBHER-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000003014 phosphoric acid esters Chemical class 0.000 description 4
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 229910052728 basic metal Inorganic materials 0.000 description 3
- 150000003818 basic metals Chemical class 0.000 description 3
- 239000010779 crude oil Substances 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000013518 transcription Methods 0.000 description 2
- 230000035897 transcription Effects 0.000 description 2
- WELJZGZTFLZLRE-KVVVOXFISA-N (z)-octadec-9-enoic acid;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O WELJZGZTFLZLRE-KVVVOXFISA-N 0.000 description 1
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 1
- GPZYYYGYCRFPBU-UHFFFAOYSA-N 6-Hydroxyflavone Chemical compound C=1C(=O)C2=CC(O)=CC=C2OC=1C1=CC=CC=C1 GPZYYYGYCRFPBU-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 241001649081 Dina Species 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- NAGJZTKCGNOGPW-UHFFFAOYSA-K dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [O-]P([O-])([S-])=S NAGJZTKCGNOGPW-UHFFFAOYSA-K 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- MOYKHGMNXAOIAT-JGWLITMVSA-N isosorbide dinitrate Chemical compound [O-][N+](=O)O[C@H]1CO[C@@H]2[C@H](O[N+](=O)[O-])CO[C@@H]21 MOYKHGMNXAOIAT-JGWLITMVSA-N 0.000 description 1
- 229960000201 isosorbide dinitrate Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- IIGMITQLXAGZTL-UHFFFAOYSA-N octyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCC IIGMITQLXAGZTL-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000004867 thiadiazoles Chemical class 0.000 description 1
- 150000003580 thiophosphoric acid esters Chemical class 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/043—Ammonium or amine salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
A cold rolling oil composition comprising a base oil, 0.5 to 30% by mass of a diester having a C group in which the main skeleton is a saturated or unsaturated hydrocarbon chain, and 0.01 to 5.0% by mass of a phosphorus compound12～28Aliphatic dicarboxylic acid and C1～9The aliphatic alcohol of (1). The cold rolling oil composition has excellent hot scuffing resistance (rolling property), and can suppress dullness of a rolled sheet.
Description
Technical field
The present invention relates to the cold-rolled lubricating oil composition, in more detail, relate to when heat-resisting scratch performance (rolling property) is improved, can suppress the cold-rolled lubricating oil composition of the dim spot (gloss is bad) that rolls plate of stainless steel especially.
Background technology
In metallic substance rolling, produce on the part working roll that rolling stock passes through when normally being rolled with the painted phenomenon that is called the roller coating of certain tone.Because this working roll usually directly contacts with rolling stock, so the surface shape of this roller coating and rolling property or rolled product has much relations.
Because the rolled metal material, above-mentioned working roll is because of heat of friction or the thermal expansion of processing heat, so the rolling pressure of plate width is inhomogeneous, is easy to generate roller coating spot.This coating spot makes the surface of milled sheet produce spot by transcription, causes dim spot, becomes big problem in the stainless steel and other metal materials that requires extra high surface quality rolling.
In hard metallic substance such as stainless steel rolling, how will reduce with the contact area of material, can be used for working roll at the path roller that unit surface applies high loading.But if the roller footpath is little, the roller self rigidity is low, need carry out reinforcement with the intermediate roll or the support roll in big footpath.
As the milling train of this form, the milling train of known for example multiple roll type.In the milling train of this multiple roll type, support roll is divided into roller more than 5 at direction of principal axis, and they are called as the sectional type support roll.This sectional type support roll has the crown that is made of particular design cylinder roller bearing and adjusts function, can operate the extrusion capacity of each bearing independently of one another by eccentric bush mechanism, on working roll, can make various crown patterns, also can control the shape of rolling plate.In the milling train of sectional type support roll form, exist by intermediate roll sectional type support roll part that contacts with working roll and the part that does not contact, be that reason makes above-mentioned roller coating produce the situation of spot sometimes with it.In addition, thus this coating spot is rolled on the plate surface reason that produces dim spot by transcription to rolling to become on the plate.
On the other hand, the performance as the ROLLING OIL of the rolling processing that is used for this metallic substance requires rolling property excellence, promptly obtains high rolling rate under low rolling loading, and does not also produce heat scratch etc. under harsh condition.
Summary of the invention
Under this situation, the object of the present invention is to provide the cold-rolled lubricating oil composition, the dim spot of the milled sheet that its roller coating spot that can alleviate the sectional type support roll produces, alleviating the dim spot of the milled sheet due to the roller coating spot on the width of working roll and improve scuff resistance can (rolling property).
Present inventors are in order to develop the cold-rolled lubricating oil composition with above-mentioned excellent function, carried out deep repeatedly research, it found that: with the ratio of regulation contain base oil, carbon number at the diester by branch-like aliphatic dicarboxylic acid and the preparation of straight chain shape fatty alcohol of specific scope, carbon number at the monoesters of specified range and the composition of phosphorus series compound, can realize above-mentioned purpose by said composition.The present invention finishes based on this knowledge.
That is, the invention provides:
(1) cold-rolled lubricating oil composition is characterized in that: contain the C that base oil, (A) main framing are made of saturated or undersaturated hydrocarbon chain
6～28Aliphatic dicarboxylic acid and C
1～9Diester 0.5～30 quality % and (C) phosphorus series compound 0.01～5.0 quality % of fatty alcohol preparation.
(2) above-mentioned (1) described cold-rolled lubricating oil composition, wherein the hydrocarbon chain of aliphatic dicarboxylic acid is a branch-like in the diester of (A) component.
(3) above-mentioned (1) described cold-rolled lubricating oil composition is characterized in that: also contain (B) C
13～48Monoesters 0.5～40 quality %.
(4) above-mentioned (1) described cold-rolled lubricating oil composition, wherein the aliphatic dicarboxylic acid in the diester of (A) component is C
12～28Aliphatic dicarboxylic acid and C
1～6The diester of straight chain shape fatty alcohol preparation.
(5) above-mentioned (1) described cold-rolled lubricating oil composition, wherein the aliphatic dicarboxylic acid in the diester of (A) component is a saturated aliphatic dicarboxylic acids.
(6) above-mentioned (1) described cold-rolled lubricating oil composition, wherein the phosphorus series compound of (C) component is at least a for what choose from ortho-phosphoric acid ester, its amine salt and alkylthio phosphoric acid ester.
(7) above-mentioned (1) described cold-rolled lubricating oil composition, wherein the phosphorus series compound of (C) component is the amine salt of ortho-phosphoric acid ester.
Embodiment
In cold-rolled lubricating oil composition of the present invention, can use mineral oil and/or synthetic oil as base oil.
As above-mentioned mineral oil, can enumerate various mineral oil.For example can enumerate paraffin base system crude oil, middle base system crude oil or naphthyl is that crude oil carries out air distillation or the residual oil of air distillation is carried out the distilled oil that underpressure distillation obtains, or according to well-established law to its refining treated oil that obtains, for example solvent-refined oil, hydrofined oil, dewaxing treatment oil, clay treatment wet goods.
In addition, as synthetic oil, can use for example C
8～14Poly-alpha-olefin, olefin copolymer (for example ethylene-propylene copolymer etc.), or branched olefin or their hydride such as polybutene, polypropylene, and polyol ester ester compound, alkylbenzenes etc. such as (fatty acid ester of TriMethylolPropane(TMP), the fatty acid esters of tetramethylolmethane etc.).
In the present invention, as base oil, can use above-mentioned mineral oil a kind, also can be used in combination more than 2 kinds, can use above-mentioned synthetic oil a kind, also can be used in combination more than 2 kinds.In addition, also this mineral oil also can be used more than a kind with synthetic oil more than a kind.In addition, as this base oil, the kinematic viscosity that preferred temperature is 40 ℃ is at 1～30mm
2In the scope of/s.If the not enough 1mm of this kinematic viscosity
2/ s, flash-point is low, and the danger that produces fire etc. owing to igniting might increase, on the other hand, if above 30mm
2/ s becomes sometimes and rolls plate surface to produce oil recessed, and glossiness descends or produces the reason of the unfavorable conditions such as dislocation of curling.Preferred kinematic viscosity is 4～20mm
2/ s.
In composition of the present invention,, use the C that constitutes by saturated or undersaturated hydrocarbon chain from main framing as (A) component
6～28Aliphatic dicarboxylic acid and C
1～9The diester of fatty alcohol preparation.
If above-mentioned aliphatic dicarboxylic acid carbon number less than 6, then heat-resisting scratch poor performance, on the other hand, and if surpass 28, when particularly using low viscous base oil, the solvability variation of diester.Preferred carbon number is 12～28, more preferably 14～24, preferred especially 16～20.
In addition, this aliphatic dicarboxylic acid preferably has side chain, owing to have side chain, its advantage is: the solvability of diester improves, and can easily prepare the rolling oil composition with desired properties.
In the present invention,, can use saturated and undersaturated aliphatic dicarboxylic acid, wherein preferred saturated aliphatic dicarboxylic acids as above-mentioned aliphatic dicarboxylic acid.As this saturated aliphatic dicarboxylic acids, preferably enumerate for example general formula (I)
(in the formula, k represents 0～3 integer, and m and n represent 1～23 integer respectively, and k, m and n add up to 8～24 integer.) shown in compound.
In the present invention, the C that constitutes by saturated or unsaturated branch-like hydrocarbon chain as the main framing that is used for (A) component diester
6～28The concrete example of aliphatic dicarboxylic acid, can enumerate following chemical formula
Shown compound etc.
On the other hand, as fatty alcohol, can use C
1～9Fatty alcohol.If its carbon number surpasses 9, the solvability variation of diester.Preferred carbon number is 1～6, more preferably 1～4.In addition, this fatty alcohol is preferably the straight chain shape.If have side chain, heat-resisting sometimes scratch poor performance.
As the concrete example of this straight chain shape fatty alcohol, can enumerate methyl alcohol, ethanol, n-propyl alcohol, propyl carbinol etc.
In the present invention, as (A) component, can use the diester by above-mentioned aliphatic dicarboxylic acid and fatty alcohol preparation, this diester can be used alone, and also can be used in combination.In addition, the content of this diester is selected in the scope of 0.5～30 quality % in the rolling oil composition.If this contains quantity not sufficient 0.5 quality %, can not give full play to the dim spot of milled sheet and alleviate raising effect with heat-resisting scratch performance, can't realize purpose of the present invention.On the other hand, if surpass 30 quality %, can't show the raising of the effect suitable with its amount, be disadvantageous economically.The preferred content of this diester is the scope of 1～20 quality %, the scope of preferred especially 1～15 quality %.
In composition of the present invention, preferably also contain C
13～48Monoesters as (B) component.Be used in combination by diester, compare, can further bring into play the raising effect with heat-resisting scratch performance of alleviating of dim spot with the situation of independent use diester with this monoesters and above-mentioned (A) component.And, can reduce the usage quantity of diester by using this monoesters.
As the monoesters of above-mentioned (B) component, can enumerate for example general formula (II)
RCOOR
1(II)
(in the formula, R represents C
11～22Alkyl, R
1Expression C
1～25Alkyl, R and R
1The total carbon number be 12～47.) shown in compound.
The preferred carbon number of the monoesters shown in the above-mentioned general formula (II) is 13～36 scope.As the concrete example of this monoesters, preferably enumerate methyl stearate, butyl stearate, octyl stearate, Wickenol 155 etc., wherein, and from the aspects such as easiness of performance and acquisition, preferred butyl stearate.
In the present invention,, can use a kind of above-mentioned monoesters, also can be used in combination as (B) component.In addition, the scope of preferred 0.5～40 quality % of the content of this monoesters in the rolling oil composition.If this contains quantity not sufficient 0.5 quality %, can not give full play to the dim spot of milled sheet and alleviate raising effect with heat-resisting scratch performance, can't realize purpose of the present invention sometimes.On the other hand, if surpass 40 quality %, can't show the raising of the effect suitable with its amount, be disadvantageous economically, and low-temperature fluidity worsens sometimes.The preferred content of this monoesters is the scope of 3～30 quality %, the scope of preferred especially 5～20 quality %.
In composition of the present invention, use phosphorus series compound as (C) component.As this phosphorus series compound, there is no particular restriction, preferably uses for example ortho-phosphoric acid ester, its amine salt, alkylthio phosphoric acid ester etc., wherein the amine salt of preferred ortho-phosphoric acid ester.
As above-mentioned ortho-phosphoric acid ester, can enumerate for example general formula (III)
Shown compound.
In the ortho-phosphoric acid ester shown in the above-mentioned general formula (III), R
2, R
3And R
4Be respectively hydrogen atom or C
4～20Alkyl, they can be mutually the same, also can be different, wherein at least 1 is preferably C
4～20Alkyl.As C
4～20Alkyl, can enumerate C
4～20Straight chain shape, chain or cyclic alkyl or alkenyl, C
6～20Aryl, C
7～20Alkaryl, C
7～20Aralkyl etc.Wherein, preferred C
7～20Alkaryl.Concrete example as these alkyl, can enumerate butyl, amyl group, hexyl, cyclohexyl, octyl group, decyl, dodecyl, tetradecyl, hexadecyl, octadecyl, oleyl, eicosyl, phenyl, aminomethyl phenyl, isopropyl phenyl, xylyl, benzyl, styroyl etc., wherein special preferable methyl phenyl, isopropyl phenyl.
In addition, as the amine salt of ortho-phosphoric acid ester, can enumerate general formula (IV)
Shown compound.
In above-mentioned general formula (IV), R
5Be C
4～20Alkyl, preferred C
8～18Alkyl, more preferably C
12～18Alkyl.R
6Be C
4～20Straight chain shape, chain, cyclic alkyl or alkenyl, preferred C
8～8, more preferably C
12～16Straight chain shape, chain, cyclic alkyl or alkenyl.A, b are respectively 1 or 2, a plurality of R
5Can be identical or different, in addition, a plurality of R
6Can be identical or different.
For above-mentioned R
5Shown C
4～20Alkyl, with above-mentioned general formula (III) in R
2～R
4Middle C
4～20The explanation of alkyl identical.In addition, as R
6, can enumerate butyl, amyl group, hexyl, cyclohexyl, octyl group, decyl, dodecyl, tetradecyl, hexadecyl, octadecyl, oleyl, eicosyl etc.
On the other hand, as the alkylthio phosphoric acid ester, can enumerate alkyl is C
4～20Straight chain shape, chain, cyclic is saturated or the various single thiophosphate esters of unsaturated group, phosphorodithioate, phosphorotrithioate etc.Here, as this alkyl, can be set forth in the R in the above-mentioned general formula (IV)
6In the explanation, the group identical with illustrative group.
In the present invention, be somebody's turn to do the phosphorus series compound of (C) component, can be used alone, also can be used in combination.In addition, the content of this phosphorus series compound is selected in the scope of 0.01～5.0 quality % in the rolling oil composition.If this content less than 0.01 quality % can't give full play to the inhibition effect of dim spot, on the other hand,, can't show the raising of the effect suitable with its amount if surpass 5.0 quality %, be disadvantageous economically.The preferred content of this phosphorus series compound is the scope of 0.02～4 quality %, the scope of preferred especially 0.1～3 quality %.
In the scope of not damaging purpose of the present invention, can make the independent or two or more combinations of composition of the present invention suitably contain various additives as required, for example oxidation inhibitor, rust-preventive agent, sanitas, defoamer etc.
As above-mentioned oxidation inhibitor, can enumerate for example amines such as alkylated diphenylamine, phenyl-a-naphthylamine, alkylation-alpha-naphthylamine, 2, phenols such as 6-ditertbutylparacresol and sulphur class etc. as rust-preventive agent and sanitas, can be enumerated for example Isosorbide Dinitrate, neutral basic metal or alkaline-earth metal sulfonate, basic metal or alkaline-earth metal phenates, basic metal or alkaline-earth metal salicylate, thiadiazoles, benzotriazole etc.In addition, as defoamer, can enumerate for example dimethyl polysiloxane, fluorine ether etc.
Below the preferred 10 quality % of the total content of the additive that these use as required, more preferably below the 5 quality %.
In rolling oil composition of the present invention, there is no particular restriction for its viscosity, in order to obtain oilness and plate surface luster, preferred 1～20mm
2The scope of/s, preferred especially 2～10mm
2The scope of/s.
Cold-rolled lubricating oil composition of the present invention with this composition produces effect as follows.
(1) milling train of the form of sectional type support roll has been used in employing, implements the shape control that the sectional type support roll produces, and can make the dim spot minimizing of roller coating spot and milled sheet.That is, can improve the shape and the surface luster (dim spot) of rolled product.
(2) if improve roll speed, the thermal value of unit time is big when rolling, the accumulation of heat of roller increases, the thermal expansion of plate width becomes inhomogeneous, therefore be easy to generate the dim spot of roller coat cloth spot or milled sheet, but the rolling oil composition of the application of the invention even improve calender speed, also is difficult for producing dim spot.
(3) heat-resisting scratch performance improves.
(4) because above-mentioned (1)～(3) can realize that the quality of productive raising and goods improves.
There is no particular restriction for metallic substance that cold-rolled lubricating oil composition of the present invention is suitable for, in metallic substance, preferably is applicable to stainless steel.
Followingly the present invention is described in more detail, but the present invention is not limited to these embodiment according to embodiment.
Embodiment 1～9 and comparative example 1～5
(1) modulation of cold-rolled lubricating oil composition
For 40 ℃ kinematic viscosity is 8.0mm
2The paraffin base system mineral oil of/s cooperates the component shown in the 1st table based on the amount shown in the 1st table of total composition, modulation cold-rolled lubricating oil composition.
The component of using is as described below.
Monoesters: butyl stearate
Diester 1:
The shown aliphatic dicarboxylic acid and the diester of methylol (using the A of special fair 7-45674 communique the 1st table) with side chain
Diester 2:
The shown aliphatic dicarboxylic acid and the diester of methylol (using the I of special fair 7-45674 communique the 1st table) with side chain
Diester 3: diisononyl adipate (DINA)
TCP: TGP
The amine salt of phosphoric acid ester: the C of two oleic acid phosphoric acid ester
12～14Alkylamine salt
(2) rolling experiment
Under the rolling experiment condition shown in the 2nd table, be rolled experiment according to the rolling scheme shown in the 3rd table, dim spot when the 3rd rolling sequence is estimated high-speed rolling, push extrusion roll (external diameter 135mm, wide 10mm) at the 4th rolling sequence with 19.6kN, the contact part of segmented roll, the dim spot of noncontact part are estimated.In addition, obtain the rolling rate of the heat scratch limit, estimate heat-resisting scratch performance at the 5th rolling sequence.(with reference to the pre-original text collection of the 51st plastic working associating oratorical contest (2000.11.3～5), 303～304 pages " simulation of the surperficial dim spot that segmented roll produces in the stainless-steel cold-rolling ")
The results are shown in table 1.In addition, dim spot carries out following 4 grade evaluations according to visual.
0: no spot
1: fuzzy spot is arranged
2: can confirm clearly spot
3: the spot that can confirm intensity
The 1st table-1
| Embodiment | ||||||
| ????1 | ????2 | ????3 | ????4 | ????5 | ||
| Component is formed (weight %) | Monoesters | ????15.0 | ????15.0 | ????15.0 | ????15.0 | ????15.0 |
| Diester 1 | ????3.0 | ????3.0 | ????3.0 | ????3.0 | ????3.0 | |
| Diester 2 | ????- | ????- | ????- | ????- | ????- | |
| Diester 3 | ????- | ????- | ????- | ????- | ????- | |
| TCP | ????0.5 | ????1 | ????- | ????- | ????0.5 | |
| The amine salt of phosphoric acid ester | ????- | ????- | ????0.5 | ????- | ????0.5 | |
| C 8Phosphorotrithioate | ????- | ????- | ????- | ????0.8 | ????- | |
| Estimate | The dim spot of the 3rd rolling sequence | ????0 | ????0 | ????0 | ????0 | ????0 |
| The dim spot of the 4th rolling sequence | ????1 | ????0 | ????0 | ????0 | ????0 | |
| The 5th rolling sequence heat scratch rolling rate of the limit (%) | ????38.5 | ????38.6 | ????38.2 | ????38.1 | ????38.3 | |
The 1st table-2
| Embodiment | |||||
| ????6 | ????7 | ????8 | ????9 | ||
| Component is formed (weight %) | Monoesters | ????15.0 | ????15.0 | ????5.0 | ????- |
| Diester 1 | ????- | ????- | ????- | ????- | |
| Diester 2 | ????3.0 | ????3.0 | ????- | ????- | |
| Diester 3 | ????- | ????- | ????25.0 | ????30.0 | |
| TCP | ????- | ????0.5 | ????- | ????- | |
| The amine salt of phosphoric acid ester | ????0.5 | ????0.5 | ????0.5 | ????0.8 | |
| C 8Phosphorotrithioate | ????- | ????- | ????- | ????- | |
| Estimate | The dim spot of the 3rd rolling sequence | ????0 | ????0 | ????0 | ????0 |
| The dim spot of the 4th rolling sequence | ????0 | ????0 | ????0 | ????0 | |
| The 5th rolling sequence heat scratch rolling rate of the limit (%) | ????38.2 | ????38.3 | ????37.6 | ????38.0 | |
The 1st table-3
| Comparative example | ||||||
| ????1 | ????2 | ????3 | ????4 | ????5 | ||
| Component is formed (weight %) | Monoesters | ????15.0 | ????18.0 | ????15.0 | ????15.0 | ????- |
| Diester 1 | ????- | ????- | ????3.0 | ????- | ????- | |
| Diester 2 | ????- | ????- | ????- | ????3.0 | ????- | |
| Diester 3 | ????- | ????- | ????- | ????- | ????30.0 | |
| TCP | ????- | ????- | ????- | ????- | ????- | |
| The amine salt of phosphoric acid ester | ????- | ????- | ????- | ????- | ????- | |
| C 8Phosphorotrithioate | ????- | ????- | ????- | ????- | ????- | |
| Estimate | The dim spot of the 3rd rolling sequence | ????2 | ????2 | ????1 | ????1 | ????2 |
| The dim spot of the 4th rolling sequence | ????2 | ????2 | ????2 | ????2 | ????2 | |
| The 5th rolling sequence heat scratch rolling rate of the limit (%) | ????18.3 | ????19.0 | ????38.2 | ????38.4 | ????38.1 | |
The 2nd table
| The rolling experiment condition | ||
| The milling train form | ????- | 4 sections reversing mills |
| Working roll | Size material hardness thickness | Ф40×200mm SUJ-2 Hs?95 Ra?0.05μm |
| Support roll | Size | Ф200×200mm |
| Rolling stock | The tension stress of material size | SUS304 (2B, O material) 1.5t * 50Wmm * number of turns 702N/mm 2 |
| The oil supply method | The oil temperature is given oil mass | 40 ℃ of 13L/min are only from the one-sided oil supply of approaching side |
The 3rd table
| Rolling scheme | |||||
| Rolling sequence | Roll speed (m/min) | Tension force (kN) | Thickness of slab (mm) | Rolling rate (%) | |
| The place ahead | The rear | ||||
| ????0 | ????- | ????- | ????- | ????1.500 | ????- |
| ????1 | ????50 | ????9.8 | ????9.8 | ????1.145 | ????23.7 |
| ????2 | ????250 | ????9.8 | ????9.8 | ????0.925 | ????19.2 |
| ????3 | ????400 | ????8.8 | ????8.8 | ????0.785 | ????15.1 |
| ????4 | ????50 | ????7.4 | ????7.4 | ????0.670 | ????14.6 |
| ????5-1 | ????100 | ????4.4 | ????4.4 | ????0.570 | ????14.9 |
| ????5-2 | ????100 | ????4.4 | ????4.4 | ????0.540 | ????19.4 |
| ????5-3 | ????100 | ????4.4 | ????4.4 | ????0.510 | ????23.9 |
| ????5-4 | ????100 | ????4.4 | ????4.4 | ????0.490 | ????26.9 |
| ????5-5 | ????100 | ????4.4 | ????4.4 | ????0.460 | ????31.3 |
| ????5-6 | ????100 | ????4.4 | ????4.4 | ????0.440 | ????34.3 |
| ????5-7 | ????100 | ????4.4 | ????4.4 | ????0.420 | ????37.3 |
| ????5-8 | ????100 | ????4.4 | ????4.4 | ????0.400 | ????40.3 |
According to the present invention, can provide and be particularly suitable for the rolling cold-rolled lubricating oil composition of stainless steel, the dim spot that rolls plate that it can alleviate due to roller coating spot of sectional type support roll is implemented in the raising with heat-resisting scratch performance (rolling property) of alleviating of rolling the dim spot of plate due to the roller coating spot of width of working roll.
Claims (7)
1, cold-rolled lubricating oil composition is characterized in that: contain the C that base oil, (A) main framing are made of saturated or undersaturated hydrocarbon chain
6～28Aliphatic dicarboxylic acid and C
1～9Diester 0.5～30 quality % and (C) phosphorus series compound 0.01～5.0 quality % of fatty alcohol preparation.
2, the described cold-rolled lubricating oil composition of claim 1, wherein the hydrocarbon chain of the aliphatic dicarboxylic acid in the diester of (A) component is a branch-like.
3, the described cold-rolled lubricating oil composition of claim 1 is characterized in that: also contain (B) C
13～48Monoesters 0.5～40 quality %.
4, the described cold-rolled lubricating oil composition of claim 1, wherein the diester of (A) component is C
12～28Aliphatic dicarboxylic acid and C
1～6The diester of straight chain shape fatty alcohol preparation.
5, the described cold-rolled lubricating oil composition of claim 1, wherein the aliphatic dicarboxylic acid in the diester of (A) component is a saturated aliphatic dicarboxylic acids.
6, the described cold-rolled lubricating oil composition of claim 1, wherein the phosphorus series compound of (C) component is at least a for what choose from ortho-phosphoric acid ester, its amine salt and alkylthio phosphoric acid ester.
7, the described cold-rolled lubricating oil composition of claim 1, wherein the phosphorus series compound of (C) component is the amine salt of ortho-phosphoric acid ester.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002139680 | 2002-05-15 | ||
| JP139680/2002 | 2002-05-15 |
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|---|---|
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| CN1289646C CN1289646C (en) | 2006-12-13 |
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| CNB038107759A Expired - Fee Related CN1289646C (en) | 2002-05-15 | 2003-05-15 | Cold rolling oil composition |
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|---|---|
| JP (1) | JP4658594B2 (en) |
| KR (1) | KR101011892B1 (en) |
| CN (1) | CN1289646C (en) |
| TW (1) | TWI272304B (en) |
| WO (1) | WO2003097774A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102822325A (en) * | 2010-03-30 | 2012-12-12 | 出光兴产株式会社 | Lubricating oil composition for metal working |
| CN102002416B (en) * | 2009-09-01 | 2014-04-23 | 中国石油化工股份有限公司 | Cold rolling oil composition and use thereof |
| CN108865371A (en) * | 2018-08-01 | 2018-11-23 | 武汉钢铁有限公司 | A kind of environmentally friendly ROLLING OIL of secondary cold-rolling |
| CN112877111A (en) * | 2021-01-19 | 2021-06-01 | 常州龙邦润滑科技有限公司 | Stainless steel rolling cooling liquid and preparation method thereof |
| CN115244160A (en) * | 2020-04-06 | 2022-10-25 | 杰富意钢铁株式会社 | Cold rolling oil composition for ferritic stainless steel strip and cold rolling method for ferritic stainless steel strip |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP1958931A1 (en) * | 2007-02-02 | 2008-08-20 | Cognis IP Management GmbH | Oxidation stable carboxylic acid esters and their use |
| JP5351428B2 (en) * | 2008-03-28 | 2013-11-27 | 出光興産株式会社 | Rolling oil composition |
| WO2009119669A1 (en) * | 2008-03-28 | 2009-10-01 | 出光興産株式会社 | Lubricating oil composition for rolling with round die |
| JP6951023B2 (en) * | 2017-12-22 | 2021-10-20 | 日本パーカライジング株式会社 | Manufacturing method of cold-rolled oil and cold-rolled steel sheet |
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| JPS5224666A (en) * | 1975-08-16 | 1977-02-24 | Nippon Mining Co Ltd | Cold strip oil for stainless |
| JPS60141790A (en) * | 1983-12-29 | 1985-07-26 | Nippon Kokan Kk <Nkk> | Cold rolling oil for steel plate |
| JPH0745674B2 (en) * | 1986-03-03 | 1995-05-17 | 出光興産株式会社 | Lubricant for metal processing |
| JPH02300294A (en) * | 1989-05-16 | 1990-12-12 | Sumitomo Metal Ind Ltd | Cold rolling oil for steel sheet and cold rolling using the same |
| JPH0786200B2 (en) * | 1990-09-05 | 1995-09-20 | 日本クエーカー・ケミカル株式会社 | Cold rolling oil |
| JP2545312B2 (en) * | 1991-09-25 | 1996-10-16 | 川崎製鉄株式会社 | Cold rolling oil composition for stainless steel strip |
| JP3550449B2 (en) * | 1995-08-11 | 2004-08-04 | 日本クエーカー・ケミカル株式会社 | Cold rolling oil additives and cold rolling oils |
| JP2972169B2 (en) * | 1996-12-20 | 1999-11-08 | 新日本製鐵株式会社 | Steel sheet cold rolling method |
| JP3937061B2 (en) * | 1997-12-25 | 2007-06-27 | 新日鐵住金ステンレス株式会社 | Cold rolling oil |
| KR100285347B1 (en) * | 1998-12-01 | 2001-05-02 | 신현준 | Hot Rolled Oil Composition for Crude Rolling |
-
2003
- 2003-05-15 KR KR1020047018318A patent/KR101011892B1/en active IP Right Grant
- 2003-05-15 TW TW092113307A patent/TWI272304B/en not_active IP Right Cessation
- 2003-05-15 CN CNB038107759A patent/CN1289646C/en not_active Expired - Fee Related
- 2003-05-15 WO PCT/JP2003/006059 patent/WO2003097774A1/en active Application Filing
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002416B (en) * | 2009-09-01 | 2014-04-23 | 中国石油化工股份有限公司 | Cold rolling oil composition and use thereof |
| CN102822325A (en) * | 2010-03-30 | 2012-12-12 | 出光兴产株式会社 | Lubricating oil composition for metal working |
| CN102822325B (en) * | 2010-03-30 | 2015-04-22 | 出光兴产株式会社 | Lubricating oil composition for metal working |
| CN108865371A (en) * | 2018-08-01 | 2018-11-23 | 武汉钢铁有限公司 | A kind of environmentally friendly ROLLING OIL of secondary cold-rolling |
| CN108865371B (en) * | 2018-08-01 | 2021-06-15 | 武汉钢铁有限公司 | Environment-friendly rolling oil for secondary cold rolling |
| CN115244160A (en) * | 2020-04-06 | 2022-10-25 | 杰富意钢铁株式会社 | Cold rolling oil composition for ferritic stainless steel strip and cold rolling method for ferritic stainless steel strip |
| CN115244160B (en) * | 2020-04-06 | 2024-04-02 | 杰富意钢铁株式会社 | Cold-rolling oil composition for ferritic stainless steel strip and cold-rolling method for ferritic stainless steel strip |
| CN112877111A (en) * | 2021-01-19 | 2021-06-01 | 常州龙邦润滑科技有限公司 | Stainless steel rolling cooling liquid and preparation method thereof |
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| Publication number | Publication date |
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| CN1289646C (en) | 2006-12-13 |
| WO2003097774A1 (en) | 2003-11-27 |
| JP4658594B2 (en) | 2011-03-23 |
| JPWO2003097774A1 (en) | 2005-09-15 |
| KR20050000536A (en) | 2005-01-05 |
| TW200404887A (en) | 2004-04-01 |
| KR101011892B1 (en) | 2011-02-01 |
| TWI272304B (en) | 2007-02-01 |
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