CN1640688A - Colour glass ceramic three-dimensional pattern decorative plate - Google Patents
Colour glass ceramic three-dimensional pattern decorative plate Download PDFInfo
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- CN1640688A CN1640688A CN 200410015127 CN200410015127A CN1640688A CN 1640688 A CN1640688 A CN 1640688A CN 200410015127 CN200410015127 CN 200410015127 CN 200410015127 A CN200410015127 A CN 200410015127A CN 1640688 A CN1640688 A CN 1640688A
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Abstract
The present invention relates to a colour devitrified glass 3-D pattern decorative plate. It is characterized by that said product has 2-5000 patterns zones whose contour lines are clear and area is 4 sq.cm-1 sq.m, those devitrified glass material pattern zones are formed from 2-10 different colours of same colour with different depths or diferent mixed colours, in which it at least has two different colour zones, every colour zone is in 50%-100% of area of its pattern zone, and its thickness is up to 1 mm-60 mm. As compared with natural stone material said invented product more can express natural effect formed from lava flow, and has the advantages of low water absorption, small colour difference, high smooth finish and having not radiation element pollution, etc.
Description
Technical field
The present invention relates to be used as in a kind of microcrystal glass area construction material the imitative stone decorative material of ornament materials, particularly relate to a kind of colour devitrified glass three-D pattern dalle that is applicable in the pattern followed rock sheet material that permanent ground, metope and furniture panel decorate.It is the powder that utilizes the colour devitrified glass raw material, and the fired or product that is bonded, its goods have by 2--10 kind different color or same color but different color and luster weights of tool or different devitrified glass pattern area of mixing the clear-cut that colour cell becomes; The devitrified glass pattern area area separately of the rarest 2 kinds of different colors reaches the 5%---90% of product area in the goods, and wherein the rarest two kinds of not homochromy districts, each is in the area of the 50%---100% of its pattern area, and thickness reaches 1mm-60mm; In the intersecting area of the 1--10mm part, the ratio that the different colored material in adjacent pattern with different color district mixes mutually reaches 1: 50 to 50: 50 between the multicolour pattern in these 2 kinds of color block areas.The immitation stone plate of making therefrom as the lithotome effect more can be imitated out the product of three-D pattern effect compared to existing crystallized glass article.Adopt the imitative standard of the three-dimensional colour clocklike pattern of microcrystal glass material such as Arabescato, Snow Flower White, Dark Green, Iundra Brown, California Gilld, emerald, white jade, jasper, agate jadelike stone jade or the like top stone material, jade; Simultaneously goods of the present invention than lithotome have also that water absorption rate is low, aberration is little, advantage such as highly polished, "dead" element pollution, and become a kind of new design that quite has practicality and progressive, be suitable for the industrial circle wide popularization and application.
Background technology
Now along with the raising of development of science and technology and people's living standard, as the ornament materials of ground and metope, people wish that it has the appearance of lithotome, and the pattern of artificial grantie, marble, jade for example is to increase the top grade sense of product.
Therefore, industry is just updated the dalle structure of natural-like stone, the inventor is at glass, pottery, artificial stone, metal finishing sheet material field has multinomial China and Europe, beautiful, the developer of foreign patents such as day, as once proposing a kind of stereo ceramic granite, the patent of marble technology, its notification number is WO97/36840, on October 9th, 1997 is open, according to the made stone imitation material of this technology, its surface is formed with the pattern of clear boundary, and when standing Surface Machining, its pattern can not change basically, so can effectively promote its overall structure steadiness in the use.Yet the stone imitation material of this description of the Prior Art, boundary line between its pattern becomes vertical configuration, make colored pattern boundary transition equally hand over mixed nature,, still have a certain distance apart from people's demand so still seem not enough " natural " (natural) not as true stone material.
In order to satisfy people's practicality demand, the back inventor also once proposed a kind of " porcelain imitation granite board and manufacture method thereof ", its notification number is WO99/28262, on June 10th, 1999 is open, above-mentioned porcelain imitation granite board and manufacture method thereof, though the imitative hilllock of the porcelain stone slab that can provide user one to have more practical effect, really has progressive, but when using, reality but finds also to have in its structure deficiency, goods according to this technology only have its surperficial pattern, there are not goods at three-dimensional pattern, and not as the mobile texture that forms pattern of natural lava, so product can not reflect natural granite pattern texture from inside to outside very truly, especially the middle and lower part of limit portion does not have pattern effect, if when the exposed edge of wall that is used for furniture table-board and construction and decoration or post must want opposite side portion to carry out the edging polishing, because wherein, the bottom is not the particle pattern of one with the top layer, so have untrue in practicality than lithotome, incomplete significant deficiency.
The inventor yet once proposed ten multinomial category of glass patents, what have has just obtained patent right in 1987, as a kind of " decorating board with printed glass raster " patent wherein, its patent No. is ZL91108448.7, authorizing day is on October 17th, 1993, above-mentioned decorating board with printed glass raster and manufacture method thereof, though user one can be provided the new glass decoration sheet material that practical effect is arranged, has progressive, but when using, reality but finds also to have in its structure deficiency, goods according to this technology have just been handled one deck raster effects at the simple glass back side, though decorative effect is very magnificent, but because not at the three dimensions pattern Processing of goods, so more afterwards porcelain patent also has certain defective in practicality.
And in order to satisfy people's practicality demand, patent that the back inventor once proposed again a kind of " the three-dimensional color pattern sheet material of porcelain powder sintering ", its publication number is CN 1339363A, on March 13rd, 2002 is open, the three-dimensional color pattern sheet material of above-mentioned porcelain powder sintering, though having proposed it is the powder that utilizes the porcelain colour raw material, repressed, and the porcelain product that is fired into, its goods have different color or same color but different color and luster weights of tool or the different porcelain that mixes the clear-cut that colour cell becomes burn till pattern area, pattern area all is even distribution the 70%--100% zone from the goods top layer to bottom thickness, and can be made into the three-dimensional stone imitation material as lithotome; Though very much progress is arranged on effect, can make powder specified distribution be arranged in not homochromy district, 3-D effect is arranged, this product is too late glass product on soil resistance.And existing glass product mostly is monochrome or back and adds pattern Processing, and simultaneously, existing devitrified glass product does not all have three-D pattern, dull coloring, inflexible; And the present invention is used for devitrified glass, more can make the imitative jade of abundanter half penetrating effect, the imitative super pattern of stone material, can be used as the decorative panel of epoch-making top furniture, desk panel, top building, if adopt the devitrified glass of upper strata for feature of the present invention, make devitrified glass the three-D pattern effect occur, lower floor is the goods of ceramic sheet, then when reducing cost greatly, has improved class again.So the technology of the present invention constructed products can be used at crystallizing glass sheet material, more can solve the problem of existing crystallized glass article pattern dullness, imitative stone weak effect, be a kind of circumscribed innovative technology of existing crystallized glass article that solved revolutionaryly.
Combine by above-mentioned, the dalle of various devitrified glass natural-like stones of the prior art all can not show the sort of pattern of being made up of diverse color grains of not homochromy or same color density and powder of lithotome, and has the defective that can not copy lithotome, jade truly.
The defective that exists for the microcrystalline glass decorative plate that solves existing natural-like stone pattern, relevant manufacturer there's no one who doesn't or isn't seeks solution painstakingly, but do not see always that for a long time suitable design finished by development, this obviously is the problem that the anxious desire of relevant dealer solves.
Summary of the invention
Main purpose of the present invention is, overcome the defective of the dalle existence of existing natural-like stone, and provide a kind of colour devitrified glass three-D pattern dalle of new structure, technical problem underlying to be solved is to make it can make the three-dimensional stone imitation material that has as lithotome, or be called clone's stone natural marble, granite, the microcrystal glass material of jade, and form a kind of new board product, make the density and the position of colour devitrified glass material or porcelain mineral-type silicate starting materials local distribution can be by the feature of lithotome pattern in goods interior three-dimensional space, the manufacturing of control is arranged, and have the good effect that to copy lithotome truly.And the little pattern that contains the micro mist feature in the big pattern area of various colours can appear in the area of the pattern of clone's natural stone again, the edge transition that produces in the time of can flowing as natural lava is fine, the colourful polygon of form, many prism patterns, also have some in concave crescent shapes or many crescent shapes enrich fine pattern, and the fine pattern that also has has comprised the fritter pattern of other color, the edge of the meticulous fritter pattern that yet has is not to have a common boundary with a kind of look district, but have a common boundary with two or more more look district indentingly, the effect that generation is flowed as natural lava, especially in the processing of ceramic material micro mist, add and contain the tiny powder of 0.1mm---0.25mm to reach the effect of micro mist edge transition, and in microcrystal glass material processing, can use moisture content, low adhesive forms mobile difference, so can use diameter less than 0.1mm reach 2---5 doubly or diameter reach 2---5 powder doubly greater than 0.3mm, form the difference of flowability effect, reach the purpose of making imitative natural lava flow effect, thereby can copy more realistically such as the Arabescato in the marble, Drama White, Dark Green, Rossa Verona, Perlino Rosato, Sha Luo Hong, silver dried shrimps Huang, the gold of Rosso Norvegian and granite class is color to be bored, Giallo Veneziano, Baltic Brown, green brill, Multicolor Red, natural classical stone material such as Martiaca.
In sum, colour devitrified glass three-D pattern dalle of the present invention more can show compared to existing natural-like stone and advance the natural effect that one deck clone lithotome lava flows and forms when cloning big standard pattern.Goods of the present invention simultaneously than lithotome have also that water absorption rate is low, aberration is little, advantage such as highly polished, "dead" element pollution, be a kind of industrial circle wide popularization and application that is suitable for, quite have the new design of novelty, practicality and progressive.
Realize above-mentioned purpose, can realize by following measure:
A kind of colour devitrified glass three-D pattern of the present invention dalle is characterized in that: goods have by 2--10 kind different color or same color but different color and luster weights of tool or different 2-5000 the area that mixes the clear-cut of the microcrystal glass material that colour cell becomes reach 4cm
2-1m
2Pattern area; And wherein the rarest two kinds of not homochromy districts, each is in the area of the 50%---100% of its pattern area, and thickness reaches 1mm-60mm.
Colour devitrified glass three-D pattern dalle of the present invention is characterized in that: in the goods by 100-1,000 ten thousand areas that little devitrified glass grain is formed at 4cm
2-1m
2Pattern reach 10-100,000; The devitrified glass pattern area area separately of the rarest 2 kinds of different colors reaches the 5%---90% of product area in the goods.
Colour devitrified glass three-D pattern dalle of the present invention, it is characterized in that: in the intersecting area of the 1--10mm part, the ratio that the different colored material in adjacent pattern with different color district mixes mutually reaches 1: 50 to 50: 50 between the multicolour pattern in the goods in 2 kinds of color block areas.
Colour devitrified glass three-D pattern dalle of the present invention is characterized in that: within the wherein said pattern colour district, a kind or 1-5 kind color are arranged, by 3-1000 area at 1cm
2-150cm
2, the indent crescent shape, the polygonal pattern of being with micro mist material feature, the distance of the concave point of the straight line that two the most outstanding end points of concave crescent shape are linked to be in this and its inner fovea part is 1.5mm-10mm.
Colour devitrified glass three-D pattern dalle of the present invention, it is characterized in that: described by 2--10 kind different color or same color but the different color and luster weights of tool or different 2 or 2-50 pattern area of mixing the clear-cut of the microcrystal glass material that colour cell becomes, from the top layer or the top layer to the three dimensions of bottom thickness 70%---100%, also be provided with the piece bulk pattern that 1---5 kind diameter is formed at the colored powder material of 3mm---60mm.
Colour devitrified glass three-D pattern dalle of the present invention is characterized in that: in the described pattern area, contain the color grains material of 1---5 kind diameter at 1.5mm---30mm, the volume of this particle accounts for the 2%---80% of pattern area area.
Colour devitrified glass three-D pattern dalle of the present invention, it is characterized in that: to be the single look of red, yellow, white, blue, black, green, purple, coffee look class or two kinds mix the color lump of composition or secondary colour and the single look common color lump of forming to multiple colorant grain to described color lump mutually.
Colour devitrified glass three-D pattern dalle of the present invention is characterized in that: contain mica block in the described pattern area material.
Colour devitrified glass three-D pattern dalle of the present invention is characterized in that: the overall geometry of described goods is surface plate shape, cylindrical, cambered plate shape, partial circle cylindricality, sphere, hemispherical, awl circle shape hemispherical or the shape of justifying the moulding of shape combinatorial surface by plane and half cone.
Colour devitrified glass three-D pattern dalle of the present invention is characterized in that: its upper strata is the devitrified glass with feature of the present invention, and lower floor is the structure of porcelain plate.
Above-mentioned explanation only is the general introduction of technical solution of the present invention, for can clearer understanding technological means of the present invention, and can be implemented according to the content of specification, below with preferred embodiment of the present invention and conjunction with figs. describe in detail as after.
The specific embodiment of the present invention is provided in detail by following examples and accompanying drawing thereof.
Brief description of drawings
Fig. 1 is the planar structure schematic diagram of goods first embodiment of colour devitrified glass three-D pattern dalle of the present invention.
Fig. 2 is the structural representation of the local amplifier section in plane of look district boundary line of different color of goods first embodiment of colour devitrified glass three-D pattern dalle of the present invention.
Fig. 3 is the structural representation of the local amplifier section of section of look district boundary line of different color of goods first embodiment of colour devitrified glass three-D pattern dalle of the present invention.
Fig. 4 is the planar structure schematic diagram of the die orifice mould of the essential steel matter of goods first embodiment of colour devitrified glass three-D pattern dalle of the present invention.
Realize best mode of the present invention
Below in conjunction with accompanying drawing and preferred embodiment, the specific embodiment, structure, feature and the effect thereof of the colour devitrified glass three-D pattern dalle that foundation the present invention is proposed, describe in detail as after.
Seeing also shown in Figure 1ly, is the planar structure schematic diagram that imitative Dark Green marble first embodiment of colour devitrified glass three-D pattern dalle of the present invention is of a size of the goods of 600mm * 600mm.Pattern area (1) expression of big stain part is the blackish green district of microcrystal glass material; Pattern area (2) expression of pore part is that the microcrystal glass material powder is green, the look district of two kinds of mixed sinterings of ash; Pattern area (3) expression of oblique line part is the black chromatic color area of microcrystal glass material.
Seeing also shown in Figure 2ly, is the structural representation of the local amplifier section in plane of look district boundary line of different color of goods first embodiment of colour devitrified glass three-D pattern dalle of the present invention.Pattern area (1) expression of big stain part is the blackish green district of microcrystal glass material; Pattern area (2) expression of pore part is that microcrystal glass material is green, the look district of two kinds of powder mixed sinterings of ash; Article two, the part between the dotted line represents that blackish green colorant (1) and green, ash material (2) hand over the powder that mixes and form to hand over mixed transition region (4) naturally naturally, and the mixed ratio of the friendship of this transition region (4) reaches in 10: 50 to 30: 50.
Seeing also shown in Figure 3ly, is the structural representation of local amplifier section of look district boundary line of goods first embodiment and the different color perpendicular section in goods table plane of colour devitrified glass three-D pattern dalle of the present invention.Pattern area (1) expression of big stain part is the blackish green district of microcrystal glass material; Pattern area (2) expression of pore part is that microcrystal glass material is green, the look district of two kinds of powder mixed sinterings of ash; Article two, the part between the dotted line represents that blackish green colorant (1) and green, ash material (2) hand over the powder that mixes and form to hand over mixed transition region (4) naturally naturally, and the mixed ratio of the friendship of this transition region (4) reaches in 10: 50 to 30: 50.
Seeing also shown in Figure 4ly, is the planar structure schematic diagram of the die orifice mould of the essential steel matter of goods first embodiment of colour devitrified glass three-D pattern dalle of the present invention.Big stain represents that partly the die orifice of blackish green colorant is by district (101); Pore is partly represented, and die orifices green, two kinds of compounds of ash pass through district (102); Oblique line partly represent be the black material die orifice by the district (103); Thick black line is partly represented the head-down position on steel die orifice plane (105).
Now preparation method and the manufacturing process thereof with the colour devitrified glass three-D pattern dalle first embodiment product of the present invention specifies as follows:
(1), in making enforcement, the glass ceramics frit pellet can be by following material composition and technological principle preparation, at first prepare a kind of contain the aftermentioned composition and by with the technology composite material that composition scope (percentage by weight) mixes that is complementary, (contained composition has: SiO
255-65, AL
2O
35-10, KNaO 3-8, CaO 13-20, MgO 0-2, BaO 0-4, Ba
2O
30.5-1.5, ZnO 4-8 and an amount of fining agent and the required colouring agent of green, black, blackish green, grey isochrome); Second step was divided into composite material of all kinds, and one group of every look class is put in 1400 ℃ of-1560 ℃ of temperature and founded into glass metal; In the 3rd step, make the glass metal cooling become the glass ceramics frit grain of glass slag particle material and make its oven dry or air dry; The 4th step need be made into the required compound in goods district of all kinds with the glass ceramics frit grain by predetermined;
(2), it is first group with the blackish green colorant of microcrystal glass material (1); And each is 50% green, the grey compound is second group, and the black material is the 3rd group, and three groups of materials are respectively charged among three containers.
(3), the assembling die 10 of the die orifice of again a cover being made by product predetermined pattern shape with three big pattern colour districts is placed under the container: the raw material that make various looks are by the regulation gradation of Fig. 4 or with the pipeline mould grid areas separately that falls into simultaneously, injects, packs into.Wherein first group falls into (101) big pattern area, and second group falls into (102) big pattern area, and the 3rd group falls into (103) big pattern area.
(4), move in the plane motion of front, rear, left and right direction or vibration steel matter mould 10 with high speed machine, forming not, the powder in homochromy zone has certain friendship naturally to mix shape at intersection, form the three-dimensional structure of imitative Dark Green marble pattern very truly, make each colorant fall into the special use that is added with separating powder and burn till and reach 30mm thickness on the supporting plate, add fixative by the die orifice of pattern requirement by assembling die 10.
(5), send in the roller kilns then and burn till.Sintering process is a three phases, phase I is the temperature rise period, from 0 ℃ of-870 ℃ of particle bond, eliminate gradually in the space, begins crystallization from the interface to 980 ℃, particle is melted fully be integral body and abundant crystallization, second stage is finished from 1000 ℃ of-1240 ℃ of crystallizatioies, form the material that nucleus, crystalline phase are evenly distributed, the phase III begins progressively to lower the temperature and is cooled to room temperature, and whole firing period is 3-5 hour.
(6), through the demoulding from supporting plate, the polishing after, promptly obtain the marmorean goods of imitative Dark Green of the present invention.
The above, only be for preferable preferred embodiment of the present invention is described, yet it is not to be limitation of the present invention, any personnel that are familiar with this technology may utilize the technology contents of above-mentioned prompting to be changed or be modified to the equivalent embodiment of equivalent variations, every content that does not break away from technical solution of the present invention, to any simple modification that above embodiment did, equivalent variations and modification all still belong in the scope of technical solution of the present invention according to technical spirit of the present invention.
Industrial applicability
The present invention is to the structure of imitating natural marble, granite, penetrating or half penetrating jade decorating plate material Carried out further improvement, its structure simulation is splendid, and than natural stone also have water absorption rate low, Aberration is little, highly polished, the advantage of "dead" element pollution, more is suitable in the use practicality, And can be by the machining mass industrialized production so that manufacturing cost reduces relatively, meet through The Ji benefit, and quite have the extensive value of industry.
Claims (10)
1, a kind of colour devitrified glass three-D pattern dalle is characterized in that: goods have by 2--10 kind different color or same color but different color and luster weights of tool or different 2-5000 the area that mixes the clear-cut of the microcrystal glass material that colour cell becomes reach 4cm
2-1m
2Pattern area; And wherein the rarest two kinds of not homochromy districts, each is in the area of the 50%---100% of its pattern area, and thickness reaches 1mm-60mm.
2, colour devitrified glass three-D pattern dalle according to claim 1 is characterized in that: in the goods by 100-1,000 ten thousand areas that little devitrified glass grain is formed at 4cm
2-1m
2Pattern reach 10-100,000; The devitrified glass pattern area area separately of the rarest 2 kinds of different colors reaches the 5%---90% of product area in the goods.
3, colour devitrified glass three-D pattern dalle according to claim 1, it is characterized in that: in the intersecting area of the 1--10mm part, the ratio that the different colored material in adjacent pattern with different color district mixes mutually reaches 1: 50 to 50: 50 between the multicolour pattern in the goods in 2 kinds of color block areas.
4, colour devitrified glass three-D pattern dalle according to claim 1 is characterized in that: within the wherein said pattern colour district, a kind or 1-5 kind color are arranged, by 3-1000 area at 1cm
2-150cm
2, the indent crescent shape, the polygonal pattern of being with micro mist material feature, the distance of the concave point of the straight line that two the most outstanding end points of concave crescent shape are linked to be in this and its inner fovea part is 1.5mm-10mm.
5, colour devitrified glass three-D pattern dalle according to claim 1, it is characterized in that: described by 2--10 kind different color or same color but the different color and luster weights of tool or different 2 or 2-50 pattern area of mixing the clear-cut of the microcrystal glass material that colour cell becomes, from the top layer or the top layer to the three dimensions of bottom thickness 70%---100%, also be provided with the piece bulk pattern that 1---5 kind diameter is formed at the colored powder material of 3mm---60mm.
6, colour devitrified glass three-D pattern dalle according to claim 1, it is characterized in that: in the described pattern area, contain the color grains material of 1---5 kind diameter at 1.5mm---30mm, the volume of this particle accounts for the 2%---80% of pattern area area.
7, colour devitrified glass three-D pattern dalle according to claim 1, it is characterized in that: to be the single look of red, yellow, white, blue, black, green, purple, coffee look class or two kinds mix the color lump of composition or secondary colour and the single look common color lump of forming to multiple colorant grain to described color lump mutually.
8, colour devitrified glass three-D pattern dalle according to claim 1 is characterized in that: contain mica block in the described pattern area material.
9, colour devitrified glass three-D pattern dalle according to claim 1 is characterized in that: the overall geometry of described goods is surface plate shape, cylindrical, cambered plate shape, partial circle cylindricality, sphere, hemispherical, awl circle shape hemispherical or the shape of justifying the moulding of shape combinatorial surface by plane and half cone.
10, colour devitrified glass three-D pattern dalle according to claim 1, it is characterized in that: its upper strata is the devitrified glass with feature of the present invention, lower floor is the structure of porcelain plate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410015127 CN1640688A (en) | 2004-01-15 | 2004-01-15 | Colour glass ceramic three-dimensional pattern decorative plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410015127 CN1640688A (en) | 2004-01-15 | 2004-01-15 | Colour glass ceramic three-dimensional pattern decorative plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1640688A true CN1640688A (en) | 2005-07-20 |
Family
ID=34867936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410015127 Pending CN1640688A (en) | 2004-01-15 | 2004-01-15 | Colour glass ceramic three-dimensional pattern decorative plate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1640688A (en) |
-
2004
- 2004-01-15 CN CN 200410015127 patent/CN1640688A/en active Pending
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Open date: 20050720 |