CN1648277A - High strength steel sheet and method for manufacturing same - Google Patents
High strength steel sheet and method for manufacturing same Download PDFInfo
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- CN1648277A CN1648277A CNA2005100063139A CN200510006313A CN1648277A CN 1648277 A CN1648277 A CN 1648277A CN A2005100063139 A CNA2005100063139 A CN A2005100063139A CN 200510006313 A CN200510006313 A CN 200510006313A CN 1648277 A CN1648277 A CN 1648277A
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
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- Mechanical Engineering (AREA)
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- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Metal Rolling (AREA)
Abstract
The high strength steel sheet consists essentially of 0. 05 to 0.15% C, 0.5% or less Si, 1.00 to 2.00% Mn, 0.09% or less P, 0.01% or less S, 0.005% or less N, 0.01 to 0.1% Sol.Al, and balance of Fe and inevitable impurities; and contains 60% or more polygonal ferrite by volume, and 5 to 30% martensite by volume. The steel sheet is manufactured by the steps of: casting a slab having the specified composition; hot-rolling the slab at Ar3 point or more temperature; beginning cooling the hot-rolled steel sheet within 2 seconds after completing the hot-rolling to a temperature of from 750 DEG C to 600 DEG C at a cooling rate of 150 DEG C/s or more; holding the cooled steel sheet at a temperature between 750 DEG C and 600 DEG C for 2 to 15 seconds; cooling the steel sheet at a cooling rate of 20 DEG C/s or more; and coiling the cooled steel sheet at a temperature of 400 DEG C or less.
Description
Technical field
The present invention relates to a kind of high-strength steel sheet and manufacture method thereof that is suitable for car body, strengthening part, wheel, ground-engaging element and other so-called physical structure parts most.
Background technology
For the security of preserving our planet environment and improving the occupant, people study high strength, the thin-walled property of automotive sheet.Yet, if generally make the high strength of material, will reduce press formability, therefore, improve plasticity, be suggested as one of important topic of the scope of application that enlarges high tensile steel plate.
Corresponding above-mentioned steel, have with ferrite, martensite is the two-phase steel plate (being also referred to as Dual Phase steel, DP steel, complex tissue steel etc. in addition) of principal phase, above-mentioned two-phase steel plate, because yield ratio (Yield Ratio) (hereinafter referred to as YR) is low, the stretchiness height, therefore, draw forming and accurate plasticity press formabilities such as (Shape accuracy) are good, receive much concern as materials used in auto manufacturing, its exploitation is constantly carried out.
For example, two phase constitutions of hot-rolled steel sheet, in the process of cooling after hot rolling, separate out in a large number, make solute element multiviscosisty in remaining austenite by axle ferrite (Polygomal ferrite) such as making, and the enhancing hardenability, make its formation of martensite and form, in this technology, for formative tissue and improve mechanical characteristics, the ferritic amounts of separating out of axle such as control are very important, are correlated with therewith and carried out various research and development.
In patent documentation 1～11, composition design as steel is disclosed, heavy addition is the method for the ferrite stabilizer (P, Al etc.) of representative with Si, in process of cooling after hot rolling, promoting to stop cooling near the Al point that ferrite is separated out, keep after about 10 seconds, carry out once more the method for the so-called two-stage method of cooling of refrigerative.
On the other hand, in patent documentation 12～15, as not based on the method for adding the ferrite generting element, for example disclose by adopting and the quick cooling after the finish rolling is divided into two stages carries out etc., cooling master mode and diverse ways in the past, and obtain the manufacture method of target steel plate.
And, in patent documentation 16～18, disclose after hot rolling, carry out the method for quick cooling at once.Particularly in patent documentation 16, the steel low to silicone content adopts aforesaid method.
Patent documentation 1: the spy opens clear 60-121225 communique
Patent documentation 2: the spy opens flat 3-10049 communique
Patent documentation 3: the spy opens flat 4-235219 communique
Patent documentation 4: the spy opens flat 4-289126 communique
Patent documentation 5: the spy opens flat 4-337026 communique
Patent documentation 6: the spy opens flat 4-341523 communique
Patent documentation 7: the spy opens flat 7-150294 communique
Patent documentation 8: the spy opens flat 9-67641 communique
Patent documentation 9: the spy opens flat 9-125194 communique
Patent documentation 10: the spy opens flat 9-137249 communique
Patent documentation 11: the spy opens flat 10-195588 communique
Patent documentation 12: the spy opens clear 54-065118 communique
Patent documentation 13: the spy opens clear 56-136928 communique
Patent documentation 14: the spy opens flat 3-126813 communique
Patent documentation 15: the spy opens flat 4-276024 communique
Patent documentation 16: the spy opens the 2002-69534 communique
Patent documentation 17: the spy opens the 2001-192736 communique
Patent documentation 18: the spy opens the 2001-355023 communique
Yet, the steel of patent documentation 1～11, though all have the favorable mechanical characteristic, owing to need heavy addition Si, P, Al, existence generates red rust and causes the proterties on surface poor, the problem of coating difference and weldability difference, its scope of application is limited.
Steel plate by the method for patent documentation 12～15 is made because the addition of Si, P, Al is low, thereby in method of cooling in the past, does not make the austenite that takes place on runoff table after the hot rolling fully carry out to ferritic phase transformation.Therefore, wait a ferrite volume fraction low, martensite volume fraction height, and by the same token, wait thickization of voxel volume particle diameter, can not get the proper metal tissue of the present invention's regulation.Therefore, on mechanical characteristics, YR surpasses 0.6 and relatively poor.In order to improve the strain dispersion energy, improve accurate plasticity, need make YR below 0.6.
Like this, in the manufacture method of in the past hot rolling two-phase steel plate, sacrifice surface texture etc. and added ferrite stabilizer (Si, P, Al etc.), perhaps sacrificed mechanical characteristics.
On the other hand, in patent documentation 16,17, to YR and be used to realize that the metal structure of YR do not consider.
In addition, patent documentation 18 are manufacturing technologies that high density silicon adds steel, so the surface texture of steel plate is poor.In order to improve surface texture, also consider to reduce Si, if but reducing Si, this just can not obtain the proper metal tissue, YR characteristic variation.Like this, can not satisfy YR and surface texture simultaneously.
Summary of the invention
The present invention, its purpose is, a kind ofly bring dysgenic ferrite stabilizer (Si, P, Al) for surface texture, weldability etc. by developing without heavy addition, and suitably control metal structure, improve the method for the mechanical characteristics of steel plate, a kind of processibility (YR:0.6 is following) and good high-strength steel sheet and the manufacture method thereof of surface texture are provided.
The inventor, found by after the hot rolling 2 seconds with the super quick cooling of interior beginning more than 150 ℃/second, and at 750～600 ℃ of maintenance certain hours, even heavy addition ferrite stabilizer not, compare with two-stage method of cooling in the past, also found the phenomenon that remarkable promotion fine ferrite generates, be applied to the manufacturing of two-phase pattern hot-rolled high-strength steel plate, and finish the present invention.
The invention provides the high-strength steel sheet of following formation:
By percentage to the quality, contain that C:0.05～0.15%, Si:0.5% are following, Mn:1.00～2.00%, P:0.09% is following, S:0.01% is following, N:0.005% is following, Sol.Al:0.01～0.1%, surplus is made of Fe and unavoidable impurities, wait axle ferrite and the volume fraction that contain volume fraction and be more than 60% are 5～30% martensite.
Axle ferrite such as above-mentioned preferably has 60～95% volume fraction.In addition, wait a ferrite preferably to have the median size of 5～10 μ m.
Above-mentioned martensite preferably has 10～20% volume fraction.
Above-mentioned high-strength steel sheet preferably has mass percent and is 0.01～0.5% Si content.It is below 0.25% that Si content is more preferably mass percent.On the other hand, because Si has the effect that improves intensity, thereby preferably more than 0.01%.P content preferred mass per-cent is 0.020～0.06%.
Above-mentioned high-strength steel sheet by percentage to the quality, also can further contain and is selected from least a in Mo:0.01～0.3%, Nb:0.001～0.05%, Ti:0.001～0.1%, B:0.0003～0.002%, Cr:0.05～0.49%.
Above-mentioned high-strength steel sheet preferably has the yield ratio below 0.6.If yield ratio surpasses 0.6, the accurate plasticity during drawing, dimensional precision are with regard to variation.
In addition, the invention provides a kind of manufacture method with high-strength steel sheet of following operation:
Casting contains by percentage to the quality that C:0.05～0.15%, Si:0.5% are following, Mn:1.00～2.00%, P:0.09% is following, S:0.01% is following, N:0.005% is following, Sol.Al:0.01～0.1%, the operation of the slab that surplus is made of Fe and unavoidable impurities;
Slab to casting directly carries out hot rolling, perhaps heats, and carries out the hot rolled operation more than the temperature at the Ar3 point;
After hot rolling finishes, began to cool down with interior in 2 seconds, be cooled to 750～600 ℃ first refrigerating work procedure with the speed of cooling more than 150 ℃/second;
In 750～600 ℃ temperature range, keep 2～15 seconds operation;
Carry out refrigerative second refrigerating work procedure with the speed of cooling more than 20 ℃/second; With
The operation of batching with the temperature below 400 ℃.
Above-mentioned slab also can further contain and is selected from least a in Mo:0.01～0.3%, Nb:0.001～0.05%, Ti:0.001～0.1%, B:0.003～0.002%, Cr:0.05～0.49% by percentage to the quality.
The speed of cooling of above-mentioned first refrigerating work procedure is preferably 150～1000 ℃/second, more preferred 200～700 ℃/second.
The speed of cooling of above-mentioned second refrigerating work procedure is preferably 20～1000 ℃/second.
Above-mentioned coiling temperature is preferably 0～400 ℃.
In this manual, the per-cent of the composition of expression steel all is mass percent.
In addition, in this manual, high-strength steel sheet is meant that the tensile strength (TS) that is suitable for the physical structure parts surpasses the steel sheet of 590MPa.
According to the present invention, can obtain the good high-strength steel sheet of processibility and surface texture.The steel sheet that obtains by the present invention like this, intensity height and YR low (below 0.6) has high ductibility, press formability is good, and surface texture, spot weldability are also good, therefore are used for trolley part and physical structure parts easily.In addition, owing to can make, can not add special element and obtain good performance, therefore can reduce manufacturing cost by the operation identical with in the past soft steel plate.Thereby expectation will be practical widely from now on, can be by making the automobile lightweight environment of preserving our planet, and promote social development by improving security.
Description of drawings
Fig. 1 is the coordinate diagram of the relation of an expression yield ratio (YR) and a speed of cooling.
Embodiment
High-strength steel sheet of the present invention is characterised in that, as follows composition is done with regulation, the ferritic volume fraction of axle such as making is more than 60%, and making the martensite volume fraction is 5～30%, and the ferritic median size of axle such as making is 5～10 μ m, and these are the most important parts of the present invention.By like this composition and tissue being stipulated, can obtain the good high-strength steel sheet of processibility and surface texture.In addition, above-mentioned high-strength steel sheet, can be by carrying out hot rolling more than the temperature at the Ar3 point, then finish to begin to cool down with interior in back 2 seconds in hot rolling, be cooled to 750～600 ℃ with the speed of cooling more than 150 ℃/second, after then in 750～600 ℃ temperature range, keeping 2～15 seconds, cool off the operation of batching with the temperature below 400 ℃ and making with the speed of cooling more than 20 ℃/second.Like this, in manufacture method, beginning to cool down with interior in 2 seconds after hot rolling, carry out the super quick cooling of speed more than 150 ℃/second, keep certain hours at 750～600 ℃, also is important part of the present invention.
Below, the present invention will be described in detail.
At first the qualification reason of the chemical ingredients of steel plate of the present invention is stated.
C：0.05～0.15％
C is the important element that is used to strengthen martensitic phase, need add more than 0.05% in order to reach effect of sufficient, and on the other hand, if addition surpasses 0.15%, then stabilization of austenite is difficult to two-phaseization, and ductility reduces.From the above mentioned, C is more than 0.05% below 0.15%.If the consideration spot weldability, addition less than 0.07%, the situation that then exists tensile shear strength (Tensile ShearStrength) to reduce.In addition, if surpass 0.10%, the situation that then exists cross tensile strength (Cross Tension Strength) to reduce.Therefore, be preferably more than 0.07% below 0.10%.
Below the Si:0.5%
Si not only produces red rust and makes the surface texture variation, also makes coating, weldability variation.If surpass 0.5%, it is obvious that the detrimentally affect of Si becomes.From the above mentioned, Si is below 0.5%.Under the situation of especially paying attention to surface texture, Si is preferably below 0.25%.On the other hand, because Si has the effect that the intensity of making improves, preferably more than 0.01%.
Mn：1.00～2.00％
Therefore pearlitic generation after Mn can suppress hot rolling, in the cooling is taking on important effect in two phase constitutions form.Less than 1.00%, its effect is insufficient, and perlite produces, and it is big that YR becomes, the press formability variation.On the other hand, if surpass 2.00%, austenite is too stable, hinders to wait the ferritic generation of axle.From the above mentioned, Mn is more than 1.00% below 2.00%.And, if because Mn less than 1.30% then the situation that exists intensity to reduce, thereby preferred more than 1.30, on the other hand, if owing to surpass 1.80% then the situation that exists stretchiness to reduce, thereby preferably below 1.80%.
Below the P:0.09%
If P surpasses 0.09% then make the remarkable variation of stretchiness, therefore make it below 0.09.In addition, if surpass 0.06% then existence makes the toughness variation of weld part, the situation that bond strength is reduced is therefore preferably below 0.06%.And P has the generation of axle such as promotion ferrite more than 0.020%, reduce the effect of YR, so preferably more than 0.020%.
Below the S:0.01%
S is the impurity that contains in the crude steel, makes the plasticity and the weldability variation of former material steel plate, therefore preferably is removed or makes its reduction as far as possible in system steel operation.Yet, surpass necessary degree if reduce S content, will increase the refining cost, make therefore that S substantially is safe from harm below 0.01%.
Below the N:0.005%
N is the impurity that contains in the crude steel, makes the plasticity variation of former material steel plate, therefore preferably is removed or makes its reduction as far as possible in system steel operation.Yet, surpass necessary degree if reduce N content, will increase the refining cost, so N for be safe from harm in fact below 0.005%.
Sol.Al：0.01～0.1％
Al is used for deoxidation or N is separated out with AlN and adds.Less than 0.01%, the deoxidation denitrification effect is insufficient, and if above 0.1%, the effect of adding Al is saturated and uneconomical.From the above mentioned, Sol.Al is more than 0.01% below 0.1%.
In addition, steel of the present invention obtains target property by the above-mentioned element that must add, but must add outside the element above-mentioned, can also add one or more of the Mo, the Nb that are used for improving intensity, Ti, B, Cr as required.At this moment, if each addition difference less than 0.01%, 0.001%, 0.001%, 0.0003%, 0.05%, then additive effect is insufficient.On the other hand,, then can hinder the generation of two phase constitutions, and cause the mechanical characteristics variation owing to the precipitation strength amount is excessive (YR becomes big or the stretchiness reduction) if Mo, Nb, Ti, B surpass 0.3%, 0.05%, 0.1%, 0.002% respectively.In addition, if Cr surpasses 0.49% then the chemical treatability variation.Therefore, when adding these elements, making Mo is more than 0.01% below 0.3%, and Nb is more than 0.001% below 0.05%, and Ti is more than 0.001% below 0.1%, and B is more than 0.0003% below 0.002%, and Cr is more than 0.05% below 0.49%.
Surplus beyond above-mentioned is made of Fe and inevitable impurity.As inevitable impurity, for example, O forms non-metallic inclusion, bring detrimentally affect to quality, so O is reduced to below 0.003% preferably.In addition, in the present invention, can contain micro-Ni, V, Cu, Sb, Sn, Mg, the REM that does not harm action effect of the present invention in the scope below 0.1%.
Then the qualification reason to metal structure of the present invention is explained.
At first, the ferritic volume fraction of axle such as make more than 60%.Very important Deng axle ferrite volume fraction for discovery as the low YR characteristic of feature of the present invention.In order to make YR is below 0.6, and the ferritic volume fraction of axle such as need make is more than 60%.Deng an axle ferrite is in ferritic phase, is different from acicular ferrite from its form, and the ratio of the major diameter of ferrite crystal grain and minor axis is the tissue below 5.
Making the martensite volume fraction is 5～30%.Because martensitic volume fraction all exerts an influence to intensity, ductility and low YR characteristic, thus the same with the above-mentioned axle ferrite volume fraction that waits, be important factor for the present invention.5% intensity of martensite volume fraction less than is low, can not get low YR characteristic.On the other hand, if surpass 30% ductility descend.Therefore, make martensitic volume fraction more than 5% below 30%.In order to obtain more good low YR characteristic, the martensite volume fraction is preferably more than 10% below 20%.Remnant tissue is needle-like voxel volume (Acicular ferrite), bainite, perlite etc., if but wait axle ferrite and martensitic each volume fraction in above-mentioned scope, just can obtain effect of the present invention, therefore the volume fraction to remnant tissue is not particularly limited.
For the balance that improves intensity and ductility, promptly further improve the long-pending of intensity and tension values, the ferritic median size of axle such as also preferably making is 5～10 μ m.The tension values of stretching experiment generally with even stretchiness and local stretchiness and represent, if but wait axle ferrite particle diameter less than 5 μ m, the situation that then exists even stretchiness to reduce.On the other hand, if surpass 10 μ m, though in allowed band the local elongation variation.This is coarsening, the uneven reason that in the two-phase steel, becomes, and, promote the reason that tiny crack produces at part generation stress concentration.
Then, the manufacture method to the good high-strength steel sheet of processibility of the present invention and surface texture describes.
High-strength steel sheet of the present invention obtains by following operation: behind the slab in casting is adjusted to above-mentioned chemical ingredients scope, it is directly carried out hot rolling, perhaps heat, carry out hot rolling more than the temperature at the Ar3 point, then, finish to begin to cool down with interior in back 2 seconds in hot rolling, be cooled to 750～600 ℃ with the speed of cooling more than 150 ℃/second, then, after in 750～600 ℃ temperature range, keeping 2～15 seconds, speed with 20 ℃/second is cooled off, and batches under the temperature below 400 ℃.
In above-mentioned, do not limit the castmethod of slab.Under the situation of continuous casting, can directly carry out hot rolling, carry out reheat after also can cooling off, and implement hot rolling.
Hot rolling is implemented more than the temperature at the Ar3 point.If under the temperature of ordering less than Ar3, hot rolling is then carried out on ferrite, austenite two phase region, hinders to wait the ferritic generation of axle, and it is big that YR becomes, and ductility reduces.
Finish to begin to cool down with interior in back 2 seconds in hot rolling,, be cooled to as 750～600 ℃ that keep temperature with 150 ℃/second speed of cooling.Once cooling after this hot rolling is the greatest factor that the effect (generating the low YR effect that obtains by axle ferrites such as promotions) that obtains based on the present invention is found.By like this cooling once being stipulated, in time carry out quick cooling, can greatly promote after cooling once in the maintenance under carry out 750～600 ℃ etc. ferritic trickle the separating out of axle.Surpass 2 seconds if hot rolling finishes the back to time of cooling beginning, will generate ferrite unevenly at austenite grain boundary, and hinder cooling in keeping etc. axle is ferritic separates out.If 150 ℃/second of speed of cooling less thaies, the ferrite in still can not suppressing to cool off is separated out the inhomogeneous of austenite grain boundary, hinder the cooling back in keeping etc. axle is ferritic separates out.And in order to increase this effect, a preferred speed of cooling is more than 200 ℃/second.On the other hand, if a speed of cooling surpasses 1000 ℃/second, will exist in the thickness range, it is inhomogeneous that metal structure becomes, the situation of mechanical characteristics variation, and therefore a speed of cooling is preferably below 1000 ℃/second, more preferably below 700 ℃/second.
Once after the cooling, in 750～600 ℃ temperature range, kept 2～15 seconds.If the temperature province that keeps surpasses 750 ℃, the motivating force of ferrite generation is little so, can not get promoting to separate out effect.On the other hand, if 600 ℃ of less thaies are separated out delay because of the diffusion of Fe atom by restriction speed ferritic so, can not fully generate and wait a ferrite.In addition, if hold-time less than 2 seconds, ferritic to separate out the time inadequate, can not obtain low YR characteristic.On the other hand, if keep surpassing 15 seconds, because perlite begins generation thereby mechanical characteristics variation.
After keeping, carry out the secondary cooling, batch in the temperature below 400 ℃ with the speed of cooling more than 20 ℃/second.For the perlite in suppressing to cool off, the generation of bainite, need make the speed of cooling in the secondary cooling is more than 20 ℃/second.On the other hand, if the secondary speed of cooling surpasses 1000 ℃/second, just have in thickness range, it is inhomogeneous that metal structure becomes, the situation of mechanical characteristics variation, so the secondary speed of cooling is preferably below 1000 ℃/second.
For the perlite after suppressing to batch, the generation of bainite, martensite is produced, reach the YR below 0.6 as target, need make coiling temperature is below 400 ℃.And in order to suppress the intensity change in the coiled material, coiling temperature is preferably below 300 ℃, more preferably below 200 ℃, and, because less than 0 ℃ of cooling that is difficult to carry out based on water, so coiling temperature is preferably more than 0 ℃.
To the high-strength steel sheet of the present invention that obtains by above operation,, can also implement skin-pass in order to carry out shape correction.In addition, can carry out various surface treatments such as molten zinc plating or electro-galvanizing with high-strength steel sheet of the present invention as matrix.
Embodiment 1
After slab with the chemical ingredients shown in the table 1 cast continuously, cool off, then be heated to 1100～1300 ℃, carry out finish to gauge Ar3 point temperature～850 ℃, making thickness of slab is 1.6～3.2mm.Then, finish to begin to cool down with interior in back 1 second, be cooled to 680～720 ℃ with 300～500 ℃/second speed of cooling in finish to gauge, in this temperature range, kept 7～12 seconds, and then, cooled off with 25～30 ℃/second, batching below 350 ℃, obtain hot-rolled steel sheet.Wherein, be 550 ℃ by steel numbering system 4 being made once cooling stop temperature, it is 450 ℃ that steel numbering system 5 is made coiling temperature, and is adjusted to the described organizational composition of table 1.By observing cross section perpendicular to the steel plate width direction, measure the area occupation ratio of each phase, wait a voxel volume and martensitic volume fraction and calculate.In above-mentioned section structure, wait a ferrite particle diameter to measure by segment method, get the mean value of rolling direction and thickness of slab direction.
Table 1
| Difference | Steel numbering system | Chemical ingredients (mass percent) | Deng axle ferrite volume fraction (%) | Martensite volume fraction (%) | The main tissue of surplus | Deng axle ferrite particle diameter (μ m) | |||||||
| ?????C | ?????Si | ?????Mn | ??????P | ??????S | ???Sol.Al | ??????N | Other | ||||||
| Comparative example | ????1 | ????0.03 | ????0.30 | ????1.60 | ????0.015 | ????0.003 | ????0.04 | ????0.003 | ??????- | ????70 | ????5 | Bainite 10% | ????12 |
| Example of the present invention | ????2 | ????0.06 | ????0.01 | ????1.50 | ????0.010 | ????0.002 | ????0.05 | ????0.004 | ??????- | ????80 | ????10 | Acicular ferrite 10% | ????10 |
| Example of the present invention | ????3 | ????0.06 | ????0.01 | ????1.50 | ????0.010 | ????0.002 | ????0.05 | ????0.004 | ????0.0008B | ????70 | ????15 | Acicular ferrite 10% | ????5 |
| Comparative example | ????4 | ????0.06 | ????0.01 | ????1.50 | ????0.010 | ????0.002 | ????0.05 | ????0.004 | ??????- | ????40 | ????10 | Acicular ferrite 50% | ????11 |
| Comparative example | ????5 | ????0.06 | ????0.01 | ????1.50 | ????0.010 | ????0.002 | ????0.05 | ????0.004 | ??????- | ????70 | ????0 | Bainite 15% | ????8 |
| Example of the present invention | ????6 | ????0.08 | ????0.20 | ????1.50 | ????0.010 | ????0.005 | ????0.05 | ????0.004 | ??????- | ????90 | ????10 | ????- | ????6 |
| Example of the present invention | ????7 | ????0.11 | ????0.01 | ????1.40 | ????0.015 | ????0.001 | ????0.04 | ????0.003 | ????0.1Mo | ????85 | ????15 | ????- | ????8 |
| Example of the present invention | ????8 | ????0.14 | ????0.05 | ????1.44 | ????0.020 | ????0.007 | ????0.07 | ????0.002 | ??????- | ????70 | ????15 | Perlite 10% | ????6 |
| Comparative example | ????9 | ????0.17 | ????0.15 | ????1.60 | ????0.012 | ????0.004 | ????0.06 | ????0.004 | ??????- | ????50 | ????35 | Perlite 10% | ????4 |
| Example of the present invention | ????10 | ????0.07 | ????0.01 | ????1.70 | ????0.013 | ????0.003 | ????0.03 | ????0.004 | ??????- | ????80 | ????15 | Bainite 5% | ????9 |
| Example of the present invention | ????11 | ????0.06 | ????0.24 | ????1.65 | ????0.008 | ????0.001 | ????0.01 | ????0.003 | ??????- | ????70 | ????10 | Bainite 5% | ????8 |
| Example of the present invention | ????12 | ????0.08 | ????0.45 | ????1.45 | ????0.018 | ????0.005 | ????0.05 | ????0.002 | ????0.02Nb | ????85 | ????15 | ????- | ????7 |
| Comparative example | ????13 | ????0.09 | ????0.70 | ????1.55 | ????0.011 | ????0.002 | ????0.06 | ????0.004 | ??????- | ????85 | ????15 | ????- | ????5 |
| Comparative example | ????14 | ????0.07 | ????0.30 | ????0.80 | ????0.009 | ????0.003 | ????0.04 | ????0.004 | ??????- | ????80 | ????0 | Perlite 10% | ????12 |
| Example of the present invention | ????15 | ????0.11 | ????0.05 | ????1.75 | ????0.012 | ????0.002 | ????0.07 | ????0.003 | ??????- | ????80 | ????20 | ????- | ????9 |
| Comparative example | ????16 | ????0.08 | ????0.22 | ????2.20 | ????0.014 | ????0.001 | ????0.06 | ????0.002 | ??????- | ????50 | ????50 | ????- | ????7 |
| Example of the present invention | ????17 | ????0.10 | ????0.31 | ????1.65 | ????0.040 | ????0.004 | ????0.03 | ????0.004 | ??????- | ????85 | ????15 | ????- | ????6 |
| Comparative example | ????18 | ????0.12 | ????0.10 | ????1.54 | ????0.100 | ????0.005 | ????0.05 | ????0.004 | ??????- | ????90 | ????10 | ????- | ????10 |
| Example of the present invention | ????19 | ????0.07 | ????0.13 | ????1.35 | ????0.025 | ????0.004 | ????0.04 | ????0.003 | ????0.04Ti | ????79 | ????21 | ????- | ????5 |
| Example of the present invention | ????20 | ????0.06 | ????0.08 | ????1.10 | ????0.045 | ????0.004 | ????0.04 | ????0.004 | ????0.40Cr | ????84 | ????16 | ????- | ????9 |
To estimating by mechanical characteristics, surface shape, the spot weldability of the above-mentioned hot-rolled steel sheet that obtains.The result who obtains is represented at table 2.Each evaluation method is as follows.Mechanical characteristics, the vertical JIS5 tension test sheet of taking with rolling direction is tested according to JISZ2241.Surface texture has or not by visual judgement red rust.Spot weldability, under the condition of the weld nugget that forms 5 * thickness of slab (mm) after the spot welding, in the breaking morphology that obtains by the stripping test (Peel test using achisel) of using chisel, the base material fracture then is marked with zero, weld part fracture then is marked with *, and judge.
Table 2
| Difference | Steel numbering system | Mechanical characteristics | Surface texture | Spot weldability | |||
| ????YP ???(MPa) | ??TS(MPa) | ???EI(％) | ????YR | ||||
| Comparative example | ????1 | ????390 | ????520 | ????36.5 | ????0.75 | ????△ | ????○ |
| Example of the present invention | ????2 | ????354 | ????610 | ????31.1 | ????0.58 | ????○ | ????○ |
| Example of the present invention | ????3 | ????352 | ????640 | ????29.7 | ????0.55 | ????○ | ????○ |
| Comparative example | ????4 | ????390 | ????600 | ????31.7 | ????0.65 | ????○ | ????○ |
| Comparative example | ????5 | ????428 | ????570 | ????33.3 | ????0.75 | ????○ | ????○ |
| Example of the present invention | ????6 | ????345 | ????650 | ????29.2 | ????0.53 | ????○ | ????○ |
| Example of the present invention | ????7 | ????373 | ????690 | ????27.5 | ????0.54 | ????○ | ????○ |
| Example of the present invention | ????8 | ????462 | ????810 | ????23.5 | ????0.57 | ????○ | ????○ |
| Comparative example | ????9 | ????683 | ????1050 | ????18.1 | ????0.65 | ????○ | ????× |
| Example of the present invention | ????10 | ????369 | ????670 | ????28.4 | ????0.55 | ????○ | ????○ |
| Example of the present invention | ????11 | ????336 | ????590 | ????32.2 | ????0.57 | ????○ | ????○ |
| Example of the present invention | ????12 | ????352 | ????640 | ????29.7 | ????0.55 | ????△ | ????○ |
| Comparative example | ????13 | ????369 | ????670 | ????28.4 | ????0.55 | ????× | ????○ |
| Comparative example | ????14 | ????451 | ????530 | ????35.8 | ????0.85 | ????△ | ????○ |
| Example of the present invention | ????15 | ????383 | ????710 | ????26.8 | ????0.54 | ????○ | ????○ |
| Comparative example | ????16 | ????723 | ????850 | ????22.4 | ????0.85 | ????○ | ????○ |
| Example of the present invention | ????17 | ????385 | ????700 | ????27.1 | ????0.55 | ????△ | ????○ |
| Comparative example | ????18 | ????468 | ????780 | ????24.4 | ????0.60 | ????○ | ????× |
| Example of the present invention | ????19 | ????398 | ????675 | ????28.1 | ????0.59 | ????○ | ????○ |
| Example of the present invention | ????20 | ????389 | ????695 | ????27.3 | ????0.56 | ????○ | ????○ |
The steel capital of the present invention as shown in Table 2 has good mechanical characteristics (YR:0.6 following), and surface texture, weldability are good.And, steel numbering system 12,17, because Si content is slightly high, thereby surface texture is slightly poor, but belongs to the practical no problem quality level that.
Relative therewith, steel numbering system 1 as a comparative example, because C content is outside the scope of the invention and lower, thereby martensite hardness is not enough, it is the YR height as a result.Steel numbering system 4,5, owing to wait axle ferrite volume fraction or martensite volume fraction outside the scope of the invention, thereby can not obtain two good phase constitutions, the YR height.Steel numbering system 9, because C content is the scope of the invention outside and higher, thereby ferritic generation delay, can not obtain two good phase constitutions, the YR height.And spot weldability is also poor.Steel numbering system 13, Si content thereby produce red rust outside the scope of the invention and higher, and surface texture is poor.Steel numbering system 14, because Mn content is the scope of the invention outside and lower, thereby the austenite instabilityization, generation perlite, thereby YR height.Steel numbering system 16 because Mn content is the scope of the invention outside and higher, thereby etc. a ferritic growing amount few, the YR height.Steel numbering system 18, because P content is outside the scope of the invention and higher, thereby the obvious variation of spot weldability.
Embodiment 2
Use has the part of the slab of the chemical ingredients shown in the table 1, under the creating conditions shown in the table 3, carries out hot rolling, cools off, batches and obtain hot-rolled steel sheet.
Table 3
| Difference | Symbol | Steel numbering system | Heating temperature (℃) | Final rolling temperature (℃) | Begin to cool down the time (second) | A speed of cooling (℃/second) | Stop temperature (℃) | Hold-time (second) | Secondary speed of cooling (℃/second) | Coiling temperature (℃) |
| Example of the present invention | ????A | ????2 | ????1200 | ????850 | ????0.5 | ????460 | ????738 | ????4 | ????45 | ????382 |
| Example of the present invention | ????B | ????2 | ????1250 | ????830 | ????1 | ????290 | ????738 | ????4 | ????21 | ????373 |
| Example of the present invention | ????C | ????2 | ????1230 | ????840 | ????2 | ????530 | ????644 | ????11 | ????38 | ????324 |
| Comparative example | ????D | ????2 | ????1055 | ????820 | ????5 | ????230 | ????701 | ????12 | ????42 | ????144 |
| Comparative example | ????E | ????2 | ????1150 | ????830 | ????1 | ????50 | ????707 | ????12 | ????45 | ????136 |
| Example of the present invention | ????F | ????2 | ????1250 | ????850 | ????1 | ????180 | ????717 | ????6 | ????40 | ????317 |
| Example of the present invention | ????G | ????2 | ????1200 | ????840 | ????1 | ????220 | ????686 | ????7 | ????24 | ????259 |
| Example of the present invention | ????H | ????2 | ????1100 | ????830 | ????1 | ????450 | ????698 | ????6 | ????20 | ????116 |
| Comparative example | ????I | ????6 | ????1120 | ????820 | ????1 | ????340 | ????800 | ????8 | ????50 | ????217 |
| Example of the present invention | ????G | ????6 | ????1150 | ????810 | ????1 | ????280 | ????730 | ????10 | ????22 | ????184 |
| Example of the present invention | ????K | ????6 | ????1280 | ????830 | ????1 | ????530 | ????680 | ????10 | ????22 | ????181 |
| Example of the present invention | ????L | ????6 | ????1200 | ????830 | ????1 | ????270 | ????650 | ????13 | ????30 | ????347 |
| Comparative example | ????M | ????6 | ????1130 | ????820 | ????1 | ????390 | ????350 | ????11 | ????41 | ????285 |
| Comparative example | ????N | ????6 | ????1180 | ????840 | ????1 | ????240 | ????634 | ????- | ????46 | ????158 |
| Example of the present invention | ????O | ????6 | Directly carry | ????820 | ????1 | ????560 | ????682 | ????8 | ????33 | ????350 |
| Example of the present invention | ????P | ????6 | ????1230 | ????830 | ????1 | ????590 | ????725 | ????10 | ????30 | ????342 |
| Comparative example | ????Q | ????6 | ????1210 | ????840 | ????1 | ????580 | ????646 | ????25 | ????21 | ????219 |
| Comparative example | ????R | ????17 | ????1200 | ????850 | ????1 | ????500 | ????719 | ????12 | ????10 | ????293 |
| Example of the present invention | ????S | ????17 | ????1180 | ????830 | ????1 | ????330 | ????656 | ????6 | ????25 | ????272 |
| Example of the present invention | ????T | ????17 | ????1240 | ????820 | ????1 | ????470 | ????632 | ????12 | ????35 | ????382 |
| Example of the present invention | ????U | ????17 | ????1200 | ????830 | ????1 | ????500 | ????634 | ????10 | ????33 | ????＜100 |
| Example of the present invention | ????V | ????17 | ????1150 | ????830 | ????1 | ????460 | ????663 | ????3 | ????39 | ????350 |
| Comparative example | ????W | ????17 | ????1220 | ????830 | ????1 | ????480 | ????712 | ????7 | ????20 | ????450 |
To estimating by mechanical characteristics, surface texture, the spot weldability of the above-mentioned hot-rolled steel sheet that obtains.The result who obtains is represented at table 4.Each evaluation method is identical with embodiment 1.
Table 4
| Difference | Symbol | Deng axle ferrite volume fraction (%) | Martensite volume fraction (%) | Deng axle ferrite particle diameter (μ m) | Mechanical characteristics | |||
| ???YP ??(MPa) | ???TS ??(MPa) | ???EI(％) | ?????YR | |||||
| Example of the present invention | A | ????75 | ????10 | ????8 | ????341 | ????620 | ????30.6 | ????0.55 |
| Example of the present invention | B | ????75 | ????10 | ????9 | ????342 | ????610 | ????31.1 | ????0.56 |
| Example of the present invention | C | ????80 | ????10 | ????10 | ????354 | ????610 | ????31.1 | ????0.58 |
| Comparative example | D | ????50 | ????10 | ????13 | ????447 | ????630 | ????30.2 | ????0.71 |
| Comparative example | E | ????40 | ????5 | ????15 | ????488 | ????650 | ????29.2 | ????0.75 |
| Example of the present invention | F | ????80 | ????10 | ????9 | ????365 | ????640 | ????29.7 | ????0.57 |
| Example of the present invention | G | ????75 | ????10 | ????7 | ????330 | ????600 | ????31.7 | ????0.55 |
| Example of the present invention | H | ????80 | ????10 | ????6 | ????369 | ????670 | ????28.4 | ????0.55 |
| Comparative example | I | ????30 | ????15 | ????10 | ????490 | ????680 | ????27.9 | ????0.72 |
| Example of the present invention | G | ????85 | ????12 | ????8 | ????381 | ????680 | ????27.9 | ????0.56 |
| Example of the present invention | K | ????90 | ????10 | ????7 | ????336 | ????590 | ????32.2 | ????0.57 |
| Example of the present invention | L | ????80 | ????10 | ????5 | ????364 | ????650 | ????29.2 | ????0.56 |
| Comparative example | M | ????35 | ????5 | ????4 | ????446 | ????550 | ????34.5 | ????0.81 |
| Comparative example | N | ????45 | ????10 | ????4 | ????441 | ????630 | ????30.2 | ????0.70 |
| Example of the present invention | O | ????85 | ????13 | ????9 | ????389 | ????670 | ????28.4 | ????0.58 |
| Example of the present invention | P | ????80 | ????10 | ????8 | ????358 | ????640 | ????29.7 | ????0.56 |
| Comparative example | Q | ????80 | ????0 | ????12 | ????451 | ????530 | ????35.8 | ????0.85 |
| Comparative example | R | ????80 | ????3 | ????11 | ????498 | ????560 | ????33.9 | ????0.89 |
| Example of the present invention | S | ????85 | ????8 | ????9 | ????369 | ????670 | ????28.4 | ????0.55 |
| Example of the present invention | T | ????75 | ????18 | ????8 | ????412 | ????710 | ????26.8 | ????0.58 |
| Example of the present invention | U | ????85 | ????15 | ????5 | ????366 | ????690 | ????27.5 | ????0.53 |
| Example of the present invention | V | ????85 | ????15 | ????8 | ????385 | ????700 | ????27.1 | ????0.55 |
| Comparative example | W | ????75 | ????0 | ????9 | ????475 | ????650 | ????29.2 | ????0.73 |
Has good mechanical characteristics (YR:0.6 is following) by table 4 steel capital of the present invention as can be known.And surface texture, spot weldability all are good in the scope of embodiment 2.
Relative therewith, symbol D as a comparative example, after the rolling end to time of once cooling beginning the scope of the invention outside and longer, thereby the inhomogeneous generation of ferrite before cooling begins can not form two good phase constitutions, the YR height.Symbol E, because speed of cooling is the scope of the invention outside and lower, so the inhomogeneous generation of ferrite in cooling, can not form two good phase constitutions, the YR height.Symbol I, because once cooling stops temperature the scope of the invention outside and higher, thereby the ferrite generation in after this keeping is insufficient, can not form two good phase constitutions, the YR height.Symbol M, because cooling temperature is the scope of the invention outside and lower, thereby the ferritic generation in maintenance after this is insufficient, can not form two good phase constitutions, the YR height.Symbol N is because once so the ferrite generation is insufficient, can not form two good phase constitutions, the YR height the scope of the invention outside and inadequate the cooled hold-time.Symbol Q and since once the cooled hold-time thereby generate perlite in the maintenance the scope of the invention outside and longer, can not form two good phase constitutions, the YR height.Symbol R because the secondary speed of cooling is the scope of the invention outside and lower, so generates bainite in cooling, can not obtain two good phase constitutions, the YR height.Symbol W because coiling temperature is the scope of the invention outside and higher, thereby batching back generation Bei Shi body, can not form two good phase constitutions, the YR height.
In Fig. 1, steel No.2 has been represented the relation of a YR and a speed of cooling.With the speed more than 150 ℃/second of the scope of the invention, can obtain the low good characteristic of YR as can be known.Sample steel D owing to being 5 seconds to a refrigerative time, departs from the scope of the present invention, thereby can not get good result.
Steel plate of the present invention has good press formability, and has the surface of good proterties, thereby also goes for molded component of paying attention to appearance character etc.
Claims (15)
1. high-strength steel sheet, wherein, by percentage to the quality, contain that C:0.05～0.15%, Si:0.5% are following, Mn:1.00～2.00%, P:0.09% is following, S:0.01% is following, N:0.005% is following, Sol.Al:0.01～0.1%, surplus is made of Fe and unavoidable impurities, wait axle ferrite and the volume fraction that contain volume fraction and be more than 60% are 5～30% martensite.
2. high-strength steel sheet as claimed in claim 1, wherein, axle ferrite such as described has 60～95% volume fraction.
3. high-strength steel sheet as claimed in claim 1, wherein, described martensite has 10～20% volume fraction.
4. high-strength steel sheet as claimed in claim 1, wherein, axle ferrite such as described has the median size of 5～10 μ m.
5. high-strength steel sheet as claimed in claim 1, wherein, by percentage to the quality, also contain and be selected from least a in Mo:0.01～0.3%, Nb:0.001～0.05%, Ti:0.001～0.1%, B:0.0003～0.002%, Cr:0.05～0.49%.
6. high-strength steel sheet as claimed in claim 1, wherein, Si content is 0.01～0.5% by percentage to the quality.
7. high-strength steel sheet as claimed in claim 1, wherein, Si content is 0.01～0.25% by percentage to the quality.
8. high-strength steel sheet as claimed in claim 1, wherein, P content is 0.020～0.06% by percentage to the quality.
9. high-strength steel sheet as claimed in claim 1 wherein, has the yield ratio below 0.6.
10. the manufacture method of a high-strength steel sheet, wherein,
Have that casting contains by percentage to the quality that C:0.05～0.15%, Si:0.5% are following, Mn:1.00～2.00%, P:0.09% is following, S:0.01% is following, N:0.005% is following, Sol.Al:0.01～0.1%, the operation of the slab that surplus is made of Fe and unavoidable impurities;
Slab to casting directly carries out hot rolling, perhaps heats, and carries out the hot rolled operation more than the temperature at the Ar3 point;
After hot rolling finishes, began to cool down with interior in 2 seconds, be cooled to 750～600 ℃ first refrigerating work procedure with the speed of cooling more than 150 ℃/second;
In 750～600 ℃ temperature range, keep 2～15 seconds operation;
Carry out refrigerative second refrigerating work procedure with the speed of cooling more than 20 ℃/second; With
The operation of batching with the coiling temperature below 400 ℃.
11. the manufacture method of high-strength steel sheet as claimed in claim 10, wherein, by percentage to the quality, described slab also contains and is selected from least a in Mo:0.01～0.3%, Nb:0.001～0.05%, Ti:0.001～0.1%, B:0.0003～0.002%, Cr:0.05～0.49%.
12. the manufacture method of high-strength steel sheet as claimed in claim 10, wherein, the speed of cooling of described first refrigerating work procedure is 150～1000 ℃/second,
13. the manufacture method of high-strength steel sheet as claimed in claim 12, wherein, the speed of cooling of described first refrigerating work procedure is 200～700 ℃/second.
14. the manufacture method of high-strength steel sheet as claimed in claim 10, wherein, the speed of cooling of described second refrigerating work procedure is 20～1000 ℃/second.
15. the manufacture method of high-strength steel sheet as claimed in claim 10, wherein, described coiling temperature is 0～400 ℃.
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- 2005-01-20 US US11/040,994 patent/US20050173031A1/en not_active Abandoned
- 2005-01-21 CA CA002493523A patent/CA2493523C/en not_active Expired - Fee Related
- 2005-01-25 AU AU2005200300A patent/AU2005200300C1/en not_active Ceased
- 2005-01-26 CN CNB2005100063139A patent/CN100439542C/en not_active Expired - Fee Related
- 2005-01-26 TW TW094102230A patent/TWI277658B/en not_active IP Right Cessation
- 2005-01-27 KR KR1020050007363A patent/KR100673424B1/en active IP Right Grant
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- 2009-04-17 US US12/386,518 patent/US20090223607A1/en not_active Abandoned
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Also Published As
| Publication number | Publication date |
|---|---|
| KR20050077757A (en) | 2005-08-03 |
| CN100439542C (en) | 2008-12-03 |
| JP2005240172A (en) | 2005-09-08 |
| AU2005200300A1 (en) | 2005-08-18 |
| EP1559797A1 (en) | 2005-08-03 |
| AU2005200300C1 (en) | 2008-03-06 |
| KR100673424B1 (en) | 2007-01-24 |
| JP4470701B2 (en) | 2010-06-02 |
| EP1559797B1 (en) | 2013-06-05 |
| CA2493523C (en) | 2009-01-27 |
| US20050173031A1 (en) | 2005-08-11 |
| US20090223607A1 (en) | 2009-09-10 |
| TW200530409A (en) | 2005-09-16 |
| AU2005200300B2 (en) | 2007-05-03 |
| CA2493523A1 (en) | 2005-07-29 |
| TWI277658B (en) | 2007-04-01 |
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